US20040009356A1 - Substrate having thermal management coating for an insulating glass unit - Google Patents

Substrate having thermal management coating for an insulating glass unit Download PDF

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Publication number
US20040009356A1
US20040009356A1 US10/428,481 US42848103A US2004009356A1 US 20040009356 A1 US20040009356 A1 US 20040009356A1 US 42848103 A US42848103 A US 42848103A US 2004009356 A1 US2004009356 A1 US 2004009356A1
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United States
Prior art keywords
layer
separation layer
article
coating
unit
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US10/428,481
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English (en)
Inventor
Paul Medwick
Andrew Wagner
Dennis O'Shaughnessy
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PPG Industries Ohio Inc
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PPG Industries Ohio Inc
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=29406810&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=US20040009356(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority to CA2484181A priority Critical patent/CA2484181C/fr
Priority to AU2003231310A priority patent/AU2003231310B2/en
Priority to PCT/US2003/014027 priority patent/WO2003093188A1/fr
Priority to US10/428,481 priority patent/US20040009356A1/en
Priority to JP2004501331A priority patent/JP5066323B2/ja
Priority to ES03724450T priority patent/ES2627198T5/es
Priority to MXPA04010882A priority patent/MXPA04010882A/es
Application filed by PPG Industries Ohio Inc filed Critical PPG Industries Ohio Inc
Priority to EP03724450.6A priority patent/EP1501768B2/fr
Priority to CNB038127105A priority patent/CN100379699C/zh
Priority to RU2004135318/03A priority patent/RU2342335C2/ru
Priority to CZ2004-1076A priority patent/CZ307556B6/cs
Assigned to PPG INDUSTRIES OHIO, INC. reassignment PPG INDUSTRIES OHIO, INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: MEDWICK, PAUL A., O'SHAUGHNESSY, DENNIS J., WAGNER, ANDREW V.
Publication of US20040009356A1 publication Critical patent/US20040009356A1/en
Priority to HK06102493A priority patent/HK1081940A1/xx
Priority to US11/519,188 priority patent/US7910229B2/en
Priority to JP2009157128A priority patent/JP5448610B2/ja
Abandoned legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3613—Coatings of type glass/inorganic compound/metal/inorganic compound/metal/other
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3618—Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3639—Multilayers containing at least two functional metal layers
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
    • C03C17/366—Low-emissivity or solar control coatings
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3681—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating being used in glazing, e.g. windows or windscreens

Definitions

  • This invention relates generally to solar control coatings and, more particularly, to a coating that has solar control and spectral properties adaptable for use on a surface other than the inner surface of the outboard sheet (#2 surface) of a multi sheet-glazed insulating unit.
  • Multi sheet-glazed insulating glass units having two or more spaced glass sheets are becoming the industry standard for residential and commercial architecture in geographic regions having cool to cold climates, e.g., those climates characterized by seasons requiring extensive periods of operating heating furnaces.
  • the IG unit has improved thermal insulating performance over windows having single glass sheets due to its reduced conductive and convective transfer of heat compared to a conventional window.
  • the use of IG units has not been popular in geographic regions having warm to hot climates, e.g., those climates characterized by seasons requiring extensive periods of operating air conditioners, because the primary functionality required of windows in such regions is solar heat load reduction, not insulating value.
  • solar-control coated glasses have been introduced into the market. Such solar-control coated glasses achieve significant levels of solar heat load reduction by decreasing the amount of solar energy (in the visible and/or near-infrared portions of the electromagnetic spectrum) that is directly transmitted through the coated glass, often by absorbing large amounts of the incident energy and/or by reflecting large amounts of visible light. More recently, certain high-performance silver-based low emissivity (low-E) coatings have been recognized as also having a significant degree of solar-control functionality in addition to their excellent thermal insulating properties.
  • low-E high-performance silver-based low emissivity
  • Such silver-based solar-control/low-E coated glasses are now becoming increasingly popular not only in climates characterized by long heating seasons (for their low-E/thermal insulating performance) but also in climates characterized by long cooling seasons such as the deep South, Southeastern, and Southeastern parts of the United States due to their solar-control benefits.
  • thermal management functionalities include aesthetics, safety, and ease of cleaning.
  • architects may desire to provide a wide range of colors for an IG unit to enhance the aesthetic appearance of a building.
  • colored or tinted glass sheets can be used as the outer sheets of the IG unit.
  • a solar control coating can be deposited on the inner surface of the outer tinted glass sheet (#2 surface of the IG unit) to provide solar control properties.
  • An example of one suitable solar control coating is sold by PPG Industries, Inc. under the registered trademark Solarban® 60.
  • the Solarban® 60 coating which includes two infrared-reflecting films of silver, is discussed in U.S. Pat. No. 5,821,001.
  • tinted glass is generally not made as often as clear glass and, therefore, may not be as readily available for coating if an architect desires a particular color for an outer pane of an IG unit in a short period of time.
  • tinted glass can develop surface deterioration or corrosion during storage. Such corrosion may not be apparent until after the tinted glass is coated and can make the coating appear mottled, stained, or otherwise unacceptable.
  • U.S. Pat. No. 5,059,458 discloses a double glazed IG unit having an outer tinted glass sheet and an inner clear glass sheet having a silver layer on the outer surface of the clear glass sheet.
  • this approach also has some drawbacks. For example, using a conventional solar control coating on the #3 surface of an IG unit (the outer surface of the inner glass sheet of a two pane IG unit) provides different solar-control performance of the overall IG unit than having the coating on the #2 surface of the IG unit (all other factors remaining the same). Specifically, putting the solar control coating on the #3 surface rather than the #2 surface results in a relative increase in the shading coefficient and a relative increase in the solar heat gain coefficient.
  • a conventional Solarban® 60 coating on the #2 surface can result in a luminous transmittance of 60%, a luminous exterior reflectance of 9% to 10%, a shading coefficient (ASHRAE summer conditions) of 0.35 to 0.36, and a solar heat gain coefficient (ASHRAE summer conditions) of 0.30 to 0.31.
  • Switching the Solarban® 60 coating to the #3 surface changes the IG unit performance to a luminous transmittance of 60%, a luminous exterior reflectance of 11%, a shading coefficient (ASHRAE summer conditions) of 0.41, and a solar heat gain coefficient (ASHRAE summer conditions) of 0.36.
  • One embodiment of the present invention is a coating on clear glass which would be glazed in the inboard position of a double-glazed IG unit with the coating on the #3 surface such that, when combined with an uncoated tinted or clear outboard light (pane) in the IG unit, the IG unit has aesthetics and thermal management performance that are similar if not identical to IG units fabricated using a conventional solar control coating on the #2 surface of a clear or tinted glass sheet, respectively.
  • the invention is not limited thereto. More particularly and not limiting to the invention, the coated clear glass substrates of the present invention can be used as an outboard light of an IG unit (i.e. with the thermal management coating of the invention in the #2 surface orientation) if the resultant aesthetics and thermal-management performance of such an IG unit configuration are acceptable for the particular use.
  • a coated article for use in an IG unit comprises a substrate and a coating formed over at least a portion of the substrate.
  • the coating can comprise a first separation layer comprising at least one first dielectric layer; a first infrared reflective layer deposited over the first separation layer; a second separation layer comprising at least one dielectric layer deposited over the first infrared reflective layer; a second infrared reflective layer deposited over the second separation layer; a third separation layer comprising at least one dielectric layer deposited over the second infrared reflective layer; and a third infrared reflective layer deposited over the third separation.
  • the coating can be positioned on the #2 or #3 surface of the IG unit after being mounted.
  • Another coated article for use in an IG unit can comprise a substrate and a coating formed over at least a portion of the substrate.
  • the coating can comprise a first separation layer comprising at least one dielectric layer; a first infrared reflective layer formed over the first separation layer; a second separation layer comprising at least one dielectric layer formed over the first infrared reflective layer; and a second infrared reflective layer formed over the second separation layer.
  • the coating can be positioned on the #2 or #3 surface of the IG unit after being mounted.
  • the coating can provide a reference solar heat gain coefficient of less than or equal to 0.35.
  • An IG unit comprises a first pane defining a #1 and a #2 surface, at least one second pane defining a #3 and a #4 surface, and a coating formed over at least a portion of the #2 or #3 surface.
  • the coating can comprise a first separation layer comprising at least one first dielectric layer; a first infrared reflective layer deposited over the first separation layer; a second separation layer comprising at least one dielectric layer deposited over the first infrared reflective layer; a second infrared reflective layer deposited over the second separation layer; a third separation layer comprising at least one dielectric layer deposited over the second infrared reflective layer; and a third infrared reflective layer deposited over the third separation layer.
  • Another IG unit comprises a first pane defining a #1 and a #2 surface, at least one second pane defining a #3 and a #4 surface, and a coating formed over at least a portion of the #2 or #3 surface.
  • the coating can comprise a first separation layer comprising at least one first dielectric layer; a first infrared reflective layer deposited over the first separation layer; a second separation layer comprising at least one dielectric layer deposited over the first infrared reflective layer; and a second infrared reflective layer deposited over the second separation layer.
  • the coating can provide a reference solar heat gain coefficient of less than or equal to 0.35.
  • each numerical value should at least be construed in light of the number of reported significant digits and by applying ordinary rounding techniques.
  • all ranges disclosed herein are to be understood to encompass the beginning and ending range values and any and all subranges subsumed therein.
  • a stated range of “1 to 10” should be considered to include any and all subranges between (and inclusive of) the minimum value of 1 and the maximum value of 10; that is, all subranges beginning with a minimum value of 1 or more and ending with a maximum value of 10 or less, e.g., 5.5 to 10.
  • solar control coating refers to a coating that affects the solar properties of the coated article, such as but not limited to shading coefficient and/or emissivity and/or the amount of solar radiation reflected by and/or absorbed by and/or transmitted through the coated article, e.g., infrared or ultraviolet absorption or reflection.
  • a solar control coating can block, absorb, or filter selected portions of the solar spectrum, such as but not limited to the visible spectrum.
  • the coated article 10 includes a substrate 12 having a coating 14 .
  • the substrate 12 can be of any desired material having any desired characteristics, such as opaque, translucent, or transparent to visible light.
  • transparent is meant having visible light transmittance through the substrate of greater than 0% up to 100%.
  • the substrate can be translucent or opaque.
  • translucent is meant allowing electromagnetic energy (e.g., visible light) to pass through the substrate but diffusing this energy such that objects on the side of the substrate opposite to the viewer are not clearly visible.
  • opaque is meant having a visible light transmittance of 0%.
  • suitable substrates include, but are not limited to, plastic substrates (such as acrylic polymers, such as polyacrylates; polyalkylmethacrylates, such as polymethylmethacrylates, polyethylmethacrylates, polypropylmethacrylates, and the like; polyurethanes; polycarbonates; polyalkylterephthalates, such as polyethyleneterephthalate (PET), polypropyleneterephthalates, polybutyleneterephthalates, and the like; polysiloxane containing polymers; or copolymers of any monomers for preparing these, or any mixtures thereof); metal substrates, such as but not limited to galvanized steel, stainless steel, and aluminum; ceramic substrates; tile substrates; glass substrates; or mixtures or combinations of any of the above.
  • plastic substrates such as acrylic polymers, such as polyacrylates; polyalkylmethacrylates, such as polymethylmethacrylates, polyethylmethacrylates, polypropylmethacrylates, and the like;
  • the substrate can be conventional untinted soda-lime-silica-glass, i.e., “clear glass”, or can be tinted or otherwise colored glass, borosilicate glass, leaded glass, tempered, untempered, annealed, or heat-strengthened glass.
  • the glass may be of any type, such as conventional float glass or flat glass, and may be of any composition having any optical properties, e.g., any value of visible radiation transmission, ultraviolet radiation transmission, infrared radiation transmission, and/or total solar energy transmission. Types of glass suitable for the practice of the invention are described in, but are not to be considered as limited to, U.S. Pat. Nos.
  • the exemplary coating 14 can be a multilayer coating stack.
  • the terms “coating stack” or “coating” can include one or more layers and a “layer” can include one or more films.
  • the illustrated exemplary coating 14 includes three infrared reflective layers 16 , 18 and 20 .
  • the layer 16 is referred to as the first infrared reflective layer; the layer 18 is referred to as the second infrared reflective layer, and the layer 20 is referred to as the third (optional) infrared reflective layer.
  • the illustrated coating 14 further includes separation layers 22 , 24 , 26 and 28 .
  • the separation layer 22 or first separation layer is between the substrate 12 and the first infrared reflective layer 16 ; the separation layer 24 or second separation layer is between the first infrared reflective layer 16 and the second infrared reflective layer 18 ; the separation layer 26 or third separation layer is between the second infrared reflective layer 18 and the third infrared reflective layer 20 , and the fourth separation layer or outermost separation layer) 28 is between the third infrared reflective layer 20 and the environment.
  • the invention contemplates more than three infrared reflective layers and more than four separation layers. Further, as will be noted below, the invention also contemplates less than three infrared reflective layers and less than four separation layers.
  • the first separation layer 22 can include one or more dielectric (e.g., antireflective) layers or films and optionally one or more non-dielectric layers or films.
  • a “non-dielectric layer or film” is a material that has mobile carriers of electric charge, such as metals, semiconductors, semimetals, alloys, mixtures, or combinations thereof.
  • the dielectric layers or films can be any of the types known in the art, such as but not limited to, oxides, nitrides, and/or oxynitrides, such as but not limited to zinc oxide, zinc stannate, silicon nitride, silicon-aluminum nitride, ceramics, titanium dioxide, and/or of the types disclosed in U.S.
  • the non-dielectric layers or film(s) of the first separation layer (or subsequent separation layers) can be any of the types known in the art, such as but not limited to, titanium, copper, stainless steel, and can function (1) to protect the underlying films from damage and/or degradation during heat-treatment of the coated glass for those products designed and/or intended to be subjected to high-temperature processing after being coated, and/or (2) to enhance mechanical and/or chemical durability of the coated article's thin film optical stack, and/or (3) to contribute to and allow some control over the aesthetics and/or thermal-management performance of the coated article, e.g., by absorption. Any or all of the non-dielectric films can exhibit optical absorption in any region of the electromagnetic spectrum.
  • non-dielectric films of the separation layers over, under, and/or between the dielectric films(s).
  • non-dielectric films that can be used for optical absorption can be deposited on the substrate, between the dielectric films, or over the last deposited dielectric film of the first separation layer.
  • the first separation layer 22 can be a substantially single phase layer or film, such as a metal alloy oxide layer, e.g., zinc stannate or a mixture of phases composed of zinc and tin oxides, or can be composed of a plurality of layers or films, e.g., metal oxide films, such as those disclosed in U.S. Pat. Nos. 5,821,001; 4,898,789; and 4,898,790.
  • a metal alloy oxide layer e.g., zinc stannate or a mixture of phases composed of zinc and tin oxides
  • metal oxide films such as those disclosed in U.S. Pat. Nos. 5,821,001; 4,898,789; and 4,898,790.
  • the first separation layer 22 comprises a multi-layer structure having a first metal oxide or alloy oxide layer or film (first dielectric layer) deposited over at least a portion of a major surface of the substrate 12 and a second metal oxide layer or film (second dielectric layer) deposited over at least a portion of the first metal alloy oxide film.
  • the first metal alloy oxide layer can be an oxide mixture or alloy oxide of zinc and tin.
  • the zinc/tin alloy can comprise zinc and tin in proportions of 10 wt. % to 90 wt. % zinc and 90 wt. % to 10 wt. % tin.
  • One suitable metal alloy oxide for use in the invention is zinc stannate.
  • the second metal oxide layer can comprise a zinc containing layer, such as zinc oxide.
  • the first metal alloy oxide layer can comprise an oxide of zinc and tin, e.g., zinc stannate, and can have a thickness in the range of 100 Angstroms ( ⁇ ) to 500 ⁇ , such as 150 ⁇ to 400 ⁇ , e.g., 200 ⁇ to 350 ⁇ , e.g., 250 ⁇ to 350 ⁇ .
  • the second metal oxide layer can comprise zinc oxide and can have a thickness in the range of 50 ⁇ to 200 ⁇ , such as 75 ⁇ to 150 ⁇ , e.g., such as 100 ⁇ to 150 ⁇ , such as 130 ⁇ to 160 ⁇ .
  • the total physical thickness of the dielectric film(s) of the first separation layer 22 can be in the range of 50 ⁇ to 700 ⁇ , such as in the range of 100 ⁇ to 600 ⁇ , such as in the range of 200 ⁇ to 575 ⁇ , such as 293 ⁇ to 494 ⁇ .
  • the total physical thickness of the non-dielectric film(s) can be in the range of 0 ⁇ to 500 ⁇ , such as 0 ⁇ to 400 ⁇ , such as 0 ⁇ to 300 ⁇ , such as 0 ⁇ to 50 ⁇ , such as 0 ⁇ to 30 ⁇ .
  • the first infrared (IR)-reflective layer 16 can be deposited over the first separation layer 22 and can have a high reflectivity in the infrared (solar-infrared and/or thermal-infrared) portion of the electromagnetic spectrum, e.g., but not limiting to the invention, greater than 50%.
  • the first infrared-reflective layer 16 can include one or more films of infrared-reflective materials, such as but not limited to, gold, copper, silver, or mixtures, alloys, or combinations thereof.
  • the first infrared reflective layer 16 comprises silver. The films can exhibit some reflectivity in the visible light portion of the electromagnetic spectrum.
  • the first IR-reflective layer 16 (as well as the other IR-reflective layers) can (1) provide rejection of solar-infrared radiation and/or visible light to help control solar heat gain through the window and/or to control glare due to transmitted visible light; (2) when the infrared-reflective layer exhibits appreciable reflectivity in the thermal infrared portion of the electromagnetic spectrum e.g., but not limiting thereto greater than 50%, to impart some low-emissivity characteristics, e.g., but not limiting to the invention, an emissivity less than 0.25 to the coated article to inhibit radiative heat transfer across and/or through the IG unit, and/or (3) allow some control over the aesthetics of the coated article. Furthermore, any or all of the films of the infrared-reflective layers can exhibit optical absorption in any region of the electromagnetic spectrum.
  • the thickness of the first infrared-reflective layer can be in the range of 5 ⁇ to 200 ⁇ , such as 10 ⁇ to 200 ⁇ , such as 50 ⁇ to 200 ⁇ , such as 75 ⁇ to 175 ⁇ , such as 75 ⁇ to 150 ⁇ , such as 93 ⁇ to 109 ⁇ .
  • the first infrared-reflective layer includes silver and has a thickness in the range of 100 ⁇ to 150 ⁇ , such as 110 ⁇ to 140 ⁇ , such as 120 ⁇ to 130 ⁇ .
  • the second separation layer 24 can be provided. Otherwise, the outermost separation layer 28 discussed in detail below is applied over the first infra-red reflective layer 16 .
  • the second separation layer 24 can be deposited over the first infrared-reflective layer 16 and can include one or more dielectric layers or films and/or one or more non-dielectric layers or films.
  • the dielectric layers or films and the non-dielectric layers or films of the second separation layer can be similar to or different than the material and number of the dielectric films and/or non-dielectric films of the first separation layer 22 .
  • a non-dielectric film (“first non-dielectric film(s) of the second separation layer”) can be deposited over the first IR reflective film 16 .
  • the first non-dielectric film can be a metal, such as but not limited to, titanium and is often referred to in the art as a “primer film” or “barrier film”.
  • the first non-dielectric film(s) of the second separation layer can (1) protect the underlying infrared-reflective layer from degradation (e.g. oxidation and/or plasma-induced damage) during: (A) deposition of overlying films, e.g., dielectric films of the second separation layer 24 ; and/or (B) heat-treatment of the coated article for those products that are designed/intended to be subjected to high-temperature processing after being coated; and/or (2) to contribute to and allow some control of the aesthetics and/or thermal-management performance of the coated article.
  • degradation e.g. oxidation and/or plasma-induced damage
  • the first non-dielectric film(s) of the second separation layer 24 can exhibit optical absorption in any region of the electromagnetic spectrum, if desired.
  • Types of non-dielectric films that can be used in the practice of the invention include, but one not limited to, those disclosed in PCT/US00/15576.
  • One or more dielectric layers or films can be deposited over the first non-dielectric film(s) of the second separation layer 24 , if present, otherwise over the first infrared-reflective layer 16 .
  • the dielectric films(s) of the second separation layer 24 can include one, two, or more films with similar refractive indices in a similar fashion as described for the dielectric films of the first separation layer 22 .
  • any or all of the dielectric films of the second separation layer 24 can exhibit optical absorption in any region of the electromagnetic spectrum. It is also believed that the dielectric film(s) of the second separation layer 24 provides some protection of the underlying layers and/or films from mechanical damage and/or chemical/environmental attack, degradation, or corrosion.
  • the second separation layer 24 can include other non-dielectric layers or film(s) (“other non-dielectric film(s) of the second separation layer”) over, under or between the dielectric film(s) of the second separation layer 24 .
  • the other non-dielectric film(s) of the second separation layer 24 can be the same as and/or different material and number than the non-dielectric film(s) of the first separation layer 22 .
  • the relative proportions of the component films of the second separation layer 24 can be varied in order to optimize thermal-management performance, aesthetics, and/or chemical/mechanical durability of the coated article.
  • the first non-dielectric film(s) of the second separation layer can have a thickness in the range of 0 ⁇ to 100 ⁇ , such as 5 ⁇ to 75 ⁇ , such as 5 ⁇ to 50 ⁇ , such as 5 ⁇ to 30 ⁇ , such as 15 ⁇ to 25 ⁇ .
  • the first non-dielectric film can have a thickness in the range of 5 ⁇ to 15 ⁇ , such as 10 ⁇ to 25 ⁇ .
  • the other non-dielectric film(s) of the second separation layer 24 can have a thickness in the range of 0 ⁇ to 500 ⁇ , such as 0 ⁇ to 400 ⁇ , such as 0 ⁇ to 300 ⁇ .
  • the dielectric layers or film(s) of the second separation layer 24 can be in the range of 600 ⁇ to 1000 ⁇ , such as in the range of 700 ⁇ to 900 ⁇ , such as in the range of 725 ⁇ to 875 ⁇ , such as 739 ⁇ to 852 ⁇ .
  • the second separation layer 24 can have a thickness in the range of 600 ⁇ to 1500 ⁇ , such as in the range of 705 ⁇ to 1375 ⁇ , such as in the range of 730 ⁇ to 1250 ⁇ , such as 730 ⁇ to 1230 ⁇ .
  • the second separation layer 24 can be a multilayer structure having one or more metal oxide or metal alloy oxide layers or films, such as those described above with respect to the first separation layer 22 .
  • the second separation layer 24 has a first metal oxide layer or film, e.g., a zinc oxide layer, deposited over the first primer film (first non-dielectric layer).
  • a second metal alloy oxide layer or film e.g., a zinc stannate layer, can be deposited over the first zinc oxide layer.
  • a third metal oxide layer e.g., another zinc oxide layer, can be deposited over the zinc stannate layer to form a multi-film second separation layer 24 .
  • the first and third metal oxide layers of the second separation layer 24 can have a thickness in the range of 50 ⁇ to 200 ⁇ , e.g., 75 ⁇ to 150 ⁇ , e.g., 100 ⁇ to 120 ⁇ , e.g., 110 ⁇ to 120 ⁇ .
  • the second metal alloy oxide layer can have a thickness in the range of 100 ⁇ to 500 ⁇ , e.g., 200 ⁇ to 500 ⁇ , e.g., 300 ⁇ to 500 ⁇ , e.g., 400 ⁇ to 500 ⁇ , e.g., 450 ⁇ to 500 ⁇ .
  • the second infrared-reflective (IR) layer 18 can be deposited over the second separation layer 24 and can include one or more films of infrared-reflective materials of the type referred to above for the first infrared-reflective layer 16 .
  • the materials of the second infrared reflective layer can be the same or different than the materials of the first infrared reflective layer.
  • the thickness of the second infrared-reflecting layer can be in the range of 50 ⁇ to 250 ⁇ , such as 75 ⁇ to 225 ⁇ , such as 75 ⁇ to 200 ⁇ , such as 120 ⁇ to 150 ⁇ , such as 130 ⁇ to 150 ⁇ , such as 114 ⁇ to 197 ⁇ .
  • the third separation layer 26 is provided; otherwise the outermost separation layer 28 discussed in detail below can be applied over the second infrared-reflecting layer 18 .
  • the third separation layer 26 can be deposited over the second infrared-reflective layer 18 and can include one or more dielectric layers or films and/or one or more non-dielectric layers or films, such as those described above.
  • the dielectric films and the non-dielectric films of the third separation layer 26 can be similar to or different than the material and number of the dielectric films and/or non-dielectric films of the first and/or second separation layers 22 , 24 .
  • the first non-dielectric film(s) of the third separation layer 26 can have a thickness in the range of 0 ⁇ to 100 ⁇ , such as 5 ⁇ to 75 ⁇ , such as 5 ⁇ to 50 ⁇ , such as 5 ⁇ to 30 ⁇ , such as 15 ⁇ to 25 ⁇ .
  • the first non-dielectric film can have a thickness in the range of 5 ⁇ to 15 ⁇ , such as 10 ⁇ to 25 ⁇ .
  • the other non-dielectric film(s) of the third separation layer 26 can have a thickness in the range of 0 ⁇ to 500 ⁇ , such as 0 ⁇ to 400 ⁇ , such as 0 ⁇ to 300 ⁇ .
  • One or more dielectric layers or films can be deposited over the first non-dielectric film(s) of the third separation layer 26 , if present, otherwise over the second infrared-reflective layer 18 .
  • the relative proportions of the component films of the third separation layer may be varied in order to optimize thermal-management performance, aesthetics, and/or chemical/mechanical durability of the coated article.
  • the dielectric film(s) of the third separation layer 26 can be in the range of 600 ⁇ to 1000 ⁇ , such as 625 ⁇ to 900 ⁇ , such as 650 ⁇ to 875 ⁇ , such as 729 ⁇ to 764 ⁇ .
  • the third separation layer 26 can have a thickness in the range of 600 ⁇ to 1600 ⁇ , such as 630 ⁇ to 1375 ⁇ , such as 755 ⁇ to 1250 ⁇ , such as 730 ⁇ to 1230 ⁇ .
  • the third separation 26 can be a multi-layer structure similar to the second separation layer.
  • the third separation layer 26 can include a first metal oxide layer, e.g., a zinc oxide layer, a second metal alloy oxide layer, e.g., a zinc stannate layer over the first zinc oxide layer, and a third metal oxide layer, e.g., another zinc oxide layer, deposited over the zinc stannate layer.
  • the first and third metal oxide layers can have thicknesses in the range of 50 ⁇ to 200 ⁇ , such as 75 ⁇ to 150 ⁇ , e.g., 100 ⁇ to 120 ⁇ , e.g., 100 ⁇ .
  • the metal alloy oxide layer can have a thickness in the range of 100 ⁇ to 1,000 ⁇ , e.g., 200 ⁇ to 800 ⁇ , e.g., 300 ⁇ to 600 ⁇ , e.g., 500 ⁇ .
  • the third infrared-reflective (IR) layer 20 can be deposited over the third separation layer 26 and can include one or more films of infrared-reflective materials of the type referred to in the discussion regarding the first and/or second infrared-reflective layers 16 , 18 , respectively.
  • the material(s) of the third infrared reflective layer 20 can be the same or different than the material(s) of the first and/or second infrared reflective layers 16 , 18 .
  • the thickness of the third infrared-reflecting layer 20 can be in the range of 50 ⁇ to 250 ⁇ , such as 75 ⁇ to 225 ⁇ , such as 75 ⁇ to 200 ⁇ , such as 140 to 180 ⁇ , such as 150 to 170 ⁇ , such as 160 to 170 ⁇ , such as 138 ⁇ to 181 ⁇ .
  • an additional infrared reflective layer e.g. a fourth infrared-reflective layer (not shown) similar to the first, second and/or third infrared-reflecting layers 16 , 18 and 20 , respectively
  • an additional separation layer (not shown) similar to the second and/or third separation layers 24 and 26 , respectively, can be provided.
  • the fourth or outermost separation layer 28 discussed in detail below can be applied over the third infrared-reflecting layer 16 .
  • the outermost separation layer 28 can be deposited over the third infrared-reflective layer 20 and can include one or more dielectric layers or films and/or one or more non-dielectric layers or films.
  • the dielectric films and the non-dielectric films of the outermost separation layer can be similar to or different than the materials and number of the dielectric films and/or non-dielectric films of the first, second, and/or third separation layers 22 , 24 and 26 , respectively.
  • a first primer film or first non-dielectric film(s) of the outermost separation layer such as titanium, can be deposited over the underlying infrared reflective layer, e.g. the third infrared-reflective layer 20 .
  • the thickness of the first non-dielectric film(s) of the outermost separation layer can be in the range of 0 ⁇ to 100 ⁇ , such as 5 ⁇ to 75 ⁇ , such as 5 ⁇ to 50 ⁇ , such as 5 ⁇ to 30 ⁇ , such as 5 ⁇ to 15 ⁇ , such as 10 ⁇ to 20 ⁇ , such as 15 ⁇ to 25 ⁇ .
  • the other non-dielectric film(s) of the outermost separation layer 28 can have a thickness in the range of 0 ⁇ to 500 ⁇ , such as 0 ⁇ to 400 ⁇ , such as 0 ⁇ to 300 ⁇ .
  • One or more dielectric layers or films and one or more protective films can be deposited over the first non-dielectric film(s) of the outermost separation layer 28 , if present, otherwise over the third infrared-reflective layer 20 .
  • the relative proportions of the component films of the outermost separation layer 28 can be varied in order to optimize thermal-management performance, aesthetics, and/or chemical/mechanical durability of the coated article.
  • the outermost separation layer 28 can have a thickness in the range of 170 ⁇ to 600 ⁇ , such as in the range of 205 ⁇ to 500 ⁇ , such as in the range of 235 ⁇ to 430 ⁇ .
  • the thickness of any temporary overcoat (described below) is not included because it is removed before the product is used.
  • the dielectric film(s) of the outermost separation layer can be in the range of 100 ⁇ to 400 ⁇ , such as in the range of 150 ⁇ to 350 ⁇ , such as in the range of 175 ⁇ to 325 ⁇ , such as 206 ⁇ to 310 ⁇ .
  • the outermost separation layer 28 excluding the protective film(s), can have a thickness in the range of 100 ⁇ to 1000 ⁇ , such as in the range of 155 ⁇ to 725 ⁇ , such as in the range of 180 ⁇ to 675 ⁇ , such as 185 ⁇ to 705 ⁇ .
  • the outermost separation layer 28 can be comprised of one or more metal oxide or metal alloy oxide containing layers or films such as those discussed above with respect to the first, second, or separation layers.
  • the outermost separation layer 28 is a multi-film layer having a first metal oxide layer or film, e.g., a zinc oxide layer or film, deposited over the third primer film and a second metal alloy oxide layer or film, e.g., a zinc stannate layer or film, deposited over the zinc oxide layer or film.
  • the metal oxide layer or film can have a thickness in the range of 25 ⁇ to 200 ⁇ , such as 50 ⁇ to 150 ⁇ , such as 100 ⁇ .
  • the metal alloy oxide film can have a thickness in the range of 25 ⁇ to 500 ⁇ , e.g., 50 ⁇ to 250 ⁇ , e.g., 100 ⁇ to 210 ⁇ .
  • a permanent protective overcoat can be deposited over the outermost separation layer 28 to provide protection against mechanical and chemical attack.
  • the protective overcoat can be a metal oxide, such as titanium dioxide or zirconium oxide, having a thickness in the range of about 10 ⁇ to 100 ⁇ , e.g., 20 ⁇ to 60 ⁇ , e.g., 30 ⁇ to 40 ⁇ , such as 30 ⁇ to 46 ⁇ .
  • the inclusion of protective films as components of the outermost separation layer 28 is optional.
  • the protective film(s) can protect the underlying layers from mechanical damage and/or chemical attack due to environmental exposure during storage, shipment, and processing of the coated article.
  • the protective film(s) can also contribute to the aesthetics and/or thermal-management performance of the coated article.
  • the protective film(s) can be one, two, or more films with similar refractive indices.
  • any or all of the protective films can exhibit optical absorption in any region of the electromagnetic spectrum, if desired.
  • the protective films can be of the durable type, which provide mechanical and chemical protection and remain on the outermost surface of the coating. These types of protective films are disclosed in U.S. Pat. No. 4,786,563.
  • the protective films can be of the less durable type, e.g. zinc oxide.
  • a temporary protective film such as commercially available fro PPG Industries, Inc. and identified by the trademark “TPO” and described in U.S. Patent Application Nos. 60/142,090 and 09/567,934 can be deposited over the permanent protective overcoat.
  • the function of the temporary protective film is to provide additional protection of the underlying layers from mechanical damage during packaging, shipment, and downstream processing (e.g. unpacking, unloading, cutting, seaming/edging, edge deletion of the MSVD coating, and/or washing) of the coated article.
  • the temporary film can be applied using an aqueous wet-chemical process after all MSVD coating layers have been deposited on the substrate and the MSVD-coated article has exited the MSVD coating chamber(s).
  • the temporary film can serve as a sacrificial protective film and can be removed from the MSVD-coated article by contact of the article's coated surface with water (such as in the washing step normally employed in flat glass fabrication processes) prior to installation of the coated article in an IG unit or other product.
  • water such as in the washing step normally employed in flat glass fabrication processes
  • the aesthetic and thermal-management performance data pertaining to the present invention is made without the presence of the temporary film either because the temporary film has not been applied, and/or because the temporary film has already been removed. Further in the discussion of the thickness of the protective film(s) of the outermost layer, the temporary film is excluded for the reasons discussed.
  • an exemplary double glazed unit 30 having the coated article 10 (inner pane) incorporating features of the invention spaced from a sheet 32 (outer pane) by a spacer frame 34 .
  • the invention is not limited by the construction and method of fabricating the IG unit.
  • the unit can be one or more of the types disclosed in U.S. Pat. No. 5,655,282.
  • the sheet 32 is the outer sheet and the coated article 10 is the inner sheet.
  • Surface 40 of the sheet 32 is the outer surface of the outer sheet or the #1 surface.
  • Surface 42 of the sheet 32 is the inner surface of the outer sheet 32 or the #2 surface.
  • the surface 44 of the sheet 12 is the inner surface of the inner sheet or the #4 surface.
  • the opposite surface of the sheet 12 is the outer surface of the inner sheet 12 and has the coating 14 and is the #3 surface.
  • the invention is not limited to the manner the IG unit is mounted in a sash, wall fenestration or any opening of a structure. Further, the glass sheets can be mounted in a sash or window frame, e.g., as disclosed in PCT/US99/15698.
  • the coating of the invention can provide reference IG unit values as follows.
  • the “reference IG unit values” or “reference values” are those values calculated from the measured spectral properties of the coating for a “reference IG unit” using WINDOW 4.1 fenestration software available from Lawrence Berkeley National Laboratory.
  • the reference IG unit is defined as a dual pane unit having an outer pane of 6 mm SOLEXIA® glass commercially available from PPG Industries, Inc. and an inner pane of clear glass commercially available from PPG Industries, Inc separated by a distance of 0.5 inch (1.27 cm) by an air gap and with the coating on the #3 surface.
  • SOLEXIA® glass is a subset of tinted glasses and typically has the following properties for a nominal 6 mm monolithic piece: a luminous transmittance of 75% to 80%, a luminous reflectance of 7% to 8% and a total solar absorption of 46% to 48%.
  • the clear glass typically has a luminous transmittance above 85%, a luminous reflectance of 7% to 9%, and a total solar absorption of 15% to 16%.
  • a clear monolithic piece of glass having a thickness of about 6 mm has the following properties: a luminous transmittance of above 85%, a luminous reflectance of 7% to 9%, and a total solar absorption of 15% to 16%.
  • the SOLEXIA® glass referred to in the discussion of the invention and used in the Examples for a monolithic piece in the range of 5.5 mm to 6 mm had the following properties: a nominal luminous transmittance of 76.8%, a nominal luminous reflectance of 7.5%, a nominal total solar absorption of 47.2%, a transmitted color of L*T of 90.4, a*T of ⁇ 7.40, b*T of 1.16; and reflected color of L*R of 33.1, a*R of ⁇ 2.70, b*R of ⁇ 0.50.
  • the clear glass referred to in the discussion of the invention and used in the Examples for a monolithic piece in the range of 5.5 to 6 mm had the following properties; a nominal luminous transmittance of 88.5%, a nominal luminous reflectance of 8.5%, a nominal total solar absorption of 15.8%, transmitted color of L*T of 95.4, a*T of ⁇ 1.80, b*T of 0.12; and reflected color of L*R of 35.0, a*R of ⁇ 0.80, b*R of ⁇ 1.00.
  • the color values herein are those determinable by the CIELAB 1976 (L*, a*, b*) system, Illuminant D65, 10 degree observer.
  • Quoted solar properties correspond to the Lawrence Berkeley National Laboratory's WINDOW 4.1 wavelength range and integration (trapezoidal) scheme.
  • the shading coefficient (SC) and solar heat gain coefficient (SHGC) for a reference IG unit were calculated under ASHRAE standard assumed summer conditions (exterior environment temperature of 89° F., interior environment temperature of 75° F., wind speed of 7.50 miles/hour (windward directed), solar load of 248.2 Btu/hour-ft 2 , sky temperature of 89° F., sky emissivity of 1.00).
  • LSG is an abbreviation for “Light-to-Solar Gain” ratio and is equal to the ratio of the luminous transmittance (expressed as a decimal) to the solar heat gain coefficient (SHGC).
  • SHGC solar heat gain coefficient
  • the coating 14 can provide reference IG unit values (i.e., calculated values for the coating in a reference IG unit) as follows: reference visible light transmittance in the range of 4-0% to 70%, such as 50% to 65%, such as 50% to 60%.
  • the coating can provide a reference transmitted color having a transmitted a* (a*T) in the range of ⁇ 5 to ⁇ 12, such as ⁇ 7 to ⁇ 11, such as ⁇ 8 to ⁇ 11, such as ⁇ 9 to ⁇ 10.
  • the coating can provide a transmitted b* (b*T) in the range of 0 to 5, such as 1 to 5, such as 2 to 5, such as 2.5 to 5, such as 3 to 5, such as 4 to 5.
  • the coating can provide an exterior visible light reflectance (Rext vis) in the range of greater than 0% to less than 20%, such as 5% to 15%, such as 6% to 11%, such as 8% to 11%, such as 8% to 10%.
  • the coating 14 can provide a reference reflected exterior a* (Rexta*) in the range of ⁇ 2 to ⁇ 8, such as ⁇ 2 to ⁇ 7, such as ⁇ 3 to ⁇ 6, such as ⁇ 3 to ⁇ 5.
  • the coating can provide a reference reflected exterior b* (Rextb*) in the range of 0 to ⁇ 5, such as 0 to ⁇ 4, such as 0 to ⁇ 3, such as ⁇ 1 to ⁇ 3.
  • the coating can provide a reference shading coefficient in the range of 0.25 to 0.45, such as 0.3 to 0.4, such as 0.35 to 0.37, such as less than or equal to 0.41, such as less than or equal to 0.37, such as less than or equal to 0.36, such as less than or equal to 0.35, such as less than or equal to 0.33, such as less than or equal to 0.32, such as less than or equal to 0.31.
  • the coating can provide a reference solar heat gain coefficient in the range of 0.2 to 0.4, such as 0.3 to 0.4, such as 0.3 to 0.35, such as 0.3 to 0.32, such as than or equal to 0.36, such as less than or equal to 0.35, such as less than or equal to 0.33, such as less than or equal to 0.32, such as less than or equal to 0.31.
  • the coatings were deposited using an in-line magnetron sputter deposition system Model No. ILS 1600 sold by Airco Temescal on a 6 mm clear glass sheet.
  • Quoted thermal management performance values correspond to center-of-glass (COG) values only; edge effects due to the spacer and frame are not included.
  • the luminous transmittance and the luminous exterior reflectance were measured using a Lamda 9 Spectrophotometer and were determined using the WINDOW 4.1 fenestration simulation software, available from Lawrence Berkeley National Laboratory (LBNL).
  • Emissivity was determined by measurements using an Emissivity Mattson Galaxy 5030 FTIR infrared spectrophotometer in accordance with ASTM E-1585-93 with intervals for infrared integration over wavelength range of 5-40 microns. Color data reference the CIELAB 1976 (L*,a*,b*) system, Illuminant D65, 10 degree observer. Quoted solar properties correspond to the Lawrence Berkeley National Laboratory's WINDOW 4.1 wavelength range and integration (trapezoidal) scheme. R-Sheet is electrical sheet resistance of the sample's coated surface as measured with a four-point probe.
  • the shading coefficient (SC) and solar heat gain coefficient (SHGC) of the IG unit were calculated under ASHRAE standard assumed summer conditions (exterior environment temperature of 89° F., interior environment temperature of 75° F., wind speed of 7.50 miles/hour (windward directed), solar load of 248.2 Btu/hour-ft 2 , sky temperature of 89° F., sky emissivity of 1.00). Unless indicated otherwise, the coated glass sheet had a nominal thickness of 6 millimeters (mm). Because the lateral dimensions do not have any bearing on the COG properties, they are not discussed regarding COG properties.
  • the “IG unit performance” data were calculated from the measured spectral properties of the coatings for a “reference IG unit” as described above using WINDOW 4.1 fenestration software available from Lawrence Berkeley National Laboratory.
  • Sample 1 included:
  • a first separation layer 22 having a dielectric film of an oxide of an alloy of 54% zinc and 46% tin (by weight) deposited on a clear glass substrate.
  • the dielectric film had physical thickness estimated to be about 341 ⁇ (34.1 nanometers, nm);
  • a first infrared-reflective layer 16 deposited on the first separation layer was a metallic silver (Ag) having a physical thickness of the silver layer estimated to be about 123 ⁇ (12.3 nm);
  • a second separation layer 24 included a primer film of metallic titanium (Ti) having a physical thickness estimated to be about 15 ⁇ (1.5 nm) deposited on the silver film of the first infrared-reflective layer 16 and a dielectric film of an oxide of an alloy of 54% zinc: 46% tin (by weight) having a physical thickness estimated to be about 808 ⁇ (80.8 nm) deposited on the primer film;
  • a second infrared-reflective layer 18 was metallic silver (Ag) having a thickness estimated to be about 172 ⁇ (17.2 nm) deposited on the dielectric film of the second separation layer;
  • An outermost separation layer 28 included a primer film of metallic titanium (Ti) having a physical thickness of about 15 ⁇ (1.5 nm) deposited on the second infrared-reflecting layer, a film of an oxide of an alloy of 54% zinc: 46% tin (by weight) having a physical thickness estimated to be about 244 ⁇ (24.4 nm), and protective overcoat film of an oxide of titanium (Ti) having a physical thickness of estimated to be about 30 ⁇ (3 nm) deposited on the dielectric film.
  • the coated monolithic sheet of sample 1 had the properties, among others, detailed in Table 3.
  • TABLE 3 Coated Surface Glass Surface Reflected Solar Performance Data Sample Transmitted Color Data Reflected Color Data Color Data TSET TSER1 TSER2 R sheet ID L* a* b* L* a* b* L* a* b* (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) Emissivity (ohms/sq) 1 86.44 ⁇ 2.41 4.40 45.45 ⁇ 12.73 ⁇ 4.67 44.39 ⁇ 11.77 ⁇ 12.40 30.55 53.45 31.84 0.035 1.9
  • Sample 2 included:
  • a first separation layer 22 having a dielectric film of an oxide of an alloy of 54% zinc: 46% tin (by weight) having a physical thickness estimated to be about 378 ⁇ (37.8 nm) deposited on a clear glass substrate;
  • a second separation layer 24 having a primer film of deposited metallic titanium (Ti) having a physical thickness estimated to be about 15 ⁇ (1.5 nm) deposited on the first infrared-reflecting layer, a dielectric film of an oxide of an alloy of 54% zinc: 46% tin (by weight) having a physical thickness of estimated to be about 739 ⁇ (73.9 nm) deposited on the primer film,
  • a third separation layer 26 having a primer film deposited as metallic titanium (Ti) having a physical thickness estimated to be about 15 ⁇ (1.5 nm) deposited on the second infrared-reflecting layer 18 , and a dielectric film of an oxide of an alloy of 54% zinc: 46% tin (by weight) having a physical thickness estimated to be about 729 ⁇ (72.9 nm) deposited on the primer layer of the third separation layer 26 ;
  • An outermost separation layer 28 having a primer film deposited as metallic titanium (Ti) having a physical thickness estimated to be about 15 ⁇ (1.5 nm) deposited on the third infrared reflecting layer, a dielectric film of an oxide of an alloy of 54% zinc: 46% tin (by weight) having a physical thickness estimated to be about 262 ⁇ (26.2 nm) deposited on the primer layer, and a protective film of an oxide of titanium (Ti) having a physical thickness estimated to be about 30 ⁇ (3 nm) deposited on the dielectric film of the outermost separation layer 28 ;
  • Sample 2 had the properties detailed in following Tables 5 and 6. TABLE 5 Coated Surface Glass Surface Reflected Solar Performance Data Sample Transmitted Color Data Reflected Color Data Color Data TSET TSER1 TSER2 R sheet ID L* a* b* L* a* b* L* a* b* (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) Emissivity (ohms/sq) 2 84.49 ⁇ 2.29 8.15 49.83 ⁇ 14.85 ⁇ 10.77 48.16 ⁇ 16.09 ⁇ 19.34 25.64 60.65 37.34 0.031 1.8
  • Sample 3 included:
  • a first separation layer 22 having a dielectric film of an oxide of an alloy of 54% zinc: 46% tin (by weight) deposited on the glass substrate.
  • the dielectric film had physical thickness estimated to be about 336 ⁇ (33.6 nanometers, nm);
  • a first infrared-reflective layer 16 deposited on the first separation layer was a metallic silver (Ag) having a physical thickness of the silver layer estimated to be about 111 ⁇ (11.1 nm);
  • a second separation layer 24 having a primer film of metallic titanium (Ti) having a physical thickness estimated to be about 15 ⁇ (1.5 nm) deposited on the silver film of the first infrared-reflective layer 16 and a dielectric film of an oxide of an alloy of 54% zinc: 46% tin (by weight) having a physical thickness estimated to be about 842 ⁇ (84.2 nm) deposited on the primer film;
  • a second infrared-reflective layer 18 was metallic silver (Ag) having a thickness estimated to be about 161 ⁇ (16.1 nm) deposited on the dielectric film of the second separation layer;
  • An outermost separation layer 28 included a primer film of metallic titanium (Ti) having a physical thickness of about 15 ⁇ (1.5 nm) deposited on the second infrared-reflecting layer, a film of an oxide of an alloy of 54% zinc: 46% tin (by weight) having a physical thickness estimated to be about 245 ⁇ (24.5 nm), and protective film of an oxide of titanium (Ti) having a physical thickness of estimated to be about 30 ⁇ (3 nm) deposited on the dielectric film.
  • Ti metallic titanium
  • Sample 3 had properties as detailed in Tables 7 and 8. TABLE 7 Coated Surface Glass Surface Reflected Solar Performance Data Sample Transmitted Color Data Reflected Color Data Color Data TSET TSER1 TSER2 R sheet ID L* a* b* L* a* b* L* a* b* (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) Emissivity (ohms/sq) 3 85.85 ⁇ 2.63 1.03 42.76 ⁇ 12.80 1.40 41.50 ⁇ 15.49 ⁇ 7.00 29.24 54.18 29.60 0.033 2.26
  • a first separation layer 22 having a dielectric film of an oxide of an alloy of 54% zinc: 46% tin (by weight) deposited on the glass substrate.
  • the dielectric film had physical thickness estimated to be about 293 ⁇ (29.3 nanometers, nm);
  • a second separation layer 24 having a primer film of metallic titanium (Ti) having a physical thickness estimated to be about 15 ⁇ (1.5 nm) deposited on the silver film of the first infrared-reflective layer 16 and a dielectric film of an oxide of an alloy of 54% zinc: 46% tin (by weight) having a physical thickness estimated to be about 851 ⁇ (85.1 nm) deposited on the primer film;
  • An outermost separation layer 28 having a primer film of metallic titanium (Ti) having a physical thickness of about 15 ⁇ (1.5 nm) deposited on the second infrared-reflecting layer, a film of an oxide of an alloy of 54% zinc: 46% tin (by weight) having a physical thickness estimated to be about 245 ⁇ (24.5 nm), and protective overcoat film of an oxide of titanium (Ti) having a physical thickness of estimated to be about 30 ⁇ (3 nm) deposited on the dielectric film.
  • Sample 4 had properties detailed in Tables 9 and 10. TABLE 9 Coated Surface Glass Surface Reflected Solar Performance Data Sample Transmitted Color Data Reflected Color Data Color Data TSET TSER1 TSER2 R sheet ID L* a* b* L* a* b* L* a* b* (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) Emissivity (ohms/sq) 4 83.34 ⁇ 3.63 2.43 51.22 ⁇ 7.65 1.27 48.20 ⁇ 15.21 ⁇ 11.49 25.26 60.97 32.76 0.031 1.89
  • a first separation layer 22 having a dielectric film of an oxide of an alloy of 54% zinc: 46% tin (by weight) deposited on a 2.3 millimeter thick clear glass substrate having a thickness of 2.5 mm.
  • the dielectric film had physical thickness estimated to be about 319 ⁇ (31.9 nanometers, nm);
  • a first infrared-reflective layer 16 of a metallic silver (Ag) deposited on the first separation layer had a physical thickness estimated to be about 114 ⁇ (11.4 nm);
  • a second separation layer 24 having a primer film of metallic titanium (Ti) having a physical thickness estimated to be about 15 ⁇ (1.5 nm) deposited on the silver film of the first infrared-reflective layer 16 and a dielectric film of an oxide of an alloy of 54% zinc: 46% tin (by weight) having a physical thickness estimated to be about 845 ⁇ (84.5 nm) deposited on the primer film;
  • An outermost separation layer 28 having a primer film of metallic titanium (Ti) having a physical thickness of about 15 ⁇ (1.5 nm) deposited on the second infrared-reflecting layer, a film of an oxide of an alloy of 54% zinc: 46% tin (by weight) having a physical thickness estimated to be about 257 ⁇ (25.7 nm), and protective overcoat film of an oxide of titanium (Ti) having a physical thickness of estimated to be about 30 ⁇ (3 nm) deposited on the dielectric film.
  • Sample 5 had properties shown on Tables 11 and 12. TABLE 11 Coated Surface Glass Surface Reflected Solar Performance Data Sample Transmitted Color Data Reflected Color Data Color Data TSET TSER1 TSER2 R sheet ID L* a* b* L* a* b* L* a* b* (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) Emissivity (ohms/sq) 5 87.59 ⁇ 2.54 2.01 41.74 ⁇ 10.82 ⁇ 1.92 40.98 ⁇ 12.68 ⁇ 11.60 30.48 55.57 42.20 0.035 2.06
  • a first separation layer 22 having included a first dielectric film of an oxide of an alloy of 54% zinc: 46% tin (by weight) deposited on a glass substrate having a thickness of about 2.3 millimeters; the dielectric film had physical thickness estimated to be about 240 ⁇ (24.0 nanometers, nm), a second dielectric film of an oxide of an alloy of 90% zinc: 10% tin (by weight) deposited on the first dielectric layer; the second dielectric film had physical thickness estimated to be about 80 ⁇ (8.0 nanometers, nm) providing dielectric films having a combined thickness of 320 ⁇ (32.0 nm);
  • a second separation layer 24 having a primer film of metallic titanium (Ti) having a physical thickness estimated to be about 25 ⁇ (2.5 nm) deposited on the silver film of the first infrared-reflective layer 16 and a first dielectric film of an oxide of an alloy of 90% zinc: 10% tin (by weight) deposited on the primer film of the second separation layer;
  • the first dielectric film had physical thickness estimated to be about 84 ⁇ (8.4 nanometers, nm) a second dielectric film of an oxide of an alloy of 54% zinc: 46% tin (by weight) deposited on the first dielectric film;
  • the second dielectric film had physical thickness estimated to be about 676 ⁇ (67.6 nanometers, nm), a third dielectric film of an oxide of an alloy of 90% zinc: 10% tin (by weight) deposited on the second dielectric layer;
  • the third dielectric film had physical thickness estimated to be about 84 ⁇ (8.4 nanometers, nm) providing three dielectric films having
  • An outermost separation layer 28 having a primer film of metallic titanium (Ti) having a physical thickness of about 25 ⁇ (2.5 nm) deposited on the second infrared-reflecting layer, a first dielectric film of an oxide of an alloy of 90% zinc: 10% tin (by weight) deposited on the primer film of the outermost separation layer; the first dielectric film had physical thickness estimated to be about 85 ⁇ (8.5 nanometers, nm), a second dielectric film of an oxide of an alloy of 54% zinc: 46% tin (by weight) deposited on the first dielectric film; the second dielectric film had physical thickness estimated to be about 172 ⁇ (17.2 nanometers, nm), the first and second dielectric films having a combined physical thickness estimated to be about 257 ⁇ (25.7 nm), and a protective overcoat film of an oxide of titanium (Ti) having a physical thickness of estimated to be about 30 ⁇ (3 nm) deposited on the dielectric film.
  • Ti metallic titanium
  • the piece of the monolithic coated glass of Sample 6 having lateral dimensions of approximately 4 inch ⁇ 4 inch and nominal thickness of 2.3 millimeters, had properties as detailed in Tables 13 and 14 after it was heated in a box oven (1300° F. oven temperature setpoint) for approximately 3 minutes, then removed from the oven and subsequently allowed to cool to room temperature in ambient air.
  • the lateral dimensions of Sample 6 were presented because the sample was heat-treated and the dimensions are of interest.
  • Sample 6 had properties shown on Tables 13 and 14. TABLE 13 Coated Surface Glass Surface Reflected Solar Performance Data Sample Transmitted Color Data Reflected Color Data Color Data TSET TSER1 TSER2 R sheet ID L* a* b* L* a* b* L* a* b* (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) Emissivity (ohms/sq) 6 (after 89.60 ⁇ 0.79 3.93 41.41 ⁇ 12.04 0.80 39.83 ⁇ 9.51 ⁇ 10.76 33.11 56.28 44.54 0.029 1.26 heating)
  • a first separation layer 22 having a first dielectric film of an oxide of an alloy of 54% zinc: 46% tin (by weight) deposited on a 4 ⁇ 4 inch 2.3 mm glass substrate; the dielectric film had physical thickness estimated to be about 302 ⁇ (30.2 nanometers, nm), a second dielectric film of an oxide of an alloy of 90% zinc: 10% tin (by weight) deposited on the first dielectric layer; the second dielectric film had physical thickness estimated to be about 75 ⁇ (7.5 nanometers, nm) providing dielectric films having a combined physical thickness estimated to be 377 ⁇ (37.7 nm);
  • a first infrared-reflective layer 16 deposited on the first separation layer was a metallic silver (Ag) having a physical thickness of the silver layer estimated to be about 93 ⁇ (9.3 nm);
  • a second separation layer 24 having a primer film of metallic titanium (Ti) having a physical thickness estimated to be about 25 ⁇ (2.5 nm) deposited on the silver film of the first infrared-reflective layer 16 and a first dielectric film of an oxide of an alloy of 90% zinc: 10% tin (by weight) deposited on the primer film of the second separation layer;
  • the first dielectric film had physical thickness estimated to be about 74 ⁇ (7.4 nanometers, nm) a second dielectric film of an oxide of an alloy of 54% zinc: 46% tin (by weight) deposited on the first dielectric film;
  • the second dielectric film had physical thickness estimated to be about 591 ⁇ (59.1 nanometers, nm), a third dielectric film of an oxide of an alloy of 90% zinc: 10% tin (by weight) deposited on the second dielectric layer;
  • the third dielectric film had physical thickness estimated to be about 74 ⁇ (7.4 nanometers, nm) providing three dielectric films having
  • a second infrared-reflective layer 18 was metallic silver (Ag) having a thickness estimated to be about 114 ⁇ (11.4 nm) deposited on the third dielectric film of the second separation layer;
  • a third separation layer 26 having a primer film of metallic titanium (Ti) having a physical thickness estimated to be about 25 ⁇ (2.5 nm) deposited on the silver film of the second infrared-reflective layer 18 and a first dielectric film of an oxide of an alloy of 90% zinc: 10% tin (by weight) deposited on the primer film of the second separation layer;
  • the first dielectric film had physical thickness estimated to be about 73 ⁇ (7.3 nanometers, nm) a second dielectric film of an oxide of an alloy of 54% zinc: 46% tin (by weight) deposited on the first dielectric film;
  • the second dielectric film had physical thickness estimated to be about 583 ⁇ (58.3 nanometers, nm), a third dielectric film of an oxide of an alloy of 90% zinc: 10% tin (by weight) deposited on the second dielectric layer;
  • the third dielectric film had physical thickness estimated to be about 73 ⁇ (7.3 nanometers, nm) providing three dielectric films having a combined
  • a third infrared-reflective layer 20 was metallic silver (Ag) having a thickness estimated to be about 138 ⁇ (13.8 nm) deposited on the third dielectric film of the third separation layer 26 ;
  • An outermost separation layer 28 having a primer film of metallic titanium (Ti) having a physical thickness of about 25 ⁇ (2.5 nm) deposited on the third infrared-reflecting layer, a first dielectric film of an oxide of an alloy of 90% zinc: 10% tin (by weight) deposited on the primer film of the outermost separation layer; the first dielectric film had physical thickness estimated to be about 87 ⁇ (8.7 nanometers, nm), a second dielectric film of an oxide of an alloy of 54% zinc: 46% tin (by weight) deposited on the first dielectric film; the second dielectric film had physical thickness estimated to be about 175 ⁇ (17.5 nanometers, nm), the first and second dielectric films having a combined physical thickness estimated to be about 262 ⁇ (26.2 nm), and a protective overcoat film of an oxide of titanium (Ti) having a physical thickness of estimated to be about 30 ⁇ (3 nm) deposited on the dielectric film.
  • Ti metallic titanium
  • Sample 7 had properties detailed in Tables 15 and 16 after it was heated in a box oven (1300° F. oven temperature setpoint) for approximately 3 minutes, then removed from the oven and allowed to cool to room temperature in ambient air: TABLE 15 Coated Surface Glass Surface Reflected Solar Performance Data Sample Transmitted Color Data Reflected Color Data Color Data TSET TSER1 TSER2 R sheet ID L* a* b* L* a* b* L* a* b* (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) Emissivity (ohms/sq) 7 (after 90.13 ⁇ 3.32 2.78 26.33 6.46 0.39 28.22 4.00 ⁇ 1.85 32.59 53.28 40.66 0.027 1.13 heating)
  • Sample 8 included:
  • a first separation layer 22 having a first dielectric film of an oxide of an alloy of 54% zinc: 46% tin (by weight) deposited on a glass substrate having a thickness of about 6 millimeters; the dielectric film had physical thickness estimated to be about 257 ⁇ (25.7 nanometers, nm), a second dielectric film of an oxide of an alloy of 90% zinc: 10% tin (by weight) deposited on the first dielectric layer; the second dielectric film had physical thickness estimated to be about 64 ⁇ (6.4 nanometers, nm) providing dielectric films having a combined physical estimated thickness of 321 ⁇ (32.1 nm);
  • a first infrared-reflective layer 16 having a metallic silver (Ag) having a physical thickness of the silver layer estimated to be about 119 ⁇ (11.9 nm) deposited on the first separation layer was;
  • a second separation layer 24 having a primer film of metallic titanium (Ti) having a physical thickness estimated to be about 20 ⁇ (2.0 nm) deposited on the silver film of the first infrared-reflective layer 16 and a first dielectric film of an oxide of an alloy of 90% zinc: 10% tin (by weight) deposited on the primer film of the second separation layer;
  • the first dielectric film had physical thickness estimated to be about 92 ⁇ (9.2 nanometers, nm), a second dielectric film of an oxide of an alloy of 54% zinc: 46% tin (by weight) deposited on the first dielectric film;
  • the second dielectric film had physical thickness estimated to be about 632 ⁇ (63.2 nanometers, nm), a third dielectric film of an oxide of an alloy of 90% zinc: 10% tin (by weight) deposited on the second dielectric layer;
  • the third dielectric film had physical thickness estimated to be about 108 ⁇ (10.8 nanometers, nm) providing three dielectric films having a combined physical
  • An outermost separation layer 28 having a primer film of metallic titanium (Ti) having a physical thickness of about 20 ⁇ (2.0 nm) deposited on the second infrared-reflecting layer, a first dielectric film of an oxide of an alloy of 90% zinc: 10% tin (by weight) deposited on the primer film of the outermost separation layer; the first dielectric film had physical thickness estimated to be about 72 ⁇ (7.2 nanometers, nm), a second dielectric film of an oxide of an alloy of 54% zinc: 46% tin (by weight) deposited on the first dielectric film; the second dielectric film had physical thickness estimated to be about 134 ⁇ (13.4 nanometers, nm), the first and second dielectric films having a combined physical thickness estimated to be about 206 ⁇ (20.6 nm), and a protective overcoat film of an oxide of titanium (Ti) having a physical thickness of estimated to be about 44 ⁇ (4.4 nm) deposited on the dielectric film.
  • Ti metallic titanium
  • Sample 8 had the properties in Tables 17 and 18. TABLE 17 Coated Surface Glass Surface Reflected Solar Performance Data Sample Transmitted Color Data Reflected Color Data Color Data TSET TSER1 TSER2 R sheet ID L* a* b* L* a* b* L* a* b* (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) Emissivity (ohms/sq) 8 87.50 ⁇ 2.94 4.68 41.67 ⁇ 9.28 ⁇ 2.29 41.34 ⁇ 10.49 ⁇ 13.35 29.62 56.70 33.78 0.031 1.55
  • a first separation layer 22 having a first dielectric film of an oxide of an alloy of 54% zinc: 46% tin (by weight) deposited on a glass substrate having a thickness of about 6 millimeters; the dielectric film had physical thickness estimated to be about 286 ⁇ (28.6 nanometers, nm), a second dielectric film of an oxide of an alloy of 90% zinc: 10% tin (by weight) deposited on the first dielectric layer; the second dielectric film had physical thickness estimated to be about 67 ⁇ (6.7 nanometers, nm) providing dielectric films having a combined physical estimated thickness of 353 ⁇ (35.3 nm);
  • a second separation layer 24 having a primer film of metallic titanium (Ti) having a physical thickness estimated to be about 20 ⁇ (2.0 nm) deposited on the silver film of the first infrared-reflective layer 16 and a first dielectric film of an oxide of an alloy of 90% zinc: 10% tin (by weight) deposited on the primer film of the second separation layer;
  • the first dielectric film had physical thickness estimated to be about 94 ⁇ (9.4 nanometers, nm), a second dielectric film of an oxide of an alloy of 54% zinc: 46% tin (by weight) deposited on the first dielectric film;
  • the second dielectric film had physical thickness estimated to be about 648 ⁇ (64.8 nanometers, nm), a third dielectric film of an oxide of an alloy of 90% zinc: 10% tin (by weight) deposited on the second dielectric layer;
  • the third dielectric film had physical thickness estimated to be about 111 ⁇ (1.11 nanometers, nm) providing three dielectric films having a combined
  • An outermost separation layer 28 included a primer film of metallic titanium (Ti) having a physical thickness of about 20 ⁇ (2.0 nm) deposited on the second infrared-reflecting layer, a first dielectric film of an oxide of an alloy of 90% zinc: 10% tin (by weight) deposited on the primer film of the outermost separation layer; the first dielectric film had physical thickness estimated to be about 75 ⁇ (7.5 nanometers, nm), a second dielectric film of an oxide of an alloy of 54% zinc: 46% tin (by weight) deposited on the first dielectric film; the second dielectric film had physical thickness estimated to be about 139 ⁇ (13.9 nanometers, nm), the first and second dielectric films having a combined physical thickness estimated to be about 214 ⁇ (21.4 nm), and a protective overcoat film of an oxide of titanium (Ti) having a physical thickness of estimated to be about 44 ⁇ (4.4 nm) deposited on the dielectric film.
  • Ti metallic titanium
  • Sample 9 had the properties detailed in Tables 19 and 20. TABLE 19 Coated Surface Glass Surface Reflected Solar Performance Data Sample Transmitted Color Data Reflected Color Data Color Data TSET TSER1 TSER2 R sheet ID L* a* b* L* a* b* L* a* b* (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) Emissivity (ohms/sq) 9 87.23 ⁇ 4.36 5.11 44.35 ⁇ 1.44 ⁇ 1.32 43.52 ⁇ 5.60 ⁇ 12.58 29.55 57.65 33.88 0.025 1.58
  • Sample 10 included:
  • a first separation layer 22 having a first dielectric film of an oxide of an alloy of 54% zinc: 46% tin (by weight) deposited on a glass substrate having a thickness of about 6 millimeters; the dielectric film had physical thickness estimated to be about 390 ⁇ (39.0 nanometers, nm), a second dielectric film of an oxide of an alloy of 90% zinc: 10% tin (by weight) deposited on the first dielectric layer; the second dielectric film had physical thickness estimated to be about 104 ⁇ (10.4 nanometers, nm) providing dielectric films having a combined physical estimated thickness of 494 ⁇ (49.4 nm);
  • a second separation layer 24 having a primer film of metallic titanium (Ti) having a physical thickness estimated to be about 20 ⁇ (2.0 nm) deposited on the silver film of the first infrared-reflective layer 16 and a first dielectric film of an oxide of an alloy of 90% zinc: 10% tin (by weight) deposited on the primer film of the second separation layer;
  • the first dielectric film had physical thickness estimated to be about 97 ⁇ (9.7 nanometers, nm), a second dielectric film of an oxide of an alloy of 54% zinc: 46% tin (by weight) deposited on the first dielectric film;
  • the second dielectric film had physical thickness estimated to be about 551 ⁇ (55.1 nanometers, nm), a third dielectric film of an oxide of an alloy of 90% zinc: 10% tin (by weight) deposited on the second dielectric layer;
  • the third dielectric film had physical thickness estimated to be about 97 ⁇ (9.7 nanometers, nm) providing three dielectric films having a combined
  • a third separation layer 24 having a primer film of metallic titanium (Ti) having a physical thickness estimated to be about 20 ⁇ (2.0 nm) deposited on the silver film of the first infrared-reflective layer 18 and a first dielectric film of an oxide of an alloy of 90% zinc: 10% tin (by weight) deposited on the primer film of the second separation layer;
  • the first dielectric film had physical thickness estimated to be about 99 ⁇ (9.9 nanometers, nm), and a second dielectric film of an oxide of an alloy of 54% zinc: 46% tin (by weight) deposited on the first dielectric film;
  • the second dielectric film had physical thickness estimated to be about 565 ⁇ (56.5 nanometers, nm) a third dielectric film of an oxide of an alloy of 90% zinc: 10% tin (by weight) deposited on the second dielectric layer;
  • the third dielectric film had physical thickness estimated to be about 99 ⁇ (9.9 nanometers, nm) providing three dielectric films having a combined physical
  • a third infrared-reflective layer 20 was metallic silver (Ag) having a thickness estimated to be about 181 ⁇ (18.1 nm) deposited on the third dielectric film of the third separation layer.
  • An outermost separation layer 28 included a primer film of metallic titanium (Ti) having a physical thickness of about 20 ⁇ (2.0 nm) deposited on the second infrared-reflecting layer, a first dielectric film of an oxide of an alloy of 90% zinc: 10% tin (by weight) deposited on the primer film of the outermost separation layer; the first dielectric film had physical thickness estimated to be about 93 ⁇ (9.3 nanometers, nm), a second dielectric film of an oxide of an alloy of 54% zinc: 46% tin (by weight) deposited on the first dielectric film; the second dielectric film had physical thickness estimated to be about 217 ⁇ (21.7 nanometers, nm), the first and second dielectric films having a combined physical thickness estimated to be about 310 ⁇ (31.0 nm), and a protective overcoat film of an oxide of titanium (Ti) having a physical thickness of estimated to be about 46 ⁇ (4.6 nm) deposited on the dielectric film.
  • Ti metallic titanium
  • Sample 10 had the properties detailed in Tables 21 and 22. TABLE 21 Coated Surface Glass Surface Reflected Solar Performance Data Sample Transmitted Color Data Reflected Color Data Color Data TSET TSER1 TSER2 R sheet ID L* a* b* L* a* b* L* a* b* (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) (%) Emissivity (ohms/sq) 10 85.57 ⁇ 4.44 1.94 34.05 ⁇ 1.93 0.47 37.35 ⁇ 6.00 ⁇ 1.96 25.17 57.82 33.05 0.026 1.06
  • Samples 11-13 had the layer structures shown in Table 23 below and were deposited on a 6 mm clear glass sheet. TABLE 23 ZnO Zn 2 SnO 4 ZnO Zn 2 SnO 4 ZnO “bottom “bottom “bottom basecoat basecoat bottom bottom centercoat” centercoat” centercoat” center center component component Ag Ti primer component component component Ag Ti primer Sample # (nm) (nm) (nm) (nm) (nm) (nm) (nm) (nm) 11 33.0 14.6 12.2 1.1 12.1 49.3 12.1 13.9 1.2 12 32.3 16.1 12.4 2.1 11.4 49.2 12.1 14.3 2.2 13 29.1 13.7 12.2 1.1 12.1 49.3 12.1 13.9 1.2 ZnO Zn 2 SnO 4 ZnO “top “top “top ZnO Zn 2 SnO 4 centercoat” centercoat” centercoat” top top Topcoat Topcoat TiO 2 component component Ag Ti primer component Component Overcoat Sample # (nm)
  • Samples 11-13 provided the spectral properties shown in Tables 24 for a coated sheet.
  • the calculated reference IG unit performance for Samples 11-13 is shown in Table 25.
  • TABLE 24 Solar Performance Data** TSET, TSER2, Coated Surface Glass Surface total solar TSER1, total total solar Transmitted Reflected Reflected energy solar reflectance reflectance Rsheet Color Data* Color Data* Color Data* transmittance from coated from uncoated (ohms/ Sample # L* T a* T b* T L* T a* R b* R L* R a* R b* R (%) surface (%) glass surface (%) Emissivity square) 11 87.23 ⁇ 4.67 2.62 27.21 ⁇ 4.82 ⁇ 5.52 32.97 ⁇ 4.35 ⁇ 4.17 26.66 55.69 35.34 0.030 1.18 12 89.79 ⁇ 2.86 1.93 27.21 ⁇ 5.20 ⁇ 5.00 31.99 ⁇ 5.19 ⁇ 3.96 29.37 56.88 35.29 0.012 0.85 13 87.
  • IG units can be made using the coatings of the invention with varies types of glasses.

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AU2003231310A AU2003231310B2 (en) 2002-05-03 2003-05-02 Substrate having thermal management coating for an insulating glass unit
RU2004135318/03A RU2342335C2 (ru) 2002-05-03 2003-05-02 Подложка с теплорегулирующим покрытием для изоляционного стеклянного блока
JP2004501331A JP5066323B2 (ja) 2002-05-03 2003-05-02 断熱性ガラスユニット用の熱管理被覆を有する基体
ES03724450T ES2627198T5 (es) 2002-05-03 2003-05-02 Sustrato que tiene revestimiento de gestión térmica para una unidad de vidrio aislante
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CA2484181A CA2484181C (fr) 2002-05-03 2003-05-02 Substrat presentant un revetement de gestion thermique pour une unite de vitrage isolant
EP03724450.6A EP1501768B2 (fr) 2002-05-03 2003-05-02 Substrat presentant un revetement de gestion thermique pour une unite de vitrage isolant
PCT/US2003/014027 WO2003093188A1 (fr) 2002-05-03 2003-05-02 Substrat presentant un revetement de gestion thermique pour une unite de vitrage isolant
US10/428,481 US20040009356A1 (en) 2002-05-03 2003-05-02 Substrate having thermal management coating for an insulating glass unit
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US11/519,188 US7910229B2 (en) 2002-05-03 2006-09-11 Substrate having thermal management coating for an insulating glass unit
JP2009157128A JP5448610B2 (ja) 2002-05-03 2009-07-01 断熱性ガラスユニット用の熱管理被覆を有する基体

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Cited By (51)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030224181A1 (en) * 2002-05-31 2003-12-04 Finley James J. Article having an aesthetic coating
US20030228472A1 (en) * 2002-04-29 2003-12-11 Hoffman Wayne L. Coatings having low emissivity and low solar reflectance
US20040016202A1 (en) * 2002-05-16 2004-01-29 Hoffman Wayne L. High shading performance coatings
US20040071985A1 (en) * 2002-07-31 2004-04-15 Krisko Annette J. Temperable high shading performance coatings
US20050079369A1 (en) * 2003-10-14 2005-04-14 Guardian Industries Corp. Heat treatable coated article and method of making same
US20050191502A1 (en) * 2004-02-27 2005-09-01 Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) Coated article with low-E coating including tin oxide interlayer
US20070082169A1 (en) * 2005-10-11 2007-04-12 Klaus Hartig High infrared reflection coatings
US20070082186A1 (en) * 2005-10-11 2007-04-12 Klaus Hartig High infrared reflection coatings, thin film coating deposition methods, and associated technologies
US20070082206A1 (en) * 2005-10-11 2007-04-12 Klaus Hartig High infrared reflection coatings and associated technologies
US20070082219A1 (en) * 2003-11-28 2007-04-12 Saint-Gobain Glass France Transparent substrate which can be used alternatively or cumulatively for thermal control, electromagnetic armour and heated glazing
WO2007064450A2 (fr) * 2005-12-01 2007-06-07 Guardian Industries Corp. Unité de fenêtre de vitrage isolant et son procédé de fabrication
US20070166553A1 (en) * 2004-03-11 2007-07-19 Guardian Industries Corp. Coated article with low-E coating including tin oxide interlayer
US20070264479A1 (en) * 2006-05-09 2007-11-15 Thiel James P Aesthetic transparency
US20080086973A1 (en) * 2004-06-23 2008-04-17 Merete Hallenstvet Structural Metal Element With Improved Thermal Properties
US20080138547A1 (en) * 2006-11-09 2008-06-12 Agc Flat Glass North America, Inc. Optical coating with improved durability
WO2009029466A1 (fr) * 2007-08-24 2009-03-05 Ppg Industries Ohio, Inc. Élément transparent de véhicule
US7820309B2 (en) 2007-09-14 2010-10-26 Cardinal Cg Company Low-maintenance coatings, and methods for producing low-maintenance coatings
US7862910B2 (en) 2006-04-11 2011-01-04 Cardinal Cg Company Photocatalytic coatings having improved low-maintenance properties
AU2007230224B2 (en) * 2006-03-28 2011-03-31 Vitro Flat Glass Llc Low solar absorbing blue glass, solar reflecting coated blue glass, and insulating unit having a low solar heat gain
CN102046554A (zh) * 2008-05-19 2011-05-04 法国圣戈班玻璃厂 提供有薄层叠层的窗玻璃
US8025957B2 (en) 2007-05-09 2011-09-27 Ppg Industries Ohio, Inc. Vehicle transparency
US20110236715A1 (en) * 2010-03-29 2011-09-29 Ppg Industries Ohio, Inc. Solar control coatings with discontinuous metal layer
US20120268695A1 (en) * 2009-10-28 2012-10-25 Marten Walther Device, in particular for a display unit
USRE43817E1 (en) 2004-07-12 2012-11-20 Cardinal Cg Company Low-maintenance coatings
US20130230698A1 (en) * 2009-05-22 2013-09-05 Guardian Industries Corp. Coated article with low-e coating having zinc stannage based layer between ir reflecting layers for reduced mottling and corresponding method
US20140098414A1 (en) * 2011-03-09 2014-04-10 Nitto Denko Corporation Infrared reflective film
US8697243B2 (en) 2008-03-20 2014-04-15 Agc Glass Europe Film-coated glazing
US20140272453A1 (en) * 2013-03-12 2014-09-18 Ppg Industries Ohio, Inc. Solar Control Coatings Providing Increased Absorption Or Tint
WO2015023303A1 (fr) * 2013-08-16 2015-02-19 Guardian Industries Corp. Article revêtu avec un revêtement de faible émissivité ayant une faible transmission visible qui peut être utilisé dans une unité de fenêtre ig pour aspect gris
US20150191393A1 (en) * 2010-03-29 2015-07-09 Ppg Industries Ohio, Inc. Tempered and non-tempered glass coatings having similar optical characteristics
US20150191965A1 (en) * 2013-03-14 2015-07-09 Intermolecular Inc. Low-E Panels and Methods for Forming the Same
US9296650B1 (en) * 2014-10-13 2016-03-29 Intermolecular, Inc. Low-E panels and methods for forming the same
US20160124119A1 (en) * 2013-04-30 2016-05-05 Saint-Gobain Glass France Substrate provided with a stack having thermal properties
US20160214887A1 (en) * 2013-09-05 2016-07-28 Saint-Gobain Glass France Method for manufacturing a material including a substrate having a tin and indium oxide-based functional layer
US9469566B2 (en) 2015-03-20 2016-10-18 Cardinal Cg Company Nickel-aluminum blocker film low-emissivity coatings
US20160354995A1 (en) * 2015-06-03 2016-12-08 Saint-Gobain Performance Plastics Corporation Solar control film
US9630876B2 (en) 2013-05-30 2017-04-25 Agc Glass Europe Low-emissivity and anti-solar glazing
US9738967B2 (en) 2006-07-12 2017-08-22 Cardinal Cg Company Sputtering apparatus including target mounting and control
US9745792B2 (en) 2015-03-20 2017-08-29 Cardinal Cg Company Nickel-aluminum blocker film multiple cavity controlled transmission coating
US9752377B2 (en) 2015-03-20 2017-09-05 Cardinal Cg Company Nickel-aluminum blocker film controlled transmission coating
US20180355485A1 (en) * 2015-12-11 2018-12-13 Michiels Group A method of manufacturing a coated polymer substrate having low emissivity
WO2019005896A1 (fr) * 2017-06-30 2019-01-03 Saint-Gobain Performance Plastics Corporation Film de protection solaire
US10539726B2 (en) 2015-09-01 2020-01-21 Vitro Flat Glass Llc Solar control coating with enhanced solar control performance
US10562812B2 (en) 2018-06-12 2020-02-18 Guardian Glass, LLC Coated article having metamaterial-inclusive layer, coating having metamaterial-inclusive layer, and/or method of making the same
US10604442B2 (en) 2016-11-17 2020-03-31 Cardinal Cg Company Static-dissipative coating technology
US10654748B2 (en) 2010-03-29 2020-05-19 Vitro Flat Glass Llc Solar control coatings providing increased absorption or tint
US10654747B2 (en) * 2010-03-29 2020-05-19 Vitro Flat Glass Llc Solar control coatings with subcritical copper
US10830933B2 (en) 2018-06-12 2020-11-10 Guardian Glass, LLC Matrix-embedded metamaterial coating, coated article having matrix-embedded metamaterial coating, and/or method of making the same
US11028012B2 (en) 2018-10-31 2021-06-08 Cardinal Cg Company Low solar heat gain coatings, laminated glass assemblies, and methods of producing same
US11078718B2 (en) 2018-02-05 2021-08-03 Vitro Flat Glass Llc Solar control coatings with quadruple metallic layers
EP2577368B1 (fr) 2010-05-25 2023-07-26 AGC Glass Europe Vitrage de contrôle solaire à faible facteur solaire

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100802790B1 (ko) 2003-05-30 2008-02-12 피피지 인더스트리즈 오하이오 인코포레이티드 기구 투명체
US7998602B2 (en) 2003-05-30 2011-08-16 Ppg Industries Ohio, Inc. Appliance with coated transparency
US7655313B2 (en) * 2007-03-15 2010-02-02 Guardian Industries Corp. Low-E coated articles and methods of making same
DE102010008518B4 (de) * 2010-02-18 2013-11-28 Von Ardenne Anlagentechnik Gmbh Wärmebehandelbares Infrarotstrahlung reflektierendes Schichtsystem und Verfahren zu dessen Herstellung
US8337988B2 (en) * 2010-04-22 2012-12-25 Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) Coated article having low-E coating with absorber layer(s)
US8445111B2 (en) * 2010-10-14 2013-05-21 Guardian Industries Corp. Gadolinium oxide-doped zirconium oxide overcoat and/or method of making the same
CN102030485A (zh) * 2010-11-16 2011-04-27 华中科技大学 智能调控复合膜玻璃及其制备方法
US8557391B2 (en) 2011-02-24 2013-10-15 Guardian Industries Corp. Coated article including low-emissivity coating, insulating glass unit including coated article, and/or methods of making the same
US8790783B2 (en) * 2011-03-03 2014-07-29 Guardian Industries Corp. Barrier layers comprising Ni and/or Ti, coated articles including barrier layers, and methods of making the same
FR2985724B1 (fr) * 2012-01-16 2014-03-07 Saint Gobain Substrat muni d'un empilement a proprietes thermiques comportant quatre couches fonctionnelles metalliques.
US10040719B2 (en) 2012-01-17 2018-08-07 Cardinal Cg Company Low solar transmittance coatings
CN102673042A (zh) * 2012-04-26 2012-09-19 蒙特集团（香港）有限公司 一种新型宽幅遮阳材料及其制作方法
US9469565B2 (en) 2012-05-31 2016-10-18 Guardian Industries Corp. Window with selectively writable image(s) and method of making same
KR101809341B1 (ko) 2013-03-12 2017-12-14 비트로, 에스.에이.비. 데 씨.브이. 유사한 광학 특성을 갖는 강화 및 비강화 유리 코팅층
JP6487424B2 (ja) * 2013-06-27 2019-03-20 カール・ツァイス・エスエムティー・ゲーエムベーハー マイクロリソグラフィ投影露光システムのミラー及びミラーを加工する方法
RU2554608C2 (ru) * 2013-07-01 2015-06-27 Общество с ограниченной ответственностью "Солар" Способ получения просветляющего покрытия
US8940400B1 (en) * 2013-09-03 2015-01-27 Guardian Industries Corp. IG window unit including double silver coating having increased SHGC to U-value ratio, and corresponding coated article for use in IG window unit or other window
JP6287502B2 (ja) * 2014-04-03 2018-03-07 セントラル硝子株式会社 低放射窓材
US10345499B2 (en) 2015-02-03 2019-07-09 Vitro Flat Glass LLC.. Solar control coating with enhanced solar control performance
CN106273881B (zh) * 2015-05-29 2019-06-21 法国圣戈班玻璃公司 低辐射玻璃及其制造方法、车窗
FR3038595A1 (fr) * 2015-07-06 2017-01-13 Saint Gobain Vitrage comprenant un revetement fonctionnel a base d'argent et d'indium
FR3038596B1 (fr) * 2015-07-08 2021-12-10 Saint Gobain Materiau muni d'un empilement a proprietes thermiques
RU2683727C2 (ru) * 2015-07-15 2019-04-01 Тюркийе Шише Ве Кам Фабрикалари А.Ш. Архитектурное стекло с низкоэмиссионным покрытием, имеющим многослойную структуру, обладающее высокой прочностью, и/или способ его изготовления
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CN106349495A (zh) * 2016-09-30 2017-01-25 郑州航空工业管理学院 一种用于通航飞机舷窗玻璃的高耐磨节能薄膜及其制备方法
FR3057900A1 (fr) * 2016-10-26 2018-04-27 Saint-Gobain Glass France Vitrage multiple comprenant au moins une feuille de verre mince revetue d'un empilement a faible emissivite
US11220455B2 (en) 2017-08-04 2022-01-11 Vitro Flat Glass Llc Flash annealing of silver coatings
US20190041550A1 (en) 2017-08-04 2019-02-07 Vitro Flat Glass Llc Flash Annealing of Transparent Conductive Oxide and Semiconductor Coatings
GB201820002D0 (en) * 2018-12-07 2019-01-23 Pilkington Group Ltd Coated glass pane
CN110103549B (zh) * 2019-04-10 2021-04-13 江苏理工学院 一种高反射多层隔热窗膜及其制备方法

Citations (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4746347A (en) * 1987-01-02 1988-05-24 Ppg Industries, Inc. Patterned float glass method
US4786563A (en) * 1985-12-23 1988-11-22 Ppg Industries, Inc. Protective coating for low emissivity coated articles
US4792536A (en) * 1987-06-29 1988-12-20 Ppg Industries, Inc. Transparent infrared absorbing glass and method of making
US4898790A (en) * 1986-12-29 1990-02-06 Ppg Industries, Inc. Low emissivity film for high temperature processing
US4898789A (en) * 1988-04-04 1990-02-06 Ppg Industries, Inc. Low emissivity film for automotive heat load reduction
US4996105A (en) * 1986-11-27 1991-02-26 Asahi Glass Company Ltd. Transparent laminated product
US5059458A (en) * 1987-08-14 1991-10-22 Pilkington Plc Glazing units
US5240886A (en) * 1990-07-30 1993-08-31 Ppg Industries, Inc. Ultraviolet absorbing, green tinted glass
US5306547A (en) * 1990-12-14 1994-04-26 Southwall Technologies Inc. Low transmission heat-reflective glazing materials
US5393593A (en) * 1990-10-25 1995-02-28 Ppg Industries, Inc. Dark gray, infrared absorbing glass composition and coated glass for privacy glazing
US5595825A (en) * 1993-09-23 1997-01-21 Saint-Gobain Vitrage Transparent substrate provided with a stack of thin films acting on solar and/or infrared radiation
US5821001A (en) * 1996-04-25 1998-10-13 Ppg Industries, Inc. Coated articles
US5837361A (en) * 1995-11-10 1998-11-17 Saint-Gobain Vitrage Substrates coated with a stack of thin layers having reflection properties in the infrared and/or with respect to solar radiation
US5942338A (en) * 1996-04-25 1999-08-24 Ppg Industries Ohio, Inc. Coated articles
US6042934A (en) * 1993-08-12 2000-03-28 Saint-Gobain Vitrage Transparent substrate provided with a stack of thin layers
US20020045037A1 (en) * 1996-12-12 2002-04-18 Saint-Gobain Vitrage Glazing assembly comprising a substrate provided with a stack of thin layers for solar protection and / or thermal insulation

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US142090A (en) 1873-08-26 Improvement in beer-faucets
US567934A (en) 1896-09-15 John f
JPS5931147A (ja) * 1982-08-17 1984-02-20 株式会社豊田中央研究所 可視光透過性熱線しやへい膜およびその製造方法
CA1331867C (fr) * 1986-12-29 1994-09-06 James Joseph Finley Pellicule a faible pouvoir emissif pour traitement a haute temperature
US5902505A (en) * 1988-04-04 1999-05-11 Ppg Industries, Inc. Heat load reduction windshield
AU5437790A (en) * 1989-04-11 1990-11-05 Andus Corporation Transparent conductive coatings
US5675944A (en) 1990-09-04 1997-10-14 P.P.G. Industries, Inc. Low thermal conducting spacer assembly for an insulating glazing unit and method of making same
FR2701475B1 (fr) * 1993-02-11 1995-03-31 Saint Gobain Vitrage Int Substrats en verre revêtus d'un empilement de couches minces, application à des vitrages à propriétés de réflexion dans l'infra-rouge et/ou à propriétés dans le domaine du rayonnement solaire.
US5688585A (en) * 1993-08-05 1997-11-18 Guardian Industries Corp. Matchable, heat treatable, durable, IR-reflecting sputter-coated glasses and method of making same
US5557462A (en) * 1995-01-17 1996-09-17 Guardian Industries Corp. Dual silver layer Low-E glass coating system and insulating glass units made therefrom
GB9508543D0 (en) 1995-04-27 1995-06-14 Glaverbel Coated substrate having high luminous transmission, low solar factor and neutral aspect in reflection
GB9606281D0 (en) * 1996-03-26 1996-05-29 Glaverbel Coated substrate for a transparent assembly with high selectivity
FR2748743B1 (fr) * 1996-05-14 1998-06-19 Saint Gobain Vitrage Vitrage a revetement antireflet
DE19741714C2 (de) 1997-09-22 2002-03-21 Inst Molekulare Biotechnologie Verfahren zur Synthese und Amplifikation von Nukleinsäuren
GB9820109D0 (en) 1998-09-15 1998-11-11 Nat Power Plc Vitrified carbon compositions
MXPA01012881A (es) 1999-06-16 2002-07-30 Ppg Ind Ohio Inc Capas protectoras para articulo recubierto por bombardeo ionico.
US6849328B1 (en) 1999-07-02 2005-02-01 Ppg Industries Ohio, Inc. Light-transmitting and/or coated article with removable protective coating and methods of making the same
US20020136905A1 (en) * 1999-11-24 2002-09-26 Medwick Paul A. Low shading coefficient and low emissivity coatings and coated articles
MXPA02004955A (es) * 1999-11-24 2002-09-18 Ppg Ind Ohio Inc Revestimientos de coeficiente de oscurecimiento bajo y de baja enmisividad y articulos revestidos.
WO2003037056A1 (fr) 2001-10-26 2003-05-01 Central Glass Company, Limited Substrat dote d'un film de protection electromagnetique
CA2475192C (fr) † 2002-02-11 2008-12-09 Ppg Industries Ohio, Inc. Revetement contre le soleil
JP5993649B2 (ja) 2012-07-31 2016-09-14 東京エレクトロン株式会社 プローブカードへの基板当接装置、基板当接装置を備えた基板検査装置、及びプローブカードへの基板当接方法

Patent Citations (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4786563A (en) * 1985-12-23 1988-11-22 Ppg Industries, Inc. Protective coating for low emissivity coated articles
US4996105A (en) * 1986-11-27 1991-02-26 Asahi Glass Company Ltd. Transparent laminated product
US4898790A (en) * 1986-12-29 1990-02-06 Ppg Industries, Inc. Low emissivity film for high temperature processing
US4746347A (en) * 1987-01-02 1988-05-24 Ppg Industries, Inc. Patterned float glass method
US4792536A (en) * 1987-06-29 1988-12-20 Ppg Industries, Inc. Transparent infrared absorbing glass and method of making
US5059458A (en) * 1987-08-14 1991-10-22 Pilkington Plc Glazing units
US4898789A (en) * 1988-04-04 1990-02-06 Ppg Industries, Inc. Low emissivity film for automotive heat load reduction
US5240886A (en) * 1990-07-30 1993-08-31 Ppg Industries, Inc. Ultraviolet absorbing, green tinted glass
US5385872A (en) * 1990-07-30 1995-01-31 Ppg Industries, Inc. Ultraviolet absorbing green tinted glass
US5393593A (en) * 1990-10-25 1995-02-28 Ppg Industries, Inc. Dark gray, infrared absorbing glass composition and coated glass for privacy glazing
US5306547A (en) * 1990-12-14 1994-04-26 Southwall Technologies Inc. Low transmission heat-reflective glazing materials
US6042934A (en) * 1993-08-12 2000-03-28 Saint-Gobain Vitrage Transparent substrate provided with a stack of thin layers
US5595825A (en) * 1993-09-23 1997-01-21 Saint-Gobain Vitrage Transparent substrate provided with a stack of thin films acting on solar and/or infrared radiation
US5837361A (en) * 1995-11-10 1998-11-17 Saint-Gobain Vitrage Substrates coated with a stack of thin layers having reflection properties in the infrared and/or with respect to solar radiation
US5821001A (en) * 1996-04-25 1998-10-13 Ppg Industries, Inc. Coated articles
US5942338A (en) * 1996-04-25 1999-08-24 Ppg Industries Ohio, Inc. Coated articles
US20020045037A1 (en) * 1996-12-12 2002-04-18 Saint-Gobain Vitrage Glazing assembly comprising a substrate provided with a stack of thin layers for solar protection and / or thermal insulation

Cited By (132)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7758915B2 (en) 2002-04-29 2010-07-20 Cardinal Cg Company Low-emissivity coating having low solar reflectance
US20040028955A1 (en) * 2002-04-29 2004-02-12 Hoffman Wayne L. Low-emissivity coating having low solar reflectance
US20030228472A1 (en) * 2002-04-29 2003-12-11 Hoffman Wayne L. Coatings having low emissivity and low solar reflectance
US20060222763A1 (en) * 2002-04-29 2006-10-05 Hoffman Wayne L Coatings having low emissivity and low solar reflectance
US7670641B2 (en) 2002-04-29 2010-03-02 Cardinal Cg Company Coatings having low emissivity and low solar reflectance
US20040016202A1 (en) * 2002-05-16 2004-01-29 Hoffman Wayne L. High shading performance coatings
US7687149B2 (en) 2002-05-16 2010-03-30 Cardinal Cg Company High shading performance coatings
US7588829B2 (en) * 2002-05-31 2009-09-15 Ppg Industries Ohio, Inc. Article having an aesthetic coating
US20030224181A1 (en) * 2002-05-31 2003-12-04 Finley James J. Article having an aesthetic coating
US20040071985A1 (en) * 2002-07-31 2004-04-15 Krisko Annette J. Temperable high shading performance coatings
US20060172138A1 (en) * 2003-10-14 2006-08-03 Guardian Industries Corp. Heat treatable coated article and method of making same
US7081301B2 (en) * 2003-10-14 2006-07-25 Guardian Industries Corp. Coated article with and oxide of silicon zirconium or zirconium yttrium oxide in overcoat, and/or niobium nitrude in ir reflecting layer
WO2005037723A3 (fr) * 2003-10-14 2006-02-02 Guardian Industries Article revetu traitable thermiquement et son procede de fabrication
US20050079369A1 (en) * 2003-10-14 2005-04-14 Guardian Industries Corp. Heat treatable coated article and method of making same
US7405004B2 (en) * 2003-10-14 2008-07-29 Guardian Industries Corp. Heat treatable coated article and method of making same
US20070082219A1 (en) * 2003-11-28 2007-04-12 Saint-Gobain Glass France Transparent substrate which can be used alternatively or cumulatively for thermal control, electromagnetic armour and heated glazing
US7972713B2 (en) 2003-11-28 2011-07-05 Saint-Gobain Glass France Transparent substrate which can be used alternatively or cumulatively for thermal control, electromagnetic armour and heated glazing
US8440329B2 (en) 2003-11-28 2013-05-14 Saint-Gobain Glass France Transparent substrate which can be used alternatively or cumulatively, for thermal control, for electromagnetic armour and for heated glazing
US7858191B2 (en) 2004-02-27 2010-12-28 Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) Coated article with low-E coating including tin oxide interlayer
US20050191502A1 (en) * 2004-02-27 2005-09-01 Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) Coated article with low-E coating including tin oxide interlayer
US7081302B2 (en) * 2004-02-27 2006-07-25 Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) Coated article with low-E coating including tin oxide interlayer
US7534496B2 (en) * 2004-02-27 2009-05-19 Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) Coated article with low-E coating including tin oxide interlayer
US8187713B2 (en) 2004-02-27 2012-05-29 Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C) Coated article with low-E coating including tin oxide interlayer
US20060172139A1 (en) * 2004-02-27 2006-08-03 C.R.V.C. Coated article with low-E coating including tin oxide interlayer
US20090214880A1 (en) * 2004-02-27 2009-08-27 C.R.V.C., Dudelange, Grand Duche De Luxembourg Coated article with low-E coating including tin oxide interlayer
US20110097590A1 (en) * 2004-02-27 2011-04-28 C.R.V.C. Coated article with low-E coating including tin oxide interlayer
US20110117371A1 (en) * 2004-03-11 2011-05-19 Guardian Industries Corp. Coated article with low-E coating including tin oxide interlayer
US7897260B2 (en) 2004-03-11 2011-03-01 Guardian Industries Corp. Coated article with low-E coating including tin oxide interlayer
US20070166553A1 (en) * 2004-03-11 2007-07-19 Guardian Industries Corp. Coated article with low-E coating including tin oxide interlayer
US8609260B2 (en) 2004-03-11 2013-12-17 Guardian Industries Corp. Coated article with low-E coating including tin oxide interlayer
US8124237B2 (en) 2004-03-11 2012-02-28 Guardian Industries Corp. Coated article with low-E coating including tin oxide interlayer
US8357458B2 (en) 2004-03-11 2013-01-22 Guardian Industries Corp. Coated article with low-E coating including tin oxide interlayer
US20080086973A1 (en) * 2004-06-23 2008-04-17 Merete Hallenstvet Structural Metal Element With Improved Thermal Properties
USRE43817E1 (en) 2004-07-12 2012-11-20 Cardinal Cg Company Low-maintenance coatings
USRE44155E1 (en) 2004-07-12 2013-04-16 Cardinal Cg Company Low-maintenance coatings
US20070081228A1 (en) * 2005-10-11 2007-04-12 Klaus Hartig Multiple cavity low-emissivity coatings
US20070082169A1 (en) * 2005-10-11 2007-04-12 Klaus Hartig High infrared reflection coatings
US7572509B2 (en) * 2005-10-11 2009-08-11 Cardinal Cg Company High infrared reflection coatings and thin film coating deposition methods
US7572511B2 (en) * 2005-10-11 2009-08-11 Cardinal Cg Company High infrared reflection coatings
US20170009516A1 (en) * 2005-10-11 2017-01-12 Cardinal Cg Company High quality reflectance coatings
US9663984B2 (en) 2005-10-11 2017-05-30 Cardinal Cg Company High infrared reflection coatings, thin film coating deposition methods and associated technologies
US11028011B2 (en) 2005-10-11 2021-06-08 Cardinal Cg Company High infrared reflection coatings, thin film coating deposition methods and associated technologies
US10773996B2 (en) * 2005-10-11 2020-09-15 Cardinal Cg Company Deposition methods for high quality reflectance coatings
US20100297413A1 (en) * 2005-10-11 2010-11-25 Cardinal Cg Company High quality reflectance coatings
US7342716B2 (en) 2005-10-11 2008-03-11 Cardinal Cg Company Multiple cavity low-emissivity coatings
US20140065328A1 (en) * 2005-10-11 2014-03-06 Cardinal Cg Company High quality reflectance coatings
US7339728B2 (en) 2005-10-11 2008-03-04 Cardinal Cg Company Low-emissivity coatings having high visible transmission and low solar heat gain coefficient
US7906203B2 (en) 2005-10-11 2011-03-15 Cardinal Cg Company High infrared reflection coatings
US9376853B2 (en) * 2005-10-11 2016-06-28 Cardinal Cg Company High quality reflectance coatings
US8586215B2 (en) * 2005-10-11 2013-11-19 Cardinal Cg Company High quality reflectance coatings
US10590035B2 (en) 2005-10-11 2020-03-17 Cardinal Cg Company High quality reflectance coatings
US20170283314A1 (en) * 2005-10-11 2017-10-05 Cardinal Cg Company Deposition methods for high quality reflectance coatings
US20110128617A1 (en) * 2005-10-11 2011-06-02 Cardinal Cg Company High infrared reflection coatings, thin film coating deposition methods and associated technologies
US20070082186A1 (en) * 2005-10-11 2007-04-12 Klaus Hartig High infrared reflection coatings, thin film coating deposition methods, and associated technologies
US7572510B2 (en) * 2005-10-11 2009-08-11 Cardinal Cg Company High infrared reflection coatings and associated technologies
US20070082206A1 (en) * 2005-10-11 2007-04-12 Klaus Hartig High infrared reflection coatings and associated technologies
US10442728B2 (en) 2005-10-11 2019-10-15 Cardinal Cg Company High infrared reflection coatings, thin film coating deposition methods and associated technologies
US8088473B2 (en) 2005-10-11 2012-01-03 Cardinal Cg Company High infrared reflection coatings, thin film coating deposition methods and associated technologies
US20070082124A1 (en) * 2005-10-11 2007-04-12 Klaus Hartig Methods and equipment for depositing high quality reflective coatings
US20070081227A1 (en) * 2005-10-11 2007-04-12 Klaus Hartig Low-emissivity coatings having high visible transmission and low solar heat gain coefficient
US8283059B2 (en) * 2005-10-11 2012-10-09 Cardinal Cg Company High quality reflectance coatings
US10094163B2 (en) * 2005-10-11 2018-10-09 Cardinal Cg Company High quality reflectance coatings
US20070082168A1 (en) * 2005-10-11 2007-04-12 Klaus Hartig High infrared reflection coatings and thin film coating deposition methods
US8025941B2 (en) 2005-12-01 2011-09-27 Guardian Industries Corp. IG window unit and method of making the same
WO2007064450A2 (fr) * 2005-12-01 2007-06-07 Guardian Industries Corp. Unité de fenêtre de vitrage isolant et son procédé de fabrication
US20070128449A1 (en) * 2005-12-01 2007-06-07 Guardian Industries Corp. IG window unit and method of making the same
WO2007064450A3 (fr) * 2005-12-01 2007-11-08 Guardian Industries Unité de fenêtre de vitrage isolant et son procédé de fabrication
AU2007230224B2 (en) * 2006-03-28 2011-03-31 Vitro Flat Glass Llc Low solar absorbing blue glass, solar reflecting coated blue glass, and insulating unit having a low solar heat gain
US7862910B2 (en) 2006-04-11 2011-01-04 Cardinal Cg Company Photocatalytic coatings having improved low-maintenance properties
US20070264479A1 (en) * 2006-05-09 2007-11-15 Thiel James P Aesthetic transparency
US9738967B2 (en) 2006-07-12 2017-08-22 Cardinal Cg Company Sputtering apparatus including target mounting and control
US20080138547A1 (en) * 2006-11-09 2008-06-12 Agc Flat Glass North America, Inc. Optical coating with improved durability
US8025957B2 (en) 2007-05-09 2011-09-27 Ppg Industries Ohio, Inc. Vehicle transparency
WO2009029466A1 (fr) * 2007-08-24 2009-03-05 Ppg Industries Ohio, Inc. Élément transparent de véhicule
US8506768B2 (en) 2007-09-14 2013-08-13 Cardinal Cg Company Low-maintenance coatings, and methods for producing low-maintenance coatings
US7820309B2 (en) 2007-09-14 2010-10-26 Cardinal Cg Company Low-maintenance coatings, and methods for producing low-maintenance coatings
US7820296B2 (en) 2007-09-14 2010-10-26 Cardinal Cg Company Low-maintenance coating technology
US8696879B2 (en) 2007-09-14 2014-04-15 Cardinal Cg Company Low-maintenance coating technology
US8697243B2 (en) 2008-03-20 2014-04-15 Agc Glass Europe Film-coated glazing
CN102046554A (zh) * 2008-05-19 2011-05-04 法国圣戈班玻璃厂 提供有薄层叠层的窗玻璃
US9789750B2 (en) * 2009-05-22 2017-10-17 Centre Luxembourgeois de Recherches pour la Verre et la Ceramique S.A. (C.R.V.C.) Coated article with low-E coating having zinc stannate based layer between IR reflecting layers for reduced mottling and corresponding method
US20130230698A1 (en) * 2009-05-22 2013-09-05 Guardian Industries Corp. Coated article with low-e coating having zinc stannage based layer between ir reflecting layers for reduced mottling and corresponding method
US10384422B2 (en) * 2009-10-28 2019-08-20 Schott Ag Device, in particular for a display unit
US20120268695A1 (en) * 2009-10-28 2012-10-25 Marten Walther Device, in particular for a display unit
US10981826B2 (en) 2010-03-29 2021-04-20 Vitro Flat Glass Llc Solar control coatings with subcritical copper
US9932267B2 (en) * 2010-03-29 2018-04-03 Vitro, S.A.B. De C.V. Solar control coatings with discontinuous metal layer
US9604875B2 (en) * 2010-03-29 2017-03-28 Vitro, S.A.B. De C.V. Tempered and non-tempered glass coatings having similar optical characteristics
US11267752B2 (en) 2010-03-29 2022-03-08 Vitro Flat Glass Llc Solar control coating with discontinuous metal layer
US11286200B2 (en) 2010-03-29 2022-03-29 Vitro Flat Glass Llc Solar control coatings with subcritical copper
US10654748B2 (en) 2010-03-29 2020-05-19 Vitro Flat Glass Llc Solar control coatings providing increased absorption or tint
US10703673B2 (en) 2010-03-29 2020-07-07 Vitro Flat Glass Llc Solar control coating with discontinuous metal layer
US10654749B2 (en) * 2010-03-29 2020-05-19 Vitro Flat Glass Llc Solar control coatings providing increased absorption or tint
US20110236715A1 (en) * 2010-03-29 2011-09-29 Ppg Industries Ohio, Inc. Solar control coatings with discontinuous metal layer
US10358384B2 (en) 2010-03-29 2019-07-23 Vitro, S.A.B. De C.V. Solar control coatings with discontinuous metal layer
US11401207B2 (en) 2010-03-29 2022-08-02 Vitro Flat Glass Llc Solar control coatings providing increased absorption or tint
US20150191393A1 (en) * 2010-03-29 2015-07-09 Ppg Industries Ohio, Inc. Tempered and non-tempered glass coatings having similar optical characteristics
US11891328B2 (en) 2010-03-29 2024-02-06 Vitro Flat Glass Llc Solar control coatings providing increased absorption or tint
US10654747B2 (en) * 2010-03-29 2020-05-19 Vitro Flat Glass Llc Solar control coatings with subcritical copper
EP2577368B1 (fr) 2010-05-25 2023-07-26 AGC Glass Europe Vitrage de contrôle solaire à faible facteur solaire
US20140098414A1 (en) * 2011-03-09 2014-04-10 Nitto Denko Corporation Infrared reflective film
US20140272453A1 (en) * 2013-03-12 2014-09-18 Ppg Industries Ohio, Inc. Solar Control Coatings Providing Increased Absorption Or Tint
US9410359B2 (en) * 2013-03-14 2016-08-09 Intermolecular, Inc. Low-e panels and methods for forming the same
US20150191965A1 (en) * 2013-03-14 2015-07-09 Intermolecular Inc. Low-E Panels and Methods for Forming the Same
US9846264B2 (en) * 2013-04-30 2017-12-19 Saint-Gobain Glass France Substrate provided with a stack having thermal properties
US20160124119A1 (en) * 2013-04-30 2016-05-05 Saint-Gobain Glass France Substrate provided with a stack having thermal properties
US9630876B2 (en) 2013-05-30 2017-04-25 Agc Glass Europe Low-emissivity and anti-solar glazing
WO2015023303A1 (fr) * 2013-08-16 2015-02-19 Guardian Industries Corp. Article revêtu avec un revêtement de faible émissivité ayant une faible transmission visible qui peut être utilisé dans une unité de fenêtre ig pour aspect gris
US10378271B2 (en) 2013-08-16 2019-08-13 Guardian Europe S.A.R.L. Coated article with low-E coating having low visible transmission which may be used in IG window unit for grey appearance
US20160214887A1 (en) * 2013-09-05 2016-07-28 Saint-Gobain Glass France Method for manufacturing a material including a substrate having a tin and indium oxide-based functional layer
US9296650B1 (en) * 2014-10-13 2016-03-29 Intermolecular, Inc. Low-E panels and methods for forming the same
US11149486B2 (en) 2015-03-20 2021-10-19 Cardinal Cg Company Nickel-aluminum blocker film multiple cavity controlled transmission coating
US10563451B2 (en) 2015-03-20 2020-02-18 Cardinal Cg Company Nickel-aluminum blocker film controlled transmission coating
US10465434B2 (en) 2015-03-20 2019-11-05 Cardinal Cg Company Nickel-aluminum blocker film multiple cavity controlled transmission coating
US10067274B2 (en) 2015-03-20 2018-09-04 Cardinal Cg Company Nickel-aluminum blocker film low-emissivity coatings
US9752377B2 (en) 2015-03-20 2017-09-05 Cardinal Cg Company Nickel-aluminum blocker film controlled transmission coating
US9745792B2 (en) 2015-03-20 2017-08-29 Cardinal Cg Company Nickel-aluminum blocker film multiple cavity controlled transmission coating
US9469566B2 (en) 2015-03-20 2016-10-18 Cardinal Cg Company Nickel-aluminum blocker film low-emissivity coatings
JP2018517938A (ja) * 2015-06-03 2018-07-05 サン−ゴバン パフォーマンス プラスティックス コーポレイション ソーラーコントロールフィルム
US20160354995A1 (en) * 2015-06-03 2016-12-08 Saint-Gobain Performance Plastics Corporation Solar control film
US10539726B2 (en) 2015-09-01 2020-01-21 Vitro Flat Glass Llc Solar control coating with enhanced solar control performance
US11402557B2 (en) 2015-09-01 2022-08-02 Vitro Flat Glass Llc Solar control coating with enhanced solar control performance
US20180355485A1 (en) * 2015-12-11 2018-12-13 Michiels Group A method of manufacturing a coated polymer substrate having low emissivity
US10604442B2 (en) 2016-11-17 2020-03-31 Cardinal Cg Company Static-dissipative coating technology
US11325859B2 (en) 2016-11-17 2022-05-10 Cardinal Cg Company Static-dissipative coating technology
WO2019005896A1 (fr) * 2017-06-30 2019-01-03 Saint-Gobain Performance Plastics Corporation Film de protection solaire
CN110741480A (zh) * 2017-06-30 2020-01-31 美国圣戈班性能塑料公司 日光控制膜
US11782198B2 (en) 2017-06-30 2023-10-10 Saint-Gobain Performance Plastics Corporation Solar control film
US11078718B2 (en) 2018-02-05 2021-08-03 Vitro Flat Glass Llc Solar control coatings with quadruple metallic layers
US11885174B2 (en) 2018-02-05 2024-01-30 Vitro Flat Glass Llc Solar control coatings with quadruple metallic layers
US10562812B2 (en) 2018-06-12 2020-02-18 Guardian Glass, LLC Coated article having metamaterial-inclusive layer, coating having metamaterial-inclusive layer, and/or method of making the same
US10830933B2 (en) 2018-06-12 2020-11-10 Guardian Glass, LLC Matrix-embedded metamaterial coating, coated article having matrix-embedded metamaterial coating, and/or method of making the same
US11028012B2 (en) 2018-10-31 2021-06-08 Cardinal Cg Company Low solar heat gain coatings, laminated glass assemblies, and methods of producing same

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AU2003231310B2 (en) 2007-03-29
HK1081940A1 (en) 2006-05-26
US20070116967A1 (en) 2007-05-24
JP2009215168A (ja) 2009-09-24
MXPA04010882A (es) 2005-01-25
RU2342335C2 (ru) 2008-12-27
CA2484181C (fr) 2010-02-23
CN100379699C (zh) 2008-04-09
EP1501768A1 (fr) 2005-02-02
US7910229B2 (en) 2011-03-22
JP2005524598A (ja) 2005-08-18
JP5066323B2 (ja) 2012-11-07
JP5448610B2 (ja) 2014-03-19
WO2003093188A1 (fr) 2003-11-13
RU2004135318A (ru) 2005-06-27
CZ20041076A3 (cs) 2005-03-16
ES2627198T5 (es) 2020-08-21
CA2484181A1 (fr) 2003-11-13
AU2003231310A1 (en) 2003-11-17
CZ307556B6 (cs) 2018-12-05
EP1501768B1 (fr) 2017-04-19
ES2627198T3 (es) 2017-07-27
EP1501768B2 (fr) 2020-02-12

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