US20200393196A1 - Device and method for processing boil-off gas in liquefied gas regasification system - Google Patents

Device and method for processing boil-off gas in liquefied gas regasification system Download PDF

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Publication number
US20200393196A1
US20200393196A1 US16/957,015 US201816957015A US2020393196A1 US 20200393196 A1 US20200393196 A1 US 20200393196A1 US 201816957015 A US201816957015 A US 201816957015A US 2020393196 A1 US2020393196 A1 US 2020393196A1
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Prior art keywords
gas
boil
pressure
low
heat exchanger
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US16/957,015
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English (en)
Inventor
Du Hyeon CHO
Su Kyung AN
Young Hyun Kim
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Hanwha Ocean Co Ltd
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Daewoo Shipbuilding and Marine Engineering Co Ltd
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Assigned to DAEWOO SHIPBUILDING & MARINE ENGINEERING CO., LTD. reassignment DAEWOO SHIPBUILDING & MARINE ENGINEERING CO., LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: KIM, YOUNG HYUN, AN, SU KYUNG, CHO, DU HYEON
Publication of US20200393196A1 publication Critical patent/US20200393196A1/en
Assigned to HANWHA OCEAN CO., LTD. reassignment HANWHA OCEAN CO., LTD. CHANGE OF NAME (SEE DOCUMENT FOR DETAILS). Assignors: DAEWOO SHIPBUILDING & MARINE ENGINEERING CO., LTD.
Abandoned legal-status Critical Current

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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0022—Hydrocarbons, e.g. natural gas
    • F25J1/0025—Boil-off gases "BOG" from storages
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63B—SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING 
    • B63B25/00—Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby
    • B63B25/02—Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby for bulk goods
    • B63B25/08—Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby for bulk goods fluid
    • B63B25/12—Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby for bulk goods fluid closed
    • B63B25/16—Load-accommodating arrangements, e.g. stowing, trimming; Vessels characterised thereby for bulk goods fluid closed heat-insulated
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C6/00—Methods and apparatus for filling vessels not under pressure with liquefied or solidified gases
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C9/00—Methods or apparatus for discharging liquefied or solidified gases from vessels not under pressure
    • F17C9/02—Methods or apparatus for discharging liquefied or solidified gases from vessels not under pressure with change of state, e.g. vaporisation
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
    • F25J1/0035—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work
    • F25J1/0037—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work of a return stream
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
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    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
    • F25J1/0045—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by vaporising a liquid return stream
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
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    • F25J1/0202—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using only internal refrigeration means, i.e. without external refrigeration in a quasi-closed internal refrigeration loop
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0228—Coupling of the liquefaction unit to other units or processes, so-called integrated processes
    • F25J1/0229—Integration with a unit for using hydrocarbons, e.g. consuming hydrocarbons as feed stock
    • F25J1/023—Integration with a unit for using hydrocarbons, e.g. consuming hydrocarbons as feed stock for the combustion as fuels, i.e. integration with the fuel gas system
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0257—Construction and layout of liquefaction equipments, e.g. valves, machines
    • F25J1/0275—Construction and layout of liquefaction equipments, e.g. valves, machines adapted for special use of the liquefaction unit, e.g. portable or transportable devices
    • F25J1/0277—Offshore use, e.g. during shipping
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
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    • F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0279—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc.
    • F25J1/0285—Combination of different types of drivers mechanically coupled to the same refrigerant compressor, possibly split on multiple compressor casings
    • F25J1/0288—Combination of different types of drivers mechanically coupled to the same refrigerant compressor, possibly split on multiple compressor casings using work extraction by mechanical coupling of compression and expansion of the refrigerant, so-called companders
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    • F17C2223/0161—Liquefied gas, e.g. LPG, GPL cryogenic, e.g. LNG, GNL, PLNG
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    • F17C2223/03—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the pressure level
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    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
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    • F17C2225/0107—Single phase
    • F17C2225/0123—Single phase gaseous, e.g. CNG, GNC
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    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
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    • F17C2225/036—Very high pressure, i.e. above 80 bars
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    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
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    • F17C2265/00—Effects achieved by gas storage or gas handling
    • F17C2265/05—Regasification
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    • F17C2270/00—Applications
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    • F17C7/00—Methods or apparatus for discharging liquefied, solidified, or compressed gases from pressure vessels, not covered by another subclass
    • F17C7/02—Discharging liquefied gases
    • F17C7/04—Discharging liquefied gases with change of state, e.g. vaporisation
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
    • F25J2230/08—Cold compressor, i.e. suction of the gas at cryogenic temperature and generally without afterstage-cooler
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
    • F25J2230/30—Compression of the feed stream

Definitions

  • the present invention relates to a device and method for processing boil-off gas in a liquefied gas regasification system, and, more particularly, to a device and method for processing boil-off gas in a liquefied gas regasification system, which can allow reliquefaction and recovery of boil-off gas even when there is little or no regasified gas to be delivered in the liquefied gas regasification system.
  • natural gas is transported in a liquid state to a distant destination by an LNG carrier after being transformed into liquefied natural gas (LNG) through liquefaction at extremely low temperatures at a production site.
  • LNG is obtained by cooling natural gas to a cryogenic temperature of about ⁇ 163° C. and has a volume of about 1/600 that of natural gas in a gaseous state.
  • LNG is suited to long distance transport by sea.
  • LNG transported by an LNG carrier may be regasified on the land or at sea before being supplied to onshore gas consumers.
  • ships adapted to regasify LNG received from an LNG carrier at sea and supply the regasified LNG to gas consumers include LNG regasification ships and floating offshore structures (hereinafter collectively referred to as “LNG regasification ship”), such as an LNG regasification vessel (LNG RV), which is an LNG carrier provided with an LNG regasification system, and a floating storage and regasification unit (FSRU).
  • LNG regasification ship such as an LNG regasification vessel (LNG RV), which is an LNG carrier provided with an LNG regasification system, and a floating storage and regasification unit (FSRU).
  • LNG RV LNG regasification vessel
  • FSRU floating storage and regasification unit
  • a regasification facility provided to an LNG regasification ship includes: a high-pressure pump compressing low-pressure LNG stored in an LNG storage tank to a pressure required for a gas consumer; and a vaporizer (high-pressure vaporizer) vaporizing the compressed LNG by heating to a temperature required for a gas pipe network (regas network) using a heating medium, such as seawater. Regasified gas obtained through the high-pressure pump and the vaporizer is delivered to the gas consumer via the gas pipe network.
  • An LNG storage tank provided to an LNG regasification ship stores LNG in a liquid state at an extremely low temperature of about ⁇ 163° C. Accordingly, it is preferable that the LNG storage tank be insulated such that LNG can be maintained in a liquid state. However, even when the LNG storage tank is insulated, LNG can naturally vaporize due to intrusion of external heat and the like. When boil-off gas (BOG) continues to be generated due to natural vaporization of LNG, the pressure of the LNG storage tank rises.
  • BOG boil-off gas
  • the boil-off gas discharged from the LNG storage tank is recondensed using cold heat of LNG and is then supplied to a high-pressure pump and a vaporizer along with LNG to be regasified before being supplied to a gas consumer.
  • the amount of boil-off gas which can be recondensed is proportional to the amount of LNG to be regasified. That is, the boil-off gas can be treated by recondensation only when the amount of LNG to be regasified is sufficient to allow recondensation of the boil-off gas discharged from the LNG storage tank.
  • uncondensed boil-off gas not receiving sufficient cold heat from LNG due to reduction in amount of LNG to be regasified or boil-off gas generated during interruption of regasification of LNG can be returned to the LNG storage tank.
  • boil-off gas in excess of the capacity of the LNG storage tank to receive boil-off gas, determined by the allowable pressure level of the LNG tank can be supplied as a fuel to an engine.
  • boil-off gas in excess of both the capacity of the LNG storage tank and fuel requirements of the engine needs to be sent to a gas combustion unit (GCU) to be combusted or needs to be vented to the air.
  • GCU gas combustion unit
  • boil-off gas mainly contains methane that has the highest boiling point among components constituting LNG, burning or venting the boil-off gas is a great economic loss.
  • Embodiments of the present invention have been conceived to solve such a problem in the art and it is an aspect of the present invention to provide a device and method for processing boil-off gas in a liquefied gas regasification system, which allows reliquefaction and recovery of boil-off gas without waste even when the amount of LNG to be regasified is not sufficient to allow recondensation of boil-off gas.
  • a device for processing boil-off gas in a liquefied gas regasification system including: a fuel compressor compressing boil-off gas to a pressure required for a fuel demand site; a high-pressure compressor disposed in series with the fuel compressor downstream of the fuel compressor and compressing the low-pressure boil-off gas compressed by the fuel compressor to a pressure required for a regasified gas demand site; a low-temperature heat exchanger cooling the high-pressure boil-off gas compressed by the high-pressure compressor; a decompression unit decompressing the high-pressure boil-off gas cooled by the low-temperature heat exchanger to an internal pressure of a liquefied gas storage tank; and a liquefied gas drum separating flash gas generated during decompression by the decompression unit, wherein reliquefied boil-off gas separated by the liquefied gas drum is returned to the liquefied gas storage tank.
  • the device may further include: an expander expanding and cooling some of the high-pressure boil-off gas to be supplied to the low-temperature heat exchanger, wherein the low-temperature heat exchanger may cool the high-pressure boil-off gas through heat exchange with the boil-off gas expanded and cooled by the expander.
  • the device may further include: a high-temperature heat exchanger precooling the high-pressure boil-off gas to be supplied to the low-temperature heat exchanger to an inlet temperature of the expander, wherein some of the high-pressure boil-off gas to be supplied to the low-temperature heat exchanger from the high-temperature heat exchanger may be sent to the expander.
  • the high-temperature heat exchanger may cool the high-pressure boil-off gas to be supplied to the low-temperature heat exchanger and the expander through heat exchange with the expanded boil-off gas heated through heat exchange in the low-temperature heat exchanger and discharged from the low-temperature heat exchanger.
  • the device may further include: a gas compressor compressing the expanded boil-off gas subjected to heat exchange in the low-temperature heat exchanger and discharged from the low-temperature heat exchanger to a pressure of a flow of the boil-off gas compressed by the fuel compressor, wherein the boil-off gas compressed by the gas compressor may be joined with the flow of the boil-off gas compressed by the fuel compressor.
  • the gas compressor may be connected to the expander via a common shaft.
  • the device may further include: a gas cooler regulating a temperature of the boil-off gas compressed and heated by the gas compressor.
  • the flash gas separated by the liquefied gas drum may be joined with a flow of the expanded boil-off gas to be supplied to the low-temperature heat exchanger.
  • a method for processing boil-off gas in a liquefied gas regasification system including: compressing boil-off gas to a low pressure required for a fuel demand site; compressing the low-pressure boil-off gas to a high pressure required for a regasified gas demand site; cooling the high-pressure boil-off gas; decompressing the cooled high-pressure boil-off gas to an internal pressure of a liquefied gas storage tank; and separating flash gas generated during decompression of the cooled high-pressure boil-off gas and returning reliquefied boil-off gas to the liquefied gas storage tank.
  • Cooling the high-pressure boil-off gas may include: expanding and cooling some of the high-pressure boil-off gas before cooling the high-pressure boil-off gas; and liquefying at least part of the high-pressure boil-off gas through heat exchange between the expanded and cooled boil-off gas and the high-pressure boil-off gas.
  • the method may further include: precooling the high-pressure boil-off gas through heat exchange with the expanded boil-off gas heated while cooling the high-pressure boil-off gas, before performing heat exchange between the expanded and cooled boil-off gas and the high-pressure boil-off gas.
  • Precooling the high-pressure boil-off gas may include: cooling the high-pressure boil-off gas to an inlet temperature of an expander expanding the high-pressure boil-off gas.
  • the expanded boil-off gas heated while cooling the high-pressure boil-off gas may be compressed to a pressure of a flow of boil-off gas to be compressed by a fuel compressor before being joined with the flow of the boil-off gas.
  • Expansion work in expanding the high-pressure boil-off gas may be recovered as compression work in compressing the expanded boil-off gas.
  • the separated flash gas may be joined with a flow of the expanded boil-off gas exchanging heat with the high-pressure boil-off gas.
  • boil-off gas can be recondensed and recovered without waste even when the amount of liquefied gas to be regasified or fuel consumption is not sufficient to recondense boil-off gas, thereby allowing efficient recovery of boil-off gas without waste.
  • the internal pressure of a liquefied gas storage tank can be kept constant within a safe operating range while reducing the amount of discarded LNG.
  • FIG. 1 is a schematic diagram of a device for processing boil-off gas in a liquefied gas regasification system according to one embodiment of the present invention.
  • liquefied gas may refer to a gas that can be transported in liquid form by being liquefied at low temperature, for example, liquefied petrochemical gas such as liquefied natural gas (LNG), liquefied ethane gas (LEG), liquefied petroleum gas (LPG), liquefied ethylene gas, and liquefied propylene gas.
  • liquefied gas may also refer to a gas in a liquid state, such as liquefied carbon dioxide, liquefied hydrogen, and liquefied ammonia.
  • LNG which is a typical liquefied gas, as an example.
  • LNG mainly contains methane and further contains ethane, propane, butane, and the like
  • the composition of LNG may vary depending on the place of production.
  • an LNG regasification ship may include any ship that is provided with an LNG regasification facility to regasify LNG and supply the regasified LNG to gas consumers, including self-propelled ships, such as LNG regasification vessels (RVs), and floating offshore structures, such as floating storage regasification units (FSRUs).
  • the LNG regasification ship may include floating storage power plants (FSPPs), which produce electricity using regasified gas as fuel and supply the produced electricity to onshore power consumers while regasifying LNG and supplyng the regasified LNG to gas consumers.
  • FSPPs floating storage power plants
  • a device and method for processing boil-off gas in a liquefied gas regasification system will be described as applied to a ship such as an LNG FSRU provided with a regasification system or an LNG FSPP provided with both a regasification system and a power generation system.
  • a ship regasifies LNG at sea to supply the regasified LNG to onshore gas consumers via a pipe network (regas network) and also produces electricity using LNG as fuel to supply the produced electricity to onshore power consumers.
  • pipe network regas network
  • FIG. 1 is a schematic diagram of an LNG regasification system according to one embodiment of the present invention. Now, a device and method for processing boil-off gas in the LNG regasification system according to one embodiment of the present invention will be described with reference to FIG. 1 .
  • the device for processing boil-off gas in the LNG regasification system includes: a fuel compressor 600 compressing boil-off gas to a pressure required for a fuel demand site; a high-pressure compressor 700 compressing the boil-off gas to a pressure required for a regasified gas demand site; an expander 420 expanding the high-pressure boil-off gas compressed by the high-pressure compressor 700 ; and a low-temperature heat exchanger 200 liquefying the high-pressure boil-off gas using cold heat of the boil-off gas cooled by being expanded by the expander 420 .
  • an LNG FSRU or an LNG FSPP includes an LNG regasification system.
  • the LNG regasification system may include: an LNG storage tank (not shown); a high-pressure pump (not shown) compressing LNG to be regasified to a pressure required for the regasified gas demand site; and a vaporizer (not shown) vaporizing the compressed LNG and supplying the vaporized LNG to the regasified gas demand site.
  • LNG stored in the LNG storage tank is compressed to a pressure required for the regasified gas demand site by the high-pressure pump, is vaporized by the vaporizer, and is supplied to the regasified gas demand site.
  • the LNG storage tank stores LNG at an extremely low temperature of about ⁇ 163° C. and a pressure of about 0.5 bar to 1.1 bar. That is, the LNG storage tank is preferably insulated such that LNG can be stored in a constant liquid state.
  • the LNG storage tank may be designed to withstand pressure rise caused by boil-off gas generated in the LNG storage tank until a preset pressure is reached.
  • the LNG storage tank may be designed such that, when the internal pressure of the storage tank exceeds the preset pressure, a safety valve is opened to discharge the boil-off gas from the LNG storage tank.
  • a boil-off gas line BL connects the LNG storage tank to the fuel compressor 600 , such that the boil-off gas discharged from the LNG storage tank is supplied to the fuel compressor 600 through the boil-off gas line BL.
  • the fuel compressor 600 compresses the boil-off gas delivered through the boil-off gas line BL to a low pressure required for the fuel demand site.
  • the fuel demand site may be a power generation engine (dual fuel diesel electric (DFDE) engine) that generates electricity using boil-off gas compressed to a low pressure as fuel.
  • the power generation engine may be, for example, a dual fuel diesel generator (DFDG).
  • the DFDG is a generator connected to an engine shaft and uses a four-stroke cycle.
  • the DFDE engine uses an Otto cycle, in which low-pressure natural gas at a pressure of about 2 bar to about 8 bar, or about 6.5 bar is injected into a combustion air inlet and then compressed by a piston moving upward.
  • the fuel compressor 600 compresses boil-off gas to a pressure of about 2 bar to 8 bar, or about 5 bar to 6.5 bar.
  • Boil-off gas compressed by the fuel compressor 600 will hereinafter be referred to as “low-pressure boil-off gas”.
  • the fuel compressor 600 may be a two-stage compressor that includes two compression units, such as a first fuel compression unit 610 and a second fuel compression unit 620 , to compress boil-off gas to low pressures in two stages.
  • two compression units such as a first fuel compression unit 610 and a second fuel compression unit 620 .
  • first fuel compression unit 610 and the second fuel compression unit 620 may be connected to each other via a common shaft.
  • the device for processing boil-off gas may further include: a first cooler 630 disposed downstream of the fuel compressor 600 to cool the low-pressure boil-off gas heated by being compressed by the first fuel compression unit 610 and the second fuel compression unit 620 .
  • first cooler 630 is shown as disposed downstream of the second fuel compression unit 620 in FIG. 1 , it will be understood that the present invention is not limited thereto and the first cooler may be disposed both downstream of the first fuel compression unit 610 and downstream of the second fuel compression unit 620 .
  • the first cooler 630 may be a seawater cooler that cools the low-pressure boil-off gas through heat exchange with cooling water, seawater, or the like, or may be an atmospheric cooler that cools the low-pressure boil-off gas through heat exchange with air.
  • the first cooler 630 may cool the low-pressure boil-off gas to a temperature required for the fuel demand site or to an inlet temperature of the high-pressure compressor 700 described below.
  • the device for processing boil-off gas may further include: a fuel supply line EL disposed downstream of the first cooler 630 to be connected to the fuel demand site; and a high-pressure gas line HL disposed downstream of the first cooler 630 to be connected to the high-pressure compressor 700 .
  • the low-pressure boil-off gas compressed by the fuel compressor 600 and cooled by the first cooler 630 is delivered to the fuel demand site through the fuel supply line EL or delivered to the high-pressure compressor 700 through the high-pressure gas line HL.
  • a flow rate of the low-pressure boil-off gas sent to the fuel supply line EL or the high-pressure gas line HL may be controlled by a controller (not shown).
  • the controller may perform control such that some of the low-pressure boil-off gas corresponding to fuel requirements of the fuel demand site, that is, load-dependent fuel requirements of the power generation engine, is first sent to the fuel supply line EL and the other low-pressure boil-off gas remaining after supply to the fuel demand site is sent to the high-pressure gas line HL.
  • the high-pressure gas line HL may connect the fuel compressor 600 to the high-pressure compressor 700 , and the fuel compressor 600 and the high-pressure compressor 700 according to this embodiment may be connected to each other in series via the high-pressure gas line HL. That is, all or a portion of the low pressure boil-off gas compressed by the fuel compressor 600 is supplied to the high-pressure compressor 700 through the high-pressure gas line HL.
  • the high-pressure compressor 700 compresses the low-pressure boil-off gas to a delivery pressure, that is, a pressure required for the regasified gas demand site.
  • a delivery pressure that is, a pressure required for the regasified gas demand site.
  • the regasified gas demand site may be an onshore gas terminal, and, in this embodiment, the pressure of regasified gas required for the regasified gas demand site may range from about 50 barg to about 100 barg.
  • the high-pressure compressor 700 compresses the low-pressure boil-off gas to a pressure of about 50 barg to 100 barg.
  • Boil-off gas compressed by the high-pressure compressor 700 will hereinafter be referred to as “high-pressure boil-off gas”.
  • the high-pressure compressor 700 is connected to the regasified gas demand site via a regasified gas delivery line SL, such that the high-pressure boil-off gas compressed by the high-pressure compressor 700 can be supplied to the onshore gas terminal along with a regasified gas vaporized by the vaporizer through the regasified gas delivery line SL.
  • the regasification gas delivery line SL may also be connected to the vaporizer of the LNG regasification system.
  • the high-pressure compressor 700 may be a three-stage compressor that includes three compression units, such as a first high-pressure compression unit 710 , a second high-pressure compression unit 730 , and a third high-pressure compression unit 750 , to compress the low-pressure boil-off gas in three stages.
  • three compression units such as a first high-pressure compression unit 710 , a second high-pressure compression unit 730 , and a third high-pressure compression unit 750 , to compress the low-pressure boil-off gas in three stages.
  • the high-pressure compressor 700 is described as being a three-stage compressor in this embodiment, it will be understood that the present invention is not limited thereto.
  • first high-pressure compression unit 710 the second high-pressure compression unit 730 and the third high-pressure compression unit 750 may be connected to one another via a common shaft.
  • a cooler may be disposed downstream of each of the compression units of the high-pressure compressor 700 . That is, the device for processing boil-off gas according to this embodiment may further include: a second cooler 720 disposed downstream of the first high-pressure compression unit 710 to cool the boil-off gas to be supplied to the second high-pressure compression unit 730 from the first high-pressure compression unit 710 ; a third cooler 740 disposed downstream of the second high-pressure compression unit 730 to cool the boil-off gas to be supplied to the third high-pressure compression unit 750 from the second high-pressure compression unit 730 ; and a fourth cooler 760 disposed downstream of the third high-pressure compression unit 750 to cool the boil-off gas discharged from the third high-pressure compression unit 750 .
  • Each of the second cooler 720 , the third cooler 740 , and the fourth cooler 760 may be a seawater cooler that cools the high-pressure boil-off gas through heat exchange with cooling water, seawater, or the like, or may be an atmospheric cooler that cools the high-pressure boil-off gas through heat exchange with air.
  • the device for processing boil-off gas may further include: a reliquefaction line RL branched off of the regasified gas delivery line SL connecting the high-pressure compressor 700 to the regasified gas demand site and connected to the low-temperature heat exchanger 200 .
  • a portion of the high-pressure boil-off gas remaining after supply to the regasified gas demand site is delivered to the low-temperature heat exchanger 200 through the reliquefaction line RL to be reliquefied and recovered.
  • the device for processing boil-off gas may further include: a decompression valve decompressing the high-pressure boil-off gas cooled by the low-temperature heat exchanger 200 ; and a liquefied gas drum 100 performing gas/liquid separation by separating flash gas generated during decompression by the decompression valve 800 from the decompressed boil-off gas.
  • the high-pressure boil-off gas cooled by the low-temperature heat exchanger 200 is decompressed by the depressurization valve 800 and is then subjected to gas/liquid separation by the liquefied gas drum 100 to allow recovery of reliquefied boil-off gas in a liquid state.
  • the reliquefied boil-off gas, from which the flash gas has been separated by the liquefied gas drum 100 , may be returned to the LNG storage tank.
  • the decompression valve 800 may decompress the high-pressure boil-off gas to an internal pressure of the LNG storage tank such that the reliquefied boil-off gas can be returned to the LNG storage tank.
  • the device for processing boil-off gas may further include: a flash gas line FL connecting the liquefied gas drum 100 to a low-temperature inlet of the low-temperature heat exchanger 200 .
  • the gaseous flash gas separated by the liquefied gas drum 100 is supplied to the low-temperature heat exchanger 200 through the flash gas line FL.
  • the gaseous flash gas separated by the liquefied gas drum 100 may be used as a refrigerant cooling the high-pressure boil-off gas introduced into the low-temperature heat exchanger 200 through a high-temperature inlet of the low-temperature heat exchanger 200 .
  • the device for processing boil-off gas may further include: an expansion line PL branched off of the reliquefaction line RL upstream of the low-temperature heat exchanger 200 and connected to the expander 420 .
  • some of the high-pressure boil-off gas to be supplied to the low-temperature heat exchanger 200 from the high-pressure compressor 700 through the reliquefaction line RL may be supplied to the expander 420 through the expansion line PL.
  • the expansion line PL may be connected between an outlet of the expander 420 and the flash gas line FL. That is, the boil-off gas expanded by the expander 420 may be joined with a flow of the flash gas to be introduced into the low-temperature heat exchanger 200 through the flash gas line FL.
  • Boil-off gas is cooled while being expanded by the expander 420 .
  • the expanded boil-off gas may be used as a refrigerant cooling the high-pressure boil-off gas in the low-temperature heat exchanger 200 .
  • boiling includes liquefaction, condensation, and supercooling of boil-off gas.
  • the high-pressure boil-off gas may be introduced in a liquid state, a gaseous state, or a gas-liquid mixed state into the low-temperature heat exchanger 200 and may be liquefied or supercooled through heat exchange in the low-temperature heat exchanger 200 .
  • the high-pressure boil-off gas exchanges heat with a mixture of the flash gas and the expanded boil-off gas, such that the high-pressure boil-off gas is cooled and the mixture is heated.
  • the device for processing boil-off gas may further include: a high-temperature heat exchanger 300 disposed upstream of a point at which the expansion line PL is branched off of the reliquefaction line RL and precooling the high-pressure boil-off gas to be introduced into the low-temperature heat exchanger 200 .
  • the high-temperature heat exchanger 300 may cool the high-pressure boil-off gas to an inlet temperature of the expander 420 .
  • Some of the high-pressure boil-off gas precooled by the high-temperature heat exchanger 300 is supplied to the expander 420 and the other high pressure boil-off gas remaining after supply to the expander 420 is supplied to the low-temperature heat exchanger 200 to be cooled.
  • the high-pressure boil-off gas to be supplied to the low-temperature heat exchanger 200 and the expander 420 exchanges heat with a flow of the mixture discharged from the low-temperature heat exchanger 200 after being used to cool the high-pressure boil-off gas, such that the high-pressure boil-off gas is cooled and the mixture is heated.
  • the high-pressure boil-off gas cooled by the high-temperature heat exchanger 300 is divided and supplied to the low-temperature heat exchanger 200 and the expander 420 .
  • the flash gas line is connected between the liquefied gas drum 100 , the low-temperature heat exchanger 200 , the high-temperature heat exchanger 300 , and the fuel compressor 600 .
  • the flow of the mixture heated by the high-temperature heat exchanger 300 is joined with a flow of the low-pressure boil-off gas to be compressed by the fuel compressor 600 through the flash gas line FL.
  • the flow of the mixture used as a refrigerant cooling the high-pressure boil-off gas in the low-temperature heat exchanger 200 and the high-temperature heat exchanger 300 is recovered to the fuel compressor 600 to be compressed to low pressure.
  • the flash gas line FL is shown as joined upstream of the second fuel compression unit 620 of the fuel compressor 600 . That is, according to this embodiment, the flow of the mixture used as a refrigerant in the low-temperature heat exchanger 200 and the high-temperature heat exchanger 300 is joined with the flow of the boil-off gas to be introduced into the second fuel compression unit 620 .
  • the flash gas line FL may be joined with the boil-off gas line BL at a point upstream of the fuel compressor 600 , at which a flow of the boil-off gas compressed by the fuel compressor 600 has a most similar pressure to the flow of the mixture through the flash gas line FL.
  • the flow of the mixture will be described as joined with the flow of the boil-off gas upstream of the second fuel compression unit 620 .
  • the device for processing boil-off gas may further include: a gas compressor 410 compressing the flow of the mixture to be introduced into the boil-off gas line BL through the flash gas line FL to a pressure of the boil-off gas to be introduced into the second fuel compression unit 620 ; and a gas cooler 500 regulating the temperature of the flow of the mixture compressed by the gas compressor 410 .
  • the gas compressor 410 may be connected to the expander 420 via a common shaft. That is, expansion work in the expander 420 is recovered as compression work in the gas compressor 410 .
  • the gas compressor 410 and the expander 420 are described as used in conjunction with each other via the common shaft to form a compander 400 , as shown in FIG. 1 .
  • boil-off gas introduced into the fuel compressor 600 through the boil-off gas line BL has a flow rate of about 2.3 ton/hr, a pressure of about 0 barg, and a temperature is about ⁇ 120° C.
  • the present invention is not limited thereto and process conditions described in this embodiment, such as the flow rate, pressure, and temperature of a fluid, may be varied depending on the delivery pressure of regasified gas or the composition of LNG.
  • the boil-off gas introduced into the fuel compressor 600 through the boil-off gas line BL is compressed to about 2.2 barg by the first fuel compression unit 610 and is heated to ⁇ 27° C. while being compressed.
  • the boil-off gas compressed by the first fuel compression unit 610 is introduced into the second fuel compression unit 620 through the boil-off gas line BL.
  • a flow of the mixture used as a refrigerant in the low-temperature heat exchanger 200 and the high-temperature heat exchanger 300 is joined with a flow of the boil-off gas compressed by the first fuel compression unit 610 .
  • the flow of the mixture through the flash gas line FL may have a flow rate of about 6.9 ton/hr, a pressure of about 2.2 barg, and a temperature of about 43° C.
  • a net flow of boil-off gas into the second fuel compression unit 620 that is, a mixed flow of the boil-off gas compressed by the first fuel compression unit 610 and the mixture delivered through the flash gas line FL, has a flow rate of about 9.5 ton/hr, a pressure of about 2.2 barg, and a temperature of about 23.3° C.
  • the flow of the boil-off gas is compressed to about 5.5 barg.
  • Some of the low-pressure boil-off gas compressed by the second fuel compression unit 620 is supplied to the fuel demand site and the other low-pressure boil-off gas is introduced into the high-pressure compressor 700 .
  • the low-pressure boil-off gas sent to the fuel supply line EL to be supplied to the fuel demand site has a flow rate of about 0.7 ton/hr
  • the low-pressure boil-off gas sent to the high-pressure gas line HL to be introduced into the high-pressure compressor 700 has a flow rate of about 8.8 ton/hr.
  • the flow rate of the low-pressure boil-off gas sent to the high-pressure gas line HL to be introduced into the high-pressure compressor 700 corresponds to about 10 million standard cubic feet per day (MMSCFD).
  • the boil-off gas introduced into the high-pressure compressor is compressed to about 15.5 barg by the first high-pressure compression unit 710 , is compressed to about 40 barg by the second high-pressure compression unit 730 , and is compressed to about 100 barg by the third high-pressure compression unit 750 .
  • Some of the high-pressure boil-off gas compressed to 100 barg by the high-pressure compressor 700 is supplied to the regasified gas demand site through the regasified gas delivery line SL and the other high-pressure boil-off gas is sent to the reliquefaction line RL.
  • a boil-off gas processing method will be described with reference to the case in which regasified gas demand by the regasified gas demand site can be met by regasified gas supplied from the vaporizer because regasification is not performed, that is, there is no regasified gas demand by the regasified gas demand site, or regasified gas demand by the regasified gas demand site is low.
  • the high pressure boil-off gas compressed by the high-pressure compressor 700 and having a pressure of 100 barg, a temperature of about 43° C., and a flow rate of 8.8 ton/hr (10 MMSCFD) is supplied to the high-temperature heat exchanger 300 through the reliquefaction line RL.
  • the high-pressure boil-off gas is cooled to about 25° C.
  • Some of the high-pressure boil-off gas cooled by the high-temperature heat exchanger 300 is sent to the expander 420 through the expansion line PL and the other high-pressure boil-off gas remaining after supply to the expansion line PL is supplied to the low-temperature heat exchanger 200 through the reliquefaction line RL.
  • the high-pressure boil-off gas cooled by the high-temperature heat exchanger 300 and having a flow rate of about 8.8 ton/hr is distributed to the expansion line PL at a flow rate of 6.5 ton/hr and the low-temperature heat exchanger 200 at a flow rate of about 2.3 ton/hr.
  • the high pressure boil-off gas having a flow rate of about 2.3 ton/hr and a temperature of ⁇ 25° C. is cooled (liquefied) to about ⁇ 157° C.
  • the high-pressure boil-off gas cooled by the low-temperature heat exchanger 200 is decompressed to about 0.5 barg by the depressurization valve 800 and is cooled to about ⁇ 168.1° C. while being decompressed.
  • the reliquefied boil-off gas passing through the decompression valve 800 and having a pressure of about 0.5 barg, a temperature of ⁇ 168.1° C., and a flow rate of 2.3 ton/hr is supplied to the liquefied gas drum 100 , and is then subjected to gas/liquid separation in the liquefied gas drum 100 before being returned to the LNG storage tank.
  • reliquefied boil-off gas in a liquid state from which flash gas having a flow rate of about 0.4 ton/hr of has been separated by the liquefied gas drum 100 , is returned to the LNG storage tank at a flow rate of about 1.9 ton/hr.
  • the gaseous flash gas separated by the liquefied gas drum 100 and having a flow rate of about 0.4 ton/hr, a pressure of 0.5 barg, and a temperature of ⁇ 168.1° C. is supplied to the low-temperature heat exchanger 200 through the flash gas line FL to recover cold heat therefrom.
  • a flow of the flash gas to be supplied to the low-temperature heat exchanger 200 is joined with a flow of the boil-off gas expanded by the expander 420 .
  • the high-pressure boil-off gas having a flow rate of about 6.5 ton/hr, a pressure of 100 barg, and a temperature ⁇ 25° C. is introduced into the expander 420 .
  • the high-pressure boil-off gas is expanded to about 0.5 barg by the expander 420 and is cooled to ⁇ 158.6° C. while being expanded.
  • a flow of a mixture of the boil-off gas expanded by the expander 420 and having a flow rate of about 6.5 ton/hr, a pressure of 0.5 barg, and a temperature of ⁇ 158.6° C. and the flash gas separated by the liquefied gas drum 100 and having a flow rate of 0.4 ton/hr, a pressure of 0.5 barg, and a temperature of ⁇ 168.1° C. is supplied as a refrigerant to the low-temperature heat exchanger 200 , wherein the flow of a mixture has a flow rate of about 6.9 ton/hr, a pressure of 0.5 barg, and a temperature of ⁇ 159 ° C.
  • the flow of the mixture is heated to about ⁇ 90.7° C. while cooling the high-pressure boil-off gas in the low-temperature heat exchanger 200 .
  • the flow of the mixture heated while cooling the high-pressure boil-off gas in the low-temperature heat exchanger 200 is supplied as a refrigerant to the high-temperature heat exchanger 300 .
  • the flow of the mixture is heated to about 40.0° C. while cooling the high-pressure boil-off gas in the high-temperature heat exchanger 300 .
  • the flow of the mixture heated while cooling the high-pressure boil-off gas in the high-temperature heat exchanger 300 is compressed to about 2.2 barg by the gas compressor 410 and is then adjusted to about 43° C. by a fifth cooler 500 before being joined with a flow of the boil-off gas to be supplied to the second fuel compression unit 620 .
  • boil-off gas generated in an LNG regasification system is liquefied using cold heat recovered by expanding the boil-off gas itself, rather than being recovered by condensing the boil-off gas using cold heat of LNG to be regasified, whereby all of the boil-off gas can be reliquefied and recovered regardless of the flow rate of regasified gas or fuel consumption.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Ocean & Marine Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
US16/957,015 2017-12-29 2018-12-28 Device and method for processing boil-off gas in liquefied gas regasification system Abandoned US20200393196A1 (en)

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KR1020170183742A KR102387172B1 (ko) 2017-12-29 2017-12-29 액화가스 재기화 시스템의 증발가스 처리 장치 및 방법
KR10-2017-0183742 2017-12-29
PCT/KR2018/016899 WO2019132608A1 (ko) 2017-12-29 2018-12-28 액화가스 재기화 시스템의 증발가스 처리 장치 및 방법

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EP3733499A1 (en) 2020-11-04
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WO2019132608A1 (ko) 2019-07-04
EP3733499A4 (en) 2021-09-08
JP6986159B2 (ja) 2021-12-22
KR102387172B1 (ko) 2022-04-15
CN111527024A (zh) 2020-08-11

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