US2082188A - Moth-proofing detergent composition - Google Patents
Moth-proofing detergent composition Download PDFInfo
- Publication number
- US2082188A US2082188A US535564A US53556431A US2082188A US 2082188 A US2082188 A US 2082188A US 535564 A US535564 A US 535564A US 53556431 A US53556431 A US 53556431A US 2082188 A US2082188 A US 2082188A
- Authority
- US
- United States
- Prior art keywords
- acid
- moth
- parts
- proofing
- detergent composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title description 10
- 239000003599 detergent Substances 0.000 title description 5
- 239000003795 chemical substances by application Substances 0.000 description 15
- 239000000344 soap Substances 0.000 description 13
- 239000002253 acid Substances 0.000 description 11
- 150000003839 salts Chemical class 0.000 description 10
- 230000007935 neutral effect Effects 0.000 description 9
- 238000005406 washing Methods 0.000 description 9
- 210000002268 wool Anatomy 0.000 description 8
- 239000002585 base Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 125000005496 phosphonium group Chemical group 0.000 description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 4
- -1 aromatic hydroxy-carboxylic acids Chemical class 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 4
- YDZIHVHNIDNTRU-UHFFFAOYSA-N [Cl-].C1(=CC=CC=C1)C1=C(C([PH+](Cl)Cl)(C2=CC=CC=C2)C2=CC=CC=C2)C=CC=C1 Chemical compound [Cl-].C1(=CC=CC=C1)C1=C(C([PH+](Cl)Cl)(C2=CC=CC=C2)C2=CC=CC=C2)C=CC=C1 YDZIHVHNIDNTRU-UHFFFAOYSA-N 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 210000003746 feather Anatomy 0.000 description 3
- 210000004209 hair Anatomy 0.000 description 3
- 229960002050 hydrofluoric acid Drugs 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- QYHFIVBSNOWOCQ-UHFFFAOYSA-N selenic acid Chemical compound O[Se](O)(=O)=O QYHFIVBSNOWOCQ-UHFFFAOYSA-N 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 150000001447 alkali salts Chemical class 0.000 description 2
- 125000005907 alkyl ester group Chemical group 0.000 description 2
- 239000005018 casein Substances 0.000 description 2
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 2
- 235000021240 caseins Nutrition 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 235000021313 oleic acid Nutrition 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical class C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 230000003389 potentiating effect Effects 0.000 description 2
- 238000009877 rendering Methods 0.000 description 2
- 229940000207 selenious acid Drugs 0.000 description 2
- MCAHWIHFGHIESP-UHFFFAOYSA-N selenous acid Chemical compound O[Se](O)=O MCAHWIHFGHIESP-UHFFFAOYSA-N 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- YDOVRFJDZXIYMW-UHFFFAOYSA-N 3,4-dichloro-2-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(Cl)C(Cl)=C1O YDOVRFJDZXIYMW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 150000005840 aryl radicals Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 150000002889 oleic acids Chemical class 0.000 description 1
- FWZMWMSAGOVWEZ-UHFFFAOYSA-N potassium;hydrofluoride Chemical compound F.[K] FWZMWMSAGOVWEZ-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/06—Inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/28—Organic compounds, e.g. vitamins containing halogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/34—Organic compounds, e.g. vitamins containing phosphorus
Definitions
- the present invention relates to new watersoluble soaps, being compositions consisting of neutral or acid soapy washing agents and moth proofing agents having an aflinity for wool, said soaps being suitable for cleaning and rendering moth-proof wool, feathers, hair and the like in one and the same process.
- neutral washing agents for instance, the neutral alkali salts of palmitic, stearic, oleic acids. as contained in the usual soaps and by acid washing agents, the alkyl esters of sulfurized castor oil or of sulfurized oleic acid or oleyl-methylamlno-methane or similar washing agents resistant to acid reaction.
- the new compositions are obtainable in a known manner by incorporating into such neutral or acid washing agents, moth-proofing agents as above described.
- the new compositions thus produced are colorless or slightly colored in the dry state, being and are soluble in water. All these soaps, in the form of lumps, powders, pastes or solutions, can be used 'for simultaneously cleaning and mothprooflng materials liable to attack by moths.
- the specific moth-proofing agent incorporated with the soapy component depends on the chemical behavior of said soapy component, which is more fully, described hereafter. Thus, when ,using as mothproofing agent the free selenic acid or selenious acid itself or acid salts of hydrofluoric acid or hydro-fluo-silicic acid or their soluble salts or suitable mixtures of the above.
- a soapy component resistant to the acid reaction is required, for example, oleyl methyl aminoethane sulfonic acid, while the salts of quaternary phosphonium bases may be combined with the neutral alkali salts of palmitic, stearic, oleic acid and the like.
- Example 1 To 80 parts of a neutral or acid sulfonic acid or oleyl-hydroxy-ethane-sulfonic acid-.(sodium salt) soap 20 parts of triphenyl-dichloro-benzylphosphonium chloride are added, and the whole is intimately mixed. Instead of the triphenyl-dichloro-benzyl-phosphonium chloride also other salts of quaternary phosphonium bases can be used either alone or mixed with another one, the quantity depending on the efficacy of selected compounds. 10 parts of this special soap dissolved inl000 parts of water are used for washing woolen material in the customary manner at about 40 to 50 C. The material treated in such a manner is cleaned and moth-proofed at the same time.
- Example 2 To 80 parts of oleyl-methylamino-ethane-sulfonic acid 20 parts of sodiumsilico-fluoride are added, and the whole is intimately mixed.
- Example 3.-80 parts of oleyl-hydroxy-ethanesulfonic acid in the form of its sodium salt and 20 parts of dichloro-salicylic acid are intimately mixed.
- Wool treated in a solution of 20 parts of such a soap in 1000 parts of water is cleaned and renderedmoth-proof in this way.
- Example 4 -20 parts of bis-1.3-dichloro-benzol-i-sulfo-1.3-phenylene-diamide are emulsified in 80 parts of the alkyl ester of sulfurized castor oil.
- Wool treated in a solution of 20 parts of such a soap in 1000 parts of water at 60 C. is cleaned and rendered moth-proof at the same time.
- a mixture of different soaps may be applied, and the process may be varied within wide limits according to requirements.
- a mothproofing detergent composition consisting essentially 10f a neutral soapy washing agent in preponderating proportion, and a watersoluble salt of an organic quaternary phosphoni um base, said composition being at the most only slightly colored in the dry state, being soluble in water, and being adapted for simultaneously cleaning and rendering moth-proof wool, feathers, hair and like materials.
- a nrothp'moflng detergent composition consisting essentially of a. neutral soapy washing agent selected from the group consisting of oleic,
- wool selected from the group consisting of salts of organic quaternary phosphonium bases, aromatic hydroxy-carboxylic acids,
- a nrothp'moflng detergent composition consisting essentially of a. neutral soapy washing agent selected from the group consisting of oleic,
- wool selected from the group consisting of salts of organic quaternary phosphonium bases, aromatic hydroxy-carboxylic acids,
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Dentistry (AREA)
- Toxicology (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US9584036 US2130435A (en) | 1931-05-06 | 1936-08-13 | Mothproofing detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2082188X | 1930-05-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2082188A true US2082188A (en) | 1937-06-01 |
Family
ID=7984035
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US535564A Expired - Lifetime US2082188A (en) | 1930-05-30 | 1931-05-06 | Moth-proofing detergent composition |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US2082188A (en(2012)) |
| FR (1) | FR717976A (en(2012)) |
| NL (1) | NL29846C (en(2012)) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE970785C (de) * | 1948-10-09 | 1958-10-30 | Henkel & Cie Gmbh | Verfahren zur UEberfuehrung der wasserunloeslichen Kontaktinsekticide Difluordiphenyltrichloraethan, Dichlordiphenyltrichloraethan und ª†-Hexachlorcyclohexan in eine fuer die Anwendung in waessriger Loesung geeignete feste Form |
-
0
- NL NL29846D patent/NL29846C/xx active
-
1931
- 1931-05-06 US US535564A patent/US2082188A/en not_active Expired - Lifetime
- 1931-05-30 FR FR717976D patent/FR717976A/fr not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE970785C (de) * | 1948-10-09 | 1958-10-30 | Henkel & Cie Gmbh | Verfahren zur UEberfuehrung der wasserunloeslichen Kontaktinsekticide Difluordiphenyltrichloraethan, Dichlordiphenyltrichloraethan und ª†-Hexachlorcyclohexan in eine fuer die Anwendung in waessriger Loesung geeignete feste Form |
Also Published As
| Publication number | Publication date |
|---|---|
| NL29846C (en(2012)) | |
| FR717976A (fr) | 1932-01-16 |
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