US20200056304A1 - Carbon fibers which can be produced regeneratively or part-regeneratively from co2 using combined production methods - Google Patents

Carbon fibers which can be produced regeneratively or part-regeneratively from co2 using combined production methods Download PDF

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Publication number
US20200056304A1
US20200056304A1 US16/346,638 US201716346638A US2020056304A1 US 20200056304 A1 US20200056304 A1 US 20200056304A1 US 201716346638 A US201716346638 A US 201716346638A US 2020056304 A1 US2020056304 A1 US 2020056304A1
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Prior art keywords
polyacrylonitrile
synthesis
carbon fibers
methanol
production
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Abandoned
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US16/346,638
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English (en)
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Kolja Kuse
Uwe Arnold
Thomas Brück
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    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N1/00—Microorganisms, e.g. protozoa; Compositions thereof; Processes of propagating, maintaining or preserving microorganisms or compositions thereof; Processes of preparing or isolating a composition containing a microorganism; Culture media therefor
    • C12N1/12—Unicellular algae; Culture media therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F120/42—Nitriles
    • C08F120/44—Acrylonitrile
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/42—Nitriles
    • C08F220/44—Acrylonitrile
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
    • D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
    • D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
    • D01F9/14—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
    • D01F9/20—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products
    • D01F9/21—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F9/22—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from polyaddition, polycondensation or polymerisation products from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyacrylonitriles
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
    • C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
    • C12P7/18—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic polyhydric
    • C12P7/20—Glycerol
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P7/00—Preparation of oxygen-containing organic compounds
    • C12P7/64—Fats; Fatty oils; Ester-type waxes; Higher fatty acids, i.e. having at least seven carbon atoms in an unbroken chain bound to a carboxyl group; Oxidised oils or fats
    • C12P7/6436—Fatty acid esters
    • C12P7/6445—Glycerides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T50/00—Aeronautics or air transport
    • Y02T50/60—Efficient propulsion technologies, e.g. for aircraft
    • Y02T50/678—Aviation using fuels of non-fossil origin

Definitions

  • the Paris Agreement of December 2015 challenges the international community to keep the average global temperature increase below 2° C. by 2100 and beyond. For this purpose, measures are required which. (although) increasing the effort in process technology, significantly increase the efficiency of the conversion of CO2 into usable regeneratively produced material.
  • the materials consists essentially of two categories of materials that drive the world economy.
  • One category includes materials such as fuels, lubricating oils and other liquid or gaseous fuels for the operation of gas turbines, diesel power plants, the propulsion of aircraft, vehicles and ships, as well as the heating of buildings or the operation of cookers.
  • the second category involves the production of building and construction materials that can be produced from CO2.
  • Another goal of limiting global warming is the conversion of CO2 from fossil or natural sources into construction and building materials, as described in PCT/EP2009/008497.
  • CO2 sequestration measures are therefore necessary at the beginning of such a new material production process chain, since the required CO2 from these sources is much cheaper to obtain or sequester than directly from the air, which has only a comparatively low CO2 concentration.
  • An energy- and mass-efficient method for adsorption and binding of CO2 from atmospheric or sequestered sources is the production of algal biomass, which is about 20 times better than the equivalent CO2 binding with terrestrial plants due to the high growth rate of the organisms.
  • the large-scale production of algae biomass is recommended for economic reasons in technically simple open cultivation basins, which are low-cost industrially scale.
  • carbon fiber base material so-called precursors are generated in a cost effective manner with reasonable space requirement from the CO2 through several different alternative paths or process chains, from which then with the help of carbonisation (through pyrolysis) tensile and especially very rigid carbon fibers are produced, which have a solid state of aggregation over millions of years.
  • carbon dioxide sequestered CO2 is introduced into algae tanks in addition to the amount of CO2 absorbed from the air to prevent it from entering the atmosphere.
  • glycerol glycerol
  • glycerol is obtained from the fats and oils of the algal biomass, with initially also a relatively large amount of biodiesel being produced as the basis for fuel such as kerosene or truck and ship fuel.
  • This fuel can be burned at a later stage of the installation of plants in biodiesel power plants, either for power generation, whereby the sequestered CO2 is passed back into the algae tanks and is thus circulated, or for example by gasification to be supplied in whole or in part to the precursor production.
  • the aim is to control the ratio of the production of valuable building materials for the industry as well as valuable fuel for the industry as needed. This need can be very different for example today compared to the future.
  • the algae cultivation tanks which are preferably installed in sunny areas, absorb free CO2 from the ambient air when the air is preferably pumped directly to the algae tank water with the appropriate technology under high pressure and with the finest nozzles.
  • Triglycerides, triglycerides, also glycerol triesters, more rarely obsolete referred to as neutral fats, are triple esters of the trivalent alcohol glycerol with three acid molecules and should according to the IUPAC recommendation exclusively referred to as triacylglycerols, short TAGs, (or exact tri-O-acylglycerole).
  • Tri refers to three acyl acid residues esterified with glycerol.
  • Triacylglycerols with three fatty acids are the compounds in fats and fatty oils. Natural fats consist for the most part of triglycerols with three long-chain fatty acids, which usually consist of unbranched chains with 4 to 26, typically 12 to 22 carbon atoms. These are liquid at room temperature, and are also referred to as oils or, to distinguish them from mineral oils or essential oils, fatty oils. Pure triacylglycerols of fatty acids are also referred to as neutral fats. Suitable algae strains, including saltwater algae, are capable of producing large quantities of these fatty oils.
  • Fischer-Tropsch synthesis as the basis for the production of acrylonitrile from propene via the intermediate step methanol has not been described in the prior art and has in comparison to the production of algal biomass the advantage of a comparatively small area consumption, but also has the disadvantage of comparably higher costs, which can, however, be compensated by an initially correspondingly high CO2 emissions trading price. In the end, however, one would like to get along without emission rights in the long term and therefore reduce the production price.
  • the electrolysis to produce the amounts of hydrogen required for the Fischer-Tropsch process releases quantities of oxygen needed for the process of producing acrylonitrile from the algal mass. This leads to an increase in the overall efficiency and thus to a reduction in the price of the polyacrylonitrile fibers.
  • the combination of the methods yields further advantages as a by-product.
  • Process chain 4 like 1 but with upstream MeOH production via BtL/MeOH synthesis a) without energetic biodiesel use b) with energetic biodiesel use 5.
  • Process chain 5. CO2 ⁇ FTS+MeOH synthesis ⁇ MOBIL (MtP) ⁇ SOHIO ⁇ DRALON a) without upstream electrolysis for H2 supply b) with upstream electrolysis for H2 supply 6.
  • Process chain 7 like 6 but with autothermal reforming (ATR) of biodiesel with partial biodiesel oxidation and FTS/MeOH synthesis a) high-temperature ATR, air supply, max. syngas b) low-temperature ATR, exclusion of air, max. propylene c) as a) but with +9% CO2 feed towards FTS d) like a) but with +50% CO2 feed towards FTS 8.
  • Process chain 8 like 7a but with upstream BtL/MeOH synth. for syngas use a) 60% of the total biomass supply towards BtL b) 90% of the total biomass supply towards BtL 9.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biotechnology (AREA)
  • Medicinal Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Genetics & Genomics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Textile Engineering (AREA)
  • Biochemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Microbiology (AREA)
  • Virology (AREA)
  • Cell Biology (AREA)
  • Tropical Medicine & Parasitology (AREA)
  • Botany (AREA)
  • Biomedical Technology (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Inorganic Fibers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Micro-Organisms Or Cultivation Processes Thereof (AREA)
  • Artificial Filaments (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
US16/346,638 2016-11-01 2017-10-30 Carbon fibers which can be produced regeneratively or part-regeneratively from co2 using combined production methods Abandoned US20200056304A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE202016006700.2U DE202016006700U1 (de) 2016-11-01 2016-11-01 Carbonfaser
DE202016006700.2 2016-11-01
PCT/EP2017/001269 WO2018095559A1 (fr) 2016-11-01 2017-10-30 Fibres de carbone pouvant être fabriquées à partir de co2 de manière purement régénérative ou partiellement régénérative à l'aide de procédés de fabrication combinés

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2017/001269 A-371-Of-International WO2018095559A1 (fr) 2016-11-01 2017-10-30 Fibres de carbone pouvant être fabriquées à partir de co2 de manière purement régénérative ou partiellement régénérative à l'aide de procédés de fabrication combinés

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US17/487,503 Continuation US11898275B2 (en) 2016-11-01 2021-09-28 Carbon fibers which can be produced regeneratively or part-regeneratively from CO2 using combined production methods

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US17/487,503 Active US11898275B2 (en) 2016-11-01 2021-09-28 Carbon fibers which can be produced regeneratively or part-regeneratively from CO2 using combined production methods

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US (2) US20200056304A1 (fr)
EP (1) EP3610057A1 (fr)
JP (1) JP7075062B2 (fr)
KR (1) KR102471716B1 (fr)
CN (1) CN110168153B (fr)
AU (2) AU2017366602A1 (fr)
BR (1) BR112019008977B1 (fr)
CA (1) CA3042282A1 (fr)
CL (1) CL2019001201A1 (fr)
DE (1) DE202016006700U1 (fr)
MX (1) MX2019005128A (fr)
PE (1) PE20191164A1 (fr)
WO (1) WO2018095559A1 (fr)
ZA (1) ZA201903224B (fr)

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Publication number Priority date Publication date Assignee Title
DE202022000235U1 (de) * 2022-01-29 2022-02-11 Britta Waschl Baumaterialien aus Carbonfasern, die aus CO2 hergestellt werden

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0959239A (ja) * 1995-08-22 1997-03-04 Mitsui Toatsu Chem Inc アクリロニトリルの製造方法
FR2912742B1 (fr) 2007-02-16 2010-03-05 Arkema France Procede de synthese d'acrylonitrile a partir de glycerol
WO2008144448A1 (fr) * 2007-05-18 2008-11-27 Primafuel, Inc. Processus en phase gazeuse pour production de monoalcool à partir du glycérol
US7645807B1 (en) * 2007-07-03 2010-01-12 G.D.O. Inc. Production of biodiesel and a side stream of crude glycerol which is converted to methanol
FI20085400A0 (fi) * 2007-11-09 2008-04-30 Upm Kymmene Oyj Menetelmä jäteveden integroidulle käsittelylle
FR2935148B1 (fr) * 2008-08-25 2010-08-27 Arkema France Procede de fabrication de fibres de carbone.
WO2011043151A1 (fr) * 2009-10-08 2011-04-14 三井化学株式会社 Procédé pour la production de méthanol
JP2011084528A (ja) 2009-10-16 2011-04-28 Mitsubishi Chemicals Corp プロピレンの製造方法
CN102527225B (zh) * 2010-12-17 2016-04-06 中国科学院过程工程研究所 一种使用可再生的电石渣捕集烟气中二氧化碳的方法
US20140165569A1 (en) * 2011-05-04 2014-06-19 Ztek Corporation Zero emission power plant with co2 waste utilization
US9458569B2 (en) * 2013-01-16 2016-10-04 Clean-Vantage Llc Wet oxidation of biomass
DE202015000375U1 (de) 2015-01-17 2015-03-02 Kolja Kuse Carbonisierungsreaktor zur kombinierten Erzeugung von Konstruktionsmaterial und Strom mit Hilfe von Sonnenlicht

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Publication number Publication date
AU2017366602A1 (en) 2019-06-20
KR102471716B1 (ko) 2022-11-28
EP3610057A1 (fr) 2020-02-19
RU2019115459A3 (fr) 2021-02-26
CL2019001201A1 (es) 2019-10-04
JP7075062B2 (ja) 2022-05-25
CN110168153B (zh) 2022-09-30
BR112019008977B1 (pt) 2022-12-13
PE20191164A1 (es) 2019-09-09
CA3042282A1 (fr) 2018-05-31
MX2019005128A (es) 2019-11-12
JP2019536919A (ja) 2019-12-19
BR112019008977A2 (pt) 2019-07-09
RU2019115459A (ru) 2020-11-23
US11898275B2 (en) 2024-02-13
KR20190087447A (ko) 2019-07-24
ZA201903224B (en) 2021-07-28
DE202016006700U1 (de) 2017-04-26
CN110168153A (zh) 2019-08-23
AU2022213744A1 (en) 2022-09-01
US20220081806A1 (en) 2022-03-17
WO2018095559A1 (fr) 2018-05-31

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