US20150133296A1 - Phytosanitary composition comprising essential oils that potentiate antifungal activity - Google Patents

Phytosanitary composition comprising essential oils that potentiate antifungal activity Download PDF

Info

Publication number
US20150133296A1
US20150133296A1 US13/982,181 US201213982181A US2015133296A1 US 20150133296 A1 US20150133296 A1 US 20150133296A1 US 201213982181 A US201213982181 A US 201213982181A US 2015133296 A1 US2015133296 A1 US 2015133296A1
Authority
US
United States
Prior art keywords
oil
composition according
phytosanitary composition
mixtures
phytosanitary
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US13/982,181
Other languages
English (en)
Inventor
Unai Ona Ugalde Martinez
Ana Belen Rodriguez Urra
Ainara UBEGUN LIZASO
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Biofungitek SL
Original Assignee
Biofungitek SL
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Biofungitek SL filed Critical Biofungitek SL
Assigned to BIOFUNGITEK, SOCIEDAD LIMITADA reassignment BIOFUNGITEK, SOCIEDAD LIMITADA ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: RODRIGUEZ URRA, ANA BELEN, UBEGUN LIZASO, AINARA, UGALDE MARTINEZ, UNAI ONA
Assigned to BIOFUNGITEK, SOCIEDAD LIMITADA reassignment BIOFUNGITEK, SOCIEDAD LIMITADA CHANGE OF ADDRESS Assignors: RODRIGUEZ URRA, ANA BELEN, UBEGUN LIZASO, AINARA, UGALDE MARTINEZ, UNAI ONA
Publication of US20150133296A1 publication Critical patent/US20150133296A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/04—Carbon disulfide; Carbon monoxide; Carbon dioxide
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16—Heavy metals; Compounds thereof
    • A01N59/20—Copper
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08—Magnoliopsida [dicotyledons]
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08—Magnoliopsida [dicotyledons]
    • A01N65/22—Lamiaceae or Labiatae [Mint family], e.g. thyme, rosemary, skullcap, selfheal, lavender, perilla, pennyroyal, peppermint or spearmint
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08—Magnoliopsida [dicotyledons]
    • A01N65/24—Lauraceae [Laurel family], e.g. laurel, avocado, sassafras, cinnamon or camphor
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08—Magnoliopsida [dicotyledons]
    • A01N65/26—Meliaceae [Chinaberry or Mahogany family], e.g. mahogany, langsat or neem
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08—Magnoliopsida [dicotyledons]
    • A01N65/28—Myrtaceae [Myrtle family], e.g. teatree or clove
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/08—Magnoliopsida [dicotyledons]
    • A01N65/36—Rutaceae [Rue family], e.g. lime, orange, lemon, corktree or pricklyash
    • C05G3/02—
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants

Definitions

  • This invention relates to phytosanitary compositions having fungicidal properties comprising a mixture of essential oils obtained from plants and agents having known fungicidal properties such as alkali metal or ammonium bicarbonates, or compounds based on copper or copper salts, for use mainly in contact protection against fungicidal infections in cultivated plants and post-harvesting, and in other antifungal applications.
  • agents having known fungicidal properties such as alkali metal or ammonium bicarbonates, or compounds based on copper or copper salts
  • the effect of the agents having known fungicidal properties is synergistically potentiated by the essential oils mentioned.
  • This invention also relates to use of these essential oils as potentiators for agents having known fungicidal properties.
  • Essential oils are complex mixtures of natural molecules which are fundamentally obtained from plants. They are secondary metabolites which can normally be obtained by extraction with organic solvents and subsequent concentration, or by physical treatments with steam followed by separation of the water-insoluble phase. Generally they are volatile liquids soluble in organic solvents and have a density lower than that of water.
  • jojoba oil Simmondsia californica
  • rosemary oil Rosemarinus officianalis
  • thyme oil T. vulgaris
  • clarified hydrophobic extract of neem oil A. indica
  • cottonseed oil Gossypium hirsutum
  • garlic extract Dayan, F. E. et al. “Natural products in crop protection”. Bioorg. and Med. Chem. 17 (2009), 4022-4034).
  • the chemical composition of essential oils differs not only in the quantity but also in the quality and the stereochemical type of the molecules in the extracted substances.
  • the extraction product may vary according to climate, the composition of the soil, the organ of the plant used for extraction, and the age and stage of growth of the plant. It also depends on the extraction process used.
  • inorganic salts such as the bicarbonates of alkali metals, mainly lithium, sodium or potassium, and ammonium bicarbonate as fungicidal agents is also known from the prior art (U.S. Pat. No. 5,346,704).
  • the use of these inorganic salts, in particular those containing the bicarbonate anion, does not give rise to any risks to human health or to the environment.
  • one object of this invention is to provide a phytosanitary composition having antifungal properties comprising: 1) one or more essential oils obtained from plants and 2) one or more agents having known fungicidal properties.
  • This composition synergistically improves the antifungal properties of the agents having known antifungal activity, has a minimum of secondary toxic effects and is harmless to human beings and the environment.
  • composition according to this invention may be applied in agriculture to protect crops from the stage of germination to harvesting, and during the storage and transport of these crops, seeds, flowers or grains.
  • another possible application is in the elimination of fungi which attack painted surfaces and to protect carpets and fabrics in the home and in any other application against fungal attack through contact.
  • thyme oil Thymus vulgaris
  • oregano oil Origanum vulgaris
  • clove oil Syzygium aromaticum
  • nutmeg oil Myristica fragrans
  • cinnamon oil Cinnamomum zeylanicum
  • laurel oil Laurus nobilis
  • orange oil Citrus ⁇ sinensis
  • mint oil Mentha ⁇ piperita
  • valerian oil Valeriana officinalis
  • citronella oil Cymbopogon nardos
  • lavender oil Lavanda angustifolia
  • jojoba oil Simmondsia californica
  • rosemary oil Rosemarinus officianalis
  • neem oil Azadirachta indica
  • cottonseed oil Gossypium hirsutum
  • Gossypium hirsutum or mixtures thereof.
  • the phytosanitary composition may comprise a mixture of active compounds isolated from the essential oils according to this invention, such as phenolic monoterpenoids such as carvacrol and thymol, allylbenzenes such as eugenol, monosubstituted phenols such as trans-cinamaldehyde, cyclic monoterpenes such as limonene, bicyclic monoterpenes such as camphene and linear terpenes such as nerol, any of their families and mixtures thereof, and agents having known fungicidal properties.
  • active compounds isolated from the essential oils according to this invention such as phenolic monoterpenoids such as carvacrol and thymol, allylbenzenes such as eugenol, monosubstituted phenols such as trans-cinamaldehyde, cyclic monoterpenes such as limonene, bicyclic monoterpenes such as camphene and linear terpenes such as nerol, any
  • agents having known fungicidal properties which may be used in the composition according to the invention there are the carbonates or bicarbonates of alkali metals, preferably of lithium, sodium or potassium, ammonium carbonate or bicarbonate and fungicidal agents based on copper or its salts or mixtures thereof. More preferably the agent having known fungicidal properties is potassium bicarbonate.
  • the quantity of essential oils present in the composition according to this invention lies within the range from 0.01% to 99.99% by weight of the total composition. Also the quantity of the agent having known fungicidal properties in the composition according to this invention may vary between 99.99% and 0.01% by weight of the total composition.
  • composition according to this invention may be prepared by mixing the essential oil or oils and the agent having fungicidal properties through any method of mixing known in the art.
  • essential oils are liquid at ambient temperature, as a result of which the composition will generally be in the form of a liquid.
  • the composition may also be in liquid or solid form, such as a suspension, dispersion, emulsion, spray, microencapsulate or any other type of mixture which remains stable over time or may be incorporated in polymers, waxes or any other similar supports.
  • phytosanitary composition according to this invention may be used as such, or may be used to formulate a phytosanitary product together with different additives used in the art which offer different properties, such as surfactants, polymers, alkanising agents, pH-control agents, among many other additives used in the formulation of products used in the agricultural industry.
  • the phytosanitary composition according to this invention falls within the group of contact phytosanitary agents, that is the form of the protection against fungal diseases is through contact, given that the composition remains on the surface of different parts of the plant, protecting it externally against the external attack of fungi.
  • the phytosanitary composition according to this invention can be applied by any method of application known in the art, such as spraying.
  • the fungicidal composition according to this invention may further comprise a fertiliser, which may be selected from the group comprising compounds containing nitrogen and/or phosphorus such as urea, melamine, hexamine, dicyanodiamide, ameline, cyanuric acid, melamine nitrate, triethyl phosphite and the like or mixtures thereof.
  • a fertiliser which may be selected from the group comprising compounds containing nitrogen and/or phosphorus such as urea, melamine, hexamine, dicyanodiamide, ameline, cyanuric acid, melamine nitrate, triethyl phosphite and the like or mixtures thereof.
  • composition according to this invention may also comprise any compound or product having chemical and/or biological activity used in agriculture, such as herbicides, insecticides, plant growth regulators and the like, or mixtures thereof.
  • the fungus Botrytis cinerea was cultured in PDB (potato dextrose broth) medium with different concentrations of KHCO 3 and the % inhibition representing the extent to which growth was impeded in comparison with a control which did not have the compound under test, in this case KHCO 3 , was determined.
  • the % inhibition was calculated in the following way:
  • OD control is the optical density of the control culture (without test compound) and OD x is the optical density of the culture with the test substance.
  • the optical density of the liquid culture was measured 24 hours after the start of culturing.
  • the fungus B. cinerea was cultured in a similar way to Example 1 with the difference that different concentrations of carvacrol, the compound isolated from the essential oil of oregano, were used in the medium. The 24 hour optical density of the culture was measured and the results are shown in Table II.
  • the fungus B. cinerea was cultured in a similar way to Example 1 with the difference that different concentrations of carvacrol were used in the medium and that a constant concentration of KHCO 3 (30 mM) was used for all the cultures.
  • the optical density of the culture was measured at 24 hour and the results are shown in Table III.
  • Alternaria alternate was cultured in a similar way to Example 1 with the difference that different concentrations of copper oxychloride, a copper-based fungicide extensively used in agriculture, were used in the medium. The 24 hour optical density of the culture was measured and the results are shown in Table IV.
  • Alternaria alternate was cultured in a similar way to Example 2.
  • the 24 hour optical density of the culture was measured and the results are shown in Table V.
  • the fungus A. alternata was cultured in a similar way to Example 4 with the difference that different concentrations of carvacrol were used in the medium and that a constant concentration of copper oxychloride (5 ppm) was used throughout. The 24 hour optical density of the culture was measured and the results are shown in Table VI.
  • a carvacrol concentration of 35 ppm and 5 ppm of copper oxychloride inhibit the growth of A. alternata by more than 50%, while carvacrol alone in that concentration provides 27% inhibition and copper oxychloride only 10%.
  • the fungus Penicillium digitatum was cultured in a similar way to Example 1. The 24 hour optical density of the culture was measured and the results are shown in Table VII.
  • the fungus P. digitatum was cultured in a similar way to Example 1 with the difference that different concentrations of thymol, a compound isolated from thyme oil, were used in the medium.
  • the 24 hour optical density of the culture was measured and the results are shown in Table VIII.
  • the fungus P. digitatum was cultured in a similar way to Example 7 with the difference that different concentrations of thymol were used in the medium and that a constant concentration of KHCO 3 (30 mM) was used throughout. The 24 hour optical density of the culture was measured and the results are shown in Table IX.
US13/982,181 2011-03-18 2012-01-05 Phytosanitary composition comprising essential oils that potentiate antifungal activity Abandoned US20150133296A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ESP201130390 2011-03-18
ES201130390A ES2361432B9 (es) 2011-03-18 2011-03-18 Composición fitosanitaria que comprende aceites esenciales potenciadores de la actividad antifúngica.
PCT/ES2012/070005 WO2012127082A1 (es) 2011-03-18 2012-01-05 Composicioón fitosanitaria que comprende aceites esenciales potenciadores de la actividad antifúngica

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
PCT/ES2012/070005 A-371-Of-International WO2012127082A1 (es) 2011-03-18 2012-01-05 Composicioón fitosanitaria que comprende aceites esenciales potenciadores de la actividad antifúngica

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US15/890,484 Division US10863749B2 (en) 2011-03-18 2018-02-07 Phytosanitary composition comprising essential oils that potentiate antifungal activity

Publications (1)

Publication Number Publication Date
US20150133296A1 true US20150133296A1 (en) 2015-05-14

Family

ID=44072798

Family Applications (3)

Application Number Title Priority Date Filing Date
US13/982,181 Abandoned US20150133296A1 (en) 2011-03-18 2012-01-05 Phytosanitary composition comprising essential oils that potentiate antifungal activity
US15/890,484 Active 2032-11-06 US10863749B2 (en) 2011-03-18 2018-02-07 Phytosanitary composition comprising essential oils that potentiate antifungal activity
US16/231,734 Active US10813360B2 (en) 2011-03-18 2018-12-24 Phytosanitary composition comprising essential oils that potentiate antifungal activity

Family Applications After (2)

Application Number Title Priority Date Filing Date
US15/890,484 Active 2032-11-06 US10863749B2 (en) 2011-03-18 2018-02-07 Phytosanitary composition comprising essential oils that potentiate antifungal activity
US16/231,734 Active US10813360B2 (en) 2011-03-18 2018-12-24 Phytosanitary composition comprising essential oils that potentiate antifungal activity

Country Status (14)

Country Link
US (3) US20150133296A1 (zh)
EP (4) EP4014739A1 (zh)
CN (2) CN107079926A (zh)
BR (1) BR112013022159B1 (zh)
CL (1) CL2013002170A1 (zh)
ES (2) ES2361432B9 (zh)
MA (1) MA35012B1 (zh)
MX (1) MX365322B (zh)
PE (1) PE20140805A1 (zh)
PL (1) PL2687095T3 (zh)
PT (1) PT2687095T (zh)
TN (1) TN2013000302A1 (zh)
WO (1) WO2012127082A1 (zh)
ZA (1) ZA201305518B (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11358905B2 (en) * 2019-01-25 2022-06-14 Amvac Chemical Corporation Microfibrillated cellulose as rheology modifier in high ionic strength agricultural formulations
US11771095B2 (en) 2020-03-13 2023-10-03 Harpe Bioherbicide Solutions Inc. Herbicidal Mentha pantsd, extract compositions and methods of using same000000000000000,001

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10820597B2 (en) 2011-03-18 2020-11-03 Biofungitek, S.L. Phytosanitary composition comprising essential oils that potentiate antifungal activity
ES2361432B9 (es) 2011-03-18 2012-04-24 Biofungitek, Sociedad Limitada Composición fitosanitaria que comprende aceites esenciales potenciadores de la actividad antifúngica.
CA2855000A1 (en) * 2011-11-09 2013-05-16 Stockton (Israel) Ltd. Combinations of antifungal compounds and tea tree oil
WO2013068958A1 (en) * 2011-11-09 2013-05-16 Biomor Israel Ltd. Combinations of antifungal compounds and tea tree oil for the treatment of oomycetes plant infection
ES2439616B2 (es) * 2012-07-20 2014-12-19 Decco Worldwide Post-Harvest Holding Co. B.V. Formulacion de recubrimiento que comprende cinamaldehído y aditivos alimentarios fungiestáticos
EP3318127A1 (en) * 2013-09-30 2018-05-09 Basf Se Compositions comprising khco3
CN103960092B (zh) * 2014-05-06 2015-09-16 云南省烟草公司玉溪市公司 一种烟草种植病虫害立体生物防治方法
CN104255801B (zh) * 2014-08-29 2016-06-29 浙江大洋生物科技集团股份有限公司 具有杀菌作用的作物补钾组合物及其制备方法和用途
CN104336108A (zh) * 2014-10-29 2015-02-11 苏州科大微龙信息技术有限公司 一种香茅醇铜菜豆锈病防治合剂
US20180117082A1 (en) * 2015-03-25 2018-05-03 The University Of Nottingham Antifungal composition/treatment
EP3192370B1 (en) * 2016-01-15 2020-03-04 Rendapart Environmentally friendly herbicidal formulations
CN106489514A (zh) * 2016-12-19 2017-03-15 重庆信首科技有限公司 一种大棚蔬菜的防虫种植方法
US10537519B2 (en) * 2017-08-16 2020-01-21 Sci-Chem International Pty Ltd Compositions for treating infections
CN108935456A (zh) * 2018-07-06 2018-12-07 青岛日晟源作物营养有限公司 一种农药增效剂及其在除草组合物、杀虫组合物和杀菌组合物中的应用
CN109430265B (zh) * 2018-11-23 2021-03-26 中国科学院兰州化学物理研究所 利用凹凸棒石稳定水包油乳液制备香芹酚微胶囊抗菌剂的方法
US20200338016A1 (en) * 2019-04-26 2020-10-29 Mark Edward Fenzl Combination broad-spectrum antibiotic preparations for drug-resistant pathogens
CN110506760A (zh) * 2019-08-14 2019-11-29 山东劲脉植物细胞信息技术有限公司 一种植物用生物组合物、制剂及其施用方法
EP4017263A4 (en) * 2019-08-22 2023-08-16 Botanohealth Ltd MUCILAGE-BASED PLANT PROTECTION PRODUCT AND METHOD THEREOF
IT202100021707A1 (it) * 2021-08-10 2023-02-10 Sipcam Oxon S P A Associazioni fitosanitarie comprendenti carvacrolo, composizioni e loro uso.

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4617419A (en) * 1985-09-26 1986-10-14 International Flavors & Fragrances Inc. Process for preparing natural benzaldehyde and acetaldehyde, natural benzaldehyde and acetaldehyde compositions, products produced thereby and organoleptic utilities therefor
US7053071B2 (en) * 2001-11-30 2006-05-30 The Burnham Institute Induction of apoptosis in cancer cells
US20100099777A1 (en) * 2008-10-17 2010-04-22 Devisetty Bala N Cinnamaldehyde - Allicin Compositions and Their Method of Use

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2677222B1 (fr) * 1991-06-04 1997-06-27 Derives Resiniques Terpenique Composition fongicide a base de tallate de cuivre associe a des derives terpeniques et sa fabrication.
US5338551A (en) * 1992-07-02 1994-08-16 Lajoie M Stephen Polyfunctional agrochemical bicarbonate-containing compositions
FR2758436B1 (fr) * 1997-01-20 2000-04-07 Action Pin Composition adjuvante a usage phytosanitaire
US5958462A (en) * 1997-05-23 1999-09-28 Mclean; Linsey Therapeutic bath salts and method of use
FR2784860B1 (fr) * 1998-10-26 2000-12-29 Action Pin Composition liquide a activite fongicide, bactericide ou bacteriostatique et procedes de preparation et de mise en oeuvre
JP2001316204A (ja) 2000-04-28 2001-11-13 Kao Corp 植物活力剤
JP4342761B2 (ja) * 2001-04-17 2009-10-14 花王株式会社 殺菌剤組成物
FR2828064B1 (fr) * 2001-08-01 2004-05-21 Action Pin Utilisation de derives terpeniques comme agent anti-rebond augmentant la retention
GB2408933A (en) * 2003-12-12 2005-06-15 Reckitt Benckiser Healthcare Antimicrobial composition
FR2867948B1 (fr) * 2004-03-29 2008-02-22 Hightech Bio Activities Holdin Composition decontaminante presentant a la fois des proprietes bactericides, fongicides et virucides, procedes d'obtention et utilisations d'une telle composition
US20060008486A1 (en) * 2004-07-06 2006-01-12 Lewis Susan E Multifunctional compositions having combined insecticidal, mitacidal and fungicidal activity
US20060165746A1 (en) * 2005-01-24 2006-07-27 Arie Markus Formulations containing microencapsulated essential oils
GB0602426D0 (en) 2006-02-07 2006-03-22 Trouw Internat Bv Feed for fish
FR2917947B1 (fr) * 2007-06-29 2009-10-09 Action Pin Sa Composition phytosanitaire pour le traitement preventif et curatif du mildiou
ES2328322A1 (es) * 2007-10-08 2009-11-11 Timac Agro España, S.A. Composiciones de origen natural para tratar fisiopatias y enfermedades producidas por agentes patogenos de frutas y hortalizas, despues de su cosecha, y metodo para su aplicacion.
NO20100451A1 (no) 2010-03-26 2011-09-27 Ewos Innovation As Forbindelse og sammensetning for kontroll av fiskeparasitter
ES2357389B1 (es) 2011-03-11 2011-09-26 Biofungitek, Sociedad Limitada Composición fungicida y bactericida que comprende compuestos orgánicos volátiles de origen natural.
ES2361432B9 (es) 2011-03-18 2012-04-24 Biofungitek, Sociedad Limitada Composición fitosanitaria que comprende aceites esenciales potenciadores de la actividad antifúngica.

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4617419A (en) * 1985-09-26 1986-10-14 International Flavors & Fragrances Inc. Process for preparing natural benzaldehyde and acetaldehyde, natural benzaldehyde and acetaldehyde compositions, products produced thereby and organoleptic utilities therefor
US7053071B2 (en) * 2001-11-30 2006-05-30 The Burnham Institute Induction of apoptosis in cancer cells
US20100099777A1 (en) * 2008-10-17 2010-04-22 Devisetty Bala N Cinnamaldehyde - Allicin Compositions and Their Method of Use

Non-Patent Citations (7)

* Cited by examiner, † Cited by third party
Title
Abdelgaleil (Bioresource Technology (2008), vol. 99, pp. 5947-5950). *
“Chemistry Explained” (http://www.chemistryexplained.com/elements/P-T/Sodium.html) - accessed 12/2/2016 *
El-Baroty (African Journal of Biochemistry Research (2010), vol. 4, no. 6, pp. 167-174). *
Evonik Industries AG (GPS Safety Summary for K2CO3; March 2014; version 002) *
Kong (Journal of Nematology (2007), vol. 39, no. 1, pp. 31-36). *
Ozcan (International Journal of Food Sciences and Nutrition (2008), vol. 59, no. 7-8, pp. 691-698) *
Singh (Food and Chemical Toxicology (2007), vol. 45, pp. 1650-1661) *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11358905B2 (en) * 2019-01-25 2022-06-14 Amvac Chemical Corporation Microfibrillated cellulose as rheology modifier in high ionic strength agricultural formulations
US11771095B2 (en) 2020-03-13 2023-10-03 Harpe Bioherbicide Solutions Inc. Herbicidal Mentha pantsd, extract compositions and methods of using same000000000000000,001

Also Published As

Publication number Publication date
TN2013000302A1 (en) 2015-01-20
PE20140805A1 (es) 2014-07-10
PL2687095T3 (pl) 2018-07-31
EP2687095B1 (en) 2018-02-21
US10813360B2 (en) 2020-10-27
ZA201305518B (en) 2016-01-27
US10863749B2 (en) 2020-12-15
EP4014740A1 (en) 2022-06-22
PT2687095T (pt) 2018-04-20
BR112013022159B1 (pt) 2022-03-03
US20180168169A1 (en) 2018-06-21
EP4014739A1 (en) 2022-06-22
ES2361432B9 (es) 2012-04-24
ES2361432A1 (es) 2011-06-17
EP3351108A1 (en) 2018-07-25
WO2012127082A1 (es) 2012-09-27
EP2687095A4 (en) 2014-09-03
MX2013008517A (es) 2013-08-12
CN107079926A (zh) 2017-08-22
ES2361432B1 (es) 2011-11-24
US20190133139A1 (en) 2019-05-09
MX365322B (es) 2019-05-29
CN103429088B (zh) 2017-02-22
EP2687095A1 (en) 2014-01-22
CL2013002170A1 (es) 2014-06-13
MA35012B1 (fr) 2014-04-03
BR112013022159A2 (pt) 2020-07-21
ES2665948T3 (es) 2018-04-30
CN103429088A (zh) 2013-12-04

Similar Documents

Publication Publication Date Title
US10813360B2 (en) Phytosanitary composition comprising essential oils that potentiate antifungal activity
US20220322681A1 (en) Antimicrobial nano-emulsion
US20240057594A1 (en) Solutions for enhancing the effectiveness of insecticides and fungicides on living plants and related methods
US20120294959A1 (en) Botanical pesticide for agriculture/horticulture crops
CA3060884C (en) Phytosanitary composition comprising essential oils that potentiate antifungal activity
US10820597B2 (en) Phytosanitary composition comprising essential oils that potentiate antifungal activity
Gettys et al. Evaluating the effects of acetic acid and d-limonene on four aquatic plants
US20220000104A1 (en) Solutions for enhancing the effectiveness of insecticides and fungicides on living plants and related methods
CN102715182A (zh) 一种含有活性组分百可得和抑霉唑的杀菌组合物
Sagliker Carbon mineralisation in orange grove soils treated with different doses of glyphosate-amine salt
ES2387488B1 (es) Composición protectora contra enfermedades de plantas y frutos que comprende sales de carbonato y agentes aceptadores de pares de electrones
Deka et al. Bioactivity of an organic synergist in enhancing the efficacy of Neem Kernel Aqueous extracts (NKAE) and three recommended acaricides in controlling tea red spider mite (Oligonychus coffeae)
WO2022020972A1 (es) Formulación repelente de insectos para la industria forestal
Hester et al. IR-4 Ornamental Horticulture Program Liverwort Efficacy Study
CN103583552A (zh) 一种用于防治稻飞虱的组合物
Namdeo et al. Influence of gibberellic acid (GA3) on growth, physiological and yield parameters in Ajwain (Trachyspermum ammi L.)

Legal Events

Date Code Title Description
AS Assignment

Owner name: BIOFUNGITEK, SOCIEDAD LIMITADA, SPAIN

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:UGALDE MARTINEZ, UNAI ONA;RODRIGUEZ URRA, ANA BELEN;UBEGUN LIZASO, AINARA;REEL/FRAME:030895/0437

Effective date: 20130716

AS Assignment

Owner name: BIOFUNGITEK, SOCIEDAD LIMITADA, SPAIN

Free format text: CHANGE OF ADDRESS;ASSIGNORS:UGALDE MARTINEZ, UNAI ONA;RODRIGUEZ URRA, ANA BELEN;UBEGUN LIZASO, AINARA;REEL/FRAME:034795/0982

Effective date: 20130716

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION