US1856033A - Artificial forms or threads fast to water and easily dyed and process of making same - Google Patents
Artificial forms or threads fast to water and easily dyed and process of making same Download PDFInfo
- Publication number
- US1856033A US1856033A US175936A US17593627A US1856033A US 1856033 A US1856033 A US 1856033A US 175936 A US175936 A US 175936A US 17593627 A US17593627 A US 17593627A US 1856033 A US1856033 A US 1856033A
- Authority
- US
- United States
- Prior art keywords
- water
- making same
- threads
- easily dyed
- fast
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title description 5
- 238000000034 method Methods 0.000 title description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 6
- 239000000020 Nitrocellulose Substances 0.000 description 5
- 229940081735 acetylcellulose Drugs 0.000 description 5
- 229920002301 cellulose acetate Polymers 0.000 description 5
- 229920001220 nitrocellulos Polymers 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 229920002678 cellulose Polymers 0.000 description 4
- 239000001913 cellulose Substances 0.000 description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-M hydrosulfide Chemical compound [SH-] RWSOTUBLDIXVET-UHFFFAOYSA-M 0.000 description 4
- 229920002955 Art silk Polymers 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- SMEGJBVQLJJKKX-HOTMZDKISA-N [(2R,3S,4S,5R,6R)-5-acetyloxy-3,4,6-trihydroxyoxan-2-yl]methyl acetate Chemical compound CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)O)OC(=O)C)O)O SMEGJBVQLJJKKX-HOTMZDKISA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009967 direct dyeing Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000988 sulfur dye Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/24—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from cellulose derivatives
- D01F2/28—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from cellulose derivatives from organic cellulose esters or ethers, e.g. cellulose acetate
Definitions
- the present invention relates to artificial forms or threads fast to water and easily dyed and a process of preparing the same. It comprises the new products as well as the method of making these products.
- What I claim is The process of forming cellulose filaments, fast and dyeable with wool and cotton dyes, which consists in preparing a cellulose solution containing acetate cellulose and nitrocellulose in proportions ranging from 80 to 95 parts of acetate cellulose as compared with 20 to 5 parts of nitrocellulose, forming filaments therefrom, treating the filaments thus formed in a denitrating bath having not less than an 8 per cent hydrosulfide content and maintained at a temperature of above 50 degrees centigrade.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Description
Patented Apr. 26, 1932 UNITED STATES PATENT OFFICE FRITZ STRAUB, OF BASEL, SWITZERLAND, ASSIGNOR TO THE FIRM SOCIETY OF CHEM- ICAL INDUSTRY IN BASLE, OF BASEL, SWITZERLAND ARTIFICIAL FORMS OR THREADS FAST TO WATER AND EASILY DYED AND PROCESS OF MAKING SAME No Drawing. Application filed March 16, 1927, Serial No. 175,936, and in Switzerland March 24, 1926.
The present invention relates to artificial forms or threads fast to water and easily dyed and a process of preparing the same. It comprises the new products as well as the method of making these products.
It is known that of the various kinds of artificial silk the commonly called acetate silk possesses the most valuable properties, as it is considerably faster to water than the other kinds of artificial silk and has a lusitre which closely resembles that of natural sil C.
The disadvantage of acetate silk, however, is its small tendency to absorb the hitherto 5 usually employed dyestuffs, so that for this particular purpose new dyestuffs have to be brought on to the market.
By the present invention an acetate silk is made which can be dyed easily and intensely go by means of the hitherto usual dyestuffs and has all the advantageous properties of acetate silk by mixing with the cellulose acetate solution which is to be made into artificial forms or spun. a certain proportion of nitrocellin lose, and subsequent to the formation or spinning of the product. denitrating the latter by use of a denitrating bath of more energetic action than such baths as have previously been used for denitrating products made of pure nitrocellulose. Such bath contains for instance more than 8 per cent. of a soluble hydrcosulfide, and its temperature lies above This result, which is really surprising, represents an essential advance in the art of making products from acetyl cellulose capable of being easily dyed.
As a rule, the addition of 520 per cent. of a nitrocellulose to the cellulose acetate proves sufficient for obtaining the desired effect. However, it is important and should be expressly emphasized that the denitration should be intensive; the hitherto usual denitration by means of treatment with a solution of sodium hydrosulfide of 7-8 per cent. strength at s ll-50 C. does not produce the desired result.
The following example illustrates the invention A cellulose acetate solution is mixed with 5-10 per cent. (calculated on the content of cellulose acetate) of nitrocellulose whereupon the mixture is spun into threads in known manner. The spun product is passed in the course of about 3 hours through an aqueous solution of sodium hydrosulfide containing 10-12 per cent. of NaSH and advantageously also 6-12 grams of magnesium chloride per litre, the temperature of the solution being 65 C. The goods are then washed and dried. The threads thus obtained have an excellent aflinity for dyestuffs, whether they be acid, basic, mordant-dyeing, direct-dyeing or vatdyestufi's, including sulfur dyes. Thus it is possible to dye the threads easily very different tints and densities. The fastness to water, as well as the elasticity and strength are very good.
Instead of alkali hydrosulfide a soluble hydrosulfide, such as an alkali earth hydrosulfide, may be used.
What I claim is The process of forming cellulose filaments, fast and dyeable with wool and cotton dyes, which consists in preparing a cellulose solution containing acetate cellulose and nitrocellulose in proportions ranging from 80 to 95 parts of acetate cellulose as compared with 20 to 5 parts of nitrocellulose, forming filaments therefrom, treating the filaments thus formed in a denitrating bath having not less than an 8 per cent hydrosulfide content and maintained at a temperature of above 50 degrees centigrade.
In witness whereof I have hereunto signed my name this 5th day of March, 1927.
FRITZ STRAUB.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH268363X | 1926-03-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1856033A true US1856033A (en) | 1932-04-26 |
Family
ID=4476846
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US175936A Expired - Lifetime US1856033A (en) | 1926-03-24 | 1927-03-16 | Artificial forms or threads fast to water and easily dyed and process of making same |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US1856033A (en) |
| FR (1) | FR631194A (en) |
| GB (1) | GB268363A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2421391A (en) * | 1942-11-03 | 1947-06-03 | American Viscose Corp | Process for denitrating nitrocellulose articles |
-
1927
- 1927-03-16 US US175936A patent/US1856033A/en not_active Expired - Lifetime
- 1927-03-21 FR FR631194D patent/FR631194A/en not_active Expired
- 1927-03-24 GB GB8147/27A patent/GB268363A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2421391A (en) * | 1942-11-03 | 1947-06-03 | American Viscose Corp | Process for denitrating nitrocellulose articles |
Also Published As
| Publication number | Publication date |
|---|---|
| FR631194A (en) | 1927-12-15 |
| GB268363A (en) | 1928-06-25 |
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