US1985124A - Process for treating cellulose containing fabrics, threads, and the like, and product therefrom - Google Patents
Process for treating cellulose containing fabrics, threads, and the like, and product therefrom Download PDFInfo
- Publication number
- US1985124A US1985124A US611245A US61124532A US1985124A US 1985124 A US1985124 A US 1985124A US 611245 A US611245 A US 611245A US 61124532 A US61124532 A US 61124532A US 1985124 A US1985124 A US 1985124A
- Authority
- US
- United States
- Prior art keywords
- sulfuric acid
- transparent
- treatment
- fabrics
- threads
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title description 25
- 239000004744 fabric Substances 0.000 title description 22
- 229920002678 cellulose Polymers 0.000 title description 8
- 239000001913 cellulose Substances 0.000 title description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 38
- 239000000463 material Substances 0.000 description 18
- 238000011282 treatment Methods 0.000 description 17
- 230000000694 effects Effects 0.000 description 15
- 229920000742 Cotton Polymers 0.000 description 10
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- 239000003513 alkali Substances 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 8
- 239000002253 acid Substances 0.000 description 8
- 239000003518 caustics Substances 0.000 description 7
- 238000005517 mercerization Methods 0.000 description 7
- 239000000835 fiber Substances 0.000 description 6
- 239000012780 transparent material Substances 0.000 description 5
- 238000007639 printing Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 235000011121 sodium hydroxide Nutrition 0.000 description 3
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 238000010306 acid treatment Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 240000008564 Boehmeria nivea Species 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- -1 THREAD LIKE Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010017 direct printing Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06Q—DECORATING TEXTILES
- D06Q1/00—Decorating textiles
- D06Q1/02—Producing patterns by locally destroying or modifying the fibres of a web by chemical actions, e.g. making translucent
Definitions
- the principal object of the present invention accordingly is to provide a simple and efficient process for the production of transparent cotton and cellulose-containing material which,
- the concentration above the critical value can be varied within wide limits. Sulfuric acid with gravity between 51 and 54 Be. is-particularly useful. The temperature of the acid should always be maintained so that it lies below C. during the treatment. When the temperature is minus 5 C. the effect becomes quite noticeable. Very favorable temperatures are those around minus (2., although further temperature variations within the range below the zero mark are permissible.
- acid at low temperatures assures that hydrolytic decomposion of the fiber is inhibited and the fiber is thereby preserved.
- certain substances may be incorporated in the sulfuric acid as stabilizers, for example pyridine, its homologues and derivatives, monoor polyvalent alcohols, ammonium salts, formaldehyde and formaldehyde. producing compounds.
- the fibrous structures may be subjected to the treatment without previous preparation or else they may be submitted to a suitable prior treatment by mercerization with caustic alkali or by bleaching.
- the acid-treated fabrics may be suitably subjected to a mercerizing after-treatment by mercerization with caustic alkali.
- the after-treatment is especially adapt ed to fabrics that have been given a prior mercerizing treatment with caustic alkali.
- the effects obtained by such treatment may be localized, that is, confined to certain limited portions with a view to producing patterns.
- pattern effects can be obtained in which an outstanding characteristic is that the transparent and opaque undertreated portions resemble one another very closely in their feel, possessing nearly the same soft and supple characteristics.
- Fibrous structures refined in accordance with the new process here disclosed may be submitted to any dyeing and color-printing processes.
- Bleached mercerized fine cotton batiste is drawn for 8 seconds through a bath of sulfuric acid of 52 B., kept at a temperature of minus 10 C. (measured at an outside temperature of C.) and is immediately rinsed. Next the fabric while still wet is mercerized-by caustic soda while tensioned (tautened or tentered) then washed and dried in the jigging frame (Riittelspannrahmen).
- Bleached 'mixed fabric containing cotton and viscose is subjected to the action of sulfuric acid of 54 B. (measured at plus 15 C.) for 7 seconds at a temperature of minus 8". C. and is immediately thereafter washed to free it of all acid. Dryingis effected in a tenter.
- Resist-printed cotton muslin is caused to pass for 15 seconds through sulfuric acid of 51 B. (measured at plus 15 C.), at a temperature of minus 12 C. After squeezing out the liquid there the material is immediately washed with cold water and is then mercerized with soda lye. The material freed from alkali may 2.
- a process for producing ransparent mate rials which comprises treating soft cellulosecontaining material with sulfuric acid of a concentration above 50.5 B. at a temperature less than about 0 C. in the presence of a stabilizer,
- a process for producing transparent materials which. comprises treating soft cellulosecontaining material with sulfuric acid of a concentration above 50.5 B. at a temperature less than 0 C. and then mercerizing the so-treated material.
- a process for producing pattern effects pleness of such portions about the same as the which comprises applying sulfuric acid of above untreated portions of the material. 50.5 B. at below 0 c. to localized portions of A nsm t c o in .fabric cellulose-containing material, thereby causing po fl softness an upp eness as permanent 5 the portions to which applied to become and inherent characteristics of said fabric, made 5 r m so as: m 5 in accordance with the process 0! claim 1. pa ent while rnaln lnlng e n a D V musrwmsa
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatment Of Fiber Materials (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE404792X | 1931-11-23 |
Publications (1)
Publication Number | Publication Date |
---|---|
US1985124A true US1985124A (en) | 1934-12-18 |
Family
ID=6421836
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US611245A Expired - Lifetime US1985124A (en) | 1931-11-23 | 1932-05-13 | Process for treating cellulose containing fabrics, threads, and the like, and product therefrom |
Country Status (5)
Country | Link |
---|---|
US (1) | US1985124A (fr) |
BE (1) | BE392420A (fr) |
FR (1) | FR746135A (fr) |
GB (1) | GB404792A (fr) |
NL (1) | NL38925C (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2516083A (en) * | 1944-12-27 | 1950-07-18 | Heberlein Patent Corp | Transparentizing regenerated cellulose silk |
US3140197A (en) * | 1959-04-01 | 1964-07-07 | Heberlein & Co Ag | Finished textile and method of producing same |
-
0
- BE BE392420D patent/BE392420A/xx unknown
- NL NL38925D patent/NL38925C/xx active
-
1932
- 1932-05-13 US US611245A patent/US1985124A/en not_active Expired - Lifetime
- 1932-11-21 FR FR746135D patent/FR746135A/fr not_active Expired
- 1932-11-22 GB GB32996/32A patent/GB404792A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2516083A (en) * | 1944-12-27 | 1950-07-18 | Heberlein Patent Corp | Transparentizing regenerated cellulose silk |
US3140197A (en) * | 1959-04-01 | 1964-07-07 | Heberlein & Co Ag | Finished textile and method of producing same |
Also Published As
Publication number | Publication date |
---|---|
NL38925C (fr) | |
FR746135A (fr) | 1933-05-23 |
BE392420A (fr) | |
GB404792A (en) | 1934-01-25 |
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