US1870251A - Wetting and penetrating agents and process for preparing the same - Google Patents
Wetting and penetrating agents and process for preparing the same Download PDFInfo
- Publication number
- US1870251A US1870251A US415789A US41578929A US1870251A US 1870251 A US1870251 A US 1870251A US 415789 A US415789 A US 415789A US 41578929 A US41578929 A US 41578929A US 1870251 A US1870251 A US 1870251A
- Authority
- US
- United States
- Prior art keywords
- wetting
- terpineol
- isopropylated
- sulfonated
- alcohol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000009736 wetting Methods 0.000 title description 16
- 230000000149 penetrating effect Effects 0.000 title description 4
- 238000004519 manufacturing process Methods 0.000 title description 2
- 239000000203 mixture Substances 0.000 description 20
- 239000004215 Carbon black (E152) Substances 0.000 description 17
- 229930195733 hydrocarbon Natural products 0.000 description 16
- 150000002430 hydrocarbons Chemical class 0.000 description 16
- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 15
- 229940088601 alpha-terpineol Drugs 0.000 description 11
- 239000004753 textile Substances 0.000 description 11
- WUOACPNHFRMFPN-SECBINFHSA-N (S)-(-)-alpha-terpineol Chemical compound CC1=CC[C@@H](C(C)(C)O)CC1 WUOACPNHFRMFPN-SECBINFHSA-N 0.000 description 10
- OVKDFILSBMEKLT-UHFFFAOYSA-N alpha-Terpineol Natural products CC(=C)C1(O)CCC(C)=CC1 OVKDFILSBMEKLT-UHFFFAOYSA-N 0.000 description 10
- 239000000835 fiber Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 239000007864 aqueous solution Substances 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- -1 terpene alcohols Chemical class 0.000 description 7
- 239000000080 wetting agent Substances 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 5
- 229940116411 terpineol Drugs 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- FAMJUFMHYAFYNU-UHFFFAOYSA-N 1-methyl-4-(propan-2-yl)cyclohex-1-ene Chemical compound CC(C)C1CCC(C)=CC1 FAMJUFMHYAFYNU-UHFFFAOYSA-N 0.000 description 3
- CFJYNSNXFXLKNS-UHFFFAOYSA-N p-menthane Chemical compound CC(C)C1CCC(C)CC1 CFJYNSNXFXLKNS-UHFFFAOYSA-N 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- ZTFYJIXFKGPCHV-UHFFFAOYSA-N 2-propan-2-ylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(C(C)C)=CC=C21 ZTFYJIXFKGPCHV-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 150000003460 sulfonic acids Chemical class 0.000 description 2
- 235000007586 terpenes Nutrition 0.000 description 2
- 229930006727 (-)-endo-fenchol Natural products 0.000 description 1
- SQFZPHRRJHXHRA-UHFFFAOYSA-N 1-propan-2-yl-3,4-dihydro-2H-naphthalene-1-sulfonic acid Chemical compound C(C)(C)C1(CCCC2=CC=CC=C12)S(=O)(=O)O SQFZPHRRJHXHRA-UHFFFAOYSA-N 0.000 description 1
- PMPBFICDXLLSRM-UHFFFAOYSA-N 1-propan-2-ylnaphthalene Chemical compound C1=CC=C2C(C(C)C)=CC=CC2=C1 PMPBFICDXLLSRM-UHFFFAOYSA-N 0.000 description 1
- KBLAMUYRMZPYLS-UHFFFAOYSA-N 2,3-bis(2-methylpropyl)naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(O)(=O)=O)=C(CC(C)C)C(CC(C)C)=CC2=C1 KBLAMUYRMZPYLS-UHFFFAOYSA-N 0.000 description 1
- BTXXTMOWISPQSJ-UHFFFAOYSA-N 4,4,4-trifluorobutan-2-one Chemical group CC(=O)CC(F)(F)F BTXXTMOWISPQSJ-UHFFFAOYSA-N 0.000 description 1
- BQACOLQNOUYJCE-FYZZASKESA-N Abietic acid Natural products CC(C)C1=CC2=CC[C@]3(C)[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1 BQACOLQNOUYJCE-FYZZASKESA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- IAIHUHQCLTYTSF-MRTMQBJTSA-N Fenchyl alcohol Chemical compound C1C[C@]2(C)[C@H](O)C(C)(C)[C@H]1C2 IAIHUHQCLTYTSF-MRTMQBJTSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000010000 carbonizing Methods 0.000 description 1
- 208000018747 cerebellar ataxia with neuropathy and bilateral vestibular areflexia syndrome Diseases 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000009990 desizing Methods 0.000 description 1
- IAIHUHQCLTYTSF-UHFFFAOYSA-N fenchyl alcohol Natural products C1CC2(C)C(O)C(C)(C)C1C2 IAIHUHQCLTYTSF-UHFFFAOYSA-N 0.000 description 1
- 238000009963 fulling Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- UODXCYZDMHPIJE-UHFFFAOYSA-N menthanol Chemical compound CC1CCC(C(C)(C)O)CC1 UODXCYZDMHPIJE-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000001698 pyrogenic effect Effects 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
- Y10S516/03—Organic sulfoxy compound containing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S92/00—Expansible chamber devices
- Y10S92/01—Bearing on piston or cylinder
Definitions
- This invention relates to wetting and penetrating agents and to an improved process utilizing such agents for increasin the wetting and penetrating capacity 0 aqueous treating liquids employed in textile mdustries.
- wetting agents have previously been proposed for increasing the efficiency of treating baths by employing a large class of reagents known as wetting agents.
- wetting agents may be mentioned the sulfonic acids of alkylated polynuclearhydrocarbons, such as isopropyl-naphthalene sulfonic acid, diisobutyl-naphthalene sulfonic acid, and isopropyl-tetrahydro-naphthalene sulfonic acid.
- wetting agents by sulfonating the products obtained by the pyrogenic decomposition of abietic acid containing material, these products being generically described as abietene sulfonic acids in U. S. Patent No. 1,853,352, issued April 12, 1932.
- menthene alcohols while para-menthanol belongs to the class of menthane alcohols.
- the terpene alcohols may be used in the technical y pure state, as for example, pure alpha terpineol, or they may be used in admixture withclosely related products.
- the alpha terpineol may be used in the form of a liquid terpineol, the commercial product containing about 95% alpha terpineol.
- These new treating agents may be used in the various wet treatment of textiles in acid,
- Example 1 To parts ofwater are added 0.7 part of a mixture made from 50 parts of abietene sulfonic acid sodium salt, 35parts of liquid terpineol and 15 parts of water. 10 grams of cotton yarn are added to this bath and.
- Example 1 except that, in preparing the wetting out mixture, instead of using 50. parts carbon and a terpene alcohol.
- Example 4 An aqueous bath is made up of parts of water and 0.7 part of a mixture composed of 50 parts-of ahietene sulfonic acid, 35 parts of liquid terpincol and 15 parts or water. Wool is then treated in this bath for a few seconds in which time it will be thoroughly wetted.
- Example 5 A dye bath is made up of Anthrene Violet BNX- (Color Index 1163) There is then added adequate of a mixture composed of 50 parts of abietene sulfonic acid sodium salt and 35 parts of liquid terpineol, 15 parts: of water to give a 1% solution. Cotton 1111- mersed in this bath is dyed in strong and even shades. A similar hath made up but omitting the wetting mixture gives weak and uneven dyeings.
- terpene alcohol to wetting agent 7 0 1( )0
- this ratio may be varied within wide ranges.
- a ratio of 25:.100 is not too small and a ratio of 100: 100 is not too large. While the ratios within these limits give the most desirable results, noticeable improvement may also be obtained in the use of ratios outside said limits.
- concentration of the entire mixture in the treatment bath is, in the most pre ferred practice, usually around 0.5 to 1%, the limits 0.1% to 5% are not extreme.
- V 1 The processwhich comprises treating textile fibers with an aqueous solution of a 5 sulfonated polynuclear hydrocarbon of the type that are characterized by strong wetting properties and a terpene alcohol.
- a wetting inixture comprising an isopropylated sulfonated polynuclear hydrocarbon and a terpene alcohol of the group consisting of alpha -terpineol and para-menthanol.
- 'A a newcomposition of matter, a wetting mixture comprising an isopropylated sulfonated polynuclear hydrocarbon and alpha-terpineol.
- v V V 11 As a new composition of matter, an aqueous treating bath containing a, sulfonated polynuclear hydrocarbon of the type that are characterized by strong wetting properties and a terpene alcohol.
- an aqueous treating bath containing an alkylated sulfonated polynuclear hydrocarbon and a tcrpene alcohol.
- an aqueous treating bath containing an isopropylated sulfonated polynuclear hydrocarbon and a terpene alcohol.
- an aqueous treating bath containing an isopropylated sulfonated polynuclear hydrocarbon and a terpene alcohol of the group consisting of alpha-terpineol and para-menthanol.
- aqueous treating bath containing a wetting mixture comprising an isopropylated sulfonated polynuclear hydrocarbon and alphaterpineol.
- a wetting mixture comprising an isopropylated' sulfonated polynuclear hydrocarbon and a J menthane alcohol.
- an aqueous treating bath containing an isopropylated sulfonated: polynuclear hydrocarbon and a menthene alcohol.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR708177D FR708177A (enrdf_load_stackoverflow) | 1929-12-21 | ||
| US415789A US1870251A (en) | 1929-12-21 | 1929-12-21 | Wetting and penetrating agents and process for preparing the same |
| GB37016/30A GB368351A (en) | 1929-12-21 | 1930-12-08 | Wetting and penetrating agents and process for utilizing the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US415789A US1870251A (en) | 1929-12-21 | 1929-12-21 | Wetting and penetrating agents and process for preparing the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1870251A true US1870251A (en) | 1932-08-09 |
Family
ID=23647196
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US415789A Expired - Lifetime US1870251A (en) | 1929-12-21 | 1929-12-21 | Wetting and penetrating agents and process for preparing the same |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US1870251A (enrdf_load_stackoverflow) |
| FR (1) | FR708177A (enrdf_load_stackoverflow) |
| GB (1) | GB368351A (enrdf_load_stackoverflow) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2915472A (en) * | 1956-01-09 | 1959-12-01 | Pressner Samuel | Brightening compositions |
-
0
- FR FR708177D patent/FR708177A/fr active Active
-
1929
- 1929-12-21 US US415789A patent/US1870251A/en not_active Expired - Lifetime
-
1930
- 1930-12-08 GB GB37016/30A patent/GB368351A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2915472A (en) * | 1956-01-09 | 1959-12-01 | Pressner Samuel | Brightening compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| GB368351A (en) | 1932-03-04 |
| FR708177A (enrdf_load_stackoverflow) |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB345207A (en) | Sizing textile fibres | |
| US2447993A (en) | Process for dyeing textile fibers with vat dyes | |
| US1870251A (en) | Wetting and penetrating agents and process for preparing the same | |
| US1914331A (en) | Treatment of textile materials with aqueous liquids | |
| GB343872A (en) | Improvements in the manufacture and production of wetting, cleansing and dispersing agents | |
| US3433574A (en) | Dye leveller containing an anionic or non-ionic detergent with a foam depressant mixture of an alkyl ester of an alkanoic acid,an alkyl phosphate,and a fatty acid or soap | |
| US1776052A (en) | Process for treating cellulosic fibers with alkali | |
| US3892521A (en) | Process for dyeing cellulosic materials | |
| US1897120A (en) | hbtot | |
| US2750250A (en) | Method for dyeing polyacrylonitrile fabrics | |
| DE1965765A1 (de) | Verfahren zum Nachwaschen von frisch gefärbtem Textilmaterial | |
| US2063908A (en) | Amino-carboxylic acid derivatives in wet treatments | |
| US1879742A (en) | of basel | |
| Maclaren et al. | Sulfation of wool as a dye-resist process | |
| Nicholls | The Rates of Desorption of Level‐dyeing Acid Dyes from Wool | |
| CH163255A (de) | Verfahren zur Darstellung eines Behandlungsbades von grossem Benetzungs- und Durchdringungsvermögen. | |
| US2067176A (en) | Production of amino alcohol derivatives | |
| US1950287A (en) | Method of producing water-soluble | |
| DE803830C (de) | Verfahren zur Herstellung oder zum Abziehen von Faerbungen, insbesondere Kuepenfaerbungen | |
| DE721809C (de) | Netz-, Reinigungs- und Dispergiermittel | |
| DE1419045C (de) | Verfahren zur permanenten antistatischen Ausrüstung von geformten Gebilden | |
| DE2718941A1 (de) | Verfahren zum einbadigen waschen und faerben von textilen flaechengebilden in haspelkufen oder faerbetrommeln | |
| Lawrie et al. | RECENT DEVELOPMENTS IN TEXTILE FINISHING | |
| DE2256116A1 (de) | Verfahren zum faerben mit dispersionsfarbstoffen | |
| GB368293A (en) | Process of treating fibrous materials |