US20120088093A1 - Method for coating a sliding element and sliding element, in particular a piston ring - Google Patents

Method for coating a sliding element and sliding element, in particular a piston ring Download PDF

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Publication number
US20120088093A1
US20120088093A1 US13/257,396 US200913257396A US2012088093A1 US 20120088093 A1 US20120088093 A1 US 20120088093A1 US 200913257396 A US200913257396 A US 200913257396A US 2012088093 A1 US2012088093 A1 US 2012088093A1
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US
United States
Prior art keywords
coating
sliding element
nanoparticles
size
piston ring
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US13/257,396
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English (en)
Inventor
Marcus Kennedy
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Federal Mogul Burscheid GmbH
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Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
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Application filed by Individual filed Critical Individual
Assigned to FEDERAL-MOGUL BURSCHEID GMBH reassignment FEDERAL-MOGUL BURSCHEID GMBH ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: KENNEDY, MARCUS
Publication of US20120088093A1 publication Critical patent/US20120088093A1/en
Assigned to WILMINGTON TRUST, NATIONAL ASSOCIATION, AS COLLATERAL TRUSTEE reassignment WILMINGTON TRUST, NATIONAL ASSOCIATION, AS COLLATERAL TRUSTEE CONFIRMATORY GRANT OF SECURITY INTERESTS IN UNITED STATES PATENTS Assignors: BECK ARNLEY HOLDINGS LLC, CARTER AUTOMOTIVE COMPANY LLC, CLEVITE INDUSTRIES INC., FEDERAL-MOGUL CHASSIS LLC, FEDERAL-MOGUL FILTRATION LLC, FEDERAL-MOGUL FINANCING CORPORATION, FEDERAL-MOGUL IGNITION LLC, FEDERAL-MOGUL MOTORPARTS LLC, FEDERAL-MOGUL PISTON RINGS, LLC, FEDERAL-MOGUL POWERTRAIN IP LLC, FEDERAL-MOGUL POWERTRAIN LLC, FEDERAL-MOGUL PRODUCTS US LLC, FEDERAL-MOGUL SEVIERVILLE, LLC, FEDERAL-MOGUL VALVETRAIN INTERNATIONAL LLC, FEDERAL-MOGUL WORLD WIDE LLC, FELT PRODUCTS MFG. CO. LLC, F-M MOTORPARTS TSC LLC, F-M TSC REAL ESTATE HOLDINGS LLC, MUZZY-LYON AUTO PARTS LLC, TENNECO AUTOMOTIVE OPERATING COMPANY INC., TENNECO GLOBAL HOLDINGS INC., TENNECO INC., TENNECO INTERNATIONAL HOLDING CORP., THE PULLMAN COMPANY, TMC TEXAS INC.
Assigned to FEDERAL-MOGUL MOTORPARTS LLC, TENNECO INTERNATIONAL HOLDING CORP., FEDERAL-MOGUL FILTRATION LLC, TENNECO INC., MUZZY-LYON AUTO PARTS LLC, TENNECO GLOBAL HOLDINGS INC., BECK ARNLEY HOLDINGS LLC, CLEVITE INDUSTRIES INC., TMC TEXAS INC., FEDERAL-MOGUL PRODUCTS US LLC, F-M MOTORPARTS TSC LLC, F-M TSC REAL ESTATE HOLDINGS LLC, FEDERAL-MOGUL PISTON RINGS, LLC, FEDERAL-MOGUL POWERTRAIN LLC, FEDERAL-MOGUL FINANCING CORPORATION, FEDERAL-MOGUL VALVE TRAIN INTERNATIONAL LLC, FEDERAL-MOGUL IGNITION LLC, CARTER AUTOMOTIVE COMPANY LLC, FEDERAL-MOGUL CHASSIS LLC, FEDERAL-MOGUL POWERTRAIN IP LLC, FEDERAL-MOGUL SEVIERVILLE, LLC, FEDERAL-MOGUL WORLD WIDE LLC, FELT PRODUCTS MFG. CO. LLC, THE PULLMAN COMPANY, TENNECO AUTOMOTIVE OPERATING COMPANY INC. reassignment FEDERAL-MOGUL MOTORPARTS LLC RELEASE BY SECURED PARTY (SEE DOCUMENT FOR DETAILS). Assignors: WILMINGTON TRUST, NATIONAL ASSOCIATION
Abandoned legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
    • C23C30/005—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/301—AIII BV compounds, where A is Al, Ga, In or Tl and B is N, P, As, Sb or Bi
    • C23C16/303—Nitrides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/308—Oxynitrides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
    • C23C16/22—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of inorganic material, other than metallic material
    • C23C16/30—Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
    • C23C16/34—Nitrides
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16J—PISTONS; CYLINDERS; SEALINGS
    • F16J9/00—Piston-rings, e.g. non-metallic piston-rings, seats therefor; Ring sealings of similar construction
    • F16J9/26—Piston-rings, e.g. non-metallic piston-rings, seats therefor; Ring sealings of similar construction characterised by the use of particular materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent

Definitions

  • the invention relates to a method for coating a sliding element and a sliding element, in particular a piston ring.
  • sliding elements such as piston rings
  • sliding elements that they only ever bring about small friction losses.
  • piston rings acting as sliding elements in internal combustion engines an increase in friction has a direct effect upon fuel consumption.
  • oil consumption is affected by the condition of the piston rings.
  • burn mark strength and outbreak strength which must be particularly high in order to permanently realise the required friction values, are to be observed.
  • piston rings which are coated by means of PVD methods on a hard material base, in particular chromium nitride. Furthermore, the electrochemical deposition of chromium layers associated with the incorporation of A1203 or diamond particles, the size of which comes within the micrometre range, is known.
  • a DLC (diamond-like carbon) coating system that can include tungsten carbide depositions in nanocrystalline form, which are produced during the separation process and are up to 10 nm in size, is revealed by WO 2007/079834 A1.
  • DE 199 58 473 A1 relates to a method for producing composite layers with a plasma beam source, wherein nanocrystalline particles can be embedded, and that can be combined with known, separately controllable CVD or PVD methods.
  • the object forming the basis of the invention is to make available a method for coating a sliding element and a corresponding sliding element with which the required friction and wear and tear properties can be realised over the required life span.
  • the invention proposes a method for coating, comprising at least one layer and formed on at least one outer surface, a sliding element, in particular a piston ring, wherein nanoparticles are initially produced, and then infused into the coating during the coating process.
  • the nanoparticles are not produced in situ, i.e. during the coating process, but they are produced separately, to a certain extent ex situ, and incorporated into the coating during the coating process.
  • the mechanism which can be used in this way and which leads to improved mechanical properties, such as fatigue strength, burn mark strength, outbreak strength, breaking strength and elongation at rupture, functions as follows according to the current state of knowledge. It is also noted that the invention is not restricted to this.
  • the incorporation of the described particles gives rise to local crystal lattice deformations which lead to the aforementioned, improved mechanical properties.
  • an improvement of the wear and tear characteristics due to the exceptionally high grain limit density and increased elasticity and less friction are achieved.
  • the advantages of the infused nanoparticles can also be made use of in the dispersion or precipitation hardening to be implemented. That is to say, the displacements produced when stressed or already existing cannot be worked or “cut” through by the particles or the depositions, but bulge out to a certain extent between the particles. In this way, displacement rings are formed which must be bypassed by the displacements. With this bypassing, higher energy is required than when the latter are “cut through” by the particles or depositions. The loading capacity is thus increased. Furthermore, the invention advantageously further makes use of the effect that the yield stress for the migration of the displacements increases as the particle spacing decreases and the particle size decreases. The material strength increases due to this. This effect can be obtained particularly well with nanoparticles.
  • the latter upon the basis of their high defect density on the surface, the latter can be infused and incorporated practically independently of the material to be reinforced during the coating process.
  • the desired depositions which can be incoherent, partially coherent or coherent, and have the effects described above with regard to the mechanical properties, can advantageously be formed.
  • the production of the nanoparticles ex situ advantageously further guarantees that the chemical and crystallographic structure of the nanoparticles can be controlled. Furthermore, by means of this control, when producing the nanoparticles it can be guaranteed that the latter can be infused into the layer hereby growing during the coating process in the desired manner.
  • the coating as such is advantageously implemented by means of tried and tested PVD (physical vapour deposition) and/or CVD (chemical vapour deposition) coating processes.
  • nitrides in particular metal (oxy)nitrides, and in particular Cr(O)N, AlN or TiN, has proven to be particularly advantageous.
  • nanoparticles which have a particle size (diameter) of 1 to 100 nm, preferably 5 to 75 and in particular 5 to 50 nm.
  • carbides and/or silicides with the composition Me x O y , Me x C y or Me x Si y are preferred.
  • the metal here can be chromium, titanium, tantalum, silicon, indium, tin, aluminium, tungsten, vanadium or molybdenum, and/or x can be 1 to 3 and/or y can be 1 to 3.
  • the coating according to the invention can be used in many different ways, due to the proven properties it is currently preferred if the base material, i.e. the coating material of the sliding element to be coated according to the invention, is cast iron or steel.
  • one or more faces i.e. the upper and/or the lower side and/or the contact surface, i.e. the outer cylinder surface of the piston ring, can be coated.
  • the contact surface can be coated more thickly with the coating according to the invention with incorporated, separately produced nanoparticles than at least one of the faces.
  • the cross-over between the contact surface and at least one face can be rounded on the coating, in the same way as this cross-over on the base material of the piston ring can be rounded.
  • the coating of both faces can be of the same thickness. In particular applications also only the contact surface can be coated.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Pistons, Piston Rings, And Cylinders (AREA)
  • Physical Vapour Deposition (AREA)
  • Chemical Vapour Deposition (AREA)
US13/257,396 2009-03-19 2009-12-10 Method for coating a sliding element and sliding element, in particular a piston ring Abandoned US20120088093A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102009013855A DE102009013855A1 (de) 2009-03-19 2009-03-19 Verfahren zur Beschichtung eines Gleitelements und Gleitelement, insbesondere Kolbenring
DE102009013855.2 2009-03-19
PCT/EP2009/066824 WO2010105710A1 (de) 2009-03-19 2009-12-10 Verfahren zur beschichtung eines gleitelements und gleitelement, insbesondere kolbenring

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2009/066824 A-371-Of-International WO2010105710A1 (de) 2009-03-19 2009-12-10 Verfahren zur beschichtung eines gleitelements und gleitelement, insbesondere kolbenring

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US14/813,481 Division US9938626B2 (en) 2009-03-19 2015-07-30 Method for coating a sliding element using a nanoparticles infused coating

Publications (1)

Publication Number Publication Date
US20120088093A1 true US20120088093A1 (en) 2012-04-12

Family

ID=41652074

Family Applications (2)

Application Number Title Priority Date Filing Date
US13/257,396 Abandoned US20120088093A1 (en) 2009-03-19 2009-12-10 Method for coating a sliding element and sliding element, in particular a piston ring
US14/813,481 Expired - Fee Related US9938626B2 (en) 2009-03-19 2015-07-30 Method for coating a sliding element using a nanoparticles infused coating

Family Applications After (1)

Application Number Title Priority Date Filing Date
US14/813,481 Expired - Fee Related US9938626B2 (en) 2009-03-19 2015-07-30 Method for coating a sliding element using a nanoparticles infused coating

Country Status (9)

Country Link
US (2) US20120088093A1 (enrdf_load_stackoverflow)
EP (1) EP2408949B1 (enrdf_load_stackoverflow)
JP (1) JP5501437B2 (enrdf_load_stackoverflow)
KR (1) KR101670730B1 (enrdf_load_stackoverflow)
CN (2) CN102356183A (enrdf_load_stackoverflow)
BR (1) BRPI0924428B1 (enrdf_load_stackoverflow)
DE (1) DE102009013855A1 (enrdf_load_stackoverflow)
PT (1) PT2408949E (enrdf_load_stackoverflow)
WO (1) WO2010105710A1 (enrdf_load_stackoverflow)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10030773B2 (en) 2016-03-04 2018-07-24 Mahle International Gmbh Piston ring
US11143302B2 (en) * 2016-06-30 2021-10-12 Mahle Metal Leve S/A Sliding element for internal combustion engines

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102012217918B4 (de) 2012-10-01 2017-02-02 Federal-Mogul Burscheid Gmbh Gleitpartner mit einer Beschichtung, Verfahren zur Herstellung eines Gleitpartners und Verwendung von Nanopartikeln in einer Beschichtung
CN104854258B (zh) * 2012-10-11 2018-02-02 费德罗-莫格尔公司 在一个涂覆操作中在活塞环的工作面、侧面以及内径上进行耐磨涂层的化学气相沉积

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US20060219054A1 (en) * 2005-03-29 2006-10-05 Hitachi Powdered Metals Co., Ltd. Wear resistant sintered member and production method therefor
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US20080220257A1 (en) * 2005-08-18 2008-09-11 Nv Bekaert Sa Substrate Coated with a Layered Structure Comprising a Tetrahedral Carbon Layer and a Softer Outer Layer
US20090041653A1 (en) * 2007-08-08 2009-02-12 Hyundai Motor Company Method for the preparation of porous graphite carbon with high crystallinity using sucrose as a carbon precursor
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Publication number Priority date Publication date Assignee Title
US6639039B1 (en) * 1998-02-13 2003-10-28 Institut für Neue Materialien Gemeinnützige GmbH Photochromic coating composition comprising nanoscales particles and process for providing substrate coated with the same
US20070129233A1 (en) * 2003-10-29 2007-06-07 Sumitomo Electric Industries, Ltd. Ceramic composite material and method for producing same
US20060219054A1 (en) * 2005-03-29 2006-10-05 Hitachi Powdered Metals Co., Ltd. Wear resistant sintered member and production method therefor
US20080220257A1 (en) * 2005-08-18 2008-09-11 Nv Bekaert Sa Substrate Coated with a Layered Structure Comprising a Tetrahedral Carbon Layer and a Softer Outer Layer
US20060269790A1 (en) * 2005-12-21 2006-11-30 Sarabanda Jose Valentim L Piston ring for internal combustion engines
US20070227299A1 (en) * 2005-12-22 2007-10-04 Momentive Performance Materials Inc. Wear Resistant Low Friction Coating Composition, Coated Components, and Method for Coating Thereof
US20090041653A1 (en) * 2007-08-08 2009-02-12 Hyundai Motor Company Method for the preparation of porous graphite carbon with high crystallinity using sucrose as a carbon precursor
US20100261625A1 (en) * 2007-09-27 2010-10-14 Taiho Kogyo Co., Ltd. Composition for sliding member and sliding member coated with the composition

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10030773B2 (en) 2016-03-04 2018-07-24 Mahle International Gmbh Piston ring
US11143302B2 (en) * 2016-06-30 2021-10-12 Mahle Metal Leve S/A Sliding element for internal combustion engines

Also Published As

Publication number Publication date
WO2010105710A1 (de) 2010-09-23
DE102009013855A1 (de) 2010-09-23
EP2408949B1 (de) 2013-01-16
US20150330508A1 (en) 2015-11-19
PT2408949E (pt) 2013-03-11
EP2408949A1 (de) 2012-01-25
KR20110134436A (ko) 2011-12-14
CN102356183A (zh) 2012-02-15
US9938626B2 (en) 2018-04-10
CN105386050A (zh) 2016-03-09
JP5501437B2 (ja) 2014-05-21
BRPI0924428A2 (pt) 2016-01-26
BRPI0924428B1 (pt) 2019-11-05
JP2012520935A (ja) 2012-09-10
KR101670730B1 (ko) 2016-10-31

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