US20010032515A1 - Oil-less differential pressure sensor - Google Patents
Oil-less differential pressure sensor Download PDFInfo
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- US20010032515A1 US20010032515A1 US09/780,033 US78003301A US2001032515A1 US 20010032515 A1 US20010032515 A1 US 20010032515A1 US 78003301 A US78003301 A US 78003301A US 2001032515 A1 US2001032515 A1 US 2001032515A1
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- diaphragm
- pressure sensor
- outer periphery
- pressure
- diaphragms
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01L—MEASURING FORCE, STRESS, TORQUE, WORK, MECHANICAL POWER, MECHANICAL EFFICIENCY, OR FLUID PRESSURE
- G01L9/00—Measuring steady of quasi-steady pressure of fluid or fluent solid material by electric or magnetic pressure-sensitive elements; Transmitting or indicating the displacement of mechanical pressure-sensitive elements, used to measure the steady or quasi-steady pressure of a fluid or fluent solid material, by electric or magnetic means
- G01L9/0001—Transmitting or indicating the displacement of elastically deformable gauges by electric, electro-mechanical, magnetic or electro-magnetic means
- G01L9/0007—Transmitting or indicating the displacement of elastically deformable gauges by electric, electro-mechanical, magnetic or electro-magnetic means using photoelectric means
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01L—MEASURING FORCE, STRESS, TORQUE, WORK, MECHANICAL POWER, MECHANICAL EFFICIENCY, OR FLUID PRESSURE
- G01L11/00—Measuring steady or quasi-steady pressure of a fluid or a fluent solid material by means not provided for in group G01L7/00 or G01L9/00
- G01L11/02—Measuring steady or quasi-steady pressure of a fluid or a fluent solid material by means not provided for in group G01L7/00 or G01L9/00 by optical means
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01L—MEASURING FORCE, STRESS, TORQUE, WORK, MECHANICAL POWER, MECHANICAL EFFICIENCY, OR FLUID PRESSURE
- G01L13/00—Devices or apparatus for measuring differences of two or more fluid pressure values
- G01L13/02—Devices or apparatus for measuring differences of two or more fluid pressure values using elastically-deformable members or pistons as sensing elements
- G01L13/025—Devices or apparatus for measuring differences of two or more fluid pressure values using elastically-deformable members or pistons as sensing elements using diaphragms
- G01L13/026—Devices or apparatus for measuring differences of two or more fluid pressure values using elastically-deformable members or pistons as sensing elements using diaphragms involving double diaphragm
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01L—MEASURING FORCE, STRESS, TORQUE, WORK, MECHANICAL POWER, MECHANICAL EFFICIENCY, OR FLUID PRESSURE
- G01L9/00—Measuring steady of quasi-steady pressure of fluid or fluent solid material by electric or magnetic pressure-sensitive elements; Transmitting or indicating the displacement of mechanical pressure-sensitive elements, used to measure the steady or quasi-steady pressure of a fluid or fluent solid material, by electric or magnetic means
- G01L9/0041—Transmitting or indicating the displacement of flexible diaphragms
- G01L9/0051—Transmitting or indicating the displacement of flexible diaphragms using variations in ohmic resistance
- G01L9/0052—Transmitting or indicating the displacement of flexible diaphragms using variations in ohmic resistance of piezoresistive elements
- G01L9/0055—Transmitting or indicating the displacement of flexible diaphragms using variations in ohmic resistance of piezoresistive elements bonded on a diaphragm
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01L—MEASURING FORCE, STRESS, TORQUE, WORK, MECHANICAL POWER, MECHANICAL EFFICIENCY, OR FLUID PRESSURE
- G01L9/00—Measuring steady of quasi-steady pressure of fluid or fluent solid material by electric or magnetic pressure-sensitive elements; Transmitting or indicating the displacement of mechanical pressure-sensitive elements, used to measure the steady or quasi-steady pressure of a fluid or fluent solid material, by electric or magnetic means
- G01L9/0041—Transmitting or indicating the displacement of flexible diaphragms
- G01L9/0072—Transmitting or indicating the displacement of flexible diaphragms using variations in capacitance
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01L—MEASURING FORCE, STRESS, TORQUE, WORK, MECHANICAL POWER, MECHANICAL EFFICIENCY, OR FLUID PRESSURE
- G01L9/00—Measuring steady of quasi-steady pressure of fluid or fluent solid material by electric or magnetic pressure-sensitive elements; Transmitting or indicating the displacement of mechanical pressure-sensitive elements, used to measure the steady or quasi-steady pressure of a fluid or fluent solid material, by electric or magnetic means
- G01L9/0041—Transmitting or indicating the displacement of flexible diaphragms
- G01L9/0072—Transmitting or indicating the displacement of flexible diaphragms using variations in capacitance
- G01L9/0073—Transmitting or indicating the displacement of flexible diaphragms using variations in capacitance using a semiconductive diaphragm
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01L—MEASURING FORCE, STRESS, TORQUE, WORK, MECHANICAL POWER, MECHANICAL EFFICIENCY, OR FLUID PRESSURE
- G01L9/00—Measuring steady of quasi-steady pressure of fluid or fluent solid material by electric or magnetic pressure-sensitive elements; Transmitting or indicating the displacement of mechanical pressure-sensitive elements, used to measure the steady or quasi-steady pressure of a fluid or fluent solid material, by electric or magnetic means
- G01L9/0041—Transmitting or indicating the displacement of flexible diaphragms
- G01L9/0072—Transmitting or indicating the displacement of flexible diaphragms using variations in capacitance
- G01L9/0075—Transmitting or indicating the displacement of flexible diaphragms using variations in capacitance using a ceramic diaphragm, e.g. alumina, fused quartz, glass
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01L—MEASURING FORCE, STRESS, TORQUE, WORK, MECHANICAL POWER, MECHANICAL EFFICIENCY, OR FLUID PRESSURE
- G01L9/00—Measuring steady of quasi-steady pressure of fluid or fluent solid material by electric or magnetic pressure-sensitive elements; Transmitting or indicating the displacement of mechanical pressure-sensitive elements, used to measure the steady or quasi-steady pressure of a fluid or fluent solid material, by electric or magnetic means
- G01L9/0041—Transmitting or indicating the displacement of flexible diaphragms
- G01L9/0076—Transmitting or indicating the displacement of flexible diaphragms using photoelectric means
Definitions
- the present invention relates to differential pressure sensors. More specifically, the present invention relates to differential pressure sensors which measure pressure based upon diaphragm deflection.
- a differential pressure sensor is configured to respond to a differential pressure, that is, the difference between two pressures.
- One technique which is used to measure differential pressure is through a deflectable diaphragm.
- a first pressure is applied to one side of the diaphragm and a second pressure is applied to the other side of the diaphragm.
- the deflection of the diaphragm is proportional to the difference between the two applied pressures.
- Diaphragm deflection can be measured by configuring the diaphragm so that it acts as a plate of a capacitor.
- the capacitance of the diaphragm assembly changes based upon the diaphragm position. Therefore, capacitance can be related to diaphragm position which in turn is representative of the differential pressure applied to the diaphragm.
- Pressure sensors frequently operate in harsh environments. Such environments can cause failure in highly accurate pressure sensors which tend to be quite delicate.
- One technique which has been used to isolate the pressure sensor is to isolate the pressure sensor from the fluid (also called “process fluid”) whose pressure is being measured.
- One such technique uses an isolation diaphragm in which process fluid is on one side of isolation diaphragm and isolation fluid is on the other side. The isolation fluid contacts the pressure sensor diaphragm. As the process fluid pressure changes, the isolation diaphragm, responsively deflects which causes the change in pressure to be transferred through the isolation fluid to the sensor diaphragm.
- the isolation fluid in the diaphragm can introduce errors in pressure measurements and can be altered over time or due to application of heat or other external influences. Further, the fluid can leak with time which can result in reduced fluid volume or fill fluid which has been contaminated by process fluid.
- a pressure sensor for measuring a pressure difference between two fluids which does not require isolation fluid.
- the pressure sensor includes a diaphragm support member having an outer periphery and diaphragms coupled thereto. Movement of the diaphragms are the movement of a moveable member. The movement can be sensed to determine the applied differential pressure.
- the coupling member is joined to the outer periphery with a web. The web is recessed from opposed outwardly facing surfaces of the outer periphery, and first and second diaphragms disposed on opposite sides of the diaphragm support member. Each diaphragm is joined to the outer periphery and to the coupling member.
- FIG. 1 is a side cross-sectional view of a pressure sensor in accordance with one embodiment.
- FIG. 1A is an enlarged cross-sectional view showing a portion of a pressure sensor in accordance with another embodiment.
- FIGS. 2 and 3 are top plan views of portions of the pressure sensor of FIG. 1.
- FIG. 4 is a side cross-sectional view of another pressure sensor.
- FIGS. 5 and 6 are top plan views of portions of the pressure sensor of FIG. 4.
- FIG. 7 is a cross-sectional view of pressure sensor in accordance with another embodiment.
- FIG. 8 is a cross-sectional view of pressure sensor in accordance with another embodiment.
- FIGS. 9 and 10 are top plan views of portions of the pressure sensor of FIG. 8.
- FIG. 11 is a perspective view of a pressure sensor.
- FIG. 12 is a cross-sectional view of the pressure sensor of FIG. 11 taken along the line labeled 12 - 12 .
- FIGS. 12A, 12B and 12 D are top plan views of portions of the pressure sensor of FIG. 11.
- FIG. 12C is a schematic diagram of the pressure sensor of FIG. 11.
- FIG. 13 is a top plan view of a pressure sensor in accordance with another embodiment.
- FIG. 14 is a side cross-sectional view of the pressure sensor of FIG. 13 taken along the line labeled 13 - 13 .
- FIG. 15 is an enlarged plan view of a portion of the pressure sensor of FIG. 13.
- FIG. 16 is a graphical illustration of distances formed between components of the pressure sensor of FIG. 13.
- FIG. 17 is a side cross-sectional view of a pressure sensor in accordance with another embodiment.
- FIG. 18 is a simplified schematic diagram of a pressure transmitter.
- FIG. 19 is a side cross-sectional view of a pressure transmitter.
- a first embodiment of an oil-less pressure sensor is indicated at 10 .
- the pressure sensor 10 includes two diaphragm support structures 12 having bore 14 .
- Isolator diaphragms 16 A and 16 B are mounted to opposite sides of the diaphragm support structure 12 , while in the embodiment illustrated, portions 18 A and 18 B are secured together to form a rigid coupling moveable member 20 extending within the bore 14 .
- the isolator diaphragms 16 A and 16 B are secured, the diaphragm support structure 12 on outer peripheries or rims 22 A and 22 B to form corresponding annular cavities 24 A and 24 B that open to and are about an axis 15 of the bore 14 .
- the annular cavities 24 A and 24 B provide space between opposed surfaces of each of the isolator diaphragms 16 A and 16 B, and the diaphragm support structure 12 . This, in turn, allows the isolator diaphragms 16 A and 16 B to deflect relative to the diaphragm support structure 12 in response to a difference in pressures P 1 and P 2 , while providing inherent overtravel protection.
- the rigid coupling member 20 formed by portions 18 A and 18 B couples the isolator diaphragms 16 A and 16 B together and replaces an incompressible fluid commonly used in differential pressure sensors.
- the diaphragm support structure 12 and the isolator diaphragms 16 A and 16 B define a cavity 26 comprising the bore 14 and annular cavities 24 A and 24 B that can be completely isolated and sealed from the external environment.
- the inside of the cavity 26 can be evacuated or filled with an inert gas. However, the cavity 26 need not be evacuated and can be left at gauge pressure. Since the cavity 26 is substantially isolated, changes in environmental conditions will have less of an effect on sensing elements mounted within the cavity 26 to measure displacement of the isolator diaphragms 16 A and 16 B relative to the diaphragm support structure 12 . In addition, dust particles cannot easily enter the cavity 26 .
- a capacitive sensing device 28 provides a signal indicative of displacement of each of the isolator diaphragms 16 A and 16 B relative to the diaphragm support structure 12 .
- the capacitive sensing device 28 includes metallized-ring electrodes 30 A, 30 B, 32 A and 32 B that form capacitors 31 and 33 . Since isolator diaphragms 16 A and 16 B are rigidly coupled together through coupling member 20 , a capacitance of the capacitor 31 formed by metallized-ring electrodes 30 A and 30 B varies inversely with a capacitance of the capacitor 33 formed by metallized-ring electrodes 32 A and 32 B.
- capacitive sensing device 28 is but one suitable sensor to measure displacement of isolator diaphragms 16 A and 16 B relative to diaphragm support structure 12 .
- Other capacitive sensing devices can be used.
- Other suitable sensing devices that can be used to include piezoresistive or piezoelectric strain gauges, optical or acoustical sensing devices operably coupled to the isolator diaphragms 16 A and 16 B, and/or the diaphragm support structure 12 , as appropriate.
- An embodiment using an optical sensor is illustrated in co-pending patent application Ser. No. ______, entitled “OPTICAL PRESSURE SENSOR”, filed on even date herewith and herein incorporated by reference.
- FIG. 1A shows another example of one configuration for capacitive electrodes 30 A and 30 B.
- a notched region 23 is formed in rims 22 A and a complementary ledge is formed in moveable member 20 each carrying electrodes 30 B and 30 A, respectively.
- This configuration can be done official because it is not sensitive to errors which can arise into localized deflection in a diaphragm. Such localized deflection can occur in response to a large absolute pressure and are not related to the differential pressure. These localized deflections can cause errors in the configuration shown in FIG. 1.
- the electrodes 30 A, 30 B are positioned such that the capacitance is only sensitive to movement of a moveable member 20 .
- the isolator diaphragms 16 A and 16 B are made of chemically resistant material that does not abrade in order that the isolator diaphragms 16 A and 16 B can directly receive the process fluids to be measured.
- the isolator diaphragms 16 A and 16 B can be made from a single crystal corundum such as “sapphire” or “ruby” containing chromium.
- the diaphragm support structure 12 can also be made from the same material as the isolator diaphragms 16 A and 16 B, and can be directly fusion bonded to the isolator diaphragms 16 A and 16 B on the rims 22 A and 22 B at a temperature lower than the melting point of the material used to form these components.
- crystalline materials such as sapphire are used, the resulting structure of the pressure sensor 10 behaves elastically without hysteresis.
- Other suitable materials include spinels, zirconia and silicon. If the material is conductive, an electrical insulator can be used such as an oxide.
- Direct bonding of the rims 22 A and 22 B to the corresponding isolator diaphragms 16 A and 16 B typically requires that each of the bonding surfaces be atomically smooth.
- An alternative method of attachment includes depositing a glass or suitable metallic solder (preferably having a thermal expansion coefficient similar to the diaphragm support structure 12 and the isolator diaphragms 16 A and 16 B) on the rims 22 A and 22 B and/or the opposing surfaces of the isolator diaphragms 16 A and 16 B.
- a seal is formed between the rims 22 A and 22 B and the corresponding isolator diaphragms 16 A and 16 B. Since the seal forms an interface layer between the rims 22 A and 22 B and the isolator diaphragms 16 A and 16 B, atomically smooth surfaces are not required.
- the diaphragm support structure 12 includes substantially identical base members 40 A and 40 B secured together on planar surfaces 42 A and 42 B, respectively.
- Each base member 40 A and 40 B includes an aperture 44 A and 44 B, respectively, aligned with each other to form the bore 14 .
- Annular cavities 24 A and 24 B are formed by providing recessed surfaces 46 A and 46 B on the base members 40 A and 40 B below the outer peripheries 22 A and 22 B and about the apertures 44 A and 44 B.
- the metallized-ring electrodes 30 B and 32 B are provided on the recessed surfaces 46 A and 46 B, respectively.
- a suitable channel or recess 48 is provided in each of the base member 3 40 A and 40 B to allow a conductive lead 50 to extend from the metallized-ring electrodes 30 B and 32 B to an outer edge of the pressure sensor 10 .
- FIGS. 1 and 3 illustrate the isolator diaphragm 16 A.
- the metallized electrode 30 A includes a conductive lead 54 that extends through a recess 55 provided in the base member 40 A (FIG. 2).
- the isolator diaphragm 16 A is substantially identical to the isolator diaphragm 16 B. In this manner, only two unique components (i.e. the isolator diaphragms 16 A and 16 B and the base members 40 A and 40 B) need be manufactured and assembled to form the pressure sensor 10 .
- the base members 40 A and 40 B can be simple blocks of material, while the isolator diaphragms 16 A and 16 B have corresponding rims to form the annular cavities 24 A and 24 B.
- the pressure sensor 10 is formed from sapphire or other similar crystalline materials
- a suitable method of fabrication would include first micro-machining the isolator diaphragms 16 A and 16 B, and the base members 40 A and 40 B (or the diaphragm support structure 12 if the base member 40 A and 40 B are integrally joined together).
- Suitable micromachining techniques include wet or dry chemical etching, and ion or ultrasonic milling techniques.
- the metallized-ring electrodes 30 A, 30 B, 32 A and 32 B can then be deposited on the isolator diaphragms 16 A and 16 B, and the base members 40 A and 40 B by a variety of means, for example, electroless plating, evaporation or sputtering.
- any or all of the electrodes 30 A, 30 B, 32 A, 32 B, and electrodes described below can comprise ion implanted electrically conductive layers or portions.
- the pressure sensor 10 can then be assembled by first securing the isolator diaphragm 16 A to the base member 40 A, and then securing the isolator diaphragm 16 B to the base member 40 B.
- the base members 40 A and 40 B can then be secured along surfaces 42 A and 42 B, which would also form the coupling member 20 by securing the portion 18 A to the portion 18 B.
- Using separate base members 40 A and 40 B, which are later bonded together, is particularly advantageous because each of the components, the isolator diaphragms 16 A and 16 B and the base members 40 A and 40 B, need only be machined on one side thereof.
- isolator diaphragms 16 A and 16 B are preferably substantially identical for the reasons discussed above, if desired, the isolator diaphragms 16 A and 16 B can be machined differently.
- the portions 18 A and 18 B can be of different length such that one of the portions 18 A or 18 B extends further within the bore 14 or out of the bore 14 .
- FIGS. 4 - 6 illustrate a pressure sensor 70 according to a second embodiment of the present invention. Parts corresponding to those in FIGS. 1 - 3 are designated with the same reference numerals. Briefly, the second embodiment differs from the first embodiment in that the former is provided with a sensing device 72 to provide an output signal indicative of line pressures p 1 and P 2 .
- the sensing device 72 comprises two capacitors formed by metallized-ring electrodes 80 A, 80 B, 82 A and 82 B.
- the metallized-ring electrodes 80 B and 82 B are recessed surfaces of base members 40 A and 40 B, respectively, while the metallized-ring electrodes 80 A and 82 A are provided on planar surfaces of the isolator diaphragms 16 A and 16 B to face the metallized-ring electrodes 80 B and 82 B, respectively.
- the capacitor formed by metallized-ring electrodes 80 A and 80 B senses or measures displacement of a portion 73 A of the isolator diaphragm 16 A relative to the diaphragm support structure 12 .
- the capacitor formed by metallized-ring electrodes 82 A and 82 B senses or measures a portion 73 B of the isolator diaphragm 16 B relative to the diaphragm support structure 12 . Since the diaphragm support structure 12 is fixed or stationary, deflection of the portions 73 A or 73 B relative to the diaphragm support structure 12 provides an indication of line pressures P 1 and P 2 . If desired, the metallized-ring electrodes 80 A and 82 A can be provided in suitable recesses in the isolator diaphragms 16 A and 16 B.
- FIG. 5 is a plan view illustrating the position of the metallized-ring electrode 80 B upon the base member 40 A with respect to the metallized-ring electrode 30 B.
- the metallized-ring electrode 80 B includes spaced-apart conductive leads 88 A and 88 B so as to allow the conductive lead 50 of the metallized-ring electrode 30 B to extend therebetween.
- the metallized-ring electrode 80 A is positioned as illustrated in FIG. 6 and also includes spaced-apart conductive leads 90 A and 90 B on either side of the conductive lead 54 .
- suitable circuitry can be connected to the spaced-apart conductive leads 90 A and 90 B of the metallized-ring electrode 80 A to measure the resistance thereof and provide an indication as to the temperature of the isolator diaphragm 16 A, and thus, an indication of the temperature of the process fluid exerting the pressure P 1 .
- the isolator diaphragm 16 B and the base member 40 B are substantially identical to the isolator diaphragm 16 A and the base member 40 A, respectively, so the metallized ring electrode 82 A can be used to provide an indication of the temperature of process fluid exerting the pressure P 2 .
- FIG. 7 illustrates a pressure sensor according to a third embodiment of the present invention at 94 .
- the third embodiment differs from the second embodiment in that the former is provided with reinforced isolator diaphragms 16 A and 16 B.
- each isolator diaphragm 16 A and 16 B includes a center region 96 A and 96 B, respectively, of increased thickness to minimize high line pressure effects.
- Portions 18 A and 18 B extend from the center regions 96 A and 96 B, respective, and are preferably integrally formed therewith.
- a fourth embodiment of an oil-less pressure sensor is indicated at 100 in FIGS. 8 - 10 .
- the oil-less pressure sensor 100 includes a diaphragm support structure 102 having a rigid coupling member 104 .
- Isolator diaphragms 106 A and 106 B are mounted to opposite sides of the diaphragm support structure 102 and the rigid coupling member 104 .
- the isolator diaphragms 106 A and 106 B each include center regions 103 A and 103 B of increased thickness to reduce high line pressure effects.
- the diaphragms support structure 102 includes an outer periphery or rim 108 .
- the isolator diaphragm 106 A is secured to a surface 108 A of the outer periphery 108 and to a surface 104 A of the rigid coupling member 104 .
- the isolator diaphragm 106 B is secured to a surface 108 B of the outer periphery 108 and a surface 104 B of the rigid coupling member 104 .
- the oil-less pressure sensor 100 includes three principle components, the diaphragm support structure 102 and the isolator diaphragms 106 A and 106 B. Accordingly, only two sets of fusion bonds need to be made in order to assemble the oil-less pressure sensor 100 Specifically, a first set of fusion bonds formed at 104 A and 108 A secure the isolator diaphragm 106 A to the rigid coupling member 104 and the outer periphery 108 , respectively. A second set of fusion bonds formed at 104 B and 108 B secure the isolator diaphragm 106 B to the rigid coupling member 104 and to the outer periphery 108 , respectively.
- FIG. 9 illustrates the position of the metallized-ring electrodes 30 B and 80 B with a recess or channel 105 provided for the conductive leads 50 , 88 A and 88 B.
- FIG. 10 illustrates the position of metallized-ring electrodes 30 A and 80 A on the isolator diaphragm 106 A.
- a recess or channel 109 (FIG. 9) is provided for the conductive leads 54 , 90 A and 90 B.
- Isolator diaphragm 106 B is constructed substantially identical to isolator diaphragm 106 A.
- the diaphragm support assembly 102 includes at least one thin web 112 extending from the outer periphery 108 to integrally join the rigid coupling member 104 to the outer periphery 108 .
- the web 112 holds the rigid coupling member 104 in position during bonding of the isolator diaphragms 106 A and 106 B to the rigid coupling member 104 .
- a plurality of webs 112 extend from different portions of the outer periphery 108 .
- a solid thin web or disc can extend completely around the rigid coupling member 104 and can be used instead of individual webs 112 .
- webs 112 extend from a recessed support 120 that is integrally formed with the outer periphery 108 .
- the recessed support 120 further supports the metallized-ring electrodes 30 B and 32 B.
- any or all of the webs 112 can be broken after the isolator diaphragms 106 A and 106 B have been secured to the rigid coupling member 104 in order to reduce stiffness.
- the webs 112 can be removed using ultrasonic agitation or lasers.
- FIGS. 11 and 12 illustrate a fifth embodiment of an oil-less differential pressure 124 of the present invention.
- the pressure sensor 124 includes a diaphragm support structure 126 having a bore 127 .
- Isolator diaphragms 128 A and 128 B are mounted to opposite sides of the diaphragm support structure 126 , and have portions 129 A and 129 B that are secured together to form a rigid coupling member 130 extending within the bore 127 .
- the portion 129 A is integrally joined to an outer periphery portion 131 A of the isolator diaphragm 128 A with at least one and preferably a plurality of thin webs 132 .
- the webs 132 reduce the stiffness of the isolator diaphragm 128 A, allowing it to deflect more easily.
- the webs 132 hold the portion 129 A in alignment with the portion 129 B when the isolator diaphragms 128 A and 128 B are secured together and to the diaphragm support structure 126 .
- the isolator diaphragm 128 B is similarly constructed. After the isolator diaphragms 128 A and 128 B have been secured to the diaphragm support structure 126 , pressure receiving caps 134 A and 134 B, to be described below, are secured to isolator diaphragms 128 A and 128 B, respectively. The webs 132 can then be broken in order to separate the rigid coupling member 130 from the isolator diaphragms 128 A and 1283 .
- a capacitive sensing device 136 measures displacement of the rigid coupling member 130 .
- the capacitive sensing device 136 forms two equivalent capacitors 135 A and 135 B that have capacitance values which vary inversely as a function of the difference in pressure between P 1 and P 2 .
- the capacitor 135 A includes a first electrode 137 A formed on the diaphragm support structure 126 , a second electrode 137 B formed on the diaphragm support structure 126 and a third electrode 137 C formed on the portion 129 A of the isolator diaphragm 128 A
- the electrodes 137 A- 137 C form two capacitors 139 A and 139 B
- the capacitors 139 A and 139 B together are equivalent to a single capacitor that has a capacitance which varies in response to displacement of the coupling member 130 relative to the diaphragm support structure 126 .
- the electrode 137 C comprises a metallized-ring formed about the portion 129 A.
- the electrode 137 C faces the electrodes 137 A and 137 B, which are illustrated in FIG. 12B.
- the capacitor 135 B has output terminals (the conductive leads 141 A and 141 B) formed on the same surface.
- the capacitive sensing device 136 B is formed similar to the capacitive sensing device 136 A.
- a first electrode 145 A is provided on the diaphragm support structure 126
- a second electrode 145 B is provided on the diaphragm support structure 126
- a third electrode 145 C is provide on the portion 129 B.
- the diaphragm support structure 126 includes substantially identical base members 148 A and 148 B that are secured together on planar surfaces represented by dashed line 149 .
- Pressure receiving end caps 134 A and 134 B form another aspect of the present invention.
- a stress relieving annular groove or recess 150 A separates the pressure receiving end cap 134 A into a flexing assembly 151 A and an outer periphery or rim 153 A.
- the flexing assembly 151 A comprises a plate portion 154 A, a cylindrical tube 155 A that joins the plate portion 154 A to the outer rim 153 A, and a center coupling member 156 A that joins the plate portion 154 A to the portion 129 A of the isolator diaphragm 128 A.
- FIG. 12D illustrates, in plan view, the pressure receiving end cap 134 A.
- the pressure receiving end cap 134 B is formed substantially identical to the pressure receiving end cap 134 A wherein an annular groove 150 B provides a flexing assembly 151 B and an outer rim 153 B.
- a second annular groove 159 A forms a plate portion 154 B, a cylindrical tube 155 B and a center coupling member 156 B.
- the pressure receiving end caps 134 A and 134 B provides stress isolation and deflection amplification.
- O-rings 162 A and 162 B or other suitable connection means such as a braze, engage the outer rims 153 A and 153 B, respectively, and provide seals to contain the process fluids exerting the pressure P 1 and P 2 , respectively.
- Stress isolation is provided because the flexing assemblies 151 A and 151 B can move with respect to outer rims 153 A and 153 B.
- Deflection amplification occurs due to compression of the center coupling members 156 A and 156 B along with corresponding deflection of the cylindrical tubes 155 A and 155 B.
- the diaphragm support structure 126 , the isolator diaphragms 128 A and 128 B and the pressure receiving end caps 134 A and 134 B can be formed from any of the materials discussed above with respect to the previous embodiments.
- the pressure receiving end caps 134 A and 134 B are formed from Lucalox®, a polycrystalline aluminum ceramic material, available from GE Company of Fairfield, Conn. The Lucalox® is less expensive then other materials, such as sapphire. In addition, this material can be cast or machined.
- FIGS. 13, 14, 15 and 16 illustrate a sixth embodiment of an oil-less pressure sensor of the present invention generally indicated at 180 .
- the oil-less pressure sensor 180 includes a diaphragm support structure 182 and isolator diaphragms 186 A and 186 B that receive pressures P 1 and P 2 , respectively.
- the diaphragm support structure 182 includes a plurality of apertures 188 through which rigid coupling members 190 extend and are secured to the isolator diaphragms 186 A and 186 B.
- FIG. 15 is an enlarged plan view of a single aperture 188 and a single coupling member 190 .
- the isolator diaphragms 186 A and 186 B are further secured to an outer periphery 192 on surfaces 192 A and 192 B, respectively.
- An overstop member 194 is formed within the diaphragm support assembly 192 under movable portions of the isolator diaphragms 186 A and 186 B.
- the overstop member 194 includes the plurality of apertures 188 through which the rigid coupling members 190 extend.
- a suitable sensing device 196 is provided to measure displacement of isolator diaphragms 186 A and 186 B relative to the overstop member 194 .
- the sensing device 196 comprises two capacitors 197 A and 197 B.
- the capacitor 197 A includes an electrode 198 A formed on at least a portion of the overstop member 194 facing the isolator diaphragm 186 A.
- the electrode 198 A surrounds many of the plurality of the apertures 188 on the overstop member 194 .
- a movable electrode 198 B is formed on a surface 200 of the isolator diaphragm 186 A, preferably in a pattern about the apertures 188 corresponding to the pattern of the electrode 198 A on the overstop member 194 .
- Suitable channels are recessed below the surface 192 A in an outer periphery or rim 203 to allow conductive leads of the electrodes 198 A and 198 B to extend to an outer edge of the diaphragm support structure 192 .
- a capacitor 197 B is formed in a manner similar to the capacitor 197 A to measure displacement of the isolator diaphragm 186 B relative to the overstop member 194 .
- An electrode 202 A similar to electrode 198 A is provided on a surface of the overstop member 194 to face an inner surface 204 of the isolator diaphragm 186 B.
- a second electrode 202 B is formed on the inner surface 204 of the isolator diaphragm 186 B and faces the electrode 202 A.
- Suitable channels are provided in the outer periphery 203 , allowing conductive leads from the electrodes 202 A and 202 B to extend to the outer edge of the diaphragm support structure 192 .
- thin webs generally indicated at 206 hold the rigid coupling members 190 in position during fastening of the isolators diaphragms 186 A and 186 B to the rigid coupling members 190 .
- a subset of webs 206 A of the plurality of webs 206 extend from the outer periphery 203 and are integrally formed with the a subset of rigid coupling members 190 A of the plurality of rigid coupling members 190 .
- the remaining rigid coupling members 190 are held in position by the webs 206 extending from other portions of the overstop member 194 .
- the position of the webs 206 along the length of the rigid coupling members 190 can be varied as desired; however, positioning the webs 206 at the center of each coupling member 190 may be preferable in order to maintain symmetry of the rigid coupling member 190 during machining or etching when the diaphragm support structure 192 is made from a crystalline material such as sapphire. However, if the webs 206 are positioned closer to either end of the coupling members 190 , stiffness may be reduced. In order to further reduce the stiffness of the oil-less pressure sensor 180 , the webs 206 can be removed or broken after the isolator diaphragms 186 A and 186 B have been bonded to each of the rigid coupling members 190 . Ultrasonic agitation or use of lasers can be used to remove the webs 206 . If the webs 206 are positioned at one or both ends of each coupling members 190 , the webs 206 may be removed easier.
- the diaphragm support structure 192 can be made from a crystalline material such as sapphire.
- suitable materials include ruby, zirconia, silicon, silicon-carbide ceramic, zirconium, oxide ceramic, cermet ceramic, spinels and metals such as stainless steel.
- the isolator diaphragms 186 A and 186 B are formed of the same material used for the diaphragm support structure 192 , although this is not necessary. However, if the diaphragm support structure 192 and the isolator diaphragms 186 A and 186 B are made from different materials, it is preferable that the materials have similar thermal expansion coefficients in order to minimize stress induced effects.
- Displacement of either the isolator diaphragms 186 A or 186 B is limited by contact with the overstop member 194 .
- a distance between the inner surfaces 200 and 204 and corresponding surfaces of the overstep member 194 can be constant throughout, in a preferred embodiment, the distance varies approximately to the spherical deflection of the isolator diaphragms 186 A and 186 B.
- FIG. 16 graphically illustrates distances formed between the overstop member 194 and each of the isolator diaphragms 186 A and 186 B. In FIG. 16, the greatest distance is found at a portion 211 , while the least distance is found at portions 212 .
- the coupling members 190 have ends that are coplanar with surfaces 192 A and 192 B, which simplifies fabrication.
- FIG. 17 illustrates an alternative embodiment of an oil-less pressure sensor 218 where recessed surfaces 220 A and 220 B of varying depth are provided in the isolator diaphragms 224 A and 224 B.
- surfaces of a diaphragm support structure 226 and ends of rigid coupling members 228 are also substantially coplanar.
- These structures can be fabricated using any appropriate technique. Various machining, etching and deposition techniques are known in the art and may be used to fabricate the pressure sensor.
- FIG. 18 is a simplified schematic diagram of a pressure transmitter having a circuit 400 for sensing the differential pressure applied to any of the above-described pressure sensors.
- the circuit 400 includes the first capacitor C 1 , for example, capacitor 31 , and a second capacitor C 2 , for example, capacitor 33 .
- the capacitor C 1 is driven by a square wave generator 402
- the capacitor C 2 is driven by a square wave generator 404 .
- An inverting input of a low noise differential amplifier 406 is connected to the undriven plates of capacitors C 1 and C 2 , and a non-inverting input of the differential amplifier 406 is connected to electrical ground.
- the differential amplifier 406 has negative feedback through a capacitor 408 and has charge ⁇ Q from capacitors C 1 . and C 2 flowing in and out of the inverting input.
- the output of the differential amplifier 406 is a square wave representative of differential capacitance, which is converted into a digital format by A/D converter 410 .
- AQ is given as:
- the amplifier output is:
- Circuit 400 is but one suitable circuit for measuring capacitance of the capacitors C 1 and C 2 .
- Other known circuits can also be used.
- Interface circuitry 412 is connected to a 4-20 mA current loop 414 and provides the digital signal A/D converter 410 to the current loop 414 in either a digital or analog format. Interface circuitry 412 also provides power to circuit 400 from the current loop 414 . Interface circuitry 412 is also capable of receiving commands, such as those pursuant to the HART® communications standard.
- Circuit 400 can also be used to measure the capacitance of the line pressure capacitors.
- capacitor C LP1 represents the capacitor used to measure pressure P 1
- capacitor C LP2 is used to measure pressure P 2 .
- analog switches 416 A and 416 B and 416 C are operated so as to connect the line pressure capacitors C LP1 and C LP2 and a known reference capacitor C R to the square wave generators 402 and 404 and the differential amplifier 406 .
- Analog switch 418 is operated in order to initiate measurement of capacitor C LP1 or C LP2 .
- the afore-mentioned equations apply wherein C 1 is replaced by either C LP1 or C LP2 and C 2 is replaced by C R .
- FIG. 19 illustrates a pressure transmitter 450 suitable for supporting any previously described oil-less differential pressure sensors of the present invention.
- an embodiment of the oil-less differential pressure sensor of the present invention is indicated at 452 .
- Pressures P 1 and P 2 are fluidly coupled directly to the pressure sensor 452 by suitable tubes 454 A and 454 B respectively.
- the tubes 454 A and 454 B are relatively long compared to their diameters so as to provides stress isolation between the pressure sensor 452 and a housing member 456 .
- the tubes 454 A and 454 B are made of a suitably corrosion proof material, which has a thermal expansion coefficient similar to the pressure sensor 452 . If, for example, the pressure sensor 452 is made of sapphire, the tubes 454 A and 454 B can be made of sapphire, aluminum oxide, or a suitable metal or metal alloy.
- the tubes 454 A and 454 B are secured to the housing member 456 by suitable corrosion resistant brazes, indicated at 458 A and 458 B.
- a path length indicated by double arrow 460 is preferably long enough to provide corrosion resistance.
- the brazes 458 A and 458 B can be further protected by an electroplated coating of a highly corrosion resistant metal such as platinum or iridium.
- a process connector or flange 462 is secured to the housing member 456 with suitable fasteners indicated at 464 .
- the flange 462 includes fittings 466 A and 466 B connectable to process lines carrying the process fluids to be measured.
- the tubes 454 A and 454 B are attached to the pressure sensor 452 with a corrosion resistant connection indicated at 470 .
- the corrosion resistant connection 470 can be a braze wherein an inner surface off the braze, exposed to the process fluids, is protected by electroplated platinum, iridium, or other suitable metal.
- the corrosion resistant connection 470 can also be a fusion bond between the sensor 452 and the tubes 454 A and 454 B.
- the corrosion resistant connection 470 can also be a fired sol-gel based coating of a ceramic material, such as aluminum oxide sol-gel used to make a joint between the sensor 452 made of sapphire and the tubes 454 A and 454 B made of sapphire or aluminum oxide.
- a particular advantage of the oil-less differential pressure sensor and corresponding pressure transmitter of the present invention is that no intermediate isolator diaphragms are required to measure the pressures P 1 and P 2 . This significantly simplifies design and reduces manufacturing costs.
- a process barrier 472 is mounted within the housing member 456 to form a cavity 474 that prevents process fluid from escaping the housing member 456 , should any fluid connection fail.
- the cavity 474 can be a vacuum, filled with an inert gas, or filled with another suitable material.
- Feed-throughs 476 A, 476 B, 476 C and 476 D provide electrical pathways across the process barrier 472 , connecting the pressure sensor 452 to a circuit board 478 . If desired, two of the leads from the pressure sensor 452 can be made common, which would then only require three feed-throughs. If the pressure sensor 452 includes line pressure sensors, additional feed-throughs may be necessary.
- Circuit board 478 receives electrical signals from the pressure sensor 452 related to pressures P 1 and P 2 .
- the circuit board 458 includes differential amplifier 406 , A/D converter 410 and other suitable devices to digitize and process these signals.
- the circuit board 478 communicates pressure information to the interface circuitry 412 using a data bus 480 .
- the circuit board 478 is supported in an upper portion 482 of the housing member 456 .
- a second housing member 484 mates with the housing member 456 to form an enclosure. Removable covers 486 A and 486 B provide access to the interface circuitry 412 when desired.
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Abstract
A pressure sensor is provided for measuring a pressure difference between two fluids which does not require isolation fluid. The pressure sensor includes a diaphragm support member having an outer periphery and diaphragms coupled thereto. Movement of the diaphragms are the movement of a moveable member. The movement can be sensed to determine the applied differential pressure. The coupling member is joined to the outer periphery with a web. The web is recessed from opposed outwardly facing surfaces of the outer periphery, and first and second diaphragms disposed on opposite sides of the diaphragm support member. Each diaphragm is joined to the outer periphery and to the coupling member.
Description
- The present application is based on and claims the benefit of U.S. provisional patent application Ser. No. 60/181,866, filed Feb. 11, 2000, the content of which is hereby incorporated by reference in its entirety.
- The present invention relates to differential pressure sensors. More specifically, the present invention relates to differential pressure sensors which measure pressure based upon diaphragm deflection.
- Pressure sensors are used to measure pressures. A differential pressure sensor is configured to respond to a differential pressure, that is, the difference between two pressures.
- One technique which is used to measure differential pressure is through a deflectable diaphragm. A first pressure is applied to one side of the diaphragm and a second pressure is applied to the other side of the diaphragm. The deflection of the diaphragm is proportional to the difference between the two applied pressures. Diaphragm deflection can be measured by configuring the diaphragm so that it acts as a plate of a capacitor. The capacitance of the diaphragm assembly changes based upon the diaphragm position. Therefore, capacitance can be related to diaphragm position which in turn is representative of the differential pressure applied to the diaphragm.
- Pressure sensors frequently operate in harsh environments. Such environments can cause failure in highly accurate pressure sensors which tend to be quite delicate. One technique which has been used to isolate the pressure sensor is to isolate the pressure sensor from the fluid (also called “process fluid”) whose pressure is being measured. One such technique uses an isolation diaphragm in which process fluid is on one side of isolation diaphragm and isolation fluid is on the other side. The isolation fluid contacts the pressure sensor diaphragm. As the process fluid pressure changes, the isolation diaphragm, responsively deflects which causes the change in pressure to be transferred through the isolation fluid to the sensor diaphragm. However, the isolation fluid in the diaphragm can introduce errors in pressure measurements and can be altered over time or due to application of heat or other external influences. Further, the fluid can leak with time which can result in reduced fluid volume or fill fluid which has been contaminated by process fluid.
- A pressure sensor is provided for measuring a pressure difference between two fluids which does not require isolation fluid. The pressure sensor includes a diaphragm support member having an outer periphery and diaphragms coupled thereto. Movement of the diaphragms are the movement of a moveable member. The movement can be sensed to determine the applied differential pressure. The coupling member is joined to the outer periphery with a web. The web is recessed from opposed outwardly facing surfaces of the outer periphery, and first and second diaphragms disposed on opposite sides of the diaphragm support member. Each diaphragm is joined to the outer periphery and to the coupling member.
- FIG. 1 is a side cross-sectional view of a pressure sensor in accordance with one embodiment.
- FIG. 1A is an enlarged cross-sectional view showing a portion of a pressure sensor in accordance with another embodiment.
- FIGS. 2 and 3 are top plan views of portions of the pressure sensor of FIG. 1.
- FIG. 4 is a side cross-sectional view of another pressure sensor.
- FIGS. 5 and 6 are top plan views of portions of the pressure sensor of FIG. 4.
- FIG. 7 is a cross-sectional view of pressure sensor in accordance with another embodiment.
- FIG. 8 is a cross-sectional view of pressure sensor in accordance with another embodiment.
- FIGS. 9 and 10 are top plan views of portions of the pressure sensor of FIG. 8.
- FIG. 11 is a perspective view of a pressure sensor.
- FIG. 12 is a cross-sectional view of the pressure sensor of FIG. 11 taken along the line labeled12-12.
- FIGS. 12A, 12B and12D are top plan views of portions of the pressure sensor of FIG. 11.
- FIG. 12C is a schematic diagram of the pressure sensor of FIG. 11.
- FIG. 13 is a top plan view of a pressure sensor in accordance with another embodiment.
- FIG. 14 is a side cross-sectional view of the pressure sensor of FIG. 13 taken along the line labeled13-13.
- FIG. 15 is an enlarged plan view of a portion of the pressure sensor of FIG. 13.
- FIG. 16 is a graphical illustration of distances formed between components of the pressure sensor of FIG. 13.
- FIG. 17 is a side cross-sectional view of a pressure sensor in accordance with another embodiment.
- FIG. 18 is a simplified schematic diagram of a pressure transmitter.
- FIG. 19 is a side cross-sectional view of a pressure transmitter.
- A first embodiment of an oil-less pressure sensor is indicated at10. Generally, the pressure sensor 10 includes two
diaphragm support structures 12 havingbore 14.Isolator diaphragms diaphragm support structure 12, while in the embodiment illustrated,portions moveable member 20 extending within thebore 14. In addition, theisolator diaphragms diaphragm support structure 12 on outer peripheries orrims annular cavities bore 14. Theannular cavities isolator diaphragms diaphragm support structure 12. This, in turn, allows theisolator diaphragms diaphragm support structure 12 in response to a difference in pressures P1 and P2, while providing inherent overtravel protection. Therigid coupling member 20 formed byportions isolator diaphragms - The
diaphragm support structure 12 and theisolator diaphragms cavity 26 comprising thebore 14 andannular cavities cavity 26 can be evacuated or filled with an inert gas. However, thecavity 26 need not be evacuated and can be left at gauge pressure. Since thecavity 26 is substantially isolated, changes in environmental conditions will have less of an effect on sensing elements mounted within thecavity 26 to measure displacement of theisolator diaphragms diaphragm support structure 12. In addition, dust particles cannot easily enter thecavity 26. - In the embodiment illustrated, a
capacitive sensing device 28 provides a signal indicative of displacement of each of theisolator diaphragms diaphragm support structure 12. Thecapacitive sensing device 28 includes metallized-ring electrodes capacitors isolator diaphragms member 20, a capacitance of thecapacitor 31 formed by metallized-ring electrodes capacitor 33 formed by metallized-ring electrodes - It should be understood that
capacitive sensing device 28 is but one suitable sensor to measure displacement ofisolator diaphragms support structure 12. Other capacitive sensing devices can be used. Other suitable sensing devices that can be used to include piezoresistive or piezoelectric strain gauges, optical or acoustical sensing devices operably coupled to theisolator diaphragms diaphragm support structure 12, as appropriate. An embodiment using an optical sensor is illustrated in co-pending patent application Ser. No. ______, entitled “OPTICAL PRESSURE SENSOR”, filed on even date herewith and herein incorporated by reference. - FIG. 1A shows another example of one configuration for
capacitive electrodes region 23 is formed inrims 22A and a complementary ledge is formed inmoveable member 20 each carryingelectrodes electrodes moveable member 20. - Preferably, at least the
isolator diaphragms isolator diaphragms isolator diaphragms diaphragm support structure 12 can also be made from the same material as theisolator diaphragms isolator diaphragms rims diaphragm support structure 12 and theisolator diaphragms - Direct bonding of the
rims isolator diaphragms diaphragm support structure 12 and theisolator diaphragms rims isolator diaphragms rims isolator diaphragms rims isolator diaphragms - In the embodiment illustrated, the
diaphragm support structure 12 includes substantiallyidentical base members planar surfaces base member aperture bore 14.Annular cavities surfaces base members outer peripheries apertures ring electrodes surfaces recess 48 is provided in each of thebase member3 conductive lead 50 to extend from the metallized-ring electrodes - FIGS. 1 and 3 illustrate the
isolator diaphragm 16A. The metallizedelectrode 30A includes aconductive lead 54 that extends through arecess 55 provided in thebase member 40A (FIG. 2). Like thebase members isolator diaphragm 16A is substantially identical to theisolator diaphragm 16B. In this manner, only two unique components (i.e. theisolator diaphragms base members base members isolator diaphragms annular cavities - If the pressure sensor10 is formed from sapphire or other similar crystalline materials, a suitable method of fabrication would include first micro-machining the
isolator diaphragms base members diaphragm support structure 12 if thebase member ring electrodes isolator diaphragms base members electrodes - The pressure sensor10 can then be assembled by first securing the
isolator diaphragm 16A to thebase member 40A, and then securing theisolator diaphragm 16B to thebase member 40B. Thebase members surfaces coupling member 20 by securing theportion 18A to theportion 18B. Usingseparate base members isolator diaphragms base members - It should be understood that although
isolator diaphragms isolator diaphragms portions portions bore 14 or out of thebore 14. - FIGS.4-6 illustrate a
pressure sensor 70 according to a second embodiment of the present invention. Parts corresponding to those in FIGS. 1-3 are designated with the same reference numerals. Briefly, the second embodiment differs from the first embodiment in that the former is provided with asensing device 72 to provide an output signal indicative of line pressures p1 and P2. - In the embodiment illustrated, the
sensing device 72 comprises two capacitors formed by metallized-ring electrodes ring electrodes base members ring electrodes isolator diaphragms ring electrodes ring electrodes portion 73A of theisolator diaphragm 16A relative to thediaphragm support structure 12. Similarly, the capacitor formed by metallized-ring electrodes portion 73B of theisolator diaphragm 16B relative to thediaphragm support structure 12. Since thediaphragm support structure 12 is fixed or stationary, deflection of theportions diaphragm support structure 12 provides an indication of line pressures P1 and P2. If desired, the metallized-ring electrodes isolator diaphragms - FIG. 5 is a plan view illustrating the position of the metallized-
ring electrode 80B upon thebase member 40A with respect to the metallized-ring electrode 30B. The metallized-ring electrode 80B includes spaced-apart conductive leads 88A and 88B so as to allow theconductive lead 50 of the metallized-ring electrode 30B to extend therebetween. Similarly, the metallized-ring electrode 80A is positioned as illustrated in FIG. 6 and also includes spaced-apart conductive leads 90A and 90B on either side of theconductive lead 54. if desired, suitable circuitry can be connected to the spaced-apart conductive leads 90A and 90B of the metallized-ring electrode 80A to measure the resistance thereof and provide an indication as to the temperature of theisolator diaphragm 16A, and thus, an indication of the temperature of the process fluid exerting the pressure P1. In the embodiment illustrated, theisolator diaphragm 16B and thebase member 40B are substantially identical to theisolator diaphragm 16A and thebase member 40A, respectively, so the metallizedring electrode 82A can be used to provide an indication of the temperature of process fluid exerting the pressure P2. - FIG. 7 illustrates a pressure sensor according to a third embodiment of the present invention at94. Parts corresponding to those in FIG. 4 are designated with the same reference numerals. Briefly, the third embodiment differs from the second embodiment in that the former is provided with reinforced
isolator diaphragms isolator diaphragm center region 96A and 96B, respectively, of increased thickness to minimize high line pressure effects.Portions center regions 96A and 96B, respective, and are preferably integrally formed therewith. - A fourth embodiment of an oil-less pressure sensor is indicated at100 in FIGS. 8-10. Generally, the
oil-less pressure sensor 100 includes adiaphragm support structure 102 having arigid coupling member 104.Isolator diaphragms diaphragm support structure 102 and therigid coupling member 104. Theisolator diaphragms center regions structure 102 includes an outer periphery orrim 108. Theisolator diaphragm 106A is secured to asurface 108A of theouter periphery 108 and to asurface 104A of therigid coupling member 104. Similarly, theisolator diaphragm 106B is secured to asurface 108B of theouter periphery 108 and a surface 104B of therigid coupling member 104. - In this embodiment, the
oil-less pressure sensor 100 includes three principle components, thediaphragm support structure 102 and theisolator diaphragms oil-less pressure sensor 100 Specifically, a first set of fusion bonds formed at 104A and 108A secure theisolator diaphragm 106A to therigid coupling member 104 and theouter periphery 108, respectively. A second set of fusion bonds formed at 104B and 108B secure theisolator diaphragm 106B to therigid coupling member 104 and to theouter periphery 108, respectively. - The metallized-
ring electrodes ring electrodes channel 105 provided for the conductive leads 50, 88A and 88B. Of course, the side of thediaphragm support structure 102 having metallized-ring electrodes ring electrodes isolator diaphragm 106A. A recess or channel 109 (FIG. 9) is provided for the conductive leads 54, 90A and 90B.Isolator diaphragm 106B is constructed substantially identical toisolator diaphragm 106A. - Another aspect of the present invention is further illustrated in FIGS. 8 and 9 wherein the
diaphragm support assembly 102 includes at least onethin web 112 extending from theouter periphery 108 to integrally join therigid coupling member 104 to theouter periphery 108. Theweb 112 holds therigid coupling member 104 in position during bonding of theisolator diaphragms rigid coupling member 104. If desired, as illustrated in this embodiment, a plurality ofwebs 112 extend from different portions of theouter periphery 108. In an alternative embodiment, a solid thin web or disc, not shown, can extend completely around therigid coupling member 104 and can be used instead ofindividual webs 112. - In the embodiment illustrated,
webs 112 extend from a recessedsupport 120 that is integrally formed with theouter periphery 108. The recessedsupport 120 further supports the metallized-ring electrodes - If desired, any or all of the
webs 112 can be broken after theisolator diaphragms rigid coupling member 104 in order to reduce stiffness. Thewebs 112 can be removed using ultrasonic agitation or lasers. - FIGS. 11 and 12 illustrate a fifth embodiment of an oil-less
differential pressure 124 of the present invention. Thepressure sensor 124 includes adiaphragm support structure 126 having abore 127.Isolator diaphragms diaphragm support structure 126, and haveportions rigid coupling member 130 extending within thebore 127. Referring also to FIG. 12A, theportion 129A is integrally joined to anouter periphery portion 131A of theisolator diaphragm 128A with at least one and preferably a plurality ofthin webs 132. Thewebs 132 reduce the stiffness of theisolator diaphragm 128A, allowing it to deflect more easily. In addition, thewebs 132 hold theportion 129A in alignment with theportion 129B when theisolator diaphragms diaphragm support structure 126. Theisolator diaphragm 128B is similarly constructed. After theisolator diaphragms diaphragm support structure 126,pressure receiving caps isolator diaphragms webs 132 can then be broken in order to separate therigid coupling member 130 from theisolator diaphragms 128A and 1283. - A
capacitive sensing device 136 measures displacement of therigid coupling member 130. Thecapacitive sensing device 136 forms twoequivalent capacitors - Referring to FIGS. 12, 12A,12B and 12C, the
capacitor 135A includes afirst electrode 137A formed on thediaphragm support structure 126, asecond electrode 137B formed on thediaphragm support structure 126 and athird electrode 137C formed on theportion 129A of theisolator diaphragm 128A As illustrated in FIG. 12C, theelectrodes 137A-137C form twocapacitors capacitors coupling member 130 relative to thediaphragm support structure 126. - In the embodiment illustrated, the
electrode 137C comprises a metallized-ring formed about theportion 129A. Theelectrode 137C faces theelectrodes electrodes recesses diaphragm support structure 126. By forming series connectedcapacitors capacitor 135B has output terminals (the conductive leads 141A and 141B) formed on the same surface. - The capacitive sensing device136B is formed similar to the capacitive sensing device 136A. A first electrode 145A is provided on the
diaphragm support structure 126, asecond electrode 145B is provided on thediaphragm support structure 126 and athird electrode 145C is provide on theportion 129B. - In an alternative embodiment, the
diaphragm support structure 126 includes substantiallyidentical base members - Pressure receiving
end caps end cap 134A, a stress relieving annular groove orrecess 150A separates the pressure receivingend cap 134A into a flexingassembly 151A and an outer periphery orrim 153A. The flexingassembly 151A comprises aplate portion 154A, acylindrical tube 155A that joins theplate portion 154A to theouter rim 153A, and acenter coupling member 156A that joins theplate portion 154A to theportion 129A of theisolator diaphragm 128A. Preferably, as illustrated, theplate portion 154A, thecylindrical tube 155A and thecenter coupling member 156A are integrally formed with theouter rim 153A by use of a secondannular recess 159A. FIG. 12D illustrates, in plan view, the pressure receivingend cap 134A. The pressure receivingend cap 134B is formed substantially identical to the pressure receivingend cap 134A wherein anannular groove 150B provides a flexing assembly 151B and anouter rim 153B. Similarly, a secondannular groove 159A forms aplate portion 154B, acylindrical tube 155B and acenter coupling member 156B. - The pressure receiving
end caps rings outer rims flexing assemblies 151A and 151B can move with respect toouter rims center coupling members cylindrical tubes - The
diaphragm support structure 126, theisolator diaphragms end caps end caps - FIGS. 13, 14,15 and 16 illustrate a sixth embodiment of an oil-less pressure sensor of the present invention generally indicated at 180. Generally, the
oil-less pressure sensor 180 includes adiaphragm support structure 182 andisolator diaphragms diaphragm support structure 182 includes a plurality ofapertures 188 through whichrigid coupling members 190 extend and are secured to theisolator diaphragms single aperture 188 and asingle coupling member 190. Referring back to FIG. 14, theisolator diaphragms outer periphery 192 onsurfaces - An
overstop member 194 is formed within thediaphragm support assembly 192 under movable portions of theisolator diaphragms overstop member 194 includes the plurality ofapertures 188 through which therigid coupling members 190 extend. Asuitable sensing device 196 is provided to measure displacement ofisolator diaphragms overstop member 194. In the embodiment illustrated, thesensing device 196 comprises twocapacitors capacitor 197A includes anelectrode 198A formed on at least a portion of the overstopmember 194 facing theisolator diaphragm 186A. Preferably, theelectrode 198A surrounds many of the plurality of theapertures 188 on theoverstop member 194. Amovable electrode 198B is formed on asurface 200 of theisolator diaphragm 186A, preferably in a pattern about theapertures 188 corresponding to the pattern of theelectrode 198A on theoverstop member 194. Suitable channels are recessed below thesurface 192A in an outer periphery or rim 203 to allow conductive leads of theelectrodes diaphragm support structure 192. - A
capacitor 197B is formed in a manner similar to thecapacitor 197A to measure displacement of theisolator diaphragm 186B relative to theoverstop member 194. Anelectrode 202A, similar toelectrode 198A is provided on a surface of the overstopmember 194 to face aninner surface 204 of theisolator diaphragm 186B. Asecond electrode 202B is formed on theinner surface 204 of theisolator diaphragm 186B and faces theelectrode 202A. Suitable channels are provided in theouter periphery 203, allowing conductive leads from theelectrodes diaphragm support structure 192. - Like the embodiment of FIGS. 8 and 9, thin webs generally indicated at206 hold the
rigid coupling members 190 in position during fastening of theisolators diaphragms rigid coupling members 190. For purposes of explanation, a subset ofwebs 206A of the plurality ofwebs 206 extend from theouter periphery 203 and are integrally formed with the a subset ofrigid coupling members 190A of the plurality ofrigid coupling members 190. In the embodiment illustrated, the remainingrigid coupling members 190 are held in position by thewebs 206 extending from other portions of the overstopmember 194. The position of thewebs 206 along the length of therigid coupling members 190 can be varied as desired; however, positioning thewebs 206 at the center of eachcoupling member 190 may be preferable in order to maintain symmetry of therigid coupling member 190 during machining or etching when thediaphragm support structure 192 is made from a crystalline material such as sapphire. However, if thewebs 206 are positioned closer to either end of thecoupling members 190, stiffness may be reduced. In order to further reduce the stiffness of theoil-less pressure sensor 180, thewebs 206 can be removed or broken after theisolator diaphragms rigid coupling members 190. Ultrasonic agitation or use of lasers can be used to remove thewebs 206. If thewebs 206 are positioned at one or both ends of eachcoupling members 190, thewebs 206 may be removed easier. - As stated above, the
diaphragm support structure 192 can be made from a crystalline material such as sapphire. Other suitable materials include ruby, zirconia, silicon, silicon-carbide ceramic, zirconium, oxide ceramic, cermet ceramic, spinels and metals such as stainless steel. In a preferred embodiment, theisolator diaphragms diaphragm support structure 192, although this is not necessary. However, if thediaphragm support structure 192 and theisolator diaphragms - Displacement of either the
isolator diaphragms overstop member 194. Although a distance between theinner surfaces member 194 can be constant throughout, in a preferred embodiment, the distance varies approximately to the spherical deflection of theisolator diaphragms overstop member 194 and each of theisolator diaphragms portion 211, while the least distance is found atportions 212. Successively increasing distances are provided between the overstepmember 194 and each of theisolator diaphragms portion 213 has a distance greater thanportions 212; aportion 214 has a distance greater thanportion 213; aportion 215 has a distance greater thanportion 214; and aportion 216 has a distance greater thanportions 215, but less thanportion 211. It should be noted that thecoupling members 190 have ends that are coplanar withsurfaces - FIG. 17 illustrates an alternative embodiment of an
oil-less pressure sensor 218 where recessedsurfaces isolator diaphragms diaphragm support structure 226 and ends ofrigid coupling members 228 are also substantially coplanar. - These structures can be fabricated using any appropriate technique. Various machining, etching and deposition techniques are known in the art and may be used to fabricate the pressure sensor.
- Each of the above-described embodiments of an oil-less differential pressure sensor of the present invention includes electrodes forming at least the equivalent of two capacitors to form the difference in pressure between p1 and P2. FIG. 18 is a simplified schematic diagram of a pressure transmitter having a
circuit 400 for sensing the differential pressure applied to any of the above-described pressure sensors. Thecircuit 400 includes the first capacitor C1, for example,capacitor 31, and a second capacitor C2, for example,capacitor 33. The capacitor C1 is driven by asquare wave generator 402, while the capacitor C2 is driven by asquare wave generator 404. An inverting input of a low noisedifferential amplifier 406 is connected to the undriven plates of capacitors C1 and C2, and a non-inverting input of thedifferential amplifier 406 is connected to electrical ground. Thedifferential amplifier 406 has negative feedback through acapacitor 408 and has charge ΔQ from capacitors C1. and C2 flowing in and out of the inverting input. The output of thedifferential amplifier 406 is a square wave representative of differential capacitance, which is converted into a digital format by A/D converter 410. Incircuit 400, AQ is given as: - ΔQ=V pp IN(C 1 −C 2) EQ. 1
- And, the amplifier output is:
- V ppOUT =ΔQ/C 2 =V ppIN(C 1 −C 2 /C I) EQ. 2
-
Circuit 400 is but one suitable circuit for measuring capacitance of the capacitors C1 and C2. Other known circuits can also be used. - The output from
converter 410 is provided tointerface circuitry 412.Interface circuitry 412 is connected to a 4-20 mAcurrent loop 414 and provides the digital signal A/D converter 410 to thecurrent loop 414 in either a digital or analog format.Interface circuitry 412 also provides power tocircuit 400 from thecurrent loop 414.Interface circuitry 412 is also capable of receiving commands, such as those pursuant to the HART® communications standard. -
Circuit 400 can also be used to measure the capacitance of the line pressure capacitors. In FIG. 18, capacitor CLP1 represents the capacitor used to measure pressure P1, while capacitor CLP2 is used to measure pressure P2. To measure line pressure, analog switches 416A and 416B and 416C are operated so as to connect the line pressure capacitors CLP1 and CLP2 and a known reference capacitor CR to thesquare wave generators differential amplifier 406.Analog switch 418 is operated in order to initiate measurement of capacitor CLP1 or CLP2. Of course, the afore-mentioned equations apply wherein C1 is replaced by either CLP1 or CLP2 and C2 is replaced by CR. - FIG. 19 illustrates a
pressure transmitter 450 suitable for supporting any previously described oil-less differential pressure sensors of the present invention. In this Figure, an embodiment of the oil-less differential pressure sensor of the present invention is indicated at 452. Pressures P1 and P2 are fluidly coupled directly to thepressure sensor 452 bysuitable tubes tubes pressure sensor 452 and ahousing member 456. Preferably, thetubes pressure sensor 452. If, for example, thepressure sensor 452 is made of sapphire, thetubes - The
tubes housing member 456 by suitable corrosion resistant brazes, indicated at 458A and 458B. A path length indicated bydouble arrow 460 is preferably long enough to provide corrosion resistance. Thebrazes flange 462 is secured to thehousing member 456 with suitable fasteners indicated at 464. Theflange 462 includesfittings 466A and 466B connectable to process lines carrying the process fluids to be measured. - The
tubes pressure sensor 452 with a corrosion resistant connection indicated at 470. The corrosionresistant connection 470 can be a braze wherein an inner surface off the braze, exposed to the process fluids, is protected by electroplated platinum, iridium, or other suitable metal. The corrosionresistant connection 470 can also be a fusion bond between thesensor 452 and thetubes resistant connection 470 can also be a fired sol-gel based coating of a ceramic material, such as aluminum oxide sol-gel used to make a joint between thesensor 452 made of sapphire and thetubes - A particular advantage of the oil-less differential pressure sensor and corresponding pressure transmitter of the present invention, is that no intermediate isolator diaphragms are required to measure the pressures P1 and P2. This significantly simplifies design and reduces manufacturing costs.
- A
process barrier 472 is mounted within thehousing member 456 to form acavity 474 that prevents process fluid from escaping thehousing member 456, should any fluid connection fail. Thecavity 474 can be a vacuum, filled with an inert gas, or filled with another suitable material. Feed-throughs process barrier 472, connecting thepressure sensor 452 to acircuit board 478. If desired, two of the leads from thepressure sensor 452 can be made common, which would then only require three feed-throughs. If thepressure sensor 452 includes line pressure sensors, additional feed-throughs may be necessary. -
Circuit board 478 receives electrical signals from thepressure sensor 452 related to pressures P1 and P2. The circuit board 458 includesdifferential amplifier 406, A/D converter 410 and other suitable devices to digitize and process these signals. Thecircuit board 478 communicates pressure information to theinterface circuitry 412 using adata bus 480. Thecircuit board 478 is supported in anupper portion 482 of thehousing member 456. Asecond housing member 484 mates with thehousing member 456 to form an enclosure.Removable covers 486A and 486B provide access to theinterface circuitry 412 when desired. - Although the present invention has been described with reference to preferred embodiments, workers skilled in the art will recognize that changes may be made in form and detail without departing from the spirit and scope of the invention.
Claims (22)
1. A pressure sensor for measuring a pressure difference between two fluids, the pressure sensor comprising:
a diaphragm support member having an outer periphery and an opening formed therethrough;
a first diaphragm covering one side of the opening through the support member;
a second diaphragm covering the other some of the opening through the support member; and
a moveable member extending through the opening and coupled between the first and second diaphragms, wherein the moveable member moves in response to a difference between pressures applied to the first and second diaphragms.
2. The pressure sensor of wherein the first and second diaphragms are joined to the outer periphery of the diaphragm support member.
claim 1
3. The pressure sensor of including an electrode on the first diaphragm and an electrode on the diaphragm support member and wherein deflection of the first diaphragm causes a change in capacitance between the first and second electrodes.
claim 1
4. The pressure sensor of including a first electrode carried on the moveable member and a second electrode carried on the diaphragm support member and wherein a capacitance between the first and second electrode is related to movement of the moveable member within the diaphragm support member.
claim 1
5. The pressure sensor of including at least one additional electrode configured to have a capacitance which changes in response to a localized deflection in the first diaphragm.
claim 2
6. The pressure sensor of wherein the coupling member is joined to the outer periphery of the diaphragm support structure by a web, the web being recessed from opposed outwardly facing surfaces of the outer periphery.
claim 1
7. The pressure sensor of wherein the diaphragm support member includes a second web joining the coupling member to a different portion of the outer periphery.
claim 1
8. The pressure sensor of and wherein the diaphragm support member includes a support joined between the web and the outer periphery, the support being recessed from the outwardly facing surfaces.
claim 7
9. The pressure sensor of and further comprising a pair of capacitive displacement sensors to measure displacement of the diaphragms relative to the diaphragm support member, each capacitive displacement sensor comprising a first capacitor plate disposed on the support and a second capacitor plate disposed on a surface of the corresponding diaphragm facing the first capacitor plate.
claim 8
10. The pressure sensor of wherein the diaphragm support member includes a plurality of coupling members joined to the first and second diaphragms at opposite ends, each coupling member having a web joining the coupling member to the outer periphery.
claim 1
11. The pressure sensor of wherein the diaphragm support member includes an overstop member joined to the outer periphery and extending inwardly configured to limit movement of the first diaphragm.
claim 1
12. The pressure sensor of wherein the overstop member has opposed surfaces spaced-apart from each of the diaphragms.
claim 11
13. The pressure sensor of wherein diaphragm support member includes a recess and the portion of the first diaphragm deflects proximate the recess.
claim 1
14. The pressure sensor of and a sensing device for measuring deflection of the portion of the first isolator diaphragm.
claim 12
15. The pressure sensor of wherein the sensing device comprises a capacitive electrode disposed on the diaphragm support structure within the recess, and a second capacitive electrode disposed on the portion of the first isolator diaphragm and facing the first capacitive electrode.
claim 14
16. The pressure sensor of wherein the diaphragm support structure comprises sapphire.
claim 1
17. The pressure sensor of wherein the first and second diaphragms are coupled to the diaphragm support member by fusion bond.
claim 1
18. A process transmitter including a pressure sensor in accordance with .
claim 1
19. The pressure sensor of wherein the first diaphragm and the moveable member are integral.
claim 1
20. The pressure sensor of wherein the first and second diaphragms are in direct contact with a process fluid.
claim 1
21. A pressure transmitter in a process control system for measuring and sensing a pressure difference between two fluids, the transmitter comprising:
a pressure sensor comprising,
a diaphragm support member having an outer periphery and a coupling member disposed inward of the outer periphery and joined to the outer periphery with a web, the web being recessed from opposed outwardly facing surfaces of the outer periphery; and
first and second diaphragms disposed on opposite sides of the diaphragm support member, each diaphragm joined to the outer periphery and to the coupling member, and wherein the first diaphragm receives the first pressure and the second diaphragm receives the second pressure;
a sensing device operably coupled to the pressure sensor to provide an output signal indicative of a difference in pressure between the first pressure and the second pressure; and
circuitry receiving the output signal and transmitting information on the loop.
22. The pressure transmitter of wherein the sensing device comprises a capacitive sensing device.
claim 21
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/780,033 US6425290B2 (en) | 2000-02-11 | 2001-02-09 | Oil-less differential pressure sensor |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US18186600P | 2000-02-11 | 2000-02-11 | |
US09/780,033 US6425290B2 (en) | 2000-02-11 | 2001-02-09 | Oil-less differential pressure sensor |
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Publication Number | Publication Date |
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US20010032515A1 true US20010032515A1 (en) | 2001-10-25 |
US6425290B2 US6425290B2 (en) | 2002-07-30 |
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US09/780,033 Expired - Lifetime US6425290B2 (en) | 2000-02-11 | 2001-02-09 | Oil-less differential pressure sensor |
US09/780,148 Expired - Lifetime US6612174B2 (en) | 2000-02-11 | 2001-02-09 | Optical pressure sensor |
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US09/780,148 Expired - Lifetime US6612174B2 (en) | 2000-02-11 | 2001-02-09 | Optical pressure sensor |
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US (2) | US6425290B2 (en) |
EP (2) | EP1254357B1 (en) |
JP (2) | JP2003522942A (en) |
CN (1) | CN1401073A (en) |
AU (2) | AU2001234961A1 (en) |
DE (1) | DE60125018T2 (en) |
WO (2) | WO2001059419A1 (en) |
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- 2001-02-09 WO PCT/US2001/004136 patent/WO2001059419A1/en active IP Right Grant
- 2001-02-09 EP EP01907147A patent/EP1254357B1/en not_active Expired - Lifetime
- 2001-02-09 DE DE60125018T patent/DE60125018T2/en not_active Expired - Lifetime
- 2001-02-09 WO PCT/US2001/004132 patent/WO2001059418A1/en not_active Application Discontinuation
- 2001-02-09 US US09/780,148 patent/US6612174B2/en not_active Expired - Lifetime
- 2001-02-09 EP EP01907145A patent/EP1254356A1/en not_active Withdrawn
- 2001-02-09 JP JP2001558703A patent/JP4864266B2/en not_active Expired - Fee Related
Cited By (19)
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US7137302B2 (en) * | 2004-10-18 | 2006-11-21 | Silverbrook Research Pty Ltd | Capacitative pressure sensor with transition metal nitride electrode |
US20070039392A1 (en) * | 2004-10-18 | 2007-02-22 | Silverbrook Research Pty Ltd | Capacitative pressure sensor for oxidative environments |
US7854171B2 (en) | 2004-10-18 | 2010-12-21 | Silverbrook Research Pty Ltd | Temperature compensated miniature pressure sensor |
US20060081053A1 (en) * | 2004-10-18 | 2006-04-20 | Kia Silverbrook | Capacitative pressure sensor with transition metal nitride electrode |
US20090044630A1 (en) * | 2004-10-18 | 2009-02-19 | Silverbrook Research Pty Ltd | Temperature compensated miniature pressure sensor |
US7549342B2 (en) | 2004-10-18 | 2009-06-23 | Silverbrook Research Pty Ltd | Capacitative pressure sensor for oxidative environments |
US7806001B1 (en) * | 2007-06-05 | 2010-10-05 | Orbital Research Inc. | Multi-diaphragm pressure sensors |
WO2008151972A3 (en) * | 2007-06-11 | 2009-02-12 | Endress & Hauser Gmbh & Co Kg | Capacitative and piezoresistive differential pressure sensor |
WO2008151972A2 (en) * | 2007-06-11 | 2008-12-18 | Endress+Hauser Gmbh+Co.Kg | Capacitative and piezoresistive differential pressure sensor |
EP2207020B1 (en) * | 2009-01-08 | 2018-02-28 | Robert Bosch GmbH | Capacitative pressure sensor |
US20120055267A1 (en) * | 2010-09-07 | 2012-03-08 | Seiko Epson Corporation | Pressure sensor |
WO2012061580A3 (en) * | 2010-11-03 | 2012-06-28 | Avgi Engineering, Inc. | Differential pressure transmitter with intrinsic verification |
US9207140B2 (en) | 2010-11-03 | 2015-12-08 | Avgi Engineering, Inc. | Differential pressure transmitter with intrinsic verification |
US10466127B2 (en) | 2010-11-03 | 2019-11-05 | Avgi Engineering, Inc. | Differential pressure transmitter with intrinsic verification |
US20130298699A1 (en) * | 2012-04-20 | 2013-11-14 | Rosemount Aerospace Inc. | Separation mode capacitors for sensors |
US8984950B2 (en) * | 2012-04-20 | 2015-03-24 | Rosemount Aerospace Inc. | Separation mode capacitors for sensors |
US9976921B2 (en) | 2013-03-15 | 2018-05-22 | Measurement Limited | Low profile pressure sensor |
WO2017092887A1 (en) * | 2015-11-30 | 2017-06-08 | Siemens Aktiengesellschaft | Pressure sensor asembly and measurement transducer for process instrumentation with such a pressure sensor assembly |
US10983023B2 (en) * | 2015-11-30 | 2021-04-20 | Siemens Aktiengesellschaft | Pressure sensor assembly and measurement transducer for process instrumentation with the pressure sensor assembly |
Also Published As
Publication number | Publication date |
---|---|
AU2001234961A1 (en) | 2001-08-20 |
AU2001234959A1 (en) | 2001-08-20 |
JP2003522943A (en) | 2003-07-29 |
US6612174B2 (en) | 2003-09-02 |
CN1401073A (en) | 2003-03-05 |
WO2001059418A1 (en) | 2001-08-16 |
EP1254356A1 (en) | 2002-11-06 |
JP2003522942A (en) | 2003-07-29 |
EP1254357A1 (en) | 2002-11-06 |
DE60125018D1 (en) | 2007-01-18 |
DE60125018T2 (en) | 2007-06-28 |
US6425290B2 (en) | 2002-07-30 |
WO2001059419A9 (en) | 2002-10-24 |
EP1254357B1 (en) | 2006-12-06 |
JP4864266B2 (en) | 2012-02-01 |
WO2001059419A1 (en) | 2001-08-16 |
US20020020221A1 (en) | 2002-02-21 |
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