US20070154697A1 - Two-part sizing composition for reinforcement fibers - Google Patents

Two-part sizing composition for reinforcement fibers Download PDF

Info

Publication number
US20070154697A1
US20070154697A1 US11/322,331 US32233105A US2007154697A1 US 20070154697 A1 US20070154697 A1 US 20070154697A1 US 32233105 A US32233105 A US 32233105A US 2007154697 A1 US2007154697 A1 US 2007154697A1
Authority
US
United States
Prior art keywords
reinforcing fiber
polyacid
film forming
acid number
high acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US11/322,331
Other languages
English (en)
Inventor
Marc Cossement
Jean-Marc Henrion
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Owens Corning Intellectual Capital LLC
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to US11/322,331 priority Critical patent/US20070154697A1/en
Assigned to OWENS CORING COMPOSITES SPRL reassignment OWENS CORING COMPOSITES SPRL ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: COSSEMENT, MARC R., HENRION, JEAN-MARC P.
Priority to TW095145132A priority patent/TW200736182A/zh
Priority to BRPI0620728-6A priority patent/BRPI0620728A2/pt
Priority to KR1020087015982A priority patent/KR20080081164A/ko
Priority to EP20060845672 priority patent/EP1966432A2/fr
Priority to JP2008548592A priority patent/JP2009522459A/ja
Priority to CN2006800498951A priority patent/CN101351590B/zh
Priority to PCT/US2006/048130 priority patent/WO2007078900A2/fr
Priority to CA 2635451 priority patent/CA2635451A1/fr
Publication of US20070154697A1 publication Critical patent/US20070154697A1/en
Assigned to OC NL INVEST COOPERATIEF U.A. reassignment OC NL INVEST COOPERATIEF U.A. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: OWENS CORNING COMPOSITES SPRL
Assigned to OCV INTELLECTUAL CAPITAL, LLC reassignment OCV INTELLECTUAL CAPITAL, LLC ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: OC NL INVEST COOPERATIEF U.A.
Abandoned legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/26—Macromolecular compounds or prepolymers
    • C03C25/28—Macromolecular compounds or prepolymers obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/24—Coatings containing organic materials
    • C03C25/26—Macromolecular compounds or prepolymers
    • C03C25/28—Macromolecular compounds or prepolymers obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C03C25/285—Acrylic resins
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10—Coating
    • C03C25/48—Coating with two or more coatings having different compositions
    • C03C25/50—Coatings containing organic materials only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity

Definitions

  • the present invention relates generally to a sizing composition for a reinforcing fiber material, and more particularly, to a two-part sizing formulation that imparts improved strength to reinforced composites which includes a size composition and a binder composition.
  • a composite article formed from a reinforcing fiber material sized with a two-part sizing formulation is also provided.
  • Glass fibers are useful in a variety of technologies.
  • glass fibers are commonly used as reinforcements in polymer matrices to form glass fiber reinforced plastics or composites.
  • Glass fibers have been used in the form of continuous or chopped filaments, strands, rovings, woven fabrics, nonwoven fabrics, meshes, and scrims to reinforce polymers.
  • glass fiber reinforced polymer composites possess higher mechanical properties compared to unreinforced polymer composites, provided that the reinforcement fiber surface is suitably modified by a sizing composition.
  • a sizing composition may be achieved with glass fiber reinforced composites.
  • Chopped glass fibers are commonly used as reinforcement materials in reinforced composites.
  • glass fibers are formed by attenuating streams of a molten glass material from a bushing or orifice.
  • the glass fibers may be attenuated by a winder that collects gathered filaments into a package or by rollers that pull the fibers before they are collected and chopped.
  • An aqueous sizing composition, or chemical treatment, is typically applied to the fibers after they are drawn from the bushing. After the fibers are treated with the aqueous sizing composition, they may be dried in a package or chopped strand form.
  • Chopped strand segments may be mixed with a polymeric resin and supplied to a compression- or injection-molding machine to be formed into glass fiber reinforced composites.
  • the chopped strand segments are mixed with pellets of a thermoplastic polymer resin in an extruder.
  • polymer pellets are fed into a first port of a twin screw extruder and the chopped glass fibers are fed into a second port of the extruder with the melted polymer to form a fiber/resin mixture.
  • the polymer pellets and chopped strand segments are dry mixed and fed together into a single screw extruder where the resin is melted, the integrity of the glass fiber strands is destroyed, and the fiber strands are dispersed throughout the molten resin to form a fiber/resin mixture.
  • the fiber/resin mixture is degassed and formed into pellets.
  • These dry fiber strand/resin dispersion pellets are then fed to a molding machine and formed into molded composite articles that have a substantially homogeneous dispersion of glass fiber strands throughout the composite article.
  • chopped glass fibers are often bulky and do not flow well in automated equipment.
  • the chopped fiber strands may be compacted into rod-shaped bundles or pellets to improve their flowability and to enable the use of automated equipment, such as, for example, for transporting the pellets and mixing the pellets with the polymer resins.
  • U.S. Pat. No. 5,578,535 to Hill et al. discloses glass fiber pellets that are from about 20% to 30% denser than the individual glass strands from which they are made, and approximately 5 to 15 times larger in diameter.
  • pellets are prepared by hydrating cut fiber strand segments to a hydration level sufficient to prevent separation of the fiber strand segments into individual filaments but insufficient to cause the fiber strand segments to agglomerate into a clump.
  • the hydrated strand segments are then mixed for a period of time sufficient for the strand segments to form pellets.
  • Suitable mixing methods include processes that keep the fibers moving over and around one another, such as by tumbling, agitating, blending, commingling, stirring and/or intermingling the fibers.
  • Sizing compositions such as are used in reinforced composites, are well-known in the art and conventionally include a polyacid polymeric component, a film forming polymeric component, a coupling agent, and a lubricant.
  • a polyacid sizing composition is typically added to glass fibers to reduce interfilament abrasion and to make the glass fibers compatible with the polymeric matrices they are intended to reinforce.
  • the sizing composition also ensures the integrity of the strands of glass fibers, e.g., the interconnection of the glass filaments that form the strand.
  • polyacid conventional sizing compositions used in reinforced composites is the presence of a di-cationic species, such as a metallic salt of a long chain carboxylic acid, in the polymer used to form a reinforced composite article.
  • a di-cationic species such as a metallic salt of a long chain carboxylic acid
  • the interaction of the di-cationic lubricant with the polyacid conventional sizing compositions causes a decrease in mechanical strength.
  • polyamide composites reinforced with conventional sizing compositions often demonstrate a reduction in impact strengths (e.g., Charpy or Izod, un-notched or notched) as well as a reduction in tensile strength and elongation at break when such tests are run on hydro-aged composite pieces.
  • impact strengths e.g., Charpy or Izod, un-notched or notched
  • the two-part sizing formulation includes a size composition and a binder composition.
  • the size composition may be applied to a reinforcing fiber material before the binder composition is applied.
  • the reinforcing fiber material may be one or more strands of glass (e.g., Advantex® glass), natural fibers, carbon fibers, or one or more synthetic polymers.
  • the size composition includes one or more coupling agents and one or more resinous film forming agents.
  • the coupling agent is an aminosilane or a diaminosilane.
  • the size composition may optionally include conventional additives such as lubricants, wetting agents, pH adjusters, antioxidants, antifoaming agents, processing aids, antistatic agents, and/or non-ionic surfactants.
  • the binder composition includes a high acid number copolymer formed from the polymerization of maleic anhydride or maleic acid and at least one other desired monomer and/or a high acid number polycarboxylic acid.
  • the maleic anhydride or acid copolymer may be a pure copolymer or a derivative in the anhydride, acid, salt, or partial-ester, -amide, or -imide form.
  • Suitable copolymers include C 2 -C 5 ⁇ -olefins, such as butadiene-, ethylene-, propylene- or (iso)butylene-maleic acid copolymers, and methyl vinyl ether-maleic acid copolymers.
  • the binder composition includes an ethylene-maleic acid copolymer formed by the hydrolysis of an ethylene-maleic anhydride copolymer.
  • the binder composition may also include a film forming agent, which may be the same as, or different from, the film forming agent in the size composition.
  • Conventional additives such as lubricants, surfactants, and anti-static agents may also be included in the binder composition.
  • the process for making a densified reinforcing fiber product may be an in-line process that includes applying a two-part sizing formulation as described above to a strand of a reinforcing fiber material, chopping the strand of sized reinforcing fibers into segments, applying a binder composition as described above to the segments, and pelletizing and/or densifying the segments to form the densified reinforcing fiber product.
  • Pellet formation and densification may occur in separate tumbling apparatuses, such as in a rotary drum (e.g., pelletizer) and rotating zig-zag tube (e.g., densifier).
  • pellet formation and densification may occur in separate regions within a single apparatus, such as in a “Zig-Zag” blender commercially available from Patterson Kelly.
  • the size composition may be applied to the fibers as they are being formed and the binder composition may be applied to the sized fibers in a pelletizer. By applying the binder composition in the pelletizer, an application efficiency of approximately 95% to 100% for the binder composition may be obtained.
  • applying the binder composition separately from the size composition outside the fiber-forming environment permits the inclusion of materials that are not desirably applied during the fiber-forming process because of safety, flammability, irritation, stability, low compatibility with aminosilanes, viscosity, toxicity, cleanliness, odor, cost, and/or shear sensitivity.
  • a high loss-on-ignition (LOI) of the high acid number maleic anhydride copolymer, ethylene maleic acid copolymer, or polycarboxylic acid in the sizing composition provides for improved dry-as-molded mechanical properties and improved hydrolysis resistance.
  • polyurethane film formers present in the sizing composition demonstrate good compatibility with polyamide matrices, which helps to improve the dispersion of the reinforcement fiber bundles in the melt (e.g., in extrusion process or injection molding process) when forming a composite article.
  • This increased fiber dispersion may cause a reduction of defects such as visual defects in the final product, a reduction in processing breaks, and/or low mechanical properties in the final article.
  • the polyurethane dispersion present in the sizing composition improves the compatibility of the sizing composition with the di-cationic species containing polymer to improve the dispersion of the fibers during further processing to form a composite article.
  • the present invention imparts improved physical properties such as improved dry-as-molded (DaM) mechanical properties of the composite part or after aging the composite part in severe hydrolysis conditions to composites formed from industrially processable and easily dispersible pellets.
  • DaM dry-as-molded
  • the two-part sizing formulation has improved stability over conventional sizing formulations that contain an aminosilane and a polyacid in the same mixture.
  • FIG. 1 is a graphical illustration of dry-as-molded (DaM) Izod Un-notched Impact tests on polyamide 6 and polyamide 6/calcium stearate composite pieces;
  • FIG. 2 is a graphical illustration of dry-as-molded (DaM) Charpy Un-notched Impact tests on polyamide 6 and polyamide 6/calcium stearate composite pieces;
  • FIG. 3 is a graphical illustration of Charpy Un-notched Impact tests after hydro-aging polyamide 6 and polyamide 6/calcium stearate composite pieces;
  • FIG. 4 is a graphical illustration of dry-as-molded (DaM) Charpy Un-notched Impact tests on polyamide 6 and polyamide 6/calcium stearate composite pieces;
  • FIG. 5 is a graphical illustration of dry-as-molded (DaM) Charpy Un-notched Impact tests on polyamide 6 and polyamide 6/calcium stearate composite pieces.
  • DaM dry-as-molded
  • the present invention relates to a two-part sizing formulation that improves the mechanical performance of reinforced composites.
  • the two-part sizing formulation of the invention imparts improved dry-as-molded mechanical properties and hydrolysis resistance to polymer reinforced composites, such as a polyamide reinforced composite, even when such composites contain di-cationic or higher valency additives such as a calcium stearate lubricant.
  • di-cationic or higher valency additives such as a calcium stearate lubricant.
  • the two-part sizing formulation includes a size composition and a binder composition.
  • the two-part sizing formulation may be applied to a reinforcing fiber material to form a reinforcing fiber product, which may then be densified or compacted to form a densified reinforcing fiber product, such as pellets.
  • the densified pellets provide a convenient form for storage and handling of the chopped fibers used as reinforcing materials in composite structures.
  • the size composition may be applied to a reinforcing fiber material before the binder composition is applied.
  • the reinforcing fiber material may be one or more strands of glass formed by conventional techniques such as by drawing molten glass through a heated bushing to form substantially continuous glass fibers. These fibers may subsequently be collected into a glass strand. Any type of glass, such as A-type glass, C-type glass, E-type glass, S-type glass, or ECR-type glass such as Owens Corning's Advantex® glass fibers.
  • the reinforcing fiber material is E-type glass or Advantex® glass.
  • the reinforcing fiber material may be strands of one or more synthetic polymers such as polyester, polyamide, aramid, and mixtures thereof.
  • the polymer strands may be used alone as the reinforcing fiber material, or they can be used in combination with glass strands such as those described above.
  • natural fibers may be used as the reinforcing fiber material.
  • the term “natural fiber” as used in conjunction with the present invention refers to plant fibers extracted from any part of a plant, including, but not limited to, the stem, seeds, leaves, roots, or phloem.
  • Examples of natural fibers suitable for use as the reinforcing fiber material include cotton, jute, bamboo, ramie, bagasse, hemp, coir, linen, kenaf, sisal, flax, henequen, and combinations thereof. Carbon or polyaramide fibers may be also used as the reinforcing fiber material.
  • the reinforcing fiber material may include fibers that have a diameter of from about 6 microns to about 24 microns and may be cut into segments approximately 1 mm to about 50 mm in length.
  • the fibers Preferably, the fibers have a diameter from about 7 microns to about 14 microns and a length from about 3 mm to about 6 mm. Most preferably, the fibers have a diameter of approximately 10 microns.
  • each strand Prior to the densification of the reinforcing fiber material as described below, each strand may contain from approximately 500 fibers to approximately 8,000 fibers.
  • a suitable size composition includes one or more coupling agents and one or more film forming agents.
  • conventional additives such as, but not limited to, lubricants, wetting agents, pH adjusters, antioxidants, antifoaming agents, processing aids, antistatic agents, and non-ionic surfactants may be present in the size composition.
  • the size composition may be applied to the reinforcement fibers in an amount sufficient to achieve a Loss on Ignition (LOI) of from about 0.05% to about 1.0% on the dried fiber, and preferably in an amount of from 0.15% to about 0.40%.
  • LOI may be defined as the percentage of organic solid matter deposited on the glass fiber surfaces measured by the reduction in weight experienced by the fibers after heating them to a temperature sufficient to burn or pyrolyze the organic size from the fibers.
  • the size composition includes one or more coupling agents.
  • the coupling agent is a silane coupling agent.
  • silanes also function to enhance the adhesion of the polycarboxylic acid component to the reinforcement fibers and to reduce the level of fuzz, or broken fiber filaments, during subsequent processing.
  • Examples of silane coupling agents that may be used in the present size composition may be characterized by the functional groups amino, epoxy, vinyl, methacryloxy, ureido, isocyanato, and azamido.
  • the silane coupling agents include silanes containing one or more nitrogen atoms that have one or more functional groups such as amine (primary, secondary, tertiary, and quarternary), amino, imino, amido, imido, ureido, isocyanato, or azamido.
  • amine primary, secondary, tertiary, and quarternary
  • Suitable silane coupling agents include, but are not limited to, aminosilanes, silane esters, vinyl silanes, methacryloxy silanes, epoxy silanes, sulfur silanes, ureido silanes, and isocyanato silanes.
  • A-1100 ⁇ -aminopropyltriethoxysilane
  • Y-9669 n-phenyl- ⁇ -aminopropyltrimethoxysilane
  • n-trimethoxy-silyl-propyl-ethylene-diamine A-1120
  • silane coupling agents are set forth in Table 1. All of the silane coupling agents identified above and in Table 1 are available commercially from GE Silicones. TABLE 1 Silanes Label Formula Silane Esters octyltriethoxysilane A-137 CH 3 (CH 2 ) 7 (Si(OCH 2 CH 3 ) 3 methyltriethoxysilane A-162 CH 3 Si(OCH 2 CH 3 ) 3 methyltrimethoxysilane A-163 CH 3 Si(OCH 3 ) 3 proprietary A-1230 proprietary tris-[3-(trimethoxysilyl)propyl] Y-11597 — isocyanurate Vinyl Silanes proprietary RC-1 proprietary vinyltriethoxysilane A-151 CH 2 ⁇ CHSi(OCH 2 CH 3 ) 3 vinyltrimethoxysilane A-171 CH 2 ⁇ CHSi(OCH 3 ) 3 vinyl-tris-(2-methoxyethoxy) silane A-172 CH 2 ⁇ CH
  • silane coupling agents include the products from Chisso having the trade designations set forth in Table 2. TABLE 2 S-310 n-(2-aminoethyl)-3- aminopropylmethyldimethoxysilane S-320 n-(2-aminoethyl)-3- aminopropyltrimethoxysilane S-350 n-[2-(vinylbenzylamino)ethyl]-3- aminopropyl-trimethoxysilane monohydrochloride (methanol solution) S-510 3-glycidoxypropyltrimethoxysilane S-610 3-chloropropylmethydimethoxysilane S-620 3-chloropropyltrimethoxysilane
  • the silane coupling agents used in the present invention may be replaced by alternative coupling agents or mixtures.
  • A-1387 may be replaced by a version in which the methanol solvent is replaced by ethanol.
  • A-1126 an aminosilane coupling agent including a mixture of approximately 24% by weight diaminosilane modified by a surfactant in a methanol solution (GE Silicones), may be replaced with trimethoxy-silyl-propyl-ethylene-diamine (Z-6020 from Dow Corning).
  • Z-6020 trimethoxy-silyl-propyl-ethylene-diamine
  • Z-6020 may be replaced by Z-6137, a pre-hydrolyzed version lacking the alcohol solvent and including 33% diaminosilane in water at a concentration of 24% solids (commercially available from Dow Corning).
  • A-1100 may be replaced by its hydrolyzed form Y-9244, which will reduce or eliminate the ethanol emission.
  • the silane coupling agent is an aminosilane or a diaminosilane.
  • the size composition may include one or more of the above-identified coupling agents.
  • the coupling agent may be applied to the fibers in an amount sufficient to achieve a Loss on Ignition (LOI) of from about 0.02% to about 0.30% on the dried fiber, and preferably in an amount of from about 0.04% to about 0.08%.
  • LOI Loss on Ignition
  • the size composition may include at least one resinous film forming agent. Any conventional film forming agent known to those of skill in the art may be utilized in the size composition.
  • the film former may be the same as or different from the film forming agent present in the binder composition described in detail below. In the size composition, the film former acts as a polymeric binding agent to provide additional protection to the reinforcing fibers and improves processability, such as a reduction in fuzz generated by high speed chopping.
  • the film forming agent may be present on the reinforcement fibers in an amount sufficient to provide an LOI from 0% to about 1.0%.
  • the film forming agent is present on the fibers in an amount sufficient to provide an LOI from about 0.15% to about 0.60%.
  • the size composition contains a lubricant to facilitate manufacturing instead of, or in addition to, a film forming agent.
  • suitable lubricants include, but are not limited to, lubricants such as water-soluble ethyleneglycol stearates (e.g., polyethyleneglycol monostearate, butoxyethyl stearate, polyethylene glycol monooleate, and butoxyethylstearate), ethyleneglycol oleates, ethoxylated fatty amines, glycerin, emulsified mineral oils, and organopolysiloxane emulsions.
  • lubricants such as water-soluble ethyleneglycol stearates (e.g., polyethyleneglycol monostearate, butoxyethyl stearate, polyethylene glycol monooleate, and butoxyethylstearate), ethyleneglycol oleates, ethoxylated fatty amines, gly
  • lubricants include alkyl imidazoline derivatives (e.g., a cationic softener which has a solids content of approximately 90% and is available commercially from Th. Goldschmidt AG), stearic ethanolamide (e.g., Lubesize K12 (AOC)), and a polyethyleneimine polyamide salt commercially available at 50% active solid from Cognis under the trade name Emery 6760.
  • alkyl imidazoline derivatives e.g., a cationic softener which has a solids content of approximately 90% and is available commercially from Th. Goldschmidt AG
  • stearic ethanolamide e.g., Lubesize K12 (AOC)
  • AOC Lubesize K12
  • Emery 6760 polyethyleneimine polyamide salt commercially available at 50% active solid from Cognis under the trade name Emery 6760.
  • the lubricant may be present on the fibers in an amount sufficient to provide an LOI up to about 0.10%.
  • the pH preferably falls within the range of from 7 to 11.
  • the pH may be adjusted depending on the intended application, or to facilitate the compatibility of the ingredients of the size composition.
  • Any suitable pH adjuster e.g., a weak organic acid such as acetic acid or a base such as ammonia
  • a weak organic acid such as acetic acid or a base such as ammonia
  • the size composition may be made by dissolving each of the ingredients into a premix with agitation.
  • the separate premixes may then be combined with deionized water to form a main mixture and to achieve the appropriate concentration and control the mix of solids.
  • the premixes may be added in any order. If necessary, the pH of the main mixture may be adjusted to a desired level.
  • the premixes may be added separately, or they may be added at the same time to form the main mixture.
  • the two-part sizing formulation also includes a binder composition.
  • the binder composition includes a high acid number copolymer formed from the polymerization of maleic anhydride or maleic acid and at least one other desired monomer and/or a high acid number polyacid.
  • the phrase “high acid number” is intended to designate a polyacid with an acid number or acid value of greater than about 300.
  • the binder composition may include any suitable additive identified by one of skill in the art, such as, for example, adhesive film forming polymers, lubricants, a surfactant or a mixture of surfactants, antistatic agents, and crosslinking agents.
  • the binder composition may be applied to the fiber with an LOI of from about 0.20% to about 2.0%, depending on the desired application.
  • the maleic anhydride or maleic acid copolymer may be a pure copolymer or a derivative in an anhydride, acid, partial-salt, partial-ester, partial-amide, or partial-imide form.
  • Suitable copolymers include C 2 -C 5 ⁇ -olefins, such as ethylene-, propylene-, (iso)butylene-, or butadiene-maleic acid copolymers, and methyl vinyl ether-maleic acid copolymers.
  • the copolymer is poorly soluble when dispersed in water at room temperature, but when it is heated to temperatures above approximately 90° C., it dissolves by virtue of the hydrolysis of the anhydride groups of the polymer to form the corresponding polyacids.
  • one mole of anhydride is hydrolyzed to two moles of diacid in an exothermic reaction.
  • the aqueous solution formed by the hydrolysis may then be used to formulate the binder composition.
  • Similar reactions may be employed using ammonia or an amine in water, or an alcohol or an amine in a non-reactive solvent, to form, respectively, solutions of the partial-ammonium salt, partial-ester, partial-amide, or partial-imide derivatives.
  • the binder composition includes an ethylene-maleic acid (EMA) copolymer formed by the hydrolysis of an ethylene-maleic anhydride copolymer.
  • EMA ethylene-maleic acid
  • the ethylene-maleic anhydride copolymer may be formed by the radical copolymerization between ethylene and maleic anhydride in the presence of a peroxide catalyst. This copolymerization leads to an alternating copolymer that includes a high level of maleic units which gives the ethylene-maleic acid copolymer a high polyacid functionality.
  • the copolymer is an aqueous solution of the polyacid, (partial) ammonium salt, partial-ester, partial-amide, or partial-imide derivative of an alternating block copolymer of maleic anhydride, or mixtures thereof.
  • Mixtures of different ethylene maleic acid copolymers or maleic anhydride copolymers with other high acid number polycarboxylic acids such as acrylic or maleic acid homo- or co-polymers or derivates thereof such as those described above may used in the binder composition to achieve desired properties, such as improved strength in the reinforced fiber product or improved fiber processability, and also to reduce the total binder cost.
  • the binder composition may include a high acid number (e.g., high acid value) polyacid alternatively, or in addition to, the maleic anhydride or maleic acid copolymer.
  • the polyacid is a polycarboxylic acid.
  • a suitable polycarboxylic acid polymer for use in the binder composition is an organic polymer that contains numerous pendant carboxylic acid groups and is characterized by a high acid number.
  • the acid number or acid value of a substance may be described as a measure of the free acid content, and may be expressed as the number of milligrams of potassium hydroxide neutralized by the free acid present in one gram of the substance.
  • the high acid number polyacid may have an acid number of at least about 300. In at least one exemplary embodiment, the binder composition has an acid number of about 300 to about 950.
  • the polycarboxylic acid polymer may be a homopolymer or copolymer prepared from unsaturated carboxylic acids including, but not limited to, acrylic acid, methacrylic acid, crotonic acid, isocrotonic acid, maleic acid, cinnamic acid, 2-methylmaleic acid, itaconic acid, 2-methylitaconic acid, and ⁇ , ⁇ -methyleneglutaric acid.
  • the polycarboxylic acid polymer may be prepared from unsaturated anhydrides such as maleic anhydride, itaconic anhydride, acrylic anhydride, methacrylic anhydride, and mixtures thereof.
  • the polycarboxylic acid polymer may include a copolymer of one or more of the unsaturated carboxylic acids or anhydrides described above and one or more vinyl compounds including, but not limited to, styrene, ⁇ -ethylstyrene, acrylonitrile, methacrylonitrile, methyl acrylate, ethyl acrylate, n-butyl acrylate, isobutyl acrylate, methyl methacrylate, n-butyl methacrylate, isobutyl methacrylate, glycidyl methacrylate, vinyl methyl ether, vinyl acetate, 1-olefins (e.g., ethylene, isobutene) vinyl and allyl alkyl ethers (e.g., methyl vinyl ether, ethyl vinyl ether),
  • the high acid number maleic anhydride copolymer, high acid number ethylene maleic acid copolymer, or high acid number polycarboxylic acid in the binder composition may be present on the fibers in an amount sufficient to provide an LOI up to about 2.0%, preferably from about 0.10% to about 2.0%, and even more preferably from about 0.40% to about 1.0%.
  • carboxylic acid moieties be present in the size/binder composition to compensate for the polyacid that is consumed by the di-cations such that improved dry-as-molded mechanical properties and improved hydrolysis resistance may be achieved.
  • specific amount of carboxylic acid moieties present in the binder composition needed to achieve an excess (and improved physical properties) is dependent upon the amount of di-cations present in the polymer.
  • the binder composition may also include one or more film forming agents.
  • Film formers are agents which create improved adhesion between the reinforcing fibers, which results in improved strand integrity. Suitable film formers include thermosetting and thermoplastic polymers which promote the adhesion of sizing compositions.
  • Polyurethane film formers are a preferred class of film formers for use in the binder composition because they demonstrate good compatibility with polyamide matrices and help to improve the dispersion of the glass fiber bundles in the melt (e.g., extrusion process or injection molding process) when forming the composite article, which causes a reduction or elimination of defects in the final article that caused by poor dispersion of the reinforcement fibers (e.g., visual defects, processing breaks, and/or low mechanical properties).
  • the polyurethane dispersions utilized in the two-part sizing formulation of the present invention may be part of a dispersion that either is based or is not based on a blocked isocyanate.
  • the film former present in the binder composition may or may not be the same as the film former present in the size composition.
  • Baybond® XP-2602 a non-ionic polyurethane dispersion (Bayer Corp.)
  • Baybond® PU-401 and Baybond® PU-402 anionic urethane polymer dispersions (
  • suitable film forming agents for use in the binder composition include, but are not limited to, polyvinylpyrrolidone homo- and co-polymers and other polymers bearing amide-like functionality such as polyamide, polyvinylformamide, or polyacrylamide.
  • the film forming agent is an aqueous polyurethane dispersion that is not part of a dispersion that includes a polyurethane and a blocked isocyanate.
  • Suitable urethane film formers based on blocked isocyanates which may be used in the binder composition include, but are not limited to, Baybond® XW-116; Baybond® XP-055; Baybond® PU-330; Baybond® PU-400-S; Baybond® PU-401 (polyurethane dispersions based on blocked isocyanates (available from Bayer Corp.)); Baybond® VP-LS-2277 and Baybond® VP-LS-2297 (anionic/non-ionic urethane polymer dispersions (Bayer Corp.)); Baybond® PU-130 (an anionic/non-ionic urethane polymer dispersion (Bayer Corp.)); Baybond® PU-403 (a polyurethane dispersion (Bayer Corp.)); Baybond® PU-239 (a crosslinkable anionic/non-ionic urethane polymer dispersion (Bayer Corp.)); Baybond® PU-2435 (an ani
  • the film former(s) may be present in the binder composition in an amount sufficient to provide an LOI up to about 1.0%, and preferably from about 0.10% to about 0.40%. It is desirable that the amount of film former present in the two-part sizing formulation is such that the two-part sizing formulation provides the desired level of compatibility for the reinforcement fibers and the polymer matrix to help fiber dispersion during processing to form a composite part without affecting the positive effect of the polyacid moieties to improve dry-as-molded and hydro-aged mechanical properties and without developing static and/or an undesirable color in the reinforcing fiber product.
  • the binder composition may be formed by mixing a solution of the desired high acid number polyacid(s) (e.g., a polycarboxylic acid obtained by hydrolysis of the parent polyanhydride in hot water) with a solution of the film forming agent.
  • the solution may be diluted with water. It may be necessary to adjust the pH of the polyacid solution with a base before mixing it with the film former solution to reduce or eliminate the occurrence of destabilization phenomena.
  • Any suitable pH adjuster may be added to the binder composition to adjust the pH to a desired level; however, it is preferred that ammonia (NH 4 ) be added to adjust the pH.
  • the pH of the binder composition may fall in the range of from 2.5-10.
  • the total LOI for the two-part sizing formulation on the reinforcing fiber material may be from about 0.25% to about 2.05%, preferably from about 0.60% to about 1.10%.
  • One advantage of the two-part sizing formulation of the present invention is that the product resulting from the application of the two-part sizing formulation, which may contain up to about 2.0% LOI of the high acid number maleic anhydride copolymer, high acid number ethylene maleic acid copolymer, or high acid number polycarboxylic acid, provides improved mechanical properties, even when the polyamide matrix contains a di-cation additive such as calcium stearate.
  • the two-part sizing formulation of the present invention imparts improved physical properties, such as improved dry-as-molded (DaM) mechanical properties of the composite part after aging the composite part in severe hydrolysis conditions, to composites formed from industrially processable and easily dispersible pellets.
  • improved physical properties such as improved dry-as-molded (DaM) mechanical properties of the composite part after aging the composite part in severe hydrolysis conditions
  • the present invention is also advantageous in that the polyurethane film formers present in the two-part sizing formulation demonstrate good compatibility with polymer matrices (such as polyamide matrices) that contain di-cationic lubricants, which helps to improve the dispersion of the reinforcement fiber bundles in the melt (e.g., in extrusion process or injection molding process) when forming a composite article.
  • polymer matrices such as polyamide matrices
  • di-cationic lubricants helps to improve the dispersion of the reinforcement fiber bundles in the melt (e.g., in extrusion process or injection molding process) when forming a composite article.
  • This increased dispersion of the reinforcement fibers causes a reduction of defects such as visual defects, processing breaks, and/or low mechanical properties in the final product.
  • the two-part sizing formulation of the present invention has improved stability over conventional sizing formulations containing an aminosilane and a polyacid in the same mixture. Mixtures containing both aminosilanes and polyacids may not be stable due to chemical interactions between the two compounds. By placing substantially all (if not all) of the aminosilane in the size composition and the polyacid in the binder composition, both the size composition and the binder composition have increased shelf lives.
  • the process for making a densified reinforcing fiber product may be an in-line process that permits the application of the size composition, the chopping of the glass fibers, the application of the binder composition, and pelletizing the reinforcing fiber material.
  • Such an in-line process forms a pellet product that exhibits superior physical properties, such as improved strength, when integrated into a composite (e.g., when compared to pellets produced by processes previously known in the art).
  • superior properties are believed to be due to the improved compatibility of the size composition and binder composition, which permits a better coating of the reinforcing fiber material.
  • the process for making a densified reinforcing fiber product according to the invention may employ an apparatus that includes: (a) an apparatus for applying a size composition to a continuous fiber material; (b) an apparatus for cutting the glass fiber strands to form chopped strand segments; (c) an apparatus for conveying the chopped strand segments to a first tumbling apparatus; (d) an apparatus for applying a binder composition to the chopped strand segments; (e) a first tumbling apparatus for imparting a tumbling action to the chopped strand segments to disperse the binder composition and cause the chopped strand segments to align and coalesce into pellets; (f) optionally, an apparatus for conveying the pellets to a second tumbling apparatus; (g) optionally, a second tumbling apparatus for tumbling the pellets to compact them and increase their density; (h) an apparatus for conveying the densified pellets to a drying apparatus; and (i) a drying apparatus adapted to receive and dry the pellets.
  • the size composition may be applied to the reinforcing fiber material by any conventional means, including kiss roll, dip-draw, and slide or spray applicators.
  • the precursor size is applied by passing the reinforcing fiber material, e.g., strands of glass or polymer, over a kiss roll applicator.
  • the size composition is preferably applied to the strands in an amount sufficient to provide the strands with a moisture content of from about 8% by weight to about 13% by weight, more preferably about 10% to about 11% by weight.
  • the sized strands may then be chopped into strand segments.
  • the strand segments may have a length of from approximately 2 mm to approximately 50 mm.
  • the strands Preferably, have a length of from about 3 to about 4 mm. Any suitable method or apparatus known to those of ordinary skill for chopping glass fiber strands into segments may be used.
  • the binder composition may be applied to the chopped strand segments.
  • the coated chopped strand segments are then pelletized by any suitable method known to those of ordinary skill in the art, such as, for example, tumbling or otherwise agitating the chopped strand segments in a pelletizer.
  • Processes suitable for pelletizing the chopped strand segments are disclosed in U.S. Pat. Nos. 5,868,982, 5,945,134, 6,365,090, and 6,659,756 to Strait et al., and U.S. Pat. No. 5,693,378 to Hill et al., all of which are incorporated by reference in their entireties.
  • the amount of moisture in the binder composition serves to adjust the moisture content of the strand segments to a level suitable for the formation of pellets when the strand segments are tumbled in the pelletizer.
  • the moisture content of the strand segments can be adjusted prior to their introduction into the pelletizer, it is preferred that the segments are hydrated to a moisture content suitable for pellet formation in the pelletizer itself.
  • the moisture content of the chopped strand segments in the pelletizer is from about 12% by weight to about 16% by weight, and more preferably from about 13% by weight to about 14% by weight, based on the total weight of the binder-sized, chopped strand segments. If the moisture content is too low, the strand segments tend not to combine into pellets and will remain in a strand formation. On the other hand, if the moisture content is too high, the strands tend to agglomerate or clump or form pellets having a large diameter and an irregular, non-cylindrical shape.
  • the binder composition may be applied to the chopped strand segments as they enter the pelletizer, or after the chopped segments are placed in the pelletizer but prior to tumbling.
  • the binder composition may be sprayed onto the strands before they are chopped.
  • the binder composition is preferably applied to the chopped strand segments as they enter the pelletizer but before they begin to coalesce into pellets. If the binder composition is applied at other locations within the pelletizer, pellets may form before the strand segments are completely coated with the binder composition, which results in pellets containing fibers that are not coated with the binder composition. When such pellets are used in the manufacture of fiber reinforced composite articles, the uncoated fibers lack the interfacial coating required to provide good reinforcing characteristics, and the resulting composite article will have less than optimal properties.
  • the pelletizer is equipped with a spray nozzle, located adjacent to the strand segment inlet, for spraying the binder size onto the strand segments as they enter the pelletizer.
  • the pelletizer may be any apparatus capable of tumbling the strand segments in such a way that: (1) they become substantially uniformly coated with the binder composition, and (2) multiple chopped strand segments align and coalesce into pellets having a desired dimension.
  • a tumbling apparatus should have an average residence time sufficient to insure that the strand segments become substantially coated with the binder size and form pellets, but insufficient for the pellets to be damaged or degraded through abrasion (e.g., by rubbing against one another).
  • the residence time in the tumbling apparatus is from about 1 minute to about 10 minutes. More preferably, the residence time in the tumbling apparatus is from about 1 minute to about 3 minutes.
  • a preferred pelletizer is a rotating drum, such as that disclosed in U.S. Pat. No. 5,868,982, as referenced herein above.
  • U.S. Pat. No. 5,868,982 discloses an apparatus for making reinforcing fiber pellets, which is preferably provided with a system for monitoring and/or adjusting various process parameters. The moisture content of the strand segment input may be monitored and controlled using suitable method.
  • the rotating drum is adapted to accommodate a spray head for applying the binder composition to the strand segments as they enter the drum.
  • the binder composition and a solvent, such as water may be combined into one fluid stream and dispersed through the nozzle orifice.
  • This stream may be combined with two jets of air positioned approximately 180 degrees apart and at an angle of 60 degrees to the direction of the stream flow. Mixing the binder composition with the forced air streams effectively creates a mist that is propelled onto the surface of the tumbling strand segments in the drum.
  • Rotation of the drum causes the wet strand segments to tumble around one another while the surface tension created by the wet sizing or coating causes strand segments contacting one another over a substantial portion of their length to align with one another and coalesce into a cylindrically shaped pellet.
  • any fines or single fibers created during the chopping operation are recombined with and incorporated into the forming pellets to essentially eliminate individual fine fibers from the resulting pellets.
  • the drum is tilted slightly so that the end of the drum from which the pellets exit is lower than the end in which they enter to ensure that the pellets formed in the drum do not remain in the drum for an excessive period of time.
  • the size of the pellets formed in the drum is controlled primarily by the moisture content of the strand segments. If the moisture content is maintained at a high level, a greater number of strand segments will coalesce into a pellet and the pellet will have a larger diameter. On the other hand, if the moisture is maintained at a lower level, fewer strand segments will coalesce into a pellet and the pellet will have a smaller diameter.
  • the amount of binder composition that is discharged onto the strands may be controlled by a computer which monitors the weight of wet glass entering the pelletizer and adjusts the amount of the binder composition to obtain a final chopped strand having a strand solids content of from about 0.25% to about 2.05% by weight.
  • the pellets formed have a diameter of from about 20% to about 65% of their length.
  • Such pellets are typically formed by combining from about 70 strand segments to about 175 strand segments, each containing from about 500 individual filaments per strand to about 8000 individual filaments per strand.
  • the size of the pellets may also be affected by drum throughput. For example, the higher the drum throughput, the shorter the residence time of the strand segments in the drum. As a result, smaller pellets may be formed because the binder composition is not adequately dispersed on the strands which may cause the strands not to coalesce into a pellet. In addition, pellets that are formed in the drum for a shorter period of time are less compacted than those pellets that formed in the drum for a longer period of time.
  • the pellets may optionally be fed into a second tumbling apparatus or densifier, wherein the pellets are further compacted and densified.
  • a second tumbling apparatus or densifier Any low-impact tumbling apparatus that will compact the pellets without degrading them through abrasion or otherwise damaging the pellets may be used.
  • the densifier is a zig-zag tube adapted to be rotated about its longitudinal axis, such as is described in U.S. Pat. Nos. 5,868,982, 5,945,134, 6,365,090, and 6,659,756 to Strait et al.
  • the densifier has a gentler, less vigorous tumbling action than that of the pelletizer to minimize degradation of the pellets.
  • the zig-zag tube densifier is preferably tilted at a slight angle to ensure that the pellets flow through the apparatus without excessive residence times.
  • the densifier preferably has an average residence time of less than approximately 5 minutes to reduce any abrasion that may occur.
  • the average residence time in the densifier is from about 1 minute to about 2 minutes.
  • pellet formation and densification may occur in separate apparatuses, such as a separate rotary drum and a rotating zig-zag tube linked by a conveyor
  • the pelletizing process may be accomplished using any suitable apparatus.
  • pellet formation and densification may occur in separate tumbling regions or zones within a single apparatus.
  • a preferred example of such an apparatus is a “Zig-Zag” blender commercially available from Patterson Kelly.
  • a drum is equipped with an interior baffle to reduce the free-fall distance of the glass pellets and strand segments during rotation of the drum. By reducing this distance, less deterioration of the glass fibers and pellets through impact and abrasion occurs, resulting in improved physical properties in the glass fiber reinforced molded articles manufactured therefrom.
  • the pellets may be delivered onto a conveyor belt and dried, e.g., using a hooded oven supplied with hot air and cooling air or any other suitable drying apparatus easily identified by one of skill in the art. To reduce drying time to a level acceptable for commercial mass production, it is preferred that the fibers are dried at elevated temperatures of up to approximately 260° C. in a fluidized-bed oven. After drying, the densified pellets may be classified by size using a screen or other suitable device.
  • glass fiber pellets can be made that are from about 13% to about 60% denser than the corresponding unpelleted strand segments, and from about 10 times to about 65 times larger in diameter.
  • chopped 4 mm (length) segments of a 2000 filament strand composed of 14 micron (diameter) fibers typically have a bulk density of from about 33 lb/ft 3 (528.66 kg/m 3 ) to 36 lb/ft 3 (576.72 kg/m 3 ).
  • the resulting dried pellets After being hydrated to a moisture content of from about 13% to about 14% and formed into densified pellets such as is described above, according to the process of the invention, the resulting dried pellets typically have a bulk density of from about 40 lb/ft 3 (640.8 kg/m 3 ) to about 55 lb/ft 3 (881.1 kg/m 3 ). As a result of their increased diameter-to-length ratio and increased density, the resulting pellets exhibit significantly improved flowability in comparison to the unpelleted chopped strand product.
  • the size composition and the binder composition facilitate treating reinforcing fiber materials, e.g., glass, during a continuous process that includes forming the fibers as well as subsequent processing or handling.
  • an application efficiency of about 95% to about 100% for the binder composition may be obtained. This high application efficiency reduces waste water contamination in the plant. Further, because the binder composition can be applied efficiently, the binder composition may be applied with a reduction in cost.
  • the binder composition separately from the sizing composition outside the fiber-forming environment permits, materials that are not desirably applied during the fiber-forming process because of toxicity, safety, flammability, irritation, stability, low compatibility with aminosilanes, viscosity, toxicity, cleanliness, odor, cost, or shear sensitivity may be applied to the glass fibers. Also, because the polyacid in the binder composition can be applied to the glass fibers in a more concentrated form in the pelletizer than if it were applied directly to the glass strands as they are being formed, there is reduced fiber logging and waste as compared to conventional in-line processes.
  • the invention is highly suitable for in-line manufacturing processes, such as described above, it may also be used in an off-line process in which the size composition and the binder composition are applied to previously formed and packaged reinforcing fiber materials, or in which the size composition and the binder composition are applied to the reinforcing fiber material at different times.
  • the size composition may be applied to a formed fiber strand, after which the strand may be wound and stored before subsequent unwinding, chopping into segments and application of the binder composition.
  • Example 1-3 the components of Table 3 were mixed to prepare the size composition.
  • the size composition was applied to 10 ⁇ m Advantex® glass fibers to achieve a strand Loss-On-Ignition (LOI) of 0.60% on the glass fibers.
  • LOI Loss-On-Ignition
  • ASTM 2854 A conventional loss on ignition (LOI) method, ASTM 2854, was used to determine how much of the applied size composition was on the glass fibers.
  • the glass fibers were then collected into a strand and chopped wet in-line by a chopper into segments of approximately 4 mm in length.
  • Example 2 The chopped segments were then collected and approximately 1-2 days later treated under rotation in a lab pelletizer where the corresponding binder set forth in Table 2 was sprayed onto the chopped segments.
  • no binder was applied during the pelletization.
  • Glascol E5 a 25% solids solution of a low molecular weight acrylic acid homopolymer available from Ciba, was diluted to 15% solids by deionized water and used as the binder.
  • the binder composition was prepared by dispersing 132 g of ZeMac 400, an alternating copolymer of ethylene and maleic anhydride available from Zeeland Chemicals, in 870 g of deionized water and dissolved by heating to approximately 95° C. under agitation.
  • the various binder compositions were applied to achieve the corresponding LOI % set forth in Table 2.
  • the densified glass pellets were collected and dried in a moving belt lab oven for approximately 16 minutes at a maximum temperature of 220° C.
  • Example 4-7 the components of Table 4 were mixed to prepare the size composition.
  • the size composition was applied to 10 ⁇ m Advantex® glass fibers to achieve a strand Loss-On-Ignition (LOI) of 0.35% on the glass fibers.
  • LOI Loss-On-Ignition
  • ASTM 2854 A conventional loss on ignition (LOI) method, ASTM 2854, was used to determine how much of the applied size composition was on the glass fibers.
  • the glass fibers were then collected into a strand and chopped wet in-line by a chopper into segments of approximately 4 mm in length.
  • Example 4 Baybond PU-403, a 39% solids blocked isocyanate polyurethane dispersion available from Bayer Corp., was diluted to 15% solids by deionized water and used as the binder.
  • Example 5-7 the binder was prepared by diluting Glascol E5, a 25% solids solution of a low molecular weight acrylic acid homopolymer, to 15% solids by deionized water.
  • the various binder compositions were applied to achieve the corresponding LOI % set forth in Table 2.
  • the densified glass pellets were collected and dried in a moving belt lab oven for approximately 16 minutes at a maximum temperature of 220° C.
  • Example 8 The size composition of Example 8 was prepared according to the description of Table 7 set forth in U.S. Patent Publication No. 2004/0209991 A1 to Piret et al., which is hereby incorporated by reference in its entirety.
  • the size composition as set forth in Table 5 was prepared and applied to 10 ⁇ m Advantex® glass fibers as they were produced in a continuous in-line process. The glass fibers were then formed into strands and chopped into strand segments having a length of approximately 4.0 mm. The molten glass was fed through the bushing at approximately 215 lbs/hour.
  • the size composition was applied with a conventional kiss roll type applicator turning in the direction of the strand at 15 meters per minute.
  • the chopped segments were then conveyed to a pelletizer where the binder composition according to Table 6 was sprayed onto the chopped segments.
  • the binder composition was applied to achieve a strand LOI of 0.59% solid on the glass fibers.
  • the total Loss-On-Ignition (LOI) of the glass was 0.65%.
  • the densified glass pellets were conveyed to a conveyor-type or fluidized bed oven for drying.
  • Example 9 components of Table 7 were mixed to prepare the size composition.
  • the size composition was applied to 10 ⁇ m Advantex® glass fibers to achieve a strand Loss-On-Ignition (LOI) of 0.25% on the glass fibers.
  • LOI Loss-On-Ignition
  • ASTM 2854 A conventional loss on ignition (LOI) method, ASTM 2854, was used to determine how much of the applied size composition was on the glass fibers.
  • the glass fibers were then collected into a strand and chopped wet in-line by a chopper into segments of approximately 4 mm in length.
  • the chopped segments were then collected and approximately 1-2 days later treated under rotation in a lab pelletizer where the binder was sprayed onto the chopped segments.
  • the binder composition was prepared by dispersing 13.43 kg of ZeMac 400 EMA powder in 47.85 kg of deionized water and dissolving the powder by heating the water to approximately 95° C. under agitation. After the ZeMac 400 EMA powder was dissolved, the solution was further diluted by adding 19 kg of deionized water. 18.61 kg of Glascol C95, a solution of a low molecular weight acrylic acid homopolymer partially neutralized by ammonia which is available from Ciba, was then added with agitation at a temperature lower than 60° C.
  • the binder composition was applied to achieve a strand LOI of 0.61% solid on the glass fibers.
  • the total Loss-On-Ignition (LOI) of the glass fibers was 0.86%.
  • the densified glass pellets were collected and dried in a moving belt lab oven for approximately 16 minutes at a maximum temperature of 220° C.
  • Example 10 components of Table 8 were mixed to prepare the size composition.
  • the size composition was applied to 10 ⁇ m Advantex® glass fibers to achieve a strand Loss-On-Ignition (LOI) of 0.22% on the glass fibers.
  • LOI Loss-On-Ignition
  • ASTM 2854 A conventional loss on ignition (LOI) method, ASTM 2854, was used to determine how much of the applied size composition was on the glass fibers.
  • the glass fibers were then collected into a strand and chopped wet in-line by a chopper into segments of approximately 4 mm in length.
  • the chopped segments were then conveyed to a pelletizer where the binder was sprayed onto the chopped segments as they passed through the entrance chamber of the pelletizer.
  • the binder composition was prepared by dispersing 32.00 kg of ZeMac 60 EMA powder in 80.80 kg of deionized water and dissolving the powder by heating the water to approximately 95° C. with agitation. After the ZeMac 60 EMA powder was dissolved, the solution was cooled to 25° C. and the pH was adjusted to about 3.5 by the addition of approximately 9.10 kg of a 25% ammonia solution. 52.37 kg of Baybond XP-2602, a non-ionic polyurethane dispersion available from Bayer Corp., was then added slowly with agitation.
  • the densified glass pellets were conveyed to a conveyor or conveyor-type or fluidized bed oven for drying.
  • the binder composition was applied to achieve a strand LOI of 0.61% solid on the glass fibers.
  • the total LOI of the glass fibers was 0.83%.
  • Example 11 components of Table 9 were mixed to prepare the size composition.
  • the size composition was applied to 10 ⁇ m Advantex® glass fibers to achieve a strand Loss-On-Ignition (LOI) of 0.22% on the glass fibers.
  • LOI Loss-On-Ignition
  • ASTM 2854 A conventional loss on ignition (LOI) method, ASTM 2854, was used to determine how much of the applied size composition was on the glass fibers.
  • the glass fibers were then collected into a strand and chopped wet in-line by a chopper into segments of approximately 4 mm in length.
  • the chopped segments were then conveyed to a pelletizer where the binder was sprayed onto the chopped segments as they passed through the entrance chamber of the pelletizer.
  • the binder composition was prepared by dispersing 13.43 kg of ZeMac 400 EMA powder in 47.85 kg of deionized water and dissolving the powder by heating the water to approximately 95° C. under agitation. After the ZeMac 400 EMA powder was dissolved, the solution was further diluted by adding 19 kg of deionized water. 18.61 kg of Glascol C95, a solution of a low molecular weight acrylic acid homopolymer partially neutralized by ammonia which is available from Ciba, was then added with agitation at a temperature lower than 60° C.
  • the densified glass pellets were then conveyed to a conveyor-type or fluidized bed oven for drying.
  • the binder composition was applied to achieve a strand LOI of 0.50% solid on the glass fibers.
  • the total LOI of the glass fibers was 0.72%.
  • the glass fiber pellets were compounded with molding pellets of polyamide 6 (Ultramid B3 from BASF with or without added Calcium Stearate) using a twin screw co-rotating intermeshing extruder (ZSK30 Werner-Pfleiderer (Coperion)) while feeding the pellets into the melt of the second port of the extruder.
  • the fiber/resin mixture was then degassed and formed into compounded glass/resin pellets.
  • the compounded glass/resin pellets were dried for 12 hours at 95° C. by a molecular sieve circulating hot air dryer. After drying, the pellets were injection-molded by an injection-molding machine (Demag DC80 or Arburg 420C) into Axxicon ISO molds to form standardized composite specimens. The molded specimens were placed in metallic vessels containing silicagel to keep them dry.
  • a portion of the composite specimens were cross-mixed between different autoclaves to simulate the same aging for each composite specimen.
  • hydrolysis hydro-aging
  • the composites were fully immersed in an ethylene glycol/water (50/50) mixture and placed under pressure for 500 hours at a temperature of 120° C.
  • the vessel was cooled to room temperature before the tensile strengths and the Charpy un-notched impact strengths were determined.
  • Dry-as-Molded (DaM) properties such as Tensile Strength, Charpy un-notched impact strength, and Izod un-notched and notched impact strength were measured on the dry, molded specimens. The results are set forth below.
  • the tests to determine tensile strength were conducted according to the procedures set forth in ISO 527-4/1B/10.
  • the Charpy un-notched impact strength was measured according to the procedures set forth in ISO 179-1/1 Eu.
  • the Izod un-notched and notched (2 mm notch) were measured according to ISO 180/A.
  • the lab conditions were set as described in ISO 291.
  • Example 7 The reduction in the negative effects of the presence calcium stearate is also demonstrated by Example 7, in which the Charpy un-notched impact strength decreased from 104.0 KJ/m 2 to 94.7 KJ/m 2 in the presence of calcium stearate.
  • the data obtained from Examples 6 and 7 show a small difference in the Charpy un-notched impact strength (94.8 KJ/m 2 for Example 6 and 94.7 KJ/m 2 for Example 7), indicating that there may be a plateau for the number of polyacid moieties needed to achieve improved dry-as-molded mechanical properties in the composite product.
  • Similar results demonstrating a decrease in the negative effects of calcium stearate in the polyacid were obtained with respect to the Tensile strength and Izod notched and un-notched impact strengths.
  • Example 5 it can be seen that the relatively low level polyacid-containing composite resulted in better mechanical performance than the polyacid-free, polyurethane-based composite formed by the two-part sizing formulation of Example 4. This is particularly noticeable for the dry-as-molded (DaM) Izod un-notched properties (Table 11) and for the Tensile strength properties after hydro-aging when no calcium stearate is present (Table 12). However, when calcium stearate was present in the Polyamide 6, the polyacid-containing composite of Example 5 showed a loss of mechanical properties.
  • DaM dry-as-molded
  • Table 12 Tensile strength properties after hydro-aging when no calcium stearate is present
  • the polyacid-containing composite of Example 5 demonstrated a loss of dry-as-molded Charpy and Izod (notched and un-notched) impact strengths (Table 11) and Tensile strength and Charpy un-notched impact strength after hydro-aging (Table 12) compared to these same mechanical properties in the absence of calcium stearate. These losses of mechanical properties are clearly highlighted by the strongly negative delta values associated with the separate properties.
  • Examples 6 and 7 contain a higher polyacid content than Example 5 and are less sensitive to the presence of calcium stearate, as indicated by the smaller negative delta values for the dry-as-molded or properties after hydro-aging.
  • the amount of polyacid present in the two-part sizing formulation is high enough to compensate for the negative interaction with the calcium stearate. This excess in polyacid moieties result in improved and superior mechanical properties, as can be seen in FIGS. 2 and 3 .
  • Example 8 In the presence of calcium stearate, however, the level of polyacid present in the two-part sizing formulation of Example 8 was not enough to compensate for the level of calcium stearate present in the polyamide, and, as a result, the polyacid moieties were consumed by the negative interaction with the calcium stearate di-cation.
  • the low level of polyacid present in Example 8 results in lower-than-expected performance (e.g., results that are well below the results that are observed with Polyamide 6 without calcium stearate) of the dry-as-molded Charpy un-notched and Izod (notched and un-notched) impact strengths (Table 13) and the Tensile strength and Charpy un-notched impact strength after hydro-aging (Table 14).
  • Example 9 contained a higher level of polyacid in the two-part sizing formulation. It can be seen from Tables 13 and 14 that when calcium stearate was present in the Polyamide 6, the losses induced by the calcium stearate in the dry-as-molded Charpy un-notched and Izod (notched and un-notched) impact strengths (Table 13) and the Tensile strength and Charpy un-notched impact strength after hydro-aging (Table 14) of Example 9 were less severe compared to the composite product of Example 8.
  • Example 9 The improvement of the dry-as-molded Charpy un-notched impact strength of Example 9 is illustrated graphically in FIG. 4 .
  • the excess of polyacid present in the two-part sizing formulation resulted in a high mechanical performance of the composite pieces tested both before and after hydro-aging both with and without the presence of calcium stearate in the Polyamide 6.
  • Such improved mechanical properties demonstrated by the composite product of Example 9 confirms the superior and unexpected properties of the two-part sizing formulation of the present invention.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Reinforced Plastic Materials (AREA)
  • Surface Treatment Of Glass Fibres Or Filaments (AREA)
US11/322,331 2005-12-30 2005-12-30 Two-part sizing composition for reinforcement fibers Abandoned US20070154697A1 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
US11/322,331 US20070154697A1 (en) 2005-12-30 2005-12-30 Two-part sizing composition for reinforcement fibers
TW095145132A TW200736182A (en) 2005-12-30 2006-12-05 Two-part sizing composition for reinforcement fibers
CA 2635451 CA2635451A1 (fr) 2005-12-30 2006-12-15 Composition d'encollage a deux constituants pour fibres de renforcement
EP20060845672 EP1966432A2 (fr) 2005-12-30 2006-12-15 Composition d'encollage a deux constituants pour fibres de renforcement
KR1020087015982A KR20080081164A (ko) 2005-12-30 2006-12-15 강화 섬유용 2-부 사이징 조성물
BRPI0620728-6A BRPI0620728A2 (pt) 2005-12-30 2006-12-15 composição de engomagem em duas partes para fibras de reforço
JP2008548592A JP2009522459A (ja) 2005-12-30 2006-12-15 強化繊維用の２部分サイジング組成物
CN2006800498951A CN101351590B (zh) 2005-12-30 2006-12-15 用于增强纤维的两部分施胶剂组合物
PCT/US2006/048130 WO2007078900A2 (fr) 2005-12-30 2006-12-15 Composition d'encollage a deux constituants pour fibres de renforcement

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US11/322,331 US20070154697A1 (en) 2005-12-30 2005-12-30 Two-part sizing composition for reinforcement fibers

Publications (1)

Publication Number Publication Date
US20070154697A1 true US20070154697A1 (en) 2007-07-05

Family

ID=38180143

Family Applications (1)

Application Number Title Priority Date Filing Date
US11/322,331 Abandoned US20070154697A1 (en) 2005-12-30 2005-12-30 Two-part sizing composition for reinforcement fibers

Country Status (9)

Country Link
US (1) US20070154697A1 (fr)
EP (1) EP1966432A2 (fr)
JP (1) JP2009522459A (fr)
KR (1) KR20080081164A (fr)
CN (1) CN101351590B (fr)
BR (1) BRPI0620728A2 (fr)
CA (1) CA2635451A1 (fr)
TW (1) TW200736182A (fr)
WO (1) WO2007078900A2 (fr)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100055439A1 (en) * 2008-08-29 2010-03-04 Lee Jerry H C WUCS Fibers Having Improved Flowing And Dispersing Properties
US20110288194A1 (en) * 2008-11-21 2011-11-24 Arkema France Polyamide and bioresourced reinforcement compositions having improved mechanical properties
US20130150517A1 (en) * 2010-08-18 2013-06-13 Vertellus Specialties Inc. Compositions, methods and articles produced by compounding polyamides with olefin-maleic anhydride polymers
EP2620419A1 (fr) 2012-01-27 2013-07-31 3B Fibreglass Composition d'encollage à base de polyamide pour fibres de verre
WO2013139732A2 (fr) 2012-03-20 2013-09-26 Dsm Ip Assets B.V. Composition d'encollage en deux parties pour l'enduction de fibres de verre et composite renforcé avec ces fibres de verre
US10011718B2 (en) 2013-03-15 2018-07-03 Vertellus Holdings Llc Impact-modified polyamide compositions
US10743470B2 (en) 2015-11-23 2020-08-18 Cnh Industrial America Llc Shaker device for a fruit harvesting unit
US10800919B2 (en) 2014-07-14 2020-10-13 Vertellus Holdings Llc Modification of engineering plastics using olefin-maleic anhydride copolymers
US11639316B2 (en) * 2018-09-26 2023-05-02 3M Innovative Properties Company Fiber tows with a heat-activated sizing

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2848953A1 (fr) * 2011-09-23 2013-03-28 Ocv Intellectual Capital, Llc Fibres de renforcement et leur utilisation pour le renforcement de beton
KR102295134B1 (ko) * 2014-02-06 2021-08-31 오웬스 코닝 인텔렉츄얼 캐피탈 엘엘씨 보강 복합재의 지연된 분화
KR102613741B1 (ko) * 2021-06-30 2023-12-14 주식회사 케이씨씨 사이징 조성물 및 이를 사용한 유리 섬유

Citations (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3816235A (en) * 1972-08-18 1974-06-11 Owens Corning Fiberglass Corp Glass fiber size composition
US4167485A (en) * 1977-04-02 1979-09-11 Basf Aktiengesellschaft Water-soluble alkaline earth metal salts of polymers of acrylic acid, and their use as sizes
US4318960A (en) * 1977-11-07 1982-03-09 Owens-Corning Fiberglas Corporation Glass fiber size composition comprising maleic anhydride graft copolymer
US4636437A (en) * 1984-11-05 1987-01-13 Owens-Corning Fiberglas Corporation Glass fiber size and impregnant compositions
US4785039A (en) * 1984-11-05 1988-11-15 Owens-Corning Fiberglass Corporation Glass fiber size and impregnant compositions
US5002827A (en) * 1987-10-26 1991-03-26 Nippon Glass Fiber Co., Ltd. Agglomerated glass flakes
US5130197A (en) * 1985-03-25 1992-07-14 Ppg Industries, Inc. Glass fibers for reinforcing polymers
US5236982A (en) * 1992-07-13 1993-08-17 Owens-Corning Fiberglas Technology, Inc. Size composition
US5272195A (en) * 1992-07-14 1993-12-21 Phillips Petroleum Company Glass-reinforced chemically coupled branched higher alpha-olefin compounds
US5300547A (en) * 1992-10-30 1994-04-05 Phillips Petroleum Company Reinforced polypropylene compounds with improved properties
US5639807A (en) * 1994-08-05 1997-06-17 Akzo Nobel Nv Process for manufacturing carbon fiber pellets, the high density, streamlined pellets resulting therefrom and process for producing reinforced thermoplastic resins employing the pellets
US5672641A (en) * 1995-01-23 1997-09-30 Ppg Industries, Inc. Secondary coating compositions for glass fibers, glass fibers coated with the same and composites reinforced therewith
US5804313A (en) * 1996-07-15 1998-09-08 Ppg Industries, Inc. Polyamide and acrylic polymer coated glass fiber reinforcements, reinforced polymeric composites and a method of reinforcing a polymeric material
US5824413A (en) * 1996-07-15 1998-10-20 Ppg Industries, Inc. Secondary coating for fiber strands, coated strand reinforcements, reinforced polymeric composites and a method of reinforcing a polymeric material
US5868982A (en) * 1997-04-01 1999-02-09 Owens-Corning Fiberglas Technology, Inc. System for preparing glass fiber pellets
US5945134A (en) * 1997-04-01 1999-08-31 Owens Corning Fiberglas Technology, Inc. System for preparing glass fiber pellets
US20010008921A1 (en) * 1999-05-20 2001-07-19 Westvaco Corporation Hydrocarbon/acrylic hybrid resins for use as sizing compositions
US20010016259A1 (en) * 1999-02-16 2001-08-23 Les E. Campbell Sizing composition for glass fibers used to reinforce thermoplastic or thermosetting matrix polymers
US6365090B1 (en) * 1999-07-16 2002-04-02 Owens Corning Fiberglas Technology, Inc. System for preparing polymer encapsulated glass fiber pellets
US6365272B1 (en) * 1999-12-29 2002-04-02 Owens Corning Fiberglas Technology, Inc. System for preparing glass fiber pellets having low discoloration
US20040209991A1 (en) * 2001-12-21 2004-10-21 Piret Willy H Hydrolization resistant sizing compositon
US6833182B2 (en) * 1998-12-14 2004-12-21 Bayer Aktiengesellschaft Size compositions, sized glass fibers and their use
US20040258912A1 (en) * 2003-06-19 2004-12-23 Piret Willy H. Sizing composition for thermoplastic reinforcement
US6844406B2 (en) * 2000-10-04 2005-01-18 Valspar Sourcing, Inc. High functionality number, low molecular weight polymers and methods of making same
US20050214534A1 (en) * 2004-03-29 2005-09-29 Adamo Joseph R Extended curable compositions for use as binders
US20070072989A1 (en) * 2004-03-19 2007-03-29 Piret Willy H Two-part sizing composition for reinforcement fibers
US20070286999A1 (en) * 2006-06-13 2007-12-13 Jacob Cornelis Dijt Sizing composition for glass fibers, sized fiber glass products, and composites

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4201423B2 (ja) * 1999-02-25 2008-12-24 株式会社Ａｄｅｋａ ガラス繊維集束剤
JP4511669B2 (ja) * 2000-02-18 2010-07-28 旭化成ケミカルズ株式会社 強化ポリアミド樹脂組成物
US7419721B2 (en) * 2003-12-19 2008-09-02 Ppg Industries Ohio, Inc. Sizing composition and glass fiber reinforced thermoplastic resin

Patent Citations (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3816235A (en) * 1972-08-18 1974-06-11 Owens Corning Fiberglass Corp Glass fiber size composition
US4167485A (en) * 1977-04-02 1979-09-11 Basf Aktiengesellschaft Water-soluble alkaline earth metal salts of polymers of acrylic acid, and their use as sizes
US4318960A (en) * 1977-11-07 1982-03-09 Owens-Corning Fiberglas Corporation Glass fiber size composition comprising maleic anhydride graft copolymer
US4636437A (en) * 1984-11-05 1987-01-13 Owens-Corning Fiberglas Corporation Glass fiber size and impregnant compositions
US4785039A (en) * 1984-11-05 1988-11-15 Owens-Corning Fiberglass Corporation Glass fiber size and impregnant compositions
US5130197A (en) * 1985-03-25 1992-07-14 Ppg Industries, Inc. Glass fibers for reinforcing polymers
US5002827A (en) * 1987-10-26 1991-03-26 Nippon Glass Fiber Co., Ltd. Agglomerated glass flakes
US5236982A (en) * 1992-07-13 1993-08-17 Owens-Corning Fiberglas Technology, Inc. Size composition
US5272195A (en) * 1992-07-14 1993-12-21 Phillips Petroleum Company Glass-reinforced chemically coupled branched higher alpha-olefin compounds
US5300547A (en) * 1992-10-30 1994-04-05 Phillips Petroleum Company Reinforced polypropylene compounds with improved properties
US5639807A (en) * 1994-08-05 1997-06-17 Akzo Nobel Nv Process for manufacturing carbon fiber pellets, the high density, streamlined pellets resulting therefrom and process for producing reinforced thermoplastic resins employing the pellets
US5672641A (en) * 1995-01-23 1997-09-30 Ppg Industries, Inc. Secondary coating compositions for glass fibers, glass fibers coated with the same and composites reinforced therewith
US5804313A (en) * 1996-07-15 1998-09-08 Ppg Industries, Inc. Polyamide and acrylic polymer coated glass fiber reinforcements, reinforced polymeric composites and a method of reinforcing a polymeric material
US5824413A (en) * 1996-07-15 1998-10-20 Ppg Industries, Inc. Secondary coating for fiber strands, coated strand reinforcements, reinforced polymeric composites and a method of reinforcing a polymeric material
US5868982A (en) * 1997-04-01 1999-02-09 Owens-Corning Fiberglas Technology, Inc. System for preparing glass fiber pellets
US5945134A (en) * 1997-04-01 1999-08-31 Owens Corning Fiberglas Technology, Inc. System for preparing glass fiber pellets
US6833182B2 (en) * 1998-12-14 2004-12-21 Bayer Aktiengesellschaft Size compositions, sized glass fibers and their use
US20010016259A1 (en) * 1999-02-16 2001-08-23 Les E. Campbell Sizing composition for glass fibers used to reinforce thermoplastic or thermosetting matrix polymers
US20010008921A1 (en) * 1999-05-20 2001-07-19 Westvaco Corporation Hydrocarbon/acrylic hybrid resins for use as sizing compositions
US6365090B1 (en) * 1999-07-16 2002-04-02 Owens Corning Fiberglas Technology, Inc. System for preparing polymer encapsulated glass fiber pellets
US6659756B2 (en) * 1999-07-16 2003-12-09 Owens Corning Fiberglas Technology, Inc. System for preparing polymer encapsulated glass fiber pellets
US6365272B1 (en) * 1999-12-29 2002-04-02 Owens Corning Fiberglas Technology, Inc. System for preparing glass fiber pellets having low discoloration
US6844406B2 (en) * 2000-10-04 2005-01-18 Valspar Sourcing, Inc. High functionality number, low molecular weight polymers and methods of making same
US7129289B2 (en) * 2001-12-21 2006-10-31 Owens Corning Composites S.P.R.L. Hydrolization resistant sizing composition
US6896963B2 (en) * 2001-12-21 2005-05-24 Owens Corning Composites Sprl System for preparing glass fiber pellets having low discoloration
US20040209991A1 (en) * 2001-12-21 2004-10-21 Piret Willy H Hydrolization resistant sizing compositon
US20040258912A1 (en) * 2003-06-19 2004-12-23 Piret Willy H. Sizing composition for thermoplastic reinforcement
US7267782B2 (en) * 2003-06-19 2007-09-11 Owens-Corning Fiberglas Technology Ii, Llc Two-part combination of compositions for forming substantially colorless thermoplastic reinforcements
US20070072989A1 (en) * 2004-03-19 2007-03-29 Piret Willy H Two-part sizing composition for reinforcement fibers
US20050214534A1 (en) * 2004-03-29 2005-09-29 Adamo Joseph R Extended curable compositions for use as binders
US20070286999A1 (en) * 2006-06-13 2007-12-13 Jacob Cornelis Dijt Sizing composition for glass fibers, sized fiber glass products, and composites

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100055439A1 (en) * 2008-08-29 2010-03-04 Lee Jerry H C WUCS Fibers Having Improved Flowing And Dispersing Properties
US20110288194A1 (en) * 2008-11-21 2011-11-24 Arkema France Polyamide and bioresourced reinforcement compositions having improved mechanical properties
US10358527B2 (en) * 2008-11-21 2019-07-23 Arkema France Polyamide and bioresourced reinforcement compositions having improved mechanical properties
US9353262B2 (en) * 2010-08-18 2016-05-31 Vertellus Specialties Inc. Compositions, methods and articles produced by compounding polyamides with olefin-maleic anhydride polymers
US20130150517A1 (en) * 2010-08-18 2013-06-13 Vertellus Specialties Inc. Compositions, methods and articles produced by compounding polyamides with olefin-maleic anhydride polymers
EP2620419A1 (fr) 2012-01-27 2013-07-31 3B Fibreglass Composition d'encollage à base de polyamide pour fibres de verre
WO2013110515A1 (fr) 2012-01-27 2013-08-01 3B-Fibreglass Sprl Composition d'ensimage à base de polyamide pour des fibres de verre
WO2013139708A2 (fr) 2012-03-20 2013-09-26 3B Fibreglass Sprl Composition d'encollage en deux parties destinée au revêtement de fibres de verre et composite renforcé par de telles fibres de verre
WO2013139732A2 (fr) 2012-03-20 2013-09-26 Dsm Ip Assets B.V. Composition d'encollage en deux parties pour l'enduction de fibres de verre et composite renforcé avec ces fibres de verre
US10011718B2 (en) 2013-03-15 2018-07-03 Vertellus Holdings Llc Impact-modified polyamide compositions
US10435559B2 (en) 2013-03-15 2019-10-08 Vertellus Holdings Llc Impact-modified polyamide compositions
US10800919B2 (en) 2014-07-14 2020-10-13 Vertellus Holdings Llc Modification of engineering plastics using olefin-maleic anhydride copolymers
US10743470B2 (en) 2015-11-23 2020-08-18 Cnh Industrial America Llc Shaker device for a fruit harvesting unit
US11639316B2 (en) * 2018-09-26 2023-05-02 3M Innovative Properties Company Fiber tows with a heat-activated sizing

Also Published As

Publication number Publication date
KR20080081164A (ko) 2008-09-08
CN101351590B (zh) 2011-12-14
EP1966432A2 (fr) 2008-09-10
WO2007078900A2 (fr) 2007-07-12
TW200736182A (en) 2007-10-01
CN101351590A (zh) 2009-01-21
BRPI0620728A2 (pt) 2011-11-22
WO2007078900A3 (fr) 2007-08-30
CA2635451A1 (fr) 2007-07-12
JP2009522459A (ja) 2009-06-11

Similar Documents

Publication Publication Date Title
US20070154697A1 (en) Two-part sizing composition for reinforcement fibers
US20070072989A1 (en) Two-part sizing composition for reinforcement fibers
JP4963957B2 (ja) 熱可塑性強化材用サイジング組成物
US6365272B1 (en) System for preparing glass fiber pellets having low discoloration
US7129289B2 (en) Hydrolization resistant sizing composition
US20080143010A1 (en) Chemical coating composition for glass fibers for improved fiber dispersion
TW201307493A (zh) 用於熱塑性聚合材料強化物之進料中之上漿組合物，強化之聚合材料及製造方法
US20150166830A1 (en) Reinforcing fibers and their use for concrete reinforcement
US20110305904A1 (en) Sizing composition for glass fibers
EP2691345B1 (fr) Fils en fibres de verre et produits renforcés les comprenant

Legal Events

Date Code Title Description
AS Assignment

Owner name: OWENS CORING COMPOSITES SPRL, BELGIUM

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:COSSEMENT, MARC R.;HENRION, JEAN-MARC P.;REEL/FRAME:017888/0334

Effective date: 20060406

AS Assignment

Owner name: OCV INTELLECTUAL CAPITAL, LLC, OHIO

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:OC NL INVEST COOPERATIEF U.A.;REEL/FRAME:028226/0963

Effective date: 20070929

Owner name: OC NL INVEST COOPERATIEF U.A., NETHERLANDS

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:OWENS CORNING COMPOSITES SPRL;REEL/FRAME:028226/0894

Effective date: 20061020

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION