US20050279478A1 - Planar elements for use in papermaking machines - Google Patents

Planar elements for use in papermaking machines Download PDF

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Publication number
US20050279478A1
US20050279478A1 US11/148,624 US14862405A US2005279478A1 US 20050279478 A1 US20050279478 A1 US 20050279478A1 US 14862405 A US14862405 A US 14862405A US 2005279478 A1 US2005279478 A1 US 2005279478A1
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United States
Prior art keywords
planar element
nanoparticles
fibres
polymeric resin
resin matrix
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Abandoned
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US11/148,624
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English (en)
Inventor
Michael Draper
John James
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kadant Web Systems Inc
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Michael Draper
John James
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Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=34972338&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=US20050279478(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Michael Draper, John James filed Critical Michael Draper
Priority to US11/148,624 priority Critical patent/US20050279478A1/en
Publication of US20050279478A1 publication Critical patent/US20050279478A1/en
Assigned to KADANT WEB SYSTEMS, INC. reassignment KADANT WEB SYSTEMS, INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: DRAPER, MICHAEL, JAMES, JOHN
Priority to US13/754,453 priority patent/US20130139988A1/en
Abandoned legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21G—CALENDERS; ACCESSORIES FOR PAPER-MAKING MACHINES
    • D21G3/00—Doctors
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21G—CALENDERS; ACCESSORIES FOR PAPER-MAKING MACHINES
    • D21G3/00—Doctors
    • D21G3/005—Doctor knifes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y99/00—Subject matter not provided for in other groups of this subclass

Definitions

  • This invention relates generally to planar elements employed in papermaking machines as doctor blades, creping blades, coater blades, top plates in blade holders, and wear surfaces on foil blades, and is concerned in particular with synthetic composite constructions of such planar elements that incorporate nanoparticles in a polymeric resin matrix.
  • Doctor blades contact the surfaces of rolls in papermaking and web converting machines for the purpose of cleaning or sheet removal.
  • Conventional doctor blades have been made from a wide variety of materials including both metals and synthetic polymer composites.
  • a bevel edge is machined into the polymer composite to produce an angled slant at the tip of the blade to aid roll cleaning or sheet removal. The sharper and cleaner this edge is, the more efficient the performance of the doctor blade.
  • Coater blades work in a similar manner to doctor blades, and are used in a wiping mode to meter a layer of liquid onto a sheet of paper or other material. Coater blades do, however, tend to be thinner than conventional doctor blades, typically having thicknesses between 0.3 mm to 0.7 mm. Conventional coater blade materials include steel, stainless steel and steel with a treated edges for prolonging the useful life.
  • Top plates form the backbone of a doctoring system connecting the pivoting mechanism and blade keeps.
  • Synthetic top plates are currently made from similar materials to synthetic doctor blades in that they comprise a fibre or fabric reinforced polymeric resin composite. Top plates are flat, with high rigidity in their width, but with flexibility along their length, so that they can conform to a roll surface.
  • Foil blades located under the forming fabric, are used to dewater stock/slurry in the forming section of a paper machine. They work by inducing a vacuum under the fabric which, in turn, aids the dewatering of the sheet.
  • Foil blade profiles have been made from High Density Polyethylene (HDPE), but this material has insufficient wear resistance to survive for the required periods of time in many of these situations.
  • Various ceramic materials including Alumina, Zirconia, Silicon Nitride and Silicon Carbide have been added to the tip of these HDPE profiles to address this problem and produce a more even wear pattern.
  • planar element is intended to broadly encompass not only all of the above-described doctor blades, coater blades, top plates and foil blades, but also doctor blades without fabric reinforcements, creping blades, and covers for forming boards and suction boxes.
  • planar elements in accordance with the present invention comprise synthetic constructions incorporating nanoparticles.
  • Nanoparticles can be as small as 3 atoms thick, typically between 0.1 to 100 nm in size and involve interactions at a molecular or atomic level. These interactions and subsequent resulting properties can differ significantly from those at larger scales and are currently providing superior performance properties in a number of novel applications.
  • nanoparticles have been found to improve the non-stick properties of anti-marine fouling paints and anti-graffiti coatings. They have been found to improve the ultraviolet ray blocking properties of sunscreens, have enabled the production of self-cleaning windows and are being used to produce self-sanitizing tiles for use in clean environments ranging from hospitals to restaurants.
  • a planar element construction can be achieved by dispersing nanoparticles in a polymeric resin matrix so as to produce a nano-filled polymer composite.
  • the amount of nanoparticles can comprise between about 0.5 to 75%, preferably about 5 to 20%, and most preferably about 10 to 15% by weight of the polymeric resin matrix.
  • Nanoparticles may comprise powders, grains, fibres or platelets.
  • Metallic nanoparticles may be selected from the group consisting of metal oxides, carbides or nitrides, metallic complexes, ionic structures and covalent compounds.
  • Non-metallic and/or covalent nanoparticles may be selected from the group consisting of clay particles, silicates, ceramic materials, glass particles, carbon black, fumed silica, calcium carbonate, carbon nanotubes and nanospheres of ceramic powders such as Titanium oxide.
  • Synthetic doctor blades incorporating nanoparticles in accordance with the present invention have increased mechanical properties, including increased wear and abrasion resistance, improved flexural strength and increased hardness.
  • the nanoparticle reinforced doctor blades perform with improved wear characteristics, with the bevel edge wearing more evenly and maintaining its sharpness and integrity for longer than a comparable blade without any nanoparticle inclusion, whilst the increased hardness results in enhanced impact resistance which can in turn prevent premature failure.
  • the nanoparticles produce a sharper and more homogenous bevel edge than that produced in a non-nanoparticle containing synthetic doctor blade by helping to fill the minute voids that would be otherwise present in the resin matrix.
  • the nanoparticles improve the inter-laminar adhesion of the constituent layers of the synthetic doctor blade, thus improving inter-layer bonding and consequently increasing the resistance to delamination.
  • a further benefit of a nano-filled composite doctor blade is reduced frictional drag. This enables a papermaker to use less energy in running his machine at a fixed speed, or alternatively enables him to operate at a faster speed without increasing his energy consumption. Nanoparticles also impart additional chemical resistance. This is important in order for doctor blades to resist chemical degradation within the hostile environments in which they operate.
  • Carbon fibres made from carbon nanotubes and polyacrlonitrile may be used in the fabric substrates, for additional reinforcement, since these fibres tend to be stronger, stiffer and more dimensionally stable than standard carbon fibres.
  • nanoparticles into a synthetic coater blade is beneficial by both improving the uniformity and homogeneous nature of the coating edge and by imparting additional chemical resistance. Improvements in edge wear resistance, flexural strength, improved adhesion and reduced frictional drag will also be beneficial to coater blade performance.
  • Nanoparticles dispersed in the polymer resin systems of top plates will increase the strength of these composite structures, thus improving their support capability.
  • Nanofilled polymeric resin foil blades have an improved wear resistance surface with increased flexural strength, increased fracture toughness and reduced coefficient of friction.
  • the nanoparticles also impart a more consistent wear surface which provides more uniform dewatering, a more even moisture profile and ultimately a better quality of sheet.
  • FIG. 1 is a partial cross sectional view, with dimensions exaggerated for purposes of illustration, of a blade construction in accordance with one embodiment of the invention.
  • FIG. 2 is a view similar to FIG. 1 showing an alternative embodiment of the invention.
  • a planar element in the form of a doctor blade constructed in accordance with the present invention is shown at 10 comprising a composite of multiple layers 12 of resin-impregnated fabrics (commonly referred to as “pre-pregs”).
  • the pre-pregs may typically comprise woven or non-woven, unidirectional or multidirectional glass, carbon or aramid fibres, a representative example being 200 gsm plane weave E-glass style 7628 or high strength standard modulus carbon T300 supplied by PD Interglas Technologies Ltd. of Sherborne, U.K.
  • the layers 12 are impregnated and surface coated with a resin containing a dispersion of clay nanoparticles.
  • a representative resin dispersion is a bisphenol A type epoxy resin supplied by Bakelite Polymers UK Ltd. of Telford, U.K., with clay nanoparticles added to and uniformly dispersed therein in an amount of 15% by weight of the resin matrix.
  • the resin interfaces at 16 serve to adhere the layers 12 together during lamination under conditions of elevated temperature and pressure in accordance with well known practices.
  • planar element 10 manufactured by pultrusion, resin injection, and reactive resin injection molding.
  • the nanoparticles help to fill tiny voids that would be otherwise present in the polymeric resin matrix and are thereby conducive to producing a sharper, more uniform bevel edge.
  • the nanoparticles also have the effect of reinforcing the polymer composite and increasing the mechanical wear or abrasion resistance of the blade against a machine roll, thus rendering the blade particularly well suited for use in modern high speed paper machines, where the speeds attained result in both fast and severe wear of conventional doctor blades.
  • the overall result is that the nanocomposite filled blades wear more evenly, maintaining a sharper bevel edge, than traditional non-nanoparticle containing doctor blade equivalents.
  • nanocomposite filled doctor blade Another benefit of a nanocomposite filled doctor blade is the reduction in drag against the roll surface.
  • the nanoparticles have the effect of reducing the frictional drag enabling machines to run at a constant speed using less power consumption or at a faster speed using the same energy consumption.
  • Testing against a dry steel roll, rotating at 1000 m per minute (668 revs per minute), set at an angle of 25° with a load of 0.178 kg/cm (1 pli) showed over a 7% reduction in frictional drag.
  • nanoparticles also increases both the hardness and flexural strength of composite doctor blades. Improvements of 25-30% in Flexural strength and 27-32% in the modulus of elasticity have been recorded in comparisons with non-nanoparticle containing composite blades without any significant loss in glass transition temperature. The improvement in these properties enable the nanocomposite filled doctor blade to withstand higher impacts, loads and shocks.
  • carbon fibres made from carbon nanotubes and polyacrlonitrile could be used in the fabric substrate, for additional reinforcement, since these fibres tend to be stronger, stiffer and more dimensionally stable than standard carbon fibres.
  • FIG. 2 illustrates an alternative blade construction 10 ′ in which the pre-preg layers 12 ′ are adhered together by means of resin film components 18 interposed therebetween.
  • the layers 12 ′ and/or the films 18 may contain nanoparticles.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Nanotechnology (AREA)
  • Materials Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Composite Materials (AREA)
  • Paper (AREA)
  • Reinforced Plastic Materials (AREA)
  • Laminated Bodies (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Woven Fabrics (AREA)
US11/148,624 2004-06-14 2005-06-09 Planar elements for use in papermaking machines Abandoned US20050279478A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US11/148,624 US20050279478A1 (en) 2004-06-14 2005-06-09 Planar elements for use in papermaking machines
US13/754,453 US20130139988A1 (en) 2004-06-14 2013-01-30 Planar Elements for Use in Papermaking Machines

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US57941304P 2004-06-14 2004-06-14
US11/148,624 US20050279478A1 (en) 2004-06-14 2005-06-09 Planar elements for use in papermaking machines

Related Child Applications (1)

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US13/754,453 Continuation US20130139988A1 (en) 2004-06-14 2013-01-30 Planar Elements for Use in Papermaking Machines

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US20050279478A1 true US20050279478A1 (en) 2005-12-22

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US11/148,624 Abandoned US20050279478A1 (en) 2004-06-14 2005-06-09 Planar elements for use in papermaking machines
US13/754,453 Abandoned US20130139988A1 (en) 2004-06-14 2013-01-30 Planar Elements for Use in Papermaking Machines

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Country Status (12)

Country Link
US (2) US20050279478A1 (fi)
EP (1) EP1776503B2 (fi)
JP (1) JP4860607B2 (fi)
KR (1) KR20070045192A (fi)
CN (1) CN100535240C (fi)
BR (1) BRPI0512076B1 (fi)
CA (1) CA2570040C (fi)
ES (1) ES2665870T3 (fi)
FI (1) FI1776503T4 (fi)
MX (1) MXPA06014520A (fi)
RU (1) RU2352704C2 (fi)
WO (1) WO2005124019A1 (fi)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070052134A1 (en) * 2005-09-08 2007-03-08 Michael Draper Planar elements incorporating basalt fibers for use in papermaking apparatus
US20080012155A1 (en) * 2006-06-29 2008-01-17 Nachiket Raravikar Aligned nanotube bearing composite material
US20080235960A1 (en) * 2005-09-28 2008-10-02 Ike-Service Toy Blade, Structural Components of a Blade, and Method For Manufacturing a Blade and the Structural Components of a Blade
US20090202846A1 (en) * 2008-02-08 2009-08-13 Mohan Jayaraman Thermally adaptive surfaces for receiving thermal sprays
US20090226706A1 (en) * 2008-03-06 2009-09-10 Metso Paper, Inc. Doctor blade and method for manufacture of doctor blade
EP2677215A1 (en) * 2011-02-18 2013-12-25 Kabushiki Kaisha Riken Piston ring
US20140023846A1 (en) * 2012-07-23 2014-01-23 Kadant Inc. Doctor Blade Including Combination Carbon/Glass Yarns
DE102016120649A1 (de) 2016-10-28 2018-05-03 Voith Patent Gmbh Entwässerungsvorrichtung
US10190258B2 (en) * 2015-08-13 2019-01-29 Kadant Inc. Doctor blade holders and doctor blade holder systems including planar elements with three dimensional fabric reinforcement materials
EP4108828A1 (en) * 2021-06-22 2022-12-28 Valmet Technologies Oy Elongated component for a manufacturing machine of a fibrous cellulosic web, its use and method for recycling

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Publication number Priority date Publication date Assignee Title
DE102005002637A1 (de) * 2005-01-20 2006-07-27 Voith Paper Patent Gmbh Schaberklinge
DE102005038652A1 (de) 2005-08-16 2007-02-22 Voith Patent Gmbh Schabervorrichtung für Papiermaschine
FI20065639L (fi) * 2006-10-05 2008-04-06 Metso Paper Inc Paperikoneen tai vastaavan perälaatikon lamelli
US20100204364A1 (en) 2007-02-28 2010-08-12 Metso Paper, Inc. Roll cover material, use thereof for preparing a cover layer, and method of manufacturing an elastic roll cover
FI20106216A (fi) * 2010-11-18 2012-05-19 Exel Composites Oyj Menetelmä kaavinterälaminaatin valmistamiseksi sekä kaavinterälaminaatti

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US20050214033A1 (en) * 2004-03-25 2005-09-29 Macmillan David S Electrophotographic toner regulating member with polymer coating having surface roughness modified by fine particles
US6979387B2 (en) * 2002-03-08 2005-12-27 Ichikawa Co., Ltd. Doctor blade for removing water
US7066065B2 (en) * 2002-04-01 2006-06-27 Johns Manville Compression-cutting assembly and method
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US4549933A (en) * 1983-07-05 1985-10-29 Thermo Electron Corporation Doctor blade with non-homogeneous stiffness properties
US4735144A (en) * 1986-05-21 1988-04-05 Jenkins Jerome D Doctor blade and holder for metering system
US4978999A (en) * 1989-04-17 1990-12-18 Xerox Corporation Fiber reinforced cleaning blade
US5117264A (en) * 1991-04-03 1992-05-26 Xerox Corporation Damage resistant cleaning blade
US5153657A (en) * 1991-04-29 1992-10-06 Xerox Corporation Cleaning blade wear life extension by inorganic fillers reinforcement
US5638751A (en) * 1994-10-26 1997-06-17 Max Daetwyler Corporation Integrated doctor blade and back-up blade
US20020176934A1 (en) * 1997-09-11 2002-11-28 Metso Paper, Inc. Caring doctor blade and method for manufacture of same
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US6265333B1 (en) * 1998-06-02 2001-07-24 Board Of Regents, University Of Nebraska-Lincoln Delamination resistant composites prepared by small diameter fiber reinforcement at ply interfaces
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US7066065B2 (en) * 2002-04-01 2006-06-27 Johns Manville Compression-cutting assembly and method
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US20040180201A1 (en) * 2002-07-01 2004-09-16 Veedu Sreekumar T. Macroscopic fiber comprising single-wall carbon nanotubes and acrylonitrile-based polymer and process for making the same
US20040067364A1 (en) * 2002-10-08 2004-04-08 National Aerospace Laboratory Of Japan Carbon nanofiber-dispersed resin fiber-reinforced composite material
US20070265379A1 (en) * 2003-05-22 2007-11-15 Zyvex Corporation Nanocomposites and methods thereto
US20050188831A1 (en) * 2003-07-11 2005-09-01 Us Global Nanospace, Inc. Ballistic resistant turret and method of making same
US20050095938A1 (en) * 2003-10-29 2005-05-05 Rosenberger Brian T. Carbon nanotube fabrics
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US20050214033A1 (en) * 2004-03-25 2005-09-29 Macmillan David S Electrophotographic toner regulating member with polymer coating having surface roughness modified by fine particles
US7157571B2 (en) * 2004-09-30 2007-01-02 Industrial Technology Research Institute Hepatoma specific chimeric regulatory sequence

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070052134A1 (en) * 2005-09-08 2007-03-08 Michael Draper Planar elements incorporating basalt fibers for use in papermaking apparatus
US8308908B2 (en) 2005-09-28 2012-11-13 Exel Oyj Blade, structural components of a blade, and method for manufacturing a blade and the structural components of a blade
US20080235960A1 (en) * 2005-09-28 2008-10-02 Ike-Service Toy Blade, Structural Components of a Blade, and Method For Manufacturing a Blade and the Structural Components of a Blade
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CN100535240C (zh) 2009-09-02
CA2570040A1 (en) 2005-12-29
CA2570040C (en) 2012-04-24
EP1776503A1 (en) 2007-04-25
EP1776503B1 (en) 2018-02-21
KR20070045192A (ko) 2007-05-02
EP1776503B2 (en) 2023-06-07
US20130139988A1 (en) 2013-06-06
BRPI0512076A (pt) 2008-02-06
FI1776503T4 (fi) 2023-08-31
BRPI0512076B1 (pt) 2016-06-14
JP4860607B2 (ja) 2012-01-25
JP2008502817A (ja) 2008-01-31
RU2352704C2 (ru) 2009-04-20
ES2665870T3 (es) 2018-04-30
RU2007101292A (ru) 2008-07-27
CN1989296A (zh) 2007-06-27
MXPA06014520A (es) 2007-03-23
WO2005124019A1 (en) 2005-12-29

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