US2047873A - Free cutting alloys - Google Patents
Free cutting alloys Download PDFInfo
- Publication number
- US2047873A US2047873A US52667A US5266735A US2047873A US 2047873 A US2047873 A US 2047873A US 52667 A US52667 A US 52667A US 5266735 A US5266735 A US 5266735A US 2047873 A US2047873 A US 2047873A
- Authority
- US
- United States
- Prior art keywords
- per cent
- alloy
- aluminum
- lead
- alloys
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 229910045601 alloy Inorganic materials 0.000 title description 49
- 239000000956 alloy Substances 0.000 title description 49
- 238000005520 cutting process Methods 0.000 title description 11
- 229910052782 aluminium Inorganic materials 0.000 description 29
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 29
- 229910052797 bismuth Inorganic materials 0.000 description 17
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 17
- 229910052802 copper Inorganic materials 0.000 description 16
- 239000010949 copper Substances 0.000 description 16
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 15
- 238000007792 addition Methods 0.000 description 7
- 238000003754 machining Methods 0.000 description 7
- 230000000704 physical effect Effects 0.000 description 4
- 229910000881 Cu alloy Inorganic materials 0.000 description 3
- WPPDFTBPZNZZRP-UHFFFAOYSA-N aluminum copper Chemical compound [Al].[Cu] WPPDFTBPZNZZRP-UHFFFAOYSA-N 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000010791 quenching Methods 0.000 description 3
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000007669 thermal treatment Methods 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- 229910001369 Brass Inorganic materials 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 230000002301 combined effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/003—Alloys based on aluminium containing at least 2.6% of one or more of the elements: tin, lead, antimony, bismuth, cadmium, and titanium
Definitions
- This invention relates to aluminum base alloys and is particularly concerned with alloys of this nature containing substantial amounts of copper.
- Aluminum alloys for instance, containing from about 4 per cent to about 12 per cent of copper have a wide range of usefulness because of their favorable mechanical properties and their susceptibility to improvement by suitable thermal treatments.
- Mechanical cutting operations such as boring, I15 drilling, Planing, or lathe-cutting are successfully carriedout only by using certain precautions which increase the expense of the operation and which occasionally necessitate the substitution of another alloy which may be machined more readily but is otherwise not so desirable from the standpoint of physical properties.
- the ma-- Another object is to provide an aluminum base alloy that can have its physical properties improved by suitable thermal treatments and yet retain its good machining quality. Still another object is to provide a free cutting aluminum base alloy containing from 4 to 12 per cent copper, whose fundamental physical properties are not substantialy impaired by the addition of elements designed to improve the machinability. We have discovered that the addition of lead and bismuth to an aluminum base alloy containing from 4 to 12 per cent copper, greatly improves the machining quality of the base alloy without detracting from its other properties.
- the total amount of the two elements may vary between about 0.1 and 10 per cent.
- the amount of lead and bismuth to be employed in a particular case is to be determined by the properties desired in the alloy. 5 Where strength is an important consideration, the amount of these two elements should be kept relatively low. Where other properties are of greater importance 9, larger proportion of lead may be used with a resultant decrease in the 10 I strength.
- the basic nature of the alloy is not changed, however, by the presence of a large amount of lead, and the alloy is still readily machinable. In the making 01. wrought alloys we prefer to employ from about 4 to 6 per cent 15 copper, from about 0.2 to 1.5 per cent lead and from about 0.2 to 1.5 per cent bismuth, with a total of lead and bismuth varying between about 0.5 to 3.0 per cent.
- our alloy in the un-heat treated condition has a better machining quality than a binary aluminum-copper alloy having the same copper content, the advantageous properties of our composition are most apparent when the alloy is heat treated. For some applications it is sufiicient to simply heat treat and quench the alloy, while for other types of service a stronger material is needed and consequently the alloy should be aged after quenching.
- the heat treatment to be employed is of the well known type,
- the alloy is then quickly cooled to a much lower temperature, usually room temperature, by quenchingin water or some other liquid medium.
- the alloy may then be aged, if desired, by reheating to between 200 and 350 F. for several hours or longer, depending on the degree of strength desired.
- the lead and bismuth may be added directly to the molten aluminum base alloy in solid metallic form, since these elements melt at a temperature considerably below that of aluminum. 20 However, since there is a great diflerence between the specific gravity of aluminum and that of lead and bismuth, and in view of the limited solid solubility of these elements in aluminum, the
- aluminum as used herein and in the appended claims embraces the usual impurities found in aluminum ingot of commercial grade or picked up in the course of the usual handling operations incident to ordinary melting practice.
- An aluminum base alloy consisting of from about 4 to 12 per cent copper, from about 0.05 to 10 per cent lead, and 0.05 to 1.5 per cent bismuth, the balance being aluminum.
- An aluminum base alloy consisting of from about 4 to 6 per cent copper, from about 0.2 to 1.5 per cent lead, and 0.2 to 1.5 per cent bismuth, the balance being aluminum.
- An aluminum base alloy consisting of about 6 per cent copper, 0.5 per cent lead, and 0.5 per cent bismuth, the balance being aluminum.
- An aluminum base alloy consisting of from about 4 to 12 per cent copper, from about 0.05 to 10 per cent lead, from about 0.05 to 1.5 per cent 50 bismuth, and from about 0.05 to 1 per cent of at least one of the elements of the group composed of titanium, vanadium, molybdenum, tungsten, zirconium, manganese and chromium, the total amount of said hardening elements not exceeding about 2 per cent, the balance of the alloy being aluminum.
- An aluminum base alloy consisting of from about 4 to 6 per cent copper, from about 0.2 to
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Conductive Materials (AREA)
Description
' Patented July 14, 1936 FREE CUTTING ALLOYS Louis w. Kempi' and Walter A. Dean, flleveland, Ohio, assignors to Aluminum Company oi America, Pittsburgh, Pa.,
Pennsylvania a corporation of v No Drawing. Application December a, 1935,
, Serial No. 52,667 I Claims. (Cl. 75-139) This invention relates to aluminum base alloys and is particularly concerned with alloys of this nature containing substantial amounts of copper.
Despite the manifold advantages connected 5 with the use of aluminum and its alloys in commercial fields, there is an inherent drawback which somewhat curtails their use in certain potential adaptations. Aluminum alloys, for instance, containing from about 4 per cent to about 12 per cent of copper have a wide range of usefulness because of their favorable mechanical properties and their susceptibility to improvement by suitable thermal treatments. Mechanical cutting operations, however, such as boring, I15 drilling, Planing, or lathe-cutting are successfully carriedout only by using certain precautions which increase the expense of the operation and which occasionally necessitate the substitution of another alloy which may be machined more readily but is otherwise not so desirable from the standpoint of physical properties. When alloys are difficult to machine this disadvantage becomes evident, in many cases, through rapid wear of the cutting tool edge which necessitates frequent resharpening. In such cases where machining is dimcult, continual lubrication is required, the ma-- Another object is to provide an aluminum base alloy that can have its physical properties improved by suitable thermal treatments and yet retain its good machining quality. Still another object is to provide a free cutting aluminum base alloy containing from 4 to 12 per cent copper, whose fundamental physical properties are not substantialy impaired by the addition of elements designed to improve the machinability. We have discovered that the addition of lead and bismuth to an aluminum base alloy containing from 4 to 12 per cent copper, greatly improves the machining quality of the base alloy without detracting from its other properties. Additions of from about 0.05 to 10 per cent of I lead and 0.05 1.5 per cent of bismuth accom- Plish this purpose. The total amount of the two elements may vary between about 0.1 and 10 per cent. The amount of lead and bismuth to be employed in a particular case is to be determined by the properties desired in the alloy. 5 Where strength is an important consideration, the amount of these two elements should be kept relatively low. Where other properties are of greater importance 9, larger proportion of lead may be used with a resultant decrease in the 10 I strength. The basic nature of the alloy is not changed, however, by the presence of a large amount of lead, and the alloy is still readily machinable. In the making 01. wrought alloys we prefer to employ from about 4 to 6 per cent 15 copper, from about 0.2 to 1.5 per cent lead and from about 0.2 to 1.5 per cent bismuth, with a total of lead and bismuth varying between about 0.5 to 3.0 per cent.
Certain aluminum base alloys, such as one 20 composed of aluminum, 8 per cent copper and 5 per cent tin, have been made heretofore which are readily machinable but this property has been obtained, we have observed, at the expense of other properties such as strength, workability 25 and ductility. We have determined that these disadvantages may be overcome by combining copper, bismuth and lead with aluminum in suit able proportions. Although we have found that. the addition of bismuth or lead alone to alumi- 30 num-copper'alloys greatly improves their machining quality, we have now discovered that an even better machinability is obtained by usin both lead and bismuth. This improvement is gained by a co-action between the two elements 35 which has not as yet been explained. The combined effect of the two elements is, however, quite pronounced and unexpected in view of the behavior oi each one alone in aluminum-copper alloys. 40
We have furthermore found a readily machinable alloy that can be improved by the heat treating and aging process,well known in the aluminum alloy art. The well known heat treated aluminum base alloys heretofore employed usually possess 5 a sufllcient degree of machinability for ordinary machining operations, but they are not so well adapted to the manufacture of. screw machine products with respect to their free cutting qual ty. Such alloys do, however, possess an adequate strength for screw machine parts which is quite essential in view of the small dimensions of these parts andthe magnitude of the stresses to which they are often subjected in service. An alloy has long been sought which would combine the high 55 posed of 6.0 per cent copper, 0.5 per cent lead water.
strength of the well known heat treated alloys and the degree of machinability found in free cutting brass alloys; We have discovered that these apparently divergent properties are combined in our improved alloy. More particularly, we have found that the addition of lead and bismuth to an aluminum-copper alloy does not destroy the response of said alloy to solution heat treatment and aging, nor do these additions substantially alter the fundamental characteristics of the base alloy.
Although our alloy in the un-heat treated condition has a better machining quality than a binary aluminum-copper alloy having the same copper content, the advantageous properties of our composition are most apparent when the alloy is heat treated. For some applications it is sufiicient to simply heat treat and quench the alloy, while for other types of service a stronger material is needed and consequently the alloy should be aged after quenching. The heat treatment to be employed is of the well known type,
namely, heating at a temperature above about 850 F. for a sumcient length of time to obtain a substantial degree of solution of the soluble constituents. Upon obtaining this condition the alloy is then quickly cooled to a much lower temperature, usually room temperature, by quenchingin water or some other liquid medium. The alloy may then be aged, if desired, by reheating to between 200 and 350 F. for several hours or longer, depending on the degree of strength desired.
The improvement in physical properties mentioned hereinabove is exemplified in an alloy comand 0.5 per cent bismuth, the balance being aluminum. This alloy was cast in ingot form and rolled to inch rod. Sections of the rod were then heat treated at 960 F. and quenched in In this condition the alloy had a tensile strength of 44,800 pounds per square inch, a yield strength of 16,700 pounds per square inch, and an elongation of 24.5 per cent in 2 inches. When aged at 310 F. after quenching, the alloy developed atensile strength of 56,400 pounds per square inch, a yield strength of 31,700 pounds per squareinch, and an elongation of 22 per cent in 2 inches. These figures compare favorably with a wrought alloy composed of aluminum and 6 per cent copper, which when heat treated and aged, possessed .an average tensile strength of 58,000 pounds per square inch, a yield strength of 30,000 pounds per square inch, and an elonon an ordinary lathe or on an automatic screw machine, small, easily breakable chips are produced which fall away from the cutting tool as rapidly as they are formed. Furthermore, a smooth pleasing surface is left on the machined article which enhances its appearance'and obviates the necessity of a subsequent finishing operation. On the other hand under the same conditions of machining, aluminum base alloys which are notfree cutting will produce relatively long, tough chips, often in the form of spirals, which tend to accumulate around the cutting tool and unlessremoved. by the operator, they may foul the tool and mar the surface of the piece being camera machined. The surface of the machined product is also not as satisfactory as that where our improved alloy is employed.
In the production of certain articles it sometimes becomes desirable to increase the strength, 5 hardness or 'control the grain size of the alloy beyond that which is ordinarily obtainable. We have discovered that the addition of one or more of the group of elements composed of molybdenum, vanadium, titanium, tungsten, zirconium, 10 manganese, and chromium act as hardeners without changing the fundamental characteristics of the alloy. From about 0.05 to 1 per cent of any one of these elements may be used alone, but where more than one is employed the total 15 amount should not exceed about 2 per cent.
The lead and bismuth may be added directly to the molten aluminum base alloy in solid metallic form, since these elements melt at a temperature considerably below that of aluminum. 20 However, since there is a great diflerence between the specific gravity of aluminum and that of lead and bismuth, and in view of the limited solid solubility of these elements in aluminum, the
molten alloy. containing lead and bismuth must 25 be vigorously stirred to obtain a uniform distribution of these elements throughout the mass. A satisfactory method of adding such elements to aluminum is more fully described in U. S. Patent No. 1,959,029, issued March 15, 1934.
The term aluminum as used herein and in the appended claims embraces the usual impurities found in aluminum ingot of commercial grade or picked up in the course of the usual handling operations incident to ordinary melting practice.
We claim: v
1. An aluminum base alloy consisting of from about 4 to 12 per cent copper, from about 0.05 to 10 per cent lead, and 0.05 to 1.5 per cent bismuth, the balance being aluminum.
2. An aluminum base alloy consisting of from about 4 to 6 per cent copper, from about 0.2 to 1.5 per cent lead, and 0.2 to 1.5 per cent bismuth, the balance being aluminum.
3. An aluminum base alloy consisting of about 6 per cent copper, 0.5 per cent lead, and 0.5 per cent bismuth, the balance being aluminum.
4. An aluminum base alloy consisting of from about 4 to 12 per cent copper, from about 0.05 to 10 per cent lead, from about 0.05 to 1.5 per cent 50 bismuth, and from about 0.05 to 1 per cent of at least one of the elements of the group composed of titanium, vanadium, molybdenum, tungsten, zirconium, manganese and chromium, the total amount of said hardening elements not exceeding about 2 per cent, the balance of the alloy being aluminum.
5. An aluminum base alloy consisting of from about 4 to 6 per cent copper, from about 0.2 to
LOUIS W. KEMPF.
WALTER A. DEAN. go
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US52667A US2047873A (en) | 1935-12-03 | 1935-12-03 | Free cutting alloys |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US52667A US2047873A (en) | 1935-12-03 | 1935-12-03 | Free cutting alloys |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2047873A true US2047873A (en) | 1936-07-14 |
Family
ID=21979113
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US52667A Expired - Lifetime US2047873A (en) | 1935-12-03 | 1935-12-03 | Free cutting alloys |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2047873A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2706680A (en) * | 1952-02-27 | 1955-04-19 | Aluminum Co Of America | Aluminum base alloy |
| US3466907A (en) * | 1966-01-03 | 1969-09-16 | Lincoln Electric Co | Metal ribbon,welding electrodes and method and apparatus for forming same |
| JPS5118205A (en) * | 1974-08-06 | 1976-02-13 | Sumitomo Electric Industries | KAISAKUSEIARUMINIUMUGOKIN |
-
1935
- 1935-12-03 US US52667A patent/US2047873A/en not_active Expired - Lifetime
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2706680A (en) * | 1952-02-27 | 1955-04-19 | Aluminum Co Of America | Aluminum base alloy |
| US3466907A (en) * | 1966-01-03 | 1969-09-16 | Lincoln Electric Co | Metal ribbon,welding electrodes and method and apparatus for forming same |
| JPS5118205A (en) * | 1974-08-06 | 1976-02-13 | Sumitomo Electric Industries | KAISAKUSEIARUMINIUMUGOKIN |
| JPS5638668B2 (en) * | 1974-08-06 | 1981-09-08 |
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