US20100255671A1 - Nonvolatile semiconductor memory device - Google Patents
Nonvolatile semiconductor memory device Download PDFInfo
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- US20100255671A1 US20100255671A1 US12/817,675 US81767510A US2010255671A1 US 20100255671 A1 US20100255671 A1 US 20100255671A1 US 81767510 A US81767510 A US 81767510A US 2010255671 A1 US2010255671 A1 US 2010255671A1
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- 239000004065 semiconductor Substances 0.000 title claims abstract description 34
- 229910052814 silicon oxide Inorganic materials 0.000 claims abstract description 67
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 55
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 38
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 20
- 239000010703 silicon Substances 0.000 claims abstract description 20
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 19
- 239000000758 substrate Substances 0.000 claims abstract description 10
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- 238000007254 oxidation reaction Methods 0.000 claims description 33
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- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
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- 229910052581 Si3N4 Inorganic materials 0.000 description 58
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 46
- 230000035515 penetration Effects 0.000 description 12
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 10
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- 238000005229 chemical vapour deposition Methods 0.000 description 7
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- 150000004767 nitrides Chemical class 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229920002120 photoresistant polymer Polymers 0.000 description 4
- 238000000137 annealing Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000006870 function Effects 0.000 description 3
- 238000005468 ion implantation Methods 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
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- 239000000126 substance Substances 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
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- 238000003860 storage Methods 0.000 description 1
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B69/00—Erasable-and-programmable ROM [EPROM] devices not provided for in groups H10B41/00 - H10B63/00, e.g. ultraviolet erasable-and-programmable ROM [UVEPROM] devices
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B41/00—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates
- H10B41/30—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by the memory core region
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/76—Making of isolation regions between components
- H01L21/762—Dielectric regions, e.g. EPIC dielectric isolation, LOCOS; Trench refilling techniques, SOI technology, use of channel stoppers
- H01L21/76224—Dielectric regions, e.g. EPIC dielectric isolation, LOCOS; Trench refilling techniques, SOI technology, use of channel stoppers using trench refilling with dielectric materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76838—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
Definitions
- the present invention relates to a nonvolatile semiconductor memory device and, more particularly, to a nonvolatile semiconductor memory device having a multilayered oxide and nitride film.
- Micropatterning of nonvolatile semiconductor memory elements poses the problem of an increase in interference between adjacent cells. This makes it necessary to decrease the thickness of a multilayered oxide and nitride film used as an interelectrode dielectric film.
- a multilayered oxide and nitride film having nitride films in the upper and lower interfaces is already proposed.
- a nonvolatile semiconductor memory device comprising: a first dielectric layer formed on a major surface of a semiconductor substrate; a floating gate electrode layer formed on the first dielectric layer; a second dielectric layer obtained by sequentially forming, on the floating gate electrode layer, a lower dielectric film mainly containing silicon and nitrogen, an intermediate dielectric film, and an upper dielectric film mainly containing silicon and nitrogen; a control gate electrode layer formed on the second dielectric layer; a buried dielectric layer formed by covering two side surfaces in a gate width direction of a stacked structure including the first dielectric layer, the floating gate electrode layer, the second dielectric layer, and the control gate electrode layer; and a silicon oxide film formed near the buried dielectric layer in an interface between the floating gate electrode layer and the lower dielectric film.
- a nonvolatile semiconductor memory device comprising: a first dielectric layer formed on a major surface of a semiconductor substrate; a floating gate electrode layer formed on the first dielectric layer; a second dielectric layer obtained by sequentially forming, on the floating gate electrode layer, a lower dielectric film mainly containing silicon and nitrogen, an intermediate dielectric film, and an upper dielectric film mainly containing silicon and nitrogen; a control gate electrode layer formed on the second dielectric layer; a buried dielectric layer formed by covering two side surfaces in a gate width direction of a stacked structure including the first dielectric layer, the floating gate electrode layer, the second dielectric layer, and the control gate electrode layer; and a silicon oxide film formed near the buried dielectric layer in an interface between the control gate electrode layer and the upper dielectric film.
- a nonvolatile semiconductor memory device fabrication method comprising: forming a first dielectric layer on a major surface of a semiconductor substrate; forming a floating gate electrode layer on the first dielectric layer; etching two side surfaces in a gate length direction of each of the floating gate electrode layer and the first dielectric layer; covering, with an dielectric film, the two side surfaces in the gate length direction of the first dielectric layer and at least portions of the two side surfaces in the gate length direction of the floating gate electrode layer, thereby forming a buried dielectric layer having an upper surface positioned between an upper surface and a bottom surface of the floating gate electrode layer; forming a second dielectric layer on the floating gate electrode layer and the buried dielectric layer, comprising: forming a lower dielectric film mainly containing silicon and nitrogen; forming an intermediate dielectric film on the lower dielectric film; and forming an upper dielectric film mainly containing silicon and nitrogen on the intermediate dielectric film; forming a control gate electrode layer on the second di
- FIG. 1 is a sectional view showing a fabrication step of a nonvolatile semiconductor memory device according to the first embodiment
- FIG. 2 is a sectional view showing a nonvolatile semiconductor memory device fabrication step that follows FIG. 1 ;
- FIG. 3 is a sectional view showing a nonvolatile semiconductor memory device fabrication step that follows FIG. 2 ;
- FIG. 4 is a sectional view showing a nonvolatile semiconductor memory device fabrication step that follows FIG. 3 ;
- FIG. 5 is a sectional view showing a nonvolatile semiconductor memory device fabrication step that follows FIG. 4 ;
- FIG. 6 is a sectional view showing a nonvolatile semiconductor memory device fabrication step that follows FIG. 5 ;
- FIG. 7 is a sectional view taken along a line A-A′ in FIG. 6 and showing a nonvolatile semiconductor memory device fabrication step that follows FIG. 6 ;
- FIG. 8 is a sectional view showing a nonvolatile semiconductor memory device fabrication step that follows FIG. 7 ;
- FIG. 9 is a sectional view showing the nonvolatile semiconductor memory device according to the first and second embodiments.
- FIG. 10 is a graph showing the current densities of leakage currents that flow through an interelectrode dielectric film when interface oxide films are formed and no interface oxide films are formed;
- FIG. 11 is a sectional view showing a fabrication step, that follows FIG. 7 , of a nonvolatile semiconductor memory device according to the third embodiment
- FIG. 12 is a sectional view showing a nonvolatile semiconductor memory device fabrication step that follows FIG. 11 ;
- FIG. 13 is a sectional view showing the nonvolatile semiconductor memory device according to the third embodiment.
- FIGS. 1 to 8 are views showing fabrication steps of a nonvolatile semiconductor memory device according to the first embodiment of the present invention.
- a tunnel dielectric film 2 (first dielectric layer) about 1- to 15-nm-thick is first formed on the major surface of a p-type silicon substrate (or an n-type silicon substrate having a p-type well) 1 .
- the tunnel dielectric film 2 is made of, e.g., a silicon thermal oxide film, a silicon nitride film, or a stacked film of these films.
- a floating gate electrode layer 3 about 10- to 200-nm-thick made of polysilicon or the like is formed by chemical vapor deposition (CVD).
- the floating gate electrode layer 3 functions as a charge storage layer of a memory cell.
- a silicon nitride film 4 about 50- to 200-nm-thick is formed by CVD.
- a silicon oxide film 5 about 50- to 400-nm-thick is formed by CVD.
- the silicon oxide film 5 is coated with a photoresist 6 .
- the structure shown in FIG. 1 is obtained by patterning the photoresist 6 by pattern exposure.
- the silicon oxide film 5 is etched by using the photoresist 6 shown in FIG. 1 as an anti-etching mask.
- the photoresist 6 is removed after the etching, and the silicon nitride film 4 is then etched by using the silicon oxide film 5 as a mask.
- the floating gate electrode layer 3 , dielectric film 2 , and silicon substrate 1 are sequentially etched to form trenches for isolation as shown in FIG. 2 .
- a high-temperature post oxidation step is performed to remove the damage from the section formed by the etching.
- a 200- to 1,500-nm-thick buried dielectric film 7 such as a silicon oxide film is formed and buried in the isolation trenches. Furthermore, the density of the buried dielectric film 7 is increased by high-temperature annealing in a nitrogen or oxygen ambient. Planarization is then performed by chemical mechanical polishing (CMP) by using the silicon nitride film 4 as a stopper, thereby obtaining a structure shown in FIG. 3 .
- CMP chemical mechanical polishing
- the silicon oxide film 7 (buried dielectric film) is etched by using a method capable of etching with selectivity to the silicon nitride film 4 . This etching positions the upper surface of the silicon oxide film 7 between the upper surface and bottom surface of the floating gate electrode layer 3 . In this embodiment, as shown in FIG. 4 , the surface of the silicon oxide film 7 is etched away to a height corresponding to about half the film thickness of the floating gate electrode layer 3 . A structure shown in FIG. 4 is obtained by removing the silicon nitride film 4 by a method having selectivity to the silicon oxide film 7 .
- an interelectrode dielectric film 8 (second dielectric layer) is formed on the lower layers having the structure shown in FIG. 4 .
- the interelectrode dielectric film 8 is a multilayered dielectric film including three dielectric films 81 to 83 .
- the structure shown in FIG. 5 is formed by the following procedure.
- a silicon nitride film 81 (lower dielectric film) having a thickness of 0.5 to 10 nm is formed by CVD on the lower layers having the structure shown in FIG. 4 .
- a silicon oxide film 82 (intermediate dielectric film) having a thickness of 0.5 to 15 nm is formed on the silicon nitride film 81 by CVD.
- a silicon nitride film 83 (upper dielectric film) having a thickness of 0.5 to 10 nm is formed on the silicon oxide film 82 by CVD, thereby forming the interelectrode dielectric film 8 shown in FIG. 5 .
- control gate electrode layer 9 made of, e.g., polysilicon is formed on the interelectrode dielectric film 8 .
- the control gate electrode layer 9 functions as a control electrode in the nonvolatile semiconductor memory device.
- a sectional structure shown in FIG. 6 is obtained by forming a mask material 10 on the control gate electrode layer 9 .
- the mask material 10 is coated with a resist (not shown), and the resist is patterned by pattern exposure.
- This resist is used as a mask to etch away the mask material 10 , control gate electrode layer 9 , interelectrode dielectric film 8 (second dielectric layer), floating gate electrode layer 3 , and first dielectric layer 2 (this step is not shown).
- Source and drain regions 20 are formed by ion implantation in the surface of the substrate 1 as the bottom portions of the etched regions (isolation trenches) shown in FIG. 7 .
- an oxidation process is performed in a steam ambient at 750° C. for an oxidation time of 30 min.
- a silicon oxide film 13 is formed on the sidewall surfaces of the etched control gate electrode layer 9 , and on those portions of the interface, which continue from the above-mentioned sidewall surfaces, between the control gate electrode layer 9 and interelectrode dielectric film 8 (i.e., the silicon nitride film 83 ).
- the silicon oxide film 11 penetrates between the floating gate electrode layer 3 and silicon nitride film 81 from both sides, and the silicon oxide film 13 penetrates between the control gate electrode layer 9 and silicon nitride film 83 from both sides.
- the length of penetration of the silicon oxide films 11 and 13 measured in the gate length direction from the sidewalls of the floating gate electrode layer 3 and control gate electrode layer 9 is desirably 5% or more of the film thickness of the interelectrode dielectric film 8 .
- the coupling ratio decreases as the penetration length described above increases. This is so because when the penetration length increases, both the contact area between the floating gate electrode layer 3 and interelectrode dielectric film 8 and the contact area between the control gate electrode layer 9 and interelectrode dielectric film 8 reduce, and this decreases the capacitance of the interelectrode dielectric film 8 .
- the penetration length is desirably 4% or less of the cell length, i.e., the width in the gate length direction of the floating gate electrode layer 3 or control gate electrode layer 9 .
- the oxidation process may also be performed not in the steam ambient but by plasma oxidation at a temperature of about 400° C.
- a 200- to 1,500-nm-thick buried dielectric film 12 (buried dielectric layer) for isolation made of a silicon oxide film or the like is formed and buried in the isolation-trenches.
- a high-temperature annealing step is performed in a nitrogen or oxygen ambient to increase the density of the buried dielectric film 12 .
- Planarization is then performed by chemical mechanical polishing (CMP) by using the control gate electrodes 9 as stoppers.
- CMP chemical mechanical polishing
- a silicon oxide film 11 is formed near the buried dielectric film 12 in the interface between the floating gate electrode layer 3 and silicon nitride film 81
- a silicon oxide film 13 is formed near the buried dielectric film 12 in the interface between the control gate electrode layer 9 and silicon nitride film 83 .
- FIG. 10 shows the current densities of leakage currents that flow through the interelectrode dielectric film when no interface oxide films are formed and interface oxide films are formed as in this embodiment. As shown in FIG. 10 , the formation of the interface oxide films reduces the leakage current.
- the interelectrode dielectric film 8 has the three-layered structure including silicon nitride film-silicon oxide film-silicon nitride film (NON).
- the interelectrode dielectric film 8 is not limited to this structure.
- the same effects as in the above embodiment can be obtained by a silicon nitride film-silicon oxide film-silicon nitride film-silicon oxide film-silicon nitride film (NONON) five-layered structure in which the silicon oxide film as an intermediate dielectric film in the center of the three-layered structure has an ONO structure including silicon oxide film-silicon nitride film-silicon oxide film. Since a silicon nitride film traps electric charge, this structure can further reduce the leakage current flowing through the interelectrode dielectric film.
- the structure shown in FIG. 7 is formed by the same steps as in the first embodiment.
- This embodiment further ion-implants phosphorus (P) in memory cell regions of the structure shown in FIG. 7 in which source and drain regions 20 are already formed by ion implantation.
- phosphorus ions may also be implanted in, e.g., an oblique direction so as to be readily implanted into silicon nitride films 81 and 83 from the sidewalls.
- an oxidation process is performed in an oxygen ambient at 850° C. for an oxidation time of 30 min, thereby obtaining the same structure as in the first embodiment shown in FIG. 8 .
- This embodiment can also round the corners in the gate width direction of the floating gate electrode layer 3 and control gate electrode layer 9 , and recover the damage caused by mixing of ions and the like during etching, thereby reducing the leakage current. Steps to FIG. 9 after that are the same as in the first embodiment.
- the length of penetration of the silicon oxide films 11 and 13 measured from the sidewalls of the floating gate electrode layer 3 and control gate electrode layer 9 is desirably 5% or more of the film thickness of the interelectrode dielectric film 8 , in this embodiment as well.
- the penetration length is desirably 4% or less of the cell length, i.e., the width in the gate length direction of the floating gate electrode layer 3 or control gate electrode layer 9 .
- the oxidation process may also be performed not under the above-mentioned conditions but by plasma oxidation at a temperature of about 400° C.
- the interelectrode dielectric film 8 is not limited to the three-layered structure including silicon nitride film-silicon oxide film-silicon nitride film (NON) in this embodiment as well.
- the same effects as in the above embodiment can be obtained by a silicon nitride film-silicon oxide film-silicon nitride film-silicon oxide film-silicon nitride film (NONON) five-layered structure in which the silicon oxide film as an intermediate dielectric film in the center of the three-layered structure has an ONO structure including silicon oxide film-silicon nitride film-silicon oxide film. Since a silicon nitride film traps electric charge, this structure can further reduce the leakage current flowing through the interelectrode dielectric film.
- This embodiment also forms the structure shown in FIG. 7 by the same steps as in the first embodiment. In the structure shown in FIG. 7 , however, this embodiment performs wet etching on silicon nitride films 81 and 83 by using a phosphoric acid solution, thereby obtaining a structure shown in FIG. 11 .
- this wet etching partially removes one or both of the silicon nitride films 81 and 83 in the gate length direction, thereby making the width in the gate length direction smaller than that in the gate length direction of a floating gate electrode layer 3 or control gate electrode layer 9 .
- an oxidation process is performed in an oxygen ambient at 850° C. for an oxidation time of 30 min.
- This oxidation process forms interface oxide films as shown in FIG. 12 . That is, a silicon oxide film 11 is formed on the sidewall surfaces of the floating gate electrode layer 3 that is etched by etching for forming isolation trenches, and on those portions of the interface, which continue from the above-mentioned sidewall surfaces, between the floating gate electrode layer 3 and an interelectrode dielectric film 8 (i.e., the silicon nitride film 81 ).
- a silicon nitride film 13 is formed on the sidewall surfaces of the control gate electrode layer 9 that is similarly etched, and on those portions of the interface, which continue from the above-mentioned sidewall surfaces, between the control gate electrode layer 9 and interelectrode dielectric film 8 (i.e., the silicon nitride film 83 ).
- the width of the removal of the silicon nitride films 81 and 83 by the wet etching described above is desirably larger than the film thickness of the silicon oxide films 11 and 13 respectively formed on the sidewall surfaces of the floating gate electrode layer 3 and control gate electrode layer 9 .
- the floating gate electrode layer 3 and control gate electrode layer 9 are exposed by etching the silicon nitride films 81 and 83 by using a phosphoric acid solution as in this embodiment. It is possible via oxidation of the exposed surfaces to accelerate oxidation of the floating gate electrode layer 3 from both sides along the interface between the floating gate electrode layer 3 and interelectrode dielectric film 8 (silicon nitride film 81 ), and oxidation of the control gate electrode layer 9 from both sides along the interface between the control gate electrode layer 9 and interelectrode dielectric film 8 (silicon nitride film 83 ).
- the silicon oxide films 11 and 13 penetrate to portions deeper than the sidewalls of the silicon nitride films 81 and 83 partially removed by wet etching.
- This interface oxidation rounds the corners of the floating gate electrode layer 3 and control gate electrode layer 9 , and can also recover the damage caused by mixing of ions and the like during etching, thereby reducing the leakage current.
- the length of penetration of the silicon oxide films 11 and 13 measured from the sidewalls of the floating gate electrode layer 3 and control gate electrode layer 9 is desirably 5% or more of the film thickness of the interelectrode dielectric film 8 , in this embodiment as well.
- the penetration length is desirably 4% or less of the cell length, i.e., the width in the gate length direction of the floating gate electrode layer 3 or control gate electrode layer 9 .
- the oxidation process may also be performed not under the above-mentioned conditions but by plasma oxidation at a temperature of about 400° C.
- a 200- to 1,500-nm-thick buried dielectric film 12 for isolation made of a silicon oxide film or the like is formed and buried in the isolation trenches.
- a high-temperature annealing step is performed in a nitrogen or oxygen ambient to increase the density of the buried dielectric film 12 .
- Planarization is then performed by chemical mechanical polishing (CMP) by using the control gate electrodes 9 as stoppers.
- a silicon oxide film 11 is formed near the buried dielectric film 12 in the interface between the floating gate electrode layer 3 and silicon nitride film 81
- a silicon oxide film 13 is formed near the buried dielectric film 12 in the interface between the control gate electrode layer 9 and silicon nitride film 83 .
- this embodiment can remove the damaged portions that produce a leakage current, by wet-etching the sidewalls of the silicon nitride films 81 and 83 . This can also reduce the leakage current.
- the interelectrode dielectric film 8 is not limited to the three-layered structure including silicon nitride film-silicon oxide film-silicon nitride film (NON) in this embodiment as well.
- the same effects as in the above embodiment can be obtained by a silicon nitride film-silicon oxide film-silicon nitride film-silicon oxide film-silicon nitride film (NONON) five-layered structure in which the silicon oxide film as an intermediate dielectric film in the center of the three-layered structure has an ONO structure including silicon oxide film-silicon nitride film-silicon oxide film. Since a silicon nitride film traps electric charge, this structure can further reduce the leakage current flowing through the interelectrode dielectric film.
- One aspect of the present invention can provide a nonvolatile semiconductor memory device that reduces a leakage current flowing through an interelectrode dielectric film, particularly, an interelectrode dielectric film having silicon nitride films in the upper and lower interfaces.
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Abstract
A nonvolatile semiconductor memory device includes a first dielectric layer formed on the major surface of a semiconductor substrate, a floating gate electrode layer formed on the first dielectric layer, a second dielectric layer obtained by sequentially forming, on the floating gate electrode layer, a lower dielectric film mainly containing silicon and nitrogen, an intermediate dielectric film, and an upper dielectric film mainly containing silicon and nitrogen, a control gate electrode layer formed on the second dielectric layer, and a buried dielectric layer formed by covering the two side surfaces in the gate width direction of the stacked structure including the above-mentioned layers. The nonvolatile semiconductor memory device further includes a silicon oxide film formed near the buried dielectric layer in the interface between the floating gate electrode layer and lower dielectric film.
Description
- This application is based upon and claims the benefit of priority from prior Japanese Patent Application No. 2006-118272, filed Apr. 21, 2006, the entire contents of which are incorporated herein by reference.
- 1. Field of the Invention
- The present invention relates to a nonvolatile semiconductor memory device and, more particularly, to a nonvolatile semiconductor memory device having a multilayered oxide and nitride film.
- 2. Description of the Related Art
- Micropatterning of nonvolatile semiconductor memory elements poses the problem of an increase in interference between adjacent cells. This makes it necessary to decrease the thickness of a multilayered oxide and nitride film used as an interelectrode dielectric film. In addition, to reduce a leakage current that flows through the interelectrode dielectric film when its thickness decreases, a multilayered oxide and nitride film having nitride films in the upper and lower interfaces is already proposed.
- In an dielectric film having oxide films in the upper and lower interfaces, it is possible by post oxidation after cell processing to reduce a leakage current caused by the damage during the processing, and a leakage current caused by a pointed end face of an electrode layer (e.g., Jpn. Pat. Appln. KOKAI Publication No. 2003-31705).
- Unfortunately, in an interelectrode dielectric film having nitride films in the upper and lower interfaces (e.g., U.S. Pat. No. 5,661,056), the influences of the leakage current caused by the damage during the processing and the leakage current caused by the acute-angled electrode end face remain.
- According to a first aspect of the present invention, there is provided a nonvolatile semiconductor memory device comprising: a first dielectric layer formed on a major surface of a semiconductor substrate; a floating gate electrode layer formed on the first dielectric layer; a second dielectric layer obtained by sequentially forming, on the floating gate electrode layer, a lower dielectric film mainly containing silicon and nitrogen, an intermediate dielectric film, and an upper dielectric film mainly containing silicon and nitrogen; a control gate electrode layer formed on the second dielectric layer; a buried dielectric layer formed by covering two side surfaces in a gate width direction of a stacked structure including the first dielectric layer, the floating gate electrode layer, the second dielectric layer, and the control gate electrode layer; and a silicon oxide film formed near the buried dielectric layer in an interface between the floating gate electrode layer and the lower dielectric film.
- According to a second aspect of the present invention, there is provided a nonvolatile semiconductor memory device comprising: a first dielectric layer formed on a major surface of a semiconductor substrate; a floating gate electrode layer formed on the first dielectric layer; a second dielectric layer obtained by sequentially forming, on the floating gate electrode layer, a lower dielectric film mainly containing silicon and nitrogen, an intermediate dielectric film, and an upper dielectric film mainly containing silicon and nitrogen; a control gate electrode layer formed on the second dielectric layer; a buried dielectric layer formed by covering two side surfaces in a gate width direction of a stacked structure including the first dielectric layer, the floating gate electrode layer, the second dielectric layer, and the control gate electrode layer; and a silicon oxide film formed near the buried dielectric layer in an interface between the control gate electrode layer and the upper dielectric film.
- According to a third aspect of the present invention, there is provided a nonvolatile semiconductor memory device fabrication method comprising: forming a first dielectric layer on a major surface of a semiconductor substrate; forming a floating gate electrode layer on the first dielectric layer; etching two side surfaces in a gate length direction of each of the floating gate electrode layer and the first dielectric layer; covering, with an dielectric film, the two side surfaces in the gate length direction of the first dielectric layer and at least portions of the two side surfaces in the gate length direction of the floating gate electrode layer, thereby forming a buried dielectric layer having an upper surface positioned between an upper surface and a bottom surface of the floating gate electrode layer; forming a second dielectric layer on the floating gate electrode layer and the buried dielectric layer, comprising: forming a lower dielectric film mainly containing silicon and nitrogen; forming an intermediate dielectric film on the lower dielectric film; and forming an upper dielectric film mainly containing silicon and nitrogen on the intermediate dielectric film; forming a control gate electrode layer on the second dielectric layer; etching two side surfaces in a gate width direction of each of the first dielectric layer, the floating gate electrode layer, the second dielectric layer, and the control gate electrode layer, thereby forming isolation trenches; and forming, by oxidation, a first silicon oxide film near the isolation trench in an interface between the floating gate electrode layer and the lower dielectric film, and a second silicon oxide film near the isolation trench in an interface between the control gate electrode layer and the upper dielectric film.
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FIG. 1 is a sectional view showing a fabrication step of a nonvolatile semiconductor memory device according to the first embodiment; -
FIG. 2 is a sectional view showing a nonvolatile semiconductor memory device fabrication step that followsFIG. 1 ; -
FIG. 3 is a sectional view showing a nonvolatile semiconductor memory device fabrication step that followsFIG. 2 ; -
FIG. 4 is a sectional view showing a nonvolatile semiconductor memory device fabrication step that followsFIG. 3 ; -
FIG. 5 is a sectional view showing a nonvolatile semiconductor memory device fabrication step that followsFIG. 4 ; -
FIG. 6 is a sectional view showing a nonvolatile semiconductor memory device fabrication step that followsFIG. 5 ; -
FIG. 7 is a sectional view taken along a line A-A′ inFIG. 6 and showing a nonvolatile semiconductor memory device fabrication step that followsFIG. 6 ; -
FIG. 8 is a sectional view showing a nonvolatile semiconductor memory device fabrication step that followsFIG. 7 ; -
FIG. 9 is a sectional view showing the nonvolatile semiconductor memory device according to the first and second embodiments; -
FIG. 10 is a graph showing the current densities of leakage currents that flow through an interelectrode dielectric film when interface oxide films are formed and no interface oxide films are formed; -
FIG. 11 is a sectional view showing a fabrication step, that followsFIG. 7 , of a nonvolatile semiconductor memory device according to the third embodiment; -
FIG. 12 is a sectional view showing a nonvolatile semiconductor memory device fabrication step that followsFIG. 11 ; and -
FIG. 13 is a sectional view showing the nonvolatile semiconductor memory device according to the third embodiment. - Embodiments of the present invention will be explained in detail below with reference to the accompanying drawing. Note that in the following explanation, the same reference numerals denote elements having the same functions.
-
FIGS. 1 to 8 are views showing fabrication steps of a nonvolatile semiconductor memory device according to the first embodiment of the present invention. - As shown in the sectional view of
FIG. 1 , a tunnel dielectric film 2 (first dielectric layer) about 1- to 15-nm-thick is first formed on the major surface of a p-type silicon substrate (or an n-type silicon substrate having a p-type well) 1. The tunneldielectric film 2 is made of, e.g., a silicon thermal oxide film, a silicon nitride film, or a stacked film of these films. - On the tunnel
dielectric film 2, a floatinggate electrode layer 3 about 10- to 200-nm-thick made of polysilicon or the like is formed by chemical vapor deposition (CVD). The floatinggate electrode layer 3 functions as a charge storage layer of a memory cell. Then, asilicon nitride film 4 about 50- to 200-nm-thick is formed by CVD. In addition, asilicon oxide film 5 about 50- to 400-nm-thick is formed by CVD. Thesilicon oxide film 5 is coated with a photoresist 6. The structure shown inFIG. 1 is obtained by patterning thephotoresist 6 by pattern exposure. - After that, the
silicon oxide film 5 is etched by using thephotoresist 6 shown inFIG. 1 as an anti-etching mask. Thephotoresist 6 is removed after the etching, and thesilicon nitride film 4 is then etched by using thesilicon oxide film 5 as a mask. In addition, the floatinggate electrode layer 3,dielectric film 2, andsilicon substrate 1 are sequentially etched to form trenches for isolation as shown inFIG. 2 . - After that, a high-temperature post oxidation step is performed to remove the damage from the section formed by the etching. Subsequently, a 200- to 1,500-nm-thick buried
dielectric film 7 such as a silicon oxide film is formed and buried in the isolation trenches. Furthermore, the density of the burieddielectric film 7 is increased by high-temperature annealing in a nitrogen or oxygen ambient. Planarization is then performed by chemical mechanical polishing (CMP) by using thesilicon nitride film 4 as a stopper, thereby obtaining a structure shown inFIG. 3 . - The silicon oxide film 7 (buried dielectric film) is etched by using a method capable of etching with selectivity to the
silicon nitride film 4. This etching positions the upper surface of thesilicon oxide film 7 between the upper surface and bottom surface of the floatinggate electrode layer 3. In this embodiment, as shown inFIG. 4 , the surface of thesilicon oxide film 7 is etched away to a height corresponding to about half the film thickness of the floatinggate electrode layer 3. A structure shown inFIG. 4 is obtained by removing thesilicon nitride film 4 by a method having selectivity to thesilicon oxide film 7. - As shown in
FIG. 5 , an interelectrode dielectric film 8 (second dielectric layer) is formed on the lower layers having the structure shown inFIG. 4 . The interelectrodedielectric film 8 is a multilayered dielectric film including threedielectric films 81 to 83. The structure shown inFIG. 5 is formed by the following procedure. - First, a silicon nitride film 81 (lower dielectric film) having a thickness of 0.5 to 10 nm is formed by CVD on the lower layers having the structure shown in
FIG. 4 . Then, a silicon oxide film 82 (intermediate dielectric film) having a thickness of 0.5 to 15 nm is formed on thesilicon nitride film 81 by CVD. Finally, a silicon nitride film 83 (upper dielectric film) having a thickness of 0.5 to 10 nm is formed on thesilicon oxide film 82 by CVD, thereby forming the interelectrodedielectric film 8 shown inFIG. 5 . - In addition, as shown in
FIG. 6 , a 10- to 200-nm-thick controlgate electrode layer 9 made of, e.g., polysilicon is formed on the interelectrodedielectric film 8. The controlgate electrode layer 9 functions as a control electrode in the nonvolatile semiconductor memory device. A sectional structure shown inFIG. 6 is obtained by forming amask material 10 on the controlgate electrode layer 9. - After that, the
mask material 10 is coated with a resist (not shown), and the resist is patterned by pattern exposure. This resist is used as a mask to etch away themask material 10, controlgate electrode layer 9, interelectrode dielectric film 8 (second dielectric layer), floatinggate electrode layer 3, and first dielectric layer 2 (this step is not shown). - The resist and
mask material 10 are then removed to obtain a structure shown inFIG. 7 , as a sectional view taken along a line A-A′ inFIG. 6 and perpendicular to the drawing surface. Source anddrain regions 20 are formed by ion implantation in the surface of thesubstrate 1 as the bottom portions of the etched regions (isolation trenches) shown inFIG. 7 . - In this state, an oxidation process is performed in a steam ambient at 750° C. for an oxidation time of 30 min. This forms interface oxide films as shown in
FIG. 8 . That is, asilicon oxide film 11 is formed on the sidewall surfaces of the etched floatinggate electrode layer 3, and on those portions of the interface, which continue from the above-mentioned sidewall surfaces, between the floatinggate electrode layer 3 and interelectrode dielectric film 8 (i.e., the silicon nitride film 81). Also, asilicon oxide film 13 is formed on the sidewall surfaces of the etched controlgate electrode layer 9, and on those portions of the interface, which continue from the above-mentioned sidewall surfaces, between the controlgate electrode layer 9 and interelectrode dielectric film 8 (i.e., the silicon nitride film 83). - By performing the oxidation process under the oxidizing conditions with a high oxidizing power in the presence of steam as in this embodiment, it is possible to oxidize the floating
gate electrode layer 3 from both sides along the interface between the floatinggate electrode layer 3 and interelectrodedielectric film 8, and simultaneously oxidize the controlgate electrode layer 9 from both sides along the interface between the controlgate electrode layer 9 and interelectrodedielectric film 8. This rounds the corners along the gate width direction of the floatinggate electrode layer 3 and controlgate electrode 9, and makes it possible to recover the damage caused by mixing of ions and the like during the etching. Consequently, the leakage current can be reduced. - In this case, the
silicon oxide film 11 penetrates between the floatinggate electrode layer 3 andsilicon nitride film 81 from both sides, and thesilicon oxide film 13 penetrates between the controlgate electrode layer 9 andsilicon nitride film 83 from both sides. To effectively reduce the leakage current caused via the corners of the floatinggate electrode layer 3 and controlgate electrode layer 9, the length of penetration of thesilicon oxide films gate electrode layer 3 and controlgate electrode layer 9 is desirably 5% or more of the film thickness of the interelectrodedielectric film 8. - On the other hand, from the viewpoint of the coupling ratio (C1/(C1+C2)) defined by the capacitance (C1) of the interelectrode
dielectric film 8 and the capacitance (C2) of thetunnel dielectric film 2, the coupling ratio decreases as the penetration length described above increases. This is so because when the penetration length increases, both the contact area between the floatinggate electrode layer 3 and interelectrodedielectric film 8 and the contact area between the controlgate electrode layer 9 and interelectrodedielectric film 8 reduce, and this decreases the capacitance of the interelectrodedielectric film 8. - To suppress the fluctuation from the desired coupling ratio to 5% or less, therefore, the penetration length is desirably 4% or less of the cell length, i.e., the width in the gate length direction of the floating
gate electrode layer 3 or controlgate electrode layer 9. - Note that the oxidation process may also be performed not in the steam ambient but by plasma oxidation at a temperature of about 400° C.
- Subsequently, as shown in
FIGS. 9 , a 200- to 1,500-nm-thick buried dielectric film 12 (buried dielectric layer) for isolation made of a silicon oxide film or the like is formed and buried in the isolation-trenches. After that, a high-temperature annealing step is performed in a nitrogen or oxygen ambient to increase the density of the burieddielectric film 12. Planarization is then performed by chemical mechanical polishing (CMP) by using thecontrol gate electrodes 9 as stoppers. - Consequently, as shown in
FIG. 9 , asilicon oxide film 11 is formed near the burieddielectric film 12 in the interface between the floatinggate electrode layer 3 andsilicon nitride film 81, and asilicon oxide film 13 is formed near the burieddielectric film 12 in the interface between the controlgate electrode layer 9 andsilicon nitride film 83. - If no interface oxide films are formed and the corners along the gate width direction of the floating
gate electrode layer 3 and controlgate electrode layer 9 are close to the right angle, an electric field concentrates to these corners to allow a leakage current to readily flow through the interelectrodedielectric film 8. However, when thesilicon oxide films gate electrode layer 3 and controlgate electrode layer 9 can be rounded. Since this makes it possible to alleviate the field concentration near the corners, the leakage current can be reduced. -
FIG. 10 shows the current densities of leakage currents that flow through the interelectrode dielectric film when no interface oxide films are formed and interface oxide films are formed as in this embodiment. As shown inFIG. 10 , the formation of the interface oxide films reduces the leakage current. - In this embodiment, the interelectrode
dielectric film 8 has the three-layered structure including silicon nitride film-silicon oxide film-silicon nitride film (NON). However, the interelectrodedielectric film 8 is not limited to this structure. For example, the same effects as in the above embodiment can be obtained by a silicon nitride film-silicon oxide film-silicon nitride film-silicon oxide film-silicon nitride film (NONON) five-layered structure in which the silicon oxide film as an intermediate dielectric film in the center of the three-layered structure has an ONO structure including silicon oxide film-silicon nitride film-silicon oxide film. Since a silicon nitride film traps electric charge, this structure can further reduce the leakage current flowing through the interelectrode dielectric film. - Fabrication steps of a nonvolatile semiconductor memory device according to the second embodiment of the present invention will be explained below.
- In this embodiment, the structure shown in
FIG. 7 is formed by the same steps as in the first embodiment. This embodiment further ion-implants phosphorus (P) in memory cell regions of the structure shown inFIG. 7 in which source and drainregions 20 are already formed by ion implantation. In this ion implantation, phosphorus ions may also be implanted in, e.g., an oblique direction so as to be readily implanted intosilicon nitride films - After that, an oxidation process is performed in an oxygen ambient at 850° C. for an oxidation time of 30 min, thereby obtaining the same structure as in the first embodiment shown in
FIG. 8 . - Oxidation performed after phosphorus is ion-implanted into the
silicon nitride films silicon nitride films silicon oxide film 11 into the interface between a floatinggate electrode layer 3 and interelectrode dielectric film 8 (i.e., the silicon nitride film 81), and penetration in the gate length direction of asilicon oxide film 13 into the interface between a controlgate electrode layer 9 and the interelectrode dielectric film 8 (i.e., the silicon nitride film 83). - This embodiment can also round the corners in the gate width direction of the floating
gate electrode layer 3 and controlgate electrode layer 9, and recover the damage caused by mixing of ions and the like during etching, thereby reducing the leakage current. Steps toFIG. 9 after that are the same as in the first embodiment. - To effectively reduce the leakage current caused via the corners of the floating
gate electrode layer 3 and controlgate electrode layer 9, the length of penetration of thesilicon oxide films gate electrode layer 3 and controlgate electrode layer 9 is desirably 5% or more of the film thickness of the interelectrodedielectric film 8, in this embodiment as well. - On the other hand, to suppress the fluctuation from the desired coupling ratio to 5% or less, the penetration length is desirably 4% or less of the cell length, i.e., the width in the gate length direction of the floating
gate electrode layer 3 or controlgate electrode layer 9. - Note that the oxidation process may also be performed not under the above-mentioned conditions but by plasma oxidation at a temperature of about 400° C.
- The interelectrode
dielectric film 8 is not limited to the three-layered structure including silicon nitride film-silicon oxide film-silicon nitride film (NON) in this embodiment as well. For example, the same effects as in the above embodiment can be obtained by a silicon nitride film-silicon oxide film-silicon nitride film-silicon oxide film-silicon nitride film (NONON) five-layered structure in which the silicon oxide film as an intermediate dielectric film in the center of the three-layered structure has an ONO structure including silicon oxide film-silicon nitride film-silicon oxide film. Since a silicon nitride film traps electric charge, this structure can further reduce the leakage current flowing through the interelectrode dielectric film. - Fabrication steps of a nonvolatile semiconductor memory device according to the third embodiment of the present invention will be explained below.
- This embodiment also forms the structure shown in
FIG. 7 by the same steps as in the first embodiment. In the structure shown inFIG. 7 , however, this embodiment performs wet etching onsilicon nitride films FIG. 11 . - As shown in
FIG. 11 , this wet etching partially removes one or both of thesilicon nitride films gate electrode layer 3 or controlgate electrode layer 9. - After that, an oxidation process is performed in an oxygen ambient at 850° C. for an oxidation time of 30 min. This oxidation process forms interface oxide films as shown in
FIG. 12 . That is, asilicon oxide film 11 is formed on the sidewall surfaces of the floatinggate electrode layer 3 that is etched by etching for forming isolation trenches, and on those portions of the interface, which continue from the above-mentioned sidewall surfaces, between the floatinggate electrode layer 3 and an interelectrode dielectric film 8 (i.e., the silicon nitride film 81). Also, asilicon nitride film 13 is formed on the sidewall surfaces of the controlgate electrode layer 9 that is similarly etched, and on those portions of the interface, which continue from the above-mentioned sidewall surfaces, between the controlgate electrode layer 9 and interelectrode dielectric film 8 (i.e., the silicon nitride film 83). - Note that as shown in
FIG. 12 , the width of the removal of thesilicon nitride films silicon oxide films gate electrode layer 3 and controlgate electrode layer 9. - The floating
gate electrode layer 3 and controlgate electrode layer 9 are exposed by etching thesilicon nitride films gate electrode layer 3 from both sides along the interface between the floatinggate electrode layer 3 and interelectrode dielectric film 8 (silicon nitride film 81), and oxidation of the controlgate electrode layer 9 from both sides along the interface between the controlgate electrode layer 9 and interelectrode dielectric film 8 (silicon nitride film 83). - That is, it is possible to promote penetration in the gate length direction of the
silicon oxide film 11 in the interface between the floatinggate electrode layer 3 andsilicon nitride film 81, and penetration in the gate length direction of thesilicon oxide film 13 in the interface between the controlgate electrode layer 9 andsilicon nitride film 83. - Consequently, as shown in
FIG. 12 , thesilicon oxide films silicon nitride films - This interface oxidation rounds the corners of the floating
gate electrode layer 3 and controlgate electrode layer 9, and can also recover the damage caused by mixing of ions and the like during etching, thereby reducing the leakage current. - To effectively reduce the leakage current caused via the corners of the floating
gate electrode layer 3 and controlgate electrode layer 9, the length of penetration of thesilicon oxide films gate electrode layer 3 and controlgate electrode layer 9 is desirably 5% or more of the film thickness of the interelectrodedielectric film 8, in this embodiment as well. - On the other hand, to suppress the fluctuation from the desired coupling ratio to 5% or less, the penetration length is desirably 4% or less of the cell length, i.e., the width in the gate length direction of the floating
gate electrode layer 3 or controlgate electrode layer 9. - Note that the oxidation process may also be performed not under the above-mentioned conditions but by plasma oxidation at a temperature of about 400° C.
- Subsequently, as shown in
FIGS. 13 , a 200- to 1,500-nm-thick burieddielectric film 12 for isolation made of a silicon oxide film or the like is formed and buried in the isolation trenches. After that, a high-temperature annealing step is performed in a nitrogen or oxygen ambient to increase the density of the burieddielectric film 12. Planarization is then performed by chemical mechanical polishing (CMP) by using thecontrol gate electrodes 9 as stoppers. - Consequently, as shown in
FIG. 13 , asilicon oxide film 11 is formed near the burieddielectric film 12 in the interface between the floatinggate electrode layer 3 andsilicon nitride film 81, and asilicon oxide film 13 is formed near the burieddielectric film 12 in the interface between the controlgate electrode layer 9 andsilicon nitride film 83. - It is conventionally difficult to recover the damage inflicted on the sidewalls of the
silicon nitride films silicon nitride films - The interelectrode
dielectric film 8 is not limited to the three-layered structure including silicon nitride film-silicon oxide film-silicon nitride film (NON) in this embodiment as well. For example, the same effects as in the above embodiment can be obtained by a silicon nitride film-silicon oxide film-silicon nitride film-silicon oxide film-silicon nitride film (NONON) five-layered structure in which the silicon oxide film as an intermediate dielectric film in the center of the three-layered structure has an ONO structure including silicon oxide film-silicon nitride film-silicon oxide film. Since a silicon nitride film traps electric charge, this structure can further reduce the leakage current flowing through the interelectrode dielectric film. - One aspect of the present invention can provide a nonvolatile semiconductor memory device that reduces a leakage current flowing through an interelectrode dielectric film, particularly, an interelectrode dielectric film having silicon nitride films in the upper and lower interfaces.
- Additional advantages and modifications will readily occur to those skilled in the art. Therefore, the invention in its broader aspects is not limited to the specific details and representative embodiments shown and described herein. Accordingly, various modifications may be made without departing from the spirit or scope of the general inventive concept as defined by the appended claims and their equivalents.
Claims (13)
1.-14. (canceled)
15. A nonvolatile semiconductor memory device fabrication method comprising:
forming a first dielectric layer on a major surface of a semiconductor substrate;
forming a floating gate electrode layer on the first dielectric layer;
etching two side surfaces in a gate length direction of each of the floating gate electrode layer and the first dielectric layer;
covering, with an dielectric film, the two side surfaces in the gate length direction of the first dielectric layer and at least portions of the two side surfaces in the gate length direction of the floating gate electrode layer, thereby forming a buried dielectric layer having an upper surface positioned between an upper surface and a bottom surface of the floating gate electrode layer;
forming a second dielectric layer on the floating gate electrode layer and the buried dielectric layer, comprising:
forming a lower dielectric film mainly containing silicon and nitrogen;
forming an intermediate dielectric film on the lower dielectric film; and
forming an upper dielectric film mainly containing silicon and nitrogen on the intermediate dielectric film;
forming a control gate electrode layer on the second dielectric layer;
etching two side surfaces in a gate width direction of each of the first dielectric layer, the floating gate electrode layer, the second dielectric layer, and the control gate electrode layer; and
forming, by oxidation, a first silicon oxide film is an interface between the floating gate electrode layer and the lower dielectric film.
16. A method according to claim 15 , wherein a corner of the floating gate electrode layer, which is formed along the gate width direction and in contact with the first silicon oxide film is rounded.
17. A method according to claim 15 , wherein the intermediate dielectric film is a silicon oxide film.
18. A method according to claim 15 , wherein forming the intermediate dielectric film comprises:
forming a silicon oxide film;
forming an dielectric film mainly containing silicon and nitrogen on the silicon oxide film; and
forming another silicon oxide film on the dielectric film mainly containing silicon and nitrogen.
19. A method according to claim 15 , further comprising, before the oxidation, wet-etching the lower dielectric film to make a width in the gate length direction of the lower dielectric film smaller than a width in the gate length direction of the floating gate electrode layer.
20. A method according to claim 15 , wherein the oxidation is one of oxidation executed in one of a steam ambient and an oxygen ambient, and plasma oxidation.
21. A nonvolatile semiconductor memory device fabrication method comprising:
forming a first dielectric layer on a major surface of a semiconductor substrate;
forming a floating gate electrode layer on the first dielectric layer;
etching two side surfaces in a gate length direction of each of the floating gate electrode layer and the first dielectric layer;
covering, with an dielectric film, the two side surfaces in the gate length direction of the first dielectric layer and at least portions of the two side surfaces in the gate length direction of the floating gate electrode layer, thereby forming a buried dielectric layer having an upper surface positioned between an upper surface and a bottom surface of the floating gate electrode layer;
forming a second dielectric layer on the floating gate electrode layer and the buried dielectric layer, the forming the second dielectric layer comprising:
forming a lower dielectric film mainly containing silicon and nitrogen;
forming an intermediate dielectric film on the lower dielectric film; and
forming an upper dielectric film mainly containing silicon and nitrogen on the intermediate dielectric film;
forming a control gate electrode layer on the second dielectric layer;
etching two side surfaces in a gate width direction of each of the first dielectric layer, the floating gate electrode layer, the second dielectric layer, and the control gate electrode layer; and
forming, by oxidation, a first silicon oxide film in an interface between the control gate electrode layer and the upper dielectric film.
22. A method according to claim 21 , wherein a corner of the control gate electrode layer, which is formed along the gate width direction and in contact with the first silicon oxide film is rounded.
23. A method according to claim 21 , wherein the intermediate dielectric film is a silicon oxide film.
24. A method according to claim 21 , wherein forming the intermediate dielectric film comprises:
forming a silicon oxide film;
forming an dielectric film mainly containing silicon and nitrogen on the silicon oxide film; and
forming another silicon oxide film on the dielectric film mainly containing silicon and nitrogen.
25. A method according to claim 21 , further comprising, before the oxidation, wet-etching the upper dielectric film to make a width in the gate length direction of the upper dielectric film smaller than a width in the gate length direction of the control gate electrode layer.
26. A method according to claim 21 , wherein the oxidation is one of oxidation executed in one of a steam ambient and an oxygen ambient, and plasma oxidation.
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US11/785,694 US7772636B2 (en) | 2006-04-21 | 2007-04-19 | Nonvolatile semiconductor memory device with multilayer interelectrode dielectric film |
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JP2010283127A (en) * | 2009-06-04 | 2010-12-16 | Toshiba Corp | Semiconductor device and method of manufacturing the same |
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US7772636B2 (en) | 2010-08-10 |
KR100949216B1 (en) | 2010-03-24 |
JP4751232B2 (en) | 2011-08-17 |
US20070249120A1 (en) | 2007-10-25 |
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