JP2022068361A - Ant control agent - Google Patents
Ant control agent Download PDFInfo
- Publication number
- JP2022068361A JP2022068361A JP2022028852A JP2022028852A JP2022068361A JP 2022068361 A JP2022068361 A JP 2022068361A JP 2022028852 A JP2022028852 A JP 2022028852A JP 2022028852 A JP2022028852 A JP 2022028852A JP 2022068361 A JP2022068361 A JP 2022068361A
- Authority
- JP
- Japan
- Prior art keywords
- ant
- acid
- control agent
- ants
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 58
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 42
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 29
- 239000000194 fatty acid Substances 0.000 claims abstract description 29
- 229930195729 fatty acid Natural products 0.000 claims abstract description 29
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 24
- 239000004480 active ingredient Substances 0.000 claims abstract description 19
- 150000003839 salts Chemical class 0.000 claims abstract description 19
- 125000005313 fatty acid group Chemical group 0.000 claims 1
- 241000257303 Hymenoptera Species 0.000 abstract description 42
- 241001465754 Metazoa Species 0.000 abstract description 3
- 230000002829 reductive effect Effects 0.000 abstract description 2
- 230000001276 controlling effect Effects 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 45
- 230000000694 effects Effects 0.000 description 41
- -1 etc.) Substances 0.000 description 38
- 239000005871 repellent Substances 0.000 description 29
- 230000002940 repellent Effects 0.000 description 29
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 16
- 239000000203 mixture Substances 0.000 description 15
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 13
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 12
- 241000196324 Embryophyta Species 0.000 description 12
- 230000000749 insecticidal effect Effects 0.000 description 12
- 241001374762 Formica japonica Species 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 241000238631 Hexapoda Species 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 9
- 238000012790 confirmation Methods 0.000 description 9
- 239000007788 liquid Substances 0.000 description 9
- 238000005507 spraying Methods 0.000 description 9
- 239000002253 acid Substances 0.000 description 8
- 238000011156 evaluation Methods 0.000 description 8
- 239000005639 Lauric acid Substances 0.000 description 7
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 241001374765 Pristomyrmex Species 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000002518 antifoaming agent Substances 0.000 description 6
- 238000002845 discoloration Methods 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 6
- 230000002147 killing effect Effects 0.000 description 6
- 239000007921 spray Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000000443 aerosol Substances 0.000 description 5
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 229960004488 linolenic acid Drugs 0.000 description 5
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 4
- 125000005037 alkyl phenyl group Chemical group 0.000 description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 230000005764 inhibitory process Effects 0.000 description 4
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 4
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000002574 poison Substances 0.000 description 4
- 231100000614 poison Toxicity 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 4
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 4
- 229920000053 polysorbate 80 Polymers 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 239000000341 volatile oil Substances 0.000 description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 3
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 239000005642 Oleic acid Substances 0.000 description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 3
- 235000019502 Orange oil Nutrition 0.000 description 3
- 235000021314 Palmitic acid Nutrition 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 241000517830 Solenopsis geminata Species 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 230000002401 inhibitory effect Effects 0.000 description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 3
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 3
- 230000003472 neutralizing effect Effects 0.000 description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 3
- 239000010502 orange oil Substances 0.000 description 3
- 150000008048 phenylpyrazoles Chemical class 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 239000002728 pyrethroid Substances 0.000 description 3
- 125000005504 styryl group Chemical group 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 3
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 2
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 2
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- 241000238558 Eucarida Species 0.000 description 2
- 241001420794 Formica rufa Species 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 239000005643 Pelargonic acid Substances 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- 241001415041 Solenopsis richteri Species 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 235000006708 antioxidants Nutrition 0.000 description 2
- YZXBAPSDXZZRGB-DOFZRALJSA-N arachidonic acid Chemical compound CCCCC\C=C/C\C=C/C\C=C/C\C=C/CCCC(O)=O YZXBAPSDXZZRGB-DOFZRALJSA-N 0.000 description 2
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 description 2
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 2
- 229940095259 butylated hydroxytoluene Drugs 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- KEMQGTRYUADPNZ-UHFFFAOYSA-N heptadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(O)=O KEMQGTRYUADPNZ-UHFFFAOYSA-N 0.000 description 2
- 230000002363 herbicidal effect Effects 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 230000003054 hormonal effect Effects 0.000 description 2
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 description 2
- 239000003915 liquefied petroleum gas Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- UTOPWMOLSKOLTQ-UHFFFAOYSA-N octacosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCC(O)=O UTOPWMOLSKOLTQ-UHFFFAOYSA-N 0.000 description 2
- 229960002446 octanoic acid Drugs 0.000 description 2
- 235000021313 oleic acid Nutrition 0.000 description 2
- SECPZKHBENQXJG-FPLPWBNLSA-N palmitoleic acid Chemical compound CCCCCC\C=C/CCCCCCCC(O)=O SECPZKHBENQXJG-FPLPWBNLSA-N 0.000 description 2
- 239000000825 pharmaceutical preparation Substances 0.000 description 2
- 229940127557 pharmaceutical product Drugs 0.000 description 2
- RCMHUQGSSVZPDG-UHFFFAOYSA-N phenoxybenzene;phosphoric acid Chemical compound OP(O)(O)=O.C=1C=CC=CC=1OC1=CC=CC=C1 RCMHUQGSSVZPDG-UHFFFAOYSA-N 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- POSICDHOUBKJKP-UHFFFAOYSA-N prop-2-enoxybenzene Chemical compound C=CCOC1=CC=CC=C1 POSICDHOUBKJKP-UHFFFAOYSA-N 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 229940035289 tobi Drugs 0.000 description 2
- NLVFBUXFDBBNBW-PBSUHMDJSA-N tobramycin Chemical compound N[C@@H]1C[C@H](O)[C@@H](CN)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O[C@@H]2[C@@H]([C@@H](N)[C@H](O)[C@@H](CO)O2)O)[C@H](N)C[C@@H]1N NLVFBUXFDBBNBW-PBSUHMDJSA-N 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 230000037303 wrinkles Effects 0.000 description 2
- GWHCXVQVJPWHRF-KTKRTIGZSA-N (15Z)-tetracosenoic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCCCC(O)=O GWHCXVQVJPWHRF-KTKRTIGZSA-N 0.000 description 1
- SBNFWQZLDJGRLK-RTWAWAEBSA-N (1R)-trans-phenothrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 SBNFWQZLDJGRLK-RTWAWAEBSA-N 0.000 description 1
- AGMMRUPNXPWLGF-AATRIKPKSA-N (2,3,5,6-tetrafluoro-4-methylphenyl)methyl 2,2-dimethyl-3-[(e)-prop-1-enyl]cyclopropane-1-carboxylate Chemical compound CC1(C)C(/C=C/C)C1C(=O)OCC1=C(F)C(F)=C(C)C(F)=C1F AGMMRUPNXPWLGF-AATRIKPKSA-N 0.000 description 1
- CUXYLFPMQMFGPL-UHFFFAOYSA-N (9Z,11E,13E)-9,11,13-Octadecatrienoic acid Natural products CCCCC=CC=CC=CCCCCCCCC(O)=O CUXYLFPMQMFGPL-UHFFFAOYSA-N 0.000 description 1
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- ZFPGARUNNKGOBB-UHFFFAOYSA-N 1-Ethyl-2-pyrrolidinone Chemical compound CCN1CCCC1=O ZFPGARUNNKGOBB-UHFFFAOYSA-N 0.000 description 1
- GZOKBPPGHUGEHR-UHFFFAOYSA-N 1-methoxy-3-methylbutan-1-ol Chemical compound COC(O)CC(C)C GZOKBPPGHUGEHR-UHFFFAOYSA-N 0.000 description 1
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 1
- IDCPFAYURAQKDZ-UHFFFAOYSA-N 1-nitroguanidine Chemical class NC(=N)N[N+]([O-])=O IDCPFAYURAQKDZ-UHFFFAOYSA-N 0.000 description 1
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 1
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- ROHFBIREHKPELA-UHFFFAOYSA-N 2-[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]prop-2-enoic acid;methane Chemical compound C.CC(C)(C)C1=CC(CC(=C)C(O)=O)=CC(C(C)(C)C)=C1O.CC(C)(C)C1=CC(CC(=C)C(O)=O)=CC(C(C)(C)C)=C1O.CC(C)(C)C1=CC(CC(=C)C(O)=O)=CC(C(C)(C)C)=C1O.CC(C)(C)C1=CC(CC(=C)C(O)=O)=CC(C(C)(C)C)=C1O ROHFBIREHKPELA-UHFFFAOYSA-N 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 description 1
- GUUULVAMQJLDSY-UHFFFAOYSA-N 4,5-dihydro-1,2-thiazole Chemical compound C1CC=NS1 GUUULVAMQJLDSY-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- 229940100484 5-chloro-2-methyl-4-isothiazolin-3-one Drugs 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical class [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 241000382781 Aphaenogaster Species 0.000 description 1
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Natural products OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- LVDKZNITIUWNER-UHFFFAOYSA-N Bronopol Chemical compound OCC(Br)(CO)[N+]([O-])=O LVDKZNITIUWNER-UHFFFAOYSA-N 0.000 description 1
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 239000005946 Cypermethrin Substances 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 239000005896 Etofenprox Substances 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 239000005906 Imidacloprid Substances 0.000 description 1
- 235000019501 Lemon oil Nutrition 0.000 description 1
- 241001646976 Linepithema humile Species 0.000 description 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- WPPOGHDFAVQKLN-UHFFFAOYSA-N N-Octyl-2-pyrrolidone Chemical compound CCCCCCCCN1CCCC1=O WPPOGHDFAVQKLN-UHFFFAOYSA-N 0.000 description 1
- XJXROGWVRIJYMO-SJDLZYGOSA-N Nervonic acid Natural products O=C(O)[C@@H](/C=C/CCCCCCCC)CCCCCCCCCCCC XJXROGWVRIJYMO-SJDLZYGOSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 235000021319 Palmitoleic acid Nutrition 0.000 description 1
- 231100000674 Phytotoxicity Toxicity 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- VQXSOUPNOZTNAI-UHFFFAOYSA-N Pyrethrin I Natural products CC(=CC1CC1C(=O)OC2CC(=O)C(=C2C)CC=C/C=C)C VQXSOUPNOZTNAI-UHFFFAOYSA-N 0.000 description 1
- 235000005733 Raphanus sativus var niger Nutrition 0.000 description 1
- 244000155437 Raphanus sativus var. niger Species 0.000 description 1
- 239000004288 Sodium dehydroacetate Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229930003427 Vitamin E Natural products 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- LWZFANDGMFTDAV-BURFUSLBSA-N [(2r)-2-[(2r,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O LWZFANDGMFTDAV-BURFUSLBSA-N 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- PFRUBEOIWWEFOL-UHFFFAOYSA-N [N].[S] Chemical compound [N].[S] PFRUBEOIWWEFOL-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000001785 acacia senegal l. willd gum Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 235000010419 agar Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- CUXYLFPMQMFGPL-SUTYWZMXSA-N all-trans-octadeca-9,11,13-trienoic acid Chemical compound CCCC\C=C\C=C\C=C\CCCCCCCC(O)=O CUXYLFPMQMFGPL-SUTYWZMXSA-N 0.000 description 1
- 229940087168 alpha tocopherol Drugs 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000007798 antifreeze agent Substances 0.000 description 1
- 229940114079 arachidonic acid Drugs 0.000 description 1
- 235000021342 arachidonic acid Nutrition 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
- 229960004217 benzyl alcohol Drugs 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- JCTHGPXQXLMSDK-UHFFFAOYSA-N bis(Benzyloxy)methane Chemical compound C=1C=CC=CC=1COCOCC1=CC=CC=C1 JCTHGPXQXLMSDK-UHFFFAOYSA-N 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 235000019282 butylated hydroxyanisole Nutrition 0.000 description 1
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 description 1
- 239000010630 cinnamon oil Substances 0.000 description 1
- SECPZKHBENQXJG-UHFFFAOYSA-N cis-palmitoleic acid Natural products CCCCCCC=CCCCCCCCC(O)=O SECPZKHBENQXJG-UHFFFAOYSA-N 0.000 description 1
- GWHCXVQVJPWHRF-UHFFFAOYSA-N cis-tetracosenoic acid Natural products CCCCCCCCC=CCCCCCCCCCCCCCC(O)=O GWHCXVQVJPWHRF-UHFFFAOYSA-N 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 229960005424 cypermethrin Drugs 0.000 description 1
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 1
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 description 1
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 1
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- YKBZOVFACRVRJN-UHFFFAOYSA-N dinotefuran Chemical compound [O-][N+](=O)\N=C(/NC)NCC1CCOC1 YKBZOVFACRVRJN-UHFFFAOYSA-N 0.000 description 1
- LRCFXGAMWKDGLA-UHFFFAOYSA-N dioxosilane;hydrate Chemical compound O.O=[Si]=O LRCFXGAMWKDGLA-UHFFFAOYSA-N 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002169 ethanolamines Chemical class 0.000 description 1
- 229940116333 ethyl lactate Drugs 0.000 description 1
- YREQHYQNNWYQCJ-UHFFFAOYSA-N etofenprox Chemical compound C1=CC(OCC)=CC=C1C(C)(C)COCC1=CC=CC(OC=2C=CC=CC=2)=C1 YREQHYQNNWYQCJ-UHFFFAOYSA-N 0.000 description 1
- 229950005085 etofenprox Drugs 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- FYQGBXGJFWXIPP-UHFFFAOYSA-N hydroprene Chemical compound CCOC(=O)C=C(C)C=CCC(C)CCCC(C)C FYQGBXGJFWXIPP-UHFFFAOYSA-N 0.000 description 1
- 229930000073 hydroprene Natural products 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 229940056881 imidacloprid Drugs 0.000 description 1
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 1
- VPRAQYXPZIFIOH-UHFFFAOYSA-N imiprothrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCN1C(=O)N(CC#C)CC1=O VPRAQYXPZIFIOH-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- LRDFRRGEGBBSRN-UHFFFAOYSA-N isobutyronitrile Chemical compound CC(C)C#N LRDFRRGEGBBSRN-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- TYQCGQRIZGCHNB-JLAZNSOCSA-N l-ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(O)=C(O)C1=O TYQCGQRIZGCHNB-JLAZNSOCSA-N 0.000 description 1
- 239000010501 lemon oil Substances 0.000 description 1
- 231100000225 lethality Toxicity 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 235000020778 linoleic acid Nutrition 0.000 description 1
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 239000001525 mentha piperita l. herb oil Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 235000019477 peppermint oil Nutrition 0.000 description 1
- 229960000490 permethrin Drugs 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- 229960003536 phenothrin Drugs 0.000 description 1
- FURYAADUZGZUGQ-UHFFFAOYSA-N phenoxybenzene;sulfuric acid Chemical class OS(O)(=O)=O.C=1C=CC=CC=1OC1=CC=CC=C1 FURYAADUZGZUGQ-UHFFFAOYSA-N 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 229960005235 piperonyl butoxide Drugs 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 239000004302 potassium sorbate Substances 0.000 description 1
- 235000010241 potassium sorbate Nutrition 0.000 description 1
- 229940069338 potassium sorbate Drugs 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 235000010388 propyl gallate Nutrition 0.000 description 1
- 239000000473 propyl gallate Substances 0.000 description 1
- 229940075579 propyl gallate Drugs 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 description 1
- VJFUPGQZSXIULQ-XIGJTORUSA-N pyrethrin II Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VJFUPGQZSXIULQ-XIGJTORUSA-N 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229940108410 resmethrin Drugs 0.000 description 1
- VEMKTZHHVJILDY-FIWHBWSRSA-N resmethrin Chemical compound CC1(C)[C@H](C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-FIWHBWSRSA-N 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- HPYNBECUCCGGPA-UHFFFAOYSA-N silafluofen Chemical compound C1=CC(OCC)=CC=C1[Si](C)(C)CCCC1=CC=C(F)C(OC=2C=CC=CC=2)=C1 HPYNBECUCCGGPA-UHFFFAOYSA-N 0.000 description 1
- 229960004029 silicic acid Drugs 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 235000019259 sodium dehydroacetate Nutrition 0.000 description 1
- 229940079839 sodium dehydroacetate Drugs 0.000 description 1
- DSOWAKKSGYUMTF-GZOLSCHFSA-M sodium;(1e)-1-(6-methyl-2,4-dioxopyran-3-ylidene)ethanolate Chemical compound [Na+].C\C([O-])=C1/C(=O)OC(C)=CC1=O DSOWAKKSGYUMTF-GZOLSCHFSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229950006451 sorbitan laurate Drugs 0.000 description 1
- 235000011067 sorbitan monolaureate Nutrition 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
- 235000011069 sorbitan monooleate Nutrition 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 239000012747 synergistic agent Substances 0.000 description 1
- 239000003826 tablet Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229960005199 tetramethrin Drugs 0.000 description 1
- CXBMCYHAMVGWJQ-UHFFFAOYSA-N tetramethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-UHFFFAOYSA-N 0.000 description 1
- 229960000984 tocofersolan Drugs 0.000 description 1
- 235000010384 tocopherol Nutrition 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- 229960001295 tocopherol Drugs 0.000 description 1
- DDVNRFNDOPPVQJ-HQJQHLMTSA-N transfluthrin Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=C(F)C(F)=CC(F)=C1F DDVNRFNDOPPVQJ-HQJQHLMTSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 235000004835 α-tocopherol Nutrition 0.000 description 1
- 239000002076 α-tocopherol Substances 0.000 description 1
Images
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
本発明は、アリ防除剤に関する。より詳しくは、本発明は、特定の脂肪酸またはその塩を有効成分とし、忌避効果と殺アリ効果を併せ有し、しかも植物を枯殺する恐れのないアリ防除剤に関する。 The present invention relates to an ant control agent. More specifically, the present invention relates to an ant control agent containing a specific fatty acid or a salt thereof as an active ingredient, having both a repellent effect and an ant-killing effect, and having no risk of killing plants.
近年、屋外から家屋内に侵入するアリ類により刺咬被害が増加し、アリ類も不快害虫の1つに挙げられている。その防除方法としては、殺虫活性成分を含有する液剤またはエアゾール剤を、アリ類に直接噴霧して駆除するタイプのものや、毒餌剤をアリ類に巣穴まで持ち帰らせ、巣穴内のアリ類を駆除するタイプのものが主流である。
例えば、ピレスロイド系化合物を殺虫活性成分として含有させた液剤やエアゾール剤は、アリ類やアリ類の巣に直接噴霧することにより速効的な殺虫効果が得られることが知られている(例えば、特許文献1等)。また、フェニルピラゾール系化合物を殺虫活性成分として含有させた毒餌剤は、接触作用による速効的な殺虫性を示さず、アリ類が巣穴に毒餌剤を運搬して巣全体を崩壊させることが報告されている(特許文献2)。しかしながら、上記液剤やエアゾール剤は、接触作用により速効的な殺虫効果が得られるため、殺虫活性成分に接触しないアリ類は駆除することができない。また、上記毒餌剤は殺虫成分と共に含有される誘引成分によっては、運搬効果にバラツキが見られ十分な防除効果が得られないことがある。
これまでアリ類を駆除するために、ピレスロイド系化合物やフェニルピラゾール系化合物等の化学合成系殺虫成分を含有する製剤が汎用されてきたが、使用者の安全志向の向上により、天然成分由来の殺虫剤のニーズも高まってきている。例えば、ジヒドロジャスモン等の天然精油成分をアリ忌避成分として含有する、持続性に優れたアリ防除剤が報告されている(特許文献3)。しかしながら、有効成分が天然精油成分のため揮散性が高く、その忌避効果の持続性が十分ではないため、長期的なアリ防除効果は得られない。
このような状況から、アリ類に対して優れた防除効果を有し、環境や人畜に対する負荷が低減された薬剤の開発が望まれている。
In recent years, ants that invade the house from the outdoors have increased the damage caused by bites, and ants are also listed as one of the unpleasant pests. As the control method, a liquid agent or an aerosol agent containing an insecticidal active ingredient is sprayed directly onto the ants to exterminate them, or a poison bait is brought back to the ants to the burrow to remove the ants in the burrow. The type to be exterminated is the mainstream.
For example, it is known that a liquid agent or an aerosol agent containing a pyrethroid compound as an insecticidal active ingredient can obtain a rapid insecticidal effect by directly spraying it on ants or nests of ants (for example, patent). Document 1 etc.). In addition, it has been reported that poison bait containing a phenylpyrazole compound as an insecticidal active ingredient does not show rapid insecticidal activity due to contact action, and that ants carry the poison bait to the burrow and destroy the entire nest. (Patent Document 2). However, since the above liquids and aerosols have a rapid insecticidal effect due to the contact action, ants that do not come into contact with the insecticidal active ingredient cannot be exterminated. Further, depending on the attracting component contained together with the insecticidal component, the above-mentioned poison bait may have a variation in the transport effect and a sufficient control effect may not be obtained.
Until now, in order to exterminate ants, preparations containing chemically synthesized insecticidal components such as pyrethroid compounds and phenylpyrazole compounds have been widely used, but due to the improvement of users' safety consciousness, insecticides derived from natural components have been widely used. The need for agents is also increasing. For example, an ant control agent having excellent durability, which contains a natural essential oil component such as dihydrojasmon as an ant repellent component, has been reported (Patent Document 3). However, since the active ingredient is a natural essential oil component, it is highly volatile and its repellent effect is not sufficiently sustained, so that a long-term ant control effect cannot be obtained.
Under such circumstances, it is desired to develop a drug having an excellent control effect on ants and reducing the burden on the environment and humans and animals.
本発明は、アリ類に対して優れた防除効果を有し、環境や人畜に対する負荷が低減された、アリ防除剤を提供することを目的としている。 It is an object of the present invention to provide an ant control agent which has an excellent control effect on ants and has a reduced load on the environment and humans and animals.
本発明者は、上記課題を解決するために鋭意研究を重ねた結果、炭素数12以上の脂肪酸またはその塩を有効成分とする薬剤が、アリ類に対して忌避効果と殺アリ効果を併せ有することを見出し、上記課題を解決するに至ったものである。 As a result of diligent research to solve the above problems, the present inventor has a drug containing a fatty acid having 12 or more carbon atoms or a salt thereof as an active ingredient, which has both a repellent effect and an ant-killing effect on ants. We found that and came to solve the above problem.
本発明は、具体的には次の事項を要旨とする。
1.炭素数12以上の脂肪酸またはその塩を有効成分として含有することを特徴とするアリ防除剤。
2.炭素数12以上18以下の脂肪酸またはその塩を有効成分とすることを特徴とする、1.に記載のアリ防除剤。
Specifically, the present invention has the following gist.
1. 1. An ant control agent comprising a fatty acid having 12 or more carbon atoms or a salt thereof as an active ingredient.
2. 2. 1. The active ingredient is a fatty acid having 12 or more and 18 or less carbon atoms or a salt thereof. The ant control agent described in.
本発明のアリ防除剤は、忌避効果と共に殺アリ効果を発揮するという優れた特徴を有するものであり、防除性能が確実に達成されるというメリットを有する。そのため、本発明のアリ防除剤は、アリ類に直接またはアリ類の巣穴に噴霧または散布処理することにより殺アリ効果を発揮し、さらに、噴霧または散布処理した場所はアリ類に対して忌避効果を有するため、アリ類を寄せ付けず、アリ類の定着を阻害することができる。
しかも、本発明のアリ防除剤は、忌避効果の持続性にも優れるものであるから、長期的なアリ防除効果を得ることができる。
さらに、本発明のアリ防除剤は、植物を枯殺する恐れがないため、噴霧または散布処理した場所の植物に対して安全性が高いという特徴を有するものである。
The ant control agent of the present invention has an excellent feature of exhibiting an ant-killing effect as well as a repellent effect, and has an advantage that the control performance is surely achieved. Therefore, the ant control agent of the present invention exerts an ant-killing effect by spraying or spraying the ants directly or on the burrows of the ants, and further, the sprayed or sprayed place repels the ants. Since it has an effect, it can repel ants and inhibit the colonization of ants.
Moreover, since the ant control agent of the present invention is also excellent in sustainability of the repellent effect, a long-term ant control effect can be obtained.
Further, the ant control agent of the present invention is characterized in that it is highly safe for plants in the place where it is sprayed or sprayed because there is no risk of killing the plants.
以下、本発明のアリ防除剤について詳細に説明する。
本発明のアリ防除剤は、有効成分として炭素数12以上の脂肪酸またはその塩を含有し、各種のアリ類に対して有効である。例えば、イエヒメアリ、ヒメアリ、キイロヒメアリ、クロヒメアリ、トビイロケアリ、コトビイロケアリ、ハヤシトビイロケアリ、キイロシリアゲアリ、トビイロシリアゲアリ、ハリブトシリアゲアリ、オオシワアリ、トビイロシワアリ、シワアリ、オオハリアリ、メクラハリアリ、トゲアリ、クロオオアリ、ムネアカオオアリ、サムライアリ、クロヤマアリ、アカヤマアリ、クロクサアリ、アメイロアリ、アミメアリ、ウメマツアリ、シワクシケアリ、エゾクシケアリ、オオズアリ、オオズアカアリ、アズマオオズアカアリ、アシナガアリ、クロナガアリ、ムネボソアリ、トフシアリ、ルリアリ、アルゼンチンアリ、ヒアリ、アカカミアリ等に適用することができる。
Hereinafter, the ant control agent of the present invention will be described in detail.
The ant control agent of the present invention contains a fatty acid having 12 or more carbon atoms or a salt thereof as an active ingredient, and is effective against various ants. For example, fire ant, fire ant, fire ant, black imported fire ant, black imported fire ant, tobiiro keari, kotobiiro keari, hayashi tobiiro keari, kiiro silia geari, tobi iro siri geari, haributo siri geari, oshiwa ant, tobi iro shiwa ant, wrinkle ant Ali, Formica japonica, Formica japonica, Formica japonica, Formica japonica, Amime ant, Umematsu ant, Wrinkle keari, Ezokushi keari, Ozu ant, Ozu red ant, Azuma Ozu red ant, Aphaenogaster flies, Kuronaga ant, Muneboso ant, Tofushiari, Luriari, Argentine ant, etc.
本発明のアリ防除剤の有効成分は、炭素数12以上の脂肪酸である。具体的には、例えば、ラウリン酸(炭素数12)、ミリスチン酸(炭素数14)、ペンタデシル酸(炭素数15)、パルミチン酸(炭素数16)、パルミトレイン酸(炭素数16)、マルガリン酸(炭素数17)、ステアリン酸(炭素数18)、オレイン酸(炭素数18)、バクセン酸(炭素数18)、リノール酸(炭素数18)、α-リノレン酸(炭素数18)、γ-リノレン酸(炭素数18)、エレオステアリン酸(炭素数18)、アラキジン酸(炭素数20)、ミード酸(炭素数20)、アラキドン酸(炭素数20)、ベヘン酸(炭素数22)、リグノセリン酸(炭素数24)、ネルボン酸(炭素数24)、セロチン酸(炭素数26)、モンタン酸(炭素数28)、メリシン酸(炭素数30)等が挙げられる。
また、その塩としては、ナトリウム塩、カリウム塩、カルシウム塩、マグネシウム塩、エタノールアミン塩、トリエタノールアミン塩、アンモニウム塩等が挙げられるが、これらの塩は単体としてアリ防除剤中に加えてもよいが、脂肪酸と対応する中和剤とを別々に加えてアリ防除剤中で塩を形成させてもよい。例えば、脂肪酸と、中和剤としてトリエタノールアミンまたは水酸化ナトリウムを別々に加えて、トリエタノールアミン塩またはナトリウム塩として使用することができる。本発明において、中和剤として、水酸化ナトリウム、トリエタノールアミン、アンモニア、水酸化カリウムが好適である。
本発明のアリ防除剤の有効成分としては、中でも炭素数12以上の脂肪酸が好ましく、炭素数12以上18以下の脂肪酸がより好ましく、ラウリン酸とミリスチン酸、パルミチン酸、オレイン酸、リノール酸、リノレン酸が特に好ましい。
本発明のアリ防除剤は、有効成分である炭素数12以上の脂肪酸またはその塩を、防除剤全体の0.01重量%以上10重量%以下の範囲で含有することが好ましく、中でも、0.05重量%以上5重量%以下の範囲で含有することがより好ましく、0.1重量%以上3重量%以下含有することがさらに好ましい。
The active ingredient of the ant control agent of the present invention is a fatty acid having 12 or more carbon atoms. Specifically, for example, lauric acid (12 carbon atoms), myristic acid (14 carbon atoms), pentadecyl acid (15 carbon atoms), palmitic acid (16 carbon atoms), palmitoleic acid (16 carbon atoms), margaric acid (16 carbon atoms). 17 carbon atoms), stearic acid (18 carbon atoms), oleic acid (18 carbon atoms), baxenoic acid (18 carbon atoms), linoleic acid (18 carbon atoms), α-linolenic acid (18 carbon atoms), γ-linolene Acid (18 carbons), eleostearic acid (18 carbons), arachidic acid (20 carbons), meadic acid (20 carbons), arachidonic acid (20 carbons), behenic acid (22 carbons), lignoserine Examples thereof include acid (24 carbon atoms), nervonic acid (24 carbon atoms), cellotic acid (26 carbon atoms), montanic acid (28 carbon atoms), melicic acid (30 carbon atoms) and the like.
Examples of the salt include sodium salt, potassium salt, calcium salt, magnesium salt, ethanolamine salt, triethanolamine salt, ammonium salt and the like, but these salts can be added as a single substance to the ant control agent. However, the fatty acid and the corresponding neutralizing agent may be added separately to form salts in the ant control agent. For example, the fatty acid and triethanolamine or sodium hydroxide as a neutralizing agent can be added separately and used as a triethanolamine salt or a sodium salt. In the present invention, sodium hydroxide, triethanolamine, ammonia and potassium hydroxide are suitable as the neutralizing agent.
As the active ingredient of the ant control agent of the present invention, fatty acids having 12 or more carbon atoms are preferable, fatty acids having 12 or more and 18 or less carbon atoms are more preferable, and lauric acid and myristic acid, palmitic acid, oleic acid, linoleic acid, and linolenic acid are preferable. Acids are particularly preferred.
The ant control agent of the present invention preferably contains the active ingredient fatty acid having 12 or more carbon atoms or a salt thereof in a range of 0.01% by weight or more and 10% by weight or less of the entire control agent, and among them, 0. It is more preferably contained in the range of 05% by weight or more and 5% by weight or less, and further preferably 0.1% by weight or more and 3% by weight or less.
本発明のアリ防除剤は製剤化されたものであるが、製剤型としては、例えば油剤、乳剤、水和剤、フロアブル剤(水中懸濁剤、水中乳濁剤等)、マイクロカプセル剤、粉剤、粒剤、錠剤、ゲル剤、液剤、スプレー剤、エアゾール剤等が挙げられる。その中でも、スプレー剤やエアゾール剤等の噴霧用製剤や、液剤をジョウロヘッド付き容器に充填した散布剤等が、本発明のアリ類に対する忌避性能や殺アリ性能を最大限に活用することができる製剤型として好適である。
1つの製造例として、炭素数12以上の脂肪酸またはその塩を、必要に応じて界面活性剤を用いて溶剤に溶かして溶液(A液)を調製し、このA液を適量の水に混合、撹拌することにより使用時に希釈する必要がないアリ防除剤とする方法を挙げることができる。水としては、水道水、イオン交換水、蒸留水、ろ過処理した水、滅菌処理した水、地下水等が用いられる。
The ant control agent of the present invention is a pharmaceutical product, and the pharmaceutical products include, for example, oils, emulsions, wettable powders, flowable agents (suspension agents in water, emulsions in water, etc.), microcapsules, and powders. , Granules, tablets, gels, liquids, sprays, aerosols and the like. Among them, a spray formulation such as a spray agent or an aerosol agent, a spray agent in which a liquid agent is filled in a container with a jouro head, and the like can make the best use of the ant repellent performance and the ant killing performance of the present invention. Suitable as a pharmaceutical type.
As one production example, a solution (Liquid A) is prepared by dissolving a fatty acid having 12 or more carbon atoms or a salt thereof in a solvent using a surfactant as necessary, and the solution A is mixed with an appropriate amount of water. Examples thereof include a method of making an ant control agent which does not need to be diluted at the time of use by stirring. As the water, tap water, ion-exchanged water, distilled water, filtered water, sterilized water, groundwater and the like are used.
液体担体としては、例えばアルコール類(メタノール、エタノール、イソプロピルアルコール、ブタノール、ヘキサノール、ベンジルアルコール、エチレングリコール等)、エーテル類(ジエチルエーテル、エチレングリコールジメチルエーテル、ジエチレングリコールモノメチルエーテル、ジエチレングリコールモノエチルエーテル、プロピレングリコールモノメチルエーテル、テトラヒドロフラン、ジオキサン等)、エステル類(酢酸エチル、酢酸ブチル、ミリスチン酸イソプロピル、乳酸エチル等)、ケトン類(アセトン、メチルエチルケトン、メチルイソブチルケトン、シクロヘキサノン等)、芳香族または脂肪族炭化水素類(キシレン、トルエン、アルキルナフタレン、フェニルキシリルエタン、ケロシン、軽油、ヘキサン、シクロヘキサン等)、ハロゲン化炭化水素類(クロロベンゼン、ジクロロメタン、ジクロロエタン、トリクロロエタン等)、ニトリル類(アセトニトリル、イソブチロニトリル等)、スルホキシド類(ジメチルスルホキシド等)、ヘテロ環系溶剤(スルホラン、γ-ブチロラクトン、N-メチル-2-ピロリドン、N-エチル-2-ピロリドン、N-オクチル-2-ピロリドン、1,3-ジメチル-2-イミダゾリジノン)、酸アミド類(N,N-ジメチルホルムアミド、N,N-ジメチルアセトアミド等)、炭酸アルキリデン類(炭酸プロピレン等)、植物油(大豆油、綿実油等)、植物精油(オレンジ油、ヒソップ油、レモン油等)、および水が挙げられる。 Examples of the liquid carrier include alcohols (methanol, ethanol, isopropyl alcohol, butanol, hexanol, benzyl alcohol, ethylene glycol, etc.) and ethers (diethyl ether, ethylene glycol dimethyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, propylene glycol monomethyl ether). Ethers, tetrahydrofuran, dioxane, etc.), esters (ethyl acetate, butyl acetate, isopropyl myristate, ethyl lactate, etc.), ketones (acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone, etc.), aromatic or aliphatic hydrocarbons (ethyl acetate, butyl acetate, cyclohexanone, etc.) Xylene, toluene, alkylnaphthalene, phenylxysilyl ethane, kerosine, light oil, hexane, cyclohexane, etc.), halogenated hydrocarbons (chlorobenzene, dichloromethane, dichloroethane, trichloroethane, etc.), nitriles (acetohydrate, isobutyronitrile, etc.), Hydrocarbons (dimethylsulfoxide, etc.), heterocyclic solvents (sulfolane, γ-butyrolactone, N-methyl-2-pyrrolidone, N-ethyl-2-pyrrolidone, N-octyl-2-pyrrolidone, 1,3-dimethyl-2) -Imidazolidinone), acid amides (N, N-dimethylformamide, N, N-dimethylacetamide, etc.), alkylidene carbonates (propylene carbonate, etc.), vegetable oils (soybean oil, cottonseed oil, etc.), vegetable essential oils (orange oil, orange oil, etc.) Hisop oil, lemon oil, etc.), and water.
界面活性剤としては、非イオン性界面活性剤、陰イオン性界面活性剤、陽イオン性界面活性剤、および両性界面活性剤を用いることができる。非イオン性界面活性剤としては、例えば、ポリオキシアルキレンアリルフェニルエーテル、ポリオキシエチレンアルキルエーテル、ポリオキシエチレンアルキルフェニルエーテル、ポリオキシエチレンアリルフェニルエーテル、ポリオキシエチレンスチリルフェニルエーテル、ポリオキシエチレンアルキルフェニルエーテルホルムアルデヒド縮合物、ポリオキシエチレン-ポリオキシプロピレンブロックポリマー、ポリオキシエチレン-ポリオキシプロピレンブロックポリマーアルキルフェニルエーテル、ソルビタン脂肪酸エステル(ソルビタンモノオレエート、ソルビタンラウレート等)、ポリオキシエチレン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレン硬化ヒマシ油、ポリエチレングリコール脂肪酸エステル、ポリエチレングリコール脂肪酸エーテル等が挙げられる。陰イオン性界面活性剤としては、例えば、硫酸アルキル、ポリオキシエチレンアルキルエーテル硫酸、ポリオキシエチレンアルキルフェニルエーテル硫酸、ポリオキシエチレンベンジル(またはスチリル)フェニルエーテル硫酸またはポリオキシエチレン-ポリオキシプロピレンブロックポリマー硫酸のナトリウム、カルシウムまたはアンモニウムの各塩;スルホン酸アルキル、ジアルキルスルホサクシネート、アルキルベンゼンスルホン酸(ドデシルベンゼンスルホン酸カルシウム等)、モノ-またはジ-アルキルナフタレン酸スルホン酸、ナフタレンスルホン酸ホルムアルデヒド縮合物、リグニンスルホン酸、ポリオキシエチレンアルキルフェニルエーテルスルホン酸またはポリオキシエチレンアルキルエーテルスルホサクシネートのナトリウム、カルシウム、アンモニウムまたはアルカノールアミン塩の各塩;ポリオキシエチレンアルキルエーテルホスフェート、ポリオキシエチレン、モノ-またはジ-アルキルフェニルエーテルホスフェート、ポリオキシエチレンベンジル(またはスチリル)化フェニルエーテルホスフェート、ポリオキシエチレンベンジル(またはスチリル)化フェニルエーテルホスフェート、ポリオキシエチレン-ポリオキシプロピレンブロックポリマーホスフェートのナトリウムまたはカルシウム塩等の各塩が挙げられる。陽イオン性界面活性剤としては、例えば第4級アンモニウム塩、アルキルアミン塩、アルキルピリジニウム塩、アルキルオキサイド等が挙げられる。両性界面活性剤としては、例えばアルキルベタイン、アミンオキシド等が挙げられる。 As the surfactant, a nonionic surfactant, an anionic surfactant, a cationic surfactant, and an amphoteric surfactant can be used. Examples of the nonionic surfactant include polyoxyalkylene allylphenyl ether, polyoxyethylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene allyl phenyl ether, polyoxyethylene styryl phenyl ether, and polyoxyethylene alkyl phenyl. Ether formaldehyde condensate, polyoxyethylene-polyoxypropylene block polymer, polyoxyethylene-polyoxypropylene block polymer alkylphenyl ether, sorbitan fatty acid ester (sorbitan monooleate, sorbitan laurate, etc.), polyoxyethylene fatty acid ester, poly Examples thereof include oxyethylene sorbitan fatty acid ester, polyoxyethylene hydrogenated castor oil, polyethylene glycol fatty acid ester, and polyethylene glycol fatty acid ether. Anionic surfactants include, for example, alkyl sulphates, polyoxyethylene alkyl ether sulphates, polyoxyethylene alkyl phenyl ether sulphates, polyoxyethylene benzyl (or styryl) phenyl ether sulphates or polyoxyethylene-polyoxypropylene block polymers. Sodium, calcium or ammonium salts of sulfuric acid; alkyl sulfonate, dialkyl sulfosuccinate, alkylbenzene sulfonic acid (calcium dodecylbenzene sulfonate, etc.), mono- or di-alkylnaphthalene sulfonic acid, naphthalene sulfonic acid formaldehyde condensate, Salts of sodium, calcium, ammonium or alkanolamine salts of lignin sulfonic acid, polyoxyethylene alkyl phenyl ether sulfonic acid or polyoxyethylene alkyl ether sulfosuccinate; polyoxyethylene alkyl ether phosphate, polyoxyethylene, mono- or di. -Alkylphenyl ether phosphate, polyoxyethylene benzyl (or styryl) phenyl ether phosphate, polyoxyethylene benzyl (or styryl) phenyl ether phosphate, polyoxyethylene-polyoxypropylene block polymer phosphate sodium or calcium salt, etc. Salt is mentioned. Examples of the cationic surfactant include a quaternary ammonium salt, an alkylamine salt, an alkylpyridinium salt, an alkyloxide and the like. Examples of the amphoteric tenside agent include alkyl betaine, amine oxide and the like.
製剤化の際に用いられるガス状担体としては、例えばブタンガス、フロンガス、(HFO、HFC等の)代替フロン、液化石油ガス(LPG)、ジメチルエーテル、および炭酸ガス、窒素ガスが、固体担体としては、例えば粘土類(カオリン、珪藻土、ベントナイト、クレー、酸性白土等)、合成含水酸化珪素、タルク、セラミック、その他の無機鉱物(セリサイト、石英、硫黄、活性炭、炭酸カルシウム、水和シリカ等)、多孔質体等が挙げられる。 As the gaseous carrier used in the formulation, for example, butane gas, freon gas, alternative fron (such as HFO, HFC), liquefied petroleum gas (LPG), dimethyl ether, carbon dioxide gas, and nitrogen gas are used as the solid carrier. For example, clays (kaolin, diatomaceous soil, bentonite, clay, acidic white clay, etc.), synthetic hydroxide-containing silicon, talc, ceramics, other inorganic minerals (serisite, quartz, sulfur, activated carbon, calcium carbonate, hydrated silica, etc.), porous. Examples include pledges.
本発明のアリ防除剤は、必要に応じて凍結防止剤、消泡剤、防腐剤、酸化防止剤および増粘剤等を添加することができる。
凍結防止剤としては、例えば、エタノール、エチレングリコール、プロピレングリコール、エチルセロソルブ、ブチルカルビトール、3-メチル-メトキシブタノール等が挙げられる。
消泡剤としては、例えばアンチフォームE-20(シリコーンエマルジョン、花王(株)、商品名)、アンチフォームC(東レ・ダウコーニング社、商品名)、アンチフォームCエマルション(東レ・ダウコーニング社、商品名)、ロードシル454(ソルベイ社、商品名)、ロードシルアンチフォム432(ソルベイ社、商品名)、TSA730(タナック社、商品名)、TSA731(タナック社、商品名)、TSA732(タナック社、商品名)、YMA6509(タナック社、商品名)等のシリコーン系消泡剤、フルオウェットPL80(クラリアント社、商品名)等のフッ素系消泡剤が挙げられる。
防腐剤としては、例えばバイオホープおよびバイオホープL(化学名:有機窒素硫黄系複合物、有機臭素系化合物)、ベストサイド-750(化学名:イソチアゾリン系化合物、2.5~6.0%)、プリベントールD2(化学名:ベンジルアルコールモノ(ポリ)ヘミホルマル)、PROXEL GXL(S)(化学名:1,2-ベンゾイソチアゾリン-3-オン、20%)、5-クロロ-2-メチル-4-イソチアゾリン-3-オン、2-メチル-4-イソチアゾリン-3-オン、2-ブロモ-2-ニトロプロパン-1,3-ジオール、ソルビン酸カリウム、デヒドロ酢酸ナトリウム等が挙げられる。
酸化防止剤としては、テトラキス〔メチレン-3-(3,5-ジ-t-ブチル-4-ヒドロキシフェニル)プロピオネート〕メタン(トミノックスTT,(株)エーピーアイコーポレーション、商品名/IRGANOX1010またはIRGANOX1010EDS,チバ・ジャパン社、商品名)、ブチル化ヒドロキシトルエン(BHT)、ブチル化ヒドロキシ・アニソール(BHA)、没食子酸プロピル、およびビタミンE、混合トコフェロール、α-トコフェロール、エトキシキンおよびアスコルビン酸等が挙げられる。
The ant control agent of the present invention can be added with an antifreezing agent, an antifoaming agent, a preservative, an antioxidant, a thickener and the like, if necessary.
Examples of the antifreeze agent include ethanol, ethylene glycol, propylene glycol, ethyl cellosolve, butyl carbitol, 3-methyl-methoxybutanol and the like.
Examples of the defoaming agent include Antifoam E-20 (silicone emulsion, Kao Co., Ltd., trade name), Antifoam C (Toray Dow Corning Co., Ltd., trade name), Antifoam C Emulsion (Toray Dow Corning Co., Ltd., trade name). Product name), Rhodesyl 454 (Solvey, product name), Rhodesyl Antifoam 432 (Solbay, product name), TSA730 (Tanac, product name), TSA731 (Tanac, product name), TSA732 (Tanac, product name) Examples thereof include silicone-based defoamers such as YMA6509 (trade name) and YMA6509 (trade name), and fluorine-based defoamers such as Fluott PL80 (Clariant, trade name).
Examples of preservatives include Biohope and Biohope L (chemical name: organic nitrogen-sulfur complex, organic bromine-based compound), Bestside-750 (chemical name: isothiazolin-based compound, 2.5 to 6.0%). , Preventol D2 (chemical name: benzyl alcohol mono (poly) hemiformal), PROXEL GXL (S) (chemical name: 1,2-benzoisothiazolin-3-one, 20%), 5-chloro-2-methyl-4 -Isothiazolin-3-one, 2-methyl-4-isothiazolin-3-one, 2-bromo-2-nitropropane-1,3-diol, potassium sorbate, sodium dehydroacetate and the like can be mentioned.
As the antioxidant, tetrakis [methylene-3- (3,5-di-t-butyl-4-hydroxyphenyl) propionate] methane (Tominox TT, IPI Corporation, trade name / IRGANOX1010 or IRGANOX1010EDS, Ciba Japan, Inc., trade name), butylated hydroxytoluene (BHT), butylated hydroxyanisole (BHA), propyl gallate, and vitamin E, mixed tocopherol, α-tocopherol, ethoxykin, ascorbic acid and the like.
本発明のアリ防除剤は、巣穴やその周囲に処理した際に土壌への吸収を抑えて十分な殺アリ効果を発揮させるために、粘度のある液剤としてもよい。粘度を調整するに際しては、例えば、グリセリン、ザンフロー、キサンタンガム、ペクチン、アラビアガム、グアーガム、寒天、セルロースおよびその誘導体、デンプンおよびその誘導体、カルボキシアルカリ化物、ポリアクリル酸塩、ポリマレイン酸塩、ポリビニルアルコール、ポリビニルピロリドン、カルボキシビニルポリマー等の増粘剤の1種または2種以上を用いればよい。 The ant control agent of the present invention may be a viscous liquid agent in order to suppress absorption into the soil and exert a sufficient ant-killing effect when treated in or around the burrow. In adjusting the viscosity, for example, glycerin, zanflo, xanthan gum, pectin, arabic gum, guar gum, agar, cellulose and its derivatives, starch and its derivatives, carboxyalkylateds, polyacrylic acid salts, polymaleates, polyvinyl alcohol, etc. One or more thickeners such as polyvinylpyrrolidone and carboxyvinyl polymer may be used.
また必要に応じて、本発明の効果を阻害しない範囲で、例えば、天然ピレトリン、アレスリン、レスメトリン、フラメトリン、プラレトリン、テラレスリン、フタルスリン、フェノトリン、ペルメトリン、シフェノトリン、サイパーメスリン、トランスフルトリン、メトフルトリン、プロフルトリン、イミプロトリン、エンペントリン、エトフェンプロックス、シラフルオフェン等のピレスロイド系化合物;プロポクサー、カルバリル等のカーバメイト系化合物;フェニトロチオン、DDVP等の有機リン系化合物;メトキサジアゾン等のオキサジアゾール系化合物;フィプロニル等のフェニルピラゾール系化合物;アミドフルメト等のニトログアニジン系化合物;イミダクロプリド、ジノテフラン等のネオニコチノイド系化合物;メトプレン、ハイドロプレン等の昆虫幼若ホルモン様化合物;プレコセン等の抗幼若ホルモン様化合物;フィトンチッド、ハッカ油、オレンジ油、桂皮油、丁子油等の殺虫精油類等の各種アリ防除剤;サイネピリン、ピペロニルブトキサイド等の共力剤等を併用してもよい。しかしながら、使用者の安全志向の向上を考慮すると、本発明のアリ防除液剤は、本発明の有効成分以外にこれら殺虫成分等を併用しないことが好ましい。 If necessary, for example, natural pyrethrin, alesulin, resmethrin, flamethrin, prarethrin, terraresulin, phthalthrin, phenothrin, permethrin, ciphenotrin, cypermethrin, transfluthrin, methoflutrin, profluthrin, as long as the effects of the present invention are not impaired. Pyrethroid compounds such as imiprothrin, Empentrin, etofenprox, and silafluofen; carbamate compounds such as propoxer and carbalyl; organic phosphorus compounds such as fenitrothione and DDVP; oxaziazole compounds such as methoxadiazone; phenylpyrazole compounds such as fipronyl Nitroguanidine compounds such as amidoflumeth; Neonicotinoid compounds such as imidacloprid and dinotefuran; Insect immature hormone-like compounds such as metoprene and hydroprene; Anti-juvenile hormone-like compounds such as plecosene; Phytontide, peppermint oil, orange oil , Various ant control agents such as insecticidal essential oils such as cinnamon oil and chopstick oil; and synergistic agents such as cinepyrin and piperonyl butoxide may be used in combination. However, in consideration of the improvement of the safety consciousness of the user, it is preferable that the ant-controlling liquid agent of the present invention does not use these insecticidal components in combination with the active ingredient of the present invention.
本発明のアリ防除剤は、アリ類を防除したい場所1平方メートル当たり、炭素数12以上の脂肪酸またはその塩からなる有効成分を、0.01~30g、好ましくは0.05~25gとなる量で散布するとよい。処理頻度は、アリ類の発生を確認したら、1ヶ月に1回程度の頻度で処理するのがよい。処理手段は特に制限されない。
本発明のアリ防除剤は、屋外はもとより屋内においても問題無く使用することができる。例えば、アリ類に直接またはアリ類の巣穴に噴霧または散布処理することにより殺アリ効果を発揮することができる。さらに、本発明のアリ防除剤を、台所、勝手口、玄関、廊下、リビング、窓辺、ベランダ、ウッドデッキ、ポート、アスファルト等の路面、庭、プランター、植木鉢、花壇、菜園、芝生、農耕地等の家屋等の建造物またはその周辺に噴霧または散布処理することにより、殺アリ活性とアリ類に対する優れた忌避効果を発揮し、処理後のアリ防除効果はもとより、処理後も長期間にわたりアリ類を寄せ付けず、アリ類の定着を阻害することができる。
本発明のアリ防除剤は、殺アリ活性とアリ忌避効果を併せ有することにより、さらに殺虫成分を併用することなく、優れたアリ防除効果を発揮するため、家屋等の建造物への侵入を確実に防除する点において極めて実用的である。
The ant control agent of the present invention contains an active ingredient consisting of a fatty acid having 12 or more carbon atoms or a salt thereof per square meter of a place where ants are to be controlled in an amount of 0.01 to 30 g, preferably 0.05 to 25 g. It is good to spray. The treatment frequency should be about once a month after confirming the occurrence of ants. The processing means is not particularly limited.
The ant control agent of the present invention can be used indoors as well as outdoors without any problem. For example, the ant-killing effect can be exerted by spraying or spraying the ants directly or on the burrows of the ants. Further, the ant control agent of the present invention can be applied to kitchens, doorways, entrances, corridors, living rooms, windowsills, verandas, wood decks, ports, asphalt and other road surfaces, gardens, planters, plant pots, flower beds, vegetable gardens, lawns, farmlands, etc. By spraying or spraying on or around a building such as a house, it exerts an ant-killing activity and an excellent repellent effect on ants, and not only has an ant control effect after treatment, but also ants for a long period of time after treatment. It can prevent the colonization of ants by keeping them away.
Since the ant control agent of the present invention has both ant-killing activity and ant-repelling effect, it exerts an excellent ant-controlling effect without further using an insecticidal component, so that it surely invades a building such as a house. It is extremely practical in terms of controlling ants.
以下、処方例および試験例等により、本発明をさらに詳しく説明するが、本発明は、これらの例に限定されるものではない。
まず、本発明のアリ防除剤の試験検体例を示す。なお、実施例において、特に明記しない限り、部は重量部を意味する。
なお、以下の実施例および比較例の試験検体の調製に際し、ラウリン酸、ミリスチン酸、オレイン酸、パルミチン酸、リノール酸、カプリル酸、カプリン酸、モノオレイン酸ポリオキシエチレンソルビタン(Tween80)、アセトンは和光純薬工業(株)製の試薬を、リノレン酸、ペラルゴン酸は東京化成工業(株)製の試薬を、特にリノレン酸は「α-リノレン酸」を使用した。
Hereinafter, the present invention will be described in more detail with reference to formulation examples, test examples and the like, but the present invention is not limited to these examples.
First, an example of a test sample of the ant control agent of the present invention is shown. In the examples, unless otherwise specified, parts mean parts by weight.
In preparing the test specimens of the following Examples and Comparative Examples, lauric acid, myristic acid, oleic acid, palmitic acid, linoleic acid, capric acid, capric acid, polyoxyethylene sorbitan monooleate (Tween80), and acetone were used. A reagent manufactured by Wako Pure Chemical Industries, Ltd. was used, linolenic acid and pelargonic acid were used, and a reagent manufactured by Tokyo Kasei Kogyo Co., Ltd. was used. In particular, "α-linolenic acid" was used for linolenic acid.
<アリ類定着阻害確認試験>
(1)試験検体の調製
実施例1
ラウリン酸(炭素数12)2.5重量部およびアセトンを使用して全体量を100重量部とし、各成分を混合しマグネチックスターラーにて組成が均一となるように撹拌して試験検体を調製した。
実施例2~13および比較例1、2は、下記表1、2に示した配合で、実施例1と同様にしてそれぞれの試験検体を得た。
<Ant colonization inhibition confirmation test>
(1) Preparation of test sample Example 1
Prepare a test sample by using 2.5 parts by weight of lauric acid (12 carbon atoms) and acetone to make the total amount 100 parts by weight, mixing each component and stirring with a magnetic stirrer so that the composition becomes uniform. bottom.
In Examples 2 to 13 and Comparative Examples 1 and 2, the respective test samples were obtained in the same manner as in Example 1 with the formulations shown in Tables 1 and 2 below.
(2)アリ類忌避活性の試験方法
試験の概要は図1に示す。
縦25cm、横30cm、高さ10cmのプラスチック製容器の内壁面上部に供試虫が逃亡しないよう炭酸カルシウムを施した。前記容器内には、供試虫の餌場として、水を含浸した脱脂綿を2ヵ所設置した。次に直径5.5cmのろ紙に試験検体をそれぞれ2mLずつ含浸させ、1つの餌場を囲うようにろ紙を設置した。また、対照としてアセトンを2mL含浸させた直径5.5cmのろ紙を、もう1つの餌場を囲うように設置した。
次に、容器内に供試虫(50頭)を放ち、30分後の定着数(ろ紙上のアリ類の数)を計数し、下記式にて忌避率(%)を算出した。試験は、25℃、明るい条件下にて行った。
[忌避率(%)算出式]
忌避率(%)={(対照定着数-試験検体定着数)/(試験検体定着数+対照定着数)}×100
アリ類忌避活性は、上記式により算出された忌避率(%)から下記評価基準に従い4段階で評価した。
[評価基準]
「◎」:忌避率:100%
「〇」:忌避率:70%以上100%未満
「●」:忌避率:60%以上70%未満
「×」:忌避率:60%未満
上記評価基準において、忌避率60%以上の試験検体は、本発明のアリ防除剤として実用性があると判断した。
上記試験検体の組成と、忌避率(%)および忌避評価結果をまとめ、クロヤマアリに関するものを表1に、アミメアリに関するものを表2に示した。
(2) Test method for ant repellent activity The outline of the test is shown in FIG.
Calcium carbonate was applied to the upper part of the inner wall surface of a plastic container having a length of 25 cm, a width of 30 cm, and a height of 10 cm to prevent the test insects from escaping. Two places of cotton wool impregnated with water were installed in the container as feeding grounds for the test insects. Next, 2 mL of each test sample was impregnated into a filter paper having a diameter of 5.5 cm, and the filter paper was placed so as to surround one feeding area. As a control, a filter paper having a diameter of 5.5 cm impregnated with 2 mL of acetone was installed so as to surround the other feeding area.
Next, the test insects (50) were released into the container, the number of colonization (the number of ants on the filter paper) after 30 minutes was counted, and the repellent rate (%) was calculated by the following formula. The test was conducted at 25 ° C. under bright conditions.
[Judicial disqualification rate (%) calculation formula]
Repellent rate (%) = {(number of control colonization-number of test sample colonization) / (number of test sample colonization + number of control colonization)} x 100
The ant repellent activity was evaluated from the repellent rate (%) calculated by the above formula in four stages according to the following evaluation criteria.
[Evaluation criteria]
"◎": Repellent rate: 100%
"○": Repellent rate: 70% or more and less than 100% "●": Repellent rate: 60% or more and less than 70% "×": Repellent rate: Less than 60% , It was judged to be practical as an ant control agent of the present invention.
The composition of the test sample, the repellent rate (%), and the repellent evaluation result are summarized in Table 1 for Formica japonica and Table 2 for Pristomyrmex vulgaris.
表1、2の結果より明らかなように、炭素数12以上の脂肪酸はクロヤマアリ、アミメアリのアリ類の種類に関わらず忌避率が100%または70%以上であり、優れた忌避効果を奏することが確認された。これに対し、炭素数10の脂肪酸であるカプリン酸および炭素数8の脂肪酸であるカプリル酸の、クロヤマアリ、アミメアリに対する忌避率は共に60%未満であり、脂肪酸のアリ類に対する忌避効果には、その炭素数により差異があることが明らかとなった。 As is clear from the results in Tables 1 and 2, fatty acids having 12 or more carbon atoms have a repellent rate of 100% or 70% or more regardless of the types of ants such as Formica japonica and Pristomyrmex vulgaris, and can exert an excellent repellent effect. confirmed. On the other hand, caprylic acid, which is a fatty acid having 10 carbon atoms, and caprylic acid, which is a fatty acid having 8 carbon atoms, both have a repellent rate of less than 60% against black ants and ant ants. It became clear that there was a difference depending on the number of carbon atoms.
<アリ類定着阻害効果の持続性確認試験>
試験検体をそれぞれ2mLずつ含浸させた直径5.5cmのろ紙を、30日間25℃のドラフト内に置いて風乾したものを使用した以外は、上記「アリ類定着阻害確認試験」と同様に試験を行い、供試虫(50頭)を放った1時間後の定着数(ろ紙上のアリ類の数)を計数した。上記式にて忌避率(%)を算出し、上記評価基準に従い4段階で評価した。
試験検体の組成と、忌避率(%)および忌避評価結果をまとめ、クロヤマアリに関するものを表3に、アミメアリに関するものを表4に示した。
<Sustainability confirmation test of ant colonization inhibitory effect>
The test was carried out in the same manner as the above-mentioned "ant colonization inhibition confirmation test" except that a filter paper having a diameter of 5.5 cm impregnated with 2 mL of each test sample was placed in a draft at 25 ° C for 30 days and air-dried. Then, the number of colonization (the number of ants on the filter paper) 1 hour after the test insects (50) were released was counted. The repellent rate (%) was calculated by the above formula and evaluated in 4 stages according to the above evaluation criteria.
The composition of the test sample, the repellent rate (%), and the repellent evaluation results are summarized in Table 3 for Formica japonica and Table 4 for Pristomyrmex vulgaris.
表3、4の結果より明らかなように、炭素数12以上の脂肪酸は処理から30日間経過後においても、クロヤマアリ、アミメアリのアリ類の種類に関わらず忌避率が100%あるいは60%以上の実用性のある忌避効果を発揮し、処理した場所への定着阻害効果の持続性に優れることが確認された。 As is clear from the results in Tables 3 and 4, fatty acids having 12 or more carbon atoms have a practical disqualification rate of 100% or 60% or more regardless of the type of ants such as Formica japonica and Pristomyrmex vulgaris even after 30 days from the treatment. It was confirmed that it exerts a sexual repellent effect and is excellent in sustainability of the colonization inhibitory effect in the treated place.
<殺アリ活性確認試験>
(1)試験検体の調製
実施例22
ラウリン酸(炭素数12)2.5重量部、「Tween80」1.0重量部およびイオン交換水を使用して全体量を100重量部とし、各成分を混合しマグネチックスターラーにて組成が均一となるように撹拌して試験検体を調製した。
実施例23~26および比較例3は、下記表5に示した配合で、実施例22と同様にしてそれぞれの試験検体を得た。
<Ant killing activity confirmation test>
(1) Preparation of test sample Example 22
Using 2.5 parts by weight of lauric acid (12 carbon atoms), 1.0 part by weight of "Tween 80" and ion-exchanged water, the total amount is 100 parts by weight, and each component is mixed and the composition is uniform with a magnetic stirrer. A test sample was prepared by stirring so as to be.
In Examples 23 to 26 and Comparative Example 3, the respective test samples were obtained in the same manner as in Example 22 with the formulations shown in Table 5 below.
(2)殺アリ活性の試験方法
試験の概要は図2に示した。
内径100mm、高さ45mmのプラスチック製カップ(商品名:KP-200(鴻池プラスチック社製))の内壁面上部に供試虫が逃亡しないよう炭酸カルシウムを施した。前記カップ内に供試虫5頭を放ち、10cmの距離から各試験検体3mLを噴霧器で処理した。処理後、供試虫を清潔なプラスチック製カップに移し、全頭ノックダウンするまでの時間(KT)を測定した。また、12時間後に致死数を計数し、下記式にて致死率(%)を算出した。試験は、25℃、明るい条件下にて行った。
[致死率(%)算出式]
致死率(%)=致死した供試虫数/全供試虫数×100
試験検体の組成と、クロヤマアリとアミメアリに対する致死率(%)と、クロヤマアリがノックダウンするまでの時間(KT)をまとめ、表5に示した。
(2) Test method for ant-killing activity The outline of the test is shown in FIG.
Calcium carbonate was applied to the upper part of the inner wall surface of a plastic cup (trade name: KP-200 (manufactured by Koike Plastic Co., Ltd.)) having an inner diameter of 100 mm and a height of 45 mm to prevent the test insects from escaping. Five test insects were released into the cup, and 3 mL of each test sample was treated with a sprayer from a distance of 10 cm. After the treatment, the test insects were transferred to a clean plastic cup, and the time until knockdown of all the heads (KT) was measured. In addition, the number of lethality was counted after 12 hours, and the fatality rate (%) was calculated by the following formula. The test was conducted at 25 ° C. under bright conditions.
[Case fatality rate (%) calculation formula]
Case fatality rate (%) = number of dead test insects / total number of test insects x 100
Table 5 summarizes the composition of the test sample, the mortality rate (%) for Formica japonica and Pristomyrmex vulgaris, and the time until knockdown of Formica japonica (KT).
表5の結果より明らかなように、炭素数12以上の脂肪酸はクロヤマアリ、アミメアリのアリ類の種類に関わらず、殺アリ活性が100%であることが確認された。また、全頭ノックダウンするまでの時間(KT)もラウリン酸は30秒以内であり、それ以外の炭素数12以上の脂肪酸も50秒以内であることから、本発明のアリ防除剤は、アリ類に対するノックダウン効果に優れており、さらに、優れた殺アリ活性を有することが明らかとなった。 As is clear from the results in Table 5, it was confirmed that fatty acids having 12 or more carbon atoms have 100% ant-killing activity regardless of the types of ants such as Formica japonica and Pristomyrmex vulgaris. In addition, the time (KT) for knocking down all heads is within 30 seconds for lauric acid, and within 50 seconds for other fatty acids having 12 or more carbon atoms. Therefore, the ant control agent of the present invention is an ant control agent. It was clarified that it has an excellent knockdown effect on species and also has an excellent ant-killing activity.
<植物体に対する安全性の確認試験>
(1)試験検体の調製
実施例27
ラウリン酸(炭素数12)1.0重量部、「Tween80」0.3重量部およびイオン交換水を使用して全体量を100重量部とし、各成分を混合しマグネチックスターラーにて組成が均一となるように撹拌して試験検体を調製した。
実施例28~31および比較例4~6は、下記表6に示した配合で、実施例27と同様にしてそれぞれの試験検体を得た。
<Confirmation test for safety of plants>
(1) Preparation of test sample Example 27
Using 1.0 part by weight of lauric acid (12 carbon atoms), 0.3 part by weight of "Tween 80" and ion-exchanged water to make the total amount 100 parts by weight, mix each component and make the composition uniform with a magnetic stirrer. A test sample was prepared by stirring so as to be.
In Examples 28 to 31 and Comparative Examples 4 to 6, the respective test samples were obtained in the same manner as in Example 27 with the formulations shown in Table 6 below.
(2)植物体に対する安全性の確認試験方法
5cm角のセルトレイにカイワレダイコンの種を播種し、恒温室(20℃)で5日間生育させた植物体を試験に供した。
表6に示す組成の試験検体(実施例27~31および比較例4~6)を、トリガースプレーでそれぞれ4mL散布した。除草効果は、処理1日後の変色または枯死している面積割合から下記評価基準に従い6段階で評価した。
[評価基準]
「5」:80%以上変色または枯死~100%枯死(完全枯死)
「4」:60%以上80%未満の変色または枯死
「3」:40%以上60%未満の変色または枯死
「2」:20%以上40%未満の変色または枯死
「1」:20%未満の枯死
「0」:変色無し
上記試験検体の組成と植物体に対する安全性評価結果をまとめ、表6に示した。
(2) Confirmation test method for safety of plants The seeds of Kaiware daikon were sown in a 5 cm square cell tray, and the plants grown in a constant temperature room (20 ° C.) for 5 days were subjected to the test.
Test samples having the compositions shown in Table 6 (Examples 27 to 31 and Comparative Examples 4 to 6) were sprayed with 4 mL each by a trigger spray. The herbicidal effect was evaluated on a 6-point scale according to the following evaluation criteria from the area ratio of discoloration or withering after 1 day of treatment.
[Evaluation criteria]
"5": 80% or more discoloration or death to 100% death (complete death)
"4": Discoloration or death of 60% or more and less than 80% "3": Discoloration or death of 40% or more and less than 60% "2": Discoloration or death of 20% or more and less than 40% "1": Less than 20% Withering "0": No discoloration The composition of the above test sample and the safety evaluation results for plants are summarized in Table 6.
表6の結果より明らかなように、炭素数12以上の脂肪酸は、除草活性を有することが知られているぺラルゴン酸等とは異なり、植物体を枯殺する性能を有していないことが確認された。これにより、本発明のアリ防除剤は、噴霧または散布処理した場所の植物体に対する安全性が高く、薬害を発生させる恐れがないという特徴を有することが明らかとなった。 As is clear from the results in Table 6, fatty acids having 12 or more carbon atoms do not have the ability to kill plants, unlike pelargonic acid, which is known to have herbicidal activity. confirmed. From this, it was clarified that the ant control agent of the present invention has a feature that it is highly safe for plants in the place where it is sprayed or sprayed and there is no risk of causing phytotoxicity.
炭素数12以上の脂肪酸を有効成分とする本発明のアリ防除剤は、アリ類の種類に関わらず優れたアリ類忌避効果を発揮し、その忌避効果の持続性にも優れていることから、本発明のアリ防除剤を処理後から約1ヶ月程度は、家屋等の建造物へのアリ類の侵入を阻害し、処理した場所への定着阻害効果を発揮するため、極めて実用的である。
しかも、本発明のアリ防除剤は、忌避効果と共に殺アリ効果を発揮するという優れた特徴を有するものである。すなわち、本発明のアリ防除剤は、アリ類に直接またはアリ類の巣穴に噴霧または散布処理することにより殺アリ効果を発揮し、さらに、噴霧または散布処理した場所はアリ類に対して忌避効果を有するため、アリ類を寄せ付けず、アリ類の定着を阻害することができる。
さらに、本発明のアリ防除剤は、植物を枯殺する恐れがないため、処理した場所の植物体に対する安全性が高いという特徴を有するものである。
The ant control agent of the present invention containing a fatty acid having 12 or more carbon atoms as an active ingredient exhibits an excellent ant repellent effect regardless of the type of ants, and the ant repellent effect is also excellent in sustainability. About one month after the treatment of the ant control agent of the present invention, it is extremely practical because it inhibits the invasion of ants into buildings such as houses and exerts the effect of inhibiting colonization in the treated place.
Moreover, the ant control agent of the present invention has an excellent feature of exhibiting an ant-killing effect as well as a repellent effect. That is, the ant control agent of the present invention exerts an ant-killing effect by spraying or spraying the ants directly or on the burrows of the ants, and further, the sprayed or sprayed place repels the ants. Since it has an effect, it can repel ants and inhibit the colonization of ants.
Further, the ant control agent of the present invention has a feature that it is highly safe for plants in the treated place because there is no risk of killing plants.
Claims (2)
The ant control agent according to claim 1, wherein the active ingredient is a fatty acid having 12 or more and 18 or less carbon atoms or a salt thereof.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2022028852A JP7222132B2 (en) | 2017-09-05 | 2022-02-28 | Ant control agent |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2017169904A JP7033869B2 (en) | 2017-09-05 | 2017-09-05 | Ant control agent |
JP2022028852A JP7222132B2 (en) | 2017-09-05 | 2022-02-28 | Ant control agent |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2017169904A Division JP7033869B2 (en) | 2017-09-05 | 2017-09-05 | Ant control agent |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2022068361A true JP2022068361A (en) | 2022-05-09 |
JP7222132B2 JP7222132B2 (en) | 2023-02-14 |
Family
ID=87654587
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2022028852A Active JP7222132B2 (en) | 2017-09-05 | 2022-02-28 | Ant control agent |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP7222132B2 (en) |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08301713A (en) * | 1995-03-07 | 1996-11-19 | Fumakilla Ltd | Termite expellent and extermination of termite using the same |
JPH09175903A (en) * | 1995-10-23 | 1997-07-08 | Yuukou Yakuhin Kogyo Kk | Harmful insect-exterminating agent |
JPH1067607A (en) * | 1997-08-04 | 1998-03-10 | Takeda Chem Ind Ltd | Wood insecticide |
WO2009107363A1 (en) * | 2008-02-25 | 2009-09-03 | 日本エンバイロケミカルズ株式会社 | Argentine ant control agent and method for controlling argentine ant |
US20120251641A1 (en) * | 2009-04-03 | 2012-10-04 | Tyra Tech, Inc, | Methods for pest control employing microemulsion-based enhanced pest control formulations |
-
2022
- 2022-02-28 JP JP2022028852A patent/JP7222132B2/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08301713A (en) * | 1995-03-07 | 1996-11-19 | Fumakilla Ltd | Termite expellent and extermination of termite using the same |
JPH09175903A (en) * | 1995-10-23 | 1997-07-08 | Yuukou Yakuhin Kogyo Kk | Harmful insect-exterminating agent |
JPH1067607A (en) * | 1997-08-04 | 1998-03-10 | Takeda Chem Ind Ltd | Wood insecticide |
WO2009107363A1 (en) * | 2008-02-25 | 2009-09-03 | 日本エンバイロケミカルズ株式会社 | Argentine ant control agent and method for controlling argentine ant |
US20120251641A1 (en) * | 2009-04-03 | 2012-10-04 | Tyra Tech, Inc, | Methods for pest control employing microemulsion-based enhanced pest control formulations |
Also Published As
Publication number | Publication date |
---|---|
JP7222132B2 (en) | 2023-02-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP7083606B2 (en) | Pest control agent | |
US6835719B2 (en) | Pesticidal composition | |
JP2011063576A (en) | Method for exterminating insect pest and mite | |
JP6718568B1 (en) | Pest and mite control method, and pest and mite control aerosol | |
JP7033869B2 (en) | Ant control agent | |
JP5253187B2 (en) | Spider net repelling aerosol | |
JP5761967B2 (en) | Egg spider treatment agent for spiders | |
JP7222132B2 (en) | Ant control agent | |
JP6509547B2 (en) | Pest control agent and pest control method using the same | |
JP4703172B2 (en) | One-component outdoor aerosol for outdoor use | |
JP7110026B2 (en) | Pest extermination method and pest extermination agent for escaping from nest | |
JP4836763B2 (en) | Thrips control agent | |
CN106689187A (en) | Sanitary insecticidal composition containing propoxur and application thereof | |
JP7420449B2 (en) | herbicide composition | |
JP7425277B2 (en) | Selective plant growth regulator | |
JP2006117538A (en) | Solubilizable aqueous emulsion | |
JP6824016B2 (en) | A method for enhancing the control efficacy of an aerosol for controlling flying pests used outdoors and an aerosol for controlling flying pests used outdoors. | |
JP2004196727A (en) | Communication disruptive agent for trigonotylus caelestialium(kirkaldy) | |
MXPA02007894A (en) | Fungicidal mixtures. | |
JP7286717B2 (en) | Method for enhancing herbicidal activity of acetic acid and acetic acid-containing herbicide | |
JP2018162242A (en) | Aerosol agent for grape pest control and grape pest controlling method | |
KR20130025364A (en) | Insecticidal compositions and method for insect control | |
JP7364314B2 (en) | carnivorous bee repellent | |
JP7137371B2 (en) | pest control agent | |
JP2020026385A (en) | Inhibitor of starch to sugar degradation in plant body |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20220301 Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20220301 |
|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20220301 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20230110 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20230117 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20230202 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 7222132 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |