US1683315A - Process of making antistatic nitrocellulose film - Google Patents
Process of making antistatic nitrocellulose film Download PDFInfo
- Publication number
- US1683315A US1683315A US140695A US14069526A US1683315A US 1683315 A US1683315 A US 1683315A US 140695 A US140695 A US 140695A US 14069526 A US14069526 A US 14069526A US 1683315 A US1683315 A US 1683315A
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- Prior art keywords
- film
- face
- nitrocellulose
- static
- solution
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
- G03C1/85—Photosensitive materials characterised by the base or auxiliary layers characterised by antistatic additives or coatings
Definitions
- motion picture films comprise flexible, transparent, nitrocellulose bases on which are located light-sensitive photographic layers.
- the latter layers are especially sensitive to light and to electrical discharges.
- electric discharges are liable to take place during the use of negative film; and when the latter is developed, undesirable spots called static appear on the film where the electric dischar es took place. It is possible, but not usua ,for such spots to appear even on nitrocellulose film having a less sensitive positive emulsion.
- either negative or positive, having a nitrocellulose ase may be simply and inexpensively rendered anti-static by superficially hydrolyzing the rear face of the film base b the application of an alkaline solution, tlius avolding the waste or expensive recovery of organic solvents and likewise avoiding the necessity of coating the rear face with any organic or cellulos1c materials.
- the process 1s very simple and involves only the use of a dilute alkaline solution, such as an aqueous solution'of to 5 0 of oneof the h droxides,NH OP, NA H, and KOH.
- the treatment is preferably performed on the nitrocellulose .base before the latter is coated with the emulsion. While it is essential that the rear face be treated, there is no harm and a slight benefit as regards static, if the other face of the nitrocellulose base, on which the light-sensitive photographic emulsion is tobe coated, is also superficially saponified at the same time.
- the alkaline solution may be applied to the film base by any of the methods and apparatus customarily employed in the art for applyifig liquids to film.
- the film may be immersed in the dilute alkaline solution.
- the alkaline liquid may be applied to it by floating the film on the surface of the alkalineliquid with only one face in contact, or by applying the liquid to the 'face' by means of a roll over which the film is moved, or by means of brushes or wicks against which the rear face of the film is carried.
- the film base is saponified on both faces by immersion, it is, at the end of the treatment, washed by an immersion in water or by spraying of water or by passing through a countercurrent of water. Thereupon it is dried and coated with sensitive emulsion in the usual way.
- crupulous care must be taken to prevent the treating liquid from reaching the sensitive emulsion on the front face.
- applying the liquid to the rear face only, while guarding the front face may be one of those customarily employed for dyeing one sideonly of motion picture films, these being well known to those skilled in the art.
- Aqueous solutions of NAOH and ammonium hydroxid of equivalent alkalinity will operate successfully within about the same time.
- the liquid may be employed as a penetrant, butthis is not essential. Likewise the liquid may be warmed somewhat above room temperature are impaired.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
Description
Patented Sept. 4, i928.
UNITEE STATES teeters FFIQE BAY L. STINCHFIELD, OI ROCHESTER, NEW YORK, ASSIGNOR T0 EASTMAN KODAK COMPANY, OF ROCHESTER, N EW YORK, A CORPORATION OF NEW YORK.
PROCESS OF MAKING ANTISTATIC NITROGELLULOSE FILM No Drawing.
The majority of motion picture films comprise flexible, transparent, nitrocellulose bases on which are located light-sensitive photographic layers. In the case of negative films the latter layers are especially sensitive to light and to electrical discharges. Under certain conditions, met with in practice, electric discharges are liable to take place during the use of negative film; and when the latter is developed, undesirable spots called static appear on the film where the electric dischar es took place. It is possible, but not usua ,for such spots to appear even on nitrocellulose film having a less sensitive positive emulsion.
Various alterations in the film have been.
suggested for the prevention or minimizing of these harmful electric discharges. These alterations have generally been in connection with the unsensitive or rear side of the film base, and have either included the use of volatile organic solvents, or special organic coating materials or both.
I have found that motion picture film,
either negative or positive, having a nitrocellulose ase, may be simply and inexpensively rendered anti-static by superficially hydrolyzing the rear face of the film base b the application of an alkaline solution, tlius avolding the waste or expensive recovery of organic solvents and likewise avoiding the necessity of coating the rear face with any organic or cellulos1c materials. The process 1s very simple and involves only the use of a dilute alkaline solution, such as an aqueous solution'of to 5 0 of oneof the h droxides,NH OP, NA H, and KOH.
umerous tests have shown that only a few hours treatment of the rear face of the film with a dilute alkaline solution will render anti-static even the most sensitive negative motion picture film on nitrocellulose base. I shall now describe several examples of my invention, but it will be understood that Application filed October 9, 1926. Serial No. 140,695.
the latter is not limited to the details thus given, except as indicated in the appended claims. The treatment is preferably performed on the nitrocellulose .base before the latter is coated with the emulsion. While it is essential that the rear face be treated, there is no harm and a slight benefit as regards static, if the other face of the nitrocellulose base, on which the light-sensitive photographic emulsion is tobe coated, is also superficially saponified at the same time.
The alkaline solution may be applied to the film base by any of the methods and apparatus customarily employed in the art for applyifig liquids to film. For example, where both the surfaces of the nitrocellulose base are to be superficially saponified, the film may be immersed in the dilute alkaline solution. Where only one face of the film is to be treated, the alkaline liquid may be applied to it by floating the film on the surface of the alkalineliquid with only one face in contact, or by applying the liquid to the 'face' by means of a roll over which the film is moved, or by means of brushes or wicks against which the rear face of the film is carried. Where the film base is saponified on both faces by immersion, it is, at the end of the treatment, washed by an immersion in water or by spraying of water or by passing through a countercurrent of water. Thereupon it is dried and coated with sensitive emulsion in the usual way.
When the solution of alkali is applied to only-one face of the film, it is convenient to suspend the film, while such face is wet with the solution, in contact with moist air, that is, an atmosphere of high or nearly saturated humidity. This keeps the wetted face from drying during treatment. After the nitrocellulose at such face has been su erficially saponified by the solution, it is was ed with water and dried. This washing may be by means of a spray or afiotation method or a wick or a brush or any other suitable way of applying 1i uid to only the one face of the film. The film may be also washed by an immersion, spray, or countercurrent system which touches both faces, but I prefer to confine the washing to the treated face only.
While it is preferable, when working on a' manufacturing scale, to treat the rear face of the film base by my process before said base is coated with the photographic sensitive emulsion, nevertheless, it is practical to render anti-static. otherwise finished and coated nitrocellulose motion picture film by the apsilication pf my process to its rear face.
crupulous care must be taken to prevent the treating liquid from reaching the sensitive emulsion on the front face. applying the liquid to the rear face only, while guarding the front face, may be one of those customarily employed for dyeing one sideonly of motion picture films, these being well known to those skilled in the art. r
It has been found that a simple aqueous solution of hydroxid of a concentrationfrom to 5% strength is preferable, the best hydroxids being NILOH, NAOH or KOHJ The use ofan aqueous solution of ammonium hydroxid has the very great advantage that it does away with any difliculties about washing, because both the water and the ammonia volatilize away when brought into a drying atmosphere. an ammonium hydroxid solution is best con fined to the treatment of the nitrocellulose base before it is coated .with' the sensitive emulsion. If it is used in treating film which alrea'dyjcarries an emulsion-,very great precaution must be taken to prevent the ammonia fumes from fogging theemulsion. A.
3% solution of any one of the named hydroxids is a good working'strength. Thus a motion picture film has been renderedsubstantially anti-static by having its rear face hydrolyzed by three hours contact at room temperature with a 3% solution of KOH.
Aqueous solutions of NAOH and ammonium hydroxid of equivalent alkalinity will operate successfully within about the same time.
Even a shorter treatment, say, for instance, of one and one-half hours, gives a very useful effect and the action may be considerably prolonged without any injury to the film. In all-cases the'treatment must be stopped before the transparency and flexibility of the The system of On the other hand, the use' of anddo not involve loss orexpensive recovery of a volatile organic liquid. When an aqueous solution is employed, a small amount of alcohol, say 20% of the weight. of the water,
may be employed as a penetrant, butthis is not essential. Likewise the liquid may be warmed somewhat above room temperature are impaired.
Having thus described my invention, what 1 claim as new. and desire to secure by Letters Patent is:
1.. The process of lowering the static tendency of flexible, transparent, static-producing nitrocellulose .film which includes treating therear face of said film with a solution of an alkali until it is superficially hydrolyzed, the treatment being stopped before its flexibility and transparency are impaired.
J 2. The process of lowering the static tend; ency of flexible, transparent, static-producing nitrocellulose film which includes treating the rear face of said film with an ammonia solu tion until said face is superficially hydrolyzed, said solution being volatilized from said face before the flexibility and transparency of said film are impaired.
3. The process of lowering the static tendency of flexible, transparent, static-producing nitrocellulose film which includes treating the rear-face of said film with an aqueous solution. of soluble alkali hydroxid, until said face is superficially hydrolyzed, stopping the treatment-before the transparency and flexi-- bility of said film are impaired and removing the excess hydroxid from said face.
4. The process of lowering the static tend ency of-fiexible, transparent, static-producing nitrocellulose film which includes treating the rear face of said film with an aqueous solution of ammonium hvdroxid until said face is superficially hydrolyzed, stopping the treatment before the transparency and flexibility of said film are impaired, and volatilizing the water and ammonia from said treated ace.
Signed at Rochester, New' York, this 5th day of October, 1926.
RAY L. STINOHFIELD.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US140695A US1683315A (en) | 1926-10-09 | 1926-10-09 | Process of making antistatic nitrocellulose film |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US140695A US1683315A (en) | 1926-10-09 | 1926-10-09 | Process of making antistatic nitrocellulose film |
Publications (1)
Publication Number | Publication Date |
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US1683315A true US1683315A (en) | 1928-09-04 |
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Application Number | Title | Priority Date | Filing Date |
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US140695A Expired - Lifetime US1683315A (en) | 1926-10-09 | 1926-10-09 | Process of making antistatic nitrocellulose film |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2476240A (en) * | 1943-09-17 | 1949-07-12 | Gen Aniline & Film Corp | Manufacture of photographic film base |
US2829051A (en) * | 1951-07-19 | 1958-04-01 | Ciba Ltd | Photographically sensitive lenticular film |
-
1926
- 1926-10-09 US US140695A patent/US1683315A/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2476240A (en) * | 1943-09-17 | 1949-07-12 | Gen Aniline & Film Corp | Manufacture of photographic film base |
US2829051A (en) * | 1951-07-19 | 1958-04-01 | Ciba Ltd | Photographically sensitive lenticular film |
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