US20160106274A1 - Toilet scrubber and toilet cleaner - Google Patents
Toilet scrubber and toilet cleaner Download PDFInfo
- Publication number
- US20160106274A1 US20160106274A1 US14/786,401 US201414786401A US2016106274A1 US 20160106274 A1 US20160106274 A1 US 20160106274A1 US 201414786401 A US201414786401 A US 201414786401A US 2016106274 A1 US2016106274 A1 US 2016106274A1
- Authority
- US
- United States
- Prior art keywords
- staple fiber
- toilet
- woven fabric
- functional
- scrubber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000203 mixture Substances 0.000 claims abstract description 105
- 239000004745 nonwoven fabric Substances 0.000 claims abstract description 98
- 238000004140 cleaning Methods 0.000 claims abstract description 74
- 239000004744 fabric Substances 0.000 claims abstract description 27
- 239000000835 fiber Substances 0.000 claims description 107
- 229920000728 polyester Polymers 0.000 claims description 46
- 229920002647 polyamide Polymers 0.000 claims description 38
- 238000000576 coating method Methods 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 21
- -1 polyethylene terephthalate Polymers 0.000 claims description 21
- 239000003945 anionic surfactant Substances 0.000 claims description 19
- 239000011248 coating agent Substances 0.000 claims description 17
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 16
- 239000000049 pigment Substances 0.000 claims description 16
- 239000002304 perfume Substances 0.000 claims description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 12
- 230000002070 germicidal effect Effects 0.000 claims description 11
- 239000002904 solvent Substances 0.000 claims description 10
- 239000003093 cationic surfactant Substances 0.000 claims description 8
- 229920001002 functional polymer Polymers 0.000 claims description 8
- 239000002736 nonionic surfactant Substances 0.000 claims description 8
- 229920002125 Sokalan® Polymers 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 7
- 229920001600 hydrophobic polymer Polymers 0.000 claims description 6
- 238000010030 laminating Methods 0.000 claims description 6
- 238000005520 cutting process Methods 0.000 claims description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 4
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 4
- 239000004094 surface-active agent Substances 0.000 claims description 4
- 229920000571 Nylon 11 Polymers 0.000 claims description 2
- 229920001007 Nylon 4 Polymers 0.000 claims description 2
- 229920002292 Nylon 6 Polymers 0.000 claims description 2
- 229920000305 Nylon 6,10 Polymers 0.000 claims description 2
- 229920002302 Nylon 6,6 Polymers 0.000 claims description 2
- 229920000572 Nylon 6/12 Polymers 0.000 claims description 2
- 239000004696 Poly ether ether ketone Substances 0.000 claims description 2
- 239000004760 aramid Substances 0.000 claims description 2
- 229920003233 aromatic nylon Polymers 0.000 claims description 2
- 229920003235 aromatic polyamide Polymers 0.000 claims description 2
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 claims description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 2
- 229920002530 polyetherether ketone Polymers 0.000 claims description 2
- 239000011112 polyethylene naphthalate Substances 0.000 claims description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 claims description 2
- 230000000052 comparative effect Effects 0.000 description 22
- 239000000356 contaminant Substances 0.000 description 17
- 239000000975 dye Substances 0.000 description 15
- 239000011521 glass Substances 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 10
- 230000000694 effects Effects 0.000 description 9
- 235000015067 sauces Nutrition 0.000 description 9
- 238000010438 heat treatment Methods 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 238000011081 inoculation Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 241000588724 Escherichia coli Species 0.000 description 6
- 241000191940 Staphylococcus Species 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 6
- 244000052616 bacterial pathogen Species 0.000 description 6
- 230000003115 biocidal effect Effects 0.000 description 6
- 238000011109 contamination Methods 0.000 description 6
- 230000001877 deodorizing effect Effects 0.000 description 6
- 230000035943 smell Effects 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 239000003242 anti bacterial agent Substances 0.000 description 4
- 229940088710 antibiotic agent Drugs 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- 238000009987 spinning Methods 0.000 description 4
- 229920002994 synthetic fiber Polymers 0.000 description 4
- 239000012209 synthetic fiber Substances 0.000 description 4
- 229960004418 trolamine Drugs 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 241000207199 Citrus Species 0.000 description 3
- 241001360526 Escherichia coli ATCC 25922 Species 0.000 description 3
- 240000007594 Oryza sativa Species 0.000 description 3
- 235000007164 Oryza sativa Nutrition 0.000 description 3
- 241000295644 Staphylococcaceae Species 0.000 description 3
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 3
- 229930006000 Sucrose Natural products 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 235000020971 citrus fruits Nutrition 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 235000009566 rice Nutrition 0.000 description 3
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 3
- 239000005720 sucrose Substances 0.000 description 3
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical group C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 2
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 description 2
- UUUXCBNPERIZJL-UHFFFAOYSA-N C(CCCCCCCCCCCCCCCC)OS(=O)(=O)C1=CC=CC=C1.[Na] Chemical compound C(CCCCCCCCCCCCCCCC)OS(=O)(=O)C1=CC=CC=C1.[Na] UUUXCBNPERIZJL-UHFFFAOYSA-N 0.000 description 2
- ODTIBMTVVJOUKQ-UHFFFAOYSA-N CCN.C1=CC=C2C(S(=O)(=O)OCCCCCCCCCCC)=CC=CC2=C1 Chemical compound CCN.C1=CC=C2C(S(=O)(=O)OCCCCCCCCCCC)=CC=CC2=C1 ODTIBMTVVJOUKQ-UHFFFAOYSA-N 0.000 description 2
- 235000005979 Citrus limon Nutrition 0.000 description 2
- 244000131522 Citrus pyriformis Species 0.000 description 2
- 239000002033 PVDF binder Substances 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- UUXKYWQZAAZOSD-UHFFFAOYSA-N [Na].C1=CC=C2C(S(=O)(=O)OCCCCCCCCCCCCCCCCCCCCCC)=CC=CC2=C1 Chemical compound [Na].C1=CC=C2C(S(=O)(=O)OCCCCCCCCCCCCCCCCCCCCCC)=CC=CC2=C1 UUXKYWQZAAZOSD-UHFFFAOYSA-N 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 230000003466 anti-cipated effect Effects 0.000 description 2
- YUNCPNDMROTHLR-UHFFFAOYSA-N azane methyl 2-dodecylbenzenesulfonate Chemical compound N.CCCCCCCCCCCCC1=CC=CC=C1S(=O)(=O)OC YUNCPNDMROTHLR-UHFFFAOYSA-N 0.000 description 2
- PLUHAVSIMCXBEX-UHFFFAOYSA-N azane;dodecyl benzenesulfonate Chemical compound N.CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 PLUHAVSIMCXBEX-UHFFFAOYSA-N 0.000 description 2
- VPDKMELSVLIAOG-UHFFFAOYSA-N azanium;decyl sulfate Chemical compound N.CCCCCCCCCCOS(O)(=O)=O VPDKMELSVLIAOG-UHFFFAOYSA-N 0.000 description 2
- ACWQSLXTIYNAJO-UHFFFAOYSA-N azanium;nonyl sulfate Chemical compound [NH4+].CCCCCCCCCOS([O-])(=O)=O ACWQSLXTIYNAJO-UHFFFAOYSA-N 0.000 description 2
- 229960000686 benzalkonium chloride Drugs 0.000 description 2
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 2
- 235000012745 brilliant blue FCF Nutrition 0.000 description 2
- 239000004161 brilliant blue FCF Substances 0.000 description 2
- 239000002775 capsule Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 238000007766 curtain coating Methods 0.000 description 2
- RTXWGCFBOYSLIQ-UHFFFAOYSA-F dicopper;tetrasodium;4-amino-6-[[4-[4-[(8-amino-1-oxido-5,7-disulfonatonaphthalen-2-yl)diazenyl]-3-oxidophenyl]-2-oxidophenyl]diazenyl]-5-oxidonaphthalene-1,3-disulfonate Chemical compound [Na+].[Na+].[Na+].[Na+].[Cu+2].[Cu+2].[O-]S(=O)(=O)C1=CC(S([O-])(=O)=O)=C(N)C2=C([O-])C(N=NC3=CC=C(C=C3[O-])C3=CC=C(C(=C3)[O-])N=NC3=CC=C4C(=CC(=C(C4=C3[O-])N)S([O-])(=O)=O)S([O-])(=O)=O)=CC=C21 RTXWGCFBOYSLIQ-UHFFFAOYSA-F 0.000 description 2
- 238000003618 dip coating Methods 0.000 description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 2
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 2
- QGVQVNIIRBPOAM-UHFFFAOYSA-N dodecyl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(=O)OCCCCCCCCCCCC)=CC=CC2=C1 QGVQVNIIRBPOAM-UHFFFAOYSA-N 0.000 description 2
- KWKXNDCHNDYVRT-UHFFFAOYSA-N dodecylbenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1 KWKXNDCHNDYVRT-UHFFFAOYSA-N 0.000 description 2
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 238000007756 gravure coating Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- UZZYXUGECOQHPU-UHFFFAOYSA-M n-octyl sulfate Chemical compound CCCCCCCCOS([O-])(=O)=O UZZYXUGECOQHPU-UHFFFAOYSA-M 0.000 description 2
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 2
- KIHUPOKUSVEICJ-UHFFFAOYSA-N nonyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 KIHUPOKUSVEICJ-UHFFFAOYSA-N 0.000 description 2
- MXXDSLLVYZMTFA-UHFFFAOYSA-N octadecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 MXXDSLLVYZMTFA-UHFFFAOYSA-N 0.000 description 2
- DZQYCOCAFPQWBL-UHFFFAOYSA-N octadecyl sulfate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCCCCCCCOS(O)(=O)=O DZQYCOCAFPQWBL-UHFFFAOYSA-N 0.000 description 2
- 229940067739 octyl sulfate Drugs 0.000 description 2
- 229920002493 poly(chlorotrifluoroethylene) Polymers 0.000 description 2
- 239000005023 polychlorotrifluoroethylene (PCTFE) polymer Substances 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- DQFWABVCOIFBPO-UHFFFAOYSA-M potassium;tetradecyl sulfate Chemical compound [K+].CCCCCCCCCCCCCCOS([O-])(=O)=O DQFWABVCOIFBPO-UHFFFAOYSA-M 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 238000007767 slide coating Methods 0.000 description 2
- 238000007764 slot die coating Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- QVCCZAZTGUCIHD-UHFFFAOYSA-M sodium;2-[(4-amino-3-bromo-9,10-dioxoanthracen-1-yl)amino]-5-methylbenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC(C)=CC=C1NC1=CC(Br)=C(N)C2=C1C(=O)C1=CC=CC=C1C2=O QVCCZAZTGUCIHD-UHFFFAOYSA-M 0.000 description 2
- RLJSXMVTLMHXJS-UHFFFAOYSA-M sodium;4-decylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 RLJSXMVTLMHXJS-UHFFFAOYSA-M 0.000 description 2
- GGHPAKFFUZUEKL-UHFFFAOYSA-M sodium;hexadecyl sulfate Chemical compound [Na+].CCCCCCCCCCCCCCCCOS([O-])(=O)=O GGHPAKFFUZUEKL-UHFFFAOYSA-M 0.000 description 2
- FTWCSAMTIKSPAT-UHFFFAOYSA-M sodium;nonyl sulfate Chemical compound [Na+].CCCCCCCCCOS([O-])(=O)=O FTWCSAMTIKSPAT-UHFFFAOYSA-M 0.000 description 2
- NWZBFJYXRGSRGD-UHFFFAOYSA-M sodium;octadecyl sulfate Chemical compound [Na+].CCCCCCCCCCCCCCCCCCOS([O-])(=O)=O NWZBFJYXRGSRGD-UHFFFAOYSA-M 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 2
- UZZYXUGECOQHPU-UHFFFAOYSA-N sulfuric acid monooctyl ester Natural products CCCCCCCCOS(O)(=O)=O UZZYXUGECOQHPU-UHFFFAOYSA-N 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- JQGGYGKXKWTXTF-UHFFFAOYSA-N 1-ethenoxy-3-prop-2-enoxy-2,2-bis(prop-2-enoxymethyl)propane Chemical compound C=CCOCC(COCC=C)(COCC=C)COC=C JQGGYGKXKWTXTF-UHFFFAOYSA-N 0.000 description 1
- CYEJMVLDXAUOPN-UHFFFAOYSA-N 2-dodecylphenol Chemical compound CCCCCCCCCCCCC1=CC=CC=C1O CYEJMVLDXAUOPN-UHFFFAOYSA-N 0.000 description 1
- FYRWKWGEFZTOQI-UHFFFAOYSA-N 3-prop-2-enoxy-2,2-bis(prop-2-enoxymethyl)propan-1-ol Chemical compound C=CCOCC(CO)(COCC=C)COCC=C FYRWKWGEFZTOQI-UHFFFAOYSA-N 0.000 description 1
- 235000003717 Boswellia sacra Nutrition 0.000 description 1
- 240000007551 Boswellia serrata Species 0.000 description 1
- 235000012035 Boswellia serrata Nutrition 0.000 description 1
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 239000004863 Frankincense Substances 0.000 description 1
- 235000019479 German chamomile oil Nutrition 0.000 description 1
- 235000019501 Lemon oil Nutrition 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 235000019502 Orange oil Nutrition 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 229920001213 Polysorbate 20 Polymers 0.000 description 1
- 240000000513 Santalum album Species 0.000 description 1
- 235000008632 Santalum album Nutrition 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- XEKWJQURPPJYTC-UHFFFAOYSA-N [Cl-].CC(CCCCCCCCCCC[NH+](CCCCCCCCCCCC)CC)C Chemical compound [Cl-].CC(CCCCCCCCCCC[NH+](CCCCCCCCCCCC)CC)C XEKWJQURPPJYTC-UHFFFAOYSA-N 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- JQRRFDWXQOQICD-UHFFFAOYSA-N biphenylen-1-ylboronic acid Chemical compound C12=CC=CC=C2C2=C1C=CC=C2B(O)O JQRRFDWXQOQICD-UHFFFAOYSA-N 0.000 description 1
- 238000009960 carding Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229960003333 chlorhexidine gluconate Drugs 0.000 description 1
- YZIYKJHYYHPJIB-UUPCJSQJSA-N chlorhexidine gluconate Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O.C1=CC(Cl)=CC=C1NC(=N)NC(=N)NCCCCCCNC(=N)NC(=N)NC1=CC=C(Cl)C=C1 YZIYKJHYYHPJIB-UUPCJSQJSA-N 0.000 description 1
- 239000010632 citronella oil Substances 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- GFLLOMRSVVPUNQ-UHFFFAOYSA-M dimethyl-propyl-tetradecylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[N+](C)(C)CCC GFLLOMRSVVPUNQ-UHFFFAOYSA-M 0.000 description 1
- ZHDBTKPXEJDTTQ-UHFFFAOYSA-N dipyrithione Chemical compound [O-][N+]1=CC=CC=C1SSC1=CC=CC=[N+]1[O-] ZHDBTKPXEJDTTQ-UHFFFAOYSA-N 0.000 description 1
- ZAPUWVBRCYPPQT-UHFFFAOYSA-N ethyl(18-methylnonadecyl)azanium;chloride Chemical compound [Cl-].CC[NH2+]CCCCCCCCCCCCCCCCCC(C)C ZAPUWVBRCYPPQT-UHFFFAOYSA-N 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000010656 jasmine oil Substances 0.000 description 1
- 239000000171 lavandula angustifolia l. flower oil Substances 0.000 description 1
- 239000010501 lemon oil Substances 0.000 description 1
- 239000001525 mentha piperita l. herb oil Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000010502 orange oil Substances 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 235000019477 peppermint oil Nutrition 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229960003811 pyrithione disulfide Drugs 0.000 description 1
- 239000010666 rose oil Substances 0.000 description 1
- 235000019719 rose oil Nutrition 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- XNRNJIIJLOFJEK-UHFFFAOYSA-N sodium;1-oxidopyridine-2-thione Chemical compound [Na+].[O-]N1C=CC=CC1=S XNRNJIIJLOFJEK-UHFFFAOYSA-N 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229940043810 zinc pyrithione Drugs 0.000 description 1
- PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L25/00—Domestic cleaning devices not provided for in other groups of this subclass
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47K—SANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
- A47K11/00—Closets without flushing; Urinals without flushing; Chamber pots; Chairs with toilet conveniences or specially adapted for use with toilets
- A47K11/10—Hand tools for cleaning the toilet bowl, seat or cover, e.g. toilet brushes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/022—Non-woven fabric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/20—All layers being fibrous or filamentary
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/02—Coating on the layer surface on fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0261—Polyamide fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0276—Polyester fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2432/00—Cleaning articles, e.g. mops, wipes
Definitions
- the present disclosure relates to a toilet scrubber and a toilet cleaner.
- Toilet scrubbers have been widely used to remove contaminants on the toilet surface.
- a toilet scrubber 1 consists of only one layer for removing contaminants.
- the toilet scrubber 1 is used while one side thereof is connected to a handle 2 .
- the toilet scrubber of the prior art has only a function of removing contaminants, but does not have other functions, such as protecting the toilet surface from the contaminants after cleaning or removing bad smells, which causes an inconvenience in that the toilet needs to be frequently cleaned.
- a toilet scrubber has superior ability to remove contaminants on the toilet surface as well as imparting antibiotic, anti-contaminating, and deodorizing effects to the toilet surface.
- a toilet scrubber comprises a non-woven cleaning fabric layer including a cleaning composition and a functional non-woven fabric layer including a functional composition.
- a toilet cleaner comprises the toilet scrubber and a handle connected to one side of the toilet scrubber.
- a method of preparing a toilet scrubber including the steps of forming a first non-woven fabric by using a first polyester-based staple fiber, a first polyamide-based staple fiber, or a mixture thereof; coating a cleaning composition on the first non-woven fabric to form a non-woven cleaning fabric layer; forming a second non-woven fabric by using a second polyester-based staple fiber, a second polyamide-based staple fiber, or a mixture thereof; coating a functional composition on the second non-woven fabric to form a functional non-woven fabric layer; laminating the non-woven cleaning fabric layer on the functional non-woven fabric layer to form a laminate sheet; and cutting the laminate sheet.
- FIG. 1 is a perspective view showing a toilet scrubber of the prior art
- FIG. 2 is a perspective view showing a toilet scrubber according to an exemplary embodiment of the present invention
- FIG. 3 is a perspective view showing a toilet cleaner according to an exemplary embodiment of the present invention.
- FIG. 4 is a graph showing whiteness of tile surfaces after the tile surfaces are coated with steak sauce and then respectively cleaned by toilet scrubbers of Examples 1 to 3 and Comparative Example 1;
- FIG. 5 is a graph showing whiteness of tile surfaces after the tile surfaces are coated with rice paste and then respectively cleaned by the toilet scrubbers of Examples 1 to 3 and Comparative Example 1;
- FIG. 6 is a graph showing contaminant removal on tile surfaces after the tile surfaces are respectively coated with steak sauce and rice paste and then respectively cleaned by the toilet scrubbers of Examples 1 to 3 and Comparative Example 1;
- FIG. 7 is a graph showing anti-contaminating efficiency of the toilet scrubbers of Examples 1 to 3 and Comparative Example 1;
- FIG. 8 shows images displaying propagation or non-propagation of staphylococcus 5 minutes after Staphylococcus ATCC 6538 is inoculated on tiles respectively cleaned by the toilet scrubbers of Examples 1 to 3 and Comparative Example 1; and images displaying propagation or non-propagation of E. coli 5 minutes after Escherichia Coli ATCC 25922 is inoculated on tiles respectively cleaned by the toilet scrubbers of Examples 1 to 3 and Comparative Example 1.
- the disclosed toilet scrubber can effectively remove germs and bad smells as well as contaminants on the toilet surface, protect the toilet surface from the contaminants, and suppress the propagation of germs on the toilet surface, by including a non-woven cleaning fabric layer including a cleaning composition and a functional non-woven fabric layer including a functional composition.
- FIG. 2 is a perspective view of a toilet scrubber 100 .
- the toilet scrubber 100 includes a non-woven cleaning fabric layer 10 and a functional non-woven fabric layer 20 .
- the non-woven cleaning fabric layer 10 which removes contaminants on the toilet surface, includes a first non-woven fabric and a cleaning composition formed on a surface of the first non-woven fabric and/or inside the first non-woven fabric.
- the first non-woven fabric includes a first polyester-based staple fiber, a first polyamide-based staple fiber, or a mixture thereof.
- the first polyester-based staple fiber(s) and/or the first polyamide-based staple fiber(s) are both physically interlaced with and bonded to each other by various non-woven fabric preparing methods known in the art.
- This first non-woven fabric can extend the lifespan of the toilet scrubber due to excellent durability thereof.
- thermally, physically or chemically bonding webs each consisting of fibers to each other such as, bonding the fibers in the webs to each other by using an adhesive or melting the fibers in the web to bond the fibers with each other. Examples thereof are thermal bonding, spun-bond, and the like, but are not limited thereto.
- the first polyester-based staple fiber is a synthetic fiber obtained by spinning a polymer containing an ester (—COO—) bond on a main chain and then slitting it into a predetermined length.
- the first polyester-based staple fiber has superior durability and flexibility, resulting in fewer scratches on the toilet at the time of using the final scrubber.
- the first polyester-based staple fiber has excellent acid resistance, alkali resistance, and chemical resistance; high mechanical strength; little change in strength even when the scrubber is wet; is hardly discolored; and has low absorptiveness to water and thus very high dryness. Therefore, the first non-woven fabric including the first polyester-based staple fiber has high dryness and strength, excellent durability, strength, wear resistance, and chemical resistance, and the like, so that the durability, strength, and wear resistance of the toilet scrubber can be also improved.
- Non-limited examples of the first polyester-based staple fiber are a polyethylene terephthalate staple fiber, a polyethylene naphthalate staple fiber, a polybutylene terephthalate staple fiber, a poly(1,4-cyclohexylenedimethylene terephthalate staple fiber, a polyesterether staple fiber, a polyetheretherketone staple fiber, and the like, which may be used alone or in a mixture of two or more thereof.
- the fineness of the first polyester-based staple fiber is not particularly limited. But when the first polyester-based staple fiber used is too thin, a large amount of fibers are needed for giving volume, which causes the non-woven fabric layer to be too dense and stiffened and the preparation cost to be increased. In the case where the fineness of the first polyester-based staple fiber is controlled to be about 20 to 80 denier and desirably about 40 to 60 denier, a final toilet scrubber having sufficient volume and excellent touch can be prepared at a low cost.
- the first polyamide-based staple fiber is a synthetic fiber obtained by spinning a polymer containing an amide (—CONH—) bond on a main chain and then slitting it into a predetermined length.
- the first polyamide-based staple fiber has superior durability and flexibility, resulting in fewer scratches on the toilet at the time of using the final scrubber. Further, the first polyamide-based staple fiber has low absorptiveness to water and thus very high dryness; high strength; and excellent elasticity, wear resistance, chemical resistance, and heat resistance. Therefore, the first non-woven fabric including the first polyamide-based staple fiber has high dryness and strength and excellent durability, strength, wear resistance, chemical resistance, and heat resistance, so that the durability, strength, and wear resistance of the toilet scrubber can be also improved.
- Examples of the first polyamide-based staple fiber are nylon 6, nylon 66, nylon 11, nylon 610, nylon 612, nylon 4, aromatic nylon, aramid, and the like, but are not limited thereto.
- the fineness of the first polyamide-based staple fiber is not particularly limited. However, when the fineness of the first polyamide-based staple fiber is controlled to be about 20 to 80 denier and desirably about 40 to 60 denier, like the first polyester-based staple fiber, it can increase volume and improve touch of the final toilet scrubber and result in a reduction in the preparation cost thereof.
- polyamide-based staple fiber as described above leads to an improvement in durability and touch feeling but an increase in the preparation cost thereof, as compared with the use of the polyester-based staple fiber.
- the non-woven cleaning fabric layer 10 includes a cleaning composition.
- the cleaning composition may coat a surface of the first non-woven fabric or fill an inside of the first non-woven fabric, or may both coat a surface of the first non-woven fabric and fill an inside of the first non-woven fabric.
- the cleaning composition may be eluted at the time of using the toilet scrubber to thereby remove contaminants on the toilet surface.
- the cleaning composition may include an anionic surfactant; an ethanolamine-based compound; a pigment and/or dye; and a solvent.
- anionic surfactant used herein are sodium decylbenzene sulfonate, sodium dodecylbenzene sulfonate, ammonium methyl dodecylbenzene sulfonate, ammonium dodecylbenzene sulfonate, sodium octadecylbenzene sulfonate, sodium nonylbenzene sulfonate, sodium dodecylnaphthalene sulfonate, sodium heptadecylbenzene sulfonate, potassium eicososyl naphthalene sulfonate, ethylamine undecylnaphthalene sulfonate, sodium docosylnaphthalene sulfonate, sodium octadecyl sulfate, sodium hexadecyl sulfate, sodium dodecyl sulfate,
- dodecylbenzene sulfonate neutralized with Na and dodecylbenzene sulfuonate neutralized with triethanol amine may be used.
- the amount of the anionic surfactant is not particularly limited. However, when the amount of anionic surfactant used is too small, a desired cleaning power may not be obtained. On the contrary, when the amount of anionic surfactant used is too large, the preparation cost may be increased, and viscosity of the cleaning composition is too high, which makes it difficult to coat on the first non-woven fabric by a roll coating method or the like. Hence, the amount of anionic surfactant may be controlled to be about 40 to 60 wt % based on the total weight of the cleaning composition.
- dodecylbenzene sulfonate neutralized with Na 25 to 40 wt % of dodecylbenzene sulfonate neutralized with Na and 15 to 20 wt % of dodecylbenzene sulfuonate neutralized with triethanol amine may be used.
- the ethanolamine-based compound used herein has a good mixablity with water and high viscosity, thereby preventing an anionic surfactant or a pigment and/or dye from being separated at the time of forming a non-woven cleaning fabric layer. Further, it allows components in the cleaning composition to be homogeneously dispersed, thereby reducing the generation of flakes in a slitting process at the time of preparing the scrubber, and further improving the cleaning effect together with the anionic surfactant.
- ethanolamine-based compound examples include diethanolamine, triethanolamine, and the like, but are not limited thereto.
- the amount of the ethanolamine-based compound is not particularly limited. However, when the amount of the ethanolamine-based compound is about 15 to 20 wt % based on the total weight of the cleaning composition, it can reduce the generation of flakes in a slitting process at the time of preparing the scrubber and further improve the cleaning effect together with the anionic surfactant.
- the pigment and/or dye used herein are/is not particularly limited as long as it can be eluted together with other components when being contacted with water.
- Non-limited examples of the pigment or dye are pigments such as Nylosan Blue, Hostafine Blue, AquaLor Blue, water-soluble dyes such as Direct Blue 76, Direct Blue 86, Direct Blue 108, Direct Blue 199, Direct Blue 236, Acid Blue 9, Acid Blue 78, Acid Blue 82, and Acid Blue 234, and the like. Due to the inclusion of the pigment and/or dye, the color of the toilet scrubber becomes lighter as the toilet scrubber is more often used, so that the replacement time of the toilet scrubber can be anticipated.
- the amount of the pigment, dye, or mixture thereof is not particularly limited, but may be controlled to be 0.05 to 10 wt % based on the total weight of the cleaning composition depending on the coloring degree of the non-woven cleaning fabric layer.
- the solvent used herein is not particularly limited as long as it can easily dissolve the anionic surfactant, the ethanolamine-based compound, and the pigment and/or dye.
- Examples of the solvent are water and the like.
- the amount of the solvent is not particularly limited, but may be a remainder that controls the total weight of the cleaning composition to be 100 wt %.
- the viscosity of the cleaning composition is not particularly limited. However, when the viscosity of the cleaning composition is 200 to 600 cps, it can easily coat a surface of the first non-woven fabric as well as fill the inside of the first non-woven fabric by a roll coating method or the like.
- the coating amount (use amount) of the cleaning composition is not particularly limited. However, when the coating amount of the cleaning composition is 20 to 40 parts by weight based on 100 parts by weight of the first non-woven fabric, it can minimize the generation of flake at the time of preparing the scrubber and economically further maximize the cleaning effect of the scrubber.
- the toilet scrubber 100 includes a functional non-woven fabric layer 20 laminated on one side of the foregoing non-woven cleaning fabric layer 10 .
- the toilet scrubber of the present invention can effectively remove germs and bad smells, protect the toilet surface from contaminants, and suppress the propagation of germs on the toilet surface, by including the functional non-woven fabric layer 20 .
- the functional non-woven fabric layer 20 includes a second non-woven fabric and a functional composition formed on a surface of the second non-woven fabric and/or inside the second non-woven fabric.
- the second non-woven fabric includes a second polyester-based staple fiber, a second polyamide-based staple fiber, or a mixture thereof.
- the second polyester-based staple fiber(s) and/or second polyamide-based staple fiber(s) are both physically interlaced with and bonded to each other by various non-woven fabric preparing methods known in the art, like the first non-woven fabric.
- the toilet scrubber of the present invention has improved durability, resulting in extending the lifespan thereof, by including the second non-woven fabric.
- the second polyester-based staple fiber is a synthetic fiber obtained by spinning a polymer containing an ester (—COO—) bond on a main chain and then slitting it into a predetermined length, like the first polyester-based staple fiber.
- Examples of the second polyester-based staple fiber are the same as those described in the first polyester-based staple fiber.
- the first polyester-based staple fiber and the second polyester-based staple fiber may be identical to or different from each other.
- the fineness of the second polyester-based staple fiber is not particularly limited. However, when the fineness of the second polyester-based staple fiber is 20 to 80 denier and desirably 40 to 60 denier, like the fineness of the first polyester-based staple fiber. It can increase volume and improve touch of the final toilet scrubber and result in a reduction in the preparation cost.
- the second polyamide-based staple fiber is a synthetic fiber obtained by spinning a polymer containing an amide (—CONH—) bond on a main chain and then slitting it into a predetermined length, like the first polyamide-based staple fiber.
- Examples of the second polyamide-based staple fiber are the same as those described in the first polyamide-based staple fiber.
- the first polyamide-based staple fiber and the second polyamide-based staple fiber may be identical to or different from each other.
- the fineness of the second polyamide-based staple fiber is not particularly limited. However, when the fineness of the second polyamide-based staple fiber is about 20 to 80 denier and desirably about 40 to 60 denier, like the fineness of the first polyamide-based staple fiber, it can further volume feeling and touch feeling of the final toilet scrubber and result in a reduction in the preparation cost.
- the functional non-woven fabric layer 20 of the present invention includes a functional composition.
- the functional composition coats a surface of the second non-woven fabric, or coats or fills an inside of the second non-woven fabric.
- the functional composition may be eluted at the time of using the toilet scrubber to thereby effectively remove germs and bad smells, and the eluted functional composition may form a protecting film on the toilet surface to thereby protect the toilet surface from contaminants and suppress the propagation of germs on the toilet surface.
- the functional composition may include a functional polymer and one or more surfactant.
- the functional polymer is selected from the group consisting of a hydrophobic polymer, an acrylic acid polymer, a fluororesin, and a mixture thereof.
- the surfactant is a nonionic surfactant, an anionic surfactant, or a mixture thereof.
- the functional composition may further include (a) a cationic surfactant, a germicide, or a mixture thereof; (b) a pigment, a dye, or a mixture thereof; (c) a perfume; and (d) a solvent.
- the functional composition includes a functional polymer selected from the group consisting of a hydrophobic polymer, an acrylic acid polymer, a fluororesin, and a mixture thereof.
- a functional polymer selected from the group consisting of a hydrophobic polymer, an acrylic acid polymer, a fluororesin, and a mixture thereof.
- the functional composition includes the hydrophobic polymer
- the functional composition eluted from the toilet scrubber may form a protecting film on the toilet surface and fewer contaminants may be attached on the toilet surface due to the formed protecting film.
- the functional composition includes the acrylic acid polymer
- the property of the toilet surface is changed from hydrophobicity into hydrophilicity, so that the contaminants attached on the toilet surface are detached and thus easily removed.
- the functional composition includes the fluororesin, the contaminants can be prevented from being attached on the toilet surface due to the fluororesin, like the hydrophobic polymer.
- hydrophobic polymer examples include a siloxane-based polymer and the like.
- the siloxane-based polymer is not particularly limited as long as it contains a main chain in which silicon atoms and oxygen atoms are alternately bonded.
- examples thereof are polysiloxane, polyalkylsiloxane, and polyarylsiloxane, and specifically, polyethylsiloxane, polymethylsiloxane, polyphenylsiloxane, and the like, but are not limited thereto.
- the acrylic acid polymer includes an acrylic acid homopolymer consisting of only acrylic acid monomers, a cross-linked acrylic acid polymer consisting of acrylic acid monomers and a cross-linking agent, and the like, but is not limited thereto.
- the cross-linking agent are trimethylolpropane diallyl ether, trimethylolpropane triallyl ether, diallyl pentaerythritol ether, triallyl pentaerythritol ether, tetraallyl pentaerythritol ether, diallyl sucrose ether, triallyl sucrose ether, tetraallyl sucrose ether, and the like, but are not limited thereto.
- the fluororesin usable herein is not particularly limited as long as it contains fluorine in the molecule thereof.
- examples thereof are polytetrafluoroethylene (PTFE), polychlorotrifluoroethylene (PCTFE), polyvinylidene fluoride (PVDF), and the like, but are not limited thereto.
- the amount of the functional polymer is not particularly limited. However, when the amount of the functional polymer is about 0.5 to 5 wt %, it can economically further improve anti-contaminating efficiency thereof and can be homogeneously mixed with other components.
- the functional composition may be used in combination with a nonionic surfactant and/or anionic surfactant; and a cationic surfactant and/or germicide.
- a nonionic surfactant and/or anionic surfactant and the cationic surfactant and/or germicide, the functional composition can further improve cleaning, anti-contaminating, and germicidal functions, as compared with the cases where they are used alone.
- the nonionic surfactant and the anionic surfactant exhibit cleaning and anti-contaminating efficiencies
- the cationic surfactant and the germicide exhibit anti-biotic and anti-contaminating efficiencies.
- Non-limited examples of the nonionic surfactant are ethylene diamine, diethylene glycol, dodecyl phenol, nonyl phenol, tetradecyl alcohol, N-octadecyl diethanolamide, N-dodecyl monoethanolamide, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monolaurate, and the like.
- Non-limited examples of the anionic surfactant are sodium decylbenzene sulfonate, sodium dodecylbenzene sulfonate, ammonium methyl dodecylbenzene sulfonate, ammonium dodecylbenzene sulfonate, sodium octadecylbenzene sulfonate, sodium nonylbenzene sulfonate, sodium dodecylnaphthalene sulfonate, sodium heptadecylbenzene sulfonate, potassium eicososyl naphthalene sulfonate, ethylamine undecylnaphthalene sulfonate, sodium docosylnaphthalene sulfonate, sodium octadecyl sulfate, sodium hexadecyl sulfate, sodium dodecyl sulfate
- the amount of the nonionic surfactant, anionic surfactant, or mixture thereof is not particularly limited, but when the amount thereof is 10 to 35 wt % based on the total weight of the functional composition, the coating efficiency thereof can be improved and the cleaning effect thereof can be economically further improved.
- Non-limited examples of the cationic surfactant used herein are benzalkonium chloride, ethyl-dimethylstearyl ammonium chloride, benzyl-dimethyl-stearyl ammonium chloride, benzyldimethyl-stearyl ammonium chloride, trimethyl stearyl ammonium chloride, trimethylcetyl ammonium bromide, dimethylethyl dilaurylammonium chloride, dimethyl-propyl-myristyl ammonium chloride, and the like.
- Non-limited examples of the germicide are zinc pyrithione, sodium pyrithione, dipyrithione, ketaconazole, salicylic acid, chlorhexidine gluconate, 2,4,4-trichloro-2-hydroxy diphenyl ether, and the like, which may be used alone or in a mixture of two or more thereof.
- the amount of the cationic surfactant, germicide, or mixture thereof is not particularly limited, but when the amount thereof is 0.5 to 1 wt % based on the total weight of the functional composition, the anti-contaminating and germicidal effects can be economically further improved.
- the pigment and/or dye used herein are/is not particularly limited as long as it can be easily eluted together with other components at the time of being contacted with water.
- Non-limited examples of the pigment or dye are Nylosan Blue, Hostafine Blue, and AquaLor Blue, water-soluble dyes such as Direct Blue 76, Direct Blue 86, Direct Blue 108, Direct Blue 199, Direct Blue 236, Acid Blue 9, Acid Blue 78, Acid Blue 82, and Acid Blue 234, and the like. Due to the inclusion of the pigment and/or dye, the color of the toilet scrubber becomes lighter as the toilet scrubber is more often used, so that the replacement time of the toilet scrubber can be anticipated.
- the amount of the pigment, dye, or mixture thereof is not particularly limited, but may be controlled to be 0.05 to 10 wt % based on the total weight of the functional composition depending on the coloring degree of the functional non-woven fabric layer.
- the perfume used herein may remove bad smells by covering bad smell substances. Therefore, the present invention can further exhibit a deodorizing effect and further exhibit an aromatic effect by including the perfume.
- Examples of the perfume are general aromatic perfumes or natural aroma oils on the market. Specifically, examples thereof are citrus-based perfumes such as lemon, orange, and citrus, peppermint oil, citronella oil, rose oil, lavender oil, jasmine oil, lemon oil, orange oil, sandalwood, frankincense, German chamomile oil, and the like, but are not limited thereto.
- citrus-based perfumes such as lemon, orange, and citrus, peppermint oil, citronella oil, rose oil, lavender oil, jasmine oil, lemon oil, orange oil, sandalwood, frankincense, German chamomile oil, and the like, but are not limited thereto.
- the perfume may be capsulated by a polymer capsule.
- the perfume When the perfume is capsulated by the polymer capsule, the loss of perfume due to the pressure or temperature for preparing the scrubber or the formation of the functional composition can be prevented, and thus the unit cost of the perfume can be reduced and the deodorizing and aromatic effects can be improved. Further, the perfume itself can be stably treated and stored at the time of preparing the scrubber.
- the amount of the perfume is not particularly limited, but when the amount thereof is about 0.1-3 wt % based on the total weight of the functional composition, the deodorizing effect can be enhanced without deteriorating the anti-biotic effect, and the aroma effect can be better exhibited.
- the solvent used herein is not particularly limited as long as it can easily dissolve the functional polymer; the nonionic surfactant and/or anionic surfactant; the cationic surfactant and/or germicide; the pigment and/or dye; and the perfume.
- Examples of the solvent are water and the like.
- the amount of the solvent is not particularly limited, and may be a remainder that controls the total weight of the functional composition to be 100 wt %.
- the viscosity of the functional composition is not particularly limited. However, when the viscosity of the functional composition is 200 to 600 cps, it can easily coat a surface of the second non-woven fabric and fill the inside of the second non-woven fabric by a roll coating method or the like.
- the coating amount (use amount) of the functional composition is not particularly limited, but when the coating amount thereof is 20 to 40 parts by weight based on 100 parts by weight of the second non-woven fabric, it can minimize the generation of flake at the time of preparing the scrubber and economically maximize the cleaning, anti-biotic, and deodorizing effects of the scrubber.
- the toilet scrubber may be prepared by various methods, and thus the preparation of the toilet scrubber is not limited to the following method.
- the toilet scrubber may be prepared by including the steps of: forming a first non-woven fabric by using a first polyester-based staple fiber, a first polyamide-based staple fiber, or a mixture thereof; coating a cleaning composition on the first non-woven fabric to form a non-woven cleaning fabric layer; forming a second non-woven fabric by using a second polyester-based staple fiber, a second polyamide-based staple fiber, or a mixture thereof; coating a functional composition on the second non-woven fabric to form a functional non-woven fabric layer; laminating the non-woven cleaning fabric layer on the functional non-woven fabric layer to form a laminate sheet; and cutting the laminate sheet.
- a first non-woven fabric including a first polyester-based staple fiber, a first polyamide-based staple fiber, or a mixture thereof is formed (hereinafter, ‘step S 100 ’).
- step S 100 bonding between the first polyester-based staple fibers, between the first polyamide-based staple fibers, or between the first polyester-based staple fiber and the first polyamide-based staple fiber, of a first web, may be conducted by a non-woven fabric preparing method known in the art.
- the first polyester-based staple fibers are physically interlaced with each other to form the first web, and these first polyester-based staple fibers in the first web are bonded to each other by an adhesive, thermal bonding, or the like, to thereby form the first non-woven fabric.
- step S 100 includes the steps of: forming the first web consisting of the first polyester-based staple fiber and/or first polyamide-based staple fiber; and bonding the fibers of the first web to each other by the non-woven fabric preparing method known in the art.
- the forming method of the first web is not particularly limited as long as it may be known in the art.
- the first web may be formed by physically separating the first polyester-based staple fibers on a conveyor by using an opening machine, and then uniformly or randomly arranging the first polyester-based staple fibers by using a carding machine.
- the fibers of the formed first web may be bonded to each other by thermal, physical or chemical methods, such as binding the fibers to each other by an adhesive or melting the fibers and bonding them to each other.
- a non-woven cleaning fabric layer 10 is formed by forming a cleaning composition on the first non-woven fabric formed in step S 100 (hereinafter, ‘step S 200 ’).
- the cleaning composition is formed on a surface of the first non-woven fabric or inside the first non-woven fabric.
- the cleaning composition may coat the surface of the first non-woven fabric, and/or may fill an inside of the first non-woven fabric, that is, pores of the first non-woven fabric.
- step S 200 includes the steps of coating the cleaning composition on the surface and/or the inside of the first non-woven; and heating the coated cleaning composition to form the non-woven cleaning layer.
- the coating method of the cleaning composition is not particularly limited, and non-limited examples thereof are roll coating, dip coating, spray coating, gravure coating, flexo printing, slot die coating, curtain coating, slide coating, and the like.
- the heating temperature may be 160 to 200° C. and desirably 170 to 190° C. and the heating time may be 3 to 7 minutes, but they are not limited thereto.
- the non-woven cleaning fabric layer may be formed by coating the cleaning composition on the first non-woven fabric by a roll coating method and then drying it in an oven at 180° C. for 3 to 7 minutes.
- step S 300 a second non-woven fabric including a second polyester-based staple fiber, a second polyamide-based staple fiber, or a mixture thereof is formed.
- step S 300 the second non-woven fabric is formed by carrying out the same process as step S 100 as described above.
- the forming method and bonding method of the second web are the same as those of step S 100 as described above.
- the second polyester-based staple fiber when used at the time of forming the second non-woven fabric, the second polyester-based staple fiber may be identical to or different from the first polyester-based staple fiber used in step S 100 .
- the second polyimide-based staple fiber may be identical to or different from the second polyamide-based staple fiber used in step S 100 .
- a functional non-woven fabric layer 20 is formed by forming a functional composition on the second non-woven fabric formed in step S 300 (hereinafter, ‘step S 400 ’).
- the functional composition is formed on a surface of the second non-woven fabric and/or inside the second non-woven fabric.
- the functional composition may be coated on the surface of the second non-woven fabric, and/or may fill the inside of the second non-woven fabric, that is, pores of the second non-woven fabric.
- step S 400 includes the steps of coating the functional composition on the surface and/or the inside of the second non-woven fabric; and heating the coated functional composition to form the functional non-woven fabric.
- the coating method of the functional composition is not particularly limited, and non-limited examples thereof are roll coating, dip coating, spray coating, gravure coating, flexo printing, slot die coating, curtain coating, slide coating, and the like.
- the heating temperature may be 160 to 200° C. and desirably 170 to 190° C. and the heating time may be 3 to 7 minutes, but they are not limited thereto.
- the functional non-woven fabric layer may be formed by coating the functional composition on the second non-woven fabric by a roll coating method and then drying it in an oven at 180° C. for 3 to 7 minutes.
- step S 500 a laminate sheet is formed by laminating the non-woven cleaning fabric layer formed in step S 200 on the functional non-woven fabric layer formed in step S 400 (hereinafter, ‘step S 500 ’).
- the method of laminating the non-woven cleaning fabric layer on the functional non-woven fabric layer is not particularly limited as long as it may be known in the art.
- the methods is bonding the non-woven cleaning fabric layer and the functional non-woven fabric layer by using an adhesive; heating and pressing the non-woven cleaning fabric layer and the functional non-woven fabric layer by allowing the laminated sheet to penetrate between a pair of preheated rollers, and the like.
- step S 600 the laminate sheet is cut into predetermined shape and size.
- the shape of the laminate sheet is not particularly limited, and for example, may be a polygonal shape, a circular shape, or the like.
- both sides of the scrubber have a shape of S, such a scrubber is favorable since it can easily clean even an inside of the toilet.
- the toilet cleaner may include the toilet scrubber 100 and a handle 200 connected to one side of the toilet scrubber 100 .
- the handle 200 can be easily connected to and separated from the toilet scrubber 100 , and thus the toilet scrubber can be continuously replaced.
- a cleaning composition was prepared by mixing 25.3 wt % of sodium dodecylbenzene sulfonate, 16.2 wt % of triethanolamine, 0.13 wt % of AquaLor Blue 283L, and the remainder water. Then, the cleaning composition was coated on the non-woven fabric (polyethylene terephthalate staple fiber (thickness: 50 denier)) to prepare a non-woven cleaning fabric sheet.
- a functional composition was obtained by mixing 5 wt % of polymethylsiloxane, 14 wt % of Ethoxyalted Alchol (Miwon Commercial Company, LAE7), 1 wt % of benzalkonium chloride (Miwon Commercial Company, Miconuim), 0.5 wt % of AquaLor Blue (Wooshinpigment Company), 0.5 wt % of Lemon Citrus Fragrance (Hanbit Flvor & Fragrance, Company). Then, the functional composition was coated on the non-woven fabric (polyethylene terephthalate staple fiber (thickness: 50 denier)) to prepare the functional non-woven fabric sheet.
- non-woven fabric polyethylene terephthalate staple fiber (thickness: 50 denier)
- a toilet scrubber was prepared by laminating the non-woven cleaning sheet prepared in ⁇ step 1> of Example 1 on one surface of the functional non-woven fabric sheet prepared in ⁇ step 2> of Example 1, and then cutting the laminate into predetermined shape and size.
- a toilet scrubber was prepared by the same method as Example 1, except that 5 wt % of 3MTM Protective Material PM-3630 from the 3M Company was used instead of 5 wt % of polymethylsiloxane used in ⁇ step 2> of Example 1.
- a toilet scrubber was prepared by the same method as Example 1, except that 5 wt % of Acusol 845 from the Dow Chemical Company was used instead of 5 wt % of polymethylsiloxane used in ⁇ step 2> of Example 1.
- Scotch-BriteTM Clean Stick also known as Scotch-BriteTM Disposable Toilet Bowl Scrubber from the 3M Company was used for Comparative Example 1.
- the cleaning efficiency of the toilet scrubber according to the present invention was evaluated as follows.
- Waste engine oil, steak sauce, and rice paste were respectively coated on surfaces of tiles (10 cm ⁇ 10 cm), followed by heating at 145 for 1 hour. After that, the toilet scrubbers of Examples 1 to 3 and Comparative Example 1 were fitted with a push-pull tester, which was then allowed to reciprocate on the surfaces of the respective contaminated tiles 20 times. After that, the whiteness and contaminant removal for the respective tiles were measured, and then shown in FIGS. 4 to 6 .
- the anti-contaminating efficiency of the toilet scrubber according to the present invention was evaluated as follows.
- Glass surfaces were respectively cleaned by the toilet scrubbers of Examples 1 to 3 and Comparative Example 1, and then frictional forces of the respective glass surfaces were measured by using a frictional force tester. After that, the glass surfaces respectively cleaned by the toilet scrubbers were coated with steak sauce, and then the frictional force of the steak sauce layer formed on each of the glass surfaces was measured by using the frictional force tester. In addition, the frictional force of the glass surface was measured by using the frictional force tester. In addition, the glass surface not cleaned by the toilet scrubber was coated with the steak sauce, and then the frictional force of the steak sauce layer was measured by the frictional force tester. The contamination rate was calculated by Mathematical Equation 1.
- f 1 is surface frictional force of glass
- f 2 is surface frictional force of steak sauce layer formed on glass surface
- f 3 is surface frictional force of glass cleaned by toilet scrubber
- f 4 is surface frictional force of steak sauce layer formed on glass surface cleaned by toilet scrubber.
- FIG. 7 showed that the lower the value, the more superior the anti-contaminating efficiency.
- the toilet scrubbers of Examples 1 to 3 had lower contamination rates than the toilet scrubber of Comparative Example 1 (D in FIG. 7 ).
- the toilet scrubber of Example 1 had a contamination rate of 75%, which showed superior anti-contaminating efficiency as compared with the Comparative Example 1 having a contamination rate of approximately 89%.
- the toilet scrubber according to the present invention had superior anti-contaminating efficiency as compared with the toilet scrubber of the prior art.
- the germicidal efficiency of the toilet scrubber according to the present invention was evaluated as follows.
- Staphylococcus ATCC 6538 was inoculated on tile surfaces respectively cleaned by the toilet scrubbers of Examples 1 to 3, and then the staphylococcus count at the initial stage of inoculation was measured. After 5 minutes, the staphylococci on the respective tile surfaces were counted.
- a tile cleaned by the toilet scrubber of Comparative Example 1 was used for a comparative sample. The count results were shown in Table 1 and FIG. 8 below.
- Escherichia Coli ATCC 25922 was inoculated on tile surfaces respectively cleaned by the toilet scrubbers of Examples 1 to 3, and then the E. coli count at the initial stage of inoculation was measured. After 5 minutes, E. coli on the respective tile surfaces were counted. Here, a tile cleaned by the toilet scrubber of Comparative Example 1 was used for a comparative sample. The count results were shown in Table 2 and FIG. 9 below.
- the toilet scrubber of the present invention can provide superior anti-biotic, anti-contaminating, and deodorizing effects as well as a superior cleaning effect on the toilet surface, by including the non-woven cleaning fabric layer including the cleaning composition and the functional non-woven fabric layer including the functional composition.
Landscapes
- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
- Cosmetics (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020130081179A KR102049613B1 (ko) | 2013-07-10 | 2013-07-10 | 변기용 수세미 및 이를 포함하는 변기용 청소도구 |
KR10-2013-0081179 | 2013-07-10 | ||
PCT/US2014/045005 WO2015006090A1 (en) | 2013-07-10 | 2014-07-01 | Toilet scrubber and toilet cleaner |
Publications (1)
Publication Number | Publication Date |
---|---|
US20160106274A1 true US20160106274A1 (en) | 2016-04-21 |
Family
ID=52280463
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US14/786,401 Abandoned US20160106274A1 (en) | 2013-07-10 | 2014-07-01 | Toilet scrubber and toilet cleaner |
Country Status (5)
Country | Link |
---|---|
US (1) | US20160106274A1 (ko) |
EP (1) | EP3019064A4 (ko) |
KR (1) | KR102049613B1 (ko) |
CN (1) | CN105358033A (ko) |
WO (1) | WO2015006090A1 (ko) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016209899A1 (en) | 2015-06-23 | 2016-12-29 | 3M Innovative Properties Company | Disposable toilet bowl scrub system |
USD850742S1 (en) * | 2016-03-14 | 2019-06-04 | Scrub Daddy, Inc. | Scrubbing sponge handle |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20180007481A (ko) * | 2016-07-13 | 2018-01-23 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 웹의 탈착이 용이한 청소 도구 |
DE202016105523U1 (de) * | 2016-08-19 | 2016-10-26 | Nina Franz | Reinigungsgerät sowie Set aus dem Reinigungsgerät und einem Gerätehalter für das Reinigungsgerät |
CN110801173A (zh) * | 2019-10-30 | 2020-02-18 | 南宁学院 | 一种蹲便器下水口的清洗装置 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7629043B2 (en) * | 2003-12-22 | 2009-12-08 | Kimberly-Clark Worldwide, Inc. | Multi purpose cleaning product including a foam and a web |
US20050155628A1 (en) * | 2004-01-16 | 2005-07-21 | Andrew Kilkenny | Cleaning composition for disposable cleaning head |
US20050266229A1 (en) * | 2004-05-26 | 2005-12-01 | Richard Porticos | Nonwoven with attached foam particles |
CN2717379Y (zh) * | 2004-07-22 | 2005-08-17 | 花仙子企业股份有限公司 | 多层复合洁净拭布 |
JP4845525B2 (ja) * | 2006-02-08 | 2011-12-28 | ユニ・チャーム株式会社 | 清掃体及び清掃用具 |
US20080098551A1 (en) * | 2006-10-31 | 2008-05-01 | Ya-Ching Yang | Cleaning brush cap |
TW200819086A (en) * | 2006-10-31 | 2008-05-01 | Ya-Jing Yang | Cleaning brush cover |
US20090038092A1 (en) * | 2007-08-06 | 2009-02-12 | Kennedy Brook S | Hand held sponge implement |
US20100056413A1 (en) * | 2008-09-04 | 2010-03-04 | Harry Jr David Ray | high-temperature cleaning system, associated substrates, and associated methods |
-
2013
- 2013-07-10 KR KR1020130081179A patent/KR102049613B1/ko active IP Right Grant
-
2014
- 2014-07-01 WO PCT/US2014/045005 patent/WO2015006090A1/en active Application Filing
- 2014-07-01 CN CN201480038944.6A patent/CN105358033A/zh active Pending
- 2014-07-01 US US14/786,401 patent/US20160106274A1/en not_active Abandoned
- 2014-07-01 EP EP14822185.6A patent/EP3019064A4/en not_active Withdrawn
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016209899A1 (en) | 2015-06-23 | 2016-12-29 | 3M Innovative Properties Company | Disposable toilet bowl scrub system |
USD850742S1 (en) * | 2016-03-14 | 2019-06-04 | Scrub Daddy, Inc. | Scrubbing sponge handle |
Also Published As
Publication number | Publication date |
---|---|
KR102049613B1 (ko) | 2019-11-28 |
EP3019064A4 (en) | 2017-03-22 |
EP3019064A1 (en) | 2016-05-18 |
KR20150007141A (ko) | 2015-01-20 |
WO2015006090A1 (en) | 2015-01-15 |
CN105358033A (zh) | 2016-02-24 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US20160106274A1 (en) | Toilet scrubber and toilet cleaner | |
AU2013286998C1 (en) | Low-VOC cleaning substrates and compositions | |
CN101535464B (zh) | 预湿润的一次性清洁基质 | |
CA2470157C (en) | Antimicrobial pre-moistened wipers | |
EP1968529B1 (en) | Wiper for use with disinfectants | |
AU2016369276B2 (en) | Food contact surface sanitizing liquid | |
EP1676519B1 (en) | Cleaning tool | |
US20060051434A1 (en) | Cleaning tool | |
BR0208952A (pt) | Composição para limpeza de pele incorporando partìculas aniÈnicas | |
MXPA03011530A (es) | Toallitas limpiadoras humedas impresas. | |
CN116033827A (zh) | 酸性清洁和杀菌组合物 | |
US20140242195A1 (en) | Automotive surface conditioning system | |
WO2008119636A1 (de) | Textiles flächengebilde mit reinigungsvermögen | |
US7635415B2 (en) | Regenerable cleaning implement for sanitizing a surface | |
MX2013010413A (es) | Sustratos de limpieza que contienen peroxigeno con estabilidad de almacenamiento mejorada. | |
CA3045269C (en) | Method for cleaning surfaces in interior spaces and in technical equipments with benign bacteria | |
JP5822257B2 (ja) | 清掃用シート | |
TR2021020958A2 (tr) | Anti̇stati̇k yüzey temi̇zleme kompozi̇syonu ve kompozi̇syonu i̇hti̇va eden bi̇r yüzey temi̇zleme ürünü | |
JP5822256B2 (ja) | 清掃用シート | |
Menetrez | ANTIMICROBIAL TREATMENTS OF MOLD AND BACTERIA. | |
Menetrez | ANTIMICROBIAL TREATMENTS OF INDOOR MOLD AND BACTERIA. | |
WO2006028273A1 (en) | Cleaning implement | |
WO2003066794A1 (fr) | Composition detergente et lingette nettoyante | |
WO2006028280A1 (en) | Cleaning implement |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: 3M INNOVATIVE PROPERTIES COMPANY, MINNESOTA Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:EUN, SANG-WON;REEL/FRAME:036859/0353 Effective date: 20151013 |
|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |