US20230093568A1 - A Continuous Type Process Method to Increase the Rate of Reaction Between Solids, Liquids, And Gasses Per Area of the Land Occupied by Two Reactors - Google Patents

A Continuous Type Process Method to Increase the Rate of Reaction Between Solids, Liquids, And Gasses Per Area of the Land Occupied by Two Reactors Download PDF

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US20230093568A1
US20230093568A1 US17/909,393 US202117909393A US2023093568A1 US 20230093568 A1 US20230093568 A1 US 20230093568A1 US 202117909393 A US202117909393 A US 202117909393A US 2023093568 A1 US2023093568 A1 US 2023093568A1
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solids
reactor
moving
gasses
moving bed
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Prakashkumar Narasimhamurthy
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/08—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
    • B01J8/10—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles moved by stirrers or by rotary drums or rotary receptacles or endless belts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1475—Removing carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D47/00—Separating dispersed particles from gases, air or vapours by liquid as separating agent
    • B01D47/02—Separating dispersed particles from gases, air or vapours by liquid as separating agent by passing the gas or air or vapour over or through a liquid bath
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D47/00—Separating dispersed particles from gases, air or vapours by liquid as separating agent
    • B01D47/02—Separating dispersed particles from gases, air or vapours by liquid as separating agent by passing the gas or air or vapour over or through a liquid bath
    • B01D47/028—Separating dispersed particles from gases, air or vapours by liquid as separating agent by passing the gas or air or vapour over or through a liquid bath by directing the gas through a wetted wire mesh or a perforated plate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/62—Carbon oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/75—Multi-step processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77—Liquid phase processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77—Liquid phase processes
    • B01D53/78—Liquid phase processes with gas-liquid contact
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/81—Solid phase processes
    • B01D53/83—Solid phase processes with moving reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/08—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/08—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with moving particles
    • B01J8/085—Feeding reactive fluids
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16N—LUBRICATING
    • F16N7/00—Arrangements for supplying oil or unspecified lubricant from a stationary reservoir or the equivalent in or on the machine or member to be lubricated
    • F16N7/12—Arrangements for supplying oil or unspecified lubricant from a stationary reservoir or the equivalent in or on the machine or member to be lubricated with feed by capillary action, e.g. by wicks
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16N—LUBRICATING
    • F16N9/00—Arrangements for supplying oil or unspecified lubricant from a moving reservoir or the equivalent
    • F16N9/02—Arrangements for supplying oil or unspecified lubricant from a moving reservoir or the equivalent with reservoir on or in a rotary member
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2247/00—Details relating to the separation of dispersed particles from gases, air or vapours by liquid as separating agent
    • B01D2247/02—Enhancing the particle separation by electrostatic or magnetic effects
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/40—Alkaline earth metal or magnesium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/40—Alkaline earth metal or magnesium compounds
    • B01D2251/404—Alkaline earth metal or magnesium compounds of calcium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/025—Other waste gases from metallurgy plants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00743—Feeding or discharging of solids
    • B01J2208/00752—Feeding
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16N—LUBRICATING
    • F16N2210/00—Applications
    • F16N2210/14—Bearings
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/10—Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working

Definitions

  • This invention relates to a continuous type process method in two reactors to increase the rate of reaction between solids, liquids, and gasses per area of the land occupied by the reactors from increasing the surface area interface between solids, liquids, gasses and increasing the period of exposure of solids to the liquids and gasses within the reactors per area of land occupied by the reactors when all the other conditions affecting such reactions in the reactors are constant.
  • US20050180910 discloses a process for capturing CO 2 and pollution contained in a combustion flue gas in alkaline earth metal bearing minerals.
  • US 20110070137 discloses a number of process configurations of accelerated weathering of carbonate mineral-containing materials (AWC) reactors.
  • U.S. Pat. No. 5,393,314 discloses a horizontal pass, multiple packed-bed gas scrubber.
  • WO2018020005 discloses an activated carbon bed for use with a wet scrubber system.
  • US20050084434 discloses scrubbing systems and methods for coal fired combustion units.
  • the invention is advantageous to many industrial processes to increase the chemical and physical reaction rates between solids, liquids, and gasses per area of land occupied by the reactors.
  • An example of applying the invention to simultaneously capture the CO 2 and the pollution contained in the flue gas emission of a steel plant in the alkaline slag waste produced in a steel plant is described below.
  • the invention comprises two reactors of identical construction but with a small variation in the process method between the first and the second reactor.
  • the application of two reactors overcomes the corrosion issue during the carbonation of the alkaline slag with the hot, polluted and acidic flue gas. It will improve the use of recovered thermal energy. It will increase the surface area interface between the solids, liquids, gasses with the reactors, increase the period of exposure of the solids to the liquids and gasses, and contribute to increasing the reaction rates per area of the land occupied by the first and second reactors.
  • the thermal energy required to enhance the reaction rates is delivered by the thermal energy contained in the hot flue gas received into the first reactor and from the heat generated from the exothermic reactions during the carbon mineralisation occurring in both the reactors.
  • FIG. 1 The invented continuous type process method in two reactors is illustrated in FIG. 1 .
  • FIG. 1 illustrates a cross section of two reactors ( 001 ) and ( 002 ) without the moving bed of solids.
  • Both reactors mainly comprise plurality of perforated horizontal moving floor ( 003 ) mounted on a plenum ( 004 ). These are arranged one above other with a space ( 005 ) in between.
  • An opening ( 006 ) at the end of each moving floor ( 003 ) communicates with the following moving floor.
  • FIG. 1 also illustrates the cross section of the first reactor ( 001 ) with the moving bed of solids ( 010 ).
  • the ambient solid alkaline slag ( 007 ) which is crushed and granulated is conveyed into the first reactor ( 001 ) and the top most moving floor receive the solids ( 007 ).
  • the solids form a moving bed of solids ( 010 ) and travel horizontally in a direction on the top most moving floor before it falls on to the following moving floor through the opening ( 006 ) at the end of that moving floor ( 003 ) which moves the received solids horizontally in the direction opposite to the former.
  • This travel pattern of solids is repeated in the following moving floors before solids exit the first reactor from the last moving floor.
  • Ambient liquid droplets ( 008 ) are sprayed from above evenly throughout the area of each moving bed of solids.
  • the diverted hot flue gasses ( 009 ) containing CO 2 and pollution before it enters the flue stack enters the first reactor ( 001 ) above the last moving bed of solids and flow counter current to the travel direction of the solids interfacing with the falling ambient liquid droplets ( 008 ).
  • the falling ambient liquid droplets during the interface with hot flue gasses capture the particulate matter, absorb the acidic gasses and the heat contained in the gasses and fall evenly throughout the area of each moving bed of solids, filter through by gravitational flow to the bottom of the moving bed of solids and exit the first reactor.
  • the gasses get cooler, cleaner and less acidic as it travels to the top of the first reactor ( 001 ) before exiting the first reactor above the top most moving bed of solids.
  • the surfaces in contact with the gasses are smooth, plane and corrosion resistant.
  • the sprinklers and pipes are corrosion resistant.
  • the moving bed of alkaline solids absorb the acidity contained in the liquid when the liquid filters through during the reaction.
  • the solid particulates are captured as residues in the bed of solids as the liquid filters through the bed of solids.
  • the liquid is cleaner and less acidic before it reached the perforated moving floor ( 003 ) and its parts.
  • the solid pollutants remain as filtered residues in the carbonized solids exiting the first reactor.
  • the solids and the liquids exiting the first reactor will be warmer having gained energy from the hot flue gasses and the exothermic reactions.
  • the exiting non corrosive, cooler and cleaner gasses from the first reactor ( 001 ) is distributed to enter into every plenum ( 004 ) in the second reactor ( 002 ).
  • the exiting solids from the first reactor is transferred and fed into the top of the second reactor and the top most moving perforated floor receives the solids.
  • the formed moving bed of solids ( 010 ) travel above all the moving floors, similar as in the first reactor, and exit the second reactor.
  • the gasses in the plenum are evenly distributed as updraft throughout the horizontal moving perforated floor ( 003 ), the updraft then filters through the moving bed of solids ( 010 ).
  • the heat energy contained in the solids increase the reaction rates.
  • the CO 2 reduced and cleaned flue gasses exit the surface of the moving bed of solids.
  • the temperature of such gasses will be warmer than ambient after having gained heat from the exothermic reaction.
  • the fine liquid particulates contained in the gasses exiting the first reactor ( 001 ) is captured in the moving bed of solids in the second reactor ( 002 ). Therefore, the warmer gasses exiting the second reactor ( 002 ) is drier than the former ( 001 ).
  • the drier, warmer than ambient, and cleaner flue gasses exiting the second reactor ( 002 ) is safer to emit into the atmosphere than the flue gas which is currently emitted into the atmosphere in a steel plant.
  • the existing pollution emitted from a flue stack of a steel plant can be potentially reduced to near zero level by diverting all the flue gasses into the first reactor ( 001 ).
  • the warm liquid exiting the first reactor ( 001 ) is sprayed from above as droplets in the second reactor ( 002 ), as done in the first reactor ( 001 ).
  • the updraft gasses will interface with the liquids filtering through the moving bed of solids ( 010 ) and with the falling droplets (not shown in the drawing) after the updraft exit the surface of the moving bed of solids ( 010 ).
  • the liquids by gravitational flow reach the bottom of the bed and exit the second reactor.
  • the liquids are cooled to ambient, treated, pH is neutralized, and recycled back to the first reactor ( 001 )
  • the free lime normally contained in the slag waste of a steel plant restrict its use as aggregate in concrete and road construction due to the issues caused by expansion. This is one of the major reasons for slag being rejected as waste and landfilled.
  • the free lime is stabilized into oxides in the carbonized slag exiting the second reactor making it a valuable, sustainable, and a high-quality aggregate.
  • the pollutant residues captured in the carbonized slag does not affect the quality as it is permanently and safely locked in the used products. This is the safest and cost-effective method to dispose the solid pollutants captured from the polluted flue gasses.
  • the fixed packed bed of solids wet scrubbers used for pollution abatement and many other chemical processes have an inherent issue of solid matter clogging the packed bed and reducing the performance and reaction rates over a period of usage.
  • the invention overcomes this issue as it is a moving packed bed of solids wet scrubber.
  • the improvement in performance and the increase in reaction rates per area of land occupied by the reactors can be maintained consistently and continuously when all the other conditions affecting such reactions are constant in the reactors. This opens new opportunities to improve the quality output and reduce the cost of production in myriad existing industrial applications.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Biomedical Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
US17/909,393 2020-03-19 2021-09-23 A Continuous Type Process Method to Increase the Rate of Reaction Between Solids, Liquids, And Gasses Per Area of the Land Occupied by Two Reactors Pending US20230093568A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB2004019.2A GB2593207B (en) 2020-03-19 2020-03-19 A continuous type process method to increase the rate of reaction between solids, liquids, and gasses per area of the land occupied by two reactors
GB2004019.2 2020-03-19
PCT/EP2021/025106 WO2021185482A1 (fr) 2020-03-19 2021-03-16 Procédé de traitement de type continu pour augmenter la vitesse de réaction entre des solides, des liquides et des gaz par surface du terrain occupé par deux réacteurs

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US20230093568A1 true US20230093568A1 (en) 2023-03-23

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US (1) US20230093568A1 (fr)
EP (1) EP4081327A1 (fr)
CN (1) CN115461130A (fr)
AU (1) AU2021239293A1 (fr)
GB (1) GB2593207B (fr)
WO (1) WO2021185482A1 (fr)

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CN113101795A (zh) * 2021-03-26 2021-07-13 吴崇铭 一种用于微藻养殖的烟气直接耦合系统及其处理方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2303811A (en) * 1940-01-09 1942-12-01 Day And Zimmermann Inc Chemical recovery system for pulp mills
US2662756A (en) * 1950-08-22 1953-12-15 Simpson Herbert Corp Liquid contact apparatus for cleaning gas
JPS51129871A (en) * 1975-05-08 1976-11-11 Asahi Glass Co Ltd Adust removing and denitration process by catalytic reaction apparatus
JPS5484665A (en) * 1977-12-16 1979-07-05 Hitachi Zosen Corp Treating method for waste gas, etc.
DE2915968A1 (de) * 1979-04-20 1980-11-06 Heinbuch Ria Verfahren und vorrichtung zum abreinigen von kohlenwasserstoff- und staubhaltigen heissgasstroemen
US5393314A (en) 1994-05-31 1995-02-28 Powell Fabrication & Manufacturing, Inc. Horizontal pass, multiple packed-bed gas scrubber
US20050084434A1 (en) 2003-10-20 2005-04-21 Enviroserve Associates, L.L.C. Scrubbing systems and methods for coal fired combustion units
US7722842B2 (en) 2003-12-31 2010-05-25 The Ohio State University Carbon dioxide sequestration using alkaline earth metal-bearing minerals
US20110070137A1 (en) 2009-05-22 2011-03-24 Dana Brock Method of managing carbon dioxide emissions
CN105859097A (zh) * 2016-05-24 2016-08-17 华南理工大学 一种结合热电厂余热利用污泥干燥方法及其装置
US20180028964A1 (en) 2016-07-29 2018-02-01 General Electric Company Activated Carbon Bed For Use With A Wet Scrubber System
CN107789983A (zh) * 2016-08-31 2018-03-13 中国石油化工股份有限公司 一种烟气脱硝方法及脱硝反应器

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GB2593207A (en) 2021-09-22
WO2021185482A1 (fr) 2021-09-23
GB202004019D0 (en) 2020-05-06
CN115461130A (zh) 2022-12-09
EP4081327A1 (fr) 2022-11-02
GB2593207B (en) 2022-06-01
AU2021239293A1 (en) 2022-11-17

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