US20060155019A1 - Fluidising composition - Google Patents
Fluidising composition Download PDFInfo
- Publication number
- US20060155019A1 US20060155019A1 US10/524,466 US52446605A US2006155019A1 US 20060155019 A1 US20060155019 A1 US 20060155019A1 US 52446605 A US52446605 A US 52446605A US 2006155019 A1 US2006155019 A1 US 2006155019A1
- Authority
- US
- United States
- Prior art keywords
- admixture
- formula
- moiety
- moieties
- mole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000203 mixture Substances 0.000 title claims description 33
- 229920000642 polymer Polymers 0.000 claims abstract description 18
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 9
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims abstract description 6
- 150000001991 dicarboxylic acids Chemical class 0.000 claims abstract description 4
- 150000002763 monocarboxylic acids Chemical class 0.000 claims abstract description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical group [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 12
- 239000001257 hydrogen Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 11
- 239000002184 metal Substances 0.000 claims description 11
- 150000001338 aliphatic hydrocarbons Chemical group 0.000 claims description 9
- 150000001768 cations Chemical class 0.000 claims description 9
- 150000002430 hydrocarbons Chemical class 0.000 claims description 9
- 239000007787 solid Substances 0.000 claims description 9
- 239000004568 cement Substances 0.000 claims description 8
- 238000005507 spraying Methods 0.000 claims description 8
- 125000005915 C6-C14 aryl group Chemical group 0.000 claims description 6
- 239000007921 spray Substances 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- 150000001412 amines Chemical group 0.000 claims description 3
- 229930195733 hydrocarbon Natural products 0.000 claims description 3
- YASYEJJMZJALEJ-UHFFFAOYSA-N Citric acid monohydrate Chemical compound O.OC(=O)CC(O)(C(O)=O)CC(O)=O YASYEJJMZJALEJ-UHFFFAOYSA-N 0.000 claims description 2
- 229960004106 citric acid Drugs 0.000 claims description 2
- 229960002303 citric acid monohydrate Drugs 0.000 claims description 2
- 239000004567 concrete Substances 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 0 [2*]COCCCC Chemical compound [2*]COCCCC 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- VZHNMXZOSYOSLE-UHFFFAOYSA-N CC(C)C(C)C.CC1C(=O)[Y]C(=O)C1C Chemical compound CC(C)C(C)C.CC1C(=O)[Y]C(=O)C1C VZHNMXZOSYOSLE-UHFFFAOYSA-N 0.000 description 3
- FBTWQXWGNWNLNO-RQOUITMFSA-N CC.CC.CCCCC(C)C.[3H][3H] Chemical compound CC.CC.CCCCC(C)C.[3H][3H] FBTWQXWGNWNLNO-RQOUITMFSA-N 0.000 description 3
- NROOFSSHAIJPKE-UHFFFAOYSA-N C[Si](C)(C)O[Si](C)(C)C.[W].[W] Chemical compound C[Si](C)(C)O[Si](C)(C)C.[W].[W] NROOFSSHAIJPKE-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- NCHOGQMVBXIRMI-UHFFFAOYSA-N CC.CC.CCCCC(C)C Chemical compound CC.CC.CCCCC(C)C NCHOGQMVBXIRMI-UHFFFAOYSA-N 0.000 description 2
- CLIMHBDVWIGBML-UHFFFAOYSA-N CCC(C)(C)CC.CCC(C)C.CCC1(C)CC(=O)[Y]C1=O Chemical compound CCC(C)(C)CC.CCC(C)C.CCC1(C)CC(=O)[Y]C1=O CLIMHBDVWIGBML-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000011398 Portland cement Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000004570 mortar (masonry) Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- UDPPYENZTRFVGY-UHFFFAOYSA-N C.C.CCOC.CCOC.CNC(C)N(C)C(C)=O.CO(C)O(C)C Chemical compound C.C.CCOC.CCOC.CNC(C)N(C)C(C)=O.CO(C)O(C)C UDPPYENZTRFVGY-UHFFFAOYSA-N 0.000 description 1
- RWELVDBVYNMOLC-UHFFFAOYSA-N CC.CCCCC(C)C Chemical compound CC.CCCCC(C)C RWELVDBVYNMOLC-UHFFFAOYSA-N 0.000 description 1
- LFFBLAHILWNALK-UHFFFAOYSA-N CCC(C)(C)CC.CCC(C)C.CCC1CC(=O)[Y]C1=O Chemical compound CCC(C)(C)CC.CCC(C)C.CCC1CC(=O)[Y]C1=O LFFBLAHILWNALK-UHFFFAOYSA-N 0.000 description 1
- JFZLXJRWBKSMPI-RCNZPAIWSA-N CCCCC(C)C.[3H][3H] Chemical compound CCCCC(C)C.[3H][3H] JFZLXJRWBKSMPI-RCNZPAIWSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920005682 EO-PO block copolymer Polymers 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- 150000001399 aluminium compounds Chemical class 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000012612 commercial material Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229920006226 ethylene-acrylic acid Polymers 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 239000011378 shotcrete Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 239000007779 soft material Substances 0.000 description 1
- 238000012430 stability testing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/003—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
- C04B24/26—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B24/2688—Copolymers containing at least three different monomers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
- C04B24/26—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B24/2688—Copolymers containing at least three different monomers
- C04B24/2694—Copolymers containing at least three different monomers containing polyether side chains
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/30—Water reducers, plasticisers, air-entrainers, flow improvers
- C04B2103/32—Superplasticisers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00034—Physico-chemical characteristics of the mixtures
- C04B2111/00146—Sprayable or pumpable mixtures
- C04B2111/00155—Sprayable, i.e. concrete-like, materials able to be shaped by spraying instead of by casting, e.g. gunite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00034—Physico-chemical characteristics of the mixtures
- C04B2111/00146—Sprayable or pumpable mixtures
- C04B2111/00155—Sprayable, i.e. concrete-like, materials able to be shaped by spraying instead of by casting, e.g. gunite
- C04B2111/00172—Sprayable, i.e. concrete-like, materials able to be shaped by spraying instead of by casting, e.g. gunite by the wet process
Definitions
- This invention relates to the spraying of cementitious compositions and to admixtures for use in such spraying.
- cementitious compositions such as concrete is regularly used in a number of applications, most notably in tunnelling. It is a requirement that such compositions be able to be easily conveyed (usually by pumping) to a spray nozzle. This can be achieved by the addition to the cementitious composition that is to be pumped and sprayed, at the mix stage, of an admixture which confers improved fluidity of the mix. There is a considerable variety of such admixtures known to and used by the art.
- the invention therefore provides a fluidising admixture for use with sprayable cementitious compostions, the admixture consisting of
- the polymer is characterised as follows—any moiety or group present in the polymer description hereinabove and not specifically mentioned in the following embodiment is absent from the embodiment, and any numerical value not specifically mentioned remains unaltered from that of the polymer description hereinabove;
- the polymer is characterised as follows—any moiety or group present in the description of the preferred embodiment hereinabove and not specifically mentioned in the following further preferred embodiment is absent from the further preferred embodiment, and any numerical value not specifically mentioned remains unaltered from that of the preferred embodiment description hereinabove;
- the polymers for use in this invention preferably have a weight-average molecular weight of from 5000-50000, preferably from 10000-40000.
- Typical examples of preferred polymers may be prepared by the reaction of methoxypolyethyleneglycol-monovinyl ether, maleic anhydride, amine-terminated ethylene oxide-propylene oxide block copolymer and acrylic acid. Examples of these materials and their preparation may be found in International Application WO 00/77058 the contents of which are incorporated herein by reference.
- the invention also provides a method of imparting flow to a cementitious composition, comprising the addition thereto of an admixture as hereinabove described.
- the invention also provides a method of spraying a cementitious composition by preparing a cementitious mix and conveying the mix to a spray nozzle, there being added to the mix at preparation an admixture as hereinabove described.
- proportions of the solids of the three components in the admixture are as follows: limits more preferred most preferred Component 1 1-40 2-20 4-12 Component 2 0-40 2-20 4-12 Component 3 5-60 10-40 20-30
- the admixture will always contain a proportion of water, and the admixture will never be 100% solids, as the “limits” and “more preferred” columns would seem to suggest is possible. However, the skilled person will be able to determine appropriate compositions in each case, by simple experimentation.
- the admixture is added to a cementitious mixture at a rate of from 0.2-2.0%, preferably from 0.5-0.8% by weight solids on cement.
- the admixture according to this invention may be used in conjunction with all the conventional admixtures used in the spraying of cementitious compositions, for example, the various accelerators commonly added at the spray nozzle.
- the admixture according to the invention works well with both the classic alkali types (such as aluminates, caustic alkalis and “water glass”) and the newer alkali-free, generally aluminium compound-based types.
- the admixture according to the invention performs at least as well as known fluidity-improving admixtures. It has the additional major practical advantage of having a very long shelf life.This means that it can be prepared well in advance of use and stored for several months without any segregation of ingredients. Moreover, it maintains this stability in the adverse conditions often found in tunnels, such as high temperatures, on exposure to which many conventional admixtures are no longer stable.
- An admixture is prepared by mixing the following components polymer (44% aqueous solution) 1 50 parts by weight water 36 parts 2-phosphonobutane-1,2,4-tricarboxylic acid 7.8 parts (50% aqueous solution) citric acid monohydrate 7.1 parts 1
- the material used is “MVA 2453 L/44%” ex. Degussa.
- the admixture according to the invention has performance characteristics comparable with those of the high performance commercial material.
- Samples of the admixture are tested in a mortar by flow table and for setting time.
- the mortar is a 1:3 blend of CEM I42.5 Portland cement and CEM standard sand (according to DIN EN 196-1), and the admixture samples are added at a rate of 1% solids by weight on cement. Samples are also stored at 20° C., 30° C. and 40° C. for six months. At the end of the six months, the admixtures remained visually unaffected.
- the actual test results are shown in the following table: Sample No.
Landscapes
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Jellies, Jams, And Syrups (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Lubricants (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/040,475 US20080221243A1 (en) | 2002-09-09 | 2008-02-29 | Fluidising composition |
| US12/694,796 US8177905B2 (en) | 2002-09-09 | 2010-01-27 | Fluidising composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/EP2002/010045 WO2004024646A1 (en) | 2002-09-09 | 2002-09-09 | Fluidising composition |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US12/040,475 Continuation US20080221243A1 (en) | 2002-09-09 | 2008-02-29 | Fluidising composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US20060155019A1 true US20060155019A1 (en) | 2006-07-13 |
Family
ID=31984988
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US10/524,466 Abandoned US20060155019A1 (en) | 2002-09-09 | 2002-09-09 | Fluidising composition |
| US12/040,475 Abandoned US20080221243A1 (en) | 2002-09-09 | 2008-02-29 | Fluidising composition |
| US12/694,796 Expired - Fee Related US8177905B2 (en) | 2002-09-09 | 2010-01-27 | Fluidising composition |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US12/040,475 Abandoned US20080221243A1 (en) | 2002-09-09 | 2008-02-29 | Fluidising composition |
| US12/694,796 Expired - Fee Related US8177905B2 (en) | 2002-09-09 | 2010-01-27 | Fluidising composition |
Country Status (14)
| Country | Link |
|---|---|
| US (3) | US20060155019A1 (de) |
| EP (1) | EP1537058B1 (de) |
| JP (1) | JP4547261B2 (de) |
| CN (1) | CN100497233C (de) |
| AT (1) | ATE397572T1 (de) |
| AU (1) | AU2002331110B2 (de) |
| BR (1) | BR0215861B1 (de) |
| CA (1) | CA2495828C (de) |
| DE (1) | DE60227010D1 (de) |
| ES (1) | ES2307785T3 (de) |
| MX (1) | MXPA05002629A (de) |
| NO (1) | NO338998B1 (de) |
| PT (1) | PT1537058E (de) |
| WO (1) | WO2004024646A1 (de) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013001038A1 (en) * | 2011-06-29 | 2013-01-03 | Sika Technology Ag | Skin layer reduction in calcium sulfate based binder compositions |
| JP6707228B2 (ja) * | 2016-06-21 | 2020-06-10 | 竹本油脂株式会社 | コンクリート組成物及びコンクリート硬化体 |
| CN115650656A (zh) * | 2022-11-11 | 2023-01-31 | 上海城建市政工程（集团）有限公司 | 一种工作时间可调的超高性能混凝土 |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3964921A (en) * | 1975-02-27 | 1976-06-22 | Calgon Corporation | Well cementing composition having improved flow properties, containing phosphonobutane tricarboxylic acid, and method of use |
| US4040854A (en) * | 1975-02-27 | 1977-08-09 | Calgon Corporation | Methods of using cementing compositions having improved flow properties, containing phosphonobutane tricarboxylic acid |
| US4222784A (en) * | 1976-11-15 | 1980-09-16 | Lafarge | Novel binder and its utilization for preparing quick-setting mortars and microconcretes |
| US4507154A (en) * | 1981-10-12 | 1985-03-26 | Sika Ag, Vorm. Kaspar Winkler & Co. | Chloride-free setting accelerator for hydraulic binding agents |
| US5369198A (en) * | 1993-02-01 | 1994-11-29 | Chemie Linz Gesellschaft M.B.H | Copolymers based on maleic acid derivatives and vinyl monomers, their production and application |
| US5389144A (en) * | 1991-06-21 | 1995-02-14 | Sika Ag Vorm. Kaspar Winkler & Co. | Admixture for spray concrete and mortar and a method for the manufacture of spray concrete and mortar using this admixture |
| US5413819A (en) * | 1990-01-27 | 1995-05-09 | Sandoz Ltd. | Shotcrete compositions |
| US5567236A (en) * | 1992-12-29 | 1996-10-22 | C F P I | Composition containing materials improving the rheological properties of cement-based products |
| US6767164B2 (en) * | 2000-06-12 | 2004-07-27 | W. R. Grace & Co.-Conn. | Tunnel waterproofing construction method |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT374280B (de) * | 1980-06-16 | 1984-04-10 | List Hans | Messwertaufnehmer zur messung mechanischer groessen an hohlkoerpern |
| CH681720A5 (de) * | 1991-04-12 | 1993-05-14 | Sika Ag | |
| GB2347415A (en) * | 1999-03-02 | 2000-09-06 | Mbt Holding Ag | Set-retarding admixture for calcium sulfoaluminate cements |
| DE19926611A1 (de) * | 1999-06-11 | 2000-12-14 | Sueddeutsche Kalkstickstoff | Copolymere auf Basis von ungesättigten Mono- oder Dicarbonsäure-Derivaten und Oxyalkylenglykol-Alkenylethern, Verfahren zu deren Herstellung und ihre Verwendung |
-
2002
- 2002-09-09 WO PCT/EP2002/010045 patent/WO2004024646A1/en active IP Right Grant
- 2002-09-09 JP JP2004535029A patent/JP4547261B2/ja not_active Expired - Fee Related
- 2002-09-09 DE DE60227010T patent/DE60227010D1/de not_active Expired - Lifetime
- 2002-09-09 AU AU2002331110A patent/AU2002331110B2/en not_active Ceased
- 2002-09-09 AT AT02767476T patent/ATE397572T1/de not_active IP Right Cessation
- 2002-09-09 US US10/524,466 patent/US20060155019A1/en not_active Abandoned
- 2002-09-09 ES ES02767476T patent/ES2307785T3/es not_active Expired - Lifetime
- 2002-09-09 MX MXPA05002629A patent/MXPA05002629A/es active IP Right Grant
- 2002-09-09 PT PT02767476T patent/PT1537058E/pt unknown
- 2002-09-09 BR BRPI0215861-2A patent/BR0215861B1/pt not_active IP Right Cessation
- 2002-09-09 CA CA2495828A patent/CA2495828C/en not_active Expired - Fee Related
- 2002-09-09 CN CNB028295838A patent/CN100497233C/zh not_active Expired - Fee Related
- 2002-09-09 EP EP02767476A patent/EP1537058B1/de not_active Expired - Lifetime
-
2005
- 2005-04-08 NO NO20051747A patent/NO338998B1/no not_active IP Right Cessation
-
2008
- 2008-02-29 US US12/040,475 patent/US20080221243A1/en not_active Abandoned
-
2010
- 2010-01-27 US US12/694,796 patent/US8177905B2/en not_active Expired - Fee Related
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3964921A (en) * | 1975-02-27 | 1976-06-22 | Calgon Corporation | Well cementing composition having improved flow properties, containing phosphonobutane tricarboxylic acid, and method of use |
| US4040854A (en) * | 1975-02-27 | 1977-08-09 | Calgon Corporation | Methods of using cementing compositions having improved flow properties, containing phosphonobutane tricarboxylic acid |
| US4222784A (en) * | 1976-11-15 | 1980-09-16 | Lafarge | Novel binder and its utilization for preparing quick-setting mortars and microconcretes |
| US4507154A (en) * | 1981-10-12 | 1985-03-26 | Sika Ag, Vorm. Kaspar Winkler & Co. | Chloride-free setting accelerator for hydraulic binding agents |
| US5413819A (en) * | 1990-01-27 | 1995-05-09 | Sandoz Ltd. | Shotcrete compositions |
| US5389144A (en) * | 1991-06-21 | 1995-02-14 | Sika Ag Vorm. Kaspar Winkler & Co. | Admixture for spray concrete and mortar and a method for the manufacture of spray concrete and mortar using this admixture |
| US5567236A (en) * | 1992-12-29 | 1996-10-22 | C F P I | Composition containing materials improving the rheological properties of cement-based products |
| US5369198A (en) * | 1993-02-01 | 1994-11-29 | Chemie Linz Gesellschaft M.B.H | Copolymers based on maleic acid derivatives and vinyl monomers, their production and application |
| US6767164B2 (en) * | 2000-06-12 | 2004-07-27 | W. R. Grace & Co.-Conn. | Tunnel waterproofing construction method |
Also Published As
| Publication number | Publication date |
|---|---|
| MXPA05002629A (es) | 2005-05-27 |
| BR0215861A (pt) | 2005-07-05 |
| ES2307785T3 (es) | 2008-12-01 |
| PT1537058E (pt) | 2008-08-27 |
| CA2495828C (en) | 2011-01-11 |
| EP1537058B1 (de) | 2008-06-04 |
| US8177905B2 (en) | 2012-05-15 |
| BR0215861B1 (pt) | 2011-11-29 |
| US20080221243A1 (en) | 2008-09-11 |
| US20100130647A1 (en) | 2010-05-27 |
| JP2005538024A (ja) | 2005-12-15 |
| CN1668547A (zh) | 2005-09-14 |
| AU2002331110B2 (en) | 2010-09-09 |
| CN100497233C (zh) | 2009-06-10 |
| NO338998B1 (no) | 2016-11-07 |
| WO2004024646A1 (en) | 2004-03-25 |
| DE60227010D1 (de) | 2008-07-17 |
| CA2495828A1 (en) | 2004-03-25 |
| NO20051747D0 (no) | 2005-04-08 |
| ATE397572T1 (de) | 2008-06-15 |
| JP4547261B2 (ja) | 2010-09-22 |
| AU2002331110A1 (en) | 2004-04-30 |
| NO20051747L (no) | 2005-04-08 |
| EP1537058A1 (de) | 2005-06-08 |
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