US2103138A - Process for hardening waterproofing artificial gut produced from animal fibrous material - Google Patents

Process for hardening waterproofing artificial gut produced from animal fibrous material Download PDF

Info

Publication number
US2103138A
US2103138A US105145A US10514536A US2103138A US 2103138 A US2103138 A US 2103138A US 105145 A US105145 A US 105145A US 10514536 A US10514536 A US 10514536A US 2103138 A US2103138 A US 2103138A
Authority
US
United States
Prior art keywords
hardening
artificial gut
gut
formaldehyde
artificial
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US105145A
Other languages
English (en)
Inventor
Becker Oskar Walter
Weiss Emil
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Naturin GmbH and Co
Original Assignee
Naturin GmbH and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Naturin GmbH and Co filed Critical Naturin GmbH and Co
Application granted granted Critical
Publication of US2103138A publication Critical patent/US2103138A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • B24D3/02Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
    • B24D3/04Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic
    • B24D3/06Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic metallic or mixture of metals with ceramic materials, e.g. hard metals, "cermets", cements
    • B24D3/08Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic metallic or mixture of metals with ceramic materials, e.g. hard metals, "cermets", cements for close-grained structure, e.g. using metal with low melting point
    • AHUMAN NECESSITIES
    • A22BUTCHERING; MEAT TREATMENT; PROCESSING POULTRY OR FISH
    • A22CPROCESSING MEAT, POULTRY, OR FISH
    • A22C13/00Sausage casings
    • A22C13/0013Chemical composition of synthetic sausage casings
    • A22C13/0016Chemical composition of synthetic sausage casings based on proteins, e.g. collagen
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01CCHEMICAL OR BIOLOGICAL TREATMENT OF NATURAL FILAMENTARY OR FIBROUS MATERIAL TO OBTAIN FILAMENTS OR FIBRES FOR SPINNING; CARBONISING RAGS TO RECOVER ANIMAL FIBRES
    • D01C3/00Treatment of animal material, e.g. chemical scouring of wool

Definitions

  • A (CI. 18-57) the hide may be replaced by heat disintegration or biological loosening or opening up, supplemented by mechanical resolving.
  • the resulting l5 "artificial gut is dried, for example by treatment with hot air, and rendered waterproof in a suitable manner, for example with the aid of distillate of cellulose-containing substances such as wood, or formaldehyde solutions.
  • the waterproofness or resistance to boiling attained depends substantially on the composition 7 of the hardening liquid. It was found that the hardening properties of the distillates of cellulosecontaining substances are due not only to their content of formaldehyde, but also to their content of other iodine-consuming substances. Whereas the formaldehyde content can be directly determined, the content of other hardening constituents is expressed in terms of the iodine value.
  • the term iodine value is here used in the usual manner to indicate the quantity of iodine expressed in grammes which is consumed.
  • uniform artificial gut which is neither overnor under-hardened, may be obtained by treating the artificial gut with hardening liquids, preferably distillates of cellulose-containing substances, which have been adjusted to a formaldehyde content of from 0.025 to 0.2%, preferably 0.1 to 0.15%, an iodine value of from 3.5 to 8.5, preferably 5.9, and a pH value of from 2.5 to 3.0.
  • hardening liquids preferably distillates of cellulose-containing substances, which have been adjusted to a formaldehyde content of from 0.025 to 0.2%, preferably 0.1 to 0.15%, an iodine value of from 3.5 to 8.5, preferably 5.9, and a pH value of from 2.5 to 3.0.
  • composition of the cellulose derivatives. too. low iodine values of the distillates may be compensated by increasing the formaldehyde content.
  • the iodine-consuming substances in the wood distillates employed with the exceptionof formaldehyde can only be determined with difficulty.
  • the process of this invention is with advantage carried into effect by first drying the artificial gut discharging from the annular nozzle. This may be effected by conveying the gut in the form of a continuous band through drying channels in which it is subjected to the action of hot air.
  • air is blown from the nozzle head into the interior of the tube being formed and the artificial gut dried in this inflated condition.
  • the hardening is likewise with advantage effected whilst the endless tube is in this inflated condition.
  • the crude distillate obtained which is in general more highly oxidized than the distillate obtained in the carbonization of wood, contains up to 0.5% of formaldehyde and has an iodine value of about 42.5.
  • the crude distillate after a distillation is if necessary adjusted by the addition of water to a formaldehyde content. of, for example, 0.12%, whereby the iodine value is also decreased. If the iodine value of the diluted distillate amounts to less than 3.5, crude distillate is added thereto until the iodine value exceeds 3.5.
  • the formaldehyde content may be allowed to exceed the value indicated above.
  • a wood distillate may be added, the iodine value of which is very high in proportion to the formaldehyde content, for example 1.
  • the distillate is thereafter adjusted to pH values of between 2.5 and 3.0 by the addition of formic acid or acetic acid, if it is too alkaline and by the addition of ammonia if it is too acid.
  • the continuous artificial gut is painted-over or the distillate with regard to iodine value and formaldehyde content and amounts to from 2 to 30 days. After this period of action the gut is washed or rinsed with water having a pH value of 8, whereby it first becomes cloudy and then glassy. The excess portion of the hardening substances is washed away thereby. The gut is then again dried.
  • the gut after treatment with the distillate is dried and kept for three days at 25 C.
  • the gut is then washed for about 3 hours with'water having a pH value of 8 and is then again dried.
  • the gut After five-times spraying with this hardening liquid andsubsequent drying, the gut is stored for 14 days at 25 C. and 70% relative air moisture and is thereafter freed from the excess of the V artificial gut with hardening liquids containing from .025 to 2% of formaldehyde, and iodine consuming substances occurring in the distillates of cellulose containing substances, said hardening liquids having an iodine value of from 3.5 to 8.5

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Zoology (AREA)
  • Textile Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Husbandry (AREA)
  • Food Science & Technology (AREA)
  • Ceramic Engineering (AREA)
  • Molecular Biology (AREA)
  • Mechanical Engineering (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Biological Depolymerization Polymers (AREA)
  • Processing Of Solid Wastes (AREA)
  • Artificial Filaments (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
US105145A 1935-10-15 1936-10-10 Process for hardening waterproofing artificial gut produced from animal fibrous material Expired - Lifetime US2103138A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEN0038724 1935-10-15

Publications (1)

Publication Number Publication Date
US2103138A true US2103138A (en) 1937-12-21

Family

ID=6542607

Family Applications (1)

Application Number Title Priority Date Filing Date
US105145A Expired - Lifetime US2103138A (en) 1935-10-15 1936-10-10 Process for hardening waterproofing artificial gut produced from animal fibrous material

Country Status (4)

Country Link
US (1) US2103138A (fr)
FR (1) FR828461A (fr)
GB (1) GB480971A (fr)
NL (1) NL44296C (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2461602A (en) * 1946-01-17 1949-02-15 American Viscose Corp Method of manufacturing synthetic sutures and the like
US2521738A (en) * 1944-06-15 1950-09-12 Thomas L Mcmeekin Process for the production of artificial bristles and the like from proteins
US2539958A (en) * 1947-07-14 1951-01-30 American Enka Corp Method of treating casein threads, fibers, and the like
US2552130A (en) * 1946-12-13 1951-05-08 John R Evans & Company Tanning proteinaceous fibers with a mixture of an aldehyde and a polyhydric phenol in a molecular ratio of at least 2 to 1
US9938592B1 (en) 2015-04-08 2018-04-10 Matthew S. Richards Liquid smoke tanning method

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2521738A (en) * 1944-06-15 1950-09-12 Thomas L Mcmeekin Process for the production of artificial bristles and the like from proteins
US2461602A (en) * 1946-01-17 1949-02-15 American Viscose Corp Method of manufacturing synthetic sutures and the like
US2552130A (en) * 1946-12-13 1951-05-08 John R Evans & Company Tanning proteinaceous fibers with a mixture of an aldehyde and a polyhydric phenol in a molecular ratio of at least 2 to 1
US2539958A (en) * 1947-07-14 1951-01-30 American Enka Corp Method of treating casein threads, fibers, and the like
US9938592B1 (en) 2015-04-08 2018-04-10 Matthew S. Richards Liquid smoke tanning method

Also Published As

Publication number Publication date
NL44296C (fr) 1938-10-15
FR828461A (fr) 1938-05-18
GB480971A (en) 1938-03-03

Similar Documents

Publication Publication Date Title
GB416549A (en) Improvements in the manufacture of cellulose and lignocellulosic materials
GB1236910A (en) A process for the manufacture of xylose and xylitol
FI71463B (fi) Med aedelmoegel belaeggningsbart gas- vattenaonga- och roekgenomslaeppligt livsmedelhoelje speciellt korvskal
US2103138A (en) Process for hardening waterproofing artificial gut produced from animal fibrous material
US3085038A (en) Production of cellulose furfural and fodder from agricultural waste
GB513266A (en) Improvements in or relating to the manufacture of polyvinyl resins
DE329566C (de) Verfahren zur Herstellung von Zellstoff
US2194205A (en) Treatment of polyvinyl acetal resins
DE669128C (de) Verfahren zum Haerten von Kunstdaermen
US2121899A (en) Treatment of cellulose triacetate
SU454211A1 (ru) Способ сушки целлюлозы
US1794126A (en) Method of producing acetyl cellulose
US1840198A (en) Process for the extraction of cellulose from materials containing cellulose
AT62959B (de) Verfahren zur Herstellung von gärungsfählgem Zucker aus Zellulose und zellulosehältigen Substanzen.
DE1492543A1 (de) Verfahren zur Herstellung von Kunstdaermen
SU110739A1 (ru) Способ получени растворимых полиамидных смол
SU125861A1 (ru) Способ обогащени дубильных корневых экстрактов
GB187987A (en) Improved manufacture of water resisting paper
SU47816A1 (ru) Способ изготовлени прессовочных масс
AT219278B (de) Makromolekularer Polyformaldehyd
US1425581A (en) Process of preparing cellulose butyrate
SU70751A1 (ru) Способ получени бакелитированной древесины
SU480552A1 (ru) Способ модификации древесины
US2079623A (en) Tobacco treatment
SU116158A1 (ru) Способ получени ацетилцеллюлозы и ацетобутиратцеллюлозы