US1462840A - Method of determining free-phosphoric-acid content - Google Patents
Method of determining free-phosphoric-acid content Download PDFInfo
- Publication number
- US1462840A US1462840A US553739A US55373922A US1462840A US 1462840 A US1462840 A US 1462840A US 553739 A US553739 A US 553739A US 55373922 A US55373922 A US 55373922A US 1462840 A US1462840 A US 1462840A
- Authority
- US
- United States
- Prior art keywords
- acid
- phosphoric
- acid content
- determining
- determining free
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 title description 18
- 238000000034 method Methods 0.000 title description 13
- 229910000147 aluminium phosphate Inorganic materials 0.000 title description 10
- 229960004838 phosphoric acid Drugs 0.000 title description 10
- 239000002253 acid Substances 0.000 description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 229910019142 PO4 Inorganic materials 0.000 description 11
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 11
- 239000010452 phosphate Substances 0.000 description 11
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 4
- 235000011121 sodium hydroxide Nutrition 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 235000011118 potassium hydroxide Nutrition 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
- G01N31/16—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using titration
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/15—Inorganic acid or base [e.g., hcl, sulfuric acid, etc. ]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/16—Phosphorus containing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/25—Chemistry: analytical and immunological testing including sample preparation
- Y10T436/25375—Liberation or purification of sample or separation of material from a sample [e.g., filtering, centrifuging, etc.]
- Y10T436/255—Liberation or purification of sample or separation of material from a sample [e.g., filtering, centrifuging, etc.] including use of a solid sorbent, semipermeable membrane, or liquid extraction
Definitions
- This invention relates to methods of determining the free phosphoric acid content of acid phosphate, and more particularly to a method. of direct determination in-which precipitation of the free acid is unnecessary.
- the free phosphoric acid is extracted from the acid phosphate by means of an alcoholic solution and is then titrated with an alkalim'etal hydroxide such as caustic soda or caustic potash.
- an alkalim'etal hydroxide such as caustic soda or caustic potash.
- phenolphthalein is used as an indicator.
- a hydroxide of known strength is used in order to obtain the percentage of phosphoric acid present in the acid phosphate as free phosphoric acid.
- a gram of the fresh made acid phosphate is placed in a metallic flask with one hundred cubic centimeters of 95 per cent alcohol.
- 'Steel-balls of about live eighths of an inch diameter are used in the flask to aid in the digestion.
- the flask is closed with a rubber stopper and the contents are given a whirling motion for about five minutes.
- the solution then filtered and twentycubic centimeters titrated with caustic soda The number of cubic centimeters is divided by two in order to reduce the determination to a. one tenth gram basis.
- caustic soda or caustic potash of 3.11 normal strength is employed.
- the strength of the solution may be 3.11 normal strength.
- Phenolphthalein is used as indicator.
- the free phosphoric acid content of acid phosphate may be readily and quickly determined.
- the process of determining the free phosphoric acid content of acid phosphate which comprises extracting the acid from a known amount of acid phosphate with a known quantity of alcohol, and tili'ating the solution obtained with caustic soda.
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Molecular Biology (AREA)
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Description
' or caustic potash.
Patented July 24, 192
"1? A A T E FlCE- No Drawing.
To all whom it may concern:
Be it known that 1, JAMES F. IVrLKINsoN, a citizen of the United States, residing at Savannah; in the county of Chatham and State of Georgia, have invented certain new and useful Improvements in Methods of Determining Free-Phosphoric-Acid Content, of which the following is a specification.
This invention relates to methods of determining the free phosphoric acid content of acid phosphate, and more particularly to a method. of direct determination in-which precipitation of the free acid is unnecessary.
The free phosphoric acid is extracted from the acid phosphate by means of an alcoholic solution and is then titrated with an alkalim'etal hydroxide such as caustic soda or caustic potash. In determining the acidity phenolphthalein is used as an indicator.
In titrating the acid a hydroxide of known strength is used in order to obtain the percentage of phosphoric acid present in the acid phosphate as free phosphoric acid.
In practice of the process, a gram of the fresh made acid phosphate is placed in a metallic flask with one hundred cubic centimeters of 95 per cent alcohol. 'Steel-balls of about live eighths of an inch diameter are used in the flask to aid in the digestion. The flask is closed with a rubber stopper and the contents are given a whirling motion for about five minutes.
The solution then filtered and twentycubic centimeters titrated with caustic soda The number of cubic centimeters is divided by two in order to reduce the determination to a. one tenth gram basis.
In the titration caustic soda or caustic potash, of 3.11 normal strength is employed. The strength of the solution, however, may
be varied, but in varying the strength the" number of cubic centimeters of the alkali hydroxid is varied accordingto the strength;
if the strength of the solutionisdoubled the METHOD or DETERMINING nnnE-rHosrHoRIc-Acm CONTENT.
A ncauommea April 17, 1922. s an No. 553,739.
number of cubic centimeters used is doubled to obtain the proper percentage of tree phosphoric acid. Phenolphthalein is used as indicator.
By means of the present process the free phosphoric acid content of acid phosphate may be readily and quickly determined.
In the manufacture of acid phosphate thereis always a certain amountof tree phosphoric acid present depending upon the amount of sulphuric acid used in the manufacture. The present process may be used as a guide to proper acidulation in the process of manufacturing acid phosphate.
IVhile I have described, in detail, the preferred practice of my process, it is to be understood that the details of the procedure, and the proportions of ingredients may be widely varied, and that known chemical equivalents may be used in place of the ma terials mentioned, without departing from the spirit of the invention or, the scope of the subjoined claims.
, Having described any invention, I claim l. The process of determining the frephosphoric acid content of acid phosphate which comprises extracting the acid from a known amount of acid phosphate with a known quantity of alcohol, and titrat-ing the solution obtained with an alkali-metal hydroxid.
The process of determining the free phosphoric acid content of acid phosphate which comprises extracting the acid from a known amount of acid phosphate with a known quantity of alcohol, and tili'ating the solution obtained with caustic soda.
In testimonywhereot' I afiix my signature in presence of two Witnesses.
JAMES F. WILKINSON.
Witnesses:
W. W. CONNELL, J. C. PETERS.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US553739A US1462840A (en) | 1922-04-17 | 1922-04-17 | Method of determining free-phosphoric-acid content |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US553739A US1462840A (en) | 1922-04-17 | 1922-04-17 | Method of determining free-phosphoric-acid content |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1462840A true US1462840A (en) | 1923-07-24 |
Family
ID=24210555
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US553739A Expired - Lifetime US1462840A (en) | 1922-04-17 | 1922-04-17 | Method of determining free-phosphoric-acid content |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1462840A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2937930A (en) * | 1956-01-25 | 1960-05-24 | Geld Isidore | Compositional control method |
-
1922
- 1922-04-17 US US553739A patent/US1462840A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2937930A (en) * | 1956-01-25 | 1960-05-24 | Geld Isidore | Compositional control method |
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