US1985124A - Process for treating cellulose containing fabrics, threads, and the like, and product therefrom - Google Patents

Process for treating cellulose containing fabrics, threads, and the like, and product therefrom Download PDF

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Publication number
US1985124A
US1985124A US611245A US61124532A US1985124A US 1985124 A US1985124 A US 1985124A US 611245 A US611245 A US 611245A US 61124532 A US61124532 A US 61124532A US 1985124 A US1985124 A US 1985124A
Authority
US
United States
Prior art keywords
sulfuric acid
transparent
treatment
fabrics
threads
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US611245A
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English (en)
Inventor
Weiss Ernst
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Heberlein Patent Corp
Original Assignee
Heberlein Patent Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Heberlein Patent Corp filed Critical Heberlein Patent Corp
Application granted granted Critical
Publication of US1985124A publication Critical patent/US1985124A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/51Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
    • D06M11/55Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06QDECORATING TEXTILES
    • D06Q1/00Decorating textiles
    • D06Q1/02Producing patterns by locally destroying or modifying the fibres of a web by chemical actions, e.g. making translucent

Definitions

  • the principal object of the present invention accordingly is to provide a simple and efficient process for the production of transparent cotton and cellulose-containing material which,
  • the concentration above the critical value can be varied within wide limits. Sulfuric acid with gravity between 51 and 54 Be. is-particularly useful. The temperature of the acid should always be maintained so that it lies below C. during the treatment. When the temperature is minus 5 C. the effect becomes quite noticeable. Very favorable temperatures are those around minus (2., although further temperature variations within the range below the zero mark are permissible.
  • acid at low temperatures assures that hydrolytic decomposion of the fiber is inhibited and the fiber is thereby preserved.
  • certain substances may be incorporated in the sulfuric acid as stabilizers, for example pyridine, its homologues and derivatives, monoor polyvalent alcohols, ammonium salts, formaldehyde and formaldehyde. producing compounds.
  • the fibrous structures may be subjected to the treatment without previous preparation or else they may be submitted to a suitable prior treatment by mercerization with caustic alkali or by bleaching.
  • the acid-treated fabrics may be suitably subjected to a mercerizing after-treatment by mercerization with caustic alkali.
  • the after-treatment is especially adapt ed to fabrics that have been given a prior mercerizing treatment with caustic alkali.
  • the effects obtained by such treatment may be localized, that is, confined to certain limited portions with a view to producing patterns.
  • pattern effects can be obtained in which an outstanding characteristic is that the transparent and opaque undertreated portions resemble one another very closely in their feel, possessing nearly the same soft and supple characteristics.
  • Fibrous structures refined in accordance with the new process here disclosed may be submitted to any dyeing and color-printing processes.
  • Bleached mercerized fine cotton batiste is drawn for 8 seconds through a bath of sulfuric acid of 52 B., kept at a temperature of minus 10 C. (measured at an outside temperature of C.) and is immediately rinsed. Next the fabric while still wet is mercerized-by caustic soda while tensioned (tautened or tentered) then washed and dried in the jigging frame (Riittelspannrahmen).
  • Bleached 'mixed fabric containing cotton and viscose is subjected to the action of sulfuric acid of 54 B. (measured at plus 15 C.) for 7 seconds at a temperature of minus 8". C. and is immediately thereafter washed to free it of all acid. Dryingis effected in a tenter.
  • Resist-printed cotton muslin is caused to pass for 15 seconds through sulfuric acid of 51 B. (measured at plus 15 C.), at a temperature of minus 12 C. After squeezing out the liquid there the material is immediately washed with cold water and is then mercerized with soda lye. The material freed from alkali may 2.
  • a process for producing ransparent mate rials which comprises treating soft cellulosecontaining material with sulfuric acid of a concentration above 50.5 B. at a temperature less than about 0 C. in the presence of a stabilizer,
  • a process for producing transparent materials which. comprises treating soft cellulosecontaining material with sulfuric acid of a concentration above 50.5 B. at a temperature less than 0 C. and then mercerizing the so-treated material.
  • a process for producing pattern effects pleness of such portions about the same as the which comprises applying sulfuric acid of above untreated portions of the material. 50.5 B. at below 0 c. to localized portions of A nsm t c o in .fabric cellulose-containing material, thereby causing po fl softness an upp eness as permanent 5 the portions to which applied to become and inherent characteristics of said fabric, made 5 r m so as: m 5 in accordance with the process 0! claim 1. pa ent while rnaln lnlng e n a D V musrwmsa

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatment Of Fiber Materials (AREA)
US611245A 1931-11-23 1932-05-13 Process for treating cellulose containing fabrics, threads, and the like, and product therefrom Expired - Lifetime US1985124A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE404792X 1931-11-23

Publications (1)

Publication Number Publication Date
US1985124A true US1985124A (en) 1934-12-18

Family

ID=6421836

Family Applications (1)

Application Number Title Priority Date Filing Date
US611245A Expired - Lifetime US1985124A (en) 1931-11-23 1932-05-13 Process for treating cellulose containing fabrics, threads, and the like, and product therefrom

Country Status (5)

Country Link
US (1) US1985124A (fr)
BE (1) BE392420A (fr)
FR (1) FR746135A (fr)
GB (1) GB404792A (fr)
NL (1) NL38925C (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2516083A (en) * 1944-12-27 1950-07-18 Heberlein Patent Corp Transparentizing regenerated cellulose silk
US3140197A (en) * 1959-04-01 1964-07-07 Heberlein & Co Ag Finished textile and method of producing same

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2516083A (en) * 1944-12-27 1950-07-18 Heberlein Patent Corp Transparentizing regenerated cellulose silk
US3140197A (en) * 1959-04-01 1964-07-07 Heberlein & Co Ag Finished textile and method of producing same

Also Published As

Publication number Publication date
NL38925C (fr)
FR746135A (fr) 1933-05-23
BE392420A (fr)
GB404792A (en) 1934-01-25

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