US20170035058A1

US20170035058A1 - Insecticidal Compositions and Method for Insect Control

Info

Publication number: US20170035058A1
Application number: US15/299,901
Authority: US
Inventors: James F. Walter; Reid M. Ipser
Original assignee: FMC Corp
Current assignee: FMC Corp
Priority date: 2010-02-24
Filing date: 2016-10-21
Publication date: 2017-02-09
Also published as: WO2011106367A3; JP2013520510A; US9480251B2; MX2012009601A; US8658137B2; WO2011106367A2; US20120315222A1; US20140147535A1; KR20130025364A; JP5901544B2; CA2790404A1; BR112012017697A2

Abstract

An environmentally safe, non-phytotoxic pesticidal composition comprising natural plant oils geraniol and cedar oil and methods of controlling insects is provided.

Description

FIELD OF THE INVENTION

The present invention relates to pesticidal compositions containing plant essential oils and to methods of controlling insects using essential oils.

BACKGROUND OF THE INVENTION

Insect pests cause significant losses to plants and plant products as well as attack and annoy humans and animals. In household scenarios, insect pests may act as vectors for diseases and allergic matter. Over the years, synthetic chemical pesticides such as synthetic pyrethroids, chlorinated hydrocarbons, organophosphates, carbamates and the like, have provided an effective means of pest control.
However, the public has become increasingly concerned that the widespread use of synthetic chemical pesticides may have caused detrimental environmental effects that are harmful to humans and other animals. For instance, the public has become concerned about the amount of residual chemicals that persist in food, ground water and the environment, and that may be toxic, carcinogenic or otherwise incompatible to humans, domestic animals and/or fish. Moreover, some target pests have even shown an ability to develop resistance to many commonly used synthetic chemical pesticides. In recent times, regulatory guidelines have encouraged a search for potentially less dangerous pesticidal compositions via stringent restrictions on the use of certain synthetic pesticides.
Accordingly, there is a great need for environmentally safe and pesticidally effective compositions that contain no synthetic pyrethroids, chlorinated hydrocarbons, organophosphates, carbamates, and the like, that may be used against insect pests. It would also be advantageous to provide easy to use, inexpensive compositions and methods of using these compositions for controlling these pests that provide the benefits of quick knockdown and eventual mortality of the pests.

SUMMARY OF THE INVENTION

A primary object of the present invention is to provide environmentally safe, non-phytotoxic and pesticidally effective compositions for agriculture or home use against insects. In particular, the present invention provides pesticidal compositions containing natural plant oils that will not harm the environment. Other aspects of the present invention will also be apparent.

DETAILED DESCRIPTION OF THE INVENTION

The present invention provides environmentally safe, non-phytotoxic pesticidal compositions comprising natural plant oils. In particular, the present invention provides a pesticidal concentrate, an aerosol formulation or a Ready-To-Use (RTU) liquid spray composition of the active compounds generiol and cedar oil in admixture with a suitable carrier, a surface active agent and optionally an aerosol propellant.
Use of pesticidal compositions of the present invention generally results in quick knockdown and 100% mortality when compared to the individual components alone. As such, they are advantageously employed as pesticidal agents in uses such as, without limitation, households, agriculture, organic farming, professional pest control, pet bedding, foliage application, seedling box treatment, planting treatment and ornamentals.
A particular embodiment of the present invention is an insecticidal composition comprising:

- a) an active ingredient component containing geraniol and cedar oil,
- b) a suitable liquid carrier,
- c) at least one surface active agent, and
- d) optionally an aerosol propellant.

Another embodiment of the present invention is a method for controlling insects comprising applying an insecticidally effective amount of an insecticidal composition comprising:

- a) an active ingredient component containing geraniol and cedar oil,
- b) a suitable liquid carrier, and
- c) at least one surface active agent, to a locus where insect control is needed or expected to be needed.

Geraniol refers to trans-3,7-dimethyl-2,6-octadien-1-ol, CAS number 106-24-1.
Cedar oil, also known as cedar-wood oil, refers to the volatile whole oil extracts derived principally from the heartwood of Juniperus virginiana or Juniperus ashei. The CAS number for cedar oil is 8000-27-9.
The term “pesticidal concentrate” refers to a mixture of the active ingredients geraniol and cedar oil in a suitable liquid carrier and a surface active agent that requires additional dilution prior to use as a RTU spray or aerosol.
The term “Ready-To-Use liquid spray” as used herein, means a composition of geraniol and cedar oil in a suitable liquid carrier and a surface active agent that can be used without further dilution as a spray delivered by, for example, hand held spray bottles, portable spray tanks, pressurized aerosol spray cans and the like.
It is preferred that the active ingredient geraniol be present in the RTU composition in an amount of from about 0.1% to about 1.0% by weight based on all the components in the total RTU composition, most preferred in an amount of from about 0.4% to about 0.5% by weight based on all the components in the total RTU composition.
It is preferred that the active ingredient cedar oil be present in the RTU composition in an amount of from about 0.01% to about 0.05% by weight based on all the components in the total RTU composition, most preferred in an amount of about 0.02% by weight based on all the components in the total RTU composition.
The term “carrier” as used herein means a liquid material, which may be inorganic or organic and of synthetic or natural origin, with which the active compounds are mixed or formulated to facilitate application of the active ingredients to the locus where insect control is needed. In general, any of the materials customarily employed in formulating pesticides, herbicides, or fungicides, are suitable for use with the present invention. Preferred carriers include, but are not limited to, iso-paraffinic hydrocarbons, C₁to C₁₂straight or branched chain alcohols and water. The most preferred carrier is water. The carrier is present in the RTU composition in an amount that provides the correct dilution of the active ingredients.
The preferred surface active agent is sodium laureth sulfate. It is preferred that the surface active agent is present in the RTU composition in an amount of from about 0.1% to about 1.0% by weight based on all the components in the total RTU composition.
When using a pressurized aerosol spray can to deliver the RTU composition, aerosol propellants such as carbon dioxide, liquefied petroleum gasses, hydrofluorocarbons and known hydrofluorocarbon replacements are particularly useful. Carbon dioxide is the most preferred propellant.
The pesticidal compositions and methods of the present invention are effective against different species of agricultural and household pests and it will be understood that the insects exemplified and evaluated in the working Examples herein are representative of such a wider variety.
The following examples further illustrate the present invention, but, of course, should not be construed as in any way limiting its scope. The examples set forth certain data demonstrating the improved efficacy of the compositions of the present invention.

EXAMPLE 1

Pesticidal Effects of Geraniol, Cedar Oil and Mixtures Thereof

Formulations of geraniol, cedar oil and mixtures thereof were evaluated for contact toxicity against the Lasius ant (Lasius niger), lady beetle (Harmonia axyridis), brown stink bug (Halyomorpha halys), green peach aphid (Myzus persicae), house cricket (Acheta domesticus) and longtail mealy bug (Pseudococcus longispinus). The plant oil test solutions were prepared by dissolving the appropriate amount of the plant oil(s) in deionized water containing 0.5% by weight sodium laureth sulfate, for example 4.4 grams of geraniol was dissolved in 1 liter of deioinized water containing 5 grams of sodium laureth sulfate to prepare a 0.44% test solution of geraniol. Each test solution was poured into a 16 ounce spray can, a valve was installed and the can was charged with carbon dioxide as the propellant. Direct spraying of the test substance onto insects was performed to determine the efficacy of each test solution as follows:
Lasius ant and lady beetle test—In separate tests, ten insects of each species were placed onto an asphalt slab and directly sprayed for 2 seconds with the appropriate test solutions. The time to 100% percent knockdown (insects stopped moving on their own), time for 100% mortality (insects did not respond to probing) and recovery from knockdown was recorded and is summarized in Table 1 below.
Brown stink bug and house cricket test—In separate tests, ten insects of each species were placed onto a concrete slab and directly sprayed for 2 seconds with the appropriate test solutions. The time to 100% percent knockdown (insects stopped moving), time for 100% mortality (insects did not respond to probing) and recovery from knockdown was recorded and is summarized in Table 1 below.
Green peach aphid test—In separate tests, a bell pepper plant, infested with green peach aphids, was sprayed with the appropriate test solution until runoff. The time to 100% percent knockdown (insects stopped moving on their own), time for 100% mortality (insects did not respond to probing) and recovery from knockdown was recorded and is summarized in Table 1 below.
Longtail mealy bug test—In separate tests, ten longtail mealy bugs were established on several leaves of a variegated Euonymus plant, the infested leaves were sprayed with the appropriate test solution until runoff. The percent mortality was assessed after 24 hours and is summarized in Table 1 below.

TABLE 1

Insect Knockdown and Mortality Caused by Test Solutions of Geraniol,
Cedar Oil and Mixtures Thereof

		Time to		Recovery
Insect		100%	Time to 100%	from
Pest	Test Solution	Knockdown	mortality	knockdown

Lasius	0.44% geraniol	9 seconds	20 seconds	None
ant	0.02% cedar oil	29 seconds	No mortality	All
				recovered
	0.44% geraniol	4 seconds	9 seconds	None
	0.02% cedar oil
Lady	0.44% geraniol	20 seconds	60 seconds	None
beetle	0.02% cedar oil	30 seconds	No mortality	All
				recovered
	0.44% geraniol	10 seconds	30 seconds	None
	0.02% cedar oil
Brown	0.44% geraniol	20 seconds	90 seconds	None
stink bug	0.02% cedar oil	60 seconds	No mortality	All
				recovered
	0.44% geraniol	15 seconds	30 seconds	None
	0.02% cedar oil
Green	0.44% geraniol	No apparent	3 hours	None
peach		knockdown
aphid	0.02% cedar oil	No apparent	No mortality	All
		knockdown		recovered
	0.44% geraniol	30 seconds	1 hour	None
	0.02% cedar oil
House	0.44% geraniol	60 seconds	3 hours	None
cricket	0.02% cedar oil	No apparent	No mortality	All
		knockdown		recovered
	0.44% geraniol	30 seconds	25 minutes	None
	0.02% cedar oil
Longtail	0.44% geraniol	Not	50% mortality	Not
mealy bug		Determined	at 24 hours	Determined
	0.02% cedar oil	Not	0% mortality	Not
		Determined	at 24 hours	Determined
	0.44% geraniol	Not	100% mortality	Not
	0.02% cedar oil	Determined	at 24 hours	Determined

These data demonstrate that cedar oil added to geraniol provides a synergistic composition that greatly improves the time to knockdown and quickness to 100% mortality of insects as compared to the individual components and that overall, geraniol and cedar oil mixtures can be used as a safe and effective alternative pesticide for control of household pests.

Those of ordinary skill in the art will appreciate that variations of the invention may be used and that it is intended that the invention may be practiced otherwise than as specifically described herein. Accordingly, this invention includes all modifications encompassed within the spirit and scope of the invention as defined by the following claims.

Claims

1-12. (canceled)

12. A ready to use liquid spray for knocking down and controlling insects comprising:

a) geraniol in amounts ranging from about 0.1% to about 1.0%.

b) Cedar oil in amounts ranging from 0.01% to 0.05%,

c) sodium laureth sulfate, and

d) an aerosol propellant,

wherein all % amounts are weight % based on all the components in the total liquid spray.

13. The liquid spray of claim 11, wherein geraniol is in the amounts ranging from 0.1% to 0.05%.

14. The liquid spray of claim 11, wherein cedar oil is in the amounts ranging up to about 0.02%.

15. The liquid spray of claim 11, wherein the aerosol propellant is selected from the group consisting of carbon dioxide, liquefied petroleum gasses, hydrofluorocarbons and a mixture thereof.

16. The liquid spray of claim 11, wherein sodium laureth sulfate is present in an amount ranging from 0.1% to 1.0%.

17. A method of knocking down insects comprising applying an insecticidally effective amount of a ready to use liquid spray comprising:

a) geraniol in amounts ranging from about 0.1% to about 1.0%.

b) Cedar oil in amounts ranging from 0.01% to 0.05%,

c) sodium laureth sulfate, and

d) an aerosol propellant,

wherein all % amounts are weight % based on all the components in the total liquid spray, and further wherein.

18. The method of claim 17, wherein the aerosol propellant is selected from the group consisting of carbon dioxide, liquefied petroleum gasses, hydrofluorocarbons and a mixture thereof.

19. The method of claim 17, wherein sodium laureth sulfate is present in an amount ranging from 0.1% to 1.0%.

20. The method of claim 17, wherein the insects are selected from the group consisting of Lasius ant, lady bettle, brown stink bug, green peach aphid, house cricket, longtail mealy bug, and combinations thereof.

21. The method of claim 20, wherein 100% mortality of insects is achieved within 24 hours post administration to the site of interest.