US1625672A - Method of and means for waterproofing textile and other materials - Google Patents
Method of and means for waterproofing textile and other materials Download PDFInfo
- Publication number
- US1625672A US1625672A US83135A US8313526A US1625672A US 1625672 A US1625672 A US 1625672A US 83135 A US83135 A US 83135A US 8313526 A US8313526 A US 8313526A US 1625672 A US1625672 A US 1625672A
- Authority
- US
- United States
- Prior art keywords
- materials
- gum
- weight
- textile
- waterproofing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 title description 22
- 238000000034 method Methods 0.000 title description 9
- 239000004753 textile Substances 0.000 title description 9
- 238000004078 waterproofing Methods 0.000 title description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 17
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 12
- 239000000839 emulsion Substances 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000000243 solution Substances 0.000 description 9
- 229920000569 Gum karaya Polymers 0.000 description 8
- 235000010494 karaya gum Nutrition 0.000 description 8
- 235000019482 Palm oil Nutrition 0.000 description 7
- 241000934878 Sterculia Species 0.000 description 7
- 229910021529 ammonia Inorganic materials 0.000 description 7
- 229910021538 borax Inorganic materials 0.000 description 7
- 239000000231 karaya gum Substances 0.000 description 7
- 229940039371 karaya gum Drugs 0.000 description 7
- 239000002540 palm oil Substances 0.000 description 7
- 239000004328 sodium tetraborate Substances 0.000 description 7
- 235000010339 sodium tetraborate Nutrition 0.000 description 7
- 239000003760 tallow Substances 0.000 description 7
- 239000001993 wax Substances 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 235000011187 glycerol Nutrition 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- 229910021653 sulphate ion Inorganic materials 0.000 description 4
- 244000286663 Ficus elastica Species 0.000 description 3
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920001195 polyisoprene Polymers 0.000 description 3
- 229920002955 Art silk Polymers 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 235000015110 jellies Nutrition 0.000 description 2
- 239000008274 jelly Substances 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- HDUMBHAAKGUHAR-UHFFFAOYSA-J titanium(4+);disulfate Chemical compound [Ti+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O HDUMBHAAKGUHAR-UHFFFAOYSA-J 0.000 description 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 2
- 239000011686 zinc sulphate Substances 0.000 description 2
- 235000009529 zinc sulphate Nutrition 0.000 description 2
- 235000009438 Gossypium Nutrition 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 241001534756 Mungos Species 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 229940082483 carnauba wax Drugs 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- HGOMLSWXJIICBL-UHFFFAOYSA-F dialuminum;zinc;tetrasulfate;tetracosahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Al+3].[Al+3].[Zn+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O HGOMLSWXJIICBL-UHFFFAOYSA-F 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- -1 glyccrine Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 229940056211 paraffin Drugs 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/17—Natural resins, resinous alcohols, resinous acids, or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
Definitions
- This invention relates to an improved method of and means for waterproofing textile and other materials and has for its object so treating textile and other materials as to render them absolutely waterproof.
- the methods hitherto more usually employed for waterproofing-textile materials, particularly when made up into wearing apparel consisted either in the use of india rubber proofing solution, or spirit proofing solution containing wax.
- the use of india rubber proofing solution is hygienically bad inasmuch as articles so treated do not allow a free circulation of air through them and a further drawback to the use of india rubher for such a purpose is that after a while, the india rubber deteriorates and allows Water to pass through the treated material.
- a further advantage arising from the present invention is the fact that clothes made from the cheapest textile materials, such as shoddy or mungo are not only efie'ctually waterproofed in a lasting manner but keep their original shape in wear.
- the material, particularly I in the case of textile materials is preferably treated to a metal sulphate bath aft-er treat- Lnent with the emulsion and then dried by eat.
- the essential feature of the present invention is the use of karaya gum in combination with other well known ingredients for Gum karaya is a little known gum found chiefly in Nyassaland but also in Kenya, New Zealand and the North West Himalayas. This gum is obtained chiefly from a deciduousrtree OoahZospermum gossypium and also from Sfcrculz'a arena. The gum varies in colour from pale yellow to deep brown, has a slight odour of acetic acid and is almost tasteless. It is only slightly soluble in water, an analysis shows that 32.8% is soluble in water, 15.6% is moisture, 2.57% is mineral matter and the remainder is insoluble.
- Karaya gum is then soaked in waterfor about 48 hours in about the proportion of 8 parts by weight of gum with sufficient water to make a total of 100 parts.
- the gum swells up into a jelly like mass but without any trace of stickiness.
- the mass s'o produced is then treated with liquid ammonia (.880) in the-proportion of about 1 part by weight of ammonia to 200 parts by weight Ofwthfi jelly like mass.
- ammonia acts as a solventand produces a .then melted and boiled with a quantity ofthe above described soap and water after which a proportion of the gum slime is added, thoroughly mixed and finally passed through an emulsify'ng machine to bring into an emulsion.
- Convenient proportions of these various ingredients are 4: parts by weight of wax, 1 part by weight of soap, 12 parts by weight of water and 12 parts by weight of the 4% gum slime.
- the textil'e material to be waterproofed is then soaked in this emulsion until thoroughly wetted after which it is wrung out or centrifuged, then passed through about a 2% aqueous solution of titanium sulphate, zinc sulphate or alum, but preferably the titanium sulphate solution is employed.
- the material is then wrung out or centrifuged and dried at a temperature of approximately 120 F.
- the material after treatment in the sulphate or fixing bath is rinsed in water before drying.
- a slightly larger percentage of wax (about 10% extra) is preferably employed and the sulphate or fixing bath is omitted.
- the paper after manufacture is preferably passed through rollers in a trough containing the emulsion and then through a calendering machine to dry it.
- a suita le dye may be added to the emulsion so as to produce a surface dyeing and waterproofing at one operation.
- the emulsion may be added to the pulp before manufacture.
- a process for waterproofing textile ma terial consisting firstly in treating the mate I rial with an emulsion of palm oil, tallow, ammonia, glycerine, borax, wax and karaya gum and secondly with a metallic sulphate solution and finally drying by heat, as set forth.
- a water proofing solution comprising an emulsion of palm oil, tallow, ammonia, glycerine, borax, wax and karaya gum, as set forth.
- a process for waterproofing textile and other material consisting in soaking the material with an emulsion of palm oil, tallow, ammonia, glyccrine, borax, paraffin and carnaubawax, and karaya gum, wringing or centrifuging the soaked material, treating with an aqueous solution of titanium or zinc sulphate, then wringing or centrifuging and finally drying by'heat, as set forth.
- a process for the production of a waterproofing 'solution consisting firstly in preparing a soap by boiling together palm oil, tallow, glycerine, nia, secondly soaking karaya gum in water 'elly like mass and then dissolving the mass in liquid ammonia to produce a slime which is then diluted with water and thirdly in thoroughly mixing the soap and diluted slime together by passing ghlOfllgh an emulsifying machine, as set ort CHARLES JOSEPH MORETON.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Paper (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1625672X | 1925-12-24 | ||
| GB2065627A GB305493A (en) | 1927-08-05 | 1927-08-05 | Improved method of and means for waterproofing textile and other materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1625672A true US1625672A (en) | 1927-04-19 |
Family
ID=26254805
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US83135A Expired - Lifetime US1625672A (en) | 1925-12-24 | 1926-01-22 | Method of and means for waterproofing textile and other materials |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US1625672A (online.php) |
| BE (1) | BE358344A (online.php) |
| FR (1) | FR669917A (online.php) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3004269A (en) * | 1957-02-19 | 1961-10-17 | Bernauer & Co A | Lifesaving devices |
| US3272640A (en) * | 1960-12-22 | 1966-09-13 | Hercules Powder Co Ltd | Water insolubilizing and insensitizing process |
| US3476582A (en) * | 1965-04-05 | 1969-11-04 | Kuraray Co | Method of improving the water resistance of paper |
| US3477512A (en) * | 1967-12-15 | 1969-11-11 | American Cyanamid Co | Oil well fracturing method using wax emulsions |
| US3481764A (en) * | 1965-04-22 | 1969-12-02 | Sumitomo Naugatuck | Method for producing coated papers |
-
0
- BE BE358344D patent/BE358344A/xx unknown
-
1926
- 1926-01-22 US US83135A patent/US1625672A/en not_active Expired - Lifetime
-
1929
- 1929-02-20 FR FR669917D patent/FR669917A/fr not_active Expired
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3004269A (en) * | 1957-02-19 | 1961-10-17 | Bernauer & Co A | Lifesaving devices |
| US3272640A (en) * | 1960-12-22 | 1966-09-13 | Hercules Powder Co Ltd | Water insolubilizing and insensitizing process |
| US3476582A (en) * | 1965-04-05 | 1969-11-04 | Kuraray Co | Method of improving the water resistance of paper |
| US3481764A (en) * | 1965-04-22 | 1969-12-02 | Sumitomo Naugatuck | Method for producing coated papers |
| US3477512A (en) * | 1967-12-15 | 1969-11-11 | American Cyanamid Co | Oil well fracturing method using wax emulsions |
Also Published As
| Publication number | Publication date |
|---|---|
| BE358344A (online.php) | |
| FR669917A (fr) | 1929-11-22 |
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