US2317980A - Magnesium-base alloy - Google Patents

Magnesium-base alloy Download PDF

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Publication number
US2317980A
US2317980A US413159A US41315941A US2317980A US 2317980 A US2317980 A US 2317980A US 413159 A US413159 A US 413159A US 41315941 A US41315941 A US 41315941A US 2317980 A US2317980 A US 2317980A
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US
United States
Prior art keywords
magnesium
alloy
manganese
base alloy
lithium
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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US413159A
Inventor
Reginald S Dean
Clarence T Anderson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHIEAGO DEV Co
CHIEAGO DEVELOPMENT Co
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CHIEAGO DEV Co
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Publication date
Application filed by CHIEAGO DEV Co filed Critical CHIEAGO DEV Co
Priority to US413159A priority Critical patent/US2317980A/en
Priority to US443824A priority patent/US2376868A/en
Application granted granted Critical
Publication of US2317980A publication Critical patent/US2317980A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C23/00Alloys based on magnesium

Definitions

  • manganese brings about the least reduction of corrosion resistance.
  • manganese may be incorporated into magnesium in substantial amounts, in a relatively simple manner, with- "outihterfering with the desired homogeneity of the resulting alloy.
  • the amount of manganese which ordinarily can be incorporated with the magnesium without efiecting production of a non-homogeneous alloy may be substantially increased.
  • the amount of manganese which may be incorporated with the magnesium to produce a homogeneous alloy is determined, in part, by the amount of lithium which is present.
  • lithium for'example, with 5% lithium, .of manganese may be readily incorporated into magnesium with the production of a homogeneous alloy.
  • the alloys of our invention contain from about 1% to about 10% lithium, from about 2% to about 10% manganese, balance substantially all magnesium.
  • magnesiumbase alloys used for the commercial melting of magnesiumbase alloys may be used to protect the surface of the metal during melting.
  • the alloy when cast, had a hardness of 27 when measured on the Rockwell F scale.
  • the alloy may be cold rolled by any of the usual processes. When substan-' tially fully cold worked to form a sheet, it has a hardness of measured on the Rockwell 1 scale.
  • the alloy is considerably harder and stronger than at least most other magnesium base alloys which have heretofore been made available. This increased hardness and strength make the alloy particularly valuable for the construction of various parts'oi airplanes.
  • Example 2 An alloy was made containing 83% magnesium, 10% manganese, 5% lithium, and 2% silver, said alloy being prepared from the same grade of a1- loying elements and in the same manner as described in Example 1.
  • the resulting alloy when cast, is considerably harder than the alloy of- Example 1.
  • the density of the alloy was approximately 2.0. This alloy, like that of the first example, lends itself to all of the usual forms of cold working.
  • the magnesium as we have indicated, is preferably a redistilled product.
  • the manganese for best results, should be at least 99.0% pure and preferably of even greater purity.
  • the manganese utilized may be produced by a vacuum distillation process but we prefer, particularly, to employ electrolytic manganese having a purity of at least about 99.0% and preferably of 99.9%.
  • the lithium, and silver where used, are also preferably of a high degree of purity.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Printing Plates And Materials Therefor (AREA)

Description

...i an");
atenieti May ETEE MAGNESKUM-BASE ALLOY Reginald S. Dean and i'llarence T. Anderson,
Salt e City, Utah, ignore to Chicago Development Company, Chicago, 111., a corporatime or lillinois No Drawing. Application ilctober l, lilill, Serial No. 413,159
3 Claims.
rosion than magnesium-base alloys and that, of
the alloying elements which are conventionally added to magnesium, manganese brings about the least reduction of corrosion resistance. Heretofore, it ha been exceedingly dimcult to add manganese to magnesium in amounts greater than about 1% to 2% manganese without obtaining a non-homogeneous alloy.
In accordance with our invention, manganese may be incorporated into magnesium in substantial amounts, in a relatively simple manner, with- "outihterfering with the desired homogeneity of the resulting alloy. We have found that if lithium is added to magnesium, the amount of manganese which ordinarily can be incorporated with the magnesium without efiecting production of a non-homogeneous alloy may be substantially increased. The amount of manganese which may be incorporated with the magnesium to produce a homogeneous alloy is determined, in part, by the amount of lithium which is present. Thus, for'example, with 5% lithium, .of manganese may be readily incorporated into magnesium with the production of a homogeneous alloy.
In general, ,the alloys of our invention contain from about 1% to about 10% lithium, from about 2% to about 10% manganese, balance substantially all magnesium.
We have also found that the addition of silver to the lithium-manganese-magnesium alloys, described hereinabove, increases their strength in the cold rolled condition and somewhat improves their casting properties. The amount of silver which brings about these properties is of a small order, from about 0.5% to about 2.0% being sufficient in at least most cases.
The following. examples are illustrative of al- I loys made in accordance with our present invention. It will be understood that various changes may be made with respect to proportions of the alloying ingredients, within the ranges set out hereinabove, and that other changes may be made without departing from the pirit of the invention in the light of the guiding principles which are dsclosed herein.
Example 1 &
used for the commercial melting of magnesiumbase alloys may be used to protect the surface of the metal during melting. The alloy, when cast, had a hardness of 27 when measured on the Rockwell F scale. The alloy may be cold rolled by any of the usual processes. When substan-' tially fully cold worked to form a sheet, it has a hardness of measured on the Rockwell 1 scale. The alloy is considerably harder and stronger than at least most other magnesium base alloys which have heretofore been made available. This increased hardness and strength make the alloy particularly valuable for the construction of various parts'oi airplanes.
Example 2 An alloy was made containing 83% magnesium, 10% manganese, 5% lithium, and 2% silver, said alloy being prepared from the same grade of a1- loying elements and in the same manner as described in Example 1. The resulting alloy, when cast, is considerably harder than the alloy of- Example 1. Thus, in the cast condition, it has a hardness of 40 measured on the Rockwell F scale whereas in substantially the fully cold worked condition it has a hardness of measured 0n the Rockwell F scale. The density of the alloy was approximately 2.0. This alloy, like that of the first example, lends itself to all of the usual forms of cold working.
As we have indicated hereinabove, in the practice of our invention weprefer to employ alloying metals of high purity. The magnesium, as we have indicated, is preferably a redistilled product. The manganese, for best results, should be at least 99.0% pure and preferably of even greater purity. The manganese utilized may be produced by a vacuum distillation process but we prefer, particularly, to employ electrolytic manganese having a purity of at least about 99.0% and preferably of 99.9%. The lithium, and silver where used, are also preferably of a high degree of purity.
What we claim as new and desire to protect by Letters Patent of the United States is:
alloys containing from manganese, balance sub-
US413159A 1941-10-01 1941-10-01 Magnesium-base alloy Expired - Lifetime US2317980A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US413159A US2317980A (en) 1941-10-01 1941-10-01 Magnesium-base alloy
US443824A US2376868A (en) 1941-10-01 1942-05-20 Magnesium alloy

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2453444A (en) * 1945-06-28 1948-11-09 Olin Mathieson Magnesium base lithium alloys
US2474538A (en) * 1944-06-10 1949-06-28 Charles H Mahoney Alloying manganese with magnesium
US2507714A (en) * 1945-09-14 1950-05-16 Olin Mathieson Magnesium-base alloys
US2546931A (en) * 1949-03-18 1951-03-27 Dow Chemical Co Magnesium alloy
US2747991A (en) * 1945-09-14 1956-05-29 Olin Mathieson Magnesium-base alloys
US5059390A (en) * 1989-06-14 1991-10-22 Aluminum Company Of America Dual-phase, magnesium-based alloy having improved properties

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2474538A (en) * 1944-06-10 1949-06-28 Charles H Mahoney Alloying manganese with magnesium
US2453444A (en) * 1945-06-28 1948-11-09 Olin Mathieson Magnesium base lithium alloys
US2507714A (en) * 1945-09-14 1950-05-16 Olin Mathieson Magnesium-base alloys
US2747991A (en) * 1945-09-14 1956-05-29 Olin Mathieson Magnesium-base alloys
US2546931A (en) * 1949-03-18 1951-03-27 Dow Chemical Co Magnesium alloy
US5059390A (en) * 1989-06-14 1991-10-22 Aluminum Company Of America Dual-phase, magnesium-based alloy having improved properties

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