US20200194447A1 - Contact structures for three-dimensional memory device - Google Patents
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- US20200194447A1 US20200194447A1 US16/240,151 US201916240151A US2020194447A1 US 20200194447 A1 US20200194447 A1 US 20200194447A1 US 201916240151 A US201916240151 A US 201916240151A US 2020194447 A1 US2020194447 A1 US 2020194447A1
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- H—ELECTRICITY
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- H10B—ELECTRONIC MEMORY DEVICES
- H10B41/00—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates
- H10B41/50—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by the boundary region between the core region and the peripheral circuit region
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B41/00—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates
- H10B41/20—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by three-dimensional arrangements, e.g. with cells on different height levels
- H10B41/23—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by three-dimensional arrangements, e.g. with cells on different height levels with source and drain on different levels, e.g. with sloping channels
- H10B41/27—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by three-dimensional arrangements, e.g. with cells on different height levels with source and drain on different levels, e.g. with sloping channels the channels comprising vertical portions, e.g. U-shaped channels
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- H01L27/11524—
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- H10B—ELECTRONIC MEMORY DEVICES
- H10B41/00—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates
- H10B41/30—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by the memory core region
- H10B41/35—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by the memory core region with a cell select transistor, e.g. NAND
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- H—ELECTRICITY
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- H10B—ELECTRONIC MEMORY DEVICES
- H10B41/00—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates
- H10B41/40—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by the peripheral circuit region
- H10B41/41—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by the peripheral circuit region of a memory region comprising a cell select transistor, e.g. NAND
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- H—ELECTRICITY
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- H10B—ELECTRONIC MEMORY DEVICES
- H10B43/00—EEPROM devices comprising charge-trapping gate insulators
- H10B43/20—EEPROM devices comprising charge-trapping gate insulators characterised by three-dimensional arrangements, e.g. with cells on different height levels
- H10B43/23—EEPROM devices comprising charge-trapping gate insulators characterised by three-dimensional arrangements, e.g. with cells on different height levels with source and drain on different levels, e.g. with sloping channels
- H10B43/27—EEPROM devices comprising charge-trapping gate insulators characterised by three-dimensional arrangements, e.g. with cells on different height levels with source and drain on different levels, e.g. with sloping channels the channels comprising vertical portions, e.g. U-shaped channels
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B43/00—EEPROM devices comprising charge-trapping gate insulators
- H10B43/30—EEPROM devices comprising charge-trapping gate insulators characterised by the memory core region
- H10B43/35—EEPROM devices comprising charge-trapping gate insulators characterised by the memory core region with cell select transistors, e.g. NAND
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B43/00—EEPROM devices comprising charge-trapping gate insulators
- H10B43/40—EEPROM devices comprising charge-trapping gate insulators characterised by the peripheral circuit region
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B43/00—EEPROM devices comprising charge-trapping gate insulators
- H10B43/50—EEPROM devices comprising charge-trapping gate insulators characterised by the boundary region between the core and peripheral circuit regions
Definitions
- the present disclosure generally relates to the field of semiconductor technology, and more particularly, to a method for forming a three-dimensional (3D) memory.
- Planar memory cells are scaled to smaller sizes by improving process technology, circuit designs, programming algorithms, and the fabrication process.
- feature sizes of the memory cells approach a lower limit
- planar process and fabrication techniques become challenging and costly.
- memory density for planar memory cells approaches an upper limit.
- a three-dimensional (3D) memory architecture can address the density limitation in planar memory cells.
- Embodiments of contact structures for a three-dimensional memory device and methods for forming the same are described in the present disclosure.
- a three-dimensional memory structure includes a film stack disposed on a substrate, wherein the film stack includes a plurality of conductive and dielectric layer pairs, each conductive and dielectric layer pair having a conductive layer and a first dielectric layer.
- the three-dimensional memory structure also includes a staircase structure formed in the film stack, wherein the staircase structure includes a plurality of steps, each staircase step having two or more conductive and dielectric layer pairs.
- the three-dimensional memory structure further includes a plurality of coaxial contact structures formed in a first insulating layer over the staircase structure, wherein each coaxial contact structure includes one or more conductive and insulating ring pairs and a conductive core, wherein each conductive and insulating ring pair includes a conductive ring and an insulating ring.
- each conductive ring contacts the conductive layer of a corresponding conductive and dielectric layer pair of the staircase step.
- each coaxial contact structure comprises at least an outer conductive ring and an inner conductive ring, and the outer conductive ring corresponds with an upper conductive and dielectric layer pair of the staircase step, wherein the outer conductive ring includes larger diameter, and the upper conductive and dielectric layer pair is farther away from the substrate.
- each coaxial contact structure comprises at least an outer conductive ring and an inner conductive ring, and the inner conductive ring corresponds with a lower conductive and dielectric layer pair of the staircase step, wherein the inner conductive ring includes smaller diameter, and the lower conductive and dielectric layer pair is closer to the substrate.
- the conductive core contacts the conductive layer closest to the substrate in the staircase step of two or more conductive and dielectric layer pairs.
- the insulating ring of the conductive and insulating ring pair is disposed to surround a sidewall of the conductive ring and a sidewall of the conductive layer of the staircase structure, wherein the insulating ring is configured to electrically isolate the conductive ring from another conductive ring or the conductive core.
- the insulating ring is disposed on a sidewall of the first dielectric layer of the staircase step of two or more conductive and dielectric layer pairs.
- the three-dimensional memory structure further includes a barrier layer, disposed between the first insulating layer and the staircase structure, and the plurality of coaxial contact structures extending through the barrier layer.
- the three-dimensional memory structure further includes a gate dielectric layer on the conductive layer, and the conductive rings extending through the gate dielectric layer to contact the conductive layers of the staircase structure.
- a method for forming a three-dimensional (3D) memory structure includes disposing a dielectric film stack on a substrate, wherein the dielectric film stack includes a plurality of alternating dielectric layer pairs, each alternating dielectric layer pair having a first dielectric layer and a second dielectric layer different from the first dielectric layer.
- the method also includes forming a dielectric staircase in the dielectric film stack, wherein the dielectric staircase includes a plurality of steps, each dielectric staircase step having two or more alternating dielectric layer pairs.
- the method further includes disposing a first insulating layer on the dielectric staircase, forming a plurality of memory strings in the dielectric film stack, and replacing the second dielectric layers with conductive layers to form a staircase structure with a plurality of steps, wherein each staircase step includes two or more conductive and dielectric layer pairs, each conductive and dielectric layer pair having a conductive layer and the first dielectric layer.
- the method also includes forming a plurality of coaxial contact structures on the staircase structure.
- forming the coaxial contact structure includes forming a conductive and insulating ring pair for each conductive and dielectric layer pair of the staircase step in the staircase structure.
- forming the conductive ring includes forming a first contact hole to expose the conductive layer in one of the two or more conductive and dielectric layer pairs of the staircase step in the staircase structure, disposing a conductive film on a sidewall of the contact hole and the exposed conductive layer, and removing the conducive film and a portion of the conductive layer from the bottom of the first contact hole to form a conductive ring, wherein a bottom of the conductive ring is formed to contact the conductive layer in one of the two or more conductive and dielectric layer pairs of the staircase step in the staircase structure.
- forming the conductive ring further includes etching the dielectric layer of the next conductive and dielectric layer pair.
- forming the insulating ring includes disposing a second insulating layer in a first contact hole, and removing the second insulating layer from the bottom of the first contact hole. Forming the insulating ring also includes forming the insulating ring surrounding a sidewall of the conductive ring and a sidewall of the conductive layer of one of the two or more conductive and dielectric layer pairs in the staircase step in the staircase structure, and forming a second contact hole to expose the next conductive layer in the staircase step.
- forming the coaxial contact structure further includes forming a contact hole to expose the conductive layer closest to the substrate in the staircase step of two or more conductive and dielectric layer pairs, disposing a conductive material to fill the contact hole, and forming a conductive core to contact the conductive layer closest to the substrate in staircase step of two or more conductive and dielectric layer pairs.
- the method further includes performing a planarization process to remove the conductive material outside the contact hole and form a coplanar surface.
- the method further includes disposing a barrier layer on the dielectric staircase prior to the first insulating layer.
- forming the plurality of dielectric staircase steps includes disposing a patterning mask on the dielectric film stack, and etching exposed portions of the dielectric film stack in a direction perpendicular to a main surface of the substrate until portions of the two or more dielectric layer pairs are removed. Forming the plurality of dielectric staircase steps also includes trimming the patterning mask laterally, in a direction parallel to the main surface of the substrate, repeating the etching and the trimming processes until a dielectric staircase step closest to the main surface of the substrate is formed, and removing the patterning mask.
- replacing the second dielectric layers with the conductive layers to form the staircase structure includes forming one or more slit structure openings, extending horizontally along the dielectric staircase, wherein the slit structure openings penetrate vertically through the dielectric film stack.
- Replacing the second dielectric layers also includes removing the second dielectric layers of the dielectric staircase to form a plurality of horizontal tunnels, and disposing the conductive layers inside the plurality of horizontal tunnels.
- the method further includes disposing a gate dielectric layer on sidewalls of the horizontal tunnels prior to disposing the conductive layer, wherein the gate dielectric layer includes high-k dielectric material, silicon oxide, silicon nitride or silicon oxynitride.
- FIG. 1 illustrates a schematic top-down view of an exemplary three-dimensional (3D) memory die, according to some embodiments of the present disclosure.
- FIG. 2A-2B illustrate schematic top-down views of some regions of 3D memory die, according to some embodiments of the present disclosure.
- FIG. 3 illustrates a perspective view of a portion of an exemplary 3D memory array structure, in accordance with some embodiments of the present disclosure.
- FIG. 4-15 illustrate schematic cross-sectional views of an exemplary 3D memory structure at certain fabricating stages, according to some embodiments of the present disclosure.
- FIG. 16A illustrates a schematic cross-sectional view of an exemplary 3D memory structure at a certain fabricating stage, according to some embodiments of the present disclosure.
- FIG. 16B illustrates a perspective view of a portion of an exemplary 3D memory structure at a certain fabricating stage, according to some embodiments of the present disclosure.
- FIG. 17A-17D illustrate schematic cross-sectional views of an exemplary 3D memory structure at certain fabricating stages, according to some embodiments of the present disclosure.
- FIG. 18 illustrates a flow diagram of an exemplary method for forming a 3D memory structure, according to some embodiments of the present disclosure.
- references in the specification to “one embodiment,” “an embodiment,” “an example embodiment,” “some embodiments,” etc. indicate that the embodiment described can include a particular feature, structure, or characteristic, but every embodiment can not necessarily include the particular feature, structure, or characteristic. Moreover, such phrases do not necessarily refer to the same embodiment. Further, when a particular feature, structure or characteristic is described in connection with an embodiment, it would be within the knowledge of a person skilled in the pertinent art to affect such feature, structure or characteristic in connection with other embodiments whether or not explicitly described.
- terminology can be understood at least in part from usage in context.
- the term “one or more” as used herein, depending at least in part upon context can be used to describe any feature, structure, or characteristic in a singular sense or can be used to describe combinations of features, structures or characteristics in a plural sense.
- terms, such as “a,” “an,” or “the,” again, can be understood to convey a singular usage or to convey a plural usage, depending at least in part upon context.
- the term “based on” can be understood as not necessarily intended to convey an exclusive set of factors and may, instead, allow for existence of additional factors not necessarily expressly described, again, depending at least in part on context.
- spatially relative terms such as “beneath,” “below,” “lower,” “above,” “upper,” and the like, can be used herein for ease of description to describe one element or feature's relationship to another element(s) or feature(s) as illustrated in the figures.
- the spatially relative terms are intended to encompass different orientations of the device in use or process step in addition to the orientation depicted in the figures.
- the apparatus can be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein can likewise be interpreted accordingly.
- the term “substrate” refers to a material onto which subsequent material layers are added.
- the substrate includes a top surface and a bottom surface.
- the top surface of the substrate is typically where a semiconductor device is formed, and therefore the semiconductor device is formed at a top side of the substrate unless stated otherwise.
- the bottom surface is opposite to the top surface and therefore a bottom side of the substrate is opposite to the top side of the substrate.
- the substrate itself can be patterned. Materials added on top of the substrate can be patterned or can remain unpatterned.
- the substrate can include a wide array of semiconductor materials, such as silicon, germanium, gallium arsenide, indium phosphide, etc.
- the substrate can be made from an electrically non-conductive material, such as a glass, a plastic, or a sapphire wafer.
- the term “layer” refers to a material portion including a region with a thickness.
- a layer has a top side and a bottom side where the bottom side of the layer is relatively close to the substrate and the top side is relatively away from the substrate.
- a layer can extend over the entirety of an underlying or overlying structure, or can have an extent less than the extent of an underlying or overlying structure.
- a layer can be a region of a homogeneous or inhomogeneous continuous structure that has a thickness less than the thickness of the continuous structure.
- a layer can be located between any set of horizontal planes between, or at, a top surface and a bottom surface of the continuous structure.
- a layer can extend horizontally, vertically, and/or along a tapered surface.
- a substrate can be a layer, can include one or more layers therein, and/or can have one or more layer thereupon, thereabove, and/or therebelow.
- a layer can include multiple layers.
- an interconnect layer can include one or more conductive and contact layers (in which contacts, interconnect lines, and/or vertical interconnect accesses (VIAs) are formed) and one or more dielectric layers.
- the term “nominal/nominally” refers to a desired, or target, value of a characteristic or parameter for a component or a process step, set during the design phase of a product or a process, together with a range of values above and/or below the desired value.
- the range of values can be due to slight variations in manufacturing processes or tolerances.
- the term “about” indicates the value of a given quantity that can vary based on a particular technology node associated with the subject semiconductor device. Based on the particular technology node, the term “about” can indicate a value of a given quantity that varies within, for example, 10-30% of the value (e.g., ⁇ 10%, ⁇ 20%, or ⁇ 30% of the value).
- the term “horizontal/horizontally/lateral/laterally” means nominally parallel to a lateral surface of a substrate.
- the term “each” may not only necessarily mean “each of all,” but can also mean “each of a subset.”
- 3D memory refers to a three-dimensional (3D) semiconductor device with vertically oriented strings of memory cell transistors (referred to herein as “memory strings,” such as NAND strings) on a laterally-oriented substrate so that the memory strings extend in the vertical direction with respect to the substrate.
- memory strings such as NAND strings
- vertical/vertically means nominally perpendicular to the lateral surface of a substrate.
- tier is used to refer to elements of substantially the same height along the vertical direction.
- a word line and the underlying gate dielectric layer can be referred to as “a tier”
- a word line and the underlying insulating layer can together be referred to as “a tier”
- word lines of substantially the same height can be referred to as “a tier of word lines” or similar, and so on.
- a memory string of a 3D memory device includes a semiconductor pillar (e.g., silicon channel) that extends vertically through a plurality of conductive and dielectric layer pairs.
- the plurality of conductive and dielectric layer pairs are also referred to herein as an “alternating conductive and dielectric stack.”
- An intersection of the conductive layer and the semiconductor pillar can form a memory cell.
- the conductive layer of the alternating conductive and dielectric stack can be connected to a word line at the back-end-of-line, wherein the word line can electrically connect to one or more control gates.
- word lines and control gates are used interchangeably to describe the present disclosure.
- the top of the semiconductor pillar e.g., transistor drain region
- a bit line electrically connecting one or more semiconductor pillars.
- Word lines and bit lines are typically laid perpendicular to each other (e.g., in rows and columns, respectively), forming an “array” of the memory, also called a memory “block” or an “array block”.
- a memory “die” may have one or more memory “planes”, and each memory plane may have a plurality of memory blocks.
- An array block can also be divided into a plurality of memory “pages”, wherein each memory page may have a plurality of memory strings.
- erase operation can be performed for every memory block and read/write operation can be performed for every memory page.
- the array blocks are the core area in a memory device, performing storage functions. To achieve higher storage density, the number of vertical 3D memory stacks is increased greatly, adding complexity and cost in manufacturing.
- a memory die has another region, called the periphery, which provides supporting functions to the core.
- the periphery region includes many digital, analog, and/or mixed-signal circuits, for example, row and column decoders, drivers, page buffers, sense amplifiers, timing and controls, and the like circuitry.
- Peripheral circuits use active and/or passive semiconductor devices, such as transistors, diodes, capacitors, resistors, etc., as would be apparent to a person of ordinary skill in the art.
- a “memory device” is a general term and can be a memory chip (package), a memory die or any portion of a memory die.
- the disclosed structures can also be applied in similar or different semiconductor devices to, e.g., to improve metal connections or wiring.
- the specific application of the disclosed structures should not be limited by the embodiments of the present disclosure.
- FIG. 1 illustrates a top-down view of an exemplary three-dimensional (3D) memory device 100 , according to some embodiments of the present disclosure.
- the 3D memory device 100 can be a memory die and can include one or more memory planes 101 , each of which can include a plurality of memory blocks 103 . Identical and concurrent operations can take place at each memory plane 101 .
- the memory block 103 which can be megabytes (MB) in size, is the smallest size to carry out erase operations. Shown in FIG. 1 , the exemplary 3D memory device 100 includes four memory planes 101 and each memory plane 101 includes six memory blocks 103 .
- Each memory block 103 can include a plurality of memory cells, wherein each memory cell can be addressed through interconnections such as bit lines and word lines.
- bit lines and word lines can be laid out perpendicularly, forming an array of metal lines.
- the direction of bit lines and word lines are labeled as “BL” and “WL” in FIG. 1 .
- memory blocks 103 is also referred to as “memory arrays”.
- the 3D memory device 100 also includes a periphery regions 105 , an area surrounding memory planes 101 .
- the periphery region 105 contains peripheral circuits to support functions of the memory array, for example, page buffers, row and column decoders and sense amplifiers.
- the memory arrays and the peripheral circuits of the 3D memory device 100 can be formed on different substrates and can be joined together to form the 3D memory device 100 through wafer bonding.
- through array contact structures can provide vertical interconnects between the memory arrays and peripheral circuits, thereby reducing metal levels and shrinking die size.
- the region 108 of the 3D memory device 100 can include a staircase region 210 and a channel structure region 211 .
- the channel structure region 211 can include an array of memory strings 212 , each including a plurality of stacked memory cells.
- the staircase region 210 can include a staircase structure and an array of contact structures 214 formed on the staircase structure.
- a plurality of slit structures 216 extending in WL direction across the channel structure region 211 and the staircase region 210 , can divide a memory block into multiple memory fingers 218 .
- At least some slit structures 216 can function as the common source contact for an array of memory strings 212 in channel structure regions 211 .
- a top select gate cut 220 can be disposed in the middle of each memory finger 218 to divide a top select gate (TSG) of the memory finger 218 into two portions, and thereby can divide a memory finger into two programmable (read/write) pages. While erase operation of a 3D NAND memory can be carried out at memory block level, read and write operations can be carried out at memory page level.
- a page can be kilobytes (KB) in size.
- region 108 also includes dummy memory strings 222 for process variation control during fabrication and/or for additional mechanical support.
- the region 109 of the 3D memory device 100 can include the channel structure region 211 , a through array contact region 107 , and a top select gate (TSG) staircase region 224 .
- TSG top select gate
- the channel structure region 211 in the region 109 can be similar to the channel structure region 211 in region 108 .
- the TSG staircase region 224 can include an array of TSG contacts 226 formed on the staircase structure.
- the TSG staircase region 224 can be disposed on the sides of the channel structure region 211 and adjacent to through array contact region 107 in the top-down view. Multiple through array contacts 228 can be formed in the through array contact region 107 .
- FIG. 3 illustrates a perspective view of a portion of an exemplary three-dimensional (3D) memory array structure 300 , according to some embodiments of the present disclosure.
- the memory array structure 300 includes a substrate 330 , an insulating film 331 over the substrate 330 , a tier of lower select gates (LSGs) 332 over the insulating film 331 , and a plurality of tiers of control gates 333 , also referred to as “word lines (WLs)”, stacking on top of the LSGs 332 to form a film stack 335 of alternating conductive and dielectric layers.
- LSGs lower select gates
- WLs word lines
- the control gates of each tier are separated by slit structures 216 - 1 and 216 - 2 through the film stack 335 .
- the memory array structure 300 also includes a tier of top select gates (TSGs) 334 over the stack of control gates 333 .
- the stack of TSG 334 , control gates 333 and LSG 332 is also referred to as “gate electrodes.”
- the memory array structure 300 further includes memory strings 212 and doped source line regions 344 in portions of substrate 330 between adjacent LSGs 332 .
- Each memory strings 212 includes a channel hole 336 extending through the insulating film 331 and the film stack 335 of alternating conductive and dielectric layers.
- Memory strings 212 also includes a memory film 337 on a sidewall of the channel hole 336 , a channel layer 338 over the memory film 337 , and a core filling film 339 surrounded by the channel layer 338 .
- a memory cell 340 can be formed at the intersection of the control gate 333 and the memory string 212 .
- the memory array structure 300 further includes a plurality of bit lines (BLs) 341 connected to the memory strings 212 over the TSGs 334 .
- the memory array structure 300 also includes a plurality of metal interconnect lines 343 connected to the gate electrodes through a plurality of contact structures 214 .
- the edge of the film stack 335 is configured in a shape of staircase to allow an electrical connection to each tier of the gate electrodes.
- the channel structure region 211 and the staircase region 210 correspond to the channel structure region 211 and the staircase region 210 in the top-down view of FIG. 2A , wherein one of the staircase region 210 in FIG. 3 can be used as TSG staircase region 230 for TSG connection.
- each memory string 212 can include three memory cells 340 - 1 , 340 - 2 and 340 - 3 , corresponding to the control gates 333 - 1 , 333 - 2 and 333 - 3 , respectively.
- the number of control gates and the number of memory cells can be more than three to increase storage capacity.
- the memory array structure 300 can also include other structures, for example, through array contact, TSG cut, common source contact and dummy channel structure. These structures are not shown in FIG. 3 for simplicity.
- the number of vertical tiers of 3D memory cells 340 or word lines 333 increases accordingly, leading to more process complexity and higher manufacturing cost.
- a high aspect ratio etching is needed to form contact holes, followed by a high aspect ratio deposition of conductive materials inside the contact holes.
- portions of a 3D memory device can be formed on two or more wafers and then joined together through wafer bonding or flip-chip bonding.
- a 3D memory device can be formed by sequentially stacking multi-sessions, wherein each session contains a stack of word lines with less number of tiers.
- larger lateral dimensions of staircase structures due to vertically stacked word lines still limits the storage density.
- Various embodiments in the present disclosure describe a structure and method of a 3D memory with coaxial contact structures, each providing electrical contacts to two or more conductive layers of the staircase structure.
- the dimension of the staircase region 210 in FIG. 2 ) can be reduced.
- Memory density and cost per bit of the 3D NAND memory can be improved accordingly.
- FIG. 4 illustrates a cross-sectional view of an exemplary structure 400 of a three-dimensional memory device, according to some embodiments, wherein the structure 400 includes a substrate 330 and a dielectric film stack 445 .
- the cross-sectional views of FIG. 4-17D are along WL direction in FIG. 2A .
- Substrate 330 can provide a platform for forming subsequent structures.
- the substrate 330 includes any suitable material for forming the three-dimensional memory device.
- the substrate 330 can include any other suitable material, for example, silicon, silicon germanium, silicon carbide, silicon on insulator (SOI), germanium on insulator (GOI), glass, gallium nitride, gallium arsenide, III-V compound, and/or any combinations thereof.
- a front surface 330 f of the substrate 330 is also referred to as a “main surface” of the substrate herein. Layers of materials can be disposed on the front surface 330 f of the substrate. A “topmost” or “upper” layer is a layer farthest or farther away from the front surface 330 f of the substrate. A “bottommost” or “lower” layer is a layer closest or closer to the front surface 330 f of the substrate.
- peripheral devices can be formed in the periphery region 105 on the front surface 330 f of the substrate 330 .
- active device areas can be formed in the memory blocks 103 on the front surface 330 f of the substrate 330 .
- the substrate 330 can further include an insulating film 331 on the front surface 330 f .
- the insulating film 331 can be made of the same or different material from the dielectric film stack.
- the peripheral devices can include any suitable semiconductor devices, for example, metal oxide semiconductor field effect transistors (MOSFETs), diodes, resistors, capacitor, etc.
- MOSFETs metal oxide semiconductor field effect transistors
- the peripheral devices can be used in the design of digital, analog and/or mixed signal circuits supporting the storage function of the memory core, for example, row and column decoders, drivers, page buffers, sense amplifiers, timing and controls.
- the active device areas in the memory blocks are surrounded by isolation structures, such as shallow trench isolation.
- isolation structures such as shallow trench isolation.
- Doped regions such as p-type doped and/or n-type doped wells, can be formed in the active device area according to the functionality of the array devices in the memory blocks.
- the dielectric film stack 445 extends in a lateral direction that is parallel to the front surface 330 f of the substrate 330 .
- the dielectric film stack 445 includes a dielectric layer 450 (also referred to as “first dielectric layer”) and a sacrificial layer 452 (also referred to as “second dielectric layer”) alternatingly stacked on each other, wherein the dielectric layer 450 is configured to be the bottommost and the topmost layers of the dielectric film stack 445 .
- each sacrificial layer 452 is sandwiched between two dielectric layers 450
- each dielectric layer 450 is sandwiched between two sacrificial layers 452 (except the bottommost and the topmost layer).
- the dielectric layer 450 and the underlying sacrificial layer 452 are also referred to as an alternating dielectric layer pair 454 .
- the formation of the dielectric film stack 445 can include disposing the dielectric layers 450 to each have the same thickness or to have different thicknesses.
- Example thicknesses of the dielectric layers 450 can range from 10 nm to 500 nm.
- the sacrificial layer 452 can each have the same thickness or have different thicknesses.
- Example thicknesses of the sacrificial layer 452 can range from 10 nm to 500 nm.
- the dielectric film stack 445 can include layers in addition to the dielectric layer 450 and the sacrificial layer 452 , and can be made of different materials and with different thicknesses.
- the dielectric layer 450 includes any suitable insulating materials, for example, silicon oxide, silicon oxynitride, silicon nitride, TEOS or silicon oxide with F—, C—, N—, and/or H— incorporation.
- the dielectric layer 450 can also include high-k dielectric materials, for example, hafnium oxide, zirconium oxide, aluminum oxide, tantalum oxide, or lanthanum oxide films.
- the formation of the dielectric layer 450 on the substrate 330 can include any suitable deposition methods such as, chemical vapor deposition (CVD), physical vapor deposition (PVD), plasma-enhanced CVD (PECVD), rapid thermal chemical vapor deposition (RTCVD), low pressure chemical vapor deposition (LPCVD), sputtering, metal-organic chemical vapor deposition (MOCVD), atomic layer deposition (ALD), high-density-plasma CVD (HDP-CVD), thermal oxidation, nitridation, any other suitable deposition method, and/or combinations thereof.
- CVD chemical vapor deposition
- PVD physical vapor deposition
- PECVD plasma-enhanced CVD
- RTCVD rapid thermal chemical vapor deposition
- LPCVD low pressure chemical vapor deposition
- sputtering metal-organic chemical vapor deposition
- MOCVD metal-organic chemical vapor deposition
- ALD atomic layer deposition
- HDP-CVD high
- the sacrificial layer 452 includes any suitable material that is different from the dielectric layer 450 and can be removed selectively.
- the sacrificial layer 452 can include silicon oxide, silicon oxynitride, silicon nitride, TEOS, poly-crystalline silicon, poly-crystalline germanium, poly-crystalline germanium-silicon, and any combinations thereof.
- the sacrificial layer 452 also includes amorphous semiconductor materials, such as amorphous silicon or amorphous germanium.
- the sacrificial layer 452 can be disposed using a similar technique as the dielectric layer 450 , such as CVD, PVD, ALD, thermal oxidation or nitridation, or any combination thereof.
- the dielectric layer 450 can be silicon oxide and the sacrificial layer 452 can be silicon nitride.
- FIG. 5 illustrates a cross-sectional view of an exemplary structure 500 of a three dimensional memory device, according to some embodiments, wherein the structure 500 includes a dielectric staircase 560 formed in the dielectric film stack 445 .
- a dielectric staircase step 562 or a “staircase layer”, refers to a layer stack with the same lateral dimension in a surface parallel to the substrate surface 330 f
- Each dielectric staircase step 562 terminates at a shorter length than the staircase step underneath, with a lateral dimension “a” shown in FIG. 5 .
- each dielectric staircase step 562 includes two or more alternating dielectric layer pairs 454 .
- Each dielectric staircase step 562 can have a same number of alternating dielectric layer pairs or a different number of alternating dielectric layer pairs.
- FIG. 5 depicts the dielectric staircase 560 with two alternating dielectric layer pairs 454 .
- the plural steps of the dielectric staircase 560 can be formed by applying a repetitive etch-trim process on the dielectric film stack 445 using a patterning mask (not shown).
- the patterning mask can include a photoresist or carbon-based polymer material. The patterning mask can be removed after forming the dielectric staircase 560 .
- the etch-trim process includes an etching process and a trimming process. During the etching process, a portion of each dielectric staircase step 562 with exposed surface can be removed. The remaining portion of each dielectric staircase step 562 , either covered by upper levels of staircase steps or covered by the patterning mask, is not etched.
- the etch depth is a thickness of the dielectric staircase step 562 .
- the thickness of the dielectric staircase step 562 is the total thickness of two or more alternating dielectric layer pairs 454 . In the example shown in FIG. 5 , the thickness of a dielectric staircase step 562 is the thickness of two alternating dielectric layer pairs 454 .
- the etching process for the dielectric layer 450 can have a high selectivity over the sacrificial layer 452 , and/or vice versa. Accordingly, an underlying alternating dielectric layer pair 454 can function as an etch-stop layer.
- the dielectric staircase step 562 with multiple alternating dielectric layer pairs 454 can be etched during one etching cycle. And as a result, one staircase step is formed during each etch-trim cycle.
- the dielectric staircase step 562 can be etched using an anisotropic etching such as a reactive ion etch (RIE) or other dry etch processes.
- the dielectric layer 450 is silicon oxide.
- the etching of silicon oxide can include RIE using fluorine based gases, for example, carbon-fluorine (CF 4 ), hexafluoroethane (C 2 F 6 ), CHF 3 , or C 3 F 6 and/or any other suitable gases.
- the silicon oxide layer can be removed by wet chemistry, such as hydrofluoric acid or a mixture of hydrofluoric acid and ethylene glycol. In some embodiments, a timed etching approach can be used.
- the sacrificial layer 452 is silicon nitride.
- the etching of silicon nitride can include RIE using O 2 , N 2 , CF 4 , NF 3 , Cl 2 , HBr, BCl 3 , and/or combinations thereof.
- the methods and etchants to remove a single layer stack should not be limited by the embodiments of the present disclosure.
- the trimming process includes applying a suitable etching process (e.g., an isotropic dry etch or a wet etch) on the patterning mask such that the patterning mask can be pulled back laterally.
- a suitable etching process e.g., an isotropic dry etch or a wet etch
- the lateral pull-back dimension determines the lateral dimension “a” of each step of the dielectric staircase 560 .
- the patterning mask trimming process can include dry etching, such as RIE using O 2 , Ar, N 2 , etc.
- the topmost dielectric staircase step 562 can be covered by the dielectric layer 450 . In some embodiments, the topmost dielectric staircase step 562 can further be covered by other dielectric materials. A process step of removing the dielectric layer 450 and/or the other dielectric materials can be added to the etching process of each etch-trim cycle to form the dielectric staircase 560 .
- FIG. 6 illustrates a cross-sectional view of an exemplary structure 600 of a three dimensional memory device, according to some embodiments, wherein the structure 600 includes a barrier layer 664 disposed over the structure 500 .
- the barrier layer 664 covers the dielectric staircase 560 on both the top surfaces and sidewalls.
- the barrier layer 664 can be an optional etch-stop layer.
- the barrier layer 664 can be used as an etch-stop layer for protecting the underlying structure during contact hole etching processes.
- a thickness of the barrier layer 664 on sidewalls can be the same as a thickness of the barrier layer 664 on the top surfaces.
- the thickness of the barrier layer 664 on sidewalls can be different from the thickness of the barrier layer 664 on the top surfaces.
- the barrier layer 664 can be made of similar material as the dielectric layer 450 using a similar technique.
- FIG. 7 illustrates a cross-sectional view of an exemplary structure 700 of a three dimensional memory device, according to some embodiments, wherein the structure 700 includes a first insulating layer 768 disposed over the structure 600 .
- the first insulating layer 768 can be disposed on dielectric staircase 560 after forming the barrier layer 664 .
- the first insulating layer 768 can be made of any a suitable insulator and can be made of a similar material as the dielectric layer 450 using a similar technique.
- the first insulating layer 768 can also include spin-on-glass, a mixture of silicon oxide and dopants (either boron or phosphorous) that is suspended in a solvent solution, and can be disposed using processes, for example, spin-coating.
- the first insulating layer 768 can include a low-k dielectric material, such as carbon-doped oxide (CDO or SiOC or SiOC:H), or fluorine doped oxide (SiOF), etc.
- the low-k dielectric material can be disposed by CVD, PVD, sputtering, etc.
- a planarization process for example RIE etch-back or chemical mechanical polishing (CMP) can be performed to form a coplanar surface, parallel to the surface 330 f of the substrate 330 .
- the top surface 768 S of the first insulating layer 768 can be coplanar with the top surface 664 S of the uppermost portion of the barrier layer 664 .
- the barrier layer 664 can be used as a polish-stop.
- FIG. 8 illustrates a cross-sectional view of an exemplary structure 800 of a three dimensional memory device, according to some embodiments, wherein the structure 800 includes a plurality of memory strings 212 through the dielectric film stack 445 .
- the memory strings 212 correspond to the memory strings 212 in FIGS. 2A-2B and FIG. 3 .
- two memory strings are shown in FIG. 8 .
- Each memory string 212 extends through the dielectric film stack 445 of alternating dielectric layer pairs, and includes a memory film 337 over the inner surface of memory strings 212 , a channel layer 338 over the memory film 337 , and a core filling film 339 surrounded by the channel layer 338 .
- FIG. 9 illustrates a cross-sectional view of an exemplary structure 900 of a three dimensional memory device (along WL direction), according to some embodiments, wherein the sacrificial layers 452 are removed and a plurality of horizontal tunnels 970 are formed.
- a plurality of slit structure openings can be formed along WL directions (see FIGS. 2A-2B and FIG. 3 ). These slit structure openings extend through the dielectric film stack 445 .
- the sacrificial layers 452 can then be removed from the openings of the slit structures 216 along BL direction (perpendicular to WL direction, e.g., perpendicular to the cross-section shown in FIG. 9 ).
- the sacrificial layers 452 can be removed by any suitable etching process, e.g., an isotropic dry etch or wet etch, that is selective over the dielectric layers 450 , such that the etching process can have minimal impact on the dielectric layer 450 .
- the sacrificial layer 452 can be silicon nitride.
- the sacrificial layer 452 can be removed by RIE using one or more etchants of CF 4 , CHF 3 , C 4 F 8 , C 4 F 6 , and CH 2 F 2 .
- the sacrificial layer 452 can be removed using wet etch, such as phosphoric acid.
- FIG. 10 illustrates a cross-sectional view of an exemplary structure 1000 of a three dimensional memory device, according to some embodiments, wherein the structure 1000 includes the film stack 335 of alternating conductive and dielectric layers (e.g., corresponding to the film stack 335 in FIG. 3 ).
- the film stack 335 of alternating conductive and dielectric layers includes conductive layers 1072 sandwiched between the dielectric layers 450 .
- each staircase step 1076 includes two or more conductive and dielectric layer pairs 1074 , each conductive and dielectric layer pair 1074 having one conductive layer 1072 and one dielectric layer 450 .
- FIG. 10 illustrates a cross-sectional view of an exemplary structure 1000 of a three dimensional memory device, according to some embodiments, wherein the structure 1000 includes the film stack 335 of alternating conductive and dielectric layers (e.g., corresponding to the film stack 335 in FIG. 3 ).
- the film stack 335 of alternating conductive and dielectric layers includes conductive layers 1072 sandwiche
- each staircase step 1076 includes two conductive and dielectric layer pairs 1074 - 1 and 1074 - 2 , referred to as an “upper layer pair” and a “lower layer pair”, respectively.
- the dielectric staircase 560 with alternating dielectric and sacrificial layers is now changed into a staircase structure 1060 with alternating conductive and dielectric layers.
- the conductive layer 1072 can include any suitable conductive material that is suitable for a gate electrode, e.g., tungsten (W), aluminum (Al), copper (Cu), cobalt (Co), titanium (Ti), tantalum (Ta), titanium nitride (TiN), tantalum nitride (TaN), and/or any combination thereof.
- the conductive material can fill the horizontal tunnel 970 using a suitable deposition method such as CVD, physical vapor deposition (PVD), plasma-enhanced CVD (PECVD), sputtering, thermal evaporation, e-beam evaporation, metal-organic chemical vapor deposition (MOCVD), and/or ALD.
- the conductive layers 1072 include tungsten (W) deposited by CVD.
- the conductive layer 1072 can also be poly-crystalline semiconductors, such as poly-crystalline silicon, poly-crystalline germanium, poly-crystalline germanium-silicon and any other suitable material, and/or combinations thereof.
- the poly-crystalline material can be incorporated with any suitable types of dopant, such as boron, phosphorous, or arsenic.
- the conductive layer 1072 can also be amorphous semiconductors.
- the conductive layer 1072 can be made from a metal silicide, including WSi x , CoSi x , NiSi x , or AlSi x , etc.
- the forming of the metal silicide material can include forming a metal layer and a poly-crystalline semiconductor using similar techniques described above.
- the forming of metal silicide can further include applying a thermal annealing process on the deposited metal layer and the poly-crystalline semiconductor layer, followed by removal of unreacted metal.
- a gate dielectric layer can be disposed in the horizontal tunnels 970 prior to the conductive layer 1072 (not shown in FIG. 10 ) to reduce leakage current between adjacent word lines (gate electrodes) and/or to reduce leakage current between gate and channel.
- the gate dielectric layer can include silicon oxide, silicon nitride, silicon oxynitride, and/or any suitable combinations thereof.
- the gate dielectric layer can also include high-k dielectric materials, such as hafnium oxide, zirconium oxide, aluminum oxide, tantalum oxide, lanthanum oxide, and/or any combination thereof.
- the gate dielectric layer can be disposed by one or more suitable deposition processes, such as CVD, PVD, and/or ALD.
- the conductive layers 1072 function as gate electrodes at the intersection with memory strings 212 .
- the ten conductive layers 1072 can form ten gate electrodes for each memory string 212 , e.g., TSG 334 , LSG 332 and eight control gates 333 .
- each memory string 212 can have eight memory cells 340 . It is noted that the number of memory strings and memory cells are shown for illustrative purposes in FIG. 10 , and can be increased for higher storage capacity.
- conductive materials can be removed and insulating materials can be deposited in the openings to form slit structures 216 , separating a memory block into multiple programmable and readable memory fingers (see FIG. 2A-2B ).
- the doped source line regions 344 in portions of substrate 330 can be formed using techniques such as ion implantation (see FIG. 3 ).
- a conductive core can be inserted in the slit structure 216 to form common source contact to the doped source line region 344 .
- Structure 1000 can include other structures, for example, through array contact (TAC), TSG cut, common source contact and dummy channel structure, which are not shown in FIG. 10 for simplicity.
- TAC array contact
- TSG cut common source contact
- dummy channel structure which are not shown in FIG. 10 for simplicity.
- FIG. 11 illustrates a cross-sectional view of an exemplary structure 1100 of a three dimensional memory device, according to some embodiments, wherein the structure 1100 includes a plurality of first contact holes 1180 in the first insulating layer 768 with a diameter of “d 1 ”.
- one first contact hole 1180 is shown for each staircase step 1076 , which is only for illustrative purpose. Multiple first contact holes 1180 can be formed on each staircase step 1076 . In some embodiments, there are no first contact holes 1180 on dummy staircase levels.
- photoresist or polymer material can be used as a mask layer to etch the first contact holes 1180 .
- depth “H” of the first contact hole 1180 from the top surface to staircase step depends on the location of each step.
- the first contact holes 1180 for the lower staircase steps can be much deeper than the first contact holes 1180 for the upper staircase steps. Therefore, the first contact hole 1180 for the staircase step 1076 closer to the surface 330 f of the substrate 330 requires longer etch time than the first contact hole 1180 for the staircase step 1076 away from the surface 330 f of the substrate 330 .
- a selective etching process can be used such that the etching rate of the first insulating layer 768 is higher than the conductive layer 1072 and/or the barrier layer 664 .
- the barrier layer 664 can function as an etch-stop layer and can protect the underlying structure until all the first contact holes 1180 are formed on top of the barrier layer 664 for all levels of the staircase structure 1060 . And then the portions of the barrier layer 664 inside the first contact holes 1180 can be removed using the same mask layer. In some embodiments, when a gate dielectric layer is disposed on the conductive layer 1072 , the etching also includes removing the gate dielectric layer inside the first contact holes 1180 .
- the first contact holes 1180 extend through the first insulating layer 768 , the barrier layer 664 , and the optional gate dielectric layer, exposing a portion of the conductive layer 1072 of the upper layer pair 1074 - 1 in each staircase step 1076 .
- the first insulating layer 768 is silicon oxide and the barrier layer is a combination of silicon nitride and silicon oxide.
- etching silicon oxide can use anisotropic RIE with chemical etchant, for example, CF 4 , CHF 3 , C 2 F 6 , C 3 F 6 , and/or any combination thereof.
- Etching silicon nitride can use RIE with chemical etchant, for example, O 2 , N 2 , CF 4 , NF 3 , Cl 2 , HBr, BCl 3 , and/or combinations thereof.
- the diameter “d 1 ” of the first contact holes 1180 is preferably smaller than the lateral dimension “a” of the staircase structure 1060 , and will be discussed in detail in the subsequent processes.
- FIG. 12 illustrates a cross-sectional view of an exemplary structure 1200 of a three dimensional memory device, according to some embodiments, wherein the structure 1200 includes a conductive film 1282 , disposed over the structure 1100 .
- the conductive film 1282 inside the first contact hole 1180 is in direct contact with the conductive layer 1072 of the upper layer pair 1074 - 1 .
- the conductive film 1282 also covers a sidewall of the first contact hole 1180 .
- the thickness “t 1 ” of the conductive film 1282 at the bottom of the first contact hole 1180 can be the same or different from the thickness “t 2 ” on the sidewall.
- the height of the conductive film 1282 inside the first contact hole 1180 is determined by the depth “H” of the first contact hole 1180 .
- the conductive film 1282 can include any suitable conductive material, for example, a metal or metallic compound such as tungsten (W), aluminum (Al), copper (Cu), cobalt (Co), titanium (Ti), tantalum (Ta), titanium nitride (TiN), tantalum nitride (TaN), and/or any combination thereof.
- a metal or metallic compound such as tungsten (W), aluminum (Al), copper (Cu), cobalt (Co), titanium (Ti), tantalum (Ta), titanium nitride (TiN), tantalum nitride (TaN), and/or any combination thereof.
- the metal or metallic compound can be disposed using a suitable deposition method such as CVD, PVD, PECVD, sputtering, thermal evaporation, e-beam evaporation, MOCVD, and/or ALD.
- the conductive film 1282 can also be a metal silicide, including WSix, CoSix, NiSix, or AlSix, etc.
- Metal silicide material can be formed by disposing a metal layer directly on a polycrystalline silicon layer inside the first contact hole 1180 and then applying a thermal annealing process followed by removal of unreacted metal.
- the conductive film 1282 includes a combination of TiN/W/TiN deposited by CVD.
- FIG. 13 illustrates a cross-sectional view of an exemplary structure 1300 of a three dimensional memory device, according to some embodiments, wherein the structure 1300 includes a plurality of conductive rings 1384 and a plurality of ring openings 1386 .
- the conductive ring 1384 covers a sidewall of the first insulating layer 768 . Bottom of the conductive ring 1384 contacts the conductive layer 1072 of the upper layer pair 1074 - 1 .
- the conductive ring 1384 can be formed by removing the conductive film 1282 and the conductive layer 1072 from the bottom of the ring openings 1386 using anisotropic etching, such as anisotropic RIE.
- anisotropic etching such as anisotropic RIE.
- the conductive film 1282 and the conductive layer 1072 of the staircase structure 1060 can be tungsten.
- the anisotropic etching to form the conductive ring 1384 can include dry etching, for example ME with a mixture of O 2 and CF 4 , CClF 3 , or CBrF 3 .
- Anisotropic RIE can include low-pressure plasma system to increase mean-free path of the ions and reduce random scattering.
- the ions strike the structure 1300 in a vertical direction, perpendicular to the top surface 330 f of the substrate 330 .
- the height “H” (shown in FIG. 12 ) of the conductive film 1282 can be greater than the total thickness of “t 1 ” at the bottom of the first contact holes 1180 and the thickness of the conductive layer 1072 . Therefore, the conductive film 1282 and the conductive layer 1072 at the bottom of the first contact holes 1180 can be removed, while there is remaining conductive film on the sidewall of the first contact hole 1180 , forming the conductive ring 1384 .
- the thickness “t 3 ” of the conductive ring 1384 depends on the initial sidewall thickness “t 2 ” of the conductive film 1282 , as well as the sidewall profile of the first contact holes 1180 .
- the thickness “t 3 ” can further depend on the RIE process conditions, for example, total etch time, ion direction angle, pressure, DC bias voltage and RF power, etc.
- the conductive ring 1384 with a greater thickness “t 3 ” is preferred.
- trade-off between memory performance and area is needed for a limited diameter “d 1 ” of the first contact holes 1180 .
- the ring openings 1386 extend through the conductive layer 1072 of the upper layer stack 1074 - 1 , with a smaller diameter “d 2 ” than the diameter “d 1 ” of the first contact holes 1180 , as shown in FIG. 13 .
- FIG. 14 illustrates a cross-sectional view of an exemplary structure 1400 of a three dimensional memory device, according to some embodiments, wherein the structure 1400 includes a second insulating layer 1488 disposed over the structure 1300 .
- the second insulating layer 1488 covers the exposed conductive materials inside the ring openings 1386 , e.g., the conductive ring 1384 and sidewalls of the conductive layer 1072 of the upper layer pair 1074 - 1 for each staircase step 1076 .
- the second insulating layer 1488 can be made of a similar material as the first insulating layer 768 and used a similar deposition technique.
- FIG. 15 illustrates a cross-sectional view of an exemplary structure 1500 of a three dimensional memory device, according to some embodiments, wherein the structure 1500 includes a plurality of insulating rings 1590 and a plurality of second contact holes 1592 .
- the insulating rings 1590 can be formed by etching portions of the second insulating layer 1488 and the dielectric layer 450 from the bottom of the ring openings 1386 on structure 1400 (in FIG. 14 ), wherein the layer 1488 and 450 can be etched using an anisotropic etching, similar to the technique used for forming the conductive ring 1384 except using a different etchant for the dielectric material.
- the second insulating layer 1488 can be silicon oxide.
- the etching of silicon oxide can include RIE using fluorine based gases, for example, carbon-fluorine (CF 4 ), hexafluoroethane (C 2 F 6 ), CHF 3 , or C 3 F 6 and/or any other suitable gases.
- fluorine based gases for example, carbon-fluorine (CF 4 ), hexafluoroethane (C 2 F 6 ), CHF 3 , or C 3 F 6 and/or any other suitable gases.
- the second contact hole 1592 extends through the second insulating layer 1488 and the dielectric layer 450 of the upper layer pair 1074 - 1 for each staircase step 1076 , exposing the conductive layer 1072 of the lower layer pair 1074 - 2 .
- FIG. 16A illustrates a cross-sectional view of an exemplary structure 1600 of a three dimensional memory device, according to some embodiments, wherein the structure 1600 includes a plurality of conductive cores 1694 .
- the conductive core 1694 can be made of any suitable conductive materials and can be similar to the conductive film 1282 , forming by a similar technique.
- the conductive material for the conductive core 1694 can be disposed over the structure 1500 , filling the second contact hole 1592 .
- the conductive core 1694 directly contacts with the conductive layer 1072 of the lower layer pair 1074 - 2 of each staircase step 1076 .
- a planarization process such as CMP, can be used to remove any conductive materials on the top surface 768 S of the first insulating layer 768 .
- FIG. 16B illustrates a perspective view of the structures 1600 , wherein the insulating and dielectric layers are omitted for clarity.
- the conductive ring 1384 and the conductive core 1694 form a coaxial contact structure 1696 on the staircase structure 1060 .
- the staircase step 1076 of the staircase structure 1060 includes two conductive and dielectric layer pairs, the upper layer pair 1074 - 1 and the lower layer pair 1074 - 2 .
- the conductive ring 1384 can be electrically connected to the conductive layer 1072 of the upper layer pair 1074 - 1 of the staircase step 1076 .
- the conductive core 1694 can be electrically connected to the conductive layer 1072 of the lower layer pair 1074 - 2 of the staircase step 1076 .
- the conductive ring 1384 and the insulating ring 1590 form a conductive and insulating ring pair 1697 , corresponding to one of the conductive and dielectric layer pairs of the staircase step 1076 .
- FIG. 17A-17D shows another embodiment of the contact structures for the gate electrodes of a three dimensional memory device.
- a portion of the contact structure and staircase structure are illustrated as an example. Similar elements are labeled with the same reference numbers to compare with the corresponding elements in FIG. 13-16A .
- the etching process can be performed longer to form a first contact hole 1786 , wherein the first contact hole 1786 can extend further through the dielectric layer 450 of the upper layer pair 1074 - 1 in the staircase step 1076 , exposing the conductive layer 1072 of the lower layer pair 1074 - 2 (see structure 1710 in FIG. 17A ).
- FIG. 17B shows a cross-sectional view of an exemplary structure 1720 of a three dimensional memory device, according to some embodiments, wherein the structure 1720 includes the second insulating layer 1488 disposed over the structure 1710 on the conductive ring 1384 , a sidewall of the dielectric layer 450 and the exposed portion of the conductive layer 1072 of the lower layer pair 1074 - 2 of the staircase step 1076 .
- FIG. 17C shows a cross-sectional view of an exemplary structure 1730 of a three dimensional memory device, according to some embodiments, wherein the structure 1730 includes an insulating spacer 1790 and a contact hole 1792 , wherein the contact hole 1792 extends through the second insulating layer 1488 at the bottom, exposing the conductive layer 1072 of the lower layer pair 1074 - 2 of the staircase step 1076 .
- FIG. 17D shows a cross-sectional view of an exemplary structure 1740 of a three dimensional memory device, according to some embodiments, wherein the structure 1740 includes a conductive core 1794 , wherein the conductive core 1974 can be made from a similar material as the conductive core 1694 and formed by a similar technique.
- a coaxial contact structure 1796 similar to the coaxial contact structures 1696 is formed.
- the electrical conductive path for the gate electrode of each memory cell can be wired up to the surface of the wafer, enabling various configurations of word lines and select gates for the 3D memory in the back-of-line process.
- fabrication of 3D memory device can be resumed with back-end-of-line (BEOL) metal interconnects, and are known to a person with ordinary skill in the art.
- BEOL back-end-of-line
- a second session of word line stack can be added to the structure 1600 / 1740 to further increase the vertical number of memory cells.
- the staircase structure 1060 can include a plurality of staircase steps 1076 , each staircase step 1076 having N number of conductive and dielectric layer pairs 1697 , wherein N is a whole number no less than two. In this example, there can be N ⁇ 1 number of conductive and insulating ring pairs 1697 in addition to a conductive core 1694 .
- Each conductive and insulating ring pair 1697 includes one conductive ring 1384 and one insulating ring 1590 , wherein the insulating ring 1590 is disposed to surround a sidewall of the conductive ring 1384 and is configured to electrically isolate the conductive ring 1384 from another conductive ring 1384 or the conductive core 1694 .
- the conductive core 1694 is located in the center of the coaxial contact structure 1696 .
- the conductive core 1694 can also include an insulating core that fills possible seams or holes in the conductive core 1694 .
- the conductive core 1694 and the conductive rings 1384 can be arranged so that the conductive rings 1384 make electrical contact with the conductive layer 1072 of a corresponding conductive and dielectric layer pair 1697 of the staircase step 1076 .
- An outer conductive ring with a larger diameter can connect to the conductive layer 1072 of an upper conductive and dielectric layer pair of the staircase step 1076 .
- An inner conductive ring with a smaller diameter can connect to the conductive layer 1072 of a lower conductive and dielectric layer pair of the staircase step 1076 .
- the upper conductive and dielectric layer pair is farther away from the substrate, whereas the lower conductive and dielectric layer pair is closer to the substrate.
- the conductive core 1694 can connect to the bottommost conductive layer, e.g., the pair closest to the substrate, within the staircase step 1076 of N number of conductive and dielectric layer pairs.
- the conductive rings 1384 extend through the first insulating layer 768 to contact the conductive layer 1072 of the staircase structure 1060 . In some embodiments, the conductive rings 1384 also extend through the barrier layer 664 to contact the conductive layer 1072 of the staircase structure 1060 . In some embodiments, a gate dielectric layer can be disposed on the conductive layer 1072 . In this example, the conductive rings 1384 extend further through the gate dielectric layer to contact the conductive layer of the staircase structure 1060 .
- the insulating ring 1590 of the conductive and insulating ring pair 1697 can be disposed to surround a sidewall of the conductive layer of the staircase structure in addition to the sidewall of the conductive ring. In some embodiments, the insulating ring can be disposed on a sidewall of the dielectric layer of the staircase step of N number of conductive and dielectric layer pairs (similar to the structure shown in FIG. 17D ).
- the number of staircase steps can be reduced and thereby the overall lateral dimension of the staircase structure can be reduced. Accordingly the area of staircase region 210 (shown in FIG. 2A ) can be greatly reduced, and higher density memory storage can be achieved.
- FIG. 18 illustrates an exemplary method 1800 for forming staircase and contact structures for a three-dimensional memory array, according to some embodiments.
- the process steps of the method 1800 can be used to form memory device structures illustrated in FIGS. 4-16A .
- the process steps shown in method 1800 are not exhaustive and other process steps can be performed as well before, after, or between any of the illustrated process steps.
- some process steps of exemplary method 1800 can be omitted or include other process steps that are not described here for simplicity.
- process steps of method 1800 can be performed in a different order and/or vary.
- a dielectric film stack is disposed on a substrate.
- the dielectric film stack can be the dielectric film stack 445 in FIG. 4 , with alternating dielectric (first dielectric) and sacrificial (second dielectric) layers.
- the dielectric and sacrificial layers are similar to the dielectric layer 450 and the sacrificial layer 452 in FIG. 4 and can be disposed using a similar technique.
- the dielectric layer and the sacrificial layer below are called an alternating dielectric layer pair.
- a dielectric staircase is formed in the dielectric film stack.
- An example of the dielectric staircase is shown as the dielectric staircase 560 in FIG. 5 , wherein the dielectric staircase includes a plurality of staircase layers, e.g., staircase steps. Each staircase step includes two or more alternating dielectric layer pairs.
- FIG. 5 depicts a dielectric staircase with two alternating dielectric layer pairs.
- the plural steps of the dielectric staircase can be formed by applying a repetitive etch-trim process on the dielectric film stack. First, a patterning mask is disposed and patterned on the dielectric film stack.
- portions of the dielectric film stack can be exposed and etched in a direction perpendicular to a main surface of the substrate until portions of the two dielectric layer pairs are removed.
- the patterning mask is trimmed laterally, in a direction parallel to the main surface of the substrate. The etching and trimming processes can be repeated until a dielectric staircase step closest to the main surface of the substrate is formed. Finally, the patterning mask can be removed.
- a barrier layer is disposed over the dielectric staircase, wherein the barrier layer can be the barrier layer 664 in FIG. 6 and can be made of a similar material and formed using a similar technique.
- a first insulating layer is disposed over the dielectric staircase.
- the first insulating layer is disposed on the barrier layer.
- the first insulating layer can be the first insulating layer 768 in FIG. 7 .
- a planarization process such as chemical mechanical polishing (CMP) or reaction-ion-etching, can be performed to form a coplanar surface. An example of the structure is shown in FIG. 7 .
- a plurality of memory strings are formed in the dielectric film stack with alternating dielectric layer pairs.
- the memory string is similar to the memory string 212 in FIG. 8 , and includes a memory film, a channel layer and a core filling film.
- the dielectric film stack of alternating dielectric layer pairs is patterned to form a plurality of slit openings.
- the slit openings extend horizontally along the dielectric staircase and extend vertically through the dielectric film stack.
- the sacrificial layers of the dielectric staircase are removed horizontally from the slit openings to form a plurality of horizontal tunnels in the staircase structure.
- the memory film of the memory strings are exposed inside the plurality of tunnels.
- FIG. 9 shows an example of the structure after removing the sacrificial layers.
- conductive materials are disposed inside the horizontal tunnels, forming a staircase structure with alternating conductive and dielectric layers, which is similar to the staircase structure 1060 in FIG. 10 .
- the conductive layer can be made of a similar material as the conductive layer 1072 and can be disposed using a similar technique.
- a gate dielectric layer can be disposed on sidewalls of the horizontal tunnels prior to the conductive layer deposition, wherein the gate dielectric layer includes high-k dielectric material, silicon oxide, silicon nitride or silicon oxynitride.
- the staircase structure include a plurality of staircase steps, each having two conductive and dielectric layer pairs, e.g., upper layer pair and lower layer pair.
- the first insulating layer is patterned, forming a plurality of first contact holes.
- the first contact holes extend through the first insulating layer and the optional barrier layer and expose the conductive layer of upper layer pair of the staircase step.
- the first contact holes 1180 in FIG. 11 is an example of the plurality of first contact holes.
- a conductive film is disposed over the staircase structure.
- the conductive film is disposed on the exposed portion of the conductive layer of the staircase structure and also on a sidewall of the first contact hole.
- the conductive film can be the conductive film 1282 in FIG. 12 , and can be disposed using a similar technique.
- the conductive film at the bottom of the first contact holes is removed through anisotropic etching, forming conductive rings along a sidewall of the first insulating layer.
- Examples of the conductive rings are shown in FIG. 13 as the conductive rings 1384 .
- the conductive rings can be made of a similar material as the conductive rings 1384 and be formed using a similar technique.
- a second insulating layer is disposed over the staircase structure on the conductive rings.
- the second insulating layer is similar to the second insulating layer 1488 in FIG. 14 and can be made of a similar material using a similar technique.
- a plurality of insulating rings are formed by anisotropic etching of the second insulating layer.
- the insulating ring surrounds a sidewall of the conductive ring as well as an exposed portion of the conductive layer of the upper layer pair in the staircase step.
- the dielectric layer of the upper layer pair can also be removed and the conductive layer of the lower layer pair can be exposed.
- a plurality of second contact holes are formed accordingly.
- An example of the insulating rings and second contact holes is shown in FIG. 15 , as the insulating rings 1590 and the second contact hole 1592 .
- a plurality of conductive cores are formed inside the second contact holes.
- the conductive core contact the conductive layer of the lower layer pair in the staircase step.
- the conductive core can be the conductive core 1694 in FIG. 16 , and can be formed using a similar technique.
- a planarization process for example CMP, can be used to form a coplanar surface. From top down, the conductive ring, insulating ring and the conductive core form a coaxial contact structure.
- the coaxial contact structures can provide electrical connections to each of the conductive layer of the staircase structure. With two conductive and dielectric layer pairs per staircase step, the number of contact structures can be reduced to half, saving the area of staircase region. From these coaxial contact structures, back-end-of-line processes can be resumed with metal interconnect lines to form a functional 3D NAND memory.
- the staircase structure 1060 can include a plurality of staircase steps 1076 , each staircase step 1076 having N number of conductive and dielectric layer pairs 1697 , wherein N is a whole number no less than two.
- N there can be N ⁇ 1 number of conductive and insulating ring pairs 1697 in addition to a conductive core 1694 .
- N ⁇ 1 number of conductive and insulating ring pairs and the conductive core can be formed using similar processes as described in process steps 1845 - 1870 .
- a first contact hole can be formed to expose a conductive layer in one of the N number of conductive and dielectric layer pairs of the staircase step in the staircase structure. Then a conductive film can be disposed on a sidewall of the contact hole and the exposed conductive layer. Next, the conducive film and a portion of the conductive layer from the bottom of the first contact hole can be removed to form a conductive ring, wherein a bottom of the conductive ring is formed to contact the conductive layer in one of the N number of conductive and dielectric layer pairs of the staircase step in the staircase structure. In some embodiments, the dielectric layer of the next conductive and dielectric layer pair can also be removed during the etching process for the conductive ring.
- a second insulating layer can be disposed in the first contact hole and the second insulating layer can then be removed from the bottom of the first contact hole to form an insulating ring, thereby surrounding a sidewall of the conductive ring and a sidewall of the conductive layer is exposed in the first contact hole.
- the cyclic processes for the next conductive and insulating ring pairs resume, starting by forming a second contact hole to expose the next conductive layer in the staircase step, etc.
- the conductive core of the coaxial contact structure can be formed last. After forming a contact hole to expose the bottommost conductive layer, e.g., closest to the substrate, in the staircase step of N number of conductive and dielectric layer pairs, a conductive material can be disposed to fill the contact hole, and a conductive core can be formed to contact the bottommost conductive layer using a planarization process, such as chemical mechanical polishing. The conductive material outside the contact hole can be removed and the structure can be formed with a coplanar surface.
- a staircase structure is formed with a plurality of staircase steps, each step having N number of conductive layers.
- a plurality of coaxial contact structures are formed on the staircase structure.
- Each coaxial contact structure can provide N number of conductive paths to connect to the N number of the conductive layers, and to the word lines for the vertically stacked memory strings.
- Various embodiments in accordance with the present disclosure provide a 3D memory device with smaller die size, higher device density, and improved performance compared with other 3D memory devices.
- the three-dimensional memory structure includes a film stack disposed on a substrate, wherein the film stack includes a plurality of conductive and dielectric layer pairs, each conductive and dielectric layer pair having a conductive layer and a first dielectric layer.
- the three-dimensional memory structure also includes a staircase structure formed in the film stack, wherein the staircase structure includes a plurality of steps, each staircase step having two or more conductive and dielectric layer pairs.
- the three-dimensional memory structure further includes a plurality of coaxial contact structures formed in a first insulating layer over the staircase structure, wherein each coaxial contact structure includes one or more conductive and insulating ring pairs and a conductive core, wherein each conductive and insulating ring pair includes a conductive ring and an insulating ring.
- a method for forming a three-dimensional memory structure includes disposing a dielectric film stack on a substrate, wherein the dielectric film stack includes a plurality of alternating dielectric layer pairs, each alternating dielectric layer pair having a first dielectric layer and a second dielectric layer different from the first dielectric layer.
- the method also includes forming a dielectric staircase in the dielectric film stack, wherein the dielectric staircase includes a plurality of steps, each dielectric staircase step having two or more alternating dielectric layer pairs.
- the method further includes disposing a first insulating layer on the dielectric staircase, forming a plurality of memory strings in the dielectric film stack, and replacing the second dielectric layers with conductive layers to form a staircase structure with a plurality of steps, wherein each staircase step includes two or more conductive and dielectric layer pairs, each conductive and dielectric layer pair having a conductive layer and the first dielectric layer.
- the method also includes forming a plurality of coaxial contact structures on the staircase structure.
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Abstract
Description
- This application claims priority to PCT/CN2018/120715 filed on Dec. 12, 2018, which is incorporated herein by reference in its entirety.
- The present disclosure generally relates to the field of semiconductor technology, and more particularly, to a method for forming a three-dimensional (3D) memory.
- Planar memory cells are scaled to smaller sizes by improving process technology, circuit designs, programming algorithms, and the fabrication process. However, as feature sizes of the memory cells approach a lower limit, planar process and fabrication techniques become challenging and costly. As such, memory density for planar memory cells approaches an upper limit. A three-dimensional (3D) memory architecture can address the density limitation in planar memory cells.
- Embodiments of contact structures for a three-dimensional memory device and methods for forming the same are described in the present disclosure.
- In some embodiments, a three-dimensional memory structure includes a film stack disposed on a substrate, wherein the film stack includes a plurality of conductive and dielectric layer pairs, each conductive and dielectric layer pair having a conductive layer and a first dielectric layer. The three-dimensional memory structure also includes a staircase structure formed in the film stack, wherein the staircase structure includes a plurality of steps, each staircase step having two or more conductive and dielectric layer pairs. The three-dimensional memory structure further includes a plurality of coaxial contact structures formed in a first insulating layer over the staircase structure, wherein each coaxial contact structure includes one or more conductive and insulating ring pairs and a conductive core, wherein each conductive and insulating ring pair includes a conductive ring and an insulating ring.
- In some embodiments, each conductive ring contacts the conductive layer of a corresponding conductive and dielectric layer pair of the staircase step.
- In some embodiments, each coaxial contact structure comprises at least an outer conductive ring and an inner conductive ring, and the outer conductive ring corresponds with an upper conductive and dielectric layer pair of the staircase step, wherein the outer conductive ring includes larger diameter, and the upper conductive and dielectric layer pair is farther away from the substrate.
- In some embodiments, each coaxial contact structure comprises at least an outer conductive ring and an inner conductive ring, and the inner conductive ring corresponds with a lower conductive and dielectric layer pair of the staircase step, wherein the inner conductive ring includes smaller diameter, and the lower conductive and dielectric layer pair is closer to the substrate.
- In some embodiments, the conductive core contacts the conductive layer closest to the substrate in the staircase step of two or more conductive and dielectric layer pairs.
- In some embodiments, the insulating ring of the conductive and insulating ring pair is disposed to surround a sidewall of the conductive ring and a sidewall of the conductive layer of the staircase structure, wherein the insulating ring is configured to electrically isolate the conductive ring from another conductive ring or the conductive core.
- In some embodiments, the insulating ring is disposed on a sidewall of the first dielectric layer of the staircase step of two or more conductive and dielectric layer pairs.
- In some embodiments, the three-dimensional memory structure further includes a barrier layer, disposed between the first insulating layer and the staircase structure, and the plurality of coaxial contact structures extending through the barrier layer.
- In some embodiments, the three-dimensional memory structure further includes a gate dielectric layer on the conductive layer, and the conductive rings extending through the gate dielectric layer to contact the conductive layers of the staircase structure.
- Another aspect of the present disclosure provides a method for forming a three-dimensional (3D) memory device. A method for forming a three-dimensional (3D) memory structure includes disposing a dielectric film stack on a substrate, wherein the dielectric film stack includes a plurality of alternating dielectric layer pairs, each alternating dielectric layer pair having a first dielectric layer and a second dielectric layer different from the first dielectric layer. The method also includes forming a dielectric staircase in the dielectric film stack, wherein the dielectric staircase includes a plurality of steps, each dielectric staircase step having two or more alternating dielectric layer pairs. The method further includes disposing a first insulating layer on the dielectric staircase, forming a plurality of memory strings in the dielectric film stack, and replacing the second dielectric layers with conductive layers to form a staircase structure with a plurality of steps, wherein each staircase step includes two or more conductive and dielectric layer pairs, each conductive and dielectric layer pair having a conductive layer and the first dielectric layer. The method also includes forming a plurality of coaxial contact structures on the staircase structure.
- In some embodiments, forming the coaxial contact structure includes forming a conductive and insulating ring pair for each conductive and dielectric layer pair of the staircase step in the staircase structure.
- In some embodiments, forming the conductive ring includes forming a first contact hole to expose the conductive layer in one of the two or more conductive and dielectric layer pairs of the staircase step in the staircase structure, disposing a conductive film on a sidewall of the contact hole and the exposed conductive layer, and removing the conducive film and a portion of the conductive layer from the bottom of the first contact hole to form a conductive ring, wherein a bottom of the conductive ring is formed to contact the conductive layer in one of the two or more conductive and dielectric layer pairs of the staircase step in the staircase structure.
- In some embodiments, forming the conductive ring further includes etching the dielectric layer of the next conductive and dielectric layer pair.
- In some embodiments, forming the insulating ring includes disposing a second insulating layer in a first contact hole, and removing the second insulating layer from the bottom of the first contact hole. Forming the insulating ring also includes forming the insulating ring surrounding a sidewall of the conductive ring and a sidewall of the conductive layer of one of the two or more conductive and dielectric layer pairs in the staircase step in the staircase structure, and forming a second contact hole to expose the next conductive layer in the staircase step.
- In some embodiments, forming the coaxial contact structure further includes forming a contact hole to expose the conductive layer closest to the substrate in the staircase step of two or more conductive and dielectric layer pairs, disposing a conductive material to fill the contact hole, and forming a conductive core to contact the conductive layer closest to the substrate in staircase step of two or more conductive and dielectric layer pairs.
- In some embodiments, the method further includes performing a planarization process to remove the conductive material outside the contact hole and form a coplanar surface.
- In some embodiments, the method further includes disposing a barrier layer on the dielectric staircase prior to the first insulating layer.
- In some embodiments, forming the plurality of dielectric staircase steps includes disposing a patterning mask on the dielectric film stack, and etching exposed portions of the dielectric film stack in a direction perpendicular to a main surface of the substrate until portions of the two or more dielectric layer pairs are removed. Forming the plurality of dielectric staircase steps also includes trimming the patterning mask laterally, in a direction parallel to the main surface of the substrate, repeating the etching and the trimming processes until a dielectric staircase step closest to the main surface of the substrate is formed, and removing the patterning mask.
- In some embodiments, replacing the second dielectric layers with the conductive layers to form the staircase structure, includes forming one or more slit structure openings, extending horizontally along the dielectric staircase, wherein the slit structure openings penetrate vertically through the dielectric film stack. Replacing the second dielectric layers also includes removing the second dielectric layers of the dielectric staircase to form a plurality of horizontal tunnels, and disposing the conductive layers inside the plurality of horizontal tunnels.
- In some embodiments, the method further includes disposing a gate dielectric layer on sidewalls of the horizontal tunnels prior to disposing the conductive layer, wherein the gate dielectric layer includes high-k dielectric material, silicon oxide, silicon nitride or silicon oxynitride.
- Other aspects of the present disclosure can be understood by those skilled in the art in light of the description, the claims, and the drawings of the present disclosure.
- The accompanying drawings, which are incorporated herein and form a part of the specification, illustrate embodiments of the present disclosure and, together with the description, further serve to explain the principles of the present disclosure and to enable a person skilled in the pertinent art to make and use the present disclosure.
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FIG. 1 illustrates a schematic top-down view of an exemplary three-dimensional (3D) memory die, according to some embodiments of the present disclosure. -
FIG. 2A-2B illustrate schematic top-down views of some regions of 3D memory die, according to some embodiments of the present disclosure. -
FIG. 3 illustrates a perspective view of a portion of an exemplary 3D memory array structure, in accordance with some embodiments of the present disclosure. -
FIG. 4-15 illustrate schematic cross-sectional views of an exemplary 3D memory structure at certain fabricating stages, according to some embodiments of the present disclosure. -
FIG. 16A illustrates a schematic cross-sectional view of an exemplary 3D memory structure at a certain fabricating stage, according to some embodiments of the present disclosure. -
FIG. 16B illustrates a perspective view of a portion of an exemplary 3D memory structure at a certain fabricating stage, according to some embodiments of the present disclosure. -
FIG. 17A-17D illustrate schematic cross-sectional views of an exemplary 3D memory structure at certain fabricating stages, according to some embodiments of the present disclosure. -
FIG. 18 illustrates a flow diagram of an exemplary method for forming a 3D memory structure, according to some embodiments of the present disclosure. - The features and advantages of the present invention will become more apparent from the detailed description set forth below when taken in conjunction with the drawings, in which like reference characters identify corresponding elements throughout. In the drawings, like reference numbers generally indicate identical, functionally similar, and/or structurally similar elements. The drawing in which an element first appears is indicated by the leftmost digit(s) in the corresponding reference number.
- Embodiments of the present disclosure will be described with reference to the accompanying drawings.
- Although specific configurations and arrangements are discussed, it should be understood that this is done for illustrative purposes only. A person skilled in the pertinent art will recognize that other configurations and arrangements can be used without departing from the spirit and scope of the present disclosure. It will be apparent to a person skilled in the pertinent art that the present disclosure can also be employed in a variety of other applications.
- It is noted that references in the specification to “one embodiment,” “an embodiment,” “an example embodiment,” “some embodiments,” etc., indicate that the embodiment described can include a particular feature, structure, or characteristic, but every embodiment can not necessarily include the particular feature, structure, or characteristic. Moreover, such phrases do not necessarily refer to the same embodiment. Further, when a particular feature, structure or characteristic is described in connection with an embodiment, it would be within the knowledge of a person skilled in the pertinent art to affect such feature, structure or characteristic in connection with other embodiments whether or not explicitly described.
- In general, terminology can be understood at least in part from usage in context. For example, the term “one or more” as used herein, depending at least in part upon context, can be used to describe any feature, structure, or characteristic in a singular sense or can be used to describe combinations of features, structures or characteristics in a plural sense. Similarly, terms, such as “a,” “an,” or “the,” again, can be understood to convey a singular usage or to convey a plural usage, depending at least in part upon context. In addition, the term “based on” can be understood as not necessarily intended to convey an exclusive set of factors and may, instead, allow for existence of additional factors not necessarily expressly described, again, depending at least in part on context.
- It should be readily understood that the meaning of “on,” “above,” and “over” in the present disclosure should be interpreted in the broadest manner such that “on” not only means “directly on” something, but also includes the meaning of “on” something with an intermediate feature or a layer therebetween. Moreover, “above” or “over” not only means “above” or “over” something, but can also include the meaning it is “above” or “over” something with no intermediate feature or layer therebetween (i.e., directly on something).
- Further, spatially relative terms, such as “beneath,” “below,” “lower,” “above,” “upper,” and the like, can be used herein for ease of description to describe one element or feature's relationship to another element(s) or feature(s) as illustrated in the figures. The spatially relative terms are intended to encompass different orientations of the device in use or process step in addition to the orientation depicted in the figures. The apparatus can be otherwise oriented (rotated 90 degrees or at other orientations) and the spatially relative descriptors used herein can likewise be interpreted accordingly.
- As used herein, the term “substrate” refers to a material onto which subsequent material layers are added. The substrate includes a top surface and a bottom surface. The top surface of the substrate is typically where a semiconductor device is formed, and therefore the semiconductor device is formed at a top side of the substrate unless stated otherwise. The bottom surface is opposite to the top surface and therefore a bottom side of the substrate is opposite to the top side of the substrate. The substrate itself can be patterned. Materials added on top of the substrate can be patterned or can remain unpatterned. Furthermore, the substrate can include a wide array of semiconductor materials, such as silicon, germanium, gallium arsenide, indium phosphide, etc. Alternatively, the substrate can be made from an electrically non-conductive material, such as a glass, a plastic, or a sapphire wafer.
- As used herein, the term “layer” refers to a material portion including a region with a thickness. A layer has a top side and a bottom side where the bottom side of the layer is relatively close to the substrate and the top side is relatively away from the substrate. A layer can extend over the entirety of an underlying or overlying structure, or can have an extent less than the extent of an underlying or overlying structure. Further, a layer can be a region of a homogeneous or inhomogeneous continuous structure that has a thickness less than the thickness of the continuous structure. For example, a layer can be located between any set of horizontal planes between, or at, a top surface and a bottom surface of the continuous structure. A layer can extend horizontally, vertically, and/or along a tapered surface. A substrate can be a layer, can include one or more layers therein, and/or can have one or more layer thereupon, thereabove, and/or therebelow. A layer can include multiple layers. For example, an interconnect layer can include one or more conductive and contact layers (in which contacts, interconnect lines, and/or vertical interconnect accesses (VIAs) are formed) and one or more dielectric layers.
- As used herein, the term “nominal/nominally” refers to a desired, or target, value of a characteristic or parameter for a component or a process step, set during the design phase of a product or a process, together with a range of values above and/or below the desired value. The range of values can be due to slight variations in manufacturing processes or tolerances. As used herein, the term “about” indicates the value of a given quantity that can vary based on a particular technology node associated with the subject semiconductor device. Based on the particular technology node, the term “about” can indicate a value of a given quantity that varies within, for example, 10-30% of the value (e.g., ±10%, ±20%, or ±30% of the value).
- In the present disclosure, the term “horizontal/horizontally/lateral/laterally” means nominally parallel to a lateral surface of a substrate. In the present disclosure, the term “each” may not only necessarily mean “each of all,” but can also mean “each of a subset.”
- As used herein, the term “3D memory” refers to a three-dimensional (3D) semiconductor device with vertically oriented strings of memory cell transistors (referred to herein as “memory strings,” such as NAND strings) on a laterally-oriented substrate so that the memory strings extend in the vertical direction with respect to the substrate. As used herein, the term “vertical/vertically” means nominally perpendicular to the lateral surface of a substrate.
- In the present disclosure, for ease of description, “tier” is used to refer to elements of substantially the same height along the vertical direction. For example, a word line and the underlying gate dielectric layer can be referred to as “a tier,” a word line and the underlying insulating layer can together be referred to as “a tier,” word lines of substantially the same height can be referred to as “a tier of word lines” or similar, and so on.
- In some embodiments, a memory string of a 3D memory device includes a semiconductor pillar (e.g., silicon channel) that extends vertically through a plurality of conductive and dielectric layer pairs. The plurality of conductive and dielectric layer pairs are also referred to herein as an “alternating conductive and dielectric stack.” An intersection of the conductive layer and the semiconductor pillar can form a memory cell. The conductive layer of the alternating conductive and dielectric stack can be connected to a word line at the back-end-of-line, wherein the word line can electrically connect to one or more control gates. For illustrative purposes, word lines and control gates are used interchangeably to describe the present disclosure. The top of the semiconductor pillar (e.g., transistor drain region) can be connected to a bit line (electrically connecting one or more semiconductor pillars). Word lines and bit lines are typically laid perpendicular to each other (e.g., in rows and columns, respectively), forming an “array” of the memory, also called a memory “block” or an “array block”.
- A memory “die” may have one or more memory “planes”, and each memory plane may have a plurality of memory blocks. An array block can also be divided into a plurality of memory “pages”, wherein each memory page may have a plurality of memory strings. In a flash NAND memory device, erase operation can be performed for every memory block and read/write operation can be performed for every memory page. The array blocks are the core area in a memory device, performing storage functions. To achieve higher storage density, the number of vertical 3D memory stacks is increased greatly, adding complexity and cost in manufacturing.
- A memory die has another region, called the periphery, which provides supporting functions to the core. The periphery region includes many digital, analog, and/or mixed-signal circuits, for example, row and column decoders, drivers, page buffers, sense amplifiers, timing and controls, and the like circuitry. Peripheral circuits use active and/or passive semiconductor devices, such as transistors, diodes, capacitors, resistors, etc., as would be apparent to a person of ordinary skill in the art.
- Other parts of the memory devices are not discussed for ease of description. In the present disclosure, a “memory device” is a general term and can be a memory chip (package), a memory die or any portion of a memory die.
- Although using three-dimensional NAND devices as examples, in various applications and designs, the disclosed structures can also be applied in similar or different semiconductor devices to, e.g., to improve metal connections or wiring. The specific application of the disclosed structures should not be limited by the embodiments of the present disclosure.
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FIG. 1 illustrates a top-down view of an exemplary three-dimensional (3D)memory device 100, according to some embodiments of the present disclosure. The3D memory device 100 can be a memory die and can include one ormore memory planes 101, each of which can include a plurality of memory blocks 103. Identical and concurrent operations can take place at eachmemory plane 101. Thememory block 103, which can be megabytes (MB) in size, is the smallest size to carry out erase operations. Shown inFIG. 1 , the exemplary3D memory device 100 includes fourmemory planes 101 and eachmemory plane 101 includes six memory blocks 103. Eachmemory block 103 can include a plurality of memory cells, wherein each memory cell can be addressed through interconnections such as bit lines and word lines. The bit lines and word lines can be laid out perpendicularly, forming an array of metal lines. The direction of bit lines and word lines are labeled as “BL” and “WL” inFIG. 1 . In this disclosure, memory blocks 103 is also referred to as “memory arrays”. - The
3D memory device 100 also includes aperiphery regions 105, an area surrounding memory planes 101. Theperiphery region 105 contains peripheral circuits to support functions of the memory array, for example, page buffers, row and column decoders and sense amplifiers. - It is noted that, the arrangement of the memory planes 101 in the
3D memory device 100 and the arrangement of the memory blocks 103 in eachmemory plane 101 illustrated inFIG. 1 are only used as an example, which does not limit the scope of the present disclosure. - In some embodiments, the memory arrays and the peripheral circuits of the
3D memory device 100 can be formed on different substrates and can be joined together to form the3D memory device 100 through wafer bonding. In this example, through array contact structures can provide vertical interconnects between the memory arrays and peripheral circuits, thereby reducing metal levels and shrinking die size. Detailed structure and method of 3D memory with hybrid bonding is described in co-pending U.S. patent application, titled “Hybrid Bonding Contact Structure of Three-Dimensional Memory Device,” (application Ser. No. 16/046,852 and filed on Jul. 26, 2018), which is incorporated herein by reference in its entirety. - Referring to
FIG. 2A , an enlarged top-down view of aregion 108 inFIG. 1 is illustrated, according to some embodiments of the present disclosure. Theregion 108 of the3D memory device 100 can include astaircase region 210 and achannel structure region 211. Thechannel structure region 211 can include an array ofmemory strings 212, each including a plurality of stacked memory cells. Thestaircase region 210 can include a staircase structure and an array ofcontact structures 214 formed on the staircase structure. In some embodiments, a plurality ofslit structures 216, extending in WL direction across thechannel structure region 211 and thestaircase region 210, can divide a memory block intomultiple memory fingers 218. At least some slitstructures 216 can function as the common source contact for an array ofmemory strings 212 inchannel structure regions 211. A top select gate cut 220 can be disposed in the middle of eachmemory finger 218 to divide a top select gate (TSG) of thememory finger 218 into two portions, and thereby can divide a memory finger into two programmable (read/write) pages. While erase operation of a 3D NAND memory can be carried out at memory block level, read and write operations can be carried out at memory page level. A page can be kilobytes (KB) in size. In some embodiments,region 108 also includesdummy memory strings 222 for process variation control during fabrication and/or for additional mechanical support. - Referring to
FIG. 2B , an enlarged top-down view of aregion 109 inFIG. 1 is illustrated, according to some embodiments of the present disclosure. Theregion 109 of the3D memory device 100 can include thechannel structure region 211, a througharray contact region 107, and a top select gate (TSG)staircase region 224. - The
channel structure region 211 in theregion 109 can be similar to thechannel structure region 211 inregion 108. TheTSG staircase region 224 can include an array ofTSG contacts 226 formed on the staircase structure. TheTSG staircase region 224 can be disposed on the sides of thechannel structure region 211 and adjacent to througharray contact region 107 in the top-down view. Multiple througharray contacts 228 can be formed in the througharray contact region 107. -
FIG. 3 illustrates a perspective view of a portion of an exemplary three-dimensional (3D)memory array structure 300, according to some embodiments of the present disclosure. Thememory array structure 300 includes asubstrate 330, an insulatingfilm 331 over thesubstrate 330, a tier of lower select gates (LSGs) 332 over the insulatingfilm 331, and a plurality of tiers ofcontrol gates 333, also referred to as “word lines (WLs)”, stacking on top of theLSGs 332 to form afilm stack 335 of alternating conductive and dielectric layers. The dielectric layers adjacent to the tiers of control gates are not shown inFIG. 3 for clarity. - The control gates of each tier are separated by slit structures 216-1 and 216-2 through the
film stack 335. Thememory array structure 300 also includes a tier of top select gates (TSGs) 334 over the stack ofcontrol gates 333. The stack ofTSG 334,control gates 333 andLSG 332 is also referred to as “gate electrodes.” Thememory array structure 300 further includesmemory strings 212 and dopedsource line regions 344 in portions ofsubstrate 330 betweenadjacent LSGs 332. Each memory strings 212 includes achannel hole 336 extending through the insulatingfilm 331 and thefilm stack 335 of alternating conductive and dielectric layers. Memory strings 212 also includes amemory film 337 on a sidewall of thechannel hole 336, achannel layer 338 over thememory film 337, and acore filling film 339 surrounded by thechannel layer 338. Amemory cell 340 can be formed at the intersection of thecontrol gate 333 and thememory string 212. Thememory array structure 300 further includes a plurality of bit lines (BLs) 341 connected to the memory strings 212 over theTSGs 334. Thememory array structure 300 also includes a plurality ofmetal interconnect lines 343 connected to the gate electrodes through a plurality ofcontact structures 214. The edge of thefilm stack 335 is configured in a shape of staircase to allow an electrical connection to each tier of the gate electrodes. Thechannel structure region 211 and thestaircase region 210 correspond to thechannel structure region 211 and thestaircase region 210 in the top-down view ofFIG. 2A , wherein one of thestaircase region 210 inFIG. 3 can be used as TSG staircase region 230 for TSG connection. - In
FIG. 3 , for illustrative purposes, three tiers of control gates 333-1, 333-2, and 333-3 are shown together with one tier ofTSG 334 and one tier ofLSG 332. In this example, eachmemory string 212 can include three memory cells 340-1, 340-2 and 340-3, corresponding to the control gates 333-1, 333-2 and 333-3, respectively. In some embodiments, the number of control gates and the number of memory cells can be more than three to increase storage capacity. Thememory array structure 300 can also include other structures, for example, through array contact, TSG cut, common source contact and dummy channel structure. These structures are not shown inFIG. 3 for simplicity. - With the demand for higher storage capacity in a NAND flash memory, the number of vertical tiers of
3D memory cells 340 orword lines 333 increases accordingly, leading to more process complexity and higher manufacturing cost. When increasing the tiers ofmemory cells 340 orword lines 333 of thememory array structure 300, it becomes more challenging to etch deeper channel holes 336 for the memory strings 212 and also more challenging to formcontact structures 214 on the staircase structures. For example, to form thecontact structures 214 on a large number of vertically stacked word lines (gate electrodes), a high aspect ratio etching is needed to form contact holes, followed by a high aspect ratio deposition of conductive materials inside the contact holes. To reduce cost per bit for a 3D memory, dimensions of the memory structures are reduced to allow fabrication of more memory blocks on a wafer. However the increased word line stack also leads to wider staircase structures in a horizontal direction parallel to the substrate surface, resulting in awider staircase region 210 and less storage density. - To alleviate etching and deposition difficulties with more and more vertically stacked word lines, portions of a 3D memory device can be formed on two or more wafers and then joined together through wafer bonding or flip-chip bonding. Alternatively, a 3D memory device can be formed by sequentially stacking multi-sessions, wherein each session contains a stack of word lines with less number of tiers. However larger lateral dimensions of staircase structures due to vertically stacked word lines still limits the storage density.
- Various embodiments in the present disclosure describe a structure and method of a 3D memory with coaxial contact structures, each providing electrical contacts to two or more conductive layers of the staircase structure. By sharing contact structures between multiple conductive layers, the dimension of the staircase region 210 (in
FIG. 2 ) can be reduced. Memory density and cost per bit of the 3D NAND memory can be improved accordingly. -
FIG. 4 illustrates a cross-sectional view of anexemplary structure 400 of a three-dimensional memory device, according to some embodiments, wherein thestructure 400 includes asubstrate 330 and adielectric film stack 445. The cross-sectional views ofFIG. 4-17D are along WL direction inFIG. 2A . -
Substrate 330 can provide a platform for forming subsequent structures. In some embodiments, thesubstrate 330 includes any suitable material for forming the three-dimensional memory device. For example, thesubstrate 330 can include any other suitable material, for example, silicon, silicon germanium, silicon carbide, silicon on insulator (SOI), germanium on insulator (GOI), glass, gallium nitride, gallium arsenide, III-V compound, and/or any combinations thereof. - A
front surface 330 f of thesubstrate 330 is also referred to as a “main surface” of the substrate herein. Layers of materials can be disposed on thefront surface 330 f of the substrate. A “topmost” or “upper” layer is a layer farthest or farther away from thefront surface 330 f of the substrate. A “bottommost” or “lower” layer is a layer closest or closer to thefront surface 330 f of the substrate. - In some embodiments, peripheral devices can be formed in the
periphery region 105 on thefront surface 330 f of thesubstrate 330. In some embodiments, active device areas can be formed in the memory blocks 103 on thefront surface 330 f of thesubstrate 330. In some embodiments, thesubstrate 330 can further include an insulatingfilm 331 on thefront surface 330 f. The insulatingfilm 331 can be made of the same or different material from the dielectric film stack. - The peripheral devices can include any suitable semiconductor devices, for example, metal oxide semiconductor field effect transistors (MOSFETs), diodes, resistors, capacitor, etc. The peripheral devices can be used in the design of digital, analog and/or mixed signal circuits supporting the storage function of the memory core, for example, row and column decoders, drivers, page buffers, sense amplifiers, timing and controls.
- The active device areas in the memory blocks are surrounded by isolation structures, such as shallow trench isolation. Doped regions, such as p-type doped and/or n-type doped wells, can be formed in the active device area according to the functionality of the array devices in the memory blocks.
- The
dielectric film stack 445 extends in a lateral direction that is parallel to thefront surface 330 f of thesubstrate 330. Thedielectric film stack 445 includes a dielectric layer 450 (also referred to as “first dielectric layer”) and a sacrificial layer 452 (also referred to as “second dielectric layer”) alternatingly stacked on each other, wherein thedielectric layer 450 is configured to be the bottommost and the topmost layers of thedielectric film stack 445. In this configuration, eachsacrificial layer 452 is sandwiched between twodielectric layers 450, and eachdielectric layer 450 is sandwiched between two sacrificial layers 452 (except the bottommost and the topmost layer). - The
dielectric layer 450 and the underlyingsacrificial layer 452 are also referred to as an alternatingdielectric layer pair 454. The formation of thedielectric film stack 445 can include disposing thedielectric layers 450 to each have the same thickness or to have different thicknesses. Example thicknesses of thedielectric layers 450 can range from 10 nm to 500 nm. Similarly, thesacrificial layer 452 can each have the same thickness or have different thicknesses. Example thicknesses of thesacrificial layer 452 can range from 10 nm to 500 nm. - Although only 21 total layers are illustrated in the
dielectric film stack 445 inFIG. 4 , it should be understood that this is for illustrative purposes only and that any number of layers may be included in thedielectric film stack 445. - In some embodiments, the
dielectric film stack 445 can include layers in addition to thedielectric layer 450 and thesacrificial layer 452, and can be made of different materials and with different thicknesses. - In some embodiments, the
dielectric layer 450 includes any suitable insulating materials, for example, silicon oxide, silicon oxynitride, silicon nitride, TEOS or silicon oxide with F—, C—, N—, and/or H— incorporation. Thedielectric layer 450 can also include high-k dielectric materials, for example, hafnium oxide, zirconium oxide, aluminum oxide, tantalum oxide, or lanthanum oxide films. - The formation of the
dielectric layer 450 on thesubstrate 330 can include any suitable deposition methods such as, chemical vapor deposition (CVD), physical vapor deposition (PVD), plasma-enhanced CVD (PECVD), rapid thermal chemical vapor deposition (RTCVD), low pressure chemical vapor deposition (LPCVD), sputtering, metal-organic chemical vapor deposition (MOCVD), atomic layer deposition (ALD), high-density-plasma CVD (HDP-CVD), thermal oxidation, nitridation, any other suitable deposition method, and/or combinations thereof. - In some embodiments, the
sacrificial layer 452 includes any suitable material that is different from thedielectric layer 450 and can be removed selectively. For example, thesacrificial layer 452 can include silicon oxide, silicon oxynitride, silicon nitride, TEOS, poly-crystalline silicon, poly-crystalline germanium, poly-crystalline germanium-silicon, and any combinations thereof. In some embodiments, thesacrificial layer 452 also includes amorphous semiconductor materials, such as amorphous silicon or amorphous germanium. Thesacrificial layer 452 can be disposed using a similar technique as thedielectric layer 450, such as CVD, PVD, ALD, thermal oxidation or nitridation, or any combination thereof. - In some embodiments, the
dielectric layer 450 can be silicon oxide and thesacrificial layer 452 can be silicon nitride. -
FIG. 5 illustrates a cross-sectional view of anexemplary structure 500 of a three dimensional memory device, according to some embodiments, wherein thestructure 500 includes adielectric staircase 560 formed in thedielectric film stack 445. In thedielectric staircase 560, adielectric staircase step 562, or a “staircase layer”, refers to a layer stack with the same lateral dimension in a surface parallel to thesubstrate surface 330 f Eachdielectric staircase step 562 terminates at a shorter length than the staircase step underneath, with a lateral dimension “a” shown inFIG. 5 . - In some embodiments, each
dielectric staircase step 562 includes two or more alternating dielectric layer pairs 454. Eachdielectric staircase step 562 can have a same number of alternating dielectric layer pairs or a different number of alternating dielectric layer pairs. As an example,FIG. 5 depicts thedielectric staircase 560 with two alternating dielectric layer pairs 454. - The plural steps of the
dielectric staircase 560 can be formed by applying a repetitive etch-trim process on thedielectric film stack 445 using a patterning mask (not shown). In some embodiments, the patterning mask can include a photoresist or carbon-based polymer material. The patterning mask can be removed after forming thedielectric staircase 560. - The etch-trim process includes an etching process and a trimming process. During the etching process, a portion of each
dielectric staircase step 562 with exposed surface can be removed. The remaining portion of eachdielectric staircase step 562, either covered by upper levels of staircase steps or covered by the patterning mask, is not etched. The etch depth is a thickness of thedielectric staircase step 562. In some embodiments, the thickness of thedielectric staircase step 562 is the total thickness of two or more alternating dielectric layer pairs 454. In the example shown inFIG. 5 , the thickness of adielectric staircase step 562 is the thickness of two alternating dielectric layer pairs 454. The etching process for thedielectric layer 450 can have a high selectivity over thesacrificial layer 452, and/or vice versa. Accordingly, an underlying alternatingdielectric layer pair 454 can function as an etch-stop layer. By switching etching process for each layer, thedielectric staircase step 562 with multiple alternating dielectric layer pairs 454 can be etched during one etching cycle. And as a result, one staircase step is formed during each etch-trim cycle. - In some embodiments, the
dielectric staircase step 562 can be etched using an anisotropic etching such as a reactive ion etch (RIE) or other dry etch processes. In some embodiments, thedielectric layer 450 is silicon oxide. In this example, the etching of silicon oxide can include RIE using fluorine based gases, for example, carbon-fluorine (CF4), hexafluoroethane (C2F6), CHF3, or C3F6 and/or any other suitable gases. In some embodiments, the silicon oxide layer can be removed by wet chemistry, such as hydrofluoric acid or a mixture of hydrofluoric acid and ethylene glycol. In some embodiments, a timed etching approach can be used. In some embodiments, thesacrificial layer 452 is silicon nitride. In this example, the etching of silicon nitride can include RIE using O2, N2, CF4, NF3, Cl2, HBr, BCl3, and/or combinations thereof. The methods and etchants to remove a single layer stack should not be limited by the embodiments of the present disclosure. - The trimming process includes applying a suitable etching process (e.g., an isotropic dry etch or a wet etch) on the patterning mask such that the patterning mask can be pulled back laterally. The lateral pull-back dimension determines the lateral dimension “a” of each step of the
dielectric staircase 560. After patterning mask trimming, one portion of the topmostdielectric staircase step 562 is exposed and the other portion of the topmostdielectric staircase step 562 remains covered by the patterning mask. The next cycle of etch-trim process resumes with the etching process. - In some embodiments, the patterning mask trimming process can include dry etching, such as RIE using O2, Ar, N2, etc.
- In some embodiments, the topmost
dielectric staircase step 562 can be covered by thedielectric layer 450. In some embodiments, the topmostdielectric staircase step 562 can further be covered by other dielectric materials. A process step of removing thedielectric layer 450 and/or the other dielectric materials can be added to the etching process of each etch-trim cycle to form thedielectric staircase 560. -
FIG. 6 illustrates a cross-sectional view of anexemplary structure 600 of a three dimensional memory device, according to some embodiments, wherein thestructure 600 includes abarrier layer 664 disposed over thestructure 500. - The
barrier layer 664 covers thedielectric staircase 560 on both the top surfaces and sidewalls. In some embodiments, thebarrier layer 664 can be an optional etch-stop layer. For example, thebarrier layer 664 can be used as an etch-stop layer for protecting the underlying structure during contact hole etching processes. In some embodiments, a thickness of thebarrier layer 664 on sidewalls can be the same as a thickness of thebarrier layer 664 on the top surfaces. In some embodiments, the thickness of thebarrier layer 664 on sidewalls can be different from the thickness of thebarrier layer 664 on the top surfaces. In some embodiments, thebarrier layer 664 can be made of similar material as thedielectric layer 450 using a similar technique. -
FIG. 7 illustrates a cross-sectional view of anexemplary structure 700 of a three dimensional memory device, according to some embodiments, wherein thestructure 700 includes a first insulatinglayer 768 disposed over thestructure 600. - The first insulating
layer 768 can be disposed ondielectric staircase 560 after forming thebarrier layer 664. The first insulatinglayer 768 can be made of any a suitable insulator and can be made of a similar material as thedielectric layer 450 using a similar technique. In some embodiments, the first insulatinglayer 768 can also include spin-on-glass, a mixture of silicon oxide and dopants (either boron or phosphorous) that is suspended in a solvent solution, and can be disposed using processes, for example, spin-coating. In some embodiments, the first insulatinglayer 768 can include a low-k dielectric material, such as carbon-doped oxide (CDO or SiOC or SiOC:H), or fluorine doped oxide (SiOF), etc. The low-k dielectric material can be disposed by CVD, PVD, sputtering, etc. - In some embodiments, a planarization process, for example RIE etch-back or chemical mechanical polishing (CMP), can be performed to form a coplanar surface, parallel to the
surface 330 f of thesubstrate 330. In some embodiments, thetop surface 768S of the first insulatinglayer 768 can be coplanar with thetop surface 664S of the uppermost portion of thebarrier layer 664. In this example, thebarrier layer 664 can be used as a polish-stop. -
FIG. 8 illustrates a cross-sectional view of anexemplary structure 800 of a three dimensional memory device, according to some embodiments, wherein thestructure 800 includes a plurality ofmemory strings 212 through thedielectric film stack 445. The memory strings 212 correspond to the memory strings 212 inFIGS. 2A-2B andFIG. 3 . For illustrative purpose, two memory strings are shown inFIG. 8 . Eachmemory string 212 extends through thedielectric film stack 445 of alternating dielectric layer pairs, and includes amemory film 337 over the inner surface ofmemory strings 212, achannel layer 338 over thememory film 337, and acore filling film 339 surrounded by thechannel layer 338. Detailed structure and method of the NAND memory string is described in the co-pending U.S. patent application, titled “Method for Forming Gate Structure of Three-Dimensional Memory Device,” (application Ser. No. 16/047,158 and filed on Jul. 27, 2018), which is incorporated herein by reference in its entirety. -
FIG. 9 illustrates a cross-sectional view of anexemplary structure 900 of a three dimensional memory device (along WL direction), according to some embodiments, wherein thesacrificial layers 452 are removed and a plurality ofhorizontal tunnels 970 are formed. - After forming the memory strings 212, a plurality of slit structure openings can be formed along WL directions (see
FIGS. 2A-2B andFIG. 3 ). These slit structure openings extend through thedielectric film stack 445. Thesacrificial layers 452 can then be removed from the openings of theslit structures 216 along BL direction (perpendicular to WL direction, e.g., perpendicular to the cross-section shown inFIG. 9 ). - The
sacrificial layers 452 can be removed by any suitable etching process, e.g., an isotropic dry etch or wet etch, that is selective over thedielectric layers 450, such that the etching process can have minimal impact on thedielectric layer 450. In some embodiments, thesacrificial layer 452 can be silicon nitride. In this example, thesacrificial layer 452 can be removed by RIE using one or more etchants of CF4, CHF3, C4F8, C4F6, and CH2F2. In some embodiments, thesacrificial layer 452 can be removed using wet etch, such as phosphoric acid. - After removing the
sacrificial layers 452, sidewalls of thememory film 337 are exposed in thehorizontal tunnels 970. -
FIG. 10 illustrates a cross-sectional view of anexemplary structure 1000 of a three dimensional memory device, according to some embodiments, wherein thestructure 1000 includes thefilm stack 335 of alternating conductive and dielectric layers (e.g., corresponding to thefilm stack 335 inFIG. 3 ). Thefilm stack 335 of alternating conductive and dielectric layers includesconductive layers 1072 sandwiched between the dielectric layers 450. Instructure 1000, eachstaircase step 1076 includes two or more conductive and dielectric layer pairs 1074, each conductive anddielectric layer pair 1074 having oneconductive layer 1072 and onedielectric layer 450. InFIG. 10 , as an example, eachstaircase step 1076 includes two conductive and dielectric layer pairs 1074-1 and 1074-2, referred to as an “upper layer pair” and a “lower layer pair”, respectively. After disposing theconductive layers 1072 inside the plurality of horizontal tunnels, thedielectric staircase 560 with alternating dielectric and sacrificial layers is now changed into astaircase structure 1060 with alternating conductive and dielectric layers. - The
conductive layer 1072 can include any suitable conductive material that is suitable for a gate electrode, e.g., tungsten (W), aluminum (Al), copper (Cu), cobalt (Co), titanium (Ti), tantalum (Ta), titanium nitride (TiN), tantalum nitride (TaN), and/or any combination thereof. The conductive material can fill thehorizontal tunnel 970 using a suitable deposition method such as CVD, physical vapor deposition (PVD), plasma-enhanced CVD (PECVD), sputtering, thermal evaporation, e-beam evaporation, metal-organic chemical vapor deposition (MOCVD), and/or ALD. In some embodiments, theconductive layers 1072 include tungsten (W) deposited by CVD. - In some embodiments, the
conductive layer 1072 can also be poly-crystalline semiconductors, such as poly-crystalline silicon, poly-crystalline germanium, poly-crystalline germanium-silicon and any other suitable material, and/or combinations thereof. In some embodiments, the poly-crystalline material can be incorporated with any suitable types of dopant, such as boron, phosphorous, or arsenic. In some embodiments, theconductive layer 1072 can also be amorphous semiconductors. - In some embodiments, the
conductive layer 1072 can be made from a metal silicide, including WSix, CoSix, NiSix, or AlSix, etc. The forming of the metal silicide material can include forming a metal layer and a poly-crystalline semiconductor using similar techniques described above. The forming of metal silicide can further include applying a thermal annealing process on the deposited metal layer and the poly-crystalline semiconductor layer, followed by removal of unreacted metal. - In some embodiments, a gate dielectric layer can be disposed in the
horizontal tunnels 970 prior to the conductive layer 1072 (not shown inFIG. 10 ) to reduce leakage current between adjacent word lines (gate electrodes) and/or to reduce leakage current between gate and channel. The gate dielectric layer can include silicon oxide, silicon nitride, silicon oxynitride, and/or any suitable combinations thereof. The gate dielectric layer can also include high-k dielectric materials, such as hafnium oxide, zirconium oxide, aluminum oxide, tantalum oxide, lanthanum oxide, and/or any combination thereof. The gate dielectric layer can be disposed by one or more suitable deposition processes, such as CVD, PVD, and/or ALD. - The
conductive layers 1072 function as gate electrodes at the intersection with memory strings 212. InFIG. 10 , the tenconductive layers 1072 can form ten gate electrodes for eachmemory string 212, e.g.,TSG 334,LSG 332 and eightcontrol gates 333. Corresponding to eightcontrol gates 333, eachmemory string 212 can have eightmemory cells 340. It is noted that the number of memory strings and memory cells are shown for illustrative purposes inFIG. 10 , and can be increased for higher storage capacity. - After forming gate electrodes, conductive materials can be removed and insulating materials can be deposited in the openings to form slit
structures 216, separating a memory block into multiple programmable and readable memory fingers (seeFIG. 2A-2B ). - In some embodiments, the doped
source line regions 344 in portions ofsubstrate 330 can be formed using techniques such as ion implantation (seeFIG. 3 ). In this example, a conductive core can be inserted in theslit structure 216 to form common source contact to the dopedsource line region 344. -
Structure 1000 can include other structures, for example, through array contact (TAC), TSG cut, common source contact and dummy channel structure, which are not shown inFIG. 10 for simplicity. -
FIG. 11 illustrates a cross-sectional view of anexemplary structure 1100 of a three dimensional memory device, according to some embodiments, wherein thestructure 1100 includes a plurality offirst contact holes 1180 in the first insulatinglayer 768 with a diameter of “d1”. InFIG. 11 , onefirst contact hole 1180 is shown for eachstaircase step 1076, which is only for illustrative purpose. Multiplefirst contact holes 1180 can be formed on eachstaircase step 1076. In some embodiments, there are nofirst contact holes 1180 on dummy staircase levels. - In some embodiments, photoresist or polymer material can be used as a mask layer to etch the first contact holes 1180. Due to the topology of the staircase structure, depth “H” of the
first contact hole 1180 from the top surface to staircase step depends on the location of each step. For a 3D NAND memory with many tiers of word lines, thefirst contact holes 1180 for the lower staircase steps can be much deeper than thefirst contact holes 1180 for the upper staircase steps. Therefore, thefirst contact hole 1180 for thestaircase step 1076 closer to thesurface 330 f of thesubstrate 330 requires longer etch time than thefirst contact hole 1180 for thestaircase step 1076 away from thesurface 330 f of thesubstrate 330. A selective etching process can be used such that the etching rate of the first insulatinglayer 768 is higher than theconductive layer 1072 and/or thebarrier layer 664. - In some embodiments, during the etching process for
first contact holes 1180, thebarrier layer 664 can function as an etch-stop layer and can protect the underlying structure until all thefirst contact holes 1180 are formed on top of thebarrier layer 664 for all levels of thestaircase structure 1060. And then the portions of thebarrier layer 664 inside thefirst contact holes 1180 can be removed using the same mask layer. In some embodiments, when a gate dielectric layer is disposed on theconductive layer 1072, the etching also includes removing the gate dielectric layer inside the first contact holes 1180. - The
first contact holes 1180 extend through the first insulatinglayer 768, thebarrier layer 664, and the optional gate dielectric layer, exposing a portion of theconductive layer 1072 of the upper layer pair 1074-1 in eachstaircase step 1076. In some embodiments, the first insulatinglayer 768 is silicon oxide and the barrier layer is a combination of silicon nitride and silicon oxide. In this example, etching silicon oxide can use anisotropic RIE with chemical etchant, for example, CF4, CHF3, C2F6, C3F6, and/or any combination thereof. Etching silicon nitride can use RIE with chemical etchant, for example, O2, N2, CF4, NF3, Cl2, HBr, BCl3, and/or combinations thereof. - The diameter “d1” of the
first contact holes 1180 is preferably smaller than the lateral dimension “a” of thestaircase structure 1060, and will be discussed in detail in the subsequent processes. -
FIG. 12 illustrates a cross-sectional view of anexemplary structure 1200 of a three dimensional memory device, according to some embodiments, wherein thestructure 1200 includes aconductive film 1282, disposed over thestructure 1100. - In some embodiments, the
conductive film 1282 inside thefirst contact hole 1180 is in direct contact with theconductive layer 1072 of the upper layer pair 1074-1. Theconductive film 1282 also covers a sidewall of thefirst contact hole 1180. The thickness “t1” of theconductive film 1282 at the bottom of thefirst contact hole 1180 can be the same or different from the thickness “t2” on the sidewall. The height of theconductive film 1282 inside thefirst contact hole 1180 is determined by the depth “H” of thefirst contact hole 1180. - The
conductive film 1282 can include any suitable conductive material, for example, a metal or metallic compound such as tungsten (W), aluminum (Al), copper (Cu), cobalt (Co), titanium (Ti), tantalum (Ta), titanium nitride (TiN), tantalum nitride (TaN), and/or any combination thereof. The metal or metallic compound can be disposed using a suitable deposition method such as CVD, PVD, PECVD, sputtering, thermal evaporation, e-beam evaporation, MOCVD, and/or ALD. - The
conductive film 1282 can also be a metal silicide, including WSix, CoSix, NiSix, or AlSix, etc. Metal silicide material can be formed by disposing a metal layer directly on a polycrystalline silicon layer inside thefirst contact hole 1180 and then applying a thermal annealing process followed by removal of unreacted metal. - In some embodiments, the
conductive film 1282 includes a combination of TiN/W/TiN deposited by CVD. -
FIG. 13 illustrates a cross-sectional view of anexemplary structure 1300 of a three dimensional memory device, according to some embodiments, wherein thestructure 1300 includes a plurality ofconductive rings 1384 and a plurality ofring openings 1386. Theconductive ring 1384 covers a sidewall of the first insulatinglayer 768. Bottom of theconductive ring 1384 contacts theconductive layer 1072 of the upper layer pair 1074-1. - The
conductive ring 1384 can be formed by removing theconductive film 1282 and theconductive layer 1072 from the bottom of thering openings 1386 using anisotropic etching, such as anisotropic RIE. In some embodiments, theconductive film 1282 and theconductive layer 1072 of thestaircase structure 1060 can be tungsten. In this example, the anisotropic etching to form theconductive ring 1384 can include dry etching, for example ME with a mixture of O2 and CF4, CClF3, or CBrF3. - Anisotropic RIE can include low-pressure plasma system to increase mean-free path of the ions and reduce random scattering. During anisotropic etching, the ions strike the
structure 1300 in a vertical direction, perpendicular to thetop surface 330 f of thesubstrate 330. In some embodiment, the height “H” (shown inFIG. 12 ) of theconductive film 1282 can be greater than the total thickness of “t1” at the bottom of thefirst contact holes 1180 and the thickness of theconductive layer 1072. Therefore, theconductive film 1282 and theconductive layer 1072 at the bottom of thefirst contact holes 1180 can be removed, while there is remaining conductive film on the sidewall of thefirst contact hole 1180, forming theconductive ring 1384. - The thickness “t3” of the
conductive ring 1384 depends on the initial sidewall thickness “t2” of theconductive film 1282, as well as the sidewall profile of the first contact holes 1180. The thickness “t3” can further depend on the RIE process conditions, for example, total etch time, ion direction angle, pressure, DC bias voltage and RF power, etc. To reduce parasitic resistance and metal line loading, theconductive ring 1384 with a greater thickness “t3” is preferred. However trade-off between memory performance and area is needed for a limited diameter “d1” of the first contact holes 1180. - For each
staircase step 1076, thering openings 1386 extend through theconductive layer 1072 of the upper layer stack 1074-1, with a smaller diameter “d2” than the diameter “d1” of thefirst contact holes 1180, as shown inFIG. 13 . -
FIG. 14 illustrates a cross-sectional view of anexemplary structure 1400 of a three dimensional memory device, according to some embodiments, wherein thestructure 1400 includes a second insulatinglayer 1488 disposed over thestructure 1300. - The second insulating
layer 1488 covers the exposed conductive materials inside thering openings 1386, e.g., theconductive ring 1384 and sidewalls of theconductive layer 1072 of the upper layer pair 1074-1 for eachstaircase step 1076. The second insulatinglayer 1488 can be made of a similar material as the first insulatinglayer 768 and used a similar deposition technique. -
FIG. 15 illustrates a cross-sectional view of anexemplary structure 1500 of a three dimensional memory device, according to some embodiments, wherein thestructure 1500 includes a plurality of insulatingrings 1590 and a plurality of second contact holes 1592. The insulatingrings 1590 can be formed by etching portions of the second insulatinglayer 1488 and thedielectric layer 450 from the bottom of thering openings 1386 on structure 1400 (inFIG. 14 ), wherein thelayer conductive ring 1384 except using a different etchant for the dielectric material. In some embodiments, the second insulatinglayer 1488 can be silicon oxide. In this example, the etching of silicon oxide can include RIE using fluorine based gases, for example, carbon-fluorine (CF4), hexafluoroethane (C2F6), CHF3, or C3F6 and/or any other suitable gases. - The
second contact hole 1592 extends through the second insulatinglayer 1488 and thedielectric layer 450 of the upper layer pair 1074-1 for eachstaircase step 1076, exposing theconductive layer 1072 of the lower layer pair 1074-2. -
FIG. 16A illustrates a cross-sectional view of anexemplary structure 1600 of a three dimensional memory device, according to some embodiments, wherein thestructure 1600 includes a plurality ofconductive cores 1694. - The
conductive core 1694 can be made of any suitable conductive materials and can be similar to theconductive film 1282, forming by a similar technique. The conductive material for theconductive core 1694 can be disposed over thestructure 1500, filling thesecond contact hole 1592. Theconductive core 1694 directly contacts with theconductive layer 1072 of the lower layer pair 1074-2 of eachstaircase step 1076. - In some embodiments, a planarization process, such as CMP, can be used to remove any conductive materials on the
top surface 768S of the first insulatinglayer 768. -
FIG. 16B illustrates a perspective view of thestructures 1600, wherein the insulating and dielectric layers are omitted for clarity. Theconductive ring 1384 and theconductive core 1694 form acoaxial contact structure 1696 on thestaircase structure 1060. In some embodiments, thestaircase step 1076 of thestaircase structure 1060 includes two conductive and dielectric layer pairs, the upper layer pair 1074-1 and the lower layer pair 1074-2. Theconductive ring 1384 can be electrically connected to theconductive layer 1072 of the upper layer pair 1074-1 of thestaircase step 1076. Theconductive core 1694 can be electrically connected to theconductive layer 1072 of the lower layer pair 1074-2 of thestaircase step 1076. Theconductive ring 1384 and the insulatingring 1590 form a conductive and insulatingring pair 1697, corresponding to one of the conductive and dielectric layer pairs of thestaircase step 1076. -
FIG. 17A-17D shows another embodiment of the contact structures for the gate electrodes of a three dimensional memory device. InFIG. 17A-17D a portion of the contact structure and staircase structure are illustrated as an example. Similar elements are labeled with the same reference numbers to compare with the corresponding elements inFIG. 13-16A . - In this example, during the formation of the
conductive ring 1384, using similar processes as described inFIG. 13 , the etching process can be performed longer to form afirst contact hole 1786, wherein thefirst contact hole 1786 can extend further through thedielectric layer 450 of the upper layer pair 1074-1 in thestaircase step 1076, exposing theconductive layer 1072 of the lower layer pair 1074-2 (seestructure 1710 inFIG. 17A ). -
FIG. 17B shows a cross-sectional view of anexemplary structure 1720 of a three dimensional memory device, according to some embodiments, wherein thestructure 1720 includes the second insulatinglayer 1488 disposed over thestructure 1710 on theconductive ring 1384, a sidewall of thedielectric layer 450 and the exposed portion of theconductive layer 1072 of the lower layer pair 1074-2 of thestaircase step 1076. -
FIG. 17C shows a cross-sectional view of anexemplary structure 1730 of a three dimensional memory device, according to some embodiments, wherein thestructure 1730 includes an insulatingspacer 1790 and acontact hole 1792, wherein thecontact hole 1792 extends through the second insulatinglayer 1488 at the bottom, exposing theconductive layer 1072 of the lower layer pair 1074-2 of thestaircase step 1076. -
FIG. 17D shows a cross-sectional view of anexemplary structure 1740 of a three dimensional memory device, according to some embodiments, wherein thestructure 1740 includes aconductive core 1794, wherein the conductive core 1974 can be made from a similar material as theconductive core 1694 and formed by a similar technique. In this example, acoaxial contact structure 1796, similar to thecoaxial contact structures 1696 is formed. - Through the
coaxial contact structures 1696/1796, the electrical conductive path for the gate electrode of each memory cell can be wired up to the surface of the wafer, enabling various configurations of word lines and select gates for the 3D memory in the back-of-line process. - After forming
structure 1600/1740, fabrication of 3D memory device can be resumed with back-end-of-line (BEOL) metal interconnects, and are known to a person with ordinary skill in the art. In some embodiments, a second session of word line stack can be added to thestructure 1600/1740 to further increase the vertical number of memory cells. - In some embodiments, the
staircase structure 1060 can include a plurality ofstaircase steps 1076, eachstaircase step 1076 having N number of conductive and dielectric layer pairs 1697, wherein N is a whole number no less than two. In this example, there can be N−1 number of conductive and insulating ring pairs 1697 in addition to aconductive core 1694. Each conductive and insulatingring pair 1697 includes oneconductive ring 1384 and one insulatingring 1590, wherein the insulatingring 1590 is disposed to surround a sidewall of theconductive ring 1384 and is configured to electrically isolate theconductive ring 1384 from anotherconductive ring 1384 or theconductive core 1694. Theconductive core 1694 is located in the center of thecoaxial contact structure 1696. In some embodiments, theconductive core 1694 can also include an insulating core that fills possible seams or holes in theconductive core 1694. - The
conductive core 1694 and theconductive rings 1384 can be arranged so that theconductive rings 1384 make electrical contact with theconductive layer 1072 of a corresponding conductive anddielectric layer pair 1697 of thestaircase step 1076. An outer conductive ring with a larger diameter can connect to theconductive layer 1072 of an upper conductive and dielectric layer pair of thestaircase step 1076. An inner conductive ring with a smaller diameter can connect to theconductive layer 1072 of a lower conductive and dielectric layer pair of thestaircase step 1076. The upper conductive and dielectric layer pair is farther away from the substrate, whereas the lower conductive and dielectric layer pair is closer to the substrate. Theconductive core 1694 can connect to the bottommost conductive layer, e.g., the pair closest to the substrate, within thestaircase step 1076 of N number of conductive and dielectric layer pairs. - In some embodiments, the
conductive rings 1384 extend through the first insulatinglayer 768 to contact theconductive layer 1072 of thestaircase structure 1060. In some embodiments, theconductive rings 1384 also extend through thebarrier layer 664 to contact theconductive layer 1072 of thestaircase structure 1060. In some embodiments, a gate dielectric layer can be disposed on theconductive layer 1072. In this example, theconductive rings 1384 extend further through the gate dielectric layer to contact the conductive layer of thestaircase structure 1060. - In some embodiments, the insulating
ring 1590 of the conductive and insulatingring pair 1697 can be disposed to surround a sidewall of the conductive layer of the staircase structure in addition to the sidewall of the conductive ring. In some embodiments, the insulating ring can be disposed on a sidewall of the dielectric layer of the staircase step of N number of conductive and dielectric layer pairs (similar to the structure shown inFIG. 17D ). - By using the coaxial contact structure to connect two or more conductive layers of the staircase structure, the number of staircase steps can be reduced and thereby the overall lateral dimension of the staircase structure can be reduced. Accordingly the area of staircase region 210 (shown in
FIG. 2A ) can be greatly reduced, and higher density memory storage can be achieved. -
FIG. 18 illustrates anexemplary method 1800 for forming staircase and contact structures for a three-dimensional memory array, according to some embodiments. The process steps of themethod 1800 can be used to form memory device structures illustrated inFIGS. 4-16A . The process steps shown inmethod 1800 are not exhaustive and other process steps can be performed as well before, after, or between any of the illustrated process steps. In some embodiments, some process steps ofexemplary method 1800 can be omitted or include other process steps that are not described here for simplicity. In some embodiments, process steps ofmethod 1800 can be performed in a different order and/or vary. - At
process step 1810, a dielectric film stack is disposed on a substrate. The dielectric film stack can be thedielectric film stack 445 inFIG. 4 , with alternating dielectric (first dielectric) and sacrificial (second dielectric) layers. The dielectric and sacrificial layers are similar to thedielectric layer 450 and thesacrificial layer 452 inFIG. 4 and can be disposed using a similar technique. The dielectric layer and the sacrificial layer below are called an alternating dielectric layer pair. - At
process step 1815, a dielectric staircase is formed in the dielectric film stack. An example of the dielectric staircase is shown as thedielectric staircase 560 inFIG. 5 , wherein the dielectric staircase includes a plurality of staircase layers, e.g., staircase steps. Each staircase step includes two or more alternating dielectric layer pairs. As an example,FIG. 5 depicts a dielectric staircase with two alternating dielectric layer pairs. The plural steps of the dielectric staircase can be formed by applying a repetitive etch-trim process on the dielectric film stack. First, a patterning mask is disposed and patterned on the dielectric film stack. Then, portions of the dielectric film stack can be exposed and etched in a direction perpendicular to a main surface of the substrate until portions of the two dielectric layer pairs are removed. Afterwards, the patterning mask is trimmed laterally, in a direction parallel to the main surface of the substrate. The etching and trimming processes can be repeated until a dielectric staircase step closest to the main surface of the substrate is formed. Finally, the patterning mask can be removed. - At
process step 1820, a barrier layer is disposed over the dielectric staircase, wherein the barrier layer can be thebarrier layer 664 inFIG. 6 and can be made of a similar material and formed using a similar technique. - At
process step 1825, a first insulating layer is disposed over the dielectric staircase. - In some embodiments, the first insulating layer is disposed on the barrier layer. The first insulating layer can be the first insulating
layer 768 inFIG. 7 . Next, a planarization process, such as chemical mechanical polishing (CMP) or reaction-ion-etching, can be performed to form a coplanar surface. An example of the structure is shown inFIG. 7 . - At
process step 1830, a plurality of memory strings are formed in the dielectric film stack with alternating dielectric layer pairs. The memory string is similar to thememory string 212 inFIG. 8 , and includes a memory film, a channel layer and a core filling film. - At
process step 1835, the dielectric film stack of alternating dielectric layer pairs is patterned to form a plurality of slit openings. The slit openings extend horizontally along the dielectric staircase and extend vertically through the dielectric film stack. Next, the sacrificial layers of the dielectric staircase are removed horizontally from the slit openings to form a plurality of horizontal tunnels in the staircase structure. After removing the sacrificial layers, the memory film of the memory strings are exposed inside the plurality of tunnels.FIG. 9 shows an example of the structure after removing the sacrificial layers. - At
process step 1840, conductive materials are disposed inside the horizontal tunnels, forming a staircase structure with alternating conductive and dielectric layers, which is similar to thestaircase structure 1060 inFIG. 10 . The conductive layer can be made of a similar material as theconductive layer 1072 and can be disposed using a similar technique. In some embodiments, a gate dielectric layer can be disposed on sidewalls of the horizontal tunnels prior to the conductive layer deposition, wherein the gate dielectric layer includes high-k dielectric material, silicon oxide, silicon nitride or silicon oxynitride. After replacing the sacrificial layer with the conductive layer, the staircase structure include a plurality of staircase steps, each having two conductive and dielectric layer pairs, e.g., upper layer pair and lower layer pair. - At
process step 1845, the first insulating layer is patterned, forming a plurality of first contact holes. The first contact holes extend through the first insulating layer and the optional barrier layer and expose the conductive layer of upper layer pair of the staircase step. Thefirst contact holes 1180 inFIG. 11 is an example of the plurality of first contact holes. - At
process step 1850, a conductive film is disposed over the staircase structure. The conductive film is disposed on the exposed portion of the conductive layer of the staircase structure and also on a sidewall of the first contact hole. The conductive film can be theconductive film 1282 inFIG. 12 , and can be disposed using a similar technique. - At
process step 1855, the conductive film at the bottom of the first contact holes is removed through anisotropic etching, forming conductive rings along a sidewall of the first insulating layer. Examples of the conductive rings are shown inFIG. 13 as the conductive rings 1384. The conductive rings can be made of a similar material as theconductive rings 1384 and be formed using a similar technique. - At
process step 1860, a second insulating layer is disposed over the staircase structure on the conductive rings. The second insulating layer is similar to the second insulatinglayer 1488 inFIG. 14 and can be made of a similar material using a similar technique. - At
process step 1865, a plurality of insulating rings are formed by anisotropic etching of the second insulating layer. The insulating ring surrounds a sidewall of the conductive ring as well as an exposed portion of the conductive layer of the upper layer pair in the staircase step. During the etching process, the dielectric layer of the upper layer pair can also be removed and the conductive layer of the lower layer pair can be exposed. A plurality of second contact holes are formed accordingly. An example of the insulating rings and second contact holes is shown inFIG. 15 , as the insulatingrings 1590 and thesecond contact hole 1592. - At
process step 1870, a plurality of conductive cores are formed inside the second contact holes. The conductive core contact the conductive layer of the lower layer pair in the staircase step. The conductive core can be theconductive core 1694 inFIG. 16 , and can be formed using a similar technique. A planarization process, for example CMP, can be used to form a coplanar surface. From top down, the conductive ring, insulating ring and the conductive core form a coaxial contact structure. The coaxial contact structures can provide electrical connections to each of the conductive layer of the staircase structure. With two conductive and dielectric layer pairs per staircase step, the number of contact structures can be reduced to half, saving the area of staircase region. From these coaxial contact structures, back-end-of-line processes can be resumed with metal interconnect lines to form a functional 3D NAND memory. - In some embodiments, the
staircase structure 1060 can include a plurality ofstaircase steps 1076, eachstaircase step 1076 having N number of conductive and dielectric layer pairs 1697, wherein N is a whole number no less than two. In this example, there can be N−1 number of conductive and insulating ring pairs 1697 in addition to aconductive core 1694. N−1 number of conductive and insulating ring pairs and the conductive core can be formed using similar processes as described in process steps 1845-1870. - In some embodiments, to form the N−1 number of conductive and insulating ring pairs, a first contact hole can be formed to expose a conductive layer in one of the N number of conductive and dielectric layer pairs of the staircase step in the staircase structure. Then a conductive film can be disposed on a sidewall of the contact hole and the exposed conductive layer. Next, the conducive film and a portion of the conductive layer from the bottom of the first contact hole can be removed to form a conductive ring, wherein a bottom of the conductive ring is formed to contact the conductive layer in one of the N number of conductive and dielectric layer pairs of the staircase step in the staircase structure. In some embodiments, the dielectric layer of the next conductive and dielectric layer pair can also be removed during the etching process for the conductive ring.
- In some embodiments, a second insulating layer can be disposed in the first contact hole and the second insulating layer can then be removed from the bottom of the first contact hole to form an insulating ring, thereby surrounding a sidewall of the conductive ring and a sidewall of the conductive layer is exposed in the first contact hole. The cyclic processes for the next conductive and insulating ring pairs resume, starting by forming a second contact hole to expose the next conductive layer in the staircase step, etc.
- In some embodiments, the conductive core of the coaxial contact structure can be formed last. After forming a contact hole to expose the bottommost conductive layer, e.g., closest to the substrate, in the staircase step of N number of conductive and dielectric layer pairs, a conductive material can be disposed to fill the contact hole, and a conductive core can be formed to contact the bottommost conductive layer using a planarization process, such as chemical mechanical polishing. The conductive material outside the contact hole can be removed and the structure can be formed with a coplanar surface.
- Accordingly, a staircase structure is formed with a plurality of staircase steps, each step having N number of conductive layers. A plurality of coaxial contact structures are formed on the staircase structure. Each coaxial contact structure can provide N number of conductive paths to connect to the N number of the conductive layers, and to the word lines for the vertically stacked memory strings. By sharing contact structures, the lateral dimension of the staircase structure can be greatly reduced, the storage density of the 3D memory devices can be increased.
- Various embodiments in accordance with the present disclosure provide a 3D memory device with smaller die size, higher device density, and improved performance compared with other 3D memory devices.
- Accordingly, various embodiments of three-dimensional memory device and methods of making the same are described in the present disclosure.
- In some embodiments, the three-dimensional memory structure includes a film stack disposed on a substrate, wherein the film stack includes a plurality of conductive and dielectric layer pairs, each conductive and dielectric layer pair having a conductive layer and a first dielectric layer. The three-dimensional memory structure also includes a staircase structure formed in the film stack, wherein the staircase structure includes a plurality of steps, each staircase step having two or more conductive and dielectric layer pairs. The three-dimensional memory structure further includes a plurality of coaxial contact structures formed in a first insulating layer over the staircase structure, wherein each coaxial contact structure includes one or more conductive and insulating ring pairs and a conductive core, wherein each conductive and insulating ring pair includes a conductive ring and an insulating ring.
- In some embodiments, a method for forming a three-dimensional memory structure includes disposing a dielectric film stack on a substrate, wherein the dielectric film stack includes a plurality of alternating dielectric layer pairs, each alternating dielectric layer pair having a first dielectric layer and a second dielectric layer different from the first dielectric layer. The method also includes forming a dielectric staircase in the dielectric film stack, wherein the dielectric staircase includes a plurality of steps, each dielectric staircase step having two or more alternating dielectric layer pairs. The method further includes disposing a first insulating layer on the dielectric staircase, forming a plurality of memory strings in the dielectric film stack, and replacing the second dielectric layers with conductive layers to form a staircase structure with a plurality of steps, wherein each staircase step includes two or more conductive and dielectric layer pairs, each conductive and dielectric layer pair having a conductive layer and the first dielectric layer. The method also includes forming a plurality of coaxial contact structures on the staircase structure.
- The foregoing description of the specific embodiments will so fully reveal the general nature of the present disclosure that others can, by applying knowledge within the skill of the art, readily modify and/or adapt, for various applications, such specific embodiments, without undue experimentation, and without departing from the general concept of the present disclosure. Therefore, such adaptations and modifications are intended to be within the meaning and range of equivalents of the disclosed embodiments, based on the disclosure and guidance presented herein. It is to be understood that the phraseology or terminology herein is for the purpose of description and not of limitation, such that the terminology or phraseology of the present specification is to be interpreted by the skilled artisan in light of the disclosure and guidance.
- Embodiments of the present disclosure have been described above with the aid of functional building blocks illustrating the implementation of specified functions and relationships thereof. The boundaries of these functional building blocks have been arbitrarily defined herein for the convenience of the description. Alternate boundaries can be defined so long as the specified functions and relationships thereof are appropriately performed.
- The Summary and Abstract sections can set forth one or more but not all exemplary embodiments of the present disclosure as contemplated by the inventor(s), and thus, are not intended to limit the present disclosure and the appended claims in any way.
- The breadth and scope of the present disclosure should not be limited by any of the above-described exemplary embodiments, but should be defined only in accordance with the following claims and their equivalents.
Claims (20)
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US20230086425A1 (en) | 2023-03-23 |
CN109716521A (en) | 2019-05-03 |
WO2020118575A1 (en) | 2020-06-18 |
TW202023038A (en) | 2020-06-16 |
US11552091B2 (en) | 2023-01-10 |
US11910599B2 (en) | 2024-02-20 |
US20210265375A1 (en) | 2021-08-26 |
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