US20220072528A1 - Systems and methods for segregating into dual waste streams oxidizable catalyst material from inert support media - Google Patents
Systems and methods for segregating into dual waste streams oxidizable catalyst material from inert support media Download PDFInfo
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- US20220072528A1 US20220072528A1 US17/012,457 US202017012457A US2022072528A1 US 20220072528 A1 US20220072528 A1 US 20220072528A1 US 202017012457 A US202017012457 A US 202017012457A US 2022072528 A1 US2022072528 A1 US 2022072528A1
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Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
- B09B3/40—Destroying solid waste or transforming solid waste into something useful or harmless involving thermal treatment, e.g. evaporation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/72—Regeneration or reactivation of catalysts, in general including segregation of diverse particles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B07—SEPARATING SOLIDS FROM SOLIDS; SORTING
- B07B—SEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
- B07B1/00—Sieving, screening, sifting, or sorting solid materials using networks, gratings, grids, or the like
- B07B1/005—Transportable screening plants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B07—SEPARATING SOLIDS FROM SOLIDS; SORTING
- B07B—SEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
- B07B1/00—Sieving, screening, sifting, or sorting solid materials using networks, gratings, grids, or the like
- B07B1/28—Moving screens not otherwise provided for, e.g. swinging, reciprocating, rocking, tilting or wobbling screens
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B07—SEPARATING SOLIDS FROM SOLIDS; SORTING
- B07B—SEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
- B07B1/00—Sieving, screening, sifting, or sorting solid materials using networks, gratings, grids, or the like
- B07B1/28—Moving screens not otherwise provided for, e.g. swinging, reciprocating, rocking, tilting or wobbling screens
- B07B1/34—Moving screens not otherwise provided for, e.g. swinging, reciprocating, rocking, tilting or wobbling screens jigging or moving to-and-fro perpendicularly or approximately perpendiculary to the plane of the screen
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B07—SEPARATING SOLIDS FROM SOLIDS; SORTING
- B07B—SEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
- B07B1/00—Sieving, screening, sifting, or sorting solid materials using networks, gratings, grids, or the like
- B07B1/46—Constructional details of screens in general; Cleaning or heating of screens
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B07—SEPARATING SOLIDS FROM SOLIDS; SORTING
- B07B—SEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
- B07B4/00—Separating solids from solids by subjecting their mixture to gas currents
- B07B4/02—Separating solids from solids by subjecting their mixture to gas currents while the mixtures fall
-
- B09B3/0016—
-
- B09B3/0083—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
- B09B3/80—Destroying solid waste or transforming solid waste into something useful or harmless involving an extraction step
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/005—Separation by a physical processing technique only, e.g. by mechanical breaking
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/009—General processes for recovering metals or metallic compounds from spent catalysts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B07—SEPARATING SOLIDS FROM SOLIDS; SORTING
- B07B—SEPARATING SOLIDS FROM SOLIDS BY SIEVING, SCREENING, SIFTING OR BY USING GAS CURRENTS; SEPARATING BY OTHER DRY METHODS APPLICABLE TO BULK MATERIAL, e.g. LOOSE ARTICLES FIT TO BE HANDLED LIKE BULK MATERIAL
- B07B2201/00—Details applicable to machines for screening using sieves or gratings
- B07B2201/04—Multiple deck screening devices comprising one or more superimposed screens
Definitions
- the present disclosure generally relates to the field of petroleum refinement, and particularly relates to systems and methods for separating refinery byproducts into hazardous and non-hazardous components.
- the petrochemical refinement industry is constantly searching for ways to improve upon refinery efficiency and cost savings.
- One avenue for achieving these goals takes place at the front end of the refinement process through refinery material selection.
- a combination of catalysts, inert support balls, and grading material also referred to as topping or trap material
- These materials are loaded into one or more refinery unit vessels in accordance with a loading plan which specifies the quantity and distribution of the materials in the vessels.
- the particular type of catalyst chosen depends on the desired product (e.g. diesel, jet fuel, or kerosene) and catalyst performance (dictated by expected catalyst lifetime, raw material, desired finish product specifications, and other variables affecting the rate at which the catalyst is consumed).
- Topping is selected based on the desired application (e.g., hydrotreating, hydrogenation, hydrydrocracking, lube oils, or wax), and inert support balls are generally made of alumina, ceramic or silica.
- the inert support balls are loaded into the bottom of the vessel followed by a layer of catalyst (catalyst bed). Layers of inert support balls and catalyst may be deposited in an alternating fashion until, for example, 1-10 layers of catalyst may be deposited with intervening layers of inert support balls. The inert support balls help to evenly distribute raw petrochemical material and synthesized refined product across the catalyst bed. Finally, grading material may be loaded on top of the layers to “trap” or remove impurities such as vanadium, nickel, or arsenic from the raw material. This grading material may be comprised of a single material or various materials, each configured to trap/remove a particular impurity. The catalyst converts the raw material into the refined product. This reaction ultimately causes catalyst activity and pressure within the refinery unit to decrease.
- catalyst converts the raw material into the refined product. This reaction ultimately causes catalyst activity and pressure within the refinery unit to decrease.
- the mixture of catalyst, inert support balls and grading are changed out once the unit pressure and/or catalyst activity fall below a predetermined threshold.
- inert gas (often nitrogen) is forced into one or more vessels of the refinery unit to purge any remaining raw material and liquid product. This purge leaves only the catalyst, topping and inert support (collectively known as industrial waste) behind.
- the day on which this change occurs is commonly known in industry as the “oil out” date and may be predicted using unit performance indicators and raw material specifications. Data relating to a previous oil out date may also be used to predict the next oil out date.
- a target oil out date is set well in advance (often 18-24 months) to account for replacement catalyst manufacture time.
- the vessel is allowed to cool down (e.g. to 300° F.) and the remaining catalyst, topping and inert support balls are extracted. Refineries generally replace all of the catalyst within a unit at the same time to take advantage of the “unit down time” and cut costs.
- extraction involves a “gravity dump,” during which the catalyst, topping and inert support are permitted to fall through a valve in the bottom of the vessel.
- the material feeds into a pipe, which leads to flow bins or the desired packaging for holding and transporting the material.
- the rate at which the material enters the flow bins is generally regulated manually by a valve. Since each flow bin only holds about 1-2.5 tons, this process is repeated (5-500 times depending on the size of the vessel) until the vessel is empty.
- a vacuum may be used as an alternative to the gravity dump, in which case, material is vacuumed through the top of the vessel and into the flow bins or other packaging of choice.
- the vessels are refilled, and the flow bins (or packaging of choice) are directed to a holding area, where they await inventory, sampling, and profile generation for the destination process facility.
- the Environmental Protection Agency categorizes spent catalyst and topping as “hazardous waste” (e.g. K171 or K172); therefore, certain disposal guidelines must be followed.
- Another method of disposal involves “regeneration.” During regeneration, the waste is carefully roasted so that a percentage of the spent catalyst may be re-introduced into the refining process. Yet another method of disposal sends roasted waste to landfill. More recently, refineries have the option to send their waste materials to cement kilns for alumina and energy reclamation. Since kilns process liquids more easily than solids, the catalyst may be transformed into a slurry to facilitate processing. These catalyst particles fall out of the slurry suspension, clogging pipes and disrupting the overall process.
- inert support is generally classified as non-hazardous (in some instances classified as hazardous) and account for up to 25% of refinery waste
- many refineries incur the same cost/pound for processing, packaging, and transporting non-hazardous waste as they do for hazardous waste. This is because refineries do not separate the materials into hazardous and non-hazardous components prior to disposal. This unnecessary expense is often compounded by the cost of international shipping. Available options for separating the materials are insufficient as they still require the refinery to continue to ship waste offsite resulting in additional cost.
- the systems and methods described herein address at least some of the drawbacks of traditional industrial waste disposal by simplifying and mobilizing the industrial waste segregation process. Such systems and methods may allow refineries to reduce the premium on hazardous waste management and the amount of reportable hazardous waste.
- the present disclosure provides methods and systems for efficiently segregating hazardous topping and catalyst material from inert support media. Although reference is made to hazardous catalyst and topping material, it is to be understood that systems and methods disclosed herein may be used to separate hazardous materials from other hazardous materials and non-hazardous materials from other non-hazardous materials.
- a first aspect of the disclosure provides a system for segregating a mixture of oxidizable catalyst material and inert support media.
- the system may include an enclosure configured to contain inert gas and a plurality of stacked screens disposed within the enclosure.
- the stacked screens may include openings that decrease in size from a top of the stack to a bottom of the stack.
- the enclosure may include a mixture inlet positioned to enable delivery of the mixture to an uppermost stacked screen.
- the system may further comprise at least one motor for moving the stacked screens to cause the oxidizable catalyst material to separate from and migrate to a location beneath the inert support media; at least one inert support media outlet associated with at least one of the plurality of stacked screens and for conveying the separated inert support media to a location outside the enclosure; a catalyst material outlet associated with at least another of the plurality of stacked screens for conveying the separated oxidizable catalyst material to a location outside the enclosure; and an inert gas inlet associated with the enclosure for conveying the inert gas to the enclosure.
- the inert gas displaces oxygen within the enclosure to thereby limit oxidation of the oxidizable catalyst while the at least one motor moves the plurality of stacked screens.
- Another aspect of the disclosure provides a method for disposing a mixture of oxidizable catalyst material and inert support media.
- the method may include introducing inert gas into an enclosure; introducing the mixture into the enclosure; separating the oxidizable catalyst material and the inert support media within the enclosure; maintaining an inert gas environment around the oxidizable catalyst material during separating; exporting the separated inert support media from the enclosure; and grinding the separated oxidizable catalyst material into a powder for disposal as hazardous waste via incineration.
- the method may include introducing inert gas into an enclosure, wherein the enclosure contains a plurality of stacked screens having openings that decrease in size from a top of the stack to a bottom of the stack; introducing the mixture to an uppermost one of the plurality of stacked screens; moving the plurality of stacked screens to cause the oxidizable catalyst material to separate from and migrate to a location beneath the inert support media; conveying the separated inert support media to a location outside the enclosure for disposal as non-hazardous waste; and conveying the separated oxidizable catalyst material to a location outside the enclosure for at least one of reclamation, thermal destruction, thermal processing, regeneration and/or disposal in a landfill.
- FIG. 1 is a perspective view of a system for segregating a mixture of oxidizable catalyst material and inert support media in accordance with embodiments of this disclosure.
- FIG. 2 is a partial cut-away view of the assembly depicted in FIG. 1 .
- FIG. 3A is a detailed view of the screen assembly illustrated in FIG. 1 .
- FIG. 3B is a partial cut-away view of the screen assembly illustrated in FIG. 3A .
- FIG. 4 is a block diagram of a first exemplary process in accordance with embodiments of this disclosure.
- FIG. 5 is a block diagram of a second exemplary process in accordance with embodiments of this disclosure.
- FIG. 6 is a block diagram of another exemplary process in accordance with embodiments of this disclosure.
- Some embodiments of this disclosure may involve systems and methods for segregating materials in a mixture.
- Industrial waste for example, may include petrochemical refinement waste, which while classified as hazardous, may be made up of both hazardous and non-hazardous components.
- the non-hazardous components may include an inert material, such as inert support media made of, by way of example, alumina, ceramic or silica.
- the hazardous components may include an oxidizable catalyst and grading material. Together, these components may form a mixture.
- the inert materials can be sold, recycled, or disposed of as non-hazardous waste, reducing the overall disposal cost. Moreover, in some instances, the catalyst, if separated from the inert materials, might be reclaimed and reused, lowering overall processing costs. In other instances, the catalyst may be disposed of, such as through incineration.
- catalyst refers includes any of a variety of catalyst materials that are used in the refinement of oil, including but not limited to those listed in Table 1 below. It should be noted that the materials listed in the table are only exemplary, and in general, the catalyst may include any currently used or later developed catalyst material.
- segregating refers to separating (or to a process used to separate) one or more constituents of a mixture.
- segregating may include separating oxidizable catalyst from inert support media in a mixture or a process where oxidizable catalyst is separated from inert support media, or vice versa.
- screen devices for segregating, in the broadest sense, the methods of this disclosure are not limited to any particular segregation structure. Alternative structures for separating materials by size or composition may be employed within the broad scope of this disclosure.
- inert gas refers to a gas that does not undergo a chemical reaction under the prevailing conditions.
- inert gases may include elemental gases, such as, for example, nitrogen and noble gases, or may include compound gases (i.e., a mixture of gases that does not undergo chemical reaction under prevailing conditions).
- segregation systems may be mobile or may be constructed of components that may be movable.
- segregation component 100 b depicted in FIG. 1 .
- the segregation component 100 b may include various components for segregating a mixture of oxidizable catalyst material and inert support media.
- a system may include additional components, such as delivery component 100 a , an inert material collection container 134 and one or more catalyst collection containers 136 , 138 along with interconnected conveyors, as is described later in greater detail.
- Some disclosed embodiments may include an enclosure configured to contain inert gas.
- inert gas One challenge in handling some oxidizable materials is that they may become volatile when exposed to air.
- segregation of inert support media and oxidizable catalyst material may occur in any container capable of receiving an inert gas and minimizing catalyst oxidation to an acceptable level (for example, to a level sufficient to reduce unacceptable risk).
- the container may have a lid, but need not have any particular form nor be made of any particular material, so long as it enables a sufficient amount of oxygen in the enclosure to be replaced by an inert gas while the segregation is taking place.
- enclosure 108 of segregation component 100 b may be a modified shipping container that is capable of being transported by a vehicle.
- enclosure 108 may be designed to retain enough inert gas and/or exclude enough oxygen to enable a segregation process while minimizing the risk of setting off a dangerous catalyst oxidation reaction.
- enclosure 108 may be provided with sealing material to enhance inert gas retention.
- Enclosure 108 may be pressurized using the inert gas.
- Inert gas 109 may be nitrogen or any other gas that does not induce a chemical reaction (e.g., a volatile reaction) when exposed to the mixture of catalyst and support media.
- Inert gas 109 may be contained in pressurized inert gas tank and may be fluidly coupled, or flow-connected, to the enclosure.
- enclosure 108 may include one or more vents 118 for permitting gas within the enclosure to escape. Vents 118 may include openings, valves, filters, or any other mechanism suitable for allowing gas to escape enclosure 108 while limiting introduction of ambient oxygen into the enclosure.
- Enclosure 108 may also include an observation window 132 in an outer wall thereof, and an illuminator 130 (e.g., a light, etc.) (see FIG. 2 ) within the enclosure to enable external observation of the mixture segregation, as illustrated in FIG. 2 . An observer may check the progress of the segregation process through the enclosure window if desired.
- FIG. 1 illustrates an exemplary system 100 for segregating a mixture of oxidizable catalyst material and inert support media.
- System 100 may include a delivery component 100 a and a segregation component 100 b .
- Delivery component 100 a may include one or more flow bins 102 for containing the mixture of oxidizable catalyst material and inert support media therein.
- a conveyor 104 may deliver the mixture to segregation component 100 b .
- the conveyor 104 may be of any construction capable of moving material.
- the conveyor may include a belt conveyer, a slat conveyor, a troughed belt conveyor, a bucket conveyor, a screw conveyor, a vertical lift conveyor, a cart-on-track conveyor, a tow conveyor, a trolley conveyor, a sortation conveyor or any other mechanism capable of moving material from one location to another.
- the conveyor may rely on gravity to feed segregation component 100 b .
- the conveyor may simply be a chute or a conduit through which the mixture flows by gravity.
- a screw auger may be part of conveyor 104 .
- conveyor 104 may be enclosed or otherwise sealingly engaged with flow bins 102 to limit exposure of the catalyst to oxygen as the catalyst travels from delivery component 100 a to segregation component 100 b .
- Such limitation on oxygen exposure may be facilitated by a supply of inert gas to the system, as is described greater detail below.
- a mixture conveyor may include a controllable inlet for permitting selective passage of the mixture while limiting loss of inert gas.
- conveyor 104 may be selectively isolatable (either completely or partially) from the delivery component 100 a for maintaining an inert gas environment in a housing of conveyor 104 .
- a gated inlet (not shown) may permit selective passage of the mixture into conveyor 104 while limiting loss of the inert gas.
- the gate may be either electronically or mechanically controlled so that when mixture is not passing into conveyor 104 , the gate is closed. If electronic, a processor may control both the conveyor and the gate so that the gate opens to deliver mixture to a moving conveyor and closes thereafter to environmentally isolate the delivery component 100 a from the conveyor 104 .
- a goal may simply be to reduce oxygen levels below a threshold level (for example, to below a level that poses an unacceptable risk of an adverse oxidation reaction).
- segregation component 100 b may include enclosure 108 , screen assembly 110 , inert support media conveyor 114 and one or more catalyst material conveyors 116 , 120 .
- inert support media conveyor and “catalyst material conveyor” are illustrative and non-limiting.
- Conveyers 114 , 116 , and 120 may be utilized to transport other non-hazardous or hazardous materials depending on the composition of the mixture to be segregated.
- Conveyers 114 , 116 , and 120 may be utilized to transport both topping and catalyst. If for example, the mixture consists of only hazardous materials (e.g. topping and catalyst) one conveyor could be used to transport the larger of the hazardous components while one or more other conveyors could be used to transport the smaller hazardous components.
- the entirety of segregation component 100 b or components thereof may be portable so as to facilitate relocation between industrial sites.
- An inert gas inlet may be associated with the enclosure to permit the inert gas to enter the enclosure to displace oxygen within the enclosure to thereby limit oxidation of the oxidizable catalyst while the at least one motor moves the plurality of stacked screens.
- the term “associated with” means disposed on, in, in proximity to, or otherwise positioned to enable inert gas to enter the enclosure.
- Inlet refers to any opening, valve, port or other construct for allowing inert gas to flow into the enclosure.
- enclosure 108 may include an inert gas inlet 112 for receiving inert gas 109 .
- Inert gas inlet 112 may be located in a lower portion of the enclosure to enable the inert gas to flow over the catalyst material and exit the enclosure through a top portion of the enclosure. In this way, inert gas is permitted to blanket the catalyst and thereby limit the risk of oxidation.
- Some disclosed embodiments may include a plurality of stacked screens within the enclosure, the stacked screens having openings that decrease in size from a top of the stack to a bottom of the stack.
- the term “screen” includes any structure with openings therein through which material smaller than the sizes of the openings may pass.
- a screen may have a lattice or woven structure, formed of strips, wire or any other material.
- a screen may include a surface perforated with holes.
- a series of spaced apart bars may constitute a screen as may a sheet of metal, carbon fiber, or other material with openings therethrough. Indeed, any surface regardless of shape or structure may constitute a screen so long as it permits some sizes of materials to pass through while retaining larger sized materials.
- Screens are considered stacked if they assume an arrangement whereby one screen is positioned above at least one other screen, regardless of the distance between them. Typically, the distance between two stacked screens should be at least sufficient to allow material on an upper screen to pass through to a lower screen. Any number of screens may constitute a stack.
- the sizes of the openings in lower screens may be smaller than the size of the openings of upper screens. In this way, larger pieces of material may be retained on an upper screen, while smaller pieces fall through to a lower screen.
- Stacked screens may be parallel to one another, sloped, or combinations thereof.
- a “screen” may include any porous or perforated stackable structure capable of separating a material mixture into discrete components.
- each screen may include a metallic mesh having holes or openings
- a stack of screens may include screens with holes or openings that decrease in size from a top of the stack to a bottom of the stack.
- the openings in the screens may have any shape or configuration (round, rectangular, square, etc.).
- an uppermost screen of the stack may define a plurality of holes having a size (or diameter) D 1
- a second screen below the first screen may define a plurality of holes having a size (or diameter) D 2
- a third screen below the second screen may define a plurality of holes having a size (or diameter D 3 ), such that D 1 >D 2 >D 3 .
- any number of screens may be stacked together.
- the number of screens in a stack may correspond to the number of differently sized components to be segregated (e.g., three screens for three differently sized components).
- D 1 may be sized such that the largest of the three components is blocked by the first screen and the other two smaller sized components are allowed to pass through to the second screen.
- a size D 2 of the openings in the second screen may be such that the second largest component is blocked, thereby allowing the smallest component to pass through to the third screen.
- Information relating to the number of screens may be obtained in advance, e.g., based on the loading plan of the refinery, or determined on site. This configuration allows for the smaller sized hazardous components, e.g., catalyst and topping material, to filter down through the stack and the larger inert support media to remain in a separate upper portion of the stack.
- Diameter D 1 may be smaller than the size (e.g., diameter) of the inert support media, which may range in size, for example from 2 mm-2 in., including: 2-4 mm, 5-7 mm, 9-11 mm, 11-13 m, 14-17 mm, 18-21 mm, 23-27 mm, 36-40 mm, 46-50 mm, 1 ⁇ 8 in., 1 ⁇ 4 in., 3 ⁇ 8 in., 1 ⁇ 2 in., 1 in., 1.5 in, and 2 in.
- the size (e.g., diameter) of the inert support media which may range in size, for example from 2 mm-2 in., including: 2-4 mm, 5-7 mm, 9-11 mm, 11-13 m, 14-17 mm, 18-21 mm, 23-27 mm, 36-40 mm, 46-50 mm, 1 ⁇ 8 in., 1 ⁇ 4 in., 3 ⁇ 8 in., 1 ⁇ 2 in., 1 in., 1.5 in, and 2 in.
- screen assembly 110 includes a plurality of stacked screens 111 (including screens 111 a , 111 b , etc.) configured to separate the inert support media from one or more hazardous components.
- the hazardous components of the mixture are smaller in diameter than the inert support material and therefore pass through openings 113 a in screen 111 a and onto lower screen 111 b .
- screens 111 a and 111 b may be sloped to allow separated inert and hazardous components to collect at the bottom of their corresponding screens.
- the screen assembly 110 may include a base 121 on which the screens and their associated housing 123 are supported.
- a plurality of springs 119 may be disposed between the screen housing 123 and the base 121 to absorb the shock of falling material and screen vibrations.
- Housing 123 may define sidewalls to which a motor 115 may be attached.
- a sidewall may fully enclose a side of the housing 123 , as illustrated for example in FIG. 3A .
- the sidewall may only partially enclose a side of the housing such that cleaning, maintenance, or adjustments to the screens may be made through a side of the housing.
- a mixture of inert and hazardous material may enter screen assembly 110 through inlet 117 at the top of the screen assembly 110 and fall onto the topmost screen of the plurality of stacked screens 111 (i.e., screen 111 a ). Maintenance and cleaning may also be performed through a port 125 at a top of the screen assembly. It should be noted that although only one inlet 117 is illustrated in the figures, in some embodiments, multiple inlets may be provided.
- At least one inert support media outlet may be associated with at least one of the plurality of stacked screens.
- the inert support media outlet may direct the separated inert support media to a location out of the enclosure.
- the term “associated with” means positioned or otherwise oriented to permit inert support media to be transferred from at least one of the stacked screens to a location outside of the enclosure.
- Outlet refers to any opening, conduit, hole, port, valve or other construct for allowing inert support media to be removed from the screen.
- the outlet may be formed on housing 123 of screen assembly 110 . One or more outlets may be used to achieve this purpose.
- an air lock (not shown) may be associated with the inert support media outlet.
- FIG. 3A illustrates an inert support media outlet 137 a disposed on an outer surface of housing 123 .
- Outlet 137 a may be positioned to intersect with support media that has collected at a bottom of screen 111 a .
- Screen 111 a may be sloped toward outlet 137 a such that inert support media at the intersection exits through outlet 137 a .
- outlet 137 a is depicted, in general, any number of outlets may be provided.
- a catalyst material outlet may be associated with at least another of the plurality of stacked screens.
- the catalyst material outlet may direct the separated oxidizable catalyst material to a location outside the enclosure.
- the term “associated with” means positioned or otherwise oriented to permit oxidizable catalyst material to be transferred from another screen to a location outside of the enclosure.
- One or more outlets may be used to achieve this purpose.
- An air lock (not shown) may also be associated with the catalyst material outlet. The air lock may limit the amount of inert gas leaving the enclosure via the catalyst material outlet.
- catalyst material outlets 137 b and 137 c may be disposed on an outer surface of housing 123 .
- Outlets 137 b and 137 c may be positioned to intersect with oxidizable catalyst material that has collected at a bottom of screen 111 b .
- Screen 111 b may be sloped toward outlets 137 b and 137 c such that oxidizable catalyst material at the intersection exits through the outlet.
- topping may also collect at the intersection of outlet 137 b and 137 c before exiting therethrough.
- At least one motor may be utilized for moving the stacked screens to cause the oxidizable catalyst material to separate from and migrate to a location beneath the inert support media.
- the motor may be electrical and operated remotely or directly, e.g., by switch.
- the term “motor,” as used herein, may refer to any electrical mechanism for inducing vibration of the screens.
- the intensity and/or duration of the vibration may be adjusted to reflect the load of the mixture. For example, stronger vibrations may be used to facilitate separation of large mixture loads. Alternatively, vibration intensity may remain constant, but for a longer duration to facilitate separation.
- the motor may be automated, such that the vibrations begin and/or end at a certain time or when the load on the screen reaches a predetermined threshold.
- FIG. 3A illustrates a motor 115 disposed on a sidewall of the housing 123 of screen assembly 110 .
- the motor may be placed at any of a variety of locations with respect to the screen assembly, so long as its placement is sufficient to enable movement of the screens and thus separation of the catalyst and support media.
- inert support media conveyor 114 may be secured to enclosure 108 via outlet 137 a such that it collects the separated inert support media. Although only one such conveyor is shown, it is to be understood that additional inert support media conveyors (and corresponding outlets) may be utilized to collect inert support media from screen assembly 110 .
- Catalyst material conveyor 116 may be secured to enclosure 108 via outlet 137 b and 137 c such that it collects the separated catalyst material.
- outlets 137 b and 137 c may each be secured to a catalyst material conveyor, as illustrated in FIG. 2 , to enable more rapid transport of the catalyst.
- conveyor 116 may be secured to a lower section of the enclosure corresponding to a position of a bottom most screen; however, this configuration may be altered depending on the size of the components to be separated. Conveyors 114 and 116 may also use screw elevation (or any of the means discussed above with respect to conveyor 104 ) to transport the separated components out of the enclosure and to a desired location. Separated inert support media may be transported, for example from conveyor 114 to receptacle 134 for recycling or disposal, while separated catalyst material may be transported to another receptacle 136 for reclamation, regeneration or landfill disposal as illustrated in FIG. 1 .
- system 100 may include one or more sensors for detecting a reduction of oxygen in the enclosure and a regulator for at least periodically supplying additional inert gas to the enclosure to account for loss of the inert gas.
- sensor means any device, module, machine, or system for directly or indirectly measuring, detecting, sensing, recording or storing oxygen concentration.
- the sensor may be located on an outer surface of the enclosure, within the enclosure, or at any other locale suitable for measuring, detecting, recording or storing the concentration of oxygen within the enclosure. Where the sensor is located within the enclosure, an observer may check a measurement of the sensor, via, e.g., window 132 .
- the regulator may be manually operated by an observer or automated to supply inert gas when the level of inert gas within the enclosure falls below a predetermined threshold.
- the sensor measures, detects, records and/or stores an oxygen concentration within the enclosure and signals the regulator to begin or stop supplying inert gas depending on the measured oxygen concentration. In this way, the sensor and regulator work together to automatically monitor and manage the level of oxygen in the enclosure.
- FIG. 1 depicts a regulator 126 disposed on an outer surface of the enclosure and a sensor 128 on a top of surface of the enclosure.
- System 100 may also include a grinder for grinding the separated oxidizable catalyst material into a powder.
- the grinder may be located in a region supplied with the inert gas, including, by way of example, the inside of the enclosure.
- the grinder may also be stationed at a remote location so long as the catalyst is supplied with inert gas to prevent the pulverized catalyst from oxidizing.
- the grinder may include an inlet for receiving catalyst from a catalyst conveyer.
- a ground catalyst conveyor may be associated with the grinder for transporting ground catalyst from the grinder for disposal.
- FIG. 2 illustrates a catalyst conveyor 120 , grinder 122 , and ground catalyst conveyor 124 .
- Catalyst conveyor 120 may be configured to transport catalyst from screen assembly 110 to grinder 122 .
- catalyst conveyor 120 may be connected to screen assembly 110 at, for example outlet 137 d .
- Outlet 137 d may receive catalyst from a lower-most screen of screen assembly 110 or directly from an accumulation of catalyst particles at the bottom of housing 123 .
- Ground catalyst may be transported via ground catalyst conveyor 124 to a bin or other receptacle 138 for disposal via, e.g., incineration.
- the system may use one or both catalyst conveyors 116 , 120 to dispose of catalyst.
- catalyst conveyors 116 , 120 When both are in use, segregated catalyst particles of a first size may be transported for disposal via catalyst conveyor 116 while segregated catalyst particles of a second, smaller size maybe transported for disposal via catalyst conveyor 120 .
- catalyst conveyor 116 may be used to transport topping while catalyst conveyor 120 may be used to transport catalyst.
- inert gas is introduced into an enclosure.
- the enclosure may contain a plurality of stacked screens, each stacked screen having openings that decrease in size from a top of the stack to a bottom of the stack.
- the inert gas may be nitrogen and enter the enclosure 108 via inert gas inlet 112 .
- one or more flow bins 102 may be filled with a mixture of oxidizable catalyst material and inert support media.
- Enclosure 108 may be pressurized using the inert gas so as to displace oxygen within the enclosure.
- the mixture is introduced to an uppermost one of the plurality of stacked screens.
- the mixture may be transported directly from one or more flow bins 102 to the enclosure using, e.g., a gravity dump, or indirectly through conveyor 104 and into inlet 117 of screen assembly 110 , where it drops onto uppermost screen 111 a.
- the plurality of stacked screens are moved to cause the oxidizable catalyst material to separate from and migrate to a location beneath the inert support media.
- Motor 115 may be used to move the screens and thereby facilitate separation.
- the intensity and/or duration of the movement may be adjusted to reflect the load of the mixture; with longer durations and/or stronger movement being used to separate larger quantities of mixture.
- Inert support media on uppermost screen 111 a may collect at the bottom of the screen where the screen intersects with outlet 137 a , while separated catalyst material at a bottom of the stack, for example on screen 111 b , may collect where the screen intersects outlets 137 b and 137 c .
- the mixture may alternatively be deposited onto a lower screen, e.g., a second or third highest screen, so long as a sufficient number of screens are utilized to enable separation of the differently sized mixture components.
- the separated inert support media may be conveyed to a location outside the enclosure for recycling or disposal as non-hazardous waste. Separated inert support media may collect at a bottom of screen 111 a , then directed through outlet 137 a , and into inert support media conveyor 114 . Inert support media conveyor 114 may transport the separated inert support media to receptacle 134 , after which it may be disposed of or repurposed as desired.
- separated oxidizable catalyst material may be conveyed to a location outside the enclosure for at least one of reclamation or thermal destruction. Separated oxidizable catalyst material may be directed to any one of outlets 137 b , 137 c and/or 137 d . Where, for example, separated catalyst material is routed through outlets 137 b and/or 137 c , catalyst conveyor 116 may transport the separated catalyst to a receptacle 136 for reclamation and/or thermal destruction. If separated catalyst material is routed through outlet 137 d , the catalyst may be ground as described in detail with respect to FIG. 5 .
- a method of disposing of a mixture of oxidizable catalyst material and inert support media will now be discussed with respect to the exemplary method illustrated in FIG. 5 .
- inert gas is introduced into an enclosure.
- the enclosure may contain a plurality of stacked screens, each stacked screen having openings that decrease in size from a top of the stack to a bottom of the stack.
- the inert gas may be nitrogen and enter the enclosure 108 via inert gas inlet 112 .
- one or more flow bins 102 may be filled with a mixture of oxidizable catalyst material and inert support media.
- Enclosure 108 may be pressurized using the inert gas so as to displace oxygen within the enclosure.
- the mixture is introduced into the enclosure.
- the mixture may be introduced into the screen assembly via inlet 117 and onto an uppermost one of the plurality of stacked screens.
- the mixture may be transported directly from one or more flow bins 102 to the enclosure using, e.g., a gravity dump, or indirectly through conveyors 104 and 106 .
- the oxidizable catalyst material and the inert support media within the enclosure are separated.
- the plurality of stacked screens are moved to cause the oxidizable catalyst material to separate from and migrate to a location beneath the inert support media.
- Motor 115 may be used to move the screens and thereby facilitate separation.
- the intensity and/or duration of the movement may be adjusted to reflect the load of the mixture; with longer durations and/or stronger movement being used to separate larger quantities of mixture.
- Inert support media on uppermost screen 111 a may collect at the bottom of the screen where the screen intersects with outlet 137 a while separated catalyst material at a bottom of the stack, for example on screen 111 b , may collect where the screen intersects outlets 137 b and 137 c .
- the mixture may alternatively be deposited onto a lower screen, e.g., a second or third highest screen, so long as a sufficient number of screens are utilized to enable separation of the differently sized mixture components.
- an inert gas environment is maintained around the oxidizable catalyst material during separating.
- a sensor for detecting a reduction of oxygen in the enclosure and a regulator for at least periodically supplying additional inert gas to the enclosure may be used to maintain the inert gas environment.
- the regulator may be manually operated by an observer or automated to supply inert gas when the level of inert gas within the enclosure falls below a predetermined threshold.
- the sensor may measure an oxygen concentration within the enclosure and signal the regulator to begin or stop supplying inert gas depending on the measured oxygen concentration. In this way, the sensor and regulator work together to automatically monitor and manage the level of oxygen in the enclosure.
- the separated inert support media is exported from the enclosure.
- the separated inert support media may be conveyed to a location outside the enclosure for recycling or disposal as non-hazardous waste. Separated inert support media may collect at a bottom of screen 111 a , where it is then directed through outlet 137 a , and into inert support media conveyor 114 .
- Inert support media conveyor 114 may transport the separated inert support media to receptacle 134 , after which it may be disposed of or repurposed as desired.
- the separated oxidizable catalyst material is ground into a powder for disposal as hazardous waste via incineration.
- Separated catalyst material is routed through outlet 137 d , which is connected to catalyst conveyor 120 .
- Catalyst conveyor 120 transports the separated catalyst to a grinder 122 .
- the ground catalyst may be transported via ground catalyst conveyor 124 to a receptacle 138 for reclamation and/or thermal destruction.
- the receptacle may be secured to a vehicle for immediate transportation as illustrated in FIG. 1 or loaded onto a vehicle at a later time.
- a method of disposing of a mixture of oxidizable catalyst material and inert support media will now be discussed with respect to the exemplary method illustrated in FIG. 6 .
- inert gas is introduced into an enclosure.
- the enclosure may contain a plurality of stacked screens, each stacked screen having openings that decrease in size from a top of the stack to a bottom of the stack.
- the inert gas may be nitrogen and enter the enclosure 108 via inert gas inlet 112 .
- one or more flow bins 102 may be filled with a mixture of oxidizable catalyst material and inert support media.
- Enclosure 108 may be pressurized using the inert gas so as to displace oxygen within the enclosure.
- a mixture of oxidizable catalyst material, grading material and inert support media are introduced into the enclosure.
- the mixture may be introduced into the screen assembly via inlet 117 and onto an uppermost one of the plurality of stacked screens.
- the mixture may be transported directly from one or more flow bins 102 to the enclosure using, e.g., a gravity dump, or indirectly through conveyor 104 .
- the oxidizable catalyst material, grading material and the inert support media within the enclosure are separated.
- the plurality of stacked screens are moved, using, e.g., motor 115 , to facilitate separation.
- the intensity and/or duration of the movement may be adjusted to reflect the load of the mixture; with longer durations and/or stronger movement being used to separate larger quantities of mixture.
- Inert support media on uppermost screen 111 a may collect at the bottom of the screen where the screen intersects with outlet 137 a , while separated catalyst and grading material at a bottom of the stack, for example on screen 111 b , may collect where the screen intersects outlets 137 b and 137 c .
- a third screen may be utilized.
- the smaller, e.g., catalyst material will be permitted to filter through the second screen and onto the third screen.
- the smaller catalyst may be permitted to accumulate at a bottom of the screener, in which case an additional screen is not needed.
- an inert gas environment is maintained around the oxidizable catalyst material during separating.
- a sensor for detecting a reduction of oxygen in the enclosure and a regulator for at least periodically supplying additional inert gas to the enclosure may be used to maintain the inert gas environment.
- the regulator may be manually operated by an observer or automated to supply inert gas when the level of inert gas within the enclosure falls below a predetermined threshold.
- the sensor may measure an oxygen concentration within the enclosure and signal the regulator to begin or stop supplying inert gas depending on the measured oxygen concentration. In this way, the sensor and regulator work together to automatically monitor and manage the level of oxygen in the enclosure.
- the separated inert support media is exported from the enclosure.
- the separated inert support media may be conveyed to a location outside the enclosure for disposal as non-hazardous waste. Separated inert support media may collect at a bottom of screen 111 a , where it is then directed through outlet 137 a , and into inert support media conveyor 114 .
- Inert support media conveyor 114 may transport the separated inert support media to receptacle 134 , after which it may be disposed of or repurposed as desired.
- grading material is conveyed to a location outside the enclosure.
- the separated material may be directed to outlet 137 b and/or 137 c and transported outside of enclosure 108 via conveyor 116 and into receptacle 136 for collection.
- separated oxidizable catalyst material is conveyed to a location outside the enclosure. Separated oxidizable catalyst material may be directed to any one of outlets 137 b , 137 c and/or 137 d . Where, for example, separated catalyst material is routed through outlets 137 b and/or 137 c , catalyst conveyor 116 may transport the separated catalyst to receptacle 136 . In some cases, the catalyst may be comingled with the grading material disposed of at step 610 .
- the separated oxidizable catalyst material may ground into a powder for disposal as hazardous waste via incineration.
- Catalyst conveyor 120 transports the separated catalyst to a grinder 122 .
- the ground catalyst may be transported via ground catalyst conveyor 124 to a receptacle 138 for reclamation, regeneration and/or landfill disposal.
- the receptacle may be secured to a vehicle for immediate transportation as illustrated in FIG. 1 or loaded onto a vehicle at a later time.
- Disclosed embodiments may include any one of the following bullet-pointed features alone or in combination with one or more other bullet-pointed features, whether implemented in connection with a device, a system, or a method:
- system 100 is described as being used to separate refinery waste (e.g., inert material from catalyst) in a mixture, as explained previously, this is only exemplary. In general, the systems and methods of the current disclosure may be used to separate or segregate the constituent components of a mixture in any application. While illustrative embodiments have been described herein, the scope of any and all embodiments having equivalent elements, modifications, omissions, combinations (e.g., of aspects across various embodiments), adaptations and/or alterations as would be appreciated by those skilled in the art based on the present disclosure. The limitations in the claims are to be interpreted broadly based on the language employed in the claims and not limited to examples described in the present specification or during the prosecution of the application.
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Abstract
Description
- The present disclosure generally relates to the field of petroleum refinement, and particularly relates to systems and methods for separating refinery byproducts into hazardous and non-hazardous components.
- The petrochemical refinement industry is constantly searching for ways to improve upon refinery efficiency and cost savings. One avenue for achieving these goals takes place at the front end of the refinement process through refinery material selection. Generally, a combination of catalysts, inert support balls, and grading material (also referred to as topping or trap material) are selected. These materials are loaded into one or more refinery unit vessels in accordance with a loading plan which specifies the quantity and distribution of the materials in the vessels. The particular type of catalyst chosen depends on the desired product (e.g. diesel, jet fuel, or kerosene) and catalyst performance (dictated by expected catalyst lifetime, raw material, desired finish product specifications, and other variables affecting the rate at which the catalyst is consumed). Topping is selected based on the desired application (e.g., hydrotreating, hydrogenation, hydrydrocracking, lube oils, or wax), and inert support balls are generally made of alumina, ceramic or silica.
- In use, the inert support balls are loaded into the bottom of the vessel followed by a layer of catalyst (catalyst bed). Layers of inert support balls and catalyst may be deposited in an alternating fashion until, for example, 1-10 layers of catalyst may be deposited with intervening layers of inert support balls. The inert support balls help to evenly distribute raw petrochemical material and synthesized refined product across the catalyst bed. Finally, grading material may be loaded on top of the layers to “trap” or remove impurities such as vanadium, nickel, or arsenic from the raw material. This grading material may be comprised of a single material or various materials, each configured to trap/remove a particular impurity. The catalyst converts the raw material into the refined product. This reaction ultimately causes catalyst activity and pressure within the refinery unit to decrease.
- In order to efficiently process additional raw materials, the mixture of catalyst, inert support balls and grading are changed out once the unit pressure and/or catalyst activity fall below a predetermined threshold. During this process, inert gas (often nitrogen) is forced into one or more vessels of the refinery unit to purge any remaining raw material and liquid product. This purge leaves only the catalyst, topping and inert support (collectively known as industrial waste) behind. The day on which this change occurs is commonly known in industry as the “oil out” date and may be predicted using unit performance indicators and raw material specifications. Data relating to a previous oil out date may also be used to predict the next oil out date. A target oil out date is set well in advance (often 18-24 months) to account for replacement catalyst manufacture time. The vessel is allowed to cool down (e.g. to 300° F.) and the remaining catalyst, topping and inert support balls are extracted. Refineries generally replace all of the catalyst within a unit at the same time to take advantage of the “unit down time” and cut costs.
- Generally, extraction involves a “gravity dump,” during which the catalyst, topping and inert support are permitted to fall through a valve in the bottom of the vessel. The material feeds into a pipe, which leads to flow bins or the desired packaging for holding and transporting the material. The rate at which the material enters the flow bins is generally regulated manually by a valve. Since each flow bin only holds about 1-2.5 tons, this process is repeated (5-500 times depending on the size of the vessel) until the vessel is empty. A vacuum may be used as an alternative to the gravity dump, in which case, material is vacuumed through the top of the vessel and into the flow bins or other packaging of choice.
- Once the materials are extracted, the vessels are refilled, and the flow bins (or packaging of choice) are directed to a holding area, where they await inventory, sampling, and profile generation for the destination process facility. The Environmental Protection Agency categorizes spent catalyst and topping as “hazardous waste” (e.g. K171 or K172); therefore, certain disposal guidelines must be followed. Three disposal methods: are common in industry. One such method involves reclamation. During reclamation, the waste is “roasted” to render the hazardous materials inert, then processed using leaching or pyro-metallurgical techniques to extract metals, e.g., vanadium pentoxide, nickel, and molybdenum from the materials. Another method of disposal involves “regeneration.” During regeneration, the waste is carefully roasted so that a percentage of the spent catalyst may be re-introduced into the refining process. Yet another method of disposal sends roasted waste to landfill. More recently, refineries have the option to send their waste materials to cement kilns for alumina and energy reclamation. Since kilns process liquids more easily than solids, the catalyst may be transformed into a slurry to facilitate processing. These catalyst particles fall out of the slurry suspension, clogging pipes and disrupting the overall process.
- Although inert support is generally classified as non-hazardous (in some instances classified as hazardous) and account for up to 25% of refinery waste, many refineries incur the same cost/pound for processing, packaging, and transporting non-hazardous waste as they do for hazardous waste. This is because refineries do not separate the materials into hazardous and non-hazardous components prior to disposal. This unnecessary expense is often compounded by the cost of international shipping. Available options for separating the materials are insufficient as they still require the refinery to continue to ship waste offsite resulting in additional cost.
- The systems and methods described herein address at least some of the drawbacks of traditional industrial waste disposal by simplifying and mobilizing the industrial waste segregation process. Such systems and methods may allow refineries to reduce the premium on hazardous waste management and the amount of reportable hazardous waste.
- The present disclosure provides methods and systems for efficiently segregating hazardous topping and catalyst material from inert support media. Although reference is made to hazardous catalyst and topping material, it is to be understood that systems and methods disclosed herein may be used to separate hazardous materials from other hazardous materials and non-hazardous materials from other non-hazardous materials.
- A first aspect of the disclosure provides a system for segregating a mixture of oxidizable catalyst material and inert support media. The system may include an enclosure configured to contain inert gas and a plurality of stacked screens disposed within the enclosure. The stacked screens may include openings that decrease in size from a top of the stack to a bottom of the stack. The enclosure may include a mixture inlet positioned to enable delivery of the mixture to an uppermost stacked screen. The system may further comprise at least one motor for moving the stacked screens to cause the oxidizable catalyst material to separate from and migrate to a location beneath the inert support media; at least one inert support media outlet associated with at least one of the plurality of stacked screens and for conveying the separated inert support media to a location outside the enclosure; a catalyst material outlet associated with at least another of the plurality of stacked screens for conveying the separated oxidizable catalyst material to a location outside the enclosure; and an inert gas inlet associated with the enclosure for conveying the inert gas to the enclosure. The inert gas displaces oxygen within the enclosure to thereby limit oxidation of the oxidizable catalyst while the at least one motor moves the plurality of stacked screens.
- Another aspect of the disclosure provides a method for disposing a mixture of oxidizable catalyst material and inert support media. The method may include introducing inert gas into an enclosure; introducing the mixture into the enclosure; separating the oxidizable catalyst material and the inert support media within the enclosure; maintaining an inert gas environment around the oxidizable catalyst material during separating; exporting the separated inert support media from the enclosure; and grinding the separated oxidizable catalyst material into a powder for disposal as hazardous waste via incineration.
- Yet another aspect of the disclosure provides a method for disposing of a mixture of oxidizable catalyst material and inert support media. The method may include introducing inert gas into an enclosure, wherein the enclosure contains a plurality of stacked screens having openings that decrease in size from a top of the stack to a bottom of the stack; introducing the mixture to an uppermost one of the plurality of stacked screens; moving the plurality of stacked screens to cause the oxidizable catalyst material to separate from and migrate to a location beneath the inert support media; conveying the separated inert support media to a location outside the enclosure for disposal as non-hazardous waste; and conveying the separated oxidizable catalyst material to a location outside the enclosure for at least one of reclamation, thermal destruction, thermal processing, regeneration and/or disposal in a landfill.
- The accompanying drawings, which are incorporated in and constitute a part of this disclosure, illustrate various disclosed embodiments. In the drawings:
-
FIG. 1 is a perspective view of a system for segregating a mixture of oxidizable catalyst material and inert support media in accordance with embodiments of this disclosure. -
FIG. 2 is a partial cut-away view of the assembly depicted inFIG. 1 . -
FIG. 3A is a detailed view of the screen assembly illustrated inFIG. 1 . -
FIG. 3B is a partial cut-away view of the screen assembly illustrated inFIG. 3A . -
FIG. 4 is a block diagram of a first exemplary process in accordance with embodiments of this disclosure. -
FIG. 5 is a block diagram of a second exemplary process in accordance with embodiments of this disclosure. -
FIG. 6 is a block diagram of another exemplary process in accordance with embodiments of this disclosure. - The following detailed description refers to the accompanying drawings. Wherever possible, the same reference numbers are used in the drawings and the following description to refer to the same or similar parts. While several illustrative embodiments are described herein, modifications, adaptations and other implementations are possible. For example, substitutions, additions, or modifications may be made to the components illustrated in the drawings, and the illustrative methods described herein may be modified by substituting, reordering, removing, or adding steps to the disclosed methods. Accordingly, the following detailed description is not limited to the disclosed embodiments and examples. Instead, the proper scope is defined by the appended claims.
- Some embodiments of this disclosure may involve systems and methods for segregating materials in a mixture. Although embodiments of the current disclosure may be used to segregate (or separate) one or more constituent materials of any type of mixture, in the discussion that follows, an exemplary embodiment of segregating or separating constituent materials of industrial waste is described. Industrial waste for example, may include petrochemical refinement waste, which while classified as hazardous, may be made up of both hazardous and non-hazardous components. The non-hazardous components may include an inert material, such as inert support media made of, by way of example, alumina, ceramic or silica. The hazardous components may include an oxidizable catalyst and grading material. Together, these components may form a mixture. If the catalyst can be separated from the inert materials, the inert materials can be sold, recycled, or disposed of as non-hazardous waste, reducing the overall disposal cost. Moreover, in some instances, the catalyst, if separated from the inert materials, might be reclaimed and reused, lowering overall processing costs. In other instances, the catalyst may be disposed of, such as through incineration.
- The term “catalyst” as used herein refers includes any of a variety of catalyst materials that are used in the refinement of oil, including but not limited to those listed in Table 1 below. It should be noted that the materials listed in the table are only exemplary, and in general, the catalyst may include any currently used or later developed catalyst material.
-
TABLE 1 Z-863 TL (1.6) Z-853 TL (2.5) Z-853 TL (1.6) Z-803 TL (1.6) Z-753 CY (2.8) Z-753 CY (1.6) Z-503 TL (2.5) Z-503 TL (1.3) UF-210 TK-951 TK-943 TK-941 TK-931 TK-928 TK-926 TK-925 TK-915 TK-911 TK-907 TK-831 TK-799 TK-797 TK-773 TK-753 TK-743 TK-733 TK-719 TK-711 TK-710 TK-709 TK-607 TK-605 BRIM TK-576 BRIM TK-575 BRIM TK-574 TK-573 TK-570 BRIM TK-565 TK-562 TK-561 BRIM TK-561 TK-560 TK-559 BRIM TK-558 BRIM TK-554+ TK-553 TK-551 TK-550 TK-527 TK-47 TK-453 TK-45 TK-439 TK-437 TK-431 TK-341 TK-339 TK-30 TK-261 TK-250 TK-25 Top Trap TK-224 TK-222 TK-220 TK-15 TK-10 support SK-201-A SK-201-2 RN-412 TL (2.5) RN-412 TL (1.3) RN-412 RM-5030 TL (5.6) RM-5030 TL (2.5) RM-5030 TL (1.6) RM-5030 TL (1.3) RM-5030 RKS-5-7H, 16 × 11 RKNGR, 4.5 × 4.5 RK-212, 16 × 11 RK-212 RK-211, 16 × 11 RK-202, 16 × 11 RK-202 RK-201, 16 × 11 RK-201 R-67-7H, 16 × 11 R-67-7H PK-7R OptiTrap 855 MD OptiTrap (Ring) HC 6.4 OptiTrap (Ring) OptiTrap (Medallion) OptiTrap (MacroRing) NK-621 NDXi N-205 1.5Q MaxTrap (Ni, V) VGO MaxTrap (Ni, V) MaxTrap (As) LK-823 LK-821-2 LK-813 LK-811 KG-6-3Q KG-55 KG-5-2Q/3Q KG-1-5B KF-905 KF-902 KF-901-3Q KF-901-1.5E KF-859-2Q KF-859-1.5Q KF-857 KF-848-2Q KF-848-1.3Q KF-846-3Q KF-846-1.3Q KF-844 KF-843 KF-841-3Q KF-841-1.5Q KF-840-3Q KF-767 KF-757-3Q KF-757-1.5E KF-756 KF-752 KF-648-3Q KF-648-1.3Q KF-647-3Q KF-647-1.3Q KF-542-5R/9R KF-542-5Q KF-124LD InterLayer (CoMo) ICR 210L ICR 210 L ICR 179(All Sizes) ICR 179 NAQ ICR 179 LAQ ICR 178NAQ ICR 168NAQ ICR 160 LAQ ICR 154NAQ ICR 141N84 ICR 141LY8 ICR 141LY4 ICR 141LY2 ICR 141LW8 ICR 141LW4 ICR 141LW2 ICR 141LAQ ICR 141 LW8 ICR 141 LW4 ICR 141 LW2 ICR 141 LAQ ICR 139Q01 ICR 139 Q01 ICR 132NAQ ICR 122ZSF ICR 122ZSB ICR 122 ZSB ICR 114(All Sizes) ICR 114 NAQ ICD 132 NAQ HTZ-5 HTZ-3 HT-86TL HT-80R HT-428 HR-945 HR-845 HR-841 HR-806S HR-626 HR-568 HR-538 HR-448 HR-426 HR-416 HR 468 HOP-802K HOP-802 HOP-608K HOP-606HK HOP-606H HOP-603K HOP-492K HC-80 HC-53LT HC-26L HC-24L HC-150LT HC-120LT GSK-9 GSK-6A GSK-19 GN-863 TL (2.5) GC-862 TL (2.5) DN-3551 TL 1.3 DN-3531 TL DN-3310 TL DN-3300 TL DN-3120 TL DN-3110 TL DN-3100 TL DN-200 TL DN-200 DN-140 TL DN-140 DHC-39LT DD-431 DC-2551 1.3 DC-2533 DC-2532 DC-2531 TL DC-2318 TL DC-2118 TL DC-130 CR-55 CENTINEL GOLD DN-3330 CENTINEL GOLD DN-3310 CENTINEL GOLD DN-3300 CENTINEL GOLD DC-2318 CENTINEL DN-3120 CENTINEL DN-3110 CENTINEL DN-3100 CENTINEL DC-2118 CDXi CDX CatTrap 65 CatTrap 50 CatTrap 30 CatTrap 10 C-411 AT792 AT775 AT724G AT580 AT575 AT535 AT514 AT510 AT505 (All Sizes) AT505 AT405 1/10″ AT405 ASCENT DC-2531 AR-401, 11 × 6 AR-301, 4.5 × 4.5 AFS-1050 AFS-1025 AFS-1010 ADS-120 ACT-989 ACT-951 ACT-931 ACT-070 (inert) ACT-068 (inert) 834 HC (8.0) 834 HC - 8 815 HC (6.4) 815 HC (4.8) 815 HC - 6.4 815 HC - 4.8 814 HC 720X 534 SH (8.0) 534 SH (4.0) 514 SH 234 TL (3.2) 855 834 815 534 465 234 - The term “segregating,” as used herein, refers to separating (or to a process used to separate) one or more constituents of a mixture. For example, in the exemplary embodiment described below, segregating may include separating oxidizable catalyst from inert support media in a mixture or a process where oxidizable catalyst is separated from inert support media, or vice versa. While some embodiments in this disclosure employ screen devices for segregating, in the broadest sense, the methods of this disclosure are not limited to any particular segregation structure. Alternative structures for separating materials by size or composition may be employed within the broad scope of this disclosure.
- The term “inert gas,” as used herein, refers to a gas that does not undergo a chemical reaction under the prevailing conditions. As would be recognized by a person of ordinary skill in the art, inert gases may include elemental gases, such as, for example, nitrogen and noble gases, or may include compound gases (i.e., a mixture of gases that does not undergo chemical reaction under prevailing conditions).
- The systems and methods described herein may be provided on site at a refinery, in proximity to a refinery, in proximity to a remote waste treatment or reclamation facility, or at a remote waste treatment or reclamation facility. Thus, while the present disclosure is not limited to mobile segregation systems, in some disclosed embodiments, segregation systems may be mobile or may be constructed of components that may be movable.
- One example of a system for segregating a mixture of oxidizable catalyst material and inert support material may include
segregation component 100 b depicted inFIG. 1 . As described herein in greater detail, thesegregation component 100 b may include various components for segregating a mixture of oxidizable catalyst material and inert support media. In other embodiments, a system may include additional components, such asdelivery component 100 a, an inertmaterial collection container 134 and one or morecatalyst collection containers - Some disclosed embodiments may include an enclosure configured to contain inert gas. One challenge in handling some oxidizable materials is that they may become volatile when exposed to air. Thus, in some embodiments, segregation of inert support media and oxidizable catalyst material may occur in any container capable of receiving an inert gas and minimizing catalyst oxidation to an acceptable level (for example, to a level sufficient to reduce unacceptable risk). The container may have a lid, but need not have any particular form nor be made of any particular material, so long as it enables a sufficient amount of oxygen in the enclosure to be replaced by an inert gas while the segregation is taking place.
- For example, in
FIG. 1 ,enclosure 108 ofsegregation component 100 b may be a modified shipping container that is capable of being transported by a vehicle. Although not necessarily hermitically sealed,enclosure 108 may be designed to retain enough inert gas and/or exclude enough oxygen to enable a segregation process while minimizing the risk of setting off a dangerous catalyst oxidation reaction. In some embodiments,enclosure 108, may be provided with sealing material to enhance inert gas retention.Enclosure 108 may be pressurized using the inert gas.Inert gas 109 may be nitrogen or any other gas that does not induce a chemical reaction (e.g., a volatile reaction) when exposed to the mixture of catalyst and support media.Inert gas 109 may be contained in pressurized inert gas tank and may be fluidly coupled, or flow-connected, to the enclosure. In accordance with some embodiments,enclosure 108 may include one ormore vents 118 for permitting gas within the enclosure to escape.Vents 118 may include openings, valves, filters, or any other mechanism suitable for allowing gas to escapeenclosure 108 while limiting introduction of ambient oxygen into the enclosure.Enclosure 108 may also include anobservation window 132 in an outer wall thereof, and an illuminator 130 (e.g., a light, etc.) (seeFIG. 2 ) within the enclosure to enable external observation of the mixture segregation, as illustrated inFIG. 2 . An observer may check the progress of the segregation process through the enclosure window if desired. - By way of one non-limiting example,
FIG. 1 illustrates anexemplary system 100 for segregating a mixture of oxidizable catalyst material and inert support media.System 100 may include adelivery component 100 a and asegregation component 100 b.Delivery component 100 a may include one ormore flow bins 102 for containing the mixture of oxidizable catalyst material and inert support media therein. Aconveyor 104 may deliver the mixture tosegregation component 100 b. Theconveyor 104, may be of any construction capable of moving material. For example, it may include a belt conveyer, a slat conveyor, a troughed belt conveyor, a bucket conveyor, a screw conveyor, a vertical lift conveyor, a cart-on-track conveyor, a tow conveyor, a trolley conveyor, a sortation conveyor or any other mechanism capable of moving material from one location to another. In some embodiments (not shown) where thedelivery component 100 a is located abovesegregation component 100 b, the conveyor may rely on gravity to feedsegregation component 100 b. In such instances, the conveyor may simply be a chute or a conduit through which the mixture flows by gravity. Alternatively, for example, a screw auger may be part ofconveyor 104. In some embodiments,conveyor 104 may be enclosed or otherwise sealingly engaged withflow bins 102 to limit exposure of the catalyst to oxygen as the catalyst travels fromdelivery component 100 a tosegregation component 100 b. Such limitation on oxygen exposure may be facilitated by a supply of inert gas to the system, as is described greater detail below. - In some embodiments, a mixture conveyor may include a controllable inlet for permitting selective passage of the mixture while limiting loss of inert gas. For example,
conveyor 104 may be selectively isolatable (either completely or partially) from thedelivery component 100 a for maintaining an inert gas environment in a housing ofconveyor 104. A gated inlet (not shown) may permit selective passage of the mixture intoconveyor 104 while limiting loss of the inert gas. The gate may be either electronically or mechanically controlled so that when mixture is not passing intoconveyor 104, the gate is closed. If electronic, a processor may control both the conveyor and the gate so that the gate opens to deliver mixture to a moving conveyor and closes thereafter to environmentally isolate thedelivery component 100 a from theconveyor 104. It is to be understood that reference herein to environmental isolation or an inert gas environment does not necessarily require hermetic sealing. Rather, a goal may simply be to reduce oxygen levels below a threshold level (for example, to below a level that poses an unacceptable risk of an adverse oxidation reaction). - With additional reference to
FIG. 2 ,segregation component 100 b may includeenclosure 108,screen assembly 110, inertsupport media conveyor 114 and one or morecatalyst material conveyors Conveyers conveyors 116 and/or 120 may be utilized to transport both topping and catalyst. If for example, the mixture consists of only hazardous materials (e.g. topping and catalyst) one conveyor could be used to transport the larger of the hazardous components while one or more other conveyors could be used to transport the smaller hazardous components. - The entirety of
segregation component 100 b or components thereof may be portable so as to facilitate relocation between industrial sites. An inert gas inlet may be associated with the enclosure to permit the inert gas to enter the enclosure to displace oxygen within the enclosure to thereby limit oxidation of the oxidizable catalyst while the at least one motor moves the plurality of stacked screens. Here, the term “associated with” means disposed on, in, in proximity to, or otherwise positioned to enable inert gas to enter the enclosure. “Inlet” refers to any opening, valve, port or other construct for allowing inert gas to flow into the enclosure. By way of example with respect toFIG. 1 ,enclosure 108 may include aninert gas inlet 112 for receivinginert gas 109.Inert gas inlet 112 may be located in a lower portion of the enclosure to enable the inert gas to flow over the catalyst material and exit the enclosure through a top portion of the enclosure. In this way, inert gas is permitted to blanket the catalyst and thereby limit the risk of oxidation. - Some disclosed embodiments may include a plurality of stacked screens within the enclosure, the stacked screens having openings that decrease in size from a top of the stack to a bottom of the stack. As used herein, the term “screen” includes any structure with openings therein through which material smaller than the sizes of the openings may pass. For example, a screen may have a lattice or woven structure, formed of strips, wire or any other material. A screen may include a surface perforated with holes. A series of spaced apart bars may constitute a screen as may a sheet of metal, carbon fiber, or other material with openings therethrough. Indeed, any surface regardless of shape or structure may constitute a screen so long as it permits some sizes of materials to pass through while retaining larger sized materials.
- Screens are considered stacked if they assume an arrangement whereby one screen is positioned above at least one other screen, regardless of the distance between them. Typically, the distance between two stacked screens should be at least sufficient to allow material on an upper screen to pass through to a lower screen. Any number of screens may constitute a stack. The sizes of the openings in lower screens may be smaller than the size of the openings of upper screens. In this way, larger pieces of material may be retained on an upper screen, while smaller pieces fall through to a lower screen. Stacked screens may be parallel to one another, sloped, or combinations thereof.
- Thus, a “screen” may include any porous or perforated stackable structure capable of separating a material mixture into discrete components. In one embodiment, each screen may include a metallic mesh having holes or openings, and a stack of screens may include screens with holes or openings that decrease in size from a top of the stack to a bottom of the stack. The openings in the screens may have any shape or configuration (round, rectangular, square, etc.). For example, an uppermost screen of the stack (or a first screen) may define a plurality of holes having a size (or diameter) D1, a second screen below the first screen may define a plurality of holes having a size (or diameter) D2, and a third screen below the second screen may define a plurality of holes having a size (or diameter D3), such that D1>D2>D3. In general, any number of screens may be stacked together. In some embodiments, the number of screens in a stack may correspond to the number of differently sized components to be segregated (e.g., three screens for three differently sized components). For example, if the mixture includes three components to be segregated, D1 may be sized such that the largest of the three components is blocked by the first screen and the other two smaller sized components are allowed to pass through to the second screen. A size D2 of the openings in the second screen may be such that the second largest component is blocked, thereby allowing the smallest component to pass through to the third screen. Information relating to the number of screens may be obtained in advance, e.g., based on the loading plan of the refinery, or determined on site. This configuration allows for the smaller sized hazardous components, e.g., catalyst and topping material, to filter down through the stack and the larger inert support media to remain in a separate upper portion of the stack. Diameter D1 may be smaller than the size (e.g., diameter) of the inert support media, which may range in size, for example from 2 mm-2 in., including: 2-4 mm, 5-7 mm, 9-11 mm, 11-13 m, 14-17 mm, 18-21 mm, 23-27 mm, 36-40 mm, 46-50 mm, ⅛ in., ¼ in., ⅜ in., ½ in., 1 in., 1.5 in, and 2 in.
- By way of example, with reference to
FIGS. 3A-3B ,screen assembly 110 includes a plurality of stacked screens 111 (includingscreens openings 113 a inscreen 111 a and ontolower screen 111 b. In some embodiments,screens screen assembly 110 may include a base 121 on which the screens and their associatedhousing 123 are supported. A plurality ofsprings 119 may be disposed between thescreen housing 123 and the base 121 to absorb the shock of falling material and screen vibrations.Housing 123 may define sidewalls to which amotor 115 may be attached. In some embodiments, a sidewall may fully enclose a side of thehousing 123, as illustrated for example inFIG. 3A . In some embodiments, the sidewall may only partially enclose a side of the housing such that cleaning, maintenance, or adjustments to the screens may be made through a side of the housing. A mixture of inert and hazardous material may enterscreen assembly 110 throughinlet 117 at the top of thescreen assembly 110 and fall onto the topmost screen of the plurality of stacked screens 111 (i.e., screen 111 a). Maintenance and cleaning may also be performed through aport 125 at a top of the screen assembly. It should be noted that although only oneinlet 117 is illustrated in the figures, in some embodiments, multiple inlets may be provided. - At least one inert support media outlet may be associated with at least one of the plurality of stacked screens. The inert support media outlet may direct the separated inert support media to a location out of the enclosure. Here, the term “associated with” means positioned or otherwise oriented to permit inert support media to be transferred from at least one of the stacked screens to a location outside of the enclosure. “Outlet” refers to any opening, conduit, hole, port, valve or other construct for allowing inert support media to be removed from the screen. In some embodiments, the outlet may be formed on
housing 123 ofscreen assembly 110. One or more outlets may be used to achieve this purpose. In some embodiments, an air lock (not shown) may be associated with the inert support media outlet. The air lock may limit the amount of inert gas leaving the enclosure via the inert support media outlet. As used herein, “air lock” means any structure for restricting or completely preventing inert gas from leaving the enclosure. By way of example,FIG. 3A , illustrates an inertsupport media outlet 137 a disposed on an outer surface ofhousing 123.Outlet 137 a may be positioned to intersect with support media that has collected at a bottom ofscreen 111 a.Screen 111 a may be sloped towardoutlet 137 a such that inert support media at the intersection exits throughoutlet 137 a. Although oneoutlet 137 a is depicted, in general, any number of outlets may be provided. - A catalyst material outlet may be associated with at least another of the plurality of stacked screens. The catalyst material outlet may direct the separated oxidizable catalyst material to a location outside the enclosure. Here, the term “associated with” means positioned or otherwise oriented to permit oxidizable catalyst material to be transferred from another screen to a location outside of the enclosure. One or more outlets may be used to achieve this purpose. An air lock (not shown) may also be associated with the catalyst material outlet. The air lock may limit the amount of inert gas leaving the enclosure via the catalyst material outlet. By way of example, catalyst
material outlets housing 123.Outlets screen 111 b.Screen 111 b may be sloped towardoutlets outlet - To facilitate separation, at least one motor may be utilized for moving the stacked screens to cause the oxidizable catalyst material to separate from and migrate to a location beneath the inert support media. The motor may be electrical and operated remotely or directly, e.g., by switch. The term “motor,” as used herein, may refer to any electrical mechanism for inducing vibration of the screens. The intensity and/or duration of the vibration may be adjusted to reflect the load of the mixture. For example, stronger vibrations may be used to facilitate separation of large mixture loads. Alternatively, vibration intensity may remain constant, but for a longer duration to facilitate separation. The motor may be automated, such that the vibrations begin and/or end at a certain time or when the load on the screen reaches a predetermined threshold. By way of one non-limiting example,
FIG. 3A illustrates amotor 115 disposed on a sidewall of thehousing 123 ofscreen assembly 110. One having ordinary skill in the art will understand that the motor may be placed at any of a variety of locations with respect to the screen assembly, so long as its placement is sufficient to enable movement of the screens and thus separation of the catalyst and support media. - In accordance with some embodiments, inert
support media conveyor 114 may be secured toenclosure 108 viaoutlet 137 a such that it collects the separated inert support media. Although only one such conveyor is shown, it is to be understood that additional inert support media conveyors (and corresponding outlets) may be utilized to collect inert support media fromscreen assembly 110.Catalyst material conveyor 116 may be secured toenclosure 108 viaoutlet outlets FIG. 2 , to enable more rapid transport of the catalyst. Due to the smaller size of the catalyst material component,conveyor 116 may be secured to a lower section of the enclosure corresponding to a position of a bottom most screen; however, this configuration may be altered depending on the size of the components to be separated.Conveyors conveyor 114 to receptacle 134 for recycling or disposal, while separated catalyst material may be transported to anotherreceptacle 136 for reclamation, regeneration or landfill disposal as illustrated inFIG. 1 . - In some embodiments,
system 100 may include one or more sensors for detecting a reduction of oxygen in the enclosure and a regulator for at least periodically supplying additional inert gas to the enclosure to account for loss of the inert gas. As used herein, “sensor” means any device, module, machine, or system for directly or indirectly measuring, detecting, sensing, recording or storing oxygen concentration. The sensor may be located on an outer surface of the enclosure, within the enclosure, or at any other locale suitable for measuring, detecting, recording or storing the concentration of oxygen within the enclosure. Where the sensor is located within the enclosure, an observer may check a measurement of the sensor, via, e.g.,window 132. The regulator may be manually operated by an observer or automated to supply inert gas when the level of inert gas within the enclosure falls below a predetermined threshold. In some embodiments, the sensor measures, detects, records and/or stores an oxygen concentration within the enclosure and signals the regulator to begin or stop supplying inert gas depending on the measured oxygen concentration. In this way, the sensor and regulator work together to automatically monitor and manage the level of oxygen in the enclosure. By way of example,FIG. 1 depicts aregulator 126 disposed on an outer surface of the enclosure and asensor 128 on a top of surface of the enclosure. -
System 100 may also include a grinder for grinding the separated oxidizable catalyst material into a powder. In accordance with some embodiments, the grinder may be located in a region supplied with the inert gas, including, by way of example, the inside of the enclosure. The grinder may also be stationed at a remote location so long as the catalyst is supplied with inert gas to prevent the pulverized catalyst from oxidizing. The grinder may include an inlet for receiving catalyst from a catalyst conveyer. A ground catalyst conveyor may be associated with the grinder for transporting ground catalyst from the grinder for disposal. - By way of non-limiting example,
FIG. 2 illustrates acatalyst conveyor 120,grinder 122, andground catalyst conveyor 124.Catalyst conveyor 120 may be configured to transport catalyst fromscreen assembly 110 togrinder 122. In some embodiments,catalyst conveyor 120 may be connected to screenassembly 110 at, forexample outlet 137 d.Outlet 137 d may receive catalyst from a lower-most screen ofscreen assembly 110 or directly from an accumulation of catalyst particles at the bottom ofhousing 123. Ground catalyst may be transported viaground catalyst conveyor 124 to a bin orother receptacle 138 for disposal via, e.g., incineration. - It is to be understood that the system may use one or both
catalyst conveyors catalyst conveyor 116 while segregated catalyst particles of a second, smaller size maybe transported for disposal viacatalyst conveyor 120. Further still, if the mixture contains topping in addition to the catalyst and inert support media,catalyst conveyor 116 may be used to transport topping whilecatalyst conveyor 120 may be used to transport catalyst. - A method for disposing of a mixture of oxidizable catalyst material and inert support media will now be discussed with respect to the exemplary method illustrated in
FIG. 4 . - Beginning at
step 400, inert gas is introduced into an enclosure. As discussed above, the enclosure may contain a plurality of stacked screens, each stacked screen having openings that decrease in size from a top of the stack to a bottom of the stack. The inert gas may be nitrogen and enter theenclosure 108 viainert gas inlet 112. Prior to or during this time, one ormore flow bins 102 may be filled with a mixture of oxidizable catalyst material and inert support media.Enclosure 108 may be pressurized using the inert gas so as to displace oxygen within the enclosure. - At
step 402, the mixture is introduced to an uppermost one of the plurality of stacked screens. The mixture may be transported directly from one ormore flow bins 102 to the enclosure using, e.g., a gravity dump, or indirectly throughconveyor 104 and intoinlet 117 ofscreen assembly 110, where it drops ontouppermost screen 111 a. - At
step 404, the plurality of stacked screens are moved to cause the oxidizable catalyst material to separate from and migrate to a location beneath the inert support media.Motor 115 may be used to move the screens and thereby facilitate separation. The intensity and/or duration of the movement may be adjusted to reflect the load of the mixture; with longer durations and/or stronger movement being used to separate larger quantities of mixture. - Since the openings of adjacent screens, e.g.,
openings screens uppermost screen 111 a may collect at the bottom of the screen where the screen intersects withoutlet 137 a, while separated catalyst material at a bottom of the stack, for example onscreen 111 b, may collect where the screen intersectsoutlets - At
step 406, the separated inert support media may be conveyed to a location outside the enclosure for recycling or disposal as non-hazardous waste. Separated inert support media may collect at a bottom ofscreen 111 a, then directed throughoutlet 137 a, and into inertsupport media conveyor 114. Inertsupport media conveyor 114 may transport the separated inert support media toreceptacle 134, after which it may be disposed of or repurposed as desired. - At
step 408, separated oxidizable catalyst material may be conveyed to a location outside the enclosure for at least one of reclamation or thermal destruction. Separated oxidizable catalyst material may be directed to any one ofoutlets outlets 137 b and/or 137 c,catalyst conveyor 116 may transport the separated catalyst to areceptacle 136 for reclamation and/or thermal destruction. If separated catalyst material is routed throughoutlet 137 d, the catalyst may be ground as described in detail with respect toFIG. 5 . - A method of disposing of a mixture of oxidizable catalyst material and inert support media will now be discussed with respect to the exemplary method illustrated in
FIG. 5 . - Beginning at
step 500, inert gas is introduced into an enclosure. As discussed above, the enclosure may contain a plurality of stacked screens, each stacked screen having openings that decrease in size from a top of the stack to a bottom of the stack. The inert gas may be nitrogen and enter theenclosure 108 viainert gas inlet 112. Prior to or during this time, one ormore flow bins 102 may be filled with a mixture of oxidizable catalyst material and inert support media.Enclosure 108 may be pressurized using the inert gas so as to displace oxygen within the enclosure. - At
step 502, the mixture is introduced into the enclosure. As described above with respect to 402, the mixture may be introduced into the screen assembly viainlet 117 and onto an uppermost one of the plurality of stacked screens. The mixture may be transported directly from one ormore flow bins 102 to the enclosure using, e.g., a gravity dump, or indirectly throughconveyors 104 and 106. - At
step 504, the oxidizable catalyst material and the inert support media within the enclosure are separated. As withstep 404, the plurality of stacked screens are moved to cause the oxidizable catalyst material to separate from and migrate to a location beneath the inert support media.Motor 115 may be used to move the screens and thereby facilitate separation. The intensity and/or duration of the movement may be adjusted to reflect the load of the mixture; with longer durations and/or stronger movement being used to separate larger quantities of mixture. - Since the openings of adjacent screens, e.g.,
openings screens uppermost screen 111 a may collect at the bottom of the screen where the screen intersects withoutlet 137 a while separated catalyst material at a bottom of the stack, for example onscreen 111 b, may collect where the screen intersectsoutlets - At
step 506, an inert gas environment is maintained around the oxidizable catalyst material during separating. A sensor for detecting a reduction of oxygen in the enclosure and a regulator for at least periodically supplying additional inert gas to the enclosure, may be used to maintain the inert gas environment. The regulator may be manually operated by an observer or automated to supply inert gas when the level of inert gas within the enclosure falls below a predetermined threshold. The sensor may measure an oxygen concentration within the enclosure and signal the regulator to begin or stop supplying inert gas depending on the measured oxygen concentration. In this way, the sensor and regulator work together to automatically monitor and manage the level of oxygen in the enclosure. - At
step 508, the separated inert support media is exported from the enclosure. As withstep 406, the separated inert support media may be conveyed to a location outside the enclosure for recycling or disposal as non-hazardous waste. Separated inert support media may collect at a bottom ofscreen 111 a, where it is then directed throughoutlet 137 a, and into inertsupport media conveyor 114. Inertsupport media conveyor 114 may transport the separated inert support media toreceptacle 134, after which it may be disposed of or repurposed as desired. - At step 510, the separated oxidizable catalyst material is ground into a powder for disposal as hazardous waste via incineration. Separated catalyst material is routed through
outlet 137 d, which is connected tocatalyst conveyor 120.Catalyst conveyor 120 transports the separated catalyst to agrinder 122. Once ground, the ground catalyst may be transported viaground catalyst conveyor 124 to areceptacle 138 for reclamation and/or thermal destruction. The receptacle may be secured to a vehicle for immediate transportation as illustrated inFIG. 1 or loaded onto a vehicle at a later time. - A method of disposing of a mixture of oxidizable catalyst material and inert support media will now be discussed with respect to the exemplary method illustrated in
FIG. 6 . - Beginning at
step 600, inert gas is introduced into an enclosure. As discussed above, the enclosure may contain a plurality of stacked screens, each stacked screen having openings that decrease in size from a top of the stack to a bottom of the stack. The inert gas may be nitrogen and enter theenclosure 108 viainert gas inlet 112. Prior to or during this time, one ormore flow bins 102 may be filled with a mixture of oxidizable catalyst material and inert support media.Enclosure 108 may be pressurized using the inert gas so as to displace oxygen within the enclosure. - At
step 602, a mixture of oxidizable catalyst material, grading material and inert support media are introduced into the enclosure. The mixture may be introduced into the screen assembly viainlet 117 and onto an uppermost one of the plurality of stacked screens. The mixture may be transported directly from one ormore flow bins 102 to the enclosure using, e.g., a gravity dump, or indirectly throughconveyor 104. - At
step 604, the oxidizable catalyst material, grading material and the inert support media within the enclosure are separated. As discussed above with respect toFIGS. 4 and 5 , the plurality of stacked screens are moved, using, e.g.,motor 115, to facilitate separation. The intensity and/or duration of the movement may be adjusted to reflect the load of the mixture; with longer durations and/or stronger movement being used to separate larger quantities of mixture. - Since the openings of adjacent screens, e.g.,
openings screens uppermost screen 111 a may collect at the bottom of the screen where the screen intersects withoutlet 137 a, while separated catalyst and grading material at a bottom of the stack, for example onscreen 111 b, may collect where the screen intersectsoutlets - At
step 606, an inert gas environment is maintained around the oxidizable catalyst material during separating. A sensor for detecting a reduction of oxygen in the enclosure and a regulator for at least periodically supplying additional inert gas to the enclosure, may be used to maintain the inert gas environment. The regulator may be manually operated by an observer or automated to supply inert gas when the level of inert gas within the enclosure falls below a predetermined threshold. The sensor may measure an oxygen concentration within the enclosure and signal the regulator to begin or stop supplying inert gas depending on the measured oxygen concentration. In this way, the sensor and regulator work together to automatically monitor and manage the level of oxygen in the enclosure. - At
step 608, the separated inert support media is exported from the enclosure. As withstep 406, the separated inert support media may be conveyed to a location outside the enclosure for disposal as non-hazardous waste. Separated inert support media may collect at a bottom ofscreen 111 a, where it is then directed throughoutlet 137 a, and into inertsupport media conveyor 114. Inertsupport media conveyor 114 may transport the separated inert support media toreceptacle 134, after which it may be disposed of or repurposed as desired. - At
step 610, grading material is conveyed to a location outside the enclosure. The separated material may be directed tooutlet 137 b and/or 137 c and transported outside ofenclosure 108 viaconveyor 116 and intoreceptacle 136 for collection. - At
step 612, separated oxidizable catalyst material is conveyed to a location outside the enclosure. Separated oxidizable catalyst material may be directed to any one ofoutlets outlets 137 b and/or 137 c,catalyst conveyor 116 may transport the separated catalyst toreceptacle 136. In some cases, the catalyst may be comingled with the grading material disposed of atstep 610. If the catalyst material is routed throughoutlet 137 d (for example, after passing through the second screen and onto a third screen or a bottom of the screening assembly as discussed above in step 604), the separated oxidizable catalyst material may ground into a powder for disposal as hazardous waste via incineration.Catalyst conveyor 120 transports the separated catalyst to agrinder 122. Once ground, the ground catalyst may be transported viaground catalyst conveyor 124 to areceptacle 138 for reclamation, regeneration and/or landfill disposal. The receptacle may be secured to a vehicle for immediate transportation as illustrated inFIG. 1 or loaded onto a vehicle at a later time. - Disclosed embodiments may include any one of the following bullet-pointed features alone or in combination with one or more other bullet-pointed features, whether implemented in connection with a device, a system, or a method:
-
- a system for segregating a mixture of oxidizable catalyst material and inert support media
- an enclosure configured to contain inert gas
- a plurality of stacked screens within the enclosure, the stacked screens having openings that decrease in size from a top of the stack to a bottom of the stack
- a mixture inlet in the enclosure positioned to enable delivery of the mixture to an uppermost stacked screen
- at least one inert support media outlet associated with at least one of the plurality of stacked screens, wherein the at least one inert support media outlet directs separated inert support media to a location out of the enclosure
- a catalyst material outlet associated with at least another of the plurality of stacked screens, wherein the catalyst material outlet directs separated oxidizable catalyst material to a location outside the enclosure
- at least one motor for moving the stacked screens to cause the oxidizable catalyst material in the mixture to separate from and migrate to a location beneath the inert support media
- an inert gas inlet associated with the enclosure for permitting the inert gas to enter the enclosure to displace oxygen within the enclosure and thereby limit oxidation of the oxidizable catalyst material while the at least one motor moves the plurality of stacked screens
- wherein the enclosure is configured for pressurization of the inert gas
- wherein the inert gas inlet is located in a lower portion of the enclosure to enable the inert gas to flow over the oxidizable catalyst material and exit the enclosure through a top portion of the enclosure
- a sensor for detecting a reduction of oxygen in the enclosure
- a mixture conveyor for conveying the mixture to the mixture inlet, wherein the mixture conveyor is in flow communication with the enclosure and is enclosed to contain the inert gas
- at least one flow bin associated with an end of the mixture conveyor for supplying the mixture to the mixture conveyor, wherein the mixture conveyor is sealingly engaged with the flow bin and the enclosure to contain the inert gas
- wherein the mixture conveyor includes a screw auger
- wherein the mixture conveyor includes a controllable inlet for permitting selective passage of the mixture while limiting loss of the inert gas
- a regulator for at least periodically supplying additional inert gas to the enclosure to account for loss of the inert gas
- an air lock associated with the inert support media outlet for limiting the inert gas from leaving the enclosure via the inert support media outlet
- an air lock associated with the catalyst material outlet for limiting the inert gas from leaving the enclosure via the catalyst material outlet
- a pressurized inert gas tank flow-connected to the enclosure
- wherein the enclosure and plurality of stacked screens are configured as a portable unit for movement between industrial sites
- a grinder for grinding the separated oxidizable catalyst material into a powder
- wherein the grinder is located in a region supplied with the inert gas
- wherein the grinder is contained within the enclosure and the mixture inlet is a hazardous waste inlet
- an observation window in an outer wall of the enclosure, and an illuminator within the enclosure to enable external observation of the mixture segregation
- wherein the inert gas tank contains nitrogen
- a method for disposing of a mixture of oxidizable catalyst material and inert support media
- introducing inert gas into an enclosure, wherein the enclosure contains a plurality of stacked screens, the stacked screens having openings that decrease in size from a top of the stack to a bottom of the stack
- introducing the mixture to an uppermost one of the plurality of stacked screens
- moving the plurality of stacked screens to cause the oxidizable catalyst material to separate from and migrate to a location beneath the inert support media
- conveying the separated inert support media to a location outside the enclosure for disposal as non-hazardous waste
- conveying the separated oxidizable catalyst material to a location outside the enclosure for at least one of reclamation or thermal destruction
- wherein the thermal destruction includes disposal via incineration
- wherein the inert gas is nitrogen
- wherein introducing the mixture includes conveying the mixture in a closed conveyor containing the inert gas
- wherein conveying the separated oxidizable catalyst material to a location outside the enclosure includes conveying the separated oxidizable catalyst material in a closed conveyor containing the inert gas
- incinerating the separated oxidizable catalyst material in a cement kiln
- storing the separated oxidizable catalyst material for reuse in an industrial process
- storing the separated inert media for reuse in an industrial process
- wherein conveying the separated oxidizable catalyst material and inert support media to a location outside the enclosure includes using a screw auger
- sensing oxygen presence within the enclosure
- wherein the enclosure maintains an inert gas environment around the oxidizable catalyst
- a method of disposing of a mixture of oxidizable catalyst material and inert support media
- introducing inert gas into an enclosure
- introducing the mixture into the enclosure
- separating the oxidizable catalyst material and the inert support media within the enclosure
- maintaining an inert gas environment around the oxidizable catalyst material during separating
- exporting the separated inert support media from the enclosure
- grinding the separated oxidizable catalyst material into a powder for disposal as hazardous waste via incineration
- wherein the grinding occurs in an inert gas environment
- wherein introducing the mixture into the enclosure includes removing the mixture from a refinement container and transferring the mixture to the enclosure via a conveyor
- wherein the inert gas is nitrogen
- wherein the separated oxidizable catalyst material is ground into a powder for suspension in a liquid fuel for a cement kiln
- wherein the enclosure is movable and wherein the method further includes moving the enclosure to an industrial site
- wherein the mixture further comprises grading material; and separating the grading material from the inert support media
- exporting the grading material from the enclosure
- wherein the grading material is exported with the oxidizable catalyst material
- wherein the grading material is exported separately from the oxidizable catalyst material
- Although
system 100 is described as being used to separate refinery waste (e.g., inert material from catalyst) in a mixture, as explained previously, this is only exemplary. In general, the systems and methods of the current disclosure may be used to separate or segregate the constituent components of a mixture in any application. While illustrative embodiments have been described herein, the scope of any and all embodiments having equivalent elements, modifications, omissions, combinations (e.g., of aspects across various embodiments), adaptations and/or alterations as would be appreciated by those skilled in the art based on the present disclosure. The limitations in the claims are to be interpreted broadly based on the language employed in the claims and not limited to examples described in the present specification or during the prosecution of the application. The examples are to be construed as non-exclusive. Furthermore, the steps of the disclosed methods may be modified in any manner, including by reordering steps and/or inserting or deleting steps. It is intended, therefore, that the specification and examples be considered as illustrative only, with a true scope and spirit being indicated by the following claims and their full scope of equivalents.
Claims (11)
Priority Applications (2)
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US17/012,457 US20220072528A1 (en) | 2020-09-04 | 2020-09-04 | Systems and methods for segregating into dual waste streams oxidizable catalyst material from inert support media |
US18/191,775 US20230241599A1 (en) | 2020-09-04 | 2023-03-28 | Systems and methods for segregating into dual waste streams oxidizable catalyst material from inert support media |
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US17/012,457 US20220072528A1 (en) | 2020-09-04 | 2020-09-04 | Systems and methods for segregating into dual waste streams oxidizable catalyst material from inert support media |
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US18/191,775 Continuation US20230241599A1 (en) | 2020-09-04 | 2023-03-28 | Systems and methods for segregating into dual waste streams oxidizable catalyst material from inert support media |
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US17/012,457 Abandoned US20220072528A1 (en) | 2020-09-04 | 2020-09-04 | Systems and methods for segregating into dual waste streams oxidizable catalyst material from inert support media |
US18/191,775 Pending US20230241599A1 (en) | 2020-09-04 | 2023-03-28 | Systems and methods for segregating into dual waste streams oxidizable catalyst material from inert support media |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3662886A (en) * | 1970-02-05 | 1972-05-16 | Catalyst Services Inc | Handling apparatus for particulate dry product |
US3948764A (en) * | 1974-09-23 | 1976-04-06 | Browning-Ferris Industries, Inc. | Catalyst screening unit |
US20180221806A1 (en) * | 2016-01-27 | 2018-08-09 | Yi Fang | Novel air purification methodology and apparatus |
US11111743B2 (en) * | 2016-03-03 | 2021-09-07 | Recover Energy Services Inc. | Gas tight shale shaker for enhanced drilling fluid recovery and drilled solids washing |
CN214745777U (en) * | 2021-03-30 | 2021-11-16 | 北京金隅北水环保科技有限公司 | Municipal waste resource incineration treatment device |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11767975B2 (en) * | 2020-09-04 | 2023-09-26 | The Maitland Company, Llc | Systems and methods for segregating and grinding oxidizable catalyst material |
US20220072527A1 (en) * | 2020-09-04 | 2022-03-10 | The Maitland Company, Llc | On-site systems and methods for treating spent oxidizable catalyst in inert gas environments |
-
2020
- 2020-09-04 US US17/012,457 patent/US20220072528A1/en not_active Abandoned
-
2023
- 2023-03-28 US US18/191,775 patent/US20230241599A1/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3662886A (en) * | 1970-02-05 | 1972-05-16 | Catalyst Services Inc | Handling apparatus for particulate dry product |
US3948764A (en) * | 1974-09-23 | 1976-04-06 | Browning-Ferris Industries, Inc. | Catalyst screening unit |
US20180221806A1 (en) * | 2016-01-27 | 2018-08-09 | Yi Fang | Novel air purification methodology and apparatus |
US11111743B2 (en) * | 2016-03-03 | 2021-09-07 | Recover Energy Services Inc. | Gas tight shale shaker for enhanced drilling fluid recovery and drilled solids washing |
CN214745777U (en) * | 2021-03-30 | 2021-11-16 | 北京金隅北水环保科技有限公司 | Municipal waste resource incineration treatment device |
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