US1828826A - Process for the production of soap threads - Google Patents
Process for the production of soap threads Download PDFInfo
- Publication number
- US1828826A US1828826A US282889A US28288928A US1828826A US 1828826 A US1828826 A US 1828826A US 282889 A US282889 A US 282889A US 28288928 A US28288928 A US 28288928A US 1828826 A US1828826 A US 1828826A
- Authority
- US
- United States
- Prior art keywords
- soap
- kgs
- threads
- mass
- liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000344 soap Substances 0.000 title description 61
- 238000000034 method Methods 0.000 title description 24
- 238000004519 manufacturing process Methods 0.000 title description 13
- 239000007788 liquid Substances 0.000 description 19
- 239000007787 solid Substances 0.000 description 18
- 239000000203 mixture Substances 0.000 description 11
- 239000000047 product Substances 0.000 description 11
- UIIMBOGNXHQVGW-UHFFFAOYSA-M sodium bicarbonate Substances [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 11
- 239000003792 electrolyte Substances 0.000 description 10
- 229960001922 sodium perborate Drugs 0.000 description 9
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 7
- 238000005185 salting out Methods 0.000 description 7
- 238000001125 extrusion Methods 0.000 description 6
- 235000019353 potassium silicate Nutrition 0.000 description 6
- 235000017557 sodium bicarbonate Nutrition 0.000 description 6
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 6
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 5
- 229940072033 potash Drugs 0.000 description 5
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 5
- 235000015320 potassium carbonate Nutrition 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 229910021538 borax Inorganic materials 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 4
- 235000010339 sodium tetraborate Nutrition 0.000 description 4
- 238000007792 addition Methods 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 238000003825 pressing Methods 0.000 description 3
- 239000004328 sodium tetraborate Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229920002955 Art silk Polymers 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 2
- 150000001447 alkali salts Chemical class 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- -1 hydrocarbon halides Chemical class 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 235000012149 noodles Nutrition 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 235000011837 pasties Nutrition 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- 239000001488 sodium phosphate Substances 0.000 description 2
- 229910000162 sodium phosphate Inorganic materials 0.000 description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004111 Potassium silicate Substances 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000003118 aryl group Chemical class 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 150000001896 cresols Chemical class 0.000 description 1
- 229960005215 dichloroacetic acid Drugs 0.000 description 1
- CEJLBZWIKQJOAT-UHFFFAOYSA-N dichloroisocyanuric acid Chemical compound ClN1C(=O)NC(=O)N(Cl)C1=O CEJLBZWIKQJOAT-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- ULODLFDKFVIYFY-UHFFFAOYSA-N naphthalene-2-sulfonic acid;sodium Chemical compound [Na].C1=CC=CC2=CC(S(=O)(=O)O)=CC=C21 ULODLFDKFVIYFY-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229960003975 potassium Drugs 0.000 description 1
- 235000007686 potassium Nutrition 0.000 description 1
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Substances [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 1
- 235000011056 potassium acetate Nutrition 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- 229940094025 potassium bicarbonate Drugs 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Inorganic materials [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 1
- LWIHDJKSTIGBAC-UHFFFAOYSA-K potassium phosphate Substances [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 1
- 229910000160 potassium phosphate Inorganic materials 0.000 description 1
- 235000011009 potassium phosphates Nutrition 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 239000001120 potassium sulphate Substances 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- JVUYWILPYBCNNG-UHFFFAOYSA-N potassium;oxido(oxo)borane Chemical compound [K+].[O-]B=O JVUYWILPYBCNNG-UHFFFAOYSA-N 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011833 salt mixture Substances 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 235000011008 sodium phosphates Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000019794 sodium silicate Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- LUPNKHXLFSSUGS-UHFFFAOYSA-M sodium;2,2-dichloroacetate Chemical compound [Na+].[O-]C(=O)C(Cl)Cl LUPNKHXLFSSUGS-UHFFFAOYSA-M 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D13/00—Making of soap or soap solutions in general; Apparatus therefor
- C11D13/14—Shaping
- C11D13/20—Shaping in the form of small particles, e.g. powder or flakes
Definitions
- the present invention relates to a process for the production of soap in the form of fine threads. To obtain products of this kind it is necessary to satisfy two conditions,
- the process referred to one before the last is im roved on the one hand by using instead 0 soda, other desired salts or salt mixtures, for instance potash, sodium or potassium bicarbonate, potassium or sodium sulphate, potassium or sodium phosphate, potassium or sodium silicate, potassium or sodium borate, potassium or sodium acetate, potassium or sodium nitrate, the potassium or sodium salts of aromatic sulphonic a gids, such as for instance of 56b3,I1a El1 hl, lQl Sl1lph0I1lC' acids or of their homologues and substitution products or the like, which salts are referred to broadly hereinafter b the term electrolyte.
- other desired salts or salt mixtures for instance potash, sodium or potassium bicarbonate, potassium or sodium sulphate, potassium or sodium phosphate, potassium or sodium silicate, potassium or sodium borate, potassium or sodium acetate, potassium or sodium nitrate, the potassium or sodium salts of aromatic sulphonic a
- cold solidified soap can also be mixed with electrolytes, and in some circumstances, for instance when using pertxamim salts, is even advantageous.
- the upper limit for the electrolytes lies approximately between 10% and 30%, the former figure holding for the case of soda and the latter for the case of other electrolytes; it naturally depends upon the fats used for the production of the soap.
- persalts e. g. sodium perborate
- the additional advantage is attained that by rapid cooling and pressing of the soap through fine apertures products are obtained in the form of fine threads which will keep for some time without the persalt losing any oxygen.
- colloidal protectives are added at the same time, which envelop the persalts and thus protect them against decomposition.
- Such substances for instance water glass are already used at the present time in the soap industry under the name protective colloids, to protect the persalts against premature decomposition.
- the resulting mixture is converted in a manner known per se into the fine threads or fine filaments. It is more especially advisable to effect this by forcing the cold solid mass through fine mouth-pieces, in which case one can go as far as 4 mm. diameter.
- the fundamental difierence as compared with the forcing of liquid soap through such fine apertures, referred to previously, consists in this that in this case it is not liquid but solid soap that is forced through. The soap in the present process therefore does not solidify by rapid cooling and drying after it has emerged from the nozzles, but is pressed in a cool and solid state.
- fine apertures or mouth-pieces in the sense of this invention are only understood as being those having at most 1 mm. diameter; the use of wider apertures for pressing solid soap is not claimed for the mixture which comes into question.
- the process described above can also be modified if desired so that the primary material used is not liquid soap, but solid soap and the aforementioned electrolyte is then added to the said soap and mixed. This is however not advisable in general, as in such a case one has not the advantage of being able to proceed immediately from soap which is still liquid, but in some circumstances conditions of manufacture may necessitate the soap being first allowed to solidify. The entire process then remains unchanged in other respects.
- plastic masses are obtained, which solidify rapidly, and are readily pressable; products are obtained in the form of threads which no longer cake together and are immediately ready for packing.
- the advantage consists of the addition of the above kinds of salts on the one hand in removing the adhesive character from the soaps, especially if resin is used therewith, and on the other hand they make the soaps so stiff that pressing is facilitated.
- the electrolyte is correctly chosen, it is possible to obtain the valuable advantage that when hard water is used, the soap is protected from reacting with the lime and magnesium salts contained in the water, to form insoluble compounds. By this means considerable saving in washing material is obtained, and no damage occurs by the formation of stains and no yellowing by colloidally dispersed iron.
- curd soap 500 kgs. 62% curd soap are mixed with a pasty mixture prepared independently and composed of 66 kgs. crystallized sodium perborate 50 kgs. water glass of specific gravity 1.35 to 1.50 and with 1 kgs. 34% soda lye. After five to ten minutes 20 kgs. calcined soda are added, again well mixed and the whole further treated as stated in Example 1 or 2.
- the mass which is at first liquid becomes solid in the course of 5-10 minutes and can then be further treated according to Example 1 or 2.
- What I claim is 1.
- a process for the production of soap in the form of very fine threads, which will be rapidily soluble in cold water consisting 1n adding to soap mass so much of an alkali salt that no softening or salting-out occurs, and then converting the solid mass into threads having a diameter less than 1.5 mm. by extrusion.
- a process for the roduction of soap in the form of very fine t reads which will be rapidly soluble in cold water, consisting in adding to soap mass in as liquid a state as possible so much of an alkali salt that no softening or salting-out occurs, and then converting the solid mass into threads having a diameter less than 1.5 mm. by extrusion.
- a process for the production of soap in the form of very fine threads which will be rapidly soluble in cold water, consisting in adding to soap mass so much sodium perborate that no softening or salting-out occurs, and then converting the solid mass into threads having a diameter less than 1.5 mm. by extrusion.
- a process for the production of soap in the form of very fine threads which will be rapidly soluble in cold water, consisting in adding to soap mass in as liquid a state as possible so much sodium perborate that no softening or salting-out occurs, and then converting the solid mass into threads having a diameter less than 1.5 mm. by extrusion.
- a process for the production of soap in the form of very fine threads which will be rapidly soluble in cold water, consisting in adding to soap mass so much sodium perborate that no softening or salting-out occurs, together with waterglass, which prevents the decomposition of the sodium perborate, and then converting the solid mass into threads having a diameter less than 1.5 mm. by extrusion.
- a process for the production of soap in the form of very fine threads which will be rapidly soluble in cold water, consisting in adding to soap mass so much sodium perborate that no softening or salting-out ocours, and a colloidal substance that will prevent the decomposition of the sodium perborate and then converting the solid mass into threads having a diameter less than 1.5 mm. by extrusion.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEW76208D DE606366C (de) | 1927-06-10 | 1927-06-10 | Verfahren zur Herstellung von leicht loeslichen, geformten Seifenpraeparaten |
Publications (1)
Publication Number | Publication Date |
---|---|
US1828826A true US1828826A (en) | 1931-10-27 |
Family
ID=26003115
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US282889A Expired - Lifetime US1828826A (en) | 1927-06-10 | 1928-06-04 | Process for the production of soap threads |
Country Status (5)
Country | Link |
---|---|
US (1) | US1828826A (enrdf_load_html_response) |
BE (1) | BE351326A (enrdf_load_html_response) |
DE (1) | DE606366C (enrdf_load_html_response) |
FR (1) | FR654793A (enrdf_load_html_response) |
GB (1) | GB319807A (enrdf_load_html_response) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE202006013438U1 (de) * | 2006-08-31 | 2007-02-08 | Zinck, Adalbert | Beschichtungs-, Klebe- und Imprägniermittel, insbesondere als Bau- und Restaurationsmaterial |
-
0
- BE BE351326D patent/BE351326A/xx unknown
-
1927
- 1927-06-10 DE DEW76208D patent/DE606366C/de not_active Expired
-
1928
- 1928-05-23 FR FR654793D patent/FR654793A/fr not_active Expired
- 1928-05-26 GB GB15555/28A patent/GB319807A/en not_active Expired
- 1928-06-04 US US282889A patent/US1828826A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
GB319807A (en) | 1929-09-26 |
DE606366C (de) | 1934-11-30 |
BE351326A (enrdf_load_html_response) | |
FR654793A (fr) | 1929-04-10 |
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