US20090320368A1 - Methods and Systems for Gasifying a Process Stream - Google Patents

Methods and Systems for Gasifying a Process Stream Download PDF

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US20090320368A1
US20090320368A1 US12/295,099 US29509907A US2009320368A1 US 20090320368 A1 US20090320368 A1 US 20090320368A1 US 29509907 A US29509907 A US 29509907A US 2009320368 A1 US2009320368 A1 US 2009320368A1
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chamber
process stream
carbon monoxide
gasification
hydrogen
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Marco J. Castaldi
John P. Dooher
Klaus S. Lackner
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John P Dooher Trust
Columbia University in the City of New York
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Assigned to THE TRUSTEES OF COLUMBIA UNIVERSITY IN THE CITY OF NEW YORK reassignment THE TRUSTEES OF COLUMBIA UNIVERSITY IN THE CITY OF NEW YORK ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: CASTALDI, MARCO J., LACKNER, KLAUS S.
Assigned to JOHN P. DOOHER TRUST reassignment JOHN P. DOOHER TRUST ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: DOOHER, JOHN P.
Assigned to JOHN P. DOOHER TRUST reassignment JOHN P. DOOHER TRUST CORRECTIVE ASSIGNMENT TO CORRECT THE APPLICATION NUMBER 12295009 WHICH SHOULD BE 12295099 PREVIOUSLY RECORDED AT REEL: 060944 FRAME: 0599. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Assignors: DOOHER, JOHN P.
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/501Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
    • C01B3/503Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion characterised by the membrane
    • C01B3/505Membranes containing palladium
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/82Gas withdrawal means
    • C10J3/84Gas withdrawal means with means for removing dust or tar from the gas
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0643Gasification of solid fuel
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H01M8/0668Removal of carbon monoxide or carbon dioxide
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0662Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H01M8/0681Reactant purification by the use of electrochemical cells
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    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0283Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405Purification by membrane separation
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042Purification by adsorption on solids
    • C01B2203/043Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
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    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/047Composition of the impurity the impurity being carbon monoxide
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    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/0495Composition of the impurity the impurity being water
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/86Carbon dioxide sequestration
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2200/00Details of gasification apparatus
    • C10J2200/09Mechanical details of gasifiers not otherwise provided for, e.g. sealing means
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    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/0916Biomass
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    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/093Coal
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    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0969Carbon dioxide
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    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0973Water
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    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/12Heating the gasifier
    • C10J2300/1215Heating the gasifier using synthesis gas as fuel
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    • C10J2300/00Details of gasification processes
    • C10J2300/12Heating the gasifier
    • C10J2300/1223Heating the gasifier by burners
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    • C10J2300/00Details of gasification processes
    • C10J2300/12Heating the gasifier
    • C10J2300/1246Heating the gasifier by external or indirect heating
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    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1643Conversion of synthesis gas to energy
    • C10J2300/1646Conversion of synthesis gas to energy integrated with a fuel cell
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    • C10J2300/00Details of gasification processes
    • C10J2300/18Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1807Recycle loops, e.g. gas, solids, heating medium, water
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/16Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • Y02E20/18Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry

Definitions

  • FIG. 1 is a schematic diagram of a system according to some embodiments of the disclosed subject matter
  • gasification chamber 76 When operating with coal, slagging issues can be at least partially addressed orienting gasification chamber 76 in a particular manner. For example, if the ash fusion temperature is below 1000 degrees Celsius, gasification chamber 76 can be designed in a vertical configuration to allow slag to run down the walls. However, most coals can have ash fusion temperatures well above 1000 degrees Celsius. If this is the case, although ash deposition on surfaces (not shown) of gasification chamber 76 can cause problems, there are certain effects that will limit the amount of ash that is deposited to the surfaces of one or more tubes 75 . First, since the walls are hot and the core gas is cold, a driving force will push the particles (ash) toward the center (also known as the Soret effect).
  • the heat transfer across the catalyst support and the metal substrate can be nearly 1000 times faster than the heat transfer that occurs across the momentum boundary layer. Calculations indicate that the primary mechanism of heat transfer from the metal surface to the gasification reaction likely occurs via radiation.
  • the coal particles which can be considered a black body, can be maintained at a temperature close to that of the gasification reaction conditions, i.e., approximately 600K, while the surface of the metal substrate can be nearly 1200K. Hence, there can be a considerable driving force for radiative heat transfer.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Manufacturing & Machinery (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Industrial Gases (AREA)
US12/295,099 2006-03-31 2007-03-30 Methods and Systems for Gasifying a Process Stream Abandoned US20090320368A1 (en)

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Application Number Priority Date Filing Date Title
US12/295,099 US20090320368A1 (en) 2006-03-31 2007-03-30 Methods and Systems for Gasifying a Process Stream

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Application Number Priority Date Filing Date Title
US78823806P 2006-03-31 2006-03-31
US84606306P 2006-09-20 2006-09-20
US12/295,099 US20090320368A1 (en) 2006-03-31 2007-03-30 Methods and Systems for Gasifying a Process Stream
PCT/US2007/008033 WO2007123776A2 (fr) 2006-03-31 2007-03-30 Procédés et systèmes pour la gazéification d'un flux à traiter

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US20090320368A1 true US20090320368A1 (en) 2009-12-31

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US (1) US20090320368A1 (fr)
EP (1) EP2007674A4 (fr)
AU (1) AU2007240969B2 (fr)
WO (1) WO2007123776A2 (fr)

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US20090173079A1 (en) * 2008-01-07 2009-07-09 Paul Steven Wallace Method and apparatus to facilitate substitute natural gas production
US20090173081A1 (en) * 2008-01-07 2009-07-09 Paul Steven Wallace Method and apparatus to facilitate substitute natural gas production
US20090173080A1 (en) * 2008-01-07 2009-07-09 Paul Steven Wallace Method and apparatus to facilitate substitute natural gas production
US20100319537A1 (en) * 2007-05-21 2010-12-23 Peter Eisenberger System and Method for Removing Carbon Dioxide from an Atmosphere and Global Thermostat Using the Same
US20110094159A1 (en) * 2007-12-20 2011-04-28 Moeller Roland Method and Device for Reprocessing CO2 Containing Exhaust Gases
US8500858B2 (en) 2007-05-21 2013-08-06 Peter Eisenberger Carbon dioxide capture/regeneration method using vertical elevator
US8500857B2 (en) 2007-05-21 2013-08-06 Peter Eisenberger Carbon dioxide capture/regeneration method using gas mixture
US8500855B2 (en) 2010-04-30 2013-08-06 Peter Eisenberger System and method for carbon dioxide capture and sequestration
US20140209447A1 (en) * 2011-09-01 2014-07-31 Guradoor, S.L. Gasification-pyrolysis dual reactor device
US9028592B2 (en) 2010-04-30 2015-05-12 Peter Eisenberger System and method for carbon dioxide capture and sequestration from relatively high concentration CO2 mixtures
US9427726B2 (en) 2011-10-13 2016-08-30 Georgia Tech Research Corporation Vapor phase methods of forming supported highly branched polyamines
DE102015117574A1 (de) * 2015-10-01 2017-04-06 L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Verfahren und Anlage zur Erzeugung von Synthesegas mit variabler Zusammensetzung
US9908080B2 (en) 2007-05-21 2018-03-06 Peter Eisenberger System and method for removing carbon dioxide from an atmosphere and global thermostat using the same
US9925488B2 (en) 2010-04-30 2018-03-27 Peter Eisenberger Rotating multi-monolith bed movement system for removing CO2 from the atmosphere
EP3757193A1 (fr) * 2019-06-11 2020-12-30 Hydrogen Prozess Technik GbR Procédé et système de traitement des boues d'épuration, des résidus de fermentation et/ou du lisier permettant d'obtenir de l'hydrogène
US11059024B2 (en) 2012-10-25 2021-07-13 Georgia Tech Research Corporation Supported poly(allyl)amine and derivatives for CO2 capture from flue gas or ultra-dilute gas streams such as ambient air or admixtures thereof
US11286436B2 (en) * 2019-02-04 2022-03-29 Eastman Chemical Company Feed location for gasification of plastics and solid fossil fuels
US11447576B2 (en) 2019-02-04 2022-09-20 Eastman Chemical Company Cellulose ester compositions derived from recycled plastic content syngas

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GB0625156D0 (en) 2006-12-16 2007-01-24 Keld Energy Ltd Processing Biomass
SE533049C2 (sv) * 2008-06-12 2010-06-15 Cortus Ab Förfarande och anläggning för framställning av vätgas från biomassa
JP4898759B2 (ja) * 2008-10-22 2012-03-21 三菱重工業株式会社 石炭ガス化炉
US20100129691A1 (en) * 2008-11-26 2010-05-27 Good Earth Power Corporation Enhanced product gas and power evolution from carbonaceous materials via gasification
JP5572855B2 (ja) * 2009-03-24 2014-08-20 昭和シェル石油株式会社 バイオマスガス化改質触媒及びこれを用いた合成ガスの製造方法
EP2584023A1 (fr) * 2011-10-21 2013-04-24 Neste Oil Oyj Procédé de production de composition de gaz de synthèse
US9181502B2 (en) * 2012-07-09 2015-11-10 Southern Company Gasification of high ash, high ash fusion temperature bituminous coals
FR2994980B1 (fr) * 2012-09-05 2014-11-14 Commissariat Energie Atomique Procede de gazeification de charge de matiere carbonee, a rendement ameliore.
US10570348B2 (en) 2017-01-15 2020-02-25 Wormser Energy Solutions, Inc. All-steam gasification for supercritical CO2 power cycle system
US11572518B2 (en) 2019-11-25 2023-02-07 Wormser Energy Solutions, Inc. Char preparation system and gasifier for all-steam gasification with carbon capture
CN112852449B (zh) * 2020-12-24 2022-01-28 阿拉善盟正杰工程建设有限公司 一种荒煤烟气二次利用的炭化炉
CN114045181A (zh) * 2021-10-28 2022-02-15 西安热工研究院有限公司 一种旋风式生物质半气化实验装置

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