Classifications

• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
  • C10L1/00—Liquid carbonaceous fuels
  • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
  • C10L1/026—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
  • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
  • C10G2300/10—Feedstock materials
  • C10G2300/1011—Biomass
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
  • Y02E50/00—Technologies for the production of fuel of non-fossil origin
  • Y02E50/10—Biofuels, e.g. bio-diesel
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
  • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
  • Y02P30/00—Technologies relating to oil refining and petrochemical industry
  • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Definitions

• This invention relates to alternative fuel formulations including vegetable oil. More particularly the invention relates to vegetable oil fuel formulations in which glycerin does not have to be removed from raw vegetable.
• Biodiesel is an alternative fuel based on renewable resources, most commonly vegetable oil. Biodiesel itself contains no petroleum, but is typically blended with petroleum diesel to create a Biodiesel blend.
• Biodiesel is generally used to describe the output of a thermodynamic process where the glycerin component of vegetable oil is separated and removed from the ethyl or methyl esters of the source oil.
• the glycerin component of vegetable oil is normally considered a negative because its presence raises the viscosity and flash point of vegetable oil to levels that are incompatible with commonly used diesel engines.
• Biodiesel offers several benefits over typical fossil fuels. These benefits include cleaner burning and the fact that it can be produced from available renewable resources.
• Biodiesel however, also has many drawbacks. For example, the process of producing Biodiesel is capital intensive and time consuming. The Biodiesel process also has ecological negatives, primarily in the form of pollutant byproducts.
• the typical Biodiesel process begins by taking, for example, ten gallons of used vegetable oil.
• the oil is first filtered to remove food particulates in the oil.
• Methanol and lye are then added to the oil.
• the mixture is heated for a period of time, often several hours, to a temperature generally between 48 and 54 degrees C.
• the solution is then allowed to cool, generally for 8 hours or longer, during which the heavier glycerin component precipitates out of the solution.
• the glycerin by-product is approximately 8 vol. % by volume of the original oil.
• the Biodiesel fuel is cleaned with water to remove any remaining lye. If the lye is not completely removed from the fuel it can corrode certain types of vehicle fuel lines and, potentially, clog fuel filters. Finally, the Biodiesel is cleaned and dried in a process that separates water and residual impurities from the pure Biodiesel. Among the pollutant byproducts of this process is water tainted with lye.
• this invention includes what I call Alt-diesel fuel formulations and methods of making Alt-diesel fuel formulations that include vegetable oil in which glycerin may not be removed from the vegetable oil prior to use.
• One embodiment of a fuel formulation includes 25 to 75 vol. % vegetable oil in which the glycerin has not been removed, 25 to 75 vol. % petroleum diesel, 0.001 to 5 vol. % fuel stabilizer, and 0.01 to 5 vol. % cetane boost additive.
• the cetane boost additive may include octylnitrate.
• the vegetable oil may be an edible or non-edible plant oil.
• the vegetable oil may, for example, include (but is not limited to) jatropha oil, algae oil, soy oil, peanut oil.
• the formulation may further include 1 to 20 vol. % turpentine.
• the fuel formulation may also include 25 to 75 vol. % petroleum diesel.
• the fuel formulation may be configured to be used as an automotive fuel.
• Another embodiment of a fuel formulation includes 25 to 75 vol. % vegetable oil from which the glycerin has not been removed, 1 to 50 vol. % petroleum diesel, 1 to 50 vol. % turpentine, 0.001 to 5 vol. % fuel stabilizer, and 0.01 to 5 vol. % cetane boost additive.
• Yet another embodiment of a fuel formulation includes 70 to 98 vol. % vegetable oil, 1 to 20 vol. % petroleum diesel, and 1 to 20 vol. % regular gasoline.
• the glycerin is not required to be removed from the vegetable oil.
• the formulation may include 0.01 to 5 vol. % cetane booster, and/or 0.001 to 5 vol. % fuel stabilizer.
• the formulation may also include 1 to 20 vol. % turpentine.
• the fuel formulation may also include 1 to 20 vol. % kerosene.
• a fuel formulation includes 70 to 98 vol. % vegetable oil, 1 to 40 vol. % ethanol, 1 to 20 vol. % petroleum diesel, and 0.01 to 40 vol. % surfactant.
• the glycerin is not required to be removed from the vegetable oil.
• the formulation may include 0.01 to 5 vol. % cetane booster, and/or 0.001 to 5 vol. % fuel stabilizer.
• the formulation may also include 1 to 20 vol. % turpentine.
• the fuel formulation may also include 1 to 20 vol. % kerosene.
• a method of producing a fuel formulation includes blending together 70 to 98 vol. % vegetable oil from which the glycerin has not been removed, 1 to 20 vol. % petroleum diesel, and 1 to 20 vol. % regular gasoline.
• Another method of producing a fuel formulation includes blending together 70 to 98 vol. % vegetable oil from which the glycerin has not been removed, 1 to 40 vol. % ethanol, 1 to 20 vol. % petroleum diesel, and 0.01 to 40 vol. % surfactant.
• Yet another method of producing a fuel formulation includes blending together 25 to 75 vol. % vegetable oil in which the glycerin has not been removed, 1 to 50 vol. % petroleum diesel, 1 to 50 vol. % turpentine, 0.001 to 5 vol. % fuel stabilizer, and 0.01 to 5 vol. % cetane boost additive.
• Another method of producing a fuel formulation includes blending together 25 to 75 vol. % vegetable oil from which the glycerin has not been removed, 25 to 75 vol. % petroleum diesel, 0.001 to 5 vol. % fuel stabilizer; and 0.01 to 5 vol. % cetane boost additive.
• Alt-diesel formulations Alternative formulations of vegetable oil-based fuels (hereinafter referred to as Alt-diesel formulations) that overcome or lessen several of the drawbacks of Biodiesel may be produced. These formulations can be produced quickly and easily and can have little or no cold weather sensitivity at temperature lows typical to North America.
• Alt-diesel formulations can burn more cleanly than fossil fuels such as #2 diesel.
• Alt-diesel formulations can burn at least 50% more cleanly than fossil fuels and, even at least 80% or more cleanly.
• Alt-diesel formulations are noncorrosive so there are no fuel line problems or clogging of fuel filters. Vehicles may run on the Alt-diesel formulations without the need to modify the vehicles or vehicle components.
• Alt-diesel formulations are stable and can be stored for long terms before use without breaking down. Some Alt-diesel formulations may be stored at least one month, or a year or more before use.
• an Alt-diesel formulation starts with vegetable oil, for example, ten gallons of used or fresh soy oil.
• vegetable oil for example, ten gallons of used or fresh soy oil.
• oils are suitable. Virtually any non-animal plant oil can be used.
• vegetable oil will be used to refer to all non-animal plant oils suitable for use as fuel.
• Preferred oils include jatropha, algae, soy, peanut and a variety of other edible and non-edible vegetable oils. It is particularly beneficial that the described process utilize oils from non-edible plant sources.
• the oil does not include or only includes small amounts of shortening.
• vegetable shortening will work, less fuel is produced and more byproducts per gallon are generated from shortening.
• shortening is a poor fuel for use in diesel engines.
• Either fresh or used oil can be used. Used oil, however, is preferably separated before use. Used oil, for example, can be gathered from either restaurants or a manufacturing facility. It can then be strained and placed in a settling tank. The oil then preferably settles for at least twelve hours. This process separates the good oil from the water and fats. The water and fats will settle to the bottom of the tank and can be drained off. The good oil or fresh oil can then be filtered either before or after mixing with one or more fossil fuels and/or additives.
• Preferred amounts of vegetable oil in some formulations may include 25 to 75 vol. %, 30 to 70 vol. %, and 40 to 60 vol. %.
• Preferred amounts of vegetable oil in other formulations may include 70 to 98 vol. %, 75 to 95 vol. %, and 80 to 90 vol. %.
• the Alt-diesel formulation may include petroleum diesel, for example #2 diesel, which can be added to reduce the viscosity of the oil.
• Preferred amounts of petroleum diesel in some formulations may include 25 to 75 vol. %, 30 to 70 vol. %, and 40 to 60 vol. %.
• Preferred amounts of petroleum diesel in other formulations may include 1 to 20 vol. %, 5 to 15 vol. %, and 7 to 12 vol. %.
• Preferred amounts of petroleum diesel in yet other formulations may include 1 to 50 vol. %, 10 to 40 vol. % and 15 to 35 vol. %.
• the Alt-diesel formulation may include kerosene in addition to or in place of some or all of the petroleum diesel.
• Preferred amounts of kerosene in some formulations may include 25 to 75 vol. %, 30 to 70 vol. %, and 40 to 60 vol. %.
• Preferred amounts of kerosene in other formulations may include 1 to 20 vol. %, 5 to 15 vol. %, and 7 to 12 vol. %.
• Preferred amounts of kerosene in yet other formulations may include 1 to 50 vol. %, 10 to 40 vol. % and 15 to 35 vol. %.
• the Alt diesel formulation may include turpentine, which like petroleum diesel and kerosene, can be added to reduce the viscosity of the oil. Turpentine has the added benefit that it can be obtained from organic sources. Preferred amounts of turpentine in some formulations may include 25 to 75 vol. %, 30 to 70 vol. %, and 40 to 60 vol. %. Preferred amounts of turpentine in other formulations may include 1 to 20 vol. %, 5 to 15 vol. %, and 7 to 12 vol. %. Preferred amounts of turpentine in yet other formulations may include 1 to 50 vol. %, 10 to 40 vol. % and 15 to 35 vol. %.
• the Alt-diesel formulation may include a fuel stabilizer.
• Fuel stabilizers are additives which help prevent the fuel from undergoing degradation and oxidation, particularly during prolonged storage. Fuel stabilizers can also be used to prevent glycerin in the fuel from clogging the intake system.
• An example of a preferred fuel stabilizer is DIESEL KLEAN manufactured by Share Corp.
• Another example of a preferred fuel stabilizer is STA-BIL fuel stabilizer manufactured by Gold Eagle Co.
• Preferred amounts of fuel stabilizer in the formulation include 0.001 to 5 vol. %, 0.01 to 1 vol. %, and 0.05 to 0.10 vol. %.
• the Alt-diesel formulation may include regular gasoline to aid with ignition.
• Preferred amounts of regular gasoline in the formulation include 1 to 20 vol. %, 2 to 10 vol. %, and 3 to 7 vol. %.
• the Alt-diesel formulation may include a cetane booster.
• a preferred cetane booster includes octylnitrate alone or in combination with other cetane boosting agents.
• An Example of a preferred cetane booster is AMSOIL cetane boost additive.
• Preferred amounts of cetane booster in the formulation include, 0.01 to 5 vol. %, 0.05 to 3 vol. %, and 0.1 to 2 vol. %.
• One method of producing an Alt-diesel formulation may include blending vegetable oil, petroleum diesel, fuel stabilizer, regular gasoline and cetane booster. The mixture is then ready for use.
• Another method of producing an Alt-Diesel formulation may include blending vegetable oil, petroleum diesel, a fuel stabilizer, and a cetane booster.
• Yet another method of producing an Alt-Diesel formulation may include blending vegetable oil, petroleum diesel, turpentine, a fuel stabilizer, and a cetane booster.
• the Alt-diesel formulation may include ethanol.
• Ethanol can neutralize the negative attributes of glycerin in vegetable oil, as the glycerin is rendered inert and burned off in the combustion process.
• ethanol when used in the formulation the amount of gasoline, petroleum diesel, and/or kerosene used in the formulation can be reduced or even eliminated.
• the ethanol may be pure ethanol or denatured ethanol.
• Preferred amounts of ethanol in the formulation include 1 to 40 vol. %, 5 to 25 vol. %, and 10 to 20 vol. %.
• ethanol brings to the ethanol containing Alt-diesel formulation is a reduction or elimination in the need for the fuel stabilizer component used in the previous formulation (as the surfactant/fuel-line-antifreeze achieves a similar result).
• Preferred amounts of fuel stabilizer in an ethanol containing formulation include 0.001 to 1 vol. %, 0.005 to 0.75 vol. %, and 0.002 to 0.003 vol. %.
• the Alt-diesel formulation may include a surfactant.
• the surfactant component can be used to help insure the proper blending properties of the oil and ethanol. This component can also be used in the regulation of viscosity.
• Many suitable surfactants are currently used in fuel line antifreeze products sold today.
• Preferred surfactants include, but are not limited to, Toluene, Acetone, and Stoddard solvent.
• Preferred amounts of surfactant in the formulation include 0.01 to 40 vol. %, 0.1 to 10 vol. %, and 0.5 to 5 vol. %.
• An example of a method of producing an ethanol containing formulation includes blending vegetable oil, ethanol, a surfactant, and optionally, other ingredients to achieve the operational and burn characteristics of distillate petroleum fuels such as diesel and home heating oil.
• the process can be accomplished using simple mixing and filtration equipment.
• the process preferably produces no harmful by-products.
• the process preferably produces only food particulates, and then only when waste oil is used in the formulation, which can be sold to, for example, dog food manufacturers.
• the fuel also preferably leaves little or no build up in the intake and the exhaust manifolds of the engine.
• the Alt-diesel formulations can provide better lubrication than pure fossil diesel.
• the fuel can also be used as a home heating oil with no need for modification of the burner needed.
• the oil or Alt-diesel formulations are preferably filtered to run through a typical diesel vehicle fuel filter of 2 micron filtration.
• the Alt-diesel formulations are filtered to remove particulates that are more than 1 micron in diameter.
• the Alt-diesel formulations can be produced by filtering the oil or formulations using one or more filters.
• a filtration system for used oil can include screening the oil as it is poured into a settling tank. The oil is then pumped from the settling tank through a 10 to 30 micron, more preferably 15 to 20 micron filter and then through a 1 micron carbon filter. Finally, the oil is pumped through a 5 to 50 micron, more preferably, a 10 to 30 micron desiccate filter to remove any remaining water.
• the water separator is used because water can be extremely detrimental to diesel engines.
• the filtered oil can be mixed, if it wasn't mixed prior to filtering, with the fossil fuel(s) and/or additives and is ready to be pumped into the vehicle.
• the pressure required to move the thick oil through the filters can be reduced. If new oil is being used the oil may only be pumped through a ten micron desiccate filter and then mixed.
• 10 gallons of filtered oil were mixed with one gallon of kerosene and 5 oz of STA-BIL fuel stabilizer.
• the 10% kerosene is the normal amount added to regular diesel fuel to run in cold weather.
• the 10% kerosene also appeared to give the oil the same viscosity as regular diesel.
• the STA-BIL fuel stabilizer was added to attach to the micro droplets of water in the oil. 1 oz of fuel stabilizer was added to 2.5 gallons of fuel.
• the fuel was used in a diesel John Deere tractor.
• the tractor would not start at first, but did eventually start when ether was used to facilitate initial combustion.
• the engine ran very roughly until it warmed up to normal operating temperature. Once up to temperature the engine ran well.
• This test showed that an additional component should be added to the formulation to produce a flash point typically used to get combustion initiated while starting the engine. Accordingly, 5% regular gasoline was added to the mix to provide the needed flash point at ignition. With this refined formulation, the engine started and ran with no ether.
• DIESEL KLEAN with Cetane booster was added to the formulation described in Example 1 including the regular gasoline to help prevent residue build up and to raise the cetane level of the fuel.
• This mixture was then run in a used 1997 Volkswagen Passat TDI. Prior to running the mixture in the Passat, the intake was taken off of the engine. The intake was completely clogged with soot.
• the EGR valve was clogged as was the water pre-heater (this is a common problem with diesel engines run in the Northeast part of the United States). Accordingly, these parts were cleaned as well as possible prior to running the fuel.
• the 2005 Jeep Liberty Diesel has one of the most sophisticated diesel management systems of any diesel vehicle running in North America and, accordingly, provides a good test case for the use of the Alt-diesel formulation in demanding applications.
• the Jeep was bought in North Carolina and then driven to New York. The dealer noted that the Jeep might not run as well on the dirty diesel fuel sold in the north east.
• the Jeep was driven to New York on the southern-specification diesel fuel and subsequently run on the Alt-diesel formulation.
• the Jeep ran more quietly on the Alt-diesel formulation.
• New York-specification diesel was then put in the Jeep and, after being started, the check engine light came on. The conclusion is that the Jeep rejected the New York-specification diesel fuel but ran with no issues on the Alt-diesel formulation.
• Alt-diesel formulation was used as a home heating oil.
• An old oil fired hot air furnace was used for the test.
• the same filtration process described above for the cars was used, but the Alt-diesel formulation was modified. Since the oil burner had an ignition system, the gasoline was removed from the mixture. The fuel burned perfectly with no change in nozzle size.
• an embodiment of the Alt-diesel formulation for cars is:
• An ethanol containing Alt-diesel formulation was prepared by mixing 10 gallons of used Vegetable Oil, 1 Gallon denatured ethanol, 1 ⁇ 2 gallon of Kerosene, 7 oz of Diesel Klean with cetane boost, and 1.5 oz Toluene. This formulation can be used as an automotive fuel.
• An Alt diesel formulation was prepared by mixing 500 ml vegetable oil, 500 ml kerosene, 5 ml Diesel Kleen and 3 ml cetane boost additive. The fuel formulation was then tested for compliance with ASTM standards for #2 Diesel and Biodiesel. The results of these tests appear in Table 1. Preferably, the Alt-diesel formulation is selection to meet exceed one or more of these standards. As shown in Table 1, this formulation met or exceeds the requirements for #2 Diesel and Biodiesel.
• An Alt diesel formulation was prepared by mixing 500 ml vegetable oil, 250 ml kerosene, 250 turpentine, 5 ml Diesel Kleen and 10 ml cetane boost additive. The fuel formulation was then tested for compliance with ASTM standards for #2 diesel and Biodiesel. The results of these tests appear in Table 2.
• Alt-diesel formulation for cars can include 10 gallons used vegetable or peanut oil, 1 gallon of #2 diesel, 1 ⁇ 2 gallon of regular gasoline, 1.5 oz of STA-BIL fuel stabilizer, 7 oz of Diesel Klean with cetane boost or Diesel fuel supplement with cetane boost. This same formulation with or without the regular gasoline can be used as a home heating oil.
• Another ethanol containing Alt-diesel formulation is prepared by mixing 10 gallons of used vegetable oil, 1 gallon denatured ethanol, 1 ⁇ 2 gallon of #2 diesel, 7 oz of Diesel Klean with cetane boost, and 1.5 oz toluene. This formulation can be used as an automotive fuel.
• An Alt diesel formulation is prepared by mixing 500 ml vegetable oil, 500 ml #2 diesel, 5 ml Diesel Kleen and 3 ml cetane boost additive.
• Yet another Alt diesel formulation is prepared by mixing 500 ml vegetable oil, 250 ml #2 diesel, 250 turpentine, 5 ml Diesel Kleen and 10 ml cetane boost additive.
• ASTM D975 Additional Standard Standards Test Test ASTM for #2 Additional for Method Method Test Diesel (Low Standards for Biodiesel Example 4 Employed Example 2 Employed Property Method Sulfer) #2 Diesel (B100) Formulation (Intertek) Formulation (Intertek) Flash Point - degrees D93 52 C./ 135 F. *** D93A 100 * D93A Celsius minimum 125.6 F.
• #1 DF and #2 DF are intended for use in the same applications described in the definitions of Grade No. 1-D and Grade No. 2-D respectively in ASTM D975.
• ASTM test D2622 is the test recommended by the EMA while test D5453 is used by the California Air Research Board (CARB).
• CARB California Air Research Board
• EMA recommends that lubricity levels be determined by ASTM D6078, Scuffing Load Wear Test (SBOCLE).
• lubricity may be measured using the High Frequency Reciprocating Rig (HFRR), ASTM D6O79. Using this test, a wear scar of 0.45 mm at 60° C. is equivalent to a SBOCLE result of 3100 g. (4) Diesel fuels must pass the Cloud Point (D2500) Or Low Temperature Flow Test (D4539) at the use temperature. Low temperature flow capability is the responsibility of the fuel supplier for retail fuels. It is adjusted monthly during the winter, depending on local climate. Unless specifically recommended by the # engine manufacturer or discussed with the fuel supplier in advance, modification of the waxing properties of fuels using aftermarket fuel additives is not recommended as an option for meeting the low temperature operability requirement.
• HFRR High Frequency Reciprocating Rig
• ASTM D6O79 ASTM D6O79

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• Chemical & Material Sciences (AREA)
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• Chemical Kinetics & Catalysis (AREA)
• General Chemical & Material Sciences (AREA)
• Organic Chemistry (AREA)
• Liquid Carbonaceous Fuels (AREA)

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• 2007
  • 2007-07-24 US US11/878,438 patent/US20080028671A1/en not_active Abandoned
  • 2007-07-25 EP EP07810759A patent/EP2044177A1/de not_active Withdrawn
  • 2007-07-25 CA CA002657759A patent/CA2657759A1/en not_active Abandoned
  • 2007-07-25 JP JP2009521818A patent/JP2009544810A/ja active Pending
  • 2007-07-25 AU AU2007277173A patent/AU2007277173A1/en not_active Abandoned
  • 2007-07-25 WO PCT/US2007/016717 patent/WO2008013848A1/en active Application Filing

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