US20070056077A1 - Vapor permeable retroreflective garment - Google Patents
Vapor permeable retroreflective garment Download PDFInfo
- Publication number
- US20070056077A1 US20070056077A1 US11/598,616 US59861606A US2007056077A1 US 20070056077 A1 US20070056077 A1 US 20070056077A1 US 59861606 A US59861606 A US 59861606A US 2007056077 A1 US2007056077 A1 US 2007056077A1
- Authority
- US
- United States
- Prior art keywords
- stripe
- garment
- safety
- retroreflective
- safety garment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Images
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62B—DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
- A62B17/00—Protective clothing affording protection against heat or harmful chemical agents or for use at high altitudes
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D13/00—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
- A41D13/01—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches with reflective or luminous safety means
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/10—Impermeable to liquids, e.g. waterproof; Liquid-repellent
- A41D31/102—Waterproof and breathable
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/32—Retroreflective
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62B—DEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
- A62B99/00—Subject matter not provided for in other groups of this subclass
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/12—Reflex reflectors
- G02B5/122—Reflex reflectors cube corner, trihedral or triple reflector type
- G02B5/124—Reflex reflectors cube corner, trihedral or triple reflector type plural reflecting elements forming part of a unitary plate or sheet
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/12—Reflex reflectors
- G02B5/126—Reflex reflectors including curved refracting surface
- G02B5/128—Reflex reflectors including curved refracting surface transparent spheres being embedded in matrix
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S2/00—Apparel
- Y10S2/904—Polytetrafluoroethylene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24479—Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
- Y10T428/24521—Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness with component conforming to contour of nonplanar surface
- Y10T428/24545—Containing metal or metal compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
- Y10T428/2804—Next to metal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31554—Next to second layer of polyamidoester
Definitions
- This disclosure relates to retroreflective material, and more particularly retroreflective material for use on protective garments.
- Retroreflective materials have been developed for use in a variety of applications, including road signs, license plates, footwear, and clothing patches to name a few. Retroreflective materials are often used as high visibility trim materials in clothing to increase the visibility of the wearer. For example, retroreflective materials are often added to protective garments worn by firefighters, rescue personnel, EMS technicians, and the like.
- Retroreflectivity can be provided in a variety of ways, including by use of a layer of tiny glass beads or microspheres that cooperate with a reflective agent, such as a coated layer of aluminum.
- the beads can be partially embedded in a binder layer that holds the beads to fabric such that the beads are partially exposed to the atmosphere.
- Incident light entering the exposed portion of a bead is focused by the bead onto the reflective agent, which is typically disposed at the back of the bead embedded in the binder layer.
- the reflective agent reflects the incident light back through the bead, causing the light to exit through the exposed portion of the bead in a direction opposite the incident direction.
- Retroreflective materials can be particularly useful to increase the visibility of fire and rescue personnel during nighttime and twilight hours. In some situations, however, firefighter garments can be exposed to extreme temperatures during a fire, causing the retroreflective material to trap heat inside the garment. Under certain conditions, the trapped heat can result in discomfort or even burns to the skin of the firefighter.
- retroreflective material may expand rapidly when exposed to the extreme temperature from the fire. If the expanded moisture is unable to quickly permeate through the retroreflective material, the firefighter can be exposed to extreme temperatures. In some cases, this can result in steam burns on the skin of the firefighter underneath the portions of the garment having the retroreflective material.
- Conventional retroreflective materials including perforated retroreflective materials generally exhibit this phenomenon.
- conventional perforated retroreflective materials include standard retroreflective trim having needle punched holes, laser punched holes, slits, or relatively large holes made with a paper punch.
- this disclosure describes vapor permeable retroreflective material for use on protective garments.
- the material can be formed on the protective garment in a non-continuous pattern that provides a high-level of retroreflective brightness, yet also provides adequate permeability to prevent exposure to heated moisture and prolonged exposure to extreme temperatures.
- the non-continuous pattern may include retroreflective regions and non-retroreflective regions.
- the regions are arranged such that the retroreflective regions do not substantially decrease thermal decay or vapor permeability. Rather, vapor permeability and thermal decay through the protective garment may be substantially the same as if the retroreflective pattern was not present.
- a garment in one aspect, includes a protective outer layer such as an outer shell of a firefighter outfit, and a reflective material formed over a first portion of the protective outer layer.
- the retroreflective material can be formed in a non-continuous pattern to define retroreflective regions and non-retroreflective regions.
- Thermal decay through the first portion may be substantially equal to thermal decay through a second portion of the protective garment not covered by retroreflective material.
- vapor permeability through the first portion may be substantially equal to vapor permeability through a second portion of the protective garment not covered by retroreflective material.
- the garment may comprise an outer shell of a firefighter outfit and the first portion may comprise retroreflective trim on the outer shell of the firefighter outfit.
- the first portion formed with the non-continuous retroreflective pattern may have a reflective brightness greater than 50 candelas/(lux*meter 2 ) or even greater than 250 candelas/(lux*meter 2 ).
- a protective outfit in another aspect, includes a first layer, a second layer and a third layer.
- the first layer may be an outer shell including a non-continuous retroreflective portion that has retroreflective regions and non-retroreflective regions and a second portion that does not have retroreflective regions.
- vapor permeability and/or thermal decay through the non-continuous retroreflective portion may be substantially equal to vapor permeability through the second portion.
- the protective outfit may be a firefighter outfit in which the second layer is a moisture barrier and the third layer is a thermal liner.
- the protective outfit may be a thermal control outfit in which the second layer is a liquid retaining layer and the third layer is a waterproof vapor permeable layer.
- the non-continuous retroreflective portion may have a reflective brightness greater than 50 candelas/(lux*meter 2 ) or even greater than 250 candelas/(lux*meter 2 ).
- an article may include a first material, such as a durable cloth backing made of the same material as an outer shell of a firefighter outfit.
- the article may include retroreflective material formed on the first material according to a non-continuous pattern defining retroreflective regions and non-retroreflective regions.
- the retroreflective material can be arranged such that it does not substantially decrease thermal decay through the article.
- These retroreflective regions and vapor permeable non-retroreflective regions may form any of a variety of different configurations as described in greater detail below.
- the presence of the retroreflective regions may not substantially decrease thermal decay and or vapor permeability through the article.
- the article comprises a retroreflective patch for use on a garment.
- the material defining the non-continuous pattern may have a reflective brightness greater than 50 candelas/(lux*meter 2 ) or even greater than 250 candelas/(lux*meter 2 ).
- a method may include screen printing an adhesive pattern on a protective garment and pressing retroreflective beads on the adhesive pattern to create a retroreflective pattern.
- Vapor permeability and/or thermal decay through the protective garment in portions having the retroreflective pattern may be substantially the same as vapor permeability and/or thermal decay through the protective garment in portions of the garment that do not have the retroreflective pattern.
- a method may include mixing retroreflective beads into an adhesive material and screen printing a pattern on a protective garment using the mixture.
- vapor permeability and/or thermal decay through the protective garment in portions having the screened pattern may be substantially the same as vapor permeability and/or thermal decay through the protective garment in portions of the garment that do not have the screened pattern.
- Non-continuous vapor permeable material can provide several advantages.
- the non-continuous vapor permeable material can provide improved thermal and vapor transfer through protective garments having retroreflective material thereon.
- this disclosure provides techniques for fixing retroreflective material to protective garments without substantially effecting the permeability of the garment, thereby reducing the risk of injury due to heated moisture and extreme temperatures.
- the techniques described herein can provide improved thermal decay through an outer shell versus the use of conventional retroreflective material, such as perforated retroreflective material, thereby allowing any heat trapped within the protective outfit to escape.
- non-continuous retroreflective material advantages include the ability to use highly retroreflective material on a protective garment without risking potential injury to the wearer of the garment due to extreme temperatures.
- the use of retroreflective material is particularly important during nighttime and twilight hours when visibility is low.
- the disclosure below can provide for the creation of non-continuous retroreflective material having a reflective brightness greater than 50 candelas/(lux*meter 2 ) or even greater than 250 candelas/(lux*meter 2 ) without substantially changing the vapor permeability and thermal decay of the garment.
- retroreflective material on protective outfits using screen printing techniques or other techniques described herein can improve the production of protective outfits.
- the retroreflective patterns created as described below may be thinner and much less bulky that more conventional retroreflective material used on conventional protective garments.
- FIG. 1 illustrates a protective garment incorporating a non-continuous retroreflective material.
- FIGS. 2-5 further illustrate exemplary non-continuous vapor permeable retroreflective patterns.
- FIGS. 6 and 7 are flow diagrams illustrating processes for creating material having the non-continuous vapor permeable retroreflective patterns.
- FIG. 8 is a cross-sectional view of a multi-layer firefighter outfit that includes an outer shell incorporating a non-continuous retroreflective material.
- FIGS. 9 and 10 are graphs summarizing experimental data collected in testing the vapor permeability of a protective garment.
- FIGS. 11 and 12 are graphs summarizing experimental data collected in testing the thermal decay of heat escaping a protective garment.
- FIG. 13 is a graph of temperature differentials between various locations of various firefighter outfits showing thermal transfer characteristics of a garment incorporating non-continuous vapor permeable material in comparison to the prior art.
- FIG. 14 is a cross-sectional view of another protective outfit incorporating a non-continuous retroreflective material on an outer shell.
- this disclosure describes vapor permeable retroreflective material for use on protective garments.
- the material may include a non-continuous retroreflective pattern that provides a high-level of retroreflective brightness, yet provides adequate permeability to prevent exposure to heated moisture and extreme temperatures.
- this disclosure describes the garment itself, i.e., an outer layer or outer shell of a protective outfit.
- this disclosure describes an article, such as a clothing patch that could be added to a protective garment.
- this disclosure describes a protective outfit that includes the non-continuous retroreflective pattern on an outer shell and additional layers such as a thermal liner and a moisture barrier.
- the non-continuous retroreflective pattern may include retroreflective regions and non-retroreflective regions.
- the presence of retroreflective regions do not substantially decrease thermal decay or vapor permeability through the material.
- the thermal decay and vapor permeability through the material are not substantially reduced by the retroreflective pattern.
- vapor permeability and thermal decay through the material may be substantially the same as if the retroreflective pattern was not present.
- vapor permeability is a measure of the transfer rate of vapor through a material.
- Thermal decay is a measure of the rate at which heat can escape through a material.
- FIG. 1 illustrates a protective garment 10 such as an outer shell of a protective outfit worn by a firefighter.
- Protective garment 10 includes an outer shell having retroreflective material formed in a non-continuous pattern over a first portion 12 to define retroreflective regions and non-retroreflective regions.
- a second portion 14 does not have retroreflective regions.
- thermal decay through the first portion 12 is substantially equal to thermal decay through the second portion 14 .
- vapor permeability through the first portion 12 is substantially equal to thermal decay through the second portion 14 .
- First portion 12 may include an article, such as a clothing patch formed with a non-continuous retroreflective pattern, or alternatively, non-continuous retroreflective pattern may be printed directly onto the surface of protective garment 10 as discussed below. Importantly, unlike conventional retroreflective materials used with protective garments, first portion 12 does not trap heat or vapor inside protective garment 10 . Garment 10 may also include other non-retroreflective fluorescent material (not illustrated) to provide improved visibility of garment 10 during the day.
- FIGS. 2-5 illustrate a number of exemplary non-continuous patterns of retroreflective material formed on first portion 12 .
- retroreflective material may be applied in these and similar non-continuous patterns onto a patch or other material, which may be sewn or otherwise attached to protective garment 10 .
- the retroreflective material may be applied by screen printing or by heat transferring the material from a tape-like substance as described below.
- the retroreflective material may be applied directly onto protective garment 10 to realize first portion 12 .
- the patterns illustrated in FIGS. 2-5 are only exemplary, and other patterns could be used.
- FIG. 2 illustrates an example non-continuous pattern 20 defining retroreflective regions 22 and vapor permeable non-retroreflective regions 24 .
- the retroreflective regions 22 and the vapor permeable non-retroreflective regions 24 form a checkerboard-like configuration having a surface area of approximately fifty percent retroreflective material.
- the vapor permeable non-retroreflective regions 24 and the retroreflective regions 22 have sides measuring approximately 0.3175 centimeters. In that case, the retroreflective regions have surface areas substantially less than one square centimeter.
- non-continuous pattern 20 resolves this issue because the vapor permeable non-retroreflective regions 24 comprise a sufficient percentage of non-continuous pattern 20 , allowing vapor and heat to escape.
- the presence of non-retroreflective regions 24 reduces the reflective brightness of the pattern. For example, if non-retroreflective regions 24 account for 50 percent of the surface area of non-continuous pattern, the reflective brightness would be approximately 50 percent less than it would be if retroreflective materials were applied in a continuous pattern.
- the surface area of the non-retroreflective regions may need to comprise at least approximately 20% of a total surface area of the retroreflective material to ensure that vapor permeability and thermal decay through the garment are not increased.
- the examples of FIGS. 2-5 are all effective to allow vapor and heat to adequately escape.
- Non-retroreflective regions comprising greater than 20%, greater than 25%, and greater than 50% of the total surface area of the retroreflective material may be particularly effective.
- each retroreflective region may need to be sufficiently small to ensure that vapors and heat can escape through the material. Retroreflective regions having individual surface areas of less than four square centimeters and in some cases less than one square centimeter may be sufficient. This can help ensure that thermal decay and vapor permeability through portion 12 ( FIG. 1 ) formed with the non-continuous retroreflective pattern 20 ( FIG. 2 ) is substantially the same as thermal decay and vapor permeability through similar material, such as portion 14 that does not have any retroreflective regions 22 .
- FIG. 3 illustrates an example non-continuous pattern 30 defining retroreflective regions 32 and vapor permeable non-retroreflective regions 34 .
- the retroreflective regions 32 and the vapor permeable non-retroreflective regions 34 form a stripe like configuration.
- the non-retroreflective regions 34 comprise stripe-like regions that separate the retroreflective regions 32 .
- the stripe-like configuration may have a surface area comprising approximately sixty-six percent retroreflective regions 32 and approximately thirty-three percent vapor permeable non-retroreflective regions 34 .
- the non-retroreflective regions 34 are approximately 0.3175 centimeters wide and the retroreflective regions 32 are approximately 0.635 centimeters wide.
- Thermal decay and vapor permeability through portion 12 ( FIG. 1 ) formed with the non-continuous retroreflective pattern 30 is substantially the same as thermal decay and vapor permeability through similar material, such as portion 14 that does not have any retroreflective regions.
- FIG. 4 illustrates an example non-continuous pattern 40 defining retroreflective regions 42 and vapor permeable non-retroreflective regions 44 .
- the retroreflective regions 42 and the vapor permeable non-retroreflective regions 44 form a pattern with triangular shaped regions removed.
- the retroreflective regions 42 comprise approximately seventy-five percent of a surface area of the non-continuous pattern 40 .
- the retroreflective regions 42 comprise approximately fifty percent of a surface area of the non-continuous pattern 40 .
- Thermal decay and vapor permeability through portion 12 FIG.
- both the retroreflective regions and the non-retroreflective regions comprise triangular shaped regions.
- FIG. 5 illustrates an example non-continuous pattern 50 defining retroreflective regions 52 and vapor permeable non-retroreflective regions 54 .
- the retroreflective regions 52 comprise circular shaped regions within the non-retroreflective regions 54 .
- thermal decay and vapor permeability through portion 12 ( FIG. 1 ) formed with the non-continuous retroreflective pattern 50 is substantially the same as thermal decay and vapor permeability through similar material, such as portion 14 that does not have any retroreflective regions.
- FIG. 6 is a flow diagram illustrating a screen printing process that can be used to form non-continuous vapor permeable retroreflective patterns like those illustrated in FIGS. 2-5 .
- the pattern can be applied on a patch that can be sewn onto protective garment 10 ( FIG. 1 ).
- the pattern can be applied directly on a portion of garment 10 , thereby forming non-continuous retroreflective portion 12 .
- Vapor permeable retroreflective material can be formed by defining a non-continuous pattern ( 62 ), mixing retroreflective glass beads into a resin ( 64 ) and screen printing the mixture onto an article according to the defined pattern ( 66 ).
- the retroreflective beads may be half coated with aluminum. Suitable beads, for example, are #145 Reflective Glass Elements commercially available from Minnesota Mining and Manufacturing Company of St. Paul, Minn. After screen printing the mixture, the beads are oriented randomly within the resin. After screen printing the mixture, the mixture may be cured or dried according to a number of techniques.
- the reflective brightness that can be achieved by the process of FIG. 6 may be only approximately 25 candelas/(lux*meter 2 ) for total coverage because the beads are randomly oriented.
- Commonly assigned U.S. Pat. No. 5,269,840 provides additional details of one or more processes like that illustrated in FIG. 6 , and is hereby incorporated herein by reference in its entirety.
- Reflective brightness of retroreflective material is a measure of the apparent brightness of the article when viewed under standard retroreflective conditions, i.e., 0° orientation angle, ⁇ 4° entrance angle, and 0.2° observation angle. The brightness is normalized for the area of the article and the illumination from the light source used.
- the reflectivity or reflective brightness is also referred to as the coefficient of retroreflection (RA), and is expressed in units of candelas/(lux*meter 2 ).
- RA coefficient of retroreflection
- the reflective brightness of the vapor permeable retroreflective material is related to the percentage of the surface area comprising retroreflective regions. For example, if the pattern has a surface area defined by approximately fifty percent retroreflective regions and approximately fifty percent non-retroreflective regions, the reflective brightness may only be approximately 12.5 candelas/(lux*meter 2 ) if the technique of FIG. 6 is used. This may be bright enough for some applications, but not bright enough for others. For example, it can be desirable to maximize the reflective brightness of firefighting garments to better ensure that firefighters are seen by motorists during nighttime and twilight hours.
- FIG. 7 illustrates a process that can be used to create non-continuous retroreflective patterns like that illustrated in FIGS. 2-5 , wherein the reflective brightness is greater than 50 candelas/(lux*meter 2 ). In some cases, the brightness can be greater than 250 candelas/(lux*meter 2 ).
- the process of FIG. 7 involves defining a pattern ( 72 ) and screen printing an adhesive on a material according to the defined pattern ( 74 ).
- the material may comprise a portion of a protective garment or the material may comprise a patch for use with a protective garment.
- Retroreflective beads are then pressed on the adhesive pattern to create a retroreflective pattern ( 76 ).
- Pressing the retroreflective beads on the adhesive pattern ( 76 ) can be performed in a number of ways.
- glass beads are first deposited onto a substrate and the exposed surfaces of the beads are coated with aluminum.
- the substrate is then pressed onto the screened adhesive, fixing the beads in the adhesive.
- the substrate can then be peeled back, leaving the half-aluminum coated beads properly oriented in the adhesive.
- Such a method can achieve reflective brightness of approximately 500 candelas/(lux*meter 2 ) for total coverage.
- the reflective brightness of the material may be approximately 250 candelas/(lux*meter 2 ).
- the reflective brightness of the material may be approximately 330 candelas/(lux*meter 2 ). If the pattern defines seventy-five percent coverage, the reflective brightness of the material may be approximately 375 candelas/(lux*meter 2 ).
- 3M ScotchliteTM Silver Graphic Transfer Film commercially available from Minnesota Mining and Manufacturing Company of St. Paul, Minn.
- 3M Minnesota Mining and Manufacturing Company of St. Paul, Minn.
- Graphic images were made and transferred to KombatTM, fabric comprising PVI/Kevlar® blended fabric available from Southern Mills of Union City, Ga. The fabric with the graphic images was then tested. The graphic images were used as one example of a non-continuous retroreflective pattern. Specifically, the sample was prepared according to the following procedure.
- the 5720 Silver Graphic Transfer Film (SFEE1134-3-2-1A with polyester carrier) was screen printed with SX 779B FR Printable Adhesive (fire retardant SX 864B plastisol ink) available from Plast-O-Meric SP, Inc., Hampshire, Wis., modified with 3MTM 571N Coupler (A-1120 silane, 4% by weight).
- the ink was printed through a 110 Tin (43.3 T/cm) printing screen with a medium hardness squeegee onto the 5720 Graphic Transfer Film using a Cameo printer available from American M & M Screen Printing Equipment of Oshkosh, Wis.
- the artwork of the screen consisted of three stripes with different graphic patterns (checker board, hash-marks, and circles).
- the resulting prints were gelled by passing them through a TexairTM Model 30 conveyor oven available from American Screen Printing Equipment Co., Chicago, Ill., having a belt temperature of 230 degrees Fahrenheit (110 degrees Centigrade). The oven was heated by an IR panel set at 1100 degrees Fahrenheit (593 degrees Centigrade), and the belt temperature was controlled by belt speed. After gelation, the printed graphic images, were laminated to KombatTM fabric using a HIX N-800 press available from HIX Corp. of Pittsburg, Kans., set at 340 degrees Fahrenheit (171 degrees Centigrade) for 30 seconds at an air line pressure of 40 psi (276 kPa).
- Another way of pressing the retroreflective beads on the adhesive pattern comprises depositing fully aluminum-coated beads onto the adhesive and then etching the aluminum from the exposed surfaces of the beads. Such a process can be continuous, and the need to peel back and discard a substrate is avoided. Additional details of this process are provided in copending and commonly assigned published PCT Application number WO0142823 (A1), the entire content of which is hereby incorporated by reference.
- the process can achieve a reflective brightness of approximately 350 candelas/(lux*meter 2 ) or greater for total coverage. Thus, if the pattern defines fifty percent coverage, the reflective brightness of the material may be approximately 175 candelas/(lux*meter 2 ).
- the reflective brightness of the material may be approximately 231 candelas/(lux*meter 2 ). If the pattern defines seventy-five percent coverage, the reflective brightness of the material may be approximately 263 candelas/(lux*meter 2 ).
- a non-continuous vapor permeable retroreflective material having patterns like those illustrated in FIGS. 2-5 can be created as follows. Glass beads are first deposited and bonded onto a substrate and the exposed surfaces of the beads are coated with aluminum. An adhesive is then applied on top of the glass beads, creating a retroreflective tape-like substance. The pattern can then be cut into the tape-like substance before pressing the tape-like substance onto a material such as a patch or the outer shell of a firefighter outfit. Heat and pressure can be applied and the substrate can then be peeled back leaving the pattern of half-aluminum coated beads properly oriented in the adhesive and attached to the underlying material to define the non-continuous vapor permeable retroreflective material.
- 8710 3MTM ScotchliteTM Silver Transfer Film commercially available from 3M was also used to realize non-continuous vapor permeable material.
- 8710 Silver Graphic Images were made and transferred to a Nomex® outer shell material available from Southern Mills of Union City, Ga. The Nomex® outer shell material was then tested. The graphic images were used as another example of a non-continuous vapor permeable retroreflective material.
- the 8710 Silver Graphic Images were prepared according to the following procedure.
- the 8710 Silver Transfer Film (75-0001-6745-4) graphic images were plotter cut, the weed was removed, and the material was then laminated to Nomex® outer shell material using a HIX N-800 press available from HEX Corp. of Pittsburg, Kans., set at 338 degrees Fahrenheit (170 Centigrade) for 15 seconds at an air line pressure of 40 psi (276 kPa).
- the paper carrier was removed, yielding silver graphic images on the Nomex® outer shell material.
- This material containing silver images was attached (by sewing in upper right-hand corner) to other layers that make up a protective outfit. This complete assembly was then tested according to a procedures that substantially conformed standard industry testing procedures.
- Non-continuous vapor permeable retroreflective materials created as described above exhibit thermal decay properties and vapor permeability properties that have not been achieved in the prior art.
- the thermal decay and vapor permeability through non-continuous retroreflective material may be the same as the underlying material.
- the addition of the patterns of retroreflective material does not substantially alter either the vapor permeability of the material or the thermal decay through the material. For this reason, the non-continuous vapor permeable retroreflective material can improve the performance of protective firefighter garments.
- Providing retroreflective material on protective garments using screen printing techniques or non-continuous retroreflective tape like substances that are heat applied can improve the production process associated with the creation of protective garments.
- the non-continuous retroreflective patterns may be thinner and much less bulky that more conventional retroreflective material used on conventional protective garments.
- the resultant non-continuous vapor permeable retroreflective material can be non-perforated, thus avoiding any perforation steps in the production process.
- FIG. 8 is a cross-sectional view a multi-layer protective firefighter outfit.
- Firefighter outfit 80 includes an outer shell 82 , having a retroreflective portion 84 thereon.
- Firefighter outfit 80 also includes moisture barrier 86 and thermal liner 88 .
- Retroreflective portion 84 carries retroreflective material formed in a non-continuous pattern.
- Portion 84 may be a patch that is sewn or otherwise attached to outer shell 82 .
- portion 84 may include a non-continuous retroreflective pattern screened directly on outer shell 82 as described above.
- Outer shell 82 represents a typical outer shell used in firefighter protective outfits.
- outer shell may protect the firefighter from scrapes or abrasions and may be coated with a water repellent or the like.
- KombatTM fabric comprising PVI/Kevlar® blended fabric available from Southern Mills of Union City, Ga.
- Moisture barrier 86 can be used to keep liquid from penetrating into thermal liner 88 .
- Older firefighter outfits used moisture barriers that were vapor impervious. However, newer designs have utilized moisture barriers that are vapor permeable to provide added comfort to the wearer. If moisture barrier 86 is vapor permeable, hot vapors may be able to penetrate to the skin of the wearer, causing discomfort or burns if the vapors cannot escape through the outer shell or through the outer shell equipped with retroreflective material. Indeed, the use of vapor permeable moisture barriers is one of the underlying reasons that called for the non-continuous vapor permeable retroreflective material.
- An example of a suitable vapor permeable moisture barrier is CrosstechTM material on Nomex® pajama check material available from W. L. Gore of Elkton, Md.
- Thermal liner 88 can be used to protect the wearer from extreme temperatures.
- An example of a suitable thermal liner is Aralite® material including 100% Kevlar® batt with 100% Nomax® face cloth, available from Southern Mills of Union City, Ga.
- FIGS. 9 and 10 are graphs summarizing experimental data collected in testing the vapor permeability of prior art firefighter garments and firefighter garments making use of a retroreflective material formed in a non-continuous pattern.
- the various testing and experiments described below substantially conformed to the industry standard testing methods described in the above-mentioned references.
- FIG. 9 illustrates the vapor permeability of a prior art construction that utilizes a retroreflective standard trim material rather than a non-continuous vapor permeable retroreflective material for portion 84 ( FIG. 8 ).
- FIG. 10 illustrates the vapor permeability of a garment utilizing retroreflective material formed in a non-continuous pattern on portion 84 . In both cases, the respective garment was subjected to heat, and temperatures at particular points within the respective garment were recorded over time.
- line 92 graphs temperature as a function of time measured at point C ( FIG. 8 ) of a firefighter garment using a prior art retroreflective standard trim material rather than a non-continuous vapor permeable retroreflective material for portion 84 .
- line 94 illustrates temperature measured at point D of a prior art firefighter garment. Notably, after approximately 70 seconds, the temperature at point C becomes hotter than the temperature at point D. This is due, at least in part, to the fact that hot vapors were unable to adequately permeate through the prior art retroreflective material, and were driven down through the vapor permeable moisture barrier 86 and condensed, quickly raising the temperature at point C. In the experiments, the mass transfer of hot vapors was visually apparent as moisture condensed on the thermal liner 88 in the regions covered by the prior art retroreflective material. Notably, prior art retroreflective material having perforations showed similar results.
- line 102 graphs temperature as a function of time measured at point C ( FIG. 8 ) of a firefighter garment having a non-continuous vapor permeable retroreflective material for portion 84 .
- Line 104 graphs temperature as a function of time measured at point D of a firefighter garment including retroreflective material formed in a non-continuous pattern as described herein. As shown, the temperature at point C remains cooler than the temperature at point D at all times, due to the dissipation of the hot vapors developed from water retained under outer shell through portion 84 . In other words, hot vapors were able to adequately permeate through non-continuous retroreflective material, i.e., portion 84 .
- FIGS. 11 and 12 are graphs summarizing experimental data collected in testing the thermal decay of heat escaping a firefighter garment. Again, industry standard testing methods were used.
- FIG. 11 shows the thermal decay of a prior art construction that utilizes a retroreflective standard trim material rather than a non-continuous vapor permeable retroreflective material for portion 84 .
- FIG. 12 illustrates the thermal decay of a garment utilizing a non-continuous vapor permeable retroreflective material for portion 84 .
- line 112 graphs temperature as a function of time measured at point A ( FIG. 8 ) of a prior art firefighter garment.
- the prior art firefighter garment utilized retroreflective standard trim material rather than a non-continuous vapor permeable retroreflective material for portion 84 .
- the thermal decay of the temperature at point A is less than the thermal decay of the temperature at point B.
- the prior art retroreflective standard trim material reduced the rate of thermal decay through the outer shell. Heat was trapped inside the garment longer in the regions that correspond to the prior art retroreflective standard trim material.
- line 122 graphs temperature as a function of time measured at point A ( FIG. 8 ) of firefighter garment having a non-continuous vapor permeable retroreflective material for portion 84 .
- Line 124 graphs temperature as a function of time measured at point B of the firefighter garment including retroreflective material formed in a non-continuous pattern as described herein.
- the thermal decay of the temperature at point A is approximately the same as the thermal decay of the temperature at point B.
- non-continuous vapor permeable retroreflective material does not substantially decrease the thermal decay through the outer shell of the firefighter garment. Heat was not trapped inside the garment for longer periods of time in the regions that correspond to the non-continuous vapor permeable retroreflective material.
- FIG. 13 is a graph of temperature differentials between points A and B ( FIG. 8 ) for various different firefighter garments, i.e. a graph of the temperature at point A minus the temperature at point B over time.
- Line 132 corresponds to a prior art firefighter garment incorporating standard continuous non-perforated retroreflective trim.
- the temperature differential between the temperature under the outer shell versus the temperature under the outer shell with the standard retroreflective trim is relatively large. For example, after approximately 50 seconds, it was approximately 50 degrees Centigrade hotter behind the standard trim. Again, this is due to the fact that heat cannot adequately escape through the standard retroreflective trim.
- Line 134 corresponds to a prior art firefighter garment incorporating standard continuous perforated retroreflective trim.
- the temperature differential between the temperature under the outer shell versus the temperature under the outer shell with the standard continuous perforated retroreflective trim is still relatively large. In other words, perforations do not resolve the thermal decay issue. For example, after approximately 50 seconds, it was approximately 42 degrees Centigrade hotter behind the standard continuous perforated retroreflective trim. Again, this is due to the fact that heat cannot adequately escape through the standard continuous perforated retroreflective trim.
- Line 136 corresponds to a firefighter garment, incorporating a non-continuous vapor permeable retroreflective material for portion 84 ( FIG. 8 ).
- the temperature differential between the temperature under the outer shell both with and without the non-continuous retroreflective material is much smaller than that of lines 132 or 134 .
- non-continuous vapor permeable retroreflective material resolved the thermal decay issue. For example, after approximately 50 seconds, it was only approximately 4 degrees Centigrade hotter behind the non-continuous vapor permeable retroreflective material compared to the underlying material not having retroreflective material formed thereon.
- the graphs of FIGS. 9-13 illustrate the advantages of retroreflective material formed in a non-continuous pattern, in relation to the prior art.
- the retroreflective material formed in a non-continuous pattern as described herein provides improved thermal transfer and/or vapor transfer through protective garments having retroreflective material thereon.
- Conventional retroreflective material such as retroreflective trim materials and perforated retroreflective trim materials provide inadequate thermal decay and vapor permeability characteristics.
- Non-continuous vapor permeable retroreflective material exhibits substantially the same thermal decay characteristics and vapor permeability characteristics as the underlying material without the retroreflective material.
- Firefighter garments and thus multi-layer firefighter outfits, can be greatly improved by implementing non-continuous vapor permeable retroreflective material. If vapor cannot escape thought the outer shell because conventional retroreflective material provides a vapor barrier, hot vapors can be directed inward, toward the skin of the wearer, possibly causing steam burns or other discomfort to the wearer.
- the techniques described herein resolve this issue by providing a retroreflective material formed in a non-continuous pattern to define retroreflective regions and non-retroreflective regions. In this manner, the addition of retroreflective material does not substantially decrease vapor permeability of the outer shell.
- Thermal decay through an outer shell having conventional retroreflective trim material is substantially less than thermal decay through the outer shell in regions not having the conventional retroreflective trim material.
- heat trapped within the protective garment may not be able to escape fast enough for the firefighter to cool off at a desired rate.
- conventional retroreflective material such as perforated retroreflective trim material can cause heat to remain trapped inside the protective garment for longer periods of time, providing discomfort to the firefighter even after he or she has left the fire.
- the techniques described herein resolve this issue by providing a non-continuous vapor permeable retroreflective material that does not substantially decrease thermal decay of the garment in the portions having the non-continuous vapor permeable retroreflective material.
- the vapor permeable retroreflective material can reduce the heat load within the various layers that comprise the firefighter outfit, reduce negative physiological impacts on the wearer, and reduce the likelihood of producing burn injuries on the wearer.
- the techniques described herein can provide non-continuous vapor permeable retroreflective material having a reflective brightness greater than 50 candelas/(lux*meter 2 ) or even greater than 250 candelas/(lux*meter 2 ). Brightnesses in these ranges significantly increase visibility of a wearer during nighttime and twilight hours. Indeed, this can better ensure that firefighters are not only seen by night motorists, but more importantly, these brightness ranges can be achieved while still providing the vapor permeability and thermal decay characteristics described above.
- FIG. 14 is a cross-sectional view of another protective multi-layer outfit that could benefit by the teaching of this disclosure.
- Protective outfit 140 is a protective multi layer thermal control outfit.
- Protective outfit 140 includes an outer shell 142 , and a non-continuous vapor permeable retroreflective material defines portion 144 of outer shell 142 .
- portion 144 may be a patch that is sewn or otherwise attached to outer shell 142 , or alternatively, portion 144 may be a portion of outer shell 142 having a non-continuous retroreflective pattern applied thereon as described above.
- Protective outfit 140 also includes liquid retaining layer 146 and waterproof vapor permeable layer 148 .
- Protective outfit 140 may be used to keep the wearer cool through the effects of evaporative cooling and by acting as a heat sink.
- the liquid retaining layer 146 can be soaked with water and water vapors can permeate through the outer shell 142 to cool the skin of the wearer.
- the outfit makes use of non-continuous vapor permeable retroreflective material to define portion 144 of outer shell 142 . In this manner, the thermal transfer characteristics and vapor permeability characteristics of protective outfit 140 can be maintained while adding the effects of nighttime visibility through the use of retroreflective materials.
- non-continuous vapor permeable retroreflective material having retroreflective regions and non-retroreflective regions has been described.
- Thermal decay and vapor permeability through the non-continuous vapor permeable retroreflective material is substantially the same as thermal decay and vapor permeability through the underlying material that does not include non-continuous vapor permeable retroreflective material.
- non-continuous vapor permeable retroreflective material could be included in as part of any garment to provide retroreflectively in the garment and yet also provide adequate thermal decay and vapor permeability through the garment.
- the non-continuous vapor permeable retroreflective material could substantially or completely cover a garment or article.
- the retroreflective material may be made florescent to enhance daytime visibility.
- alternative methods may be used to realize non-continuous vapor permeable retroreflective material.
Landscapes
- Health & Medical Sciences (AREA)
- Textile Engineering (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Emergency Management (AREA)
- Business, Economics & Management (AREA)
- Physics & Mathematics (AREA)
- Physical Education & Sports Medicine (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Toxicology (AREA)
- Professional, Industrial, Or Sporting Protective Garments (AREA)
- Laminated Bodies (AREA)
- Details Of Garments (AREA)
Abstract
The disclosure describes vapor permeable retroreflective material for use on protective garments. The material may be formed in a non-continuous pattern that provides a high-level of retroreflective brightness, yet also provides adequate permeability to prevent exposure to trapped thermal energy and heated moisture. The non-continuous retroreflective pattern may include retroreflective regions and non-retroreflective regions arranged such that thermal decay through the protective garment is not substantially decreased in the regions corresponding to the retroreflective material. Rather, vapor permeation and thermal decay through the garment may be substantially the same as if the retroreflective material was not present.
Description
- This disclosure relates to retroreflective material, and more particularly retroreflective material for use on protective garments.
- Retroreflective materials have been developed for use in a variety of applications, including road signs, license plates, footwear, and clothing patches to name a few. Retroreflective materials are often used as high visibility trim materials in clothing to increase the visibility of the wearer. For example, retroreflective materials are often added to protective garments worn by firefighters, rescue personnel, EMS technicians, and the like.
- Retroreflectivity can be provided in a variety of ways, including by use of a layer of tiny glass beads or microspheres that cooperate with a reflective agent, such as a coated layer of aluminum. The beads can be partially embedded in a binder layer that holds the beads to fabric such that the beads are partially exposed to the atmosphere. Incident light entering the exposed portion of a bead is focused by the bead onto the reflective agent, which is typically disposed at the back of the bead embedded in the binder layer. The reflective agent reflects the incident light back through the bead, causing the light to exit through the exposed portion of the bead in a direction opposite the incident direction.
- Retroreflective materials can be particularly useful to increase the visibility of fire and rescue personnel during nighttime and twilight hours. In some situations, however, firefighter garments can be exposed to extreme temperatures during a fire, causing the retroreflective material to trap heat inside the garment. Under certain conditions, the trapped heat can result in discomfort or even burns to the skin of the firefighter.
- In particular, moisture collected under the retroreflective material may expand rapidly when exposed to the extreme temperature from the fire. If the expanded moisture is unable to quickly permeate through the retroreflective material, the firefighter can be exposed to extreme temperatures. In some cases, this can result in steam burns on the skin of the firefighter underneath the portions of the garment having the retroreflective material. Conventional retroreflective materials, including perforated retroreflective materials generally exhibit this phenomenon. For example, conventional perforated retroreflective materials include standard retroreflective trim having needle punched holes, laser punched holes, slits, or relatively large holes made with a paper punch.
- In general, this disclosure describes vapor permeable retroreflective material for use on protective garments. For example, the material can be formed on the protective garment in a non-continuous pattern that provides a high-level of retroreflective brightness, yet also provides adequate permeability to prevent exposure to heated moisture and prolonged exposure to extreme temperatures.
- In particular, the non-continuous pattern may include retroreflective regions and non-retroreflective regions. The regions are arranged such that the retroreflective regions do not substantially decrease thermal decay or vapor permeability. Rather, vapor permeability and thermal decay through the protective garment may be substantially the same as if the retroreflective pattern was not present.
- In one aspect, a garment includes a protective outer layer such as an outer shell of a firefighter outfit, and a reflective material formed over a first portion of the protective outer layer. The retroreflective material can be formed in a non-continuous pattern to define retroreflective regions and non-retroreflective regions. Thermal decay through the first portion may be substantially equal to thermal decay through a second portion of the protective garment not covered by retroreflective material. Alternatively or additionally, vapor permeability through the first portion may be substantially equal to vapor permeability through a second portion of the protective garment not covered by retroreflective material. The garment may comprise an outer shell of a firefighter outfit and the first portion may comprise retroreflective trim on the outer shell of the firefighter outfit. In some aspects, the first portion formed with the non-continuous retroreflective pattern may have a reflective brightness greater than 50 candelas/(lux*meter2) or even greater than 250 candelas/(lux*meter2).
- In another aspect, a protective outfit includes a first layer, a second layer and a third layer. The first layer may be an outer shell including a non-continuous retroreflective portion that has retroreflective regions and non-retroreflective regions and a second portion that does not have retroreflective regions. Moreover, vapor permeability and/or thermal decay through the non-continuous retroreflective portion may be substantially equal to vapor permeability through the second portion. The protective outfit may be a firefighter outfit in which the second layer is a moisture barrier and the third layer is a thermal liner. Alternatively, the protective outfit may be a thermal control outfit in which the second layer is a liquid retaining layer and the third layer is a waterproof vapor permeable layer. Again, the non-continuous retroreflective portion may have a reflective brightness greater than 50 candelas/(lux*meter2) or even greater than 250 candelas/(lux*meter2).
- In other aspects, an article may include a first material, such as a durable cloth backing made of the same material as an outer shell of a firefighter outfit. In addition, the article may include retroreflective material formed on the first material according to a non-continuous pattern defining retroreflective regions and non-retroreflective regions. The retroreflective material can be arranged such that it does not substantially decrease thermal decay through the article. These retroreflective regions and vapor permeable non-retroreflective regions may form any of a variety of different configurations as described in greater detail below. The presence of the retroreflective regions may not substantially decrease thermal decay and or vapor permeability through the article. In one particular case, the article comprises a retroreflective patch for use on a garment. The material defining the non-continuous pattern may have a reflective brightness greater than 50 candelas/(lux*meter2) or even greater than 250 candelas/(lux*meter2).
- In still other aspects, this disclosure describes one or more methods. For example, a method may include screen printing an adhesive pattern on a protective garment and pressing retroreflective beads on the adhesive pattern to create a retroreflective pattern. Vapor permeability and/or thermal decay through the protective garment in portions having the retroreflective pattern may be substantially the same as vapor permeability and/or thermal decay through the protective garment in portions of the garment that do not have the retroreflective pattern.
- Alternatively, a method may include mixing retroreflective beads into an adhesive material and screen printing a pattern on a protective garment using the mixture. Again, vapor permeability and/or thermal decay through the protective garment in portions having the screened pattern may be substantially the same as vapor permeability and/or thermal decay through the protective garment in portions of the garment that do not have the screened pattern.
- Non-continuous vapor permeable material can provide several advantages. In particular, unlike conventional retroreflective material, including perforated retroreflective material, the non-continuous vapor permeable material can provide improved thermal and vapor transfer through protective garments having retroreflective material thereon. Unlike conventional perforated retroreflective material that can decrease vapor permeability and thermal decay, this disclosure provides techniques for fixing retroreflective material to protective garments without substantially effecting the permeability of the garment, thereby reducing the risk of injury due to heated moisture and extreme temperatures. In addition, the techniques described herein can provide improved thermal decay through an outer shell versus the use of conventional retroreflective material, such as perforated retroreflective material, thereby allowing any heat trapped within the protective outfit to escape.
- Other advantages of the non-continuous retroreflective material include the ability to use highly retroreflective material on a protective garment without risking potential injury to the wearer of the garment due to extreme temperatures. The use of retroreflective material is particularly important during nighttime and twilight hours when visibility is low. The disclosure below can provide for the creation of non-continuous retroreflective material having a reflective brightness greater than 50 candelas/(lux*meter2) or even greater than 250 candelas/(lux*meter2) without substantially changing the vapor permeability and thermal decay of the garment.
- In addition, providing retroreflective material on protective outfits using screen printing techniques or other techniques described herein can improve the production of protective outfits. Moreover, the retroreflective patterns created as described below may be thinner and much less bulky that more conventional retroreflective material used on conventional protective garments.
- Additional details of these and other embodiments are set forth in the accompanying drawings and the description below. Other features, objects and advantages will become apparent from the description and drawings, and from the claims.
-
FIG. 1 illustrates a protective garment incorporating a non-continuous retroreflective material. -
FIGS. 2-5 further illustrate exemplary non-continuous vapor permeable retroreflective patterns. -
FIGS. 6 and 7 are flow diagrams illustrating processes for creating material having the non-continuous vapor permeable retroreflective patterns. -
FIG. 8 is a cross-sectional view of a multi-layer firefighter outfit that includes an outer shell incorporating a non-continuous retroreflective material. -
FIGS. 9 and 10 are graphs summarizing experimental data collected in testing the vapor permeability of a protective garment. -
FIGS. 11 and 12 are graphs summarizing experimental data collected in testing the thermal decay of heat escaping a protective garment. -
FIG. 13 is a graph of temperature differentials between various locations of various firefighter outfits showing thermal transfer characteristics of a garment incorporating non-continuous vapor permeable material in comparison to the prior art. -
FIG. 14 is a cross-sectional view of another protective outfit incorporating a non-continuous retroreflective material on an outer shell. - In general, this disclosure describes vapor permeable retroreflective material for use on protective garments. The material may include a non-continuous retroreflective pattern that provides a high-level of retroreflective brightness, yet provides adequate permeability to prevent exposure to heated moisture and extreme temperatures.
- In some cases, this disclosure describes the garment itself, i.e., an outer layer or outer shell of a protective outfit. In other cases, this disclosure describes an article, such as a clothing patch that could be added to a protective garment. In still other cases, this disclosure describes a protective outfit that includes the non-continuous retroreflective pattern on an outer shell and additional layers such as a thermal liner and a moisture barrier.
- The non-continuous retroreflective pattern may include retroreflective regions and non-retroreflective regions. However, unlike conventional retroreflective material, the presence of retroreflective regions do not substantially decrease thermal decay or vapor permeability through the material. In other words, the thermal decay and vapor permeability through the material are not substantially reduced by the retroreflective pattern. Rather, vapor permeability and thermal decay through the material may be substantially the same as if the retroreflective pattern was not present. In general, vapor permeability is a measure of the transfer rate of vapor through a material. Thermal decay is a measure of the rate at which heat can escape through a material.
-
FIG. 1 illustrates aprotective garment 10 such as an outer shell of a protective outfit worn by a firefighter.Protective garment 10 includes an outer shell having retroreflective material formed in a non-continuous pattern over afirst portion 12 to define retroreflective regions and non-retroreflective regions. Asecond portion 14 does not have retroreflective regions. As described in greater detail below, thermal decay through thefirst portion 12 is substantially equal to thermal decay through thesecond portion 14. In addition, vapor permeability through thefirst portion 12 is substantially equal to thermal decay through thesecond portion 14. -
First portion 12 may include an article, such as a clothing patch formed with a non-continuous retroreflective pattern, or alternatively, non-continuous retroreflective pattern may be printed directly onto the surface ofprotective garment 10 as discussed below. Importantly, unlike conventional retroreflective materials used with protective garments,first portion 12 does not trap heat or vapor insideprotective garment 10.Garment 10 may also include other non-retroreflective fluorescent material (not illustrated) to provide improved visibility ofgarment 10 during the day. -
FIGS. 2-5 illustrate a number of exemplary non-continuous patterns of retroreflective material formed onfirst portion 12. In particular, retroreflective material may be applied in these and similar non-continuous patterns onto a patch or other material, which may be sewn or otherwise attached toprotective garment 10. For example, the retroreflective material may be applied by screen printing or by heat transferring the material from a tape-like substance as described below. In some aspects, the retroreflective material may be applied directly ontoprotective garment 10 to realizefirst portion 12. Of course, the patterns illustrated inFIGS. 2-5 are only exemplary, and other patterns could be used. -
FIG. 2 illustrates an examplenon-continuous pattern 20 definingretroreflective regions 22 and vapor permeablenon-retroreflective regions 24. In this arrangement, theretroreflective regions 22 and the vapor permeablenon-retroreflective regions 24 form a checkerboard-like configuration having a surface area of approximately fifty percent retroreflective material. In one particular case, the vapor permeablenon-retroreflective regions 24 and theretroreflective regions 22 have sides measuring approximately 0.3175 centimeters. In that case, the retroreflective regions have surface areas substantially less than one square centimeter. - Conventional retroreflective materials can substantially reduce vapor permeability and thermal decay through garments. The use of
non-continuous pattern 20 resolves this issue because the vapor permeablenon-retroreflective regions 24 comprise a sufficient percentage ofnon-continuous pattern 20, allowing vapor and heat to escape. The presence ofnon-retroreflective regions 24, however, reduces the reflective brightness of the pattern. For example, ifnon-retroreflective regions 24 account for 50 percent of the surface area of non-continuous pattern, the reflective brightness would be approximately 50 percent less than it would be if retroreflective materials were applied in a continuous pattern. - The surface area of the non-retroreflective regions may need to comprise at least approximately 20% of a total surface area of the retroreflective material to ensure that vapor permeability and thermal decay through the garment are not increased. The examples of
FIGS. 2-5 are all effective to allow vapor and heat to adequately escape. Non-retroreflective regions comprising greater than 20%, greater than 25%, and greater than 50% of the total surface area of the retroreflective material may be particularly effective. - Another factor that can affect vapor permeability and thermal decay may be the size of each individual retroreflective region and each individual non-retroreflective region. In particular, each retroreflective region may need to be sufficiently small to ensure that vapors and heat can escape through the material. Retroreflective regions having individual surface areas of less than four square centimeters and in some cases less than one square centimeter may be sufficient. This can help ensure that thermal decay and vapor permeability through portion 12 (
FIG. 1 ) formed with the non-continuous retroreflective pattern 20 (FIG. 2 ) is substantially the same as thermal decay and vapor permeability through similar material, such asportion 14 that does not have anyretroreflective regions 22. -
FIG. 3 illustrates an examplenon-continuous pattern 30 definingretroreflective regions 32 and vapor permeablenon-retroreflective regions 34. In this arrangement, theretroreflective regions 32 and the vapor permeablenon-retroreflective regions 34 form a stripe like configuration. In other words, thenon-retroreflective regions 34 comprise stripe-like regions that separate theretroreflective regions 32. The stripe-like configuration may have a surface area comprising approximately sixty-six percentretroreflective regions 32 and approximately thirty-three percent vapor permeablenon-retroreflective regions 34. In one particular case, thenon-retroreflective regions 34 are approximately 0.3175 centimeters wide and theretroreflective regions 32 are approximately 0.635 centimeters wide. Thermal decay and vapor permeability through portion 12 (FIG. 1 ) formed with the non-continuousretroreflective pattern 30 is substantially the same as thermal decay and vapor permeability through similar material, such asportion 14 that does not have any retroreflective regions. -
FIG. 4 illustrates an examplenon-continuous pattern 40 definingretroreflective regions 42 and vapor permeablenon-retroreflective regions 44. In this arrangement, theretroreflective regions 42 and the vapor permeablenon-retroreflective regions 44 form a pattern with triangular shaped regions removed. In one case, theretroreflective regions 42 comprise approximately seventy-five percent of a surface area of thenon-continuous pattern 40. In another case, theretroreflective regions 42 comprise approximately fifty percent of a surface area of thenon-continuous pattern 40. Thermal decay and vapor permeability through portion 12 (FIG. 1 ) formed with the non-continuousretroreflective pattern 40 is substantially the same as thermal decay and vapor permeability through similar material, such asportion 14 that does not have any retroreflective regions. In still other aspects, both the retroreflective regions and the non-retroreflective regions comprise triangular shaped regions. -
FIG. 5 illustrates an examplenon-continuous pattern 50 definingretroreflective regions 52 and vapor permeablenon-retroreflective regions 54. In this arrangement, theretroreflective regions 52 comprise circular shaped regions within thenon-retroreflective regions 54. Notably, thermal decay and vapor permeability through portion 12 (FIG. 1 ) formed with the non-continuousretroreflective pattern 50 is substantially the same as thermal decay and vapor permeability through similar material, such asportion 14 that does not have any retroreflective regions. -
FIG. 6 is a flow diagram illustrating a screen printing process that can be used to form non-continuous vapor permeable retroreflective patterns like those illustrated inFIGS. 2-5 . As discussed above, the pattern can be applied on a patch that can be sewn onto protective garment 10 (FIG. 1 ). Alternatively, the pattern can be applied directly on a portion ofgarment 10, thereby forming non-continuousretroreflective portion 12. - Vapor permeable retroreflective material can be formed by defining a non-continuous pattern (62), mixing retroreflective glass beads into a resin (64) and screen printing the mixture onto an article according to the defined pattern (66). The retroreflective beads may be half coated with aluminum. Suitable beads, for example, are #145 Reflective Glass Elements commercially available from Minnesota Mining and Manufacturing Company of St. Paul, Minn. After screen printing the mixture, the beads are oriented randomly within the resin. After screen printing the mixture, the mixture may be cured or dried according to a number of techniques. The reflective brightness that can be achieved by the process of
FIG. 6 may be only approximately 25 candelas/(lux*meter2) for total coverage because the beads are randomly oriented. Commonly assigned U.S. Pat. No. 5,269,840 provides additional details of one or more processes like that illustrated inFIG. 6 , and is hereby incorporated herein by reference in its entirety. - Reflective brightness of retroreflective material is a measure of the apparent brightness of the article when viewed under standard retroreflective conditions, i.e., 0° orientation angle, −4° entrance angle, and 0.2° observation angle. The brightness is normalized for the area of the article and the illumination from the light source used. The reflectivity or reflective brightness is also referred to as the coefficient of retroreflection (RA), and is expressed in units of candelas/(lux*meter2). Reference is made to ASTM Standard Method #808-94, “Standard Practice For Describing Retroreflection.”
- As mentioned above, the reflective brightness of the vapor permeable retroreflective material is related to the percentage of the surface area comprising retroreflective regions. For example, if the pattern has a surface area defined by approximately fifty percent retroreflective regions and approximately fifty percent non-retroreflective regions, the reflective brightness may only be approximately 12.5 candelas/(lux*meter2) if the technique of
FIG. 6 is used. This may be bright enough for some applications, but not bright enough for others. For example, it can be desirable to maximize the reflective brightness of firefighting garments to better ensure that firefighters are seen by motorists during nighttime and twilight hours. -
FIG. 7 illustrates a process that can be used to create non-continuous retroreflective patterns like that illustrated inFIGS. 2-5 , wherein the reflective brightness is greater than 50 candelas/(lux*meter2). In some cases, the brightness can be greater than 250 candelas/(lux*meter2). - The process of
FIG. 7 involves defining a pattern (72) and screen printing an adhesive on a material according to the defined pattern (74). For example, the material may comprise a portion of a protective garment or the material may comprise a patch for use with a protective garment. Retroreflective beads are then pressed on the adhesive pattern to create a retroreflective pattern (76). - Pressing the retroreflective beads on the adhesive pattern (76) can be performed in a number of ways. In one case, glass beads are first deposited onto a substrate and the exposed surfaces of the beads are coated with aluminum. The substrate is then pressed onto the screened adhesive, fixing the beads in the adhesive. The substrate can then be peeled back, leaving the half-aluminum coated beads properly oriented in the adhesive. Such a method can achieve reflective brightness of approximately 500 candelas/(lux*meter2) for total coverage. Thus, if the pattern defines fifty percent coverage, the reflective brightness of the material may be approximately 250 candelas/(lux*meter2). If the pattern defines sixty-six percent coverage, the reflective brightness of the material may be approximately 330 candelas/(lux*meter2). If the pattern defines seventy-five percent coverage, the reflective brightness of the material may be approximately 375 candelas/(lux*meter2).
- 5720 3M™ Scotchlite™ Silver Graphic Transfer Film commercially available from Minnesota Mining and Manufacturing Company of St. Paul, Minn. (hereafter 3M) was used to demonstrate non-continuous vapor permeable retroreflective material. Graphic images were made and transferred to Kombat™, fabric comprising PVI/Kevlar® blended fabric available from Southern Mills of Union City, Ga. The fabric with the graphic images was then tested. The graphic images were used as one example of a non-continuous retroreflective pattern. Specifically, the sample was prepared according to the following procedure.
- The 5720 Silver Graphic Transfer Film (SFEE1134-3-2-1A with polyester carrier) was screen printed with SX 779B FR Printable Adhesive (fire retardant SX 864B plastisol ink) available from Plast-O-Meric SP, Inc., Sussex, Wis., modified with 3M™ 571N Coupler (A-1120 silane, 4% by weight). The ink was printed through a 110 Tin (43.3 T/cm) printing screen with a medium hardness squeegee onto the 5720 Graphic Transfer Film using a Cameo printer available from American M & M Screen Printing Equipment of Oshkosh, Wis. The artwork of the screen consisted of three stripes with different graphic patterns (checker board, hash-marks, and circles). The resulting prints were gelled by passing them through a
Texair™ Model 30 conveyor oven available from American Screen Printing Equipment Co., Chicago, Ill., having a belt temperature of 230 degrees Fahrenheit (110 degrees Centigrade). The oven was heated by an IR panel set at 1100 degrees Fahrenheit (593 degrees Centigrade), and the belt temperature was controlled by belt speed. After gelation, the printed graphic images, were laminated to Kombat™ fabric using a HIX N-800 press available from HIX Corp. of Pittsburg, Kans., set at 340 degrees Fahrenheit (171 degrees Centigrade) for 30 seconds at an air line pressure of 40 psi (276 kPa). After the samples had cooled to room temperature, the polyester carrier was removed, yielding silver graphic images on the Kombat™ fabric. This Kombat™ fabric, containing silver images, was attached by sewing in the upper right-hand corner to the remaining two layers that make up the protective outfit shown inFIG. 8 . This complete assembly was then tested according to a procedures that substantially conformed standard industry testing procedures. - Another way of pressing the retroreflective beads on the adhesive pattern comprises depositing fully aluminum-coated beads onto the adhesive and then etching the aluminum from the exposed surfaces of the beads. Such a process can be continuous, and the need to peel back and discard a substrate is avoided. Additional details of this process are provided in copending and commonly assigned published PCT Application number WO0142823 (A1), the entire content of which is hereby incorporated by reference. The process can achieve a reflective brightness of approximately 350 candelas/(lux*meter2) or greater for total coverage. Thus, if the pattern defines fifty percent coverage, the reflective brightness of the material may be approximately 175 candelas/(lux*meter2). If the pattern defines sixty-six percent coverage, the reflective brightness of the material may be approximately 231 candelas/(lux*meter2). If the pattern defines seventy-five percent coverage, the reflective brightness of the material may be approximately 263 candelas/(lux*meter2).
- As yet another alternative to the processes of
FIG. 6 or 7, a non-continuous vapor permeable retroreflective material having patterns like those illustrated inFIGS. 2-5 can be created as follows. Glass beads are first deposited and bonded onto a substrate and the exposed surfaces of the beads are coated with aluminum. An adhesive is then applied on top of the glass beads, creating a retroreflective tape-like substance. The pattern can then be cut into the tape-like substance before pressing the tape-like substance onto a material such as a patch or the outer shell of a firefighter outfit. Heat and pressure can be applied and the substrate can then be peeled back leaving the pattern of half-aluminum coated beads properly oriented in the adhesive and attached to the underlying material to define the non-continuous vapor permeable retroreflective material. - 8710 3M™ Scotchlite™ Silver Transfer Film commercially available from 3M was also used to realize non-continuous vapor permeable material. 8710 Silver Graphic Images were made and transferred to a Nomex® outer shell material available from Southern Mills of Union City, Ga. The Nomex® outer shell material was then tested. The graphic images were used as another example of a non-continuous vapor permeable retroreflective material.
- Specifically, the 8710 Silver Graphic Images were prepared according to the following procedure. The 8710 Silver Transfer Film (75-0001-6745-4) graphic images were plotter cut, the weed was removed, and the material was then laminated to Nomex® outer shell material using a HIX N-800 press available from HEX Corp. of Pittsburg, Kans., set at 338 degrees Fahrenheit (170 Centigrade) for 15 seconds at an air line pressure of 40 psi (276 kPa). After the samples had cooled to room temperature, the paper carrier was removed, yielding silver graphic images on the Nomex® outer shell material. This material containing silver images was attached (by sewing in upper right-hand corner) to other layers that make up a protective outfit. This complete assembly was then tested according to a procedures that substantially conformed standard industry testing procedures.
- Non-continuous vapor permeable retroreflective materials created as described above exhibit thermal decay properties and vapor permeability properties that have not been achieved in the prior art. In particular, the thermal decay and vapor permeability through non-continuous retroreflective material may be the same as the underlying material. In other words, the addition of the patterns of retroreflective material does not substantially alter either the vapor permeability of the material or the thermal decay through the material. For this reason, the non-continuous vapor permeable retroreflective material can improve the performance of protective firefighter garments.
- Providing retroreflective material on protective garments using screen printing techniques or non-continuous retroreflective tape like substances that are heat applied can improve the production process associated with the creation of protective garments. Moreover, the non-continuous retroreflective patterns may be thinner and much less bulky that more conventional retroreflective material used on conventional protective garments. In addition, the resultant non-continuous vapor permeable retroreflective material can be non-perforated, thus avoiding any perforation steps in the production process.
-
FIG. 8 is a cross-sectional view a multi-layer protective firefighter outfit.Firefighter outfit 80 includes anouter shell 82, having aretroreflective portion 84 thereon.Firefighter outfit 80 also includesmoisture barrier 86 andthermal liner 88.Retroreflective portion 84 carries retroreflective material formed in a non-continuous pattern.Portion 84 may be a patch that is sewn or otherwise attached toouter shell 82. Alternatively,portion 84 may include a non-continuous retroreflective pattern screened directly onouter shell 82 as described above. -
Outer shell 82 represents a typical outer shell used in firefighter protective outfits. For example, outer shell may protect the firefighter from scrapes or abrasions and may be coated with a water repellent or the like. An example is Kombat™ fabric comprising PVI/Kevlar® blended fabric available from Southern Mills of Union City, Ga. -
Moisture barrier 86 can be used to keep liquid from penetrating intothermal liner 88. Older firefighter outfits used moisture barriers that were vapor impervious. However, newer designs have utilized moisture barriers that are vapor permeable to provide added comfort to the wearer. Ifmoisture barrier 86 is vapor permeable, hot vapors may be able to penetrate to the skin of the wearer, causing discomfort or burns if the vapors cannot escape through the outer shell or through the outer shell equipped with retroreflective material. Indeed, the use of vapor permeable moisture barriers is one of the underlying reasons that called for the non-continuous vapor permeable retroreflective material. An example of a suitable vapor permeable moisture barrier is Crosstech™ material on Nomex® pajama check material available from W. L. Gore of Elkton, Md. -
Thermal liner 88 can be used to protect the wearer from extreme temperatures. An example of a suitable thermal liner is Aralite® material including 100% Kevlar® batt with 100% Nomax® face cloth, available from Southern Mills of Union City, Ga. -
FIGS. 9 and 10 are graphs summarizing experimental data collected in testing the vapor permeability of prior art firefighter garments and firefighter garments making use of a retroreflective material formed in a non-continuous pattern. Reference is made to industry standard testing methods described in Lawson, J. Randall and Twilley, William H., “Development of an Apparatus for Measuring the Thermal Performance of Firefighters Protective Clothing”, National Institute of Standards and Technology, Gaithersburg, Md., 1999 (NISTIR 6400); and American Society for Testing and Materials, E162 “Standard Test Method for Surface Flammability of Materials Using a Radiant Heat Energy Source”, ASTM Annual Book of Standards, Volume 04.07, West Conshohocken, Pa., 1997. The various testing and experiments described below substantially conformed to the industry standard testing methods described in the above-mentioned references. - In particular,
FIG. 9 illustrates the vapor permeability of a prior art construction that utilizes a retroreflective standard trim material rather than a non-continuous vapor permeable retroreflective material for portion 84 (FIG. 8 ).FIG. 10 illustrates the vapor permeability of a garment utilizing retroreflective material formed in a non-continuous pattern onportion 84. In both cases, the respective garment was subjected to heat, and temperatures at particular points within the respective garment were recorded over time. - Referring to
FIG. 9 ,line 92 graphs temperature as a function of time measured at point C (FIG. 8 ) of a firefighter garment using a prior art retroreflective standard trim material rather than a non-continuous vapor permeable retroreflective material forportion 84. Similarly,line 94 illustrates temperature measured at point D of a prior art firefighter garment. Notably, after approximately 70 seconds, the temperature at point C becomes hotter than the temperature at point D. This is due, at least in part, to the fact that hot vapors were unable to adequately permeate through the prior art retroreflective material, and were driven down through the vaporpermeable moisture barrier 86 and condensed, quickly raising the temperature at point C. In the experiments, the mass transfer of hot vapors was visually apparent as moisture condensed on thethermal liner 88 in the regions covered by the prior art retroreflective material. Notably, prior art retroreflective material having perforations showed similar results. - Unlike conventional retroreflective material, the use of non-continuous retroreflective material for
portion 84 resulted in the desired vapor permeability. Referring toFIG. 10 ,line 102 graphs temperature as a function of time measured at point C (FIG. 8 ) of a firefighter garment having a non-continuous vapor permeable retroreflective material forportion 84.Line 104 graphs temperature as a function of time measured at point D of a firefighter garment including retroreflective material formed in a non-continuous pattern as described herein. As shown, the temperature at point C remains cooler than the temperature at point D at all times, due to the dissipation of the hot vapors developed from water retained under outer shell throughportion 84. In other words, hot vapors were able to adequately permeate through non-continuous retroreflective material, i.e.,portion 84. -
FIGS. 11 and 12 are graphs summarizing experimental data collected in testing the thermal decay of heat escaping a firefighter garment. Again, industry standard testing methods were used.FIG. 11 shows the thermal decay of a prior art construction that utilizes a retroreflective standard trim material rather than a non-continuous vapor permeable retroreflective material forportion 84.FIG. 12 illustrates the thermal decay of a garment utilizing a non-continuous vapor permeable retroreflective material forportion 84. - Referring to
FIG. 11 ,line 112 graphs temperature as a function of time measured at point A (FIG. 8 ) of a prior art firefighter garment. Again, the prior art firefighter garment utilized retroreflective standard trim material rather than a non-continuous vapor permeable retroreflective material forportion 84.Line 114 graphs temperature as a function of time measured at point B of a prior art firefighter garment. In the experiment, the firefighter garment was exposed to extreme temperatures and then removed from proximity to the heat source and allowed to cool. In the graph, the point at time=X corresponds to the point in time when the garment was removed from the heat source. - As can be seen by comparing
line 112 toline 114, the thermal decay of the temperature at point A is less than the thermal decay of the temperature at point B. In other words, in the prior art firefighter garment it took longer for point A to cool off than it did for point B to cool off. The reason is at least in part due to the fact that the prior art retroreflective standard trim material reduced the rate of thermal decay through the outer shell. Heat was trapped inside the garment longer in the regions that correspond to the prior art retroreflective standard trim material. - Referring now to
FIG. 12 ,line 122 graphs temperature as a function of time measured at point A (FIG. 8 ) of firefighter garment having a non-continuous vapor permeable retroreflective material forportion 84.Line 124 graphs temperature as a function of time measured at point B of the firefighter garment including retroreflective material formed in a non-continuous pattern as described herein. As can be seen by comparingline 122 toline 124, the thermal decay of the temperature at point A is approximately the same as the thermal decay of the temperature at point B. In other words, non-continuous vapor permeable retroreflective material does not substantially decrease the thermal decay through the outer shell of the firefighter garment. Heat was not trapped inside the garment for longer periods of time in the regions that correspond to the non-continuous vapor permeable retroreflective material. -
FIG. 13 is a graph of temperature differentials between points A and B (FIG. 8 ) for various different firefighter garments, i.e. a graph of the temperature at point A minus the temperature at point B over time. InFIG. 13 , the point of approximately time=0 corresponds to the point in time at which the garment is removed from proximity to a heat source and allowed to cool.Line 132 corresponds to a prior art firefighter garment incorporating standard continuous non-perforated retroreflective trim. As can be seen byline 132, the temperature differential between the temperature under the outer shell versus the temperature under the outer shell with the standard retroreflective trim is relatively large. For example, after approximately 50 seconds, it was approximately 50 degrees Centigrade hotter behind the standard trim. Again, this is due to the fact that heat cannot adequately escape through the standard retroreflective trim. -
Line 134 corresponds to a prior art firefighter garment incorporating standard continuous perforated retroreflective trim. As can be seen byline 134, the temperature differential between the temperature under the outer shell versus the temperature under the outer shell with the standard continuous perforated retroreflective trim is still relatively large. In other words, perforations do not resolve the thermal decay issue. For example, after approximately 50 seconds, it was approximately 42 degrees Centigrade hotter behind the standard continuous perforated retroreflective trim. Again, this is due to the fact that heat cannot adequately escape through the standard continuous perforated retroreflective trim. -
Line 136 corresponds to a firefighter garment, incorporating a non-continuous vapor permeable retroreflective material for portion 84 (FIG. 8 ). As can be seen byline 136, the temperature differential between the temperature under the outer shell both with and without the non-continuous retroreflective material is much smaller than that oflines - The graphs of
FIGS. 9-13 illustrate the advantages of retroreflective material formed in a non-continuous pattern, in relation to the prior art. The retroreflective material formed in a non-continuous pattern as described herein provides improved thermal transfer and/or vapor transfer through protective garments having retroreflective material thereon. Conventional retroreflective material, such as retroreflective trim materials and perforated retroreflective trim materials provide inadequate thermal decay and vapor permeability characteristics. Non-continuous vapor permeable retroreflective material, however, exhibits substantially the same thermal decay characteristics and vapor permeability characteristics as the underlying material without the retroreflective material. - Firefighter garments, and thus multi-layer firefighter outfits, can be greatly improved by implementing non-continuous vapor permeable retroreflective material. If vapor cannot escape thought the outer shell because conventional retroreflective material provides a vapor barrier, hot vapors can be directed inward, toward the skin of the wearer, possibly causing steam burns or other discomfort to the wearer. The techniques described herein resolve this issue by providing a retroreflective material formed in a non-continuous pattern to define retroreflective regions and non-retroreflective regions. In this manner, the addition of retroreflective material does not substantially decrease vapor permeability of the outer shell.
- Thermal decay through an outer shell having conventional retroreflective trim material, such as perforated retroreflective trim material, is substantially less than thermal decay through the outer shell in regions not having the conventional retroreflective trim material. Thus, heat trapped within the protective garment may not be able to escape fast enough for the firefighter to cool off at a desired rate. Rather, the presence of conventional retroreflective material such as perforated retroreflective trim material can cause heat to remain trapped inside the protective garment for longer periods of time, providing discomfort to the firefighter even after he or she has left the fire. The techniques described herein resolve this issue by providing a non-continuous vapor permeable retroreflective material that does not substantially decrease thermal decay of the garment in the portions having the non-continuous vapor permeable retroreflective material. In this manner, the vapor permeable retroreflective material can reduce the heat load within the various layers that comprise the firefighter outfit, reduce negative physiological impacts on the wearer, and reduce the likelihood of producing burn injuries on the wearer.
- The techniques described herein can provide non-continuous vapor permeable retroreflective material having a reflective brightness greater than 50 candelas/(lux*meter2) or even greater than 250 candelas/(lux*meter2). Brightnesses in these ranges significantly increase visibility of a wearer during nighttime and twilight hours. Indeed, this can better ensure that firefighters are not only seen by night motorists, but more importantly, these brightness ranges can be achieved while still providing the vapor permeability and thermal decay characteristics described above.
-
FIG. 14 is a cross-sectional view of another protective multi-layer outfit that could benefit by the teaching of this disclosure.Protective outfit 140 is a protective multi layer thermal control outfit.Protective outfit 140 includes anouter shell 142, and a non-continuous vapor permeable retroreflective material definesportion 144 ofouter shell 142. For example,portion 144 may be a patch that is sewn or otherwise attached toouter shell 142, or alternatively,portion 144 may be a portion ofouter shell 142 having a non-continuous retroreflective pattern applied thereon as described above.Protective outfit 140 also includesliquid retaining layer 146 and waterproof vaporpermeable layer 148. -
Protective outfit 140 may be used to keep the wearer cool through the effects of evaporative cooling and by acting as a heat sink. Theliquid retaining layer 146 can be soaked with water and water vapors can permeate through theouter shell 142 to cool the skin of the wearer. The outfit makes use of non-continuous vapor permeable retroreflective material to defineportion 144 ofouter shell 142. In this manner, the thermal transfer characteristics and vapor permeability characteristics ofprotective outfit 140 can be maintained while adding the effects of nighttime visibility through the use of retroreflective materials. - A number of implementations and embodiments have been described. For instance, non-continuous vapor permeable retroreflective material having retroreflective regions and non-retroreflective regions has been described. Thermal decay and vapor permeability through the non-continuous vapor permeable retroreflective material is substantially the same as thermal decay and vapor permeability through the underlying material that does not include non-continuous vapor permeable retroreflective material.
- Nevertheless, it is understood that various modifications can be made without departing from the spirit and scope of this disclosure. For example, the non-continuous vapor permeable retroreflective material could be included in as part of any garment to provide retroreflectively in the garment and yet also provide adequate thermal decay and vapor permeability through the garment. In addition, the non-continuous vapor permeable retroreflective material could substantially or completely cover a garment or article. Also, the retroreflective material may be made florescent to enhance daytime visibility. In addition, alternative methods may be used to realize non-continuous vapor permeable retroreflective material. For example, various different graphic screen printing techniques, electronic digital printing techniques, plotter cutting, laser cutting, or die cutting of retroreflective substrates to be applied on a material, or other similar techniques may be used to realize non-continuous vapor permeable retroreflective material. Accordingly, other implementations and embodiments are within the scope of the following claims.
Claims (57)
1-62. (canceled)
63. A high visibility safety garment for wearing by an individual exposed to hazardous vehicular traffic, said garment constructed to comply with retroreflection standards of an acknowledged and recognized safety garment standard specifying a minimum coefficient of retroreflectivity Rmin for a horizontal stripe on a safety garment intended for encircling the torso of an individual wearing the safety garment, comprising:
a torso covering safety garment base formed at least partially of a fluorescent colored background material;
a horizontal high visibility retroreflective safety stripe attached to and encircling the base so as to encircle the torso of a garment wearer;
said stripe having a plurality of disconnected but closely spaced stripe segments separated by stripe spaces to approximate a continuous stripe in appearance;
said stripe segments formed of a retroreflective material having a coefficient of retroreflection RA;
said stripe segments and stripe spaces occupying an area Astripe, and said stripe segments occupying an area Asegment that is a sufficient percentage of the area Astripe to satisfy the relationship (Asegment/Astripe)×RA≧Rmin.
64. The safety garment of claim 63 including:
one or more additional safety stripes on the garment base formed of disconnected but closely spaced stripe segments that are formed of a material having a coefficient of retroreflection and occupy a percentage of the total area occupied by the stripe to satisfy said relationship.
65. The safety garment of claim 64 wherein:
said additional stripes are vertical.
66. The safety garment of claim 65 wherein:
said base is configured as a safety vest.
67. The safety garment of claim 64 wherein:
said stripes have an area and said stripe segments have a coefficient of retroreflection so as to comply with the standard of ANSI/ISEA 107 for a class 1 garment.
68. The safety garment of claim 64 wherein:
said stripes have an area and said segments have a coefficient of retroreflection so as to comply with the standards of a ANSI/ISEA 107 for a Class 2 garment.
69. The safety garment of claim 64 wherein:
said stripes have an area, and said stripe segments have a coefficient of retroreflection so as to comply with the standards of ANSI/ISEA 107 for a Class 3 garment.
70. The safety garment of claim 63 wherein:
said base is configured as a tee shirt.
71. The safety garment of claim 63 wherein:
said base is configured as a jacket.
72. The safety garment of claim 63 wherein:
said base and stripe are in compliance with the standards specified in the American National Standards Institute for High Visibility Safety Apparel.
73. The safety garment of claim 63 wherein:
said stripe has an area and said stripe segments have a coefficient of retroreflection so as to comply with European standard EN471.
74. The safety garment of claim 63 wherein:
said stripe has a width of at least 35 mm, said base has an exposed background material area of at least 775 square inches and a stripe area of at least 201 square inches.
75. The safety garment of claim 63 wherein:
said stripe has a width of at least 50 mm, said base has an exposed background material area of at least 1240 square inches and a stripe area of at least 310 square inches.
76. The safety garment of claim 63 wherein:
said segments are comprised of closed geometric figures in the shape of a parallelogram, in a repetitive segment-space pattern.
77. The safety garment of claim 63 wherein:
said segments are comprised of closed geometric figures in the shape of chevrons, in a repetitive segment-space pattern.
78. The safety garment of claim 63 wherein:
said segments are comprised of closed geometric figures in the shape of crosses, in a repetitive segment-space pattern.
79. The safety garment of claim 63 wherein:
said segments are comprised of closed geometric figures in the shape of pentagons, in a repetitive segment-space pattern.
80. The safety garment of claim 63 wherein:
said stripe includes identifying indicia.
81. A high visibility safety garment for wearing by an individual exposed to hazardous vehicular traffic, said garment constructed to comply with retroreflection standards of an acknowledged and recognized safety garment standard specifying a minimum coefficient of retroreflection for a horizontal stripe on a safety garment intended for encircling the torso of an individual wearing the safety garment, comprising:
a torso covering safety garment base formed of a fluorescent colored background material;
a horizontal high visibility retroreflective safety stripe attached to and encircling the garment base so as to encircle the torso of a wearer;
said safety stripe having top and bottom borders and a length so as to define a stripe area;
said safety stripe having a plurality of disconnected but closely spaced stripe segments to approximate a continuous stripe in appearance;
said stripe segments formed of a retroreflective material having a coefficient of retroreflection higher than the minimum coefficient of retroreflection specified by the standard being addressed;
said stripe segments occupying a portion of the total area of the stripe sufficient that when the ratio of the surface area occupied by the stripe segments to the total stripe area is multiplied by the retroreflection coefficient of the segment material, the result is at least equal to the minimum coefficient of retroreflection specified by the standard being addressed.
82. The safety garment of claim 81 including:
one or more additional safety stripes on the garment base formed of disconnected but closely spaced stripe segments that are formed of a material having a coefficient of retroreflection and occupy a percentage of the total area occupied by the stripe to satisfy said relationship.
83. The safety garment of claim 82 wherein:
said additional stripes are vertical.
84. The safety garment of claim 82 wherein:
said base is configured to be a safety vest.
85. The safety garment of claim 83 wherein:
said base is configured to be a jacket.
86. The safety garment of claim 82 wherein:
said base is configured to be a tee shirt.
87. The safety garment of claim 81 wherein:
said stripe has an area and said stripe segments have a coefficient of retroreflection so as to comply with the standard of ANSI/ISEA 107 for a garment chosen from the category of class 1, 2 or 3.
88. The safety garment of claim 81 wherein:
said segments are comprised of closed geometric figures in a repetitive pattern for the length of the stripe.
89. The safety garment of claim 81 wherein:
said safety stripe includes identifying indicia.
90. A high visibility safety garment for wearing by an individual exposed to hazardous vehicular traffic, said garment constructed to comply with retroreflection standards of an acknowledged and recognized safety garment standard specifying a minimum coefficient of retroreflection for a horizontal stripe on a safety garment intended for encircling the torso of an individual wearing the safety garment, comprising:
a torso covering safety garment base formed of a fluorescent colored background material;
a horizontal high visibility retroreflective safety stripe attached to and encircling the garment base so as to encircle the torso of a wearer;
said safety stripe having top and bottom boarders and a length so as to define a stripe area;
said stripe including a plurality of disconnected but closely spaced stripe segments formed of a retroreflective material and that together occupy a sufficient amount of the total stripe area such that the stripe has a composite coefficient of retroreflection that equals or exceeds the coefficient of retroreflection specified by the standard being addressed.
91. A graphic transfer device for use in fabrication of the high visibility safety stripe for a high visibility safety garment for wearing by an individual exposed to hazardous vehicular traffic, said garment constructed to comply with retroreflection standards of an acknowledged and recognized safety garment standard specifying a minimum coefficient of retroreflection for a horizontal stripe on a safety garment intended for encircling the torso of an individual wearing the safety garment, having a torso covering safety garment base formed of a fluorescent colored background material, a horizontal high visibility retroreflective safety stripe attached to and encircling the garment base so as to encircle the torso of a wearer; said safety stripe including a plurality of disconnected but closely spaced stripe segments to approximate a continuous stripe in appearance, said stripe segments formed of a retroreflective material having a coefficient of retroreflection higher than the minimum coefficient of retroreflection specified by the standard being addressed, comprising:
a flexible backing;
a layer of retroreflective optical elements adhered to one surface of the backing and having a coefficient of retroreflection that is greater than the minimum coefficient of retroreflection specified by the standard being addressed;
a plurality of disconnected but closely spaced adhesive strips located on said bead layer forming a stripe pattern corresponding to the intended safety stripe pattern of disconnected but closely spaced stripe segments of a retroreflective material occupying a sufficient portion of the total stripe area such that when the ratio of the surface area occupied by the stripe segments to the total stripe area is multiplied by the retroreflection coefficient of the segment material, the result is at least equal to the minimum coefficient of retroreflection specified by the standard being addressed;
said adhesive strips having a heat activated adhesive whereby the pattern of adhesive strips can be adhered to a high visibility safety garment base with adhering retroreflective optical elements facing outward as part of the fabrication process of attaching a high visibility safety stripe to the garment base.
92. A high visibility safety garment for wearing over the torso of a wearer, comprising:
an outer surface;
fluorescent material on the outer surface of the garment to provide improved daytime visibility;
a horizontal high visibility retroreflective safety stripe attached to the outer surface of the safety garment;
said stripe having a plurality of disconnected but closely spaced stripe segments separated by stripe spaces to approximate a continuous stripe in appearance;
said stripe segments formed of a retroreflective material having a coefficient of retroreflection RA;
said stripe segments and stripe spaces occupying an area Astripe, and said stripe segments occupying an area Asegment that is a sufficient percentage of Astripe to satisfy the relationship (Asegment/Astripe)×RA≧250 candelas/lux*meter2.
93. The high visibility safety garment as claimed in claim 92 , wherein (Asegment/Astripe)×RA is approximately 375 candelas/lux*meter2.
94. The high visibility safety garment as claimed in claim 92 , wherein (Asegment/Astripe)≦80%.
95. The high visibility safety garment as claimed in claim 92 , wherein (Asegment/Astripe)≦75%.
96. The high visibility safety garment as claimed in claim 92 , wherein (Asegment/Astripe)≦50%.
97. The high visibility safety garment as claimed in claim 92 , wherein RA is approximately 500 candelas/lux*meter2.
98. The high visibility safety garment as claimed in claim 97 , wherein (Asegment/Astripe) is approximately 50%.
99. The high visibility safety garment as claimed in claim 97 , wherein (Asegment/Astripe) is approximately 66%.
100. The high visibility safety garment as claimed in claim 97 , wherein (Asegment/Astripe) is approximately 75%.
101. The high visibility safety garment as claimed in claim 92 , further comprising one or more additional safety stripes on said outer surface formed of disconnected but closely spaced stripe segments that are formed of a material having a coefficient of retroreflection and occupy a percentage of the total area occupied by the stripe to satisfy said relationship.
102. The high visibility safety garment as claimed in claim 101 , wherein said additional stripes are vertical.
103. The high visibility safety garment as claimed in claim 92 , wherein said outer surface is configured as a jacket.
104. The high visibility safety garment as claimed in claim 92 , wherein said segments are comprised of closed geometric figures in the shape of a parallelogram, in a repetitive segment-space pattern.
105. A high visibility safety garment, comprising:
a torso covering safety garment outer shell;
fluorescent material on the outer shell to provide improved daytime visibility;
a horizontal high visibility retroreflective safety stripe attached to the outer shell of the safety garment;
said stripe having top and bottom borders and a length so as to define a stripe area;
said stripe having a plurality of disconnected but closely spaced stripe segments separated by stripe spaces to approximate a continuous stripe in appearance;
said stripe segments formed of a retroreflective material having a coefficient of retroreflection of at least approximately 350 candelas/lux*meter2;
said stripe segments occupying a portion of the total area of the stripe sufficient that when the ratio of the surface area occupied by the stripe segments to the total stripe area is multiplied by the retroreflection coefficient of the segment material, the result is at least equal to 250 candelas/lux*meter2.
106. The high visibility safety garment as claimed in claim 105 , wherein said material has a coefficient of retroreflection of approximately 500 candelas/lux*meter2.
107. The high visibility safety garment as claimed in claim 106 , wherein the result is approximately 375 candelas/lux*meter2.
108. The high visibility safety garment as claimed in claim 106 , wherein the result is approximately 330 candelas/lux*meter2.
108. The high visibility safety garment as claimed in claim 106 , wherein the result is approximately 250 candelas/lux*meter2.
109. The high visibility safety garment as claimed in claim 105 , wherein said stripe segments occupy less than 80% of the total area of the stripe.
110. The high visibility safety garment as claimed in claim 105 , wherein said stripe segments occupy less than 75% of the total area of the stripe.
111. The high visibility safety garment as claimed in claim 105 , wherein said stripe segments occupy less than 50% of the total area of the stripe.
112. The high visibility safety garment as claimed in claim 105 , further comprising one or more additional safety stripes on said outer shell formed of disconnected but closely spaced stripe segments that are formed of a material having a coefficient of retroreflection and occupy a percentage of the total area occupied by the stripe to satisfy said relationship.
113. The high visibility safety garment as claimed in claim 112 , wherein said additional stripes are vertical.
114. The high visibility safety garment as claimed in claim 105 , wherein said outer shell is configured as a jacket.
115. The high visibility safety garment as claimed in claim 105 , wherein said segments are comprised of closed geometric figures in a repetitive pattern for the length of the stripe.
116. A high visibility safety garment, comprising:
a torso covering safety garment outer shell;
fluorescent material on the outer shell to provide improved daytime visibility;
a horizontal high visibility retroreflective safety stripe attached to the outer shell of the safety garment;
said stripe having top and bottom borders and a length so as to define a stripe area;
said stripe including a plurality of disconnected but closely spaced stripe segments formed of a retroreflective material and that together occupy a sufficient amount of the total stripe area such that the stripe has a composite coefficient of retroreflection that equals or exceeds 250 candelas/lux*meter2.
117. A graphic transfer device for use in fabrication of a high visibility safety stripe of a high visibility safety garment to be worn over the torso of a wearer, said safety stripe including a plurality of disconnected but closely spaced stripe segments to approximate a continuous stripe in appearance, said stripe segments formed of a retroreflective material having a coefficient of retroreflection of at least approximately 350 candelas/lux*meter2, comprising:
a substrate;
a layer of retroreflective optical elements adhered to one surface of the substrate and having a coefficient of retroreflection of at least approximately 350 candelas/lux*meter2;
a plurality of disconnected but closely spaced adhesive strips located on said layer of optical elements forming a stripe pattern corresponding to the intended safety stripe pattern of disconnected but closely spaced stripe segments of a retroreflective material occupying a sufficient portion of the total stripe area such that when the total surface area occupied by the stripe segments to the total stripe area is multiplied by the retroreflection coefficient of the segment material, the result is at least equal to 250 candelas/lux*meter2;
said adhesive strips having a heat activated adhesive whereby the pattern of adhesive strips can be adhered to a high visibility safety garment with adhering retroreflective optical elements facing outward as part of the fabrication process of attaching a high visibility safety stripe to the garment base.
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/598,616 US20070056077A1 (en) | 2001-07-30 | 2006-11-13 | Vapor permeable retroreflective garment |
US11/839,782 US7600269B2 (en) | 2001-07-30 | 2007-08-16 | Vapor permeable retroreflective garment |
US12/553,118 US8015620B2 (en) | 2001-07-30 | 2009-09-03 | Vapor permeable retroreflective garment |
US13/210,036 US8256025B2 (en) | 2001-07-30 | 2011-08-15 | Vapor permeable retroreflective garment |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/918,267 US6931665B2 (en) | 2001-07-30 | 2001-07-30 | Vapor permeable retroreflective garment |
US11/183,027 US7107622B2 (en) | 2001-07-30 | 2005-07-15 | Vapor permeable retroreflective garment |
US11/365,944 US20060143772A1 (en) | 2001-07-30 | 2006-03-01 | Vapor permeable retroreflective garment |
US11/598,616 US20070056077A1 (en) | 2001-07-30 | 2006-11-13 | Vapor permeable retroreflective garment |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11/365,944 Continuation US20060143772A1 (en) | 2001-07-30 | 2006-03-01 | Vapor permeable retroreflective garment |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11/839,782 Continuation US7600269B2 (en) | 2001-07-30 | 2007-08-16 | Vapor permeable retroreflective garment |
Publications (1)
Publication Number | Publication Date |
---|---|
US20070056077A1 true US20070056077A1 (en) | 2007-03-15 |
Family
ID=25440100
Family Applications (7)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/918,267 Expired - Lifetime US6931665B2 (en) | 2001-07-30 | 2001-07-30 | Vapor permeable retroreflective garment |
US11/183,027 Expired - Lifetime US7107622B2 (en) | 2001-07-30 | 2005-07-15 | Vapor permeable retroreflective garment |
US11/365,944 Abandoned US20060143772A1 (en) | 2001-07-30 | 2006-03-01 | Vapor permeable retroreflective garment |
US11/598,616 Abandoned US20070056077A1 (en) | 2001-07-30 | 2006-11-13 | Vapor permeable retroreflective garment |
US11/839,782 Expired - Lifetime US7600269B2 (en) | 2001-07-30 | 2007-08-16 | Vapor permeable retroreflective garment |
US12/553,118 Expired - Fee Related US8015620B2 (en) | 2001-07-30 | 2009-09-03 | Vapor permeable retroreflective garment |
US13/210,036 Expired - Fee Related US8256025B2 (en) | 2001-07-30 | 2011-08-15 | Vapor permeable retroreflective garment |
Family Applications Before (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/918,267 Expired - Lifetime US6931665B2 (en) | 2001-07-30 | 2001-07-30 | Vapor permeable retroreflective garment |
US11/183,027 Expired - Lifetime US7107622B2 (en) | 2001-07-30 | 2005-07-15 | Vapor permeable retroreflective garment |
US11/365,944 Abandoned US20060143772A1 (en) | 2001-07-30 | 2006-03-01 | Vapor permeable retroreflective garment |
Family Applications After (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11/839,782 Expired - Lifetime US7600269B2 (en) | 2001-07-30 | 2007-08-16 | Vapor permeable retroreflective garment |
US12/553,118 Expired - Fee Related US8015620B2 (en) | 2001-07-30 | 2009-09-03 | Vapor permeable retroreflective garment |
US13/210,036 Expired - Fee Related US8256025B2 (en) | 2001-07-30 | 2011-08-15 | Vapor permeable retroreflective garment |
Country Status (11)
Country | Link |
---|---|
US (7) | US6931665B2 (en) |
EP (1) | EP1414320B1 (en) |
JP (1) | JP2004536978A (en) |
KR (1) | KR100901549B1 (en) |
CN (1) | CN100466927C (en) |
AT (1) | ATE415832T1 (en) |
CA (2) | CA2455604C (en) |
DE (1) | DE60230151D1 (en) |
HK (1) | HK1067505A1 (en) |
TW (1) | TW579282B (en) |
WO (1) | WO2003011064A1 (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20080077214A1 (en) * | 2006-09-19 | 2008-03-27 | Robert Stalick | Device and method for cooling animals |
US20100231113A1 (en) * | 2009-03-12 | 2010-09-16 | 3M Innovative Properties Company | Laminate reflective and electroluminescent article |
US20100232143A1 (en) * | 2009-03-12 | 2010-09-16 | Kenneth Burrows | Hybrid electroluminescent assembly |
US20110305006A1 (en) * | 2009-03-12 | 2011-12-15 | 3M Innovative Properties Company | Garment with a retroreflective and electroluminescent article |
CH703282A1 (en) * | 2010-06-15 | 2011-12-15 | Studio Crr Gmbh | Reflective element. |
US20230337758A1 (en) * | 2020-09-24 | 2023-10-26 | 3M Innovative Properties Company | Fabric and Garment Comprising Discrete Islands of Retroreflective Laminate |
Families Citing this family (61)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6931665B2 (en) * | 2001-07-30 | 2005-08-23 | 3M Innovative Properties Company | Vapor permeable retroreflective garment |
US20070094763A1 (en) * | 2002-08-30 | 2007-05-03 | Safety-Short Workwair Inc. | Safety outerwear with fire resistant mesh |
US7246380B2 (en) * | 2003-01-29 | 2007-07-24 | 3M Innovative Properties Company | Protective garment with repairable integrated visibility-enhancing features |
CA2437325A1 (en) * | 2003-05-14 | 2004-11-14 | Morning Pride Manufacturing, L.L.C. | Protective, torso-covering garment, as for firefighter or emergency worker, in which selected portion is heat reflective |
US7300820B2 (en) * | 2004-03-16 | 2007-11-27 | Temic Automotive Of North America, Inc. | Adhesive assembly for a circuit board |
US20060040575A1 (en) * | 2004-08-18 | 2006-02-23 | Kelleher Karen A | Reflective printing on flame resistant fabrics |
US7252396B2 (en) * | 2004-11-16 | 2007-08-07 | 3M Innovative Properties Company | Retroreflective article having at least one valve and method of making same |
DE102005025579A1 (en) * | 2005-06-01 | 2006-12-14 | Lion Apparel Deutschland Gmbh | Protective clothing with reflective tapes |
US7636950B2 (en) * | 2005-09-30 | 2009-12-29 | Nike, Inc. | Article of apparel with zonal stretch resistance |
US8336117B2 (en) * | 2005-10-19 | 2012-12-25 | Nike, Inc. | Article of apparel with material elements having a reversible structure |
US20070124975A1 (en) * | 2005-12-06 | 2007-06-07 | Rima Kasprzak | System for properly orienting and coordinating clothing |
AT504357B8 (en) * | 2007-03-30 | 2008-09-15 | Otmar Schneider | PROTECTIVE CLOTHING FOR EMPLOYEES |
DE102007050175A1 (en) * | 2007-10-19 | 2009-04-23 | W. L. Gore & Associates Gmbh | Material structure with flameproof material, especially for warning clothing |
US20090155444A1 (en) * | 2007-12-12 | 2009-06-18 | Solae, Llc | Protein Extrudates Comprising Whole Grains |
USD670917S1 (en) * | 2011-02-18 | 2012-11-20 | Columbia Sportswear North America, Inc. | Heat reflective lining material |
US8479322B2 (en) | 2009-05-07 | 2013-07-09 | Columbia Sportswear North America, Inc. | Zoned functional fabrics |
US8453270B2 (en) | 2009-05-07 | 2013-06-04 | Columbia Sportswear North America, Inc. | Patterned heat management material |
US8510871B2 (en) * | 2009-05-07 | 2013-08-20 | Columbia Sportswear North America, Inc. | Holographic patterned heat management material |
US20100299810A1 (en) * | 2009-05-28 | 2010-12-02 | Julia Ann Snyder | Methods, devices and systems for identifying an individual to a pre-defined group |
JP3158587U (en) * | 2010-01-26 | 2010-04-08 | 建治 岩田 | Retroreflective fabric and retroreflective garment using the fabric |
NZ593730A (en) * | 2010-06-24 | 2011-10-28 | Video Taped Transcripts Pty Ltd | Hot punch process for producing a perforated retroreflective trim |
AU2013101656B4 (en) * | 2010-06-24 | 2014-08-28 | Video Taped Transcripts Pty. Ltd. | Perforated retroreflective trim and a method of producing perforated retroreflective trim |
USD707974S1 (en) | 2012-05-11 | 2014-07-01 | Columbia Sportswear North America, Inc. | Patterned prismatic bodywear lining material |
US10349763B2 (en) * | 2012-05-29 | 2019-07-16 | Vecher Holdings International Inc. | Picnic size carry container that converts into a protective mat |
CN102783726A (en) * | 2012-07-26 | 2012-11-21 | 苏州汾湖电梯有限公司 | Raincoat with fluorescence strips |
US9719206B2 (en) | 2012-09-14 | 2017-08-01 | Under Armour, Inc. | Apparel with heat retention layer and method of making the same |
USD766599S1 (en) | 2013-03-11 | 2016-09-20 | Under Armour, Inc. | Lower body garment with inner surface ornamentation |
USD758745S1 (en) | 2013-03-11 | 2016-06-14 | Under Armour, Inc. | Lower body garment with outer surface ornamentation |
USD765427S1 (en) | 2013-03-11 | 2016-09-06 | Under Armour, Inc. | Upper body garment with areas of interior surface ornamentation |
US10451780B2 (en) * | 2013-12-12 | 2019-10-22 | 3M Innovative Properties Company | Retroreflective article |
US10492550B2 (en) * | 2014-01-28 | 2019-12-03 | Under Armour, Inc. | Article of apparel including thermoregulatory textile |
EP3140684A1 (en) | 2014-05-09 | 2017-03-15 | 3M Innovative Properties Company | Colored retroreflective articles |
CN106574993B (en) | 2014-05-09 | 2022-07-12 | 3M创新有限公司 | Retroreflective article |
CN104002510A (en) * | 2014-05-23 | 2014-08-27 | 常熟市明鹿无纺织有限公司 | Waterproof fabric |
EP3155462B1 (en) | 2014-06-16 | 2019-10-23 | 3M Innovative Properties Company | Retroreflective articles with wash durable bead bond layers |
WO2016039820A1 (en) | 2014-09-10 | 2016-03-17 | 3M Innovative Properties Company | Exposed lens retroreflective articles comprising a self-assembled dielectric mirror |
CN104287208A (en) * | 2014-09-28 | 2015-01-21 | 张玮 | Student raincoat |
EP3201660A1 (en) | 2014-09-30 | 2017-08-09 | 3M Innovative Properties Company | Retroreflective colored articles |
KR101571783B1 (en) | 2015-02-13 | 2015-11-25 | 윤세원 | Retroreflective sheet and method thereof |
USD773150S1 (en) | 2015-04-28 | 2016-12-06 | Shirley Hackenberg | Safety vest t-shirt |
US11925219B2 (en) * | 2015-06-18 | 2024-03-12 | Jeffrey Garre Barkshire | Fashionable high-visibility safety apparel |
US20240138499A1 (en) * | 2015-06-18 | 2024-05-02 | Jeffrey Garre Barkshire | Fashionable high-visibility safety apparel |
EP3436259A4 (en) | 2016-03-30 | 2020-02-05 | 3M Innovative Properties Company | Article featuring a predetermined pattern of randomly distributed microspheres and methods of making the same |
US10973268B2 (en) | 2016-08-25 | 2021-04-13 | Nike, Inc. | Garment with zoned insulation and variable air permeability |
JP2018116114A (en) * | 2017-01-17 | 2018-07-26 | 日本ウェーブロック株式会社 | Reflective sheet |
USD874157S1 (en) | 2017-04-06 | 2020-02-04 | Radians, Inc. | Shirt with reflective tape |
US11297885B2 (en) | 2017-05-21 | 2022-04-12 | Nike, Inc. | Reflective articles of wear |
US10555565B2 (en) * | 2017-05-31 | 2020-02-11 | Nike, Inc. | Reflective articles of wear |
EP3676091A4 (en) * | 2017-09-01 | 2021-05-26 | 3M Innovative Properties Company | Reticulated reflective material |
USD948223S1 (en) | 2017-09-01 | 2022-04-12 | 3M Innovative Properties Company | Patterned reflective material |
USD965990S1 (en) | 2017-09-01 | 2022-10-11 | 3M Innovative Properties Company | Patterned reflective material |
US11612201B2 (en) | 2017-10-16 | 2023-03-28 | Columbia Sportswear North America, Inc. | Limited conduction heat reflecting materials |
US10993484B2 (en) | 2017-10-18 | 2021-05-04 | Nike, Inc. | Wetness indicator garment |
US11425947B2 (en) * | 2017-11-17 | 2022-08-30 | Lululemon Athletica Canada Inc. | Sleeve for a garment |
US20200257024A1 (en) * | 2019-02-11 | 2020-08-13 | Fiberlok Technologies | Light retroreflective graphic textile |
WO2021070179A1 (en) * | 2019-10-07 | 2021-04-15 | Kornit Digital Ltd. | Preservation of moisture evaporation and body temperature regulation properties on garments post printing |
US11178921B2 (en) * | 2019-11-11 | 2021-11-23 | Rose Kalata | Pedestrian reflective kit |
CN111897040B (en) * | 2020-08-12 | 2022-04-15 | 常州市日月反光材料有限公司 | High-strength tear-resistant reflective film and preparation process thereof |
US20230099542A1 (en) * | 2021-09-29 | 2023-03-30 | Douglas Bradshaw | Traffic Control Safety Gloves |
CN114155727A (en) * | 2021-11-15 | 2022-03-08 | 深圳市机场股份有限公司 | Traffic clothing, light control method thereof and computer readable storage medium |
US11825890B1 (en) * | 2022-12-13 | 2023-11-28 | NingBo DingQuan JieNeng KeJi Co., Ltd | Wearable blanket |
Citations (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4103060A (en) * | 1975-01-10 | 1978-07-25 | Minnesota Mining And Manufacturing Company | Area-retroreflectorization of fabrics |
US4263345A (en) * | 1979-11-16 | 1981-04-21 | Minnesota Mining And Manufacturing Company | Coating composition for forming retroreflective treatments on fabrics |
USRE30892E (en) * | 1975-01-10 | 1982-03-30 | Minnesota Mining And Manufacturing Company | Area-retroreflectorization of fabrics |
US4418110A (en) * | 1982-06-21 | 1983-11-29 | Minnesota Mining And Manufacturing | Vapor-permeable retroreflective sheeting |
US4817210A (en) * | 1988-03-28 | 1989-04-04 | Lion Apparel, Inc. | Protective coat for firefighters |
US4950525A (en) * | 1983-04-11 | 1990-08-21 | Minnesota Mining And Manufacturing Company | Elastomeric retroreflective sheeting |
US5128804A (en) * | 1991-02-06 | 1992-07-07 | Minnesota Mining And Manufacturing Company | Permeable retroreflective sheeting |
US5207852A (en) * | 1991-02-06 | 1993-05-04 | Minnesota Mining And Manufacturing Company | Method for making permeable retroreflective sheeting |
US5269840A (en) * | 1992-02-04 | 1993-12-14 | Minnesota Mining And Manufacturing Company | Sol bonded colorant clusters and process for making |
US5316838A (en) * | 1991-09-30 | 1994-05-31 | Minnesota Mining And Manufacturing Company | Retroreflective sheet with nonwoven elastic backing |
US5467484A (en) * | 1993-12-13 | 1995-11-21 | Drescher; Bonnie J. | Non-slip glove |
US5599585A (en) * | 1992-03-12 | 1997-02-04 | Kimberly-Clark Corporation | Process to make an elastomeric metallized fabric |
US5656355A (en) * | 1992-03-12 | 1997-08-12 | Kimberly-Clark Corporation | Multilayer elastic metallized material |
US5664256A (en) * | 1994-10-07 | 1997-09-09 | Blauer Manufacturing Company, Inc. | Trousers with a removable liner |
US5830529A (en) * | 1996-01-11 | 1998-11-03 | Ross; Gregory E. | Perimeter coating alignment |
US6009560A (en) * | 1997-11-20 | 2000-01-04 | Lion Apparel, Inc. | Perforated reflective trim for use with garments |
US6148442A (en) * | 1997-01-17 | 2000-11-21 | Porter; A. Lee | Safety work-clothing |
US6155689A (en) * | 1997-12-16 | 2000-12-05 | Reflexite Corporation | Perforated retroreflective film |
US6336221B1 (en) * | 2000-11-06 | 2002-01-08 | Blauer Manufacturing Company, Inc. | Unlined waterproof clothing |
US6531212B2 (en) * | 2001-02-14 | 2003-03-11 | 3M Innovative Properties Company | Retroreflective article and method |
US6548164B1 (en) * | 1999-06-30 | 2003-04-15 | 3M Innovative Properties Company | Removable sheeting |
US6859941B2 (en) * | 2002-02-13 | 2005-03-01 | Safe Reflections, Inc. | High visibility safety apparel and graphic transfer therefor |
US6931665B2 (en) * | 2001-07-30 | 2005-08-23 | 3M Innovative Properties Company | Vapor permeable retroreflective garment |
Family Cites Families (60)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US285270A (en) * | 1883-09-18 | Julius jaegeb | ||
US2787975A (en) | 1955-10-26 | 1957-04-09 | Frank Newmiller | Turn signal for vehicle drivers |
US3190178A (en) * | 1961-06-29 | 1965-06-22 | Minnesota Mining & Mfg | Reflex-reflecting sheeting |
US3924929A (en) * | 1966-11-14 | 1975-12-09 | Minnesota Mining & Mfg | Retro-reflective sheet material |
US3849804A (en) | 1973-09-06 | 1974-11-26 | R Rakow | Light reflective safety wearing apparel |
JPS5812868B2 (en) | 1975-08-01 | 1983-03-10 | ユニチカ株式会社 | Tonosei Elephant Palm - Tonosei Elephant Palm |
US4085314A (en) | 1976-02-09 | 1978-04-18 | Minnesota Mining And Manufacturing Company | Encodable retroreflective sheeting |
US4025159A (en) * | 1976-02-17 | 1977-05-24 | Minnesota Mining And Manufacturing Company | Cellular retroreflective sheeting |
JPS52107587A (en) * | 1976-03-08 | 1977-09-09 | Furukawa Electric Co Ltd:The | Connecting methode of metal tape for use of cable |
US4055314A (en) * | 1976-09-17 | 1977-10-25 | Wyrepak Industries, Inc. | Wire pay-off cap assembly for wire spools |
US4145112A (en) * | 1977-07-14 | 1979-03-20 | Minnesota Mining And Manufacturing Company | Low-profile raised retroreflective sheeting |
US4202600A (en) * | 1978-04-24 | 1980-05-13 | Avery International Corporation | Diced retroreflective sheeting |
US4401494A (en) | 1979-07-25 | 1983-08-30 | Pernicano Vincent S | Reflective garment and method of manufacturing same |
US4533592A (en) * | 1984-08-02 | 1985-08-06 | Minnesota Mining And Manufacturing Company | Thermally stable flame retardant reflective and retroreflective trim |
US4656072A (en) * | 1985-06-17 | 1987-04-07 | Coburn Corporation | Retroreflective material for providing a colored decorative effect in visible light |
US4938563A (en) * | 1986-11-21 | 1990-07-03 | Minnesota Mining And Manufacturing Company | High efficiency cube corner retroflective material |
US5122902A (en) * | 1989-03-31 | 1992-06-16 | Minnesota Mining And Manufacturing Company | Retroreflective articles having light-transmissive surfaces |
US5264063A (en) * | 1990-05-16 | 1993-11-23 | Reflexite Corporation | Method for making flexible retroreflective sheet material |
JP2803892B2 (en) | 1990-06-04 | 1998-09-24 | 富士通株式会社 | Character recognition device |
US5202168A (en) * | 1990-09-18 | 1993-04-13 | Northrop Corporation | Precision retro-reflective target tape |
US5070436A (en) | 1990-10-29 | 1991-12-03 | Alexander Richard M | Signal vest, colored, reflective, and lighted, worn by persons seen on and nearby roadways and highways and other needed areas |
US6048611A (en) | 1992-02-03 | 2000-04-11 | 3M Innovative Properties Company | High solids moisture resistant latex pressure-sensitive adhesive |
JP3094130B2 (en) | 1992-02-12 | 2000-10-03 | 防衛庁技術研究本部長 | Camouflage nylon fabric |
EP0560384A1 (en) | 1992-03-12 | 1993-09-15 | Kimberly-Clark Corporation | Elastomeric metallized fabric and process of making same |
CA2094899C (en) | 1992-05-18 | 2000-04-11 | Britton G. Billingsley | Non-woven fluorescent retroreflective fabric |
US5601682A (en) * | 1992-07-28 | 1997-02-11 | Moore Business Forms, Inc. | Method of making reflective decals |
US5344705A (en) | 1993-05-05 | 1994-09-06 | Minnesota Mining And Manufacturing Company | Retroreflective transfer sheet material |
US5648145A (en) | 1993-09-10 | 1997-07-15 | Reflexite Corporation | Fire-resistant, retroreflective structure |
CA2171744A1 (en) | 1993-10-20 | 1995-04-27 | Gerald M. Benson | Directly machined raised structure retroreflective cube corner article and method of manufacture |
CN1105520C (en) | 1994-04-01 | 2003-04-16 | 美国3M公司 | Clothing bearing retroreflective appliques |
KR100375893B1 (en) | 1994-05-12 | 2003-05-16 | 미네소타 마이닝 앤드 매뉴팩춰링 캄파니 | Retroreflective article and its manufacturing method |
US5702846A (en) | 1994-10-03 | 1997-12-30 | Nippon Paint Co. Ltd. | Photosensitive composition for volume hologram recording |
DE69507050T2 (en) | 1994-11-23 | 1999-07-15 | Minnesota Mining And Mfg. Co., Saint Paul, Minn. | RETROREFLECTIVE OBJECT WITH A POLYETHER-POLYURETHANE BOND LAYER |
US5588156A (en) | 1995-06-07 | 1996-12-31 | Diamond Safety Gear, Inc. | Article of clothing having high visibility |
US5674605A (en) | 1995-09-15 | 1997-10-07 | Minnesota Mining And Manufacturing Company | Retroreflective transfer sheet and applique |
JP2000500407A (en) * | 1995-11-02 | 2000-01-18 | ミネソタ マイニング アンド マニュファクチャリング カンパニー | Lined microstructured article and method of making same |
USD383312S (en) * | 1996-01-19 | 1997-09-09 | Minnesota Mining And Manufacturing Company | Seal pattern on retroreflective sheeting |
US5754338A (en) * | 1996-04-01 | 1998-05-19 | Minnesota Mining And Manufacturing Company | Structured retroreflective sheeting having a rivet-like connection |
US5910858A (en) | 1996-04-01 | 1999-06-08 | Minnesota Mining And Manufacturing Company | Retroreflective sheeting with coated back surface |
US5882771A (en) * | 1996-04-10 | 1999-03-16 | Minnesota Mining And Manufacturing Company | Conformable embossable retroreflective sheeting |
US5763049A (en) * | 1996-04-30 | 1998-06-09 | Minnesota Mining And Manufacturing Company | Formed ultra-flexible retroreflective cube-corner composite sheeting with target optical properties and method for making same |
US6015214A (en) * | 1996-05-30 | 2000-01-18 | Stimsonite Corporation | Retroreflective articles having microcubes, and tools and methods for forming microcubes |
EP0995136A1 (en) | 1997-07-14 | 2000-04-26 | Reflective Technologies, Inc. | Retroreflective composition |
JPH1150378A (en) | 1997-07-30 | 1999-02-23 | Unitika Ltd | Production of printed fabric with permeability, moisture resistance, photo-accumulative property and recurrent reflection |
US6045230A (en) * | 1998-02-05 | 2000-04-04 | 3M Innovative Properties Company | Modulating retroreflective article |
USD418308S (en) * | 1998-02-05 | 2000-01-04 | Reflexite Corporation | Retroreflective sheeting |
USD413731S (en) * | 1998-06-25 | 1999-09-14 | Avery Dennison Corporation | Repeating surface pattern for retroreflective sheeting |
US6322652B1 (en) * | 1998-09-04 | 2001-11-27 | 3M Innovative Properties Company | Method of making a patterned surface articles |
US6155889A (en) * | 1999-01-06 | 2000-12-05 | Lightning Audio Corporation | Battery terminal connector |
US6159878A (en) | 1999-01-12 | 2000-12-12 | Omniglow Corporation | Layered reflecting and photoluminous fire resistant material |
US6224792B1 (en) | 1999-04-13 | 2001-05-01 | 3M Innovative Properties Company | Cutting and edge sealing cellular retroreflective sheeting |
WO2000061239A1 (en) | 1999-04-13 | 2000-10-19 | Dupont Canada Inc. | Perforated protective plastic films or sheets |
JP4132388B2 (en) | 1999-04-22 | 2008-08-13 | 株式会社小松プロセス | Retroreflective printing ink composition and retroreflective article using the same |
US6246428B1 (en) * | 1999-05-11 | 2001-06-12 | 3M Innovoative Properties Company | Method and system for thermal mass transfer printing |
ATE285588T1 (en) | 1999-06-17 | 2005-01-15 | 3M Innovative Properties Co | RETROREFLECTIVE ITEM HAVING A COLORED LAYER CONTAINING REFLECTIVE SHEETS AND A DYE COVALENTLY BONDED TO A POLYMER |
US6355302B1 (en) | 1999-12-10 | 2002-03-12 | 3M Innovative Properties Company | Continuous process for making high performance retroreflective fabric |
US6958179B2 (en) * | 1999-12-30 | 2005-10-25 | 3M Innovative Properties Company | Segmented sheeting and methods of making and using same |
US6508558B1 (en) * | 2000-10-02 | 2003-01-21 | Printmark Industries, Inc. | Retroflective prismatic retro-reflectors without visually disturbing seams |
GB0114738D0 (en) * | 2001-06-16 | 2001-08-08 | Reflec Plc | Retroreflective fabric production |
JP2004287138A (en) | 2003-03-24 | 2004-10-14 | Konica Minolta Holdings Inc | Composition for holographic recording, holographic recording medium and its recording method |
-
2001
- 2001-07-30 US US09/918,267 patent/US6931665B2/en not_active Expired - Lifetime
-
2002
- 2002-06-27 JP JP2003516308A patent/JP2004536978A/en active Pending
- 2002-06-27 KR KR1020047001300A patent/KR100901549B1/en active IP Right Grant
- 2002-06-27 EP EP02744731A patent/EP1414320B1/en not_active Expired - Lifetime
- 2002-06-27 CN CNB028173384A patent/CN100466927C/en not_active Expired - Lifetime
- 2002-06-27 CA CA 2455604 patent/CA2455604C/en not_active Expired - Lifetime
- 2002-06-27 DE DE60230151T patent/DE60230151D1/en not_active Expired - Lifetime
- 2002-06-27 AT AT02744731T patent/ATE415832T1/en not_active IP Right Cessation
- 2002-06-27 CA CA 2707746 patent/CA2707746C/en not_active Expired - Lifetime
- 2002-06-27 WO PCT/US2002/020611 patent/WO2003011064A1/en active Application Filing
- 2002-07-17 TW TW91115933A patent/TW579282B/en not_active IP Right Cessation
-
2004
- 2004-10-29 HK HK04108528A patent/HK1067505A1/en not_active IP Right Cessation
-
2005
- 2005-07-15 US US11/183,027 patent/US7107622B2/en not_active Expired - Lifetime
-
2006
- 2006-03-01 US US11/365,944 patent/US20060143772A1/en not_active Abandoned
- 2006-11-13 US US11/598,616 patent/US20070056077A1/en not_active Abandoned
-
2007
- 2007-08-16 US US11/839,782 patent/US7600269B2/en not_active Expired - Lifetime
-
2009
- 2009-09-03 US US12/553,118 patent/US8015620B2/en not_active Expired - Fee Related
-
2011
- 2011-08-15 US US13/210,036 patent/US8256025B2/en not_active Expired - Fee Related
Patent Citations (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4103060A (en) * | 1975-01-10 | 1978-07-25 | Minnesota Mining And Manufacturing Company | Area-retroreflectorization of fabrics |
USRE30892E (en) * | 1975-01-10 | 1982-03-30 | Minnesota Mining And Manufacturing Company | Area-retroreflectorization of fabrics |
US4263345A (en) * | 1979-11-16 | 1981-04-21 | Minnesota Mining And Manufacturing Company | Coating composition for forming retroreflective treatments on fabrics |
US4418110A (en) * | 1982-06-21 | 1983-11-29 | Minnesota Mining And Manufacturing | Vapor-permeable retroreflective sheeting |
US4950525A (en) * | 1983-04-11 | 1990-08-21 | Minnesota Mining And Manufacturing Company | Elastomeric retroreflective sheeting |
US4817210A (en) * | 1988-03-28 | 1989-04-04 | Lion Apparel, Inc. | Protective coat for firefighters |
US5128804A (en) * | 1991-02-06 | 1992-07-07 | Minnesota Mining And Manufacturing Company | Permeable retroreflective sheeting |
US5207852A (en) * | 1991-02-06 | 1993-05-04 | Minnesota Mining And Manufacturing Company | Method for making permeable retroreflective sheeting |
US5316838A (en) * | 1991-09-30 | 1994-05-31 | Minnesota Mining And Manufacturing Company | Retroreflective sheet with nonwoven elastic backing |
US5269840A (en) * | 1992-02-04 | 1993-12-14 | Minnesota Mining And Manufacturing Company | Sol bonded colorant clusters and process for making |
US5656355A (en) * | 1992-03-12 | 1997-08-12 | Kimberly-Clark Corporation | Multilayer elastic metallized material |
US5599585A (en) * | 1992-03-12 | 1997-02-04 | Kimberly-Clark Corporation | Process to make an elastomeric metallized fabric |
US5467484A (en) * | 1993-12-13 | 1995-11-21 | Drescher; Bonnie J. | Non-slip glove |
US5664256A (en) * | 1994-10-07 | 1997-09-09 | Blauer Manufacturing Company, Inc. | Trousers with a removable liner |
US5830529A (en) * | 1996-01-11 | 1998-11-03 | Ross; Gregory E. | Perimeter coating alignment |
US6148442A (en) * | 1997-01-17 | 2000-11-21 | Porter; A. Lee | Safety work-clothing |
US6009560A (en) * | 1997-11-20 | 2000-01-04 | Lion Apparel, Inc. | Perforated reflective trim for use with garments |
US6155689A (en) * | 1997-12-16 | 2000-12-05 | Reflexite Corporation | Perforated retroreflective film |
US6548164B1 (en) * | 1999-06-30 | 2003-04-15 | 3M Innovative Properties Company | Removable sheeting |
US6336221B1 (en) * | 2000-11-06 | 2002-01-08 | Blauer Manufacturing Company, Inc. | Unlined waterproof clothing |
US6490734B2 (en) * | 2000-11-06 | 2002-12-10 | Blauer Manufacturing Company, Inc. | Single layer jacket with detachable liner |
US6531212B2 (en) * | 2001-02-14 | 2003-03-11 | 3M Innovative Properties Company | Retroreflective article and method |
US6931665B2 (en) * | 2001-07-30 | 2005-08-23 | 3M Innovative Properties Company | Vapor permeable retroreflective garment |
US20050249926A1 (en) * | 2001-07-30 | 2005-11-10 | 3M Innovative Properties Company | Vapor permeable retroreflective garment |
US6859941B2 (en) * | 2002-02-13 | 2005-03-01 | Safe Reflections, Inc. | High visibility safety apparel and graphic transfer therefor |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20080077214A1 (en) * | 2006-09-19 | 2008-03-27 | Robert Stalick | Device and method for cooling animals |
US20100231113A1 (en) * | 2009-03-12 | 2010-09-16 | 3M Innovative Properties Company | Laminate reflective and electroluminescent article |
US20100232143A1 (en) * | 2009-03-12 | 2010-09-16 | Kenneth Burrows | Hybrid electroluminescent assembly |
US20110305006A1 (en) * | 2009-03-12 | 2011-12-15 | 3M Innovative Properties Company | Garment with a retroreflective and electroluminescent article |
US8288940B2 (en) | 2009-03-12 | 2012-10-16 | 3M Innovative Properties Company | Laminate reflective and electroluminescent article |
US8727550B2 (en) | 2009-03-12 | 2014-05-20 | Oryon Technologies, Llc | Hybrid electroluminescent assembly |
US9044055B2 (en) * | 2009-03-12 | 2015-06-02 | 3M Innovative Properties Company | Garment with a retroreflective and electroluminescent article |
CH703282A1 (en) * | 2010-06-15 | 2011-12-15 | Studio Crr Gmbh | Reflective element. |
WO2011156930A1 (en) * | 2010-06-15 | 2011-12-22 | Studio Crr Gmbh | Reflecting element |
US20230337758A1 (en) * | 2020-09-24 | 2023-10-26 | 3M Innovative Properties Company | Fabric and Garment Comprising Discrete Islands of Retroreflective Laminate |
Also Published As
Publication number | Publication date |
---|---|
EP1414320B1 (en) | 2008-12-03 |
US7107622B2 (en) | 2006-09-19 |
ATE415832T1 (en) | 2008-12-15 |
CA2707746A1 (en) | 2003-02-13 |
US20090320193A1 (en) | 2009-12-31 |
CA2455604C (en) | 2010-09-21 |
KR20040019376A (en) | 2004-03-05 |
US20110300348A1 (en) | 2011-12-08 |
US8015620B2 (en) | 2011-09-13 |
HK1067505A1 (en) | 2005-04-15 |
US7600269B2 (en) | 2009-10-13 |
US20080168591A1 (en) | 2008-07-17 |
CA2455604A1 (en) | 2003-02-13 |
JP2004536978A (en) | 2004-12-09 |
US6931665B2 (en) | 2005-08-23 |
US20050249926A1 (en) | 2005-11-10 |
US20060143772A1 (en) | 2006-07-06 |
DE60230151D1 (en) | 2009-01-15 |
EP1414320A1 (en) | 2004-05-06 |
WO2003011064A1 (en) | 2003-02-13 |
KR100901549B1 (en) | 2009-06-08 |
TW579282B (en) | 2004-03-11 |
CN100466927C (en) | 2009-03-11 |
US8256025B2 (en) | 2012-09-04 |
US20030019009A1 (en) | 2003-01-30 |
CN1551732A (en) | 2004-12-01 |
CA2707746C (en) | 2013-05-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US8256025B2 (en) | Vapor permeable retroreflective garment | |
US6974610B1 (en) | Graphic transfer for high visibility safety apparel | |
US20190187345A1 (en) | Reticulated Reflective Material | |
EP1812814B1 (en) | Retroreflective article having at least one valve and method of making same | |
US20200209442A1 (en) | Reticulated Reflective Material | |
EP3080648B1 (en) | Retroreflective article | |
US20230210200A1 (en) | A combined phosphorescent, retroreflective and fluorescent article | |
WO2002045801A2 (en) | Protective garments |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
STCB | Information on status: application discontinuation |
Free format text: EXPRESSLY ABANDONED -- DURING EXAMINATION |