US20220010399A1 - High-strength steel with excellent durability and method for manufacturing same - Google Patents

High-strength steel with excellent durability and method for manufacturing same Download PDF

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US20220010399A1
US20220010399A1 US17/294,250 US201917294250A US2022010399A1 US 20220010399 A1 US20220010399 A1 US 20220010399A1 US 201917294250 A US201917294250 A US 201917294250A US 2022010399 A1 US2022010399 A1 US 2022010399A1
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cooling
hot
phase
temperature
steel
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Sung-il Kim
Hyun-taek NA
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Posco Holdings Inc
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Posco Co Ltd
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    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/02Hardening articles or materials formed by forging or rolling, with no further heating beyond that required for the formation
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    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
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    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • C21D1/19Hardening; Quenching with or without subsequent tempering by interrupted quenching
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    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • C21D1/25Hardening, combined with annealing between 300 degrees Celsius and 600 degrees Celsius, i.e. heat refining ("Vergüten")
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    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/002Heat treatment of ferrous alloys containing Cr
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    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0205Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
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    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
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    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0231Warm rolling
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    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0263Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
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    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C18/00Alloys based on zinc
    • C22C18/04Alloys based on zinc with aluminium as the next major constituent
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
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    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
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    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
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    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/26Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/28Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/38Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • C23C2/022Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating
    • C23C2/0224Two or more thermal pretreatments
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    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas
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    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • C23C2/04Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
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    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
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    • C23C2/36Elongated material
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    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/002Bainite
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    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/005Ferrite
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    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/008Martensite

Definitions

  • members of chassis parts and wheel discs of commercial vehicles have used high-strength steel plates having a thickness of 5 mm or more and a yield strength of 450 to 600 MPa in order to secure high rigidity due to characteristics of the vehicles.
  • high-strength steel materials having a tensile strength of 650 MPa or more are currently used therein.
  • a high-strength steel material having excellent durability includes, by weight, carbon (C): 0.05 to 0.15%, silicon (Si): 0.01 to 1.0%, manganese (Mn): 1.0 to 2.3%, aluminum (Al): 0.01 to 0.1%, chromium (Cr): 0.005 to 1.0%, phosphorus (P): 0.001 to 0.05%, sulfur (S): 0.001 to 0.01%, nitrogen (N): 0.001 to 0.01%, niobium (Nb): 0.005 to 0.07%, titanium (Ti): 0.005 to 0.11%, a balance of Fe, and other inevitable impurities,
  • a sum of a fraction of a ferrite phase and a fraction of a bainite phase in a microstructure is 90% or more, and a fraction of a crystal grain, in which an aspect ratio (a ratio of short side/long side) of the crystal grain in a central portion (a portion ranging from a t/4 point to a t/2 point in a thickness direction) is 0.3 or less, is less than 50%, and a length of a grain boundary observed in a unit area (1 mm 2 ) in the central portion is 700 mm or more.
  • a method of manufacturing a high-strength steel material having excellent durability includes heating a steel slab satisfying the above-described alloy composition in a temperature within a range of 1200 to 1350° C.; hot-rolling the heated steel slab to prepare a hot-rolled steel sheet; cooling the hot-rolled steel sheet to a temperature within a range of 400 to 500° C. and then coiling (CT); and air-cooling to a temperature within a range of room temperature to 200° C. after the coiling,
  • CT coiling
  • Mn may be included in an amount of 1.0 to 2.3%, and, more advantageously, may be included in an amount of 1.1 to 2.0%.
  • Aluminum (Al) may be an element mainly added for deoxidation. When an amount thereof is less than 0.01%, an effect of the addition may not be sufficiently obtained. When an amount thereof exceeds 0.1%, it may be easy to cause corner cracks in a slab during a continuous casting process by combining with nitrogen (N) in steel to form AlN, and there may be a risk of generating defects due to formation of inclusions.
  • Phosphorus (P) may be an element simultaneously promoting solid solution strengthening and ferrite transformation.
  • manufacturing costs may be excessive, which may be economically disadvantageous, and it may be difficult to secure a target level of strength.
  • an amount of P exceeds 0.05% brittleness may occur due to grain boundary segregation, and fine cracks tend to occur during forming, to greatly deteriorate shear formability and durability.
  • N may be included in an amount of 0.001 to 0.01%.
  • the remainder of the present disclosure may be iron (Fe).
  • Fe iron
  • the impurities may not be excluded. All of these impurities are not specifically mentioned in this specification, as they are known to anyone of ordinary skill in the manufacturing process.
  • a temperature of the heating is less than 1200° C.
  • a precipitate may not be sufficiently re-dissolved, to decrease formation of a precipitate in a process after hot-rolling, and there may be a problem that coarse TiN remains.
  • a temperature of the heating exceeds 1350° C., strength may decrease due to abnormal grain growth of austenite grains, which is not allowable.
  • FDT denotes a temperature at an finishing hot-rolling (a hot-rolling end temperature)
  • CT denotes a coiling temperature
  • AR0.3 denotes a ratio (an area fraction) of crystal grains having an aspect ratio of 0.3 or less, and shows results obtained by observing at 1000 magnification.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Heat Treatment Of Steel (AREA)
  • Heat Treatment Of Sheet Steel (AREA)
US17/294,250 2018-11-26 2019-11-26 High-strength steel with excellent durability and method for manufacturing same Pending US20220010399A1 (en)

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KR1020180147124A KR102131527B1 (ko) 2018-11-26 2018-11-26 내구성이 우수한 고강도 강재 및 이의 제조방법
KR10-2018-0147124 2018-11-26
PCT/KR2019/016299 WO2020111702A1 (ko) 2018-11-26 2019-11-26 내구성이 우수한 고강도 강재 및 이의 제조방법

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EP (1) EP3889298A4 (de)
JP (1) JP7244723B2 (de)
KR (1) KR102131527B1 (de)
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WO (1) WO2020111702A1 (de)

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KR102397583B1 (ko) 2020-09-25 2022-05-13 주식회사 포스코 연신율이 우수한 고강도 후물 열연강판 및 그 제조방법
KR102409896B1 (ko) * 2020-10-23 2022-06-20 주식회사 포스코 성형성이 우수한 고강도 후물 강판 및 그 제조방법
KR102403648B1 (ko) * 2020-11-17 2022-05-30 주식회사 포스코 고강도 열연강판, 열연 도금강판 및 이들의 제조방법
CN113084453B (zh) * 2021-03-18 2022-04-29 湖南三一路面机械有限公司 耐磨钢轮、钢轮制造方法、钢轮焊接方法和压路机
KR20230072050A (ko) 2021-11-17 2023-05-24 주식회사 포스코 냉간 성형 후 내충격성이 우수한 고항복비형 고강도강 및 그 제조방법
KR20240098898A (ko) * 2022-12-21 2024-06-28 주식회사 포스코 열연강판 및 그 제조방법

Citations (2)

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US20140161659A1 (en) * 2011-08-17 2014-06-12 Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) High-strength hot-rolled steel sheet
WO2018026014A1 (ja) * 2016-08-05 2018-02-08 新日鐵住金株式会社 鋼板及びめっき鋼板

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KR20200062422A (ko) 2020-06-04
EP3889298A1 (de) 2021-10-06
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