US1721169A - Manufacture of oxide cathodes - Google Patents

Manufacture of oxide cathodes Download PDF

Info

Publication number
US1721169A
US1721169A US181619A US18161927A US1721169A US 1721169 A US1721169 A US 1721169A US 181619 A US181619 A US 181619A US 18161927 A US18161927 A US 18161927A US 1721169 A US1721169 A US 1721169A
Authority
US
United States
Prior art keywords
film
metal
alkaline earth
coating
core
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US181619A
Other languages
English (en)
Inventor
Karel Marinus Van Gessel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
RCA Corp
Original Assignee
RCA Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by RCA Corp filed Critical RCA Corp
Application granted granted Critical
Publication of US1721169A publication Critical patent/US1721169A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J9/00Apparatus or processes specially adapted for the manufacture, installation, removal, maintenance of electric discharge tubes, discharge lamps, or parts thereof; Recovery of material from discharge tubes or lamps
    • H01J9/02Manufacture of electrodes or electrode systems
    • H01J9/04Manufacture of electrodes or electrode systems of thermionic cathodes
    • H01J9/042Manufacture, activation of the emissive part

Definitions

  • Serial Oxide cathodes are manufactured by first oxidizing superficially a core of a highly refractorymetal which does not easily form an alloy with any of the alkaline earth metals such, for example, as tungsten, or molybdenum and then contacting this surface with one or more of the alkaline earth metals, which subsequently are converted into their oxides.
  • An improvement of this process is obtained by not superficially oxidizing the above-mentioned core of highly refractory metal itself but by first coating the said core with a film of a readily oxidized metal having a comparatively low pointof volatilization, oxidizing said film partially or entirely and subsequently coating the oxidized film with one or more of the alkaline earth metals. This coating is then heated to such a temperature that the metal of the film gives up its oxygen to the alkaline earth metal and-the metal of the film volatilizes. The alkaline earth metal is thereby converted into an oxide.
  • The-core which, for "example, may be of tungsten or molybdenum may be coated, for. example, witha film of copper, which subsequently is converted, partially or entirely, into copper oxide.
  • the alkaline earth metal is applied in a metallic state to the surface thus obtained. This may be effected in any manner known for this purpose, for example, by vapourizing barium and precipitating it on the core surface. On heating, 'an exchange of oxygen ensues between the copper and the barium, for which purpose additional supplementary oxygen or air may be applied, if desired, in order to oxidize the barium.
  • odes comprising coating a core of a refractory metal or metal alloy which does not readily form an alloy'with any of the alkaline earth metals, with a film of a readily oxidized metal haying a comparatively low point of vola- I tlhzatlon, oxidizing partially or entirely the sa1d film, coating the-oxidized film with one or'more of the alkaline earth metals, and then heatlng to such a temperature that the al kalme earth metal is converted into oxide. and the metal of the film is volatilized.
  • a process of manufacturing oxide cathodes comprising coating a core of a refractory metal or metal alloy which does not readily form an alloy with any of the alkaline earth metals, with a film of a readily oxidized metal having a comparatively low point of '70 volatilization, oxidizing partially or entirely the said film, coating the oxidized film with one or more of the alkaline earth metals by bringing the said film into contact with the vapour of one or more of the alkaline earth metals and precipitating the alkaline earth metal on the film, and then heating to such a temperature that the alkaline earth metal is i converted into oxide and the metal of. the film is volatilized.
  • oxide cathodes comprising coating a core of refractory metalor metal alloy with a film of a readily oxidized metal having a comparative-- ly low point of volatilization, oxidizing the 5 said'film, coating the oxidized film with an alkaline earth metal, and then heating the coated core to such a temperature that the alkaline earth metal is converted into oxide,
  • oxide cathodes which consists in coating a core of a metallic refractory substance which does not readily form an alloy with any of the alkaline earth metals, with a film of a readily oxidized metal, as copper, having a comparatively low point of volatilization, oxidizing the copper,

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Solid Thermionic Cathode (AREA)
US181619A 1926-04-06 1927-04-06 Manufacture of oxide cathodes Expired - Lifetime US1721169A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL1721169X 1926-04-06

Publications (1)

Publication Number Publication Date
US1721169A true US1721169A (en) 1929-07-16

Family

ID=19873003

Family Applications (1)

Application Number Title Priority Date Filing Date
US181619A Expired - Lifetime US1721169A (en) 1926-04-06 1927-04-06 Manufacture of oxide cathodes

Country Status (4)

Country Link
US (1) US1721169A (it)
BE (1) BE340879A (it)
DE (1) DE499670C (it)
NL (1) NL21613C (it)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3515629A (en) * 1966-09-30 1970-06-02 Raytheon Co Electrical device having intermediate dielectric layer

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4314312A1 (de) * 1993-04-30 1994-11-03 Teves Gmbh Alfred Elektrohydraulische Druckregelvorrichtung

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3515629A (en) * 1966-09-30 1970-06-02 Raytheon Co Electrical device having intermediate dielectric layer

Also Published As

Publication number Publication date
BE340879A (it)
DE499670C (de) 1930-06-12
NL21613C (it)

Similar Documents

Publication Publication Date Title
US1922254A (en) Thermionic tube electrode
US2304297A (en) Art of utilizing molybdenum
US1721169A (en) Manufacture of oxide cathodes
US2156262A (en) Process of treating metal articles to alloy constituent metals
US1972162A (en) Heater element electron emitting cathode
US2610386A (en) Semiconductive cell
US1936792A (en) Method of making copper oxide rectifiers for high voltage application
US2472189A (en) Thermionic tube having a secondary-emission electrode
US1104054A (en) Manufacture of non-oxidizing conductors.
US1809229A (en) Electric discharge tube
US1936334A (en) Electrode
US1906689A (en) Nib for gold pen-points
JP2846038B2 (ja) 電子管用金属線材の製造方法
GB976527A (en) Improvements relating to the manufacture of insulated wire
US1558961A (en) Manufacture of filaments or cathodes for electric lamps, thermionic tubes and the like
US1883840A (en) Manufacturing oxide cathodes
US1542385A (en) Thermionic cathode and method of making the same
US3262293A (en) Method of manufacturing wire
US2746129A (en) Method of producing a taut thin member
US3342634A (en) Method of producing black, metalcontaining surface layers
US1818196A (en) Method of coating substances
US1720675A (en) Manufacture of oxide cathodes
US1809095A (en) Process of coating thermionic cathodes
US1659205A (en) Method of producing refractory metals
US1870003A (en) Coating for thermionic devices