US2166325A - Treatment of cellulosic material - Google Patents
Treatment of cellulosic material Download PDFInfo
- Publication number
- US2166325A US2166325A US50870A US5087035A US2166325A US 2166325 A US2166325 A US 2166325A US 50870 A US50870 A US 50870A US 5087035 A US5087035 A US 5087035A US 2166325 A US2166325 A US 2166325A
- Authority
- US
- United States
- Prior art keywords
- treatment
- wax
- emulsion
- cellulose
- cellulosic material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 title description 8
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 13
- 239000001993 wax Substances 0.000 description 12
- 239000011347 resin Substances 0.000 description 11
- 229920005989 resin Polymers 0.000 description 11
- 239000000835 fiber Substances 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- 229920002678 cellulose Polymers 0.000 description 7
- 239000001913 cellulose Substances 0.000 description 7
- 239000000839 emulsion Substances 0.000 description 7
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000012182 japan wax Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000012260 resinous material Substances 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 2
- 229920002955 Art silk Polymers 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003467 diminishing effect Effects 0.000 description 1
- 229910000397 disodium phosphate Inorganic materials 0.000 description 1
- 235000019800 disodium phosphate Nutrition 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 235000013773 glyceryl triacetate Nutrition 0.000 description 1
- 239000001087 glyceryl triacetate Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- QUBQYFYWUJJAAK-UHFFFAOYSA-N oxymethurea Chemical compound OCNC(=O)NCO QUBQYFYWUJJAAK-UHFFFAOYSA-N 0.000 description 1
- 229950005308 oxymethurea Drugs 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 229960002622 triacetin Drugs 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
Definitions
- My present invention relates to a process of treating cellulosic fibers.
- One of its objects is an improved process of making resistant to washing cellulosic fibers treated with resins. Further objects will be seen from the detailed specification following hereafter.
- the present invention produces a great improvement in the application of the resins in question for diminishing the tendency of cellulosic fibers or fabrics to crease in that this resistance is attained without material diminution of softness of feel and with retention of resistance of the resinous material to removal by washing.
- the cellulosic material before it is impregnated with resin or sub stances which yield resin, is soaked in a solution or emulsion of wax.
- the operation may consist in thoroughly saturating the fiber or the fabric with a suitably composed emulsion of wax, then centrifuging or pressing and finally subjecting the material to the usual impregnation with resin.
- wax liquor can be added directly to the bath which is to impart resitance to creasing, so that As waxes may be used natural or artificial waxes, as well as products resembling wax, although not being strictly waxes in their chemical composition.
- the process may also be conducted by first impregnating the cellulose material with the solution of wax and a compound having the ter dency to accelerate the condensation with formaldehyde to produce resin and, after drying, treating the goods with formaldehyde vapour at a raised temperature.
- the goods to be treated are saturated with an emulsion of 3 per cent. strength of equal parts of Japan wax and the sodium salt of oleic-acid- N-methyl-tauride, the operation being conducted in a vat or on afoulard at ordinary temperature; the goods are then pressed to a content of approximately per cent. moisture.
- the goods are introduced into a solution of dimethylol-urea of 20 per cent. strength and at a temperature of 50-60 C., which also contains 6 grams each per litre of monoand di-sodium phosphate; pressing to a content of 100 per cent. moisture and drying under tension, so that no folds or creases can be produced, follow.
- the goods are subjected to the usual condensation at a raised temperature.
- the cellulose material to be treated is saturated with an emulsion of wax of 3 per cent. strength as specified in Example 1 but with addition of 6 grams each per litre of monoand disodium-phosphate, then pressed or centrifuged, dried under tension and finally treated in a closed vessel for 2 hours at 120 C., under pressure, with vapour of formaldehyde.
- cellulosic fibers is intended to include fibers of cellulose such as cotton and fibers of cellulose hydrate such as viscose artificial silk.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Reinforced Plastic Materials (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2166325X | 1934-11-23 | ||
DE503679X | 1936-10-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
US2166325A true US2166325A (en) | 1939-07-18 |
Family
ID=32070604
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US50870A Expired - Lifetime US2166325A (en) | 1934-11-23 | 1935-11-21 | Treatment of cellulosic material |
Country Status (5)
Country | Link |
---|---|
US (1) | US2166325A (cs) |
BE (2) | BE411982A (cs) |
FR (2) | FR797005A (cs) |
GB (2) | GB451082A (cs) |
NL (1) | NL43947C (cs) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3116967A (en) * | 1958-01-09 | 1964-01-07 | Sun Chemical Corp | Creaseproofing compositions for textiles |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE753610C (de) * | 1941-04-08 | 1951-08-02 | I P Bemberg A G | Verfahren zur Steigerung der Gebrauchstuechtigkeit von Seilen aus Cellulosehydratfasern |
-
0
- BE BE423647D patent/BE423647A/xx unknown
-
1935
- 1935-01-25 GB GB2525/35A patent/GB451082A/en not_active Expired
- 1935-10-07 NL NL75075A patent/NL43947C/xx active
- 1935-10-28 BE BE411982D patent/BE411982A/xx unknown
- 1935-10-28 FR FR797005D patent/FR797005A/fr not_active Expired
- 1935-11-21 US US50870A patent/US2166325A/en not_active Expired - Lifetime
-
1937
- 1937-09-17 FR FR48867D patent/FR48867E/fr not_active Expired
- 1937-10-12 GB GB27713/37A patent/GB503679A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3116967A (en) * | 1958-01-09 | 1964-01-07 | Sun Chemical Corp | Creaseproofing compositions for textiles |
Also Published As
Publication number | Publication date |
---|---|
GB451082A (en) | 1936-07-27 |
BE411982A (cs) | 1935-11-30 |
GB503679A (en) | 1939-04-12 |
NL43947C (cs) | 1938-09-15 |
FR797005A (fr) | 1936-04-20 |
BE423647A (cs) | |
FR48867E (fr) | 1938-09-19 |
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