US2133845A - Corrosion resistant tubular article - Google Patents

Corrosion resistant tubular article Download PDF

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Publication number
US2133845A
US2133845A US71806A US7180636A US2133845A US 2133845 A US2133845 A US 2133845A US 71806 A US71806 A US 71806A US 7180636 A US7180636 A US 7180636A US 2133845 A US2133845 A US 2133845A
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United States
Prior art keywords
tin
aluminum
phosphorus
tubular article
dilute acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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US71806A
Inventor
Donald K Crampton
Newell W Mitchell
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chase Brass and Copper Co Inc
Original Assignee
Chase Brass and Copper Co Inc
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Publication date
Application filed by Chase Brass and Copper Co Inc filed Critical Chase Brass and Copper Co Inc
Priority to US71806A priority Critical patent/US2133845A/en
Application granted granted Critical
Publication of US2133845A publication Critical patent/US2133845A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper
    • C22C9/01Alloys based on copper with aluminium as the next major constituent
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L58/00Protection of pipes or pipe fittings against corrosion or incrustation
    • F16L58/02Protection of pipes or pipe fittings against corrosion or incrustation by means of internal or external coatings
    • F16L58/04Coatings characterised by the materials used
    • F16L58/08Coatings characterised by the materials used by metal

Definitions

  • This invention relates to improvements in corrosion-resistant tubular articles, and more particularly, corrosion-resistant wrought-metal tubular articles formed of copper-base alloys con- 5 taining phosphorus, aluminum and tin, with or without the addition of one or more other elements which do not seriously impair the prop saline liquid or dilute acid.
  • the additional elemerits may range up to a total of about 10%, depending on what elements are added, some being more innocuous than others. While each of the elements iron, antimony and arsenic should not be present much in excess of about 0.1%, silver, which is comparatively innocuous, may be present to as high as about 10% provided not too much of other elements is present.
  • Nickel may be present to as high as about 5%, and lead and silicon may each be present to ashigh as about o o
  • the total of the phosphorus, aluminum and tin preferably should not be greater than about 7 with the phosphorus from about to about 2%, the aluminum from about to about 4%, and the tin from about to about 3 Stillbetter workability of the metal is had when the total of the phosphorus, aluminum and tin does not exceed about 5 /2%, with the 45 phosphorus from about to about 1' /2%.' the aluminum from about A% to about'3%, andthe tin from about to about 2%.
  • An advantageous alloy range consists in having the phosphorus from about. /2% to about 55 phorus, about 7 aluminum and about 3% tin, 1
  • the second having about 1% phosphorus, about 1% aluminum and about 2% tin, and the third having about 1% phosphorus, about 1 alu minum and about 1 tin.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Treatment Of Metals (AREA)

Description

; Patented Oct. 18,1938
CORROSION RESISTANT room ARTICLE Donald K. Crampton, Marion, and Newell W. Mitchell, Waterbury, Conn., assignors to Chase Brass a Copper (30., Incorporated, Waterbury, Conn., a corporation of Connecticut j No Drawing.
Application March 30, 1936,
Seria1N0.71,806 6 Claims. (01. 138-47) This invention relates to improvements in corrosion-resistant tubular articles, and more particularly, corrosion-resistant wrought-metal tubular articles formed of copper-base alloys con- 5 taining phosphorus, aluminum and tin, with or without the addition of one or more other elements which do not seriously impair the prop saline liquid or dilute acid. The additional elemerits may range up to a total of about 10%, depending on what elements are added, some being more innocuous than others. While each of the elements iron, antimony and arsenic should not be present much in excess of about 0.1%, silver, which is comparatively innocuous, may be present to as high as about 10% provided not too much of other elements is present. Nickel may be present to as high as about 5%, and lead and silicon may each be present to ashigh as about o o In order that our improved alloys may be wrought to make tubular articles such, for ex- 35 ample, as tubes, pipes, etc., for conveying or holding or otherwise contacting corrosive liquids, the total of the phosphorus, aluminum and tin preferably should not be greater than about 7 with the phosphorus from about to about 2%, the aluminum from about to about 4%, and the tin from about to about 3 Stillbetter workability of the metal is had when the total of the phosphorus, aluminum and tin does not exceed about 5 /2%, with the 45 phosphorus from about to about 1' /2%.' the aluminum from about A% to about'3%, andthe tin from about to about 2%.
An advantageous alloy range consists in having the phosphorus from about. /2% to about 55 phorus, about 7 aluminum and about 3% tin, 1
the second having about 1% phosphorus, about 1% aluminum and about 2% tin, and the third having about 1% phosphorus, about 1 alu minum and about 1 tin. v
The invention maybe carried out in other specific ways than those herein set forth without departing from the spirit and essential char- 1 1. acteristics of the invention, and the present embodiments are therefore to be considered in all respects as illustrative and not restrictive, and all'changes coming within the meaning and equivalency rangeof the appended claims are,-
intended to be embraced therein.
We claim: a V
1. A wrought-metal tubulararticle for use in contact with ,saline liquid or dilute acid and characterized by good corrosion resistance to saline liquid anddilute acid, and formed from an alloy containing: phosphorus as an essential element iromjabout toabout 2%; aluminum 2 from about 4% toabout 4%; tin from about U to about 3%; and the balance substantially I of copper. v v
2. A wrought-metal tubular article for use in contact with saline liquid or dilute acid and characterized by good corrosion resistance to saline liquid and dilute acid and formed from an alloy containing: phosphorus as an essential element from about A% to about 2%; aluminum from about 4% to about 4%; tin from about 2% to about 3%%; the sum of the phosphorus, aluminum andtin being not greater than-7.5%; and the balance substantially of copper.v
3. A wrought-metal tubular article for usein' contact with saline liquid or dilute acid and characterized by good corrosion resistance to saline liquid and-dilute acid and formed from an alloy containing: phosphorus as an essential element from about to about 1 aluminum from about to about 3%; tin from 40 about 1% to about 3%; and the balance subv stantially of copper.
4. A wrought-metal tubular article for 'use in contact with saline liquid on dilute acid and characterized by good corrosion resistance to saline liquid and dilute acid and formed from an alloy containing: phosphorusas an essential element about aluminum, about /4,%; tin about"3%; and the balance substantially of coppen I p 5. A wrought-metal tubular article for. use in contact with saline liquid or dilute acid and characterized by good corrosion resistance to saline liquid and dilute acid and formed from an alloy 7 containing: phosphorus as an essential element o about 1%;- aluminum about 1%; tin about 2%; alloy containing: phosphorusas an essentialeleand the balance substantially of copper. ment about 1%; aluminum about 1 5%; tin 6. A wrought-metal tubular article for use in about 1 and the balance substantially of contact with saline liquid or dilute acid and copper.
characterized by good corrosion resistance to DONALD K. CRAMPTON. 5 saline liquid and dilute acid and formed from an 7 NEWELL W. MITCHELL.
US71806A 1936-03-30 1936-03-30 Corrosion resistant tubular article Expired - Lifetime US2133845A (en)

Priority Applications (1)

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US71806A US2133845A (en) 1936-03-30 1936-03-30 Corrosion resistant tubular article

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US2133845A true US2133845A (en) 1938-10-18

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4436790A (en) 1981-04-23 1984-03-13 Vereinigte Deutsch Metallwerke Ag Gold-colored coin material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4436790A (en) 1981-04-23 1984-03-13 Vereinigte Deutsch Metallwerke Ag Gold-colored coin material

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