JPS62169703A - Insecticidal and acaricidal agent - Google Patents
Insecticidal and acaricidal agentInfo
- Publication number
- JPS62169703A JPS62169703A JP1264486A JP1264486A JPS62169703A JP S62169703 A JPS62169703 A JP S62169703A JP 1264486 A JP1264486 A JP 1264486A JP 1264486 A JP1264486 A JP 1264486A JP S62169703 A JPS62169703 A JP S62169703A
- Authority
- JP
- Japan
- Prior art keywords
- active ingredient
- agent
- salt
- oleate
- animals
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000000895 acaricidal effect Effects 0.000 title claims abstract description 12
- 230000000749 insecticidal effect Effects 0.000 title abstract description 5
- 239000004480 active ingredient Substances 0.000 claims abstract description 10
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 8
- 229940049964 oleate Drugs 0.000 claims abstract description 5
- 239000000642 acaricide Substances 0.000 claims description 7
- 239000002917 insecticide Substances 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 abstract description 7
- 238000003306 harvesting Methods 0.000 abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 6
- 241001465754 Metazoa Species 0.000 abstract description 4
- 239000002671 adjuvant Substances 0.000 abstract description 4
- 239000011734 sodium Substances 0.000 abstract description 3
- 229910052708 sodium Inorganic materials 0.000 abstract description 3
- 241001124076 Aphididae Species 0.000 abstract description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract description 2
- 241000339373 Thrips palmi Species 0.000 abstract description 2
- 235000013399 edible fruits Nutrition 0.000 abstract description 2
- 239000000839 emulsion Substances 0.000 abstract description 2
- 231100000053 low toxicity Toxicity 0.000 abstract description 2
- 239000000344 soap Substances 0.000 abstract description 2
- 235000013311 vegetables Nutrition 0.000 abstract description 2
- 238000005406 washing Methods 0.000 abstract description 2
- 208000019901 Anxiety disease Diseases 0.000 abstract 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 230000036506 anxiety Effects 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000011575 calcium Substances 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical class OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 abstract 1
- 239000000428 dust Substances 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical class CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 abstract 1
- 230000002503 metabolic effect Effects 0.000 abstract 1
- 125000000250 methylamino group Chemical class [H]N(*)C([H])([H])[H] 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000004563 wettable powder Substances 0.000 abstract 1
- -1 amine salt Chemical class 0.000 description 12
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 241000238876 Acari Species 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 241001414989 Thysanoptera Species 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 244000144972 livestock Species 0.000 description 2
- 230000002688 persistence Effects 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- HNMBOGGRDXLHPW-UHFFFAOYSA-N CC(C)C([S+]=P(N)([O-])O)=O Chemical compound CC(C)C([S+]=P(N)([O-])O)=O HNMBOGGRDXLHPW-UHFFFAOYSA-N 0.000 description 1
- 240000008067 Cucumis sativus Species 0.000 description 1
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 241000344246 Tetranychus cinnabarinus Species 0.000 description 1
- 241000219793 Trifolium Species 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 150000007514 bases Chemical class 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明はオレイン酸塩を有効成分としで含有する殺虫殺
ダニ剤に関する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to an insecticide and acaricide containing oleate as an active ingredient.
（従来の技術）
農作物に寄生して害を及ぼす昆虫やダニ類を駆除するた
め各種の化学物質が使用されている。これらの化学物質
は人畜毒性が強がったり、残留性が長く、そのため収穫
期直前での散布ができず殺虫効果の安定性に欠ける場合
が生じたり、昆虫やダニに抵抗性を生じたりする欠点を
有している。(Prior Art) Various chemical substances are used to exterminate insects and mites that parasitize and cause harm to agricultural crops. These chemicals have the disadvantages of being highly toxic to humans and animals, having long persistence, and therefore not being able to be sprayed just before the harvesting period, resulting in inconsistent insecticidal effects, and resistance to insects and mites. have.
（発明が解決しようとする問題点）
本発明の目的は人畜に対する毒性が極めで低く、容易に
代謝分解される殺虫殺ダニ剤を提供することにある。(Problems to be Solved by the Invention) An object of the present invention is to provide an insecticide and acaricide that has extremely low toxicity to humans and livestock and is easily metabolically decomposed.
また本発明の目的は残留性がなく、収穫期直前において
も散布が可能である殺虫殺ダニ剤を提供することにある
。Another object of the present invention is to provide an insecticide and acaricide that does not have residual properties and can be sprayed even just before the harvest period.
（問題点を解決するための手段）
本発明はオレイン酸塩を有効成分として含有する殺虫殺
ダニ剤に係る。(Means for Solving the Problems) The present invention relates to an insecticide and acaricide containing an oleate salt as an active ingredient.
本発明のオレイン酸塩は広く知られているものであり、
無機塩、有機アミン塩のいずれでも使用できる。無機塩
としては例えばナトリウム塩、カリウム塩、カルシウム
塩、マグネシウム塩、亜鉛塩、銅塩、アンモニウム塩等
を挙げることができ、有機アミン塩としては一級アミン
、二級アミン、三級アミンの塩、ビリンン類の塩等の有
機カルボン酸と塩を形成し得る塩基性化合物であればい
ずれでも使用可能である。The oleate salt of the present invention is widely known,
Either an inorganic salt or an organic amine salt can be used. Examples of inorganic salts include sodium salts, potassium salts, calcium salts, magnesium salts, zinc salts, copper salts, and ammonium salts. Examples of organic amine salts include salts of primary amines, secondary amines, and tertiary amines. Any basic compound that can form a salt with an organic carboxylic acid such as a salt of bilins can be used.
本発明の殺虫殺ダニ剤は殺虫殺ダニ作用のある公知の薬
剤、例えば鉱物油、２−ツメチルアミノ−５，６−ノメ
チルー４−ピリミジニルツメチルカーバメート、０．Ｓ
−ジメチルアセチルホスホロアミドチオエート、〇−エ
チルー〇−（４−メチルチオフェニル）−８−プロピル
ホスホロジチオエート等を併用して効果を向」ニさせる
ことも可能であり、又、本発明化合物には活性のない殺
菌作用を付与するために公知の殺菌剤、例えばＮ−（：
’１．５−ノクロロフェニル）−１，２−ツメチルシク
ロプロパン−１，２−ジカルボキシミド等を混合するこ
とも可能である。The insecticidal and acaricidal agent of the present invention includes known agents having insecticidal and acaricidal effects, such as mineral oil, 2-methylamino-5,6-nomethyl-4-pyrimidinyltumethylcarbamate, S
-Dimethylacetylphosphoramidothioate, 〇-ethyl〇-(4-methylthiophenyl)-8-propylphosphorodithioate, etc. can be used in combination to enhance the effect. Known fungicides, such as N-(:
It is also possible to mix 1,5-nochlorophenyl)-1,2-methylcyclopropane-1,2-dicarboximide and the like.
本発明の殺虫殺ダニ剤を施用するに当っては、そのまま
使用してもよく、又、一般に通常農薬の製剤」二使用さ
れる補助剤と混合して、粉剤、水利剤、乳剤、液剤、水
溶剤等にｉｌｌ［て使用しでもよい。この際効果の安定
性及び効果の向上を期するための補助剤としては、例え
ばケイソウ土、カオリン、クレー、ベントナイト、ホワ
イトカーボン、タルク等の増量剤、ポリオキシエチレン
アルキルエーテル、ポリオキシエチレンアルキルフェニ
ルエーテル、ポリオキシエチレンソルビクン脂肪酸エス
テル、ポリオキシエチレン脂肪酸エステル、アルキルベ
ンゼンスルホン酸ナトリウム、リグニンスルホン酸ナト
リウム、アルキル硫酸す］リウム、ポリオキシエチレン
アルキル硫酸ナトリウム等の界面活性剤、ベンゼン、ト
ルエン、キシレン、アセトン、シクロヘキサ７ン、メタ
ノール、エタノール、イソプロピルアルコール、グリセ
リン、エチレングリコール、プロピレングリコール、ノ
オキサン、ツメチルホルムアミド、ツメチルスルホキシ
ド、四塩化炭素等の有機溶媒、水等が使用される。When applying the insecticide and acaricide of the present invention, it may be used as is, or it may be mixed with adjuvants commonly used in conventional agricultural chemical formulations to form powders, irrigation agents, emulsions, liquids, etc. It may also be used in an aqueous solvent. In this case, examples of auxiliary agents to improve the stability and effectiveness of the effect include fillers such as diatomaceous earth, kaolin, clay, bentonite, white carbon, and talc, polyoxyethylene alkyl ether, and polyoxyethylene alkylphenyl. Surfactants such as ether, polyoxyethylene sorbicun fatty acid ester, polyoxyethylene fatty acid ester, sodium alkylbenzene sulfonate, sodium lignin sulfonate, sodium alkyl sulfate, benzene, toluene, xylene, Organic solvents such as acetone, cyclohexane, methanol, ethanol, isopropyl alcohol, glycerin, ethylene glycol, propylene glycol, nooxane, trimethylformamide, trimethylsulfoxide, carbon tetrachloride, water, and the like are used.
本発明の殺虫殺ダニ剤組成物においで補助剤を配合する
場合、その配合割合としては、有効成分量が約１〜９０
重量％、好ましくは約５〜８０重量％になるように補助
剤を添加することによって製剤される。施用量は薬剤の
製剤形態、施用方法、施用時期、対象害虫の種類等によ
って異なるものであり適宜選択されるが、一般的には有
効成分として約５００〜５０００ｐｐｍとなるように希
釈して散布する。When an adjuvant is added to the insecticide and acaricide composition of the present invention, the amount of the active ingredient is about 1 to 90%.
It is formulated by adding adjuvants to a weight %, preferably about 5 to 80 weight %. The amount to be applied varies depending on the formulation form of the drug, the method of application, the time of application, the type of target pest, etc., and is selected as appropriate, but in general, it is diluted to about 500 to 5000 ppm of the active ingredient and then sprayed. .
本希釈液を果樹、そ菜等に散布することにより、薬害も
なく、ハグニ、アブラムシ、ミナミキイロアザミウマ等
を有効に防除することができる。By spraying this diluted solution on fruit trees, vegetable crops, etc., it is possible to effectively control clover, aphids, southern thrips, etc. without causing chemical damage.
（発明の効果）
本発明において使用されるオレイン酸塩は動植物中に広
く存在する天然物油をケン化するとその成分として容易
に得られ、石ケンとしてよく知られている。このため人
畜に対する毒性は極めで低く、容易に代謝分解されるの
で残留性についても何の懸念もなく、更に収穫物を水洗
することによりオレイン酸塩は容易に除去されるため収
穫期直前での散布が可能である利点を有しでいる。(Effects of the Invention) The oleate salt used in the present invention is easily obtained as a component by saponifying natural oils widely present in animals and plants, and is well known as soap. Therefore, the toxicity to humans and livestock is extremely low, and it is easily metabolized and decomposed, so there is no concern about persistence.Furthermore, oleate can be easily removed by washing the harvest with water, so it can be used just before the harvest period. It has the advantage that it can be dispersed.
（実 施 例） 以下に本発明の実施例を挙げて説明する。尚、４一 部とあるのは重量部を示す。(Example) Examples of the present invention will be described below. Furthermore, 41 Parts indicate parts by weight.
実施例１
本発明の有効成分である第１表に記載の各種のオレイン
酸塩８０部、ポリオキシエチレンノニル７エ＝ルエーテ
ル１部及びドデシルベンゼンスルホン酸ナトリウム１部
、水１８部を均一に混合した。Example 1 80 parts of various oleates listed in Table 1, which are the active ingredients of the present invention, 1 part of polyoxyethylene nonyl 7-ether, 1 part of sodium dodecylbenzenesulfonate, and 18 parts of water were uniformly mixed. did.
この調整液剤を所定の濃度に水で希釈して、ナミハダニ
が約５０匹寄生しているインゲン葉に均一に散布した。This prepared solution was diluted with water to a predetermined concentration and uniformly sprayed on kidney bean leaves infested with about 50 red spider mites.
２４時間後、化ダニを調査し、化ダニ率を求めた。その
結果を第１表に示した。After 24 hours, the mites were investigated and the rate of mites was determined. The results are shown in Table 1.
第 １ 表 酸価２０６の脂肪酸を使用した。Chapter 1 Table A fatty acid with an acid value of 206 was used.
実施例２
実施例１と同様に調整した液剤を所定の濃度に水で希釈
して、ミナミキイロアザミウマの幼虫が２０匹寄生して
いるキュウリの苗に均一に散布した。Example 2 A liquid preparation prepared in the same manner as in Example 1 was diluted with water to a predetermined concentration and uniformly sprayed on cucumber seedlings infested with 20 larvae of southern thrips.
散布２日後及び７日後にミナミキイロアザミウマの生存
数を無散布区と比較し、防除率を算出した。Two and seven days after spraying, the number of surviving southern yellow thrips was compared with the non-sprayed area, and the control rate was calculated.
結果を第２表に示した。The results are shown in Table 2.
第２表 （以 上） 特許出願人 大塚化学株式会社 竹本油脂株式会社Table 2 (that's all) Patent applicant: Otsuka Chemical Co., Ltd. Takemoto Oil Co., Ltd.
Claims (1)
ニ剤。(1) An insecticide and acaricide containing oleate as an active ingredient.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1264486A JPS62169703A (en) | 1986-01-22 | 1986-01-22 | Insecticidal and acaricidal agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1264486A JPS62169703A (en) | 1986-01-22 | 1986-01-22 | Insecticidal and acaricidal agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62169703A true JPS62169703A (en) | 1987-07-25 |
| JPH0572881B2 JPH0572881B2 (en) | 1993-10-13 |
Family
ID=11811071
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1264486A Granted JPS62169703A (en) | 1986-01-22 | 1986-01-22 | Insecticidal and acaricidal agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62169703A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1995002961A1 (en) * | 1993-07-22 | 1995-02-02 | Japan Tobacco Inc. | Fatty acid insecticide and insecticidal method using the same |
| US10178865B2 (en) | 2013-07-18 | 2019-01-15 | Fmc Corporation | Insect repellent |
-
1986
- 1986-01-22 JP JP1264486A patent/JPS62169703A/en active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1995002961A1 (en) * | 1993-07-22 | 1995-02-02 | Japan Tobacco Inc. | Fatty acid insecticide and insecticidal method using the same |
| US10178865B2 (en) | 2013-07-18 | 2019-01-15 | Fmc Corporation | Insect repellent |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0572881B2 (en) | 1993-10-13 |
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