US1904450A - Stabilization of halogenated hydrocarbons - Google Patents
Stabilization of halogenated hydrocarbons Download PDFInfo
- Publication number
- US1904450A US1904450A US519894A US51989431A US1904450A US 1904450 A US1904450 A US 1904450A US 519894 A US519894 A US 519894A US 51989431 A US51989431 A US 51989431A US 1904450 A US1904450 A US 1904450A
- Authority
- US
- United States
- Prior art keywords
- amylene
- stabilization
- composition
- chlorinated
- matter
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/38—Separation; Purification; Stabilisation; Use of additives
- C07C17/42—Use of additives, e.g. for stabilisation
Definitions
- This invention relates to the stabilization of chlorinated hydrocarbons.
- Com ounds of this class for example, trichloret ylene, tetrachlorethane or methylene 5 chloride, tend to undergo decomposition during storage with the formation of substances of acid character. This decomposition makes the product objectionable for such purposes as extraction'and produces an acidity that corrodes storage tanks. While this type of decomposition is more or less general in all chlorinated hydrocarbons, it has been found that materials added to 16 and as such may be very satisfactory for the stabilization of one or more compounds but are not necessarily satisfactory for all others.
- Hydrocarbons for instance gasoline
- stabilizers for trichlorethylene Hydrocarbons, for instance gasoline, have been proposed as stabilizers for trichlorethylene. These are objectionable when the solvent is used in certain processes because a comparatively large amount of gasoline is 4 required to stabilize and the hydrocarbon heavy ends may be deposited in and contaminate the product.
- the object of this invention is to provide an efiective stabilizer for chlorinated hydrotb carbons which need be applied only in small Application filed march 8,
- chlorinated hydrocarbon decomposition with the resultant development of acidity, may be prevented by the addition of amylene in appropriate amounts.
- My process of stabilization consists in mixing a small amount, for instance, 0.0001- 01%, of the stabilizer with the chlorinated hydrocarbon.
- a preferred method of mixing consists in transferring the required amount of a strong stock solution of amylene, made up by weight to known concentration in the chlorinated hydrocarbon to be stabilized, into a known volume of that chlorinated hydrocarbon.
- composition of matter comprising a an chlorinated hydrocarbon and stabilizing amounts of amylene.
- composition of matter comprising a chlorinated hydrocarbon of the group comprising methylene chloride, trichlorethylene,
- composition of matter comprising a chlorinated hydrocarbon and from about M 0.0001% to about 1% by weight of amylene.
- composition of matter comprising methylene chloride and stabilizing amounts ot' amylene.
- composition of matter comprising methylene chloride and from about 0.0001% to about 1% by weight of amylene.
- composition of matter comprising trichlorethylene and stabilizing amounts of am lene. 5w A. composition of matter comprising trichlorethylene and from about 0.000196 to about 1% by weight of amylene.
- composition of matter comprising tetrachlorethane and stabilizing amounts of w amylene.
- composition of matter comprising tetrachlorethane and from about 0.0001% to about 1% by weight of amylene.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US519894A US1904450A (en) | 1931-03-03 | 1931-03-03 | Stabilization of halogenated hydrocarbons |
US519896A US2008680A (en) | 1931-03-03 | 1931-03-03 | Stabilization of halogenated hydrocarbons |
FR732569D FR732569A (fr) | 1931-03-03 | 1932-03-02 | Procédé de stabilisation des hydrocarbures chlorés |
DER84258D DE562820C (de) | 1931-03-03 | 1932-03-03 | Verfahren zum Stabilisieren von niedrigmolekularen chlorierten Kohlenwasserstoffen |
BE386905D BE386905A (da) | 1931-03-03 | 1932-03-03 | |
DER84259D DE573105C (de) | 1931-03-03 | 1932-03-03 | Verfahren zum Stabilisieren von niedrigmolekularen chlorierten Kohlenwasserstoffen |
GB6435/32A GB397915A (en) | 1931-03-03 | 1932-03-03 | Improvements in or relating to the stabilisation of chlorinated hydrocarbons |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US519894A US1904450A (en) | 1931-03-03 | 1931-03-03 | Stabilization of halogenated hydrocarbons |
US519896A US2008680A (en) | 1931-03-03 | 1931-03-03 | Stabilization of halogenated hydrocarbons |
Publications (1)
Publication Number | Publication Date |
---|---|
US1904450A true US1904450A (en) | 1933-04-18 |
Family
ID=27059988
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US519894A Expired - Lifetime US1904450A (en) | 1931-03-03 | 1931-03-03 | Stabilization of halogenated hydrocarbons |
US519896A Expired - Lifetime US2008680A (en) | 1931-03-03 | 1931-03-03 | Stabilization of halogenated hydrocarbons |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US519896A Expired - Lifetime US2008680A (en) | 1931-03-03 | 1931-03-03 | Stabilization of halogenated hydrocarbons |
Country Status (5)
Country | Link |
---|---|
US (2) | US1904450A (da) |
BE (1) | BE386905A (da) |
DE (2) | DE573105C (da) |
FR (1) | FR732569A (da) |
GB (1) | GB397915A (da) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3029297A (en) * | 1960-04-07 | 1962-04-10 | Frontier Chemical Company | Stabilization of chlorinated hydrocarbons |
US3099694A (en) * | 1960-05-27 | 1963-07-30 | Ethyl Corp | Stable methylchloroform compositions |
US3113154A (en) * | 1960-05-27 | 1963-12-03 | Ethyl Corp | Stable methylchloroform compositions |
FR2219248A1 (en) * | 1973-02-23 | 1974-09-20 | Diamond Shamrock Corp | Stabilising dichloromethane degreasing compsns. - against reaction with aliphatic cpds. in presence of metals |
FR2219247A1 (en) * | 1973-02-23 | 1974-09-20 | Diamond Shamrock Corp | Stabilising dichloromethane compsn. - using eg diisopropylamine, N-methylpyrrole, butylene oxide etc. |
US3898195A (en) * | 1973-02-23 | 1975-08-05 | Diamond Shamrock Corp | Stabilized methylene chloride composition |
US4032584A (en) * | 1976-05-03 | 1977-06-28 | Stauffer Chemical Company | Stabilized methylene chloride |
US4263464A (en) * | 1977-10-24 | 1981-04-21 | Solvay & Cie. | Stabilized compositions containing methylene chloride |
US11034637B2 (en) | 2016-01-15 | 2021-06-15 | AGC Inc. | Solvent composition, cleaning method, method of forming a coating film, heat transfer fluid, and heat cycle system |
Families Citing this family (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3000977A (en) * | 1961-09-19 | Method of stabilizing trichloroethyl- | ||
US2421035A (en) * | 1942-06-10 | 1947-05-27 | Bell Telephone Labor Inc | Composition for and method of extinguishing fires |
US2426549A (en) * | 1943-09-10 | 1947-08-26 | Sun Oil Co | Lubricant composition |
US2525473A (en) * | 1945-06-16 | 1950-10-10 | Westinghouse Electric Corp | Dielectric |
US2432807A (en) * | 1945-11-26 | 1947-12-16 | Gulf Research Development Co | Petroleum oil compositions |
US2432806A (en) * | 1945-11-26 | 1947-12-16 | Gulf Research Development Co | Petroleum oil compositions |
US2548636A (en) * | 1946-05-29 | 1951-04-10 | Hawley Products Co | Stabilized cuprammonium hydroxide solution and method of preparing the same |
DE1038035B (de) * | 1953-09-25 | 1958-09-04 | Diamond Alkali Co | Stabilisierung von technischem Tetrachloraethylen |
US2947792A (en) * | 1954-02-16 | 1960-08-02 | Diamond Alkali Co | Stabilization of tetrachloroethylene with a mixture of a hydroxy alkyne and isoeugenol |
US2751421A (en) * | 1954-02-18 | 1956-06-19 | Du Pont | Stabilization of trichloroethylene |
US3031412A (en) * | 1954-07-23 | 1962-04-24 | Detrex Chem Ind | Composition and method of inhibiting corrosion of ferrous metals by aminestabilized chlorinated hydrocarbons |
US2958711A (en) * | 1954-07-26 | 1960-11-01 | Diamond Alkali Co | Stabilization of chlorinated hydrocarbons with carboxylic acid esters of acetylenic alcohols |
NL96889C (da) * | 1954-07-26 | |||
GB787726A (en) * | 1955-06-16 | 1957-12-11 | Columbia Southern Chem Corp | A method in or relating to stabilization of halogenated hydrocarbons |
US2911449A (en) * | 1956-02-08 | 1959-11-03 | Air Reduction | Stabilization of chlorinated hydrocarbons with a synergistic combination of a tertiary acetylenic monohydric alcohol and certain phenolic compounds |
US2945895A (en) * | 1956-02-08 | 1960-07-19 | Air Reduction | Stabilization of chlorinated hydrocarbons with a synergistic combination of a tertiary acetylenic monohydric alcohol and 2, 6-di-tert-butyl-paracresol |
US2906782A (en) * | 1956-12-21 | 1959-09-29 | Sicedison Spa | Stabilization of the trichloroethylene and stabilizing product therefor |
US2959556A (en) * | 1957-12-05 | 1960-11-08 | Dow Chemical Co | Halogenated hydrocarbons inhibited with organic peroxides |
US3002029A (en) * | 1959-03-26 | 1961-09-26 | Phillips Petroleum Co | Stabilizer for bromo-substituted acetylenic compounds |
US3092981A (en) * | 1960-07-15 | 1963-06-11 | Gen Motors Corp | Refrigeration apparatus |
US3228806A (en) * | 1961-08-04 | 1966-01-11 | Du Pont | Stabilization of chlorohydrocarbons in phosphoric acid coating baths |
DE1215136B (de) * | 1961-10-12 | 1966-04-28 | Vulcan Materials Co | Stabilisierung von Di-, Tri- und Tetrachlor-aethylen sowie anderen niederen aliphatischen Chlorkohlenwasserstoffen und deren Gemischen |
US3297495A (en) * | 1962-11-29 | 1967-01-10 | Hooker Chemical Corp | Process and composition for phosphatizing metals |
NL287499A (da) * | 1962-01-10 | |||
NL300188A (da) * | 1962-11-13 | |||
US3230175A (en) * | 1963-04-01 | 1966-01-18 | Du Pont | Stabilized trichloroethylene and a process for treating metals therewith |
US3314884A (en) * | 1964-01-02 | 1967-04-18 | Mobil Oil Corp | Fuels and lubricants containing inclusion compounds |
JPS4816486B1 (da) * | 1967-08-16 | 1973-05-22 | ||
GB1288565A (da) * | 1969-03-24 | 1972-09-13 | ||
US3657120A (en) * | 1970-03-23 | 1972-04-18 | Feuerloschgeratewerk Neuruppin | Method of stabilizing bromine-containing fire extinguishing halogenated hydrocarbon composition |
BE1005713A3 (fr) * | 1992-03-02 | 1993-12-28 | Solvay | Procede de stabilisation d'un hydrofluoroalcane et compositions comprenant au moins un hydrofluoroalcane. |
US6534688B2 (en) * | 2001-06-11 | 2003-03-18 | Vulcan Chemicals | Dehydrochlorination stabilization of polychlorinated alkanes |
JP2014221727A (ja) * | 2013-05-13 | 2014-11-27 | 昭和電工株式会社 | ジクロロメタンの精製方法およびそれを用いるジフルオロメタンの製造方法 |
-
1931
- 1931-03-03 US US519894A patent/US1904450A/en not_active Expired - Lifetime
- 1931-03-03 US US519896A patent/US2008680A/en not_active Expired - Lifetime
-
1932
- 1932-03-02 FR FR732569D patent/FR732569A/fr not_active Expired
- 1932-03-03 DE DER84259D patent/DE573105C/de not_active Expired
- 1932-03-03 GB GB6435/32A patent/GB397915A/en not_active Expired
- 1932-03-03 DE DER84258D patent/DE562820C/de not_active Expired
- 1932-03-03 BE BE386905D patent/BE386905A/xx unknown
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3029297A (en) * | 1960-04-07 | 1962-04-10 | Frontier Chemical Company | Stabilization of chlorinated hydrocarbons |
US3099694A (en) * | 1960-05-27 | 1963-07-30 | Ethyl Corp | Stable methylchloroform compositions |
US3113154A (en) * | 1960-05-27 | 1963-12-03 | Ethyl Corp | Stable methylchloroform compositions |
FR2219248A1 (en) * | 1973-02-23 | 1974-09-20 | Diamond Shamrock Corp | Stabilising dichloromethane degreasing compsns. - against reaction with aliphatic cpds. in presence of metals |
FR2219247A1 (en) * | 1973-02-23 | 1974-09-20 | Diamond Shamrock Corp | Stabilising dichloromethane compsn. - using eg diisopropylamine, N-methylpyrrole, butylene oxide etc. |
US3898195A (en) * | 1973-02-23 | 1975-08-05 | Diamond Shamrock Corp | Stabilized methylene chloride composition |
US4032584A (en) * | 1976-05-03 | 1977-06-28 | Stauffer Chemical Company | Stabilized methylene chloride |
US4263464A (en) * | 1977-10-24 | 1981-04-21 | Solvay & Cie. | Stabilized compositions containing methylene chloride |
US11034637B2 (en) | 2016-01-15 | 2021-06-15 | AGC Inc. | Solvent composition, cleaning method, method of forming a coating film, heat transfer fluid, and heat cycle system |
US11718574B2 (en) | 2016-01-15 | 2023-08-08 | AGC Inc. | Solvent composition, cleaning method, method of forming a coating film, heat transfer fluid, and heat cycle system |
Also Published As
Publication number | Publication date |
---|---|
US2008680A (en) | 1935-07-23 |
FR732569A (fr) | 1932-09-22 |
DE573105C (de) | 1933-03-29 |
DE562820C (de) | 1932-10-29 |
BE386905A (da) | 1932-04-30 |
GB397915A (en) | 1933-09-04 |
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