US20090314622A1 - Oil extraction device for pyrolysis of plastics waste material and extraction method thereof - Google Patents

Oil extraction device for pyrolysis of plastics waste material and extraction method thereof Download PDF

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Publication number
US20090314622A1
US20090314622A1 US12/442,250 US44225009A US2009314622A1 US 20090314622 A1 US20090314622 A1 US 20090314622A1 US 44225009 A US44225009 A US 44225009A US 2009314622 A1 US2009314622 A1 US 2009314622A1
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Prior art keywords
gas
pyrolysis chamber
rotating
primary pyrolysis
oil
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US12/442,250
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English (en)
Inventor
Yong Sup Joo
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PULSE ENERGY CO Ltd
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PULSE ENERGY CO Ltd
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Assigned to PULSE ENERGY CO., LTD. reassignment PULSE ENERGY CO., LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: JOO, YONG SUP
Publication of US20090314622A1 publication Critical patent/US20090314622A1/en
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/80—Destroying solid waste or transforming solid waste into something useful or harmless involving an extraction step
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
    • C10B57/02—Multi-step carbonising or coking processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/002—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/40—Destroying solid waste or transforming solid waste into something useful or harmless involving thermal treatment, e.g. evaporation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
    • B29B17/02—Separating plastics from other materials
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B47/00—Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion
    • C10B47/28—Other processes
    • C10B47/30—Other processes in rotary ovens or retorts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/07—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of solid raw materials consisting of synthetic polymeric materials, e.g. tyres
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/04—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by extraction
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/10—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • F23G5/027—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/06—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2209/00—Specific waste
    • F23G2209/28—Plastics or rubber like materials
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2900/00—Special features of, or arrangements for incinerators
    • F23G2900/50205—Waste pre-treatment by pyrolysis, gasification or cracking followed by condensation of gas into combustible oil or fat
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/143—Feedstock the feedstock being recycled material, e.g. plastics

Definitions

  • the present invention relates to an oil extraction system and method for pyrolyzing waste plastic materials, and more particularly, to an oil extraction system and method for producing oil from industrial wastes such as waste plastic materials and waste Styrofoam, by pyrolyzing the industrial wastes in a pyrolysis chamber of a furnace, condensing gas produced by pyrolysis, and separating oil and water.
  • the oil extraction system according to the present invention improves efficiency of gas collection in a pyrolysis process, and thereby oil production efficiency and thereby increasing economical efficiency.
  • a waste treatment system disclosed in Korean Patent Publication No. 1995-7048 has the following configuration.
  • a waste decomposition furnace is configured with an inner furnace and an outer furnace.
  • the inner furnace is installed to rotate with an axis of a double hollow shaft (inner and outer).
  • One end of the double hollow shaft is connected to a reprocessing and collecting unit that is successively connected to an adsorption chamber containing active carbon, gas neutralization chamber containing neutralizing agent, and cooling chamber by using pipes.
  • Gas pyrolyzed from wastes in the inner furnace is filtered, neutralized, and cooled while passing the above chambers.
  • the outer furnace is formed in the outside of the inner furnace, and has a burning room formed at its bottom, a flue formed in a zigzag shape on the top of the outer furnace, and a cooling water jacket formed around the flue.
  • the flue is connected to the adsorption chamber through a duct and one end of the adsorption chamber is connected to the gas neutralization chamber through a transport duct such that gas produced by the burning room is neutralized in the gas neutralization chamber and exhausted to the outside.
  • a gas supply line is installed between the burning room and cooling chamber to supply the pyrolyzed gas into the burning room as a substitutive fuel.
  • the pyrolyzed gas is transported to the reprocessing and collecting unit through a plurality of holes formed at the outer hollow shaft.
  • films are formed in the holes by rotation of the outer hollow shaft while the inner furnace is rotated by a reduction motor, and the holes become blocked by the films. Accordingly, gas is not smoothly exhausted and oil extraction yield is decreased.
  • An oil extraction system using waste plastic materials disclosed in Korean Patent No. 0486159 is configured with: a transport screw for transporting crushed waste plastic materials contained in a hopper by a motor; a reactor for producing gas containing oil from the waste plastic materials by heating the reactor with a burner; a cooling tower for cooling the gas containing oil; a primary filtering device; a catalyst tower for deodorizing and decolorizing; and a secondary filtering device.
  • a pre-melting device is installed between the transport screw and reactor to convert the crushed waste plastic materials into a half-melt state by heating, which is to be transported to the reactor.
  • this patent has a problem that gas containing oil is partially lost in the step of pre-melting the waste plastic materials. That is, gas is partially lost in the step of pre-melting and compressing the waste plastic materials such as Styrofoam and vinyl, and in the step of pyrolyzing the waste plastic materials. Therefore, oil extraction yield is decreased.
  • the conventional waste treatment systems generally have a huge size.
  • the volume of gas produced by pyrolyzing waste materials is relatively small and efficiency of collecting the pyrolyzed gas for reprocessing is low, and thereby economical efficiency of the waste treatment facility becomes low.
  • hundreds of waste treatment systems were registered or applied for Korean patent, there is almost no waste treatment system practically running now. This means that most of the waste treatment systems registered or applied for Korean patents are not economical yet.
  • the present invention has been made in view of the above problems, and an object of the present invention is to improve economical efficiency in an oil extraction system for pyrolyzing industrial waste materials such as waste plastic materials and waste Styrofoam, by pyrolyzing the waste materials in a pyrolysis chamber of a furnace, producing gas, efficiently collecting the pyrolyzed gas, condensing the gas, and separating oil and water.
  • industrial waste materials such as waste plastic materials and waste Styrofoam
  • Another object of the present invention is to reduce costs in waste treatment of waste plastic materials.
  • Another object of the present invention is to prevent environmental pollution of soil and air by avoiding landfill and incineration.
  • Another object of the present invention is to reduce import of energy sources in oil importing countries.
  • an oil extraction system includes: a waste feeding device for supplying waste plastic materials contained in a hopper to a primary pyrolysis chamber (referred to ‘reactor’) through a feed inlet, the primary pyrolysis chamber pyrolyzing the supplied waste plastic materials; a double jacket furnace having a burner and for heating the primary pyrolysis chamber loaded in a burning room of the furnace; a rotation device for rotating the primary pyrolysis chamber loaded in the burning room of the furnace; a secondary pyrolysis chamber for re-pyrolyzing gas produced by the primary pyrolysis chamber, and for separating carbides and residue; a condenser for liquefying the gas separated from the secondary pyrolysis chamber by condensing and forming mixture of produced oil and water; and an oil-water separator for separating the produced oil and water condensed in the condenser.
  • a waste feeding device for supplying waste plastic materials contained in a hopper to a primary pyrolysis chamber (referred to ‘reactor’) through a feed
  • An oil extraction method utilizes the above oil extraction system to efficiently produce oil from industrial waste materials such as waste plastic materials and waste Styrofoam.
  • waste treatment costs of waste plastic materials may be reduced, environmental pollution of soil and air may be prevented by avoiding landfill and incineration, import of energy sources may be reduced in oil importing countries, and gas suction rate and oil extraction yield may be improved by sucking a large amount of produced gas by using gas suction pipes formed with bent ends in the primary pyrolysis chamber.
  • FIG. 1 is a view showing a configuration of an oil extraction system according to an exemplary embodiment of the present invention
  • FIG. 2 is a view showing a configuration of a waste feeding device and a carbide collecting device according to the exemplary embodiment of the present invention
  • FIG. 3 is a view showing a configuration of a primary pyrolysis chamber located in a furnace according to the exemplary embodiment of the present invention
  • FIG. 4 is a side view showing an outer configuration of the furnace of FIG. 3 ;
  • FIG. 5 is a sectional view showing an inner configuration of the furnace of FIG. 3 ;
  • FIG. 6 is a view showing a configuration of a rotation device for rotating the primary pyrolysis chamber of FIG. 3 ;
  • FIG. 7 is view showing a configuration of shaft brackets for supporting the rotation device of FIG. 6 ;
  • FIG. 8 is a view showing a secondary pyrolysis chamber for re-pyrolyzing gas produced by the primary pyrolysis chamber of FIG. 3 ;
  • FIG. 9 is a view showing a configuration of a carrier for moving the primary pyrolysis chamber of FIG. 3 on rails;
  • FIG. 10 is a view showing a connection state of a gas exhaust tube of the primary pyrolysis chamber of FIG. 3 and a rotating gas tube of the rotation device of FIG. 6 ;
  • FIG. 11 is a block diagram showing a pyrolyzing process according to an exemplary embodiment of present invention.
  • FIG. 12 is a more detailed block diagram showing a pyrolyzing process of FIG. 11 .
  • An oil extraction system for pyrolyzing waste plastic materials includes: a waste feeding device 10 and a carbide collecting device 10 ′ for feeding wastes collected in a hopper 11 and collecting residual carbides respectively; a primary pyrolysis chamber 20 for pyrolyzing the waste, that can be loaded on the top of a carrier 25 ′ moving on rails 25 and be coupled with an outer surface of a gas exhaust tube 22 ; a furnace 30 having a burning room formed for receiving the primary pyrolysis chamber 20 , a burner for heating the primary pyrolysis chamber 20 , and a double jacket body 31 ; a rotation device 40 for rotating the primary pyrolysis chamber 20 located in the burning room of the furnace 30 by connecting the primary pyrolysis chamber 20 to a rotating gas tube 42 ; and a secondary pyrolysis chamber 50 for receiving gas produced by the primary pyrolysis chamber 20 through the rotating gas tube 42 , re-pyrolyzing the gas, separating the gas and carbide particles, and preventing back
  • the waste feeding and carbide collecting device includes: a waste feeding device 10 configured with a hopper 11 having a hydraulic cylinder 12 a and a feed tube 12 b at the bottom of the hopper 11 and installed on the top of a supporting fixture 13 ; a reactor rotating device 17 installed in a middle level of the supporting fixture 13 and having hydraulic cylinders 17 a fixed to the supporting fixture 13 by a fixing pin 17 b ; and a carbide collecting device 10 ′ located at the bottom of the supporting fixture 13 and having a carbide discharge tube 14 , collector 15 a , screen filter 15 b , and blower 16 .
  • the primary pyrolysis chamber 20 includes: rotating rollers 23 and 23 ′ installed at two sides of the gas exhaust tube 22 ; a plurality of gas suction pipes 24 for sucking gas, and formed on the surface of the gas exhaust tube 22 and between the rotating rollers 23 and 23 ′; a cylindrical body containing the plurality of gas suction pipes 24 therein and a slope 21 formed in a side of its inner space.
  • a plurality of connecting pins 26 a are formed at one side surface of a gas exhaust tube flange 26 of the primary pyrolysis chamber 20 and protrude outwards from the gas exhaust tube flange 26 , and two hooking grooves 26 b are formed at two edges in the other side surface of the gas exhaust tube flange 26 .
  • the plurality of gas suction pipes 24 are formed by piercing the circumferential surface of the gas exhaust tube 22 , and the inlet 24 ′ of the gas suction pipe 24 is formed as a slope to maximize a suction rate and is equipped with a metal screen.
  • the furnace preferably includes: a burning room whose inner walls are formed with firebricks 34 ; a burner 33 installed at one side of the burning room; a double jacket body 31 for containing water; a water supply pipe 37 a and a water drain pipe 37 b installed at the upper side and lower side of the double jacket body 31 respectively; flues 35 installed at the top of the double jacket body 31 and connected to the burning room; and a door 32 a and an auxiliary door 32 b formed at the front and rear of the furnace respectively.
  • the rails 25 are preferably installed between the carbide collecting device 10 ′ and the inside of the furnace 30 .
  • the rotation device 40 includes a chain gear 43 installed at the circumferential surface of the rotating gas tube 42 and installed in the middle between shaft brackets 41 and 41 ′; the chain gear 43 is driven by a motor 44 via a chain; and one end of the rotating gas tube 42 is connected to the gas exhaust tube 22 of the primary pyrolysis chamber 20 and the other end of the rotating gas tube 42 is rotatively connected to a connecting tube 46 of the secondary pyrolysis chamber 50 .
  • the shaft brackets 41 and 41 ′ are preferably formed as upper and lower brackets having a pair of bushings 41 a to sustain the rotating gas tube 42 and a lubrication inlet is formed at the upper surface of the upper bracket.
  • the rotating gas tube 42 preferably includes: a rotating gas tube flange 47 formed at its one end; a plurality of hooking grooves 26 b formed at one side surface of the rotating gas tube flange 47 , to which connecting pins 26 a are inserted; linkages 47 b formed at the upper and lower circumferential positions of the rotating gas tube flange 47 , wherein one end of the linkage 47 b is connected to a hinged pin and the other end of the linkage 47 b is connected to an end of a hydraulic cylinder 47 c and locking hook 47 d . The other end of the hydraulic cylinder 47 c is connected to the rotating gas tube 42 .
  • the rotating gas tube 42 and connecting tube 46 are connected to each other such that the rotating gas tube 42 may rotate freely and the connecting tube 46 remains in a fixed position, and an O-ring 48 a and lubrication packings 48 are formed inside the connection part.
  • the secondary pyrolysis chamber 50 preferably includes a plurality of porous heating plates 51 , a connecting tube 46 having a backflow prevention device 54 , a residue collector 53 and an ash removal valve 52 formed at the bottom of the residue collector 53 , and a catalyst stack 55 formed at the upper part of the secondary pyrolysis chamber 50 .
  • the secondary pyrolysis chamber 50 is covered by a heat insulating material to prevent heat loss.
  • An oil extraction method for pyrolyzing waste plastic materials includes the steps of: crushing waste plastic materials containing waste plastics and waste Styrofoam, and feeding the crushed waste plastic materials into a hopper; settling a primary pyrolysis chamber to a reactor rotating device by lifting the primary pyrolysis chamber with a crane and by adjusting the position of the primary pyrolysis chamber with a hydraulic cylinder; supplying the waste plastic materials contained in the hopper into the primary pyrolysis chamber through a feed inlet; lifting the primary pyrolysis chamber with the crane, loading the primary pyrolysis chamber to a carrier located on rails, transporting the primary pyrolysis chamber into a burning room of a furnace, closing a door, and rotating and heating the primary pyrolysis chamber with a motor and a burner respectively; transporting gas produced by heating the waste plastic materials in the furnace of the primary pyrolysis chamber to a secondary pyrolysis chamber through gas suction pipes and re-pyrolyzing the gas in
  • waste plastic materials are sorted, crushed, and loaded into a hopper 11 of a waste feeding device 10 .
  • the waste plastic materials may be loaded into the hopper 11 by using a conveyor or screw system.
  • the waste plastic materials are crushed by a proper crushing device prior to loading into the hopper 11 .
  • the hopper 11 has an enclosed vessel and an air filter to prevent dust from flying.
  • the waste plastic materials are fed from the hopper 11 of the waste feeding device 10 into a primary pyrolysis chamber 20 .
  • the primary pyrolysis chamber 20 is carried by a carrier 25 ′ moving on rails 25 to the waste feeding device 10 , and is lifted to a reactor rotating device 17 by a crane. If the pyrolysis chamber 20 is rotated using a fixing pin 17 b as an axis by a hydraulic cylinder 17 a , the primary pyrolysis chamber 20 is located in a vertical state to locate an inlet of the primary pyrolysis chamber 20 to face the hopper 11 . If the primary pyrolysis chamber 20 is located in the vertical state, a feed tube 12 b of the flexible tube is inserted into the primary pyrolysis chamber 20 and the waste plastic materials are input into the primary pyrolysis chamber 20 .
  • the waste plastic materials are fed from the waste feeding device 10 into the primary pyrolysis chamber 20 .
  • the primary pyrolysis chamber 20 is lifted, located on a carrier 25 ′ on the rail 25 , pulled or pushed, and moved into a burning room of a furnace.
  • One end of the gas exhaust tube 22 of the primary pyrolysis chamber 20 is connected to the rotating gas tube 42 of the rotation device 40 .
  • a gas exhaust tube flange 26 of the primary pyrolysis chamber 20 is coupled to a rotating gas tube flange 47 of the rotation device 40 , connecting pins 26 a protruding from the gas exhaust tube flange 26 are inserted into insertion grooves 47 a of the rotating gas tube flange 47 , and one end of a locking hook 47 d is connected to an end of the linkage 47 b and the other end of the locking hook 47 d is hooked to a hooking groove 26 b of the gas exhaust tube flange 26 .
  • the linkages 47 b installed at the top and bottom of the rotating gas tube flange 47 are pulled by operating hydraulic cylinders 47 c installed at the rotating gas tube 42 and thereby the gas exhaust tube flange 26 is attached to the rotating gas tube flange 47 .
  • the gas exhaust tube flange 26 may be securely attached to the rotating gas tube flange 47 by the locking hook 47 d using the hydraulic cylinders 47 c or springs.
  • the gas exhaust tube flange 26 may be separated from the rotating gas tube flange 47 by pulling the linkage 47 b using the hydraulic cylinders and thereby releasing the locking hook 47 d.
  • a door 32 a of the furnace 30 is closed and the primary pyrolysis chamber 20 is heated by operating a burner 33 .
  • the primary pyrolysis chamber 20 While heating the primary pyrolysis chamber 20 by the burner 33 , the primary pyrolysis chamber 20 is rotated in the furnace 30 by rotating the rotation device 40 connected to primary pyrolysis chamber 20 through the rotating gas tube 42 .
  • the primary pyrolysis chamber 20 is located in the burning room of the furnace 30 .
  • Rotating rollers 23 and 23 ′ are installed on the gas exhaust tube 22 , and an end of the gas exhaust tube 22 is connected to the rotating gas tube 42 of the rotation device 40 .
  • the primary pyrolysis chamber 20 has the gas exhaust tube 22 connected to a plurality of gas suction pipes 24 located between the rotating rollers 23 and 23 ′, and a cylindrical body formed with a slope 21 at one side of the inner surface thereof. Waste plastic materials are melted and decomposed in the closed primary pyrolysis chamber 20 , and gas is produced.
  • Gas produced in the primary pyrolysis chamber 20 is discharged through the gas suction pipes 24 of the gas exhaust tube 22 .
  • the gas suction pipes 24 are bent to a direction, a slope is formed at an inlet 24 ′ of the gas suction pipe 24 and thereby increasing the size of inlet to which gas is sucked.
  • the gas suction pipes 24 are bent and rotate together with the gas exhaust tube 22 . A large amount of gas is sucked and moved to the secondary pyrolysis chamber 50 through the gas exhaust tube 22 .
  • the inlet of the gas suction pipes 24 is covered with a metal screen and thereby preventing residue of carbide to be sucked.
  • the metal screen is clogged due to soot, it may be cleaned after the primary pyrolysis chamber 20 is removed from the furnace.
  • the furnace 30 has a burning room having a predetermined space, and inner walls of the burning room are formed with firebricks 34 .
  • the burner 33 is installed at an outside of the burning room and the primary pyrolysis chamber 20 rotating in the burning room is heated by the burner 33 .
  • a body 31 of the furnace 30 is formed in a double jacket and filled with water in the double jacket, water supply pipe 37 a is formed at the upper surface of the body 31 to supply water to the jacket, water drain pipes 37 b are installed at both bottom side surfaces of the body 31 to drain water.
  • the cross section of the double jacket of the body 31 is formed in a shape of a horse's hoof.
  • Flues 35 are connected to the burning room at the top of the furnace 30 , filter is installed in the flue 35 , thereby discharging smoke from the burning room to the outside.
  • the smoke is combustion gas produced by the burner 33 , and is not gas produced by burning waste plastic materials.
  • a steam discharge tube 36 a is installed at an upper surface of the body 31 of the furnace to discharge steam produced by heating water in the jacket, and a safety valve 36 b is installed at an upper surface of the body 31 to automatically reduce steam pressure in case of emergency.
  • Various components are installed in the furnace 30 to check and control steam pressure and heating temperature, and are similar to those of conventional furnaces.
  • An auxiliary door 32 b is installed at the rear side of the furnace 30 to manage and maintain the furnace 30 .
  • a door 32 a of the furnace 30 may be opened or closed even in the case that rails 25 are installed at the bottom of the furnace 30 , and is configured to keep the burning room to be closed.
  • the primary pyrolysis chamber 20 in the burning room of the furnace 30 is rotated by the rotation device 40 connected thereto, the rotation device 40 is installed with a chain gear 43 attached to the rotating gas tube 42 between shaft brackets 41 and 41 ′, and the chain gear 43 is driven by a motor 44 via a chain to drive the rotation device 40 .
  • the rotation device 40 may be driven by other methods different from the chain gear.
  • the O-ring 48 a and lubrication packings 48 are installed to keep a connection unit of the connecting tube 46 airtight for connecting the rotating gas tube 42 of the rotation device 40 and secondary pyrolysis chamber 50 .
  • the connecting tube 46 is not rotating and the rotating gas tube 42 is rotated to rotate the primary pyrolysis chamber 20 .
  • Gas is produced from waste plastic materials in the primary pyrolysis chamber 20 heated by the furnace 30 , and is fed to the secondary pyrolysis chamber 50 by passing through the gas suction pipes 24 , gas exhaust tube 22 , rotating gas tube 42 of the rotation device 40 , and connecting tube 46 .
  • a backflow prevention device 54 is installed between connecting tube 46 and the secondary pyrolysis chamber 50 to prevent backflow of gas from the secondary pyrolysis chamber 50 .
  • Gas produced in the primary pyrolysis chamber 20 is heated again in the secondary pyrolysis chamber 50 to pyrolyze and separate carbide particles (carbon), un-decomposed residues and gas.
  • Gas produced in the primary pyrolysis chamber 20 is a mixture of carbide and un-decomposed residues, and may clog a transport path or lowering quality of produced oil.
  • a plurality of heating plates 51 are installed inside the secondary pyrolysis chamber 50 at a predetermined interval, and an ash removal valve 52 and residue collector 53 are installed at the lower part of the secondary pyrolysis chamber 50 .
  • Gas fed to the secondary pyrolysis chamber 50 is heated and decomposed by the heating plates 51 , carbide and residues are collected by a residue collector 53 , decomposed gas is separated and is fed to a condenser 60 by suction of a blower 56 .
  • Ash collected in the residue collector 53 is disposed of afterwards.
  • a blower 56 moves gas from the primary pyrolysis chamber 20 to the secondary pyrolysis chamber 50 , and moves gas from the secondary pyrolysis chamber 50 rapidly to the condenser 60 to prevent explosion of gas due to long retention time.
  • Various gauges, monitoring window and drain valve are installed to manage and control the secondary pyrolysis chamber 50 , using a method similar to conventional methods.
  • a catalyst stack 55 is installed at the upper part of the secondary pyrolysis chamber 50 to remove chlorine gas and easily solidified wax.
  • the catalyst stack 55 neutralizes toxic gas produced during decomposition of waste plastic materials, and thereby improving quality of produced oil.
  • Gas separated from carbide and residue in the secondary pyrolysis chamber 50 is fed to the condenser 60 by the blower 56 , and is liquefied in the condenser 60 .
  • the condenser 60 may be a conventional condenser that liquefies gas, and the liquefied gas is fed to an oil-water separator 70 . Uncondensed gas is fed to a gas reserve tank 80 through a pipe, and gas in the gas reserve tank is supplied to the burner 33 of the furnace 30 .
  • Liquefied oil in the condenser 60 is separated into refined oil and water by a filter of the oil-water separator 70 and is stored in an oil reserve tank.
  • the oil-water separator 70 separates oil and water from condensed oil, water is collected in a water tank, and refined oil is collected in the oil reserve tank. Gas that is not separated in the condenser 60 is separated again and fed to the gas reserve tank.
  • FIG. 1 is a view showing a configuration of an oil extraction system according to an exemplary embodiment of the present invention.
  • the oil extraction system has the following steps: loading waste plastic materials to a hopper 11 and feeding the waste plastic materials to a primary pyrolysis chamber 20 through a feed tube, in a waste feeding device 10 ⁇ pyrolyzing the fed waste plastic materials in the primary pyrolysis chamber 20 that is operating as a reactor ⁇ heating the primary pyrolysis chamber 20 in a burning room of a furnace 30 formed with a double jacket shape with a burner 33 ⁇ rotating the primary pyrolysis chamber 20 by a rotation device 40 ⁇ pyrolyzing gas produced in the primary pyrolysis chamber 20 and separating gas, carbide and residues, in a secondary pyrolysis chamber 50 ⁇ condensing gas separated in the secondary pyrolysis chamber 50 to produce reproduced oil in a condenser 60 ⁇ separating refined oil and water from the reproduced oil condensed in the condenser 60 , in a oil-water separator 70 .
  • FIG. 2 is a view showing a configuration of a waste feeding device and a carbide collecting device according to the exemplary embodiment of the present invention.
  • waste plastic materials in the hopper 11 are fed into the primary pyrolysis chamber 20 through a feed tube 12 b at the bottom of the hopper 11 , after the primary pyrolysis chamber 20 is lifted to the reactor rotating device 17 by a crane.
  • a door 32 a of the furnace 30 is opened, and the primary pyrolysis chamber 20 on rails 25 is pulled and moved towards a carbide collecting device 10 ′.
  • the primary pyrolysis chamber 20 is rotated by hydraulic cylinders 17 a of the reactor rotating device 17 , and carbide in the primary pyrolysis chamber 20 is collected in the carbide collecting device 10 ′.
  • the carbide collecting device 10 ′ includes a carbide discharge tube 14 moved by hydraulic cylinders on the carbide collecting device 10 ′ and a carbide collector 15 a under the carbide discharge tube 14 .
  • a screen filter 15 b is installed at the bottom of the carbide collector 15 a , and filters foreign materials such as iron and stone.
  • the bottom of the carbide collector 15 a is connected to a blower 16 through a pipe, the carbide in the primary pyrolysis chamber 20 is transported to the carbide collector 15 a , and the carbide in the carbide collector 15 a is discharged to a treatment facility through a carbide discharge tube.
  • the carbide in the primary pyrolysis chamber 20 is discharged by being slid by a slope 21 formed in the inside of the primary pyrolysis chamber 20 .
  • FIG. 3 is a view showing a configuration of a primary pyrolysis chamber located in a furnace according to the exemplary embodiment of the present invention.
  • a gas exhaust tube 22 is connected to gas suction pipes 24 , the primary pyrolysis chamber 20 is formed in a cylinder shape in the outside of the gas exhaust tube 22 , and a slope 21 is formed in the inner side of the primary pyrolysis chamber 20 to easily remove carbide.
  • Rotating rollers 23 and 23 ′ are installed at two sides of the gas exhaust tube 22 to smoothly rotate the primary pyrolysis chamber 20 .
  • the rotating rollers 23 and 23 ′ are located fixedly in the burning room of the furnace 30 to support the primary pyrolysis chamber 20 in the air.
  • FIG. 4 is a side view showing an outer configuration of the furnace of FIG. 3 .
  • two flues 35 , steam discharge tube 36 a , and safety valve 36 b are installed on the top of a body 31 of the furnace 30 , and a door 32 a and auxiliary door 32 b are installed in two opposite sides of the body of the furnace 30 .
  • FIG. 5 is a sectional view showing an inner configuration of the furnace of FIG. 3 .
  • the body of the furnace 30 is formed in a double jacket, and firebricks 34 are attached on the inner wall of the burning room in which the primary pyrolysis chamber 20 is located.
  • a burner 33 is installed in the outside of the burning room.
  • the burner 33 is ignited by using gas stored separately for an initial operation, and gas that is produced in the primary pyrolysis chamber 20 and left after condensing in the condenser may be supplied to the burner 33 .
  • the furnace 30 has a double jacket body in which water is contained, water supply pipe and discharge tube. Various gauges and components are installed to operate the furnace 30 .
  • FIG. 6 is a view showing a configuration of a rotation device for rotating the primary pyrolysis chamber of FIG. 3 .
  • one end of a rotating gas tube 42 is connected to the gas exhaust tube 22 of the primary pyrolysis chamber 20 , and the other end of the rotating gas tube 42 is connected to a connecting tube 46 of the secondary pyrolysis chamber 50 .
  • the rotating gas tube 42 is supported by shaft brackets 41 and 41 ′, and the shaft brackets 41 and 41 ′ are fixed on a support 45 .
  • a chain gear 43 is installed on the rotating gas tube 42 , and driven by a motor 44 mounted on the support 45 .
  • the motor 44 and chain gear 43 are connected by a chain.
  • a rotation device 40 is covered by a rotation device cover 49 to protect the shaft brackets and chain gear from external environment such as rain and snow.
  • a plurality of insertion grooves 47 a to which connecting pins 26 a are inserted are formed in one side of the rotating gas tube flange 47 of the rotating gas tube 42 connected to the primary pyrolysis chamber 20 , ends of linkages 47 b are connected by hinged pins at the top and bottom of the rotating gas tube flange 47 , and another ends of the linkages 47 b are connected to hydraulic cylinders 47 c and locking hooks 47 d.
  • the gas exhaust tube flange 26 of the gas exhaust tube 22 in the primary pyrolysis chamber 20 is contacted to the rotating gas tube flange 47 of the rotation device 40 .
  • the connecting pins 26 a protruding from the gas exhaust tube flange 26 are inserted into the insertion grooves 47 a of the rotating gas tube flange 47 .
  • the locking hook 47 d to which one end of the linkage 47 b is connected is hooked to the hooking groove 26 b of the gas exhaust tube flange 26 , and is tightened by hydraulic cylinders 47 c installed on the rotating gas tube 42 .
  • FIG. 7 is a view showing a configuration of shaft brackets for supporting the rotation device of FIG. 6 .
  • shaft brackets 41 and 41 ′ are fixed on the support 45 of the rotation device 40 to support the rotating gas tube 42 .
  • the shaft brackets 41 and 41 ′ support two sides of the rotating gas tube 42 to provide smooth rotation of the rotating gas tube 42 .
  • FIG. 8 is a view showing a secondary pyrolysis chamber for re-pyrolyzing gas produced by the primary pyrolysis chamber of FIG. 3 .
  • a secondary pyrolysis chamber 50 has a cylindrical chamber in the vertical direction.
  • a catalyst stack 55 is installed at the upper part of the secondary pyrolysis chamber 50 , and a plurality of heating plates 51 having a ring shape are installed at predetermined intervals in the middle of the secondary pyrolysis chamber 50 .
  • the distances between the heating plates 51 depends on a capacity of the secondary pyrolysis chamber 50 .
  • the heating plates 51 are heated to pyrolyze produced gas, and have a plurality of holes for gas to move upwards and for carbide and residue to fall into a residue collector 53 due to their weight.
  • An ash removal valve 52 is installed at a side of the residue collector 53 to open and close the residue collector 53 for discharging collected carbide and residue.
  • a backflow prevention device 54 is installed between the secondary pyrolysis chamber 50 and connecting tube 46 to prevent gas in the secondary pyrolysis chamber 50 from backflowing into the primary pyrolysis chamber 20 due to pressure difference between the primary pyrolysis chamber 20 and secondary pyrolysis chamber 50 .
  • the catalyst stack 55 removes chlorine gas and wax having a high solidifying property from the re-pyrolyzed gas.
  • Waste plastic materials produce toxic gases during a pyrolyzing process, and the toxic gases are modified, neutralized and removed by the catalyst stack 55 , and thereby improving quality of produced oil.
  • a blower 56 on the top of the secondary pyrolysis chamber 50 rapidly transfers gas separated in the secondary pyrolysis chamber 50 to a condenser 60 to prevent expansion of the produced gas.
  • FIG. 9 is a view showing a configuration of a carrier for moving the primary pyrolysis chamber of FIG. 3 on rails.
  • a carrier 25 ′ is installed movably on the rails 25 , and the primary pyrolysis chamber 20 is placed on the carrier to easily push the primary pyrolysis chamber 20 into or pull the primary pyrolysis chamber 20 out of the furnace 30 and to easily locate the primary pyrolysis chamber 20 on the carrier 25 ′ when the primary pyrolysis chamber 20 lifted or lowered by a crane.
  • FIG. 10 is a view showing a connection state of a gas exhaust tube of the primary pyrolysis chamber of FIG. 3 and a rotating gas tube of the rotation device of FIG. 6 .
  • FIG. 11 is a block diagram showing a pyrolyzing process according to an exemplary embodiment of present invention.
  • FIG. 11 shows a flow diagram of an oil extraction system of FIG. 1 .
  • FIG. 12 is a more detailed block diagram showing a pyrolyzing process of FIG. 11 .
  • An oil extraction system pyrolyzes waste plastic materials produced in several industries to produce oil, and prevents environmental pollution.
  • Amount of products is calculated as follows.
  • oil of 1,724 L is produced from 2.5 ton of waste materials and production efficiency is high.
  • An oil extraction system can reduce energy consumption required to operate the system by using produced gas after using energy required for an initial operation.
  • waste treatment costs of waste plastic materials may be reduced, environmental pollution of soil and air may be prevented by avoiding landfill and incineration, import of energy sources may be reduced in oil importing countries, and gas suction rate and oil extraction yield may be improved by using gas suction pipes formed with bent inlets in a primary pyrolysis chamber.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Processing Of Solid Wastes (AREA)
US12/442,250 2006-09-26 2006-11-13 Oil extraction device for pyrolysis of plastics waste material and extraction method thereof Abandoned US20090314622A1 (en)

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KR1020060093547A KR100675909B1 (ko) 2006-09-26 2006-09-26 합성수지 폐기물 열분해 유화 장치 및 방법
KR10-2006-0093547 2006-09-26
PCT/KR2006/004726 WO2008038854A1 (en) 2006-09-26 2006-11-13 Oil extraction device for pyrolysis of plastics waste material and extraction method thereof

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WO2013015819A1 (en) * 2011-07-28 2013-01-31 Jbi Inc. System and process for converting plastics to petroleum products
CN103084381A (zh) * 2013-02-07 2013-05-08 施雄飞 纺织工业废污资源再生装置及方法
WO2015040256A1 (es) * 2013-09-17 2015-03-26 Huguet Farré Jordi I Procedimiento de eliminación de plásticos contenidos en residuos urbanos e industriales, e instalación para la puesta en practica del mismo
CH716009A1 (fr) * 2019-03-29 2020-09-30 Greenlina Sa Procédé de transformation par pyrolyse de déchets mélangés en matières plastiques et en caoutchoucs et dispositif pour la mise en oeuvre du procédé.
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US20110067992A1 (en) * 2009-09-21 2011-03-24 Byung Tae Yoon Apparatus for recovering styrene monomer and method of recovering styrene monomer using auxiliary solvent
US8449725B2 (en) * 2009-09-21 2013-05-28 Korea Research Institute Of Chemical Technology Apparatus for recovering styrene monomer and method of recovering styrene monomer using auxiliary solvent
WO2013015819A1 (en) * 2011-07-28 2013-01-31 Jbi Inc. System and process for converting plastics to petroleum products
US20170073584A1 (en) * 2011-07-28 2017-03-16 Jbi Inc. System and process for converting plastics to petroleum products
CN103084381A (zh) * 2013-02-07 2013-05-08 施雄飞 纺织工业废污资源再生装置及方法
WO2015040256A1 (es) * 2013-09-17 2015-03-26 Huguet Farré Jordi I Procedimiento de eliminación de plásticos contenidos en residuos urbanos e industriales, e instalación para la puesta en practica del mismo
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WO2020198890A1 (fr) * 2019-03-29 2020-10-08 Greenlina Sa Procédé de transformation par pyrolyse de déchets mélangés en matières plastiques et en caoutchoucs et dispositif pour la mise en oeuvre du procédé
CH716009A1 (fr) * 2019-03-29 2020-09-30 Greenlina Sa Procédé de transformation par pyrolyse de déchets mélangés en matières plastiques et en caoutchoucs et dispositif pour la mise en oeuvre du procédé.
WO2021076671A1 (en) 2019-10-14 2021-04-22 William Marsh Rice University Porous polymeric carbon sorbents for gas storage and methods of making and using same
WO2021076670A1 (en) 2019-10-14 2021-04-22 William Marsh Rice University Porous polymeric carbon sorbents for co2 capture and methods of making and using same
WO2021076672A1 (en) 2019-10-14 2021-04-22 William Marsh Rice University Porous polymeric carbon sorbents for direct air capture of co2 and methods of making and using same
CN113997459A (zh) * 2020-07-27 2022-02-01 广东沃府实业有限公司 基于plc智能控制再生塑料节能环保再生机
WO2022220828A1 (en) 2021-04-14 2022-10-20 William Marsh Rice University Porous polymeric carbon sorbents and methods of making and using same
CN113462421A (zh) * 2021-07-30 2021-10-01 重庆大学 一种熔融盐加热医疗废弃物或废旧塑料的热解方法
CN114135873A (zh) * 2021-12-31 2022-03-04 广州市通用新产品开发有限公司 一种一体式集成固体废物处理装置
CN116294610A (zh) * 2023-04-21 2023-06-23 东营联合石化有限责任公司 一种原料油反应加热炉

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JP2010505021A (ja) 2010-02-18
KR100675909B1 (ko) 2007-02-02
MX2009003238A (es) 2009-07-27
EP2081701A1 (en) 2009-07-29
CA2663556A1 (en) 2008-04-03
CN101528370A (zh) 2009-09-09
WO2008038854A1 (en) 2008-04-03
BRPI0621931A2 (pt) 2011-12-20

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