US1193429A - Peter schmid and karl gross - Google Patents
Peter schmid and karl gross Download PDFInfo
- Publication number
- US1193429A US1193429A US1193429DA US1193429A US 1193429 A US1193429 A US 1193429A US 1193429D A US1193429D A US 1193429DA US 1193429 A US1193429 A US 1193429A
- Authority
- US
- United States
- Prior art keywords
- silk
- chlorid
- schmid
- gross
- karl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910000318 alkali metal phosphate Inorganic materials 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/20—Halides of elements of Groups 4 or 14 of the Periodic Table, e.g. zirconyl chloride
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
- Y10S8/916—Natural fiber dyeing
- Y10S8/917—Wool or silk
Definitions
- weighting ofsilk is generally carried out by treating the silk alternately with metal chlorid baths (preferably with tin chlorid baths) and with alkali metal phosphate baths and finally with an.
- Example I In 2 liters zinc chlorid of 54 to Baum are introduced 100 grams pure silk and 100 gr. silkworm-chrysalises (these 200 gr. silk and chrysalises are dissolved in the zinc chloridbath at a low temperature). To this solution is added the quantity of tin chlorid necessary to obtain a mixture containing equal quantities of both chlorids and this mixture is then diluted with water till a solution of 27 to 28 Baum is obtained.
- Example II 100 gr. pure silk and 100 gr.
- tin chlorid can be replaced by zinc chlorid.
- the silk weighting bath can be prepared by substituting for the silk and the chrysalises the product obtained by boiling the same with water.
- the new silk weighting baths are applied 1n the usual manner in liquid form to the silk, while the phosphate baths alternating with them may be employed in form of liquid or of froth. Obviously common salt and acid may be added where necessary to the silk weighting bath.
- the use of the new silk weighting bath has the advantage that when a mixture of zinc chlorid and tin chlorid is employed for weighting silk, the same satisfactory results are obtained as by employing the more expensive tin chlorid alone. In all cases the silk weighted by use of the new metal chlorid bath shows a better afiinity for the dye.
- a metal chlorid bath. for weighting silk comprising a solution of at least one metal chlorid with silk and silkworm-chrysalises,
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Woven Fabrics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
PETER SCHMID AND KARL GROSS, 0E BASEL, SWITZERLAND; SAID GROSS ASSIGNOR TO SAID SCHMID.
' METAL-CHLORID BATH FOR WEIGHTING SILK.
No Drawing.
To all whom it may concern:
Be it known that we, PETER SCHMID, a citizen of the Swiss Republic, and KARL Gross, a subject of the King of Prussia, both residing in Basel, Switzerland,-have invented a new Metal-Chlorid Bath for Weighting Silk, of which the following is a full, clear, and exact specification.
It is known that the weighting ofsilk is generally carried out by treating the silk alternately with metal chlorid baths (preferably with tin chlorid baths) and with alkali metal phosphate baths and finally with an.
bath can be advantageously a silk waste,
which already may contain silkworm-chrys alises, as for instance bassinets (Italian gallettamini, French palettes).
The preparation of the new silk weighting bath is illustrated by the following examples:
Example I: In 2 liters zinc chlorid of 54 to Baum are introduced 100 grams pure silk and 100 gr. silkworm-chrysalises (these 200 gr. silk and chrysalises are dissolved in the zinc chloridbath at a low temperature). To this solution is added the quantity of tin chlorid necessary to obtain a mixture containing equal quantities of both chlorids and this mixture is then diluted with water till a solution of 27 to 28 Baum is obtained.
Example II: 100 gr. pure silk and 100 gr.
. silkworm-chrysalises are dissolved in 2 liters tin chlorid of about 27 Baum. In this Specification of Letters Patent.
Patented Aug. 1, 1916.
Application filed October 7, 1915. Serial No. 54,499.
example the tin chlorid can be replaced by zinc chlorid.
In all examples the indicated proportion of sllk and chrysalises may be varied, also the proportion of tin chlorid and zinc chlorid in Example I can be varied.
In all examples the silk weighting bath can be prepared by substituting for the silk and the chrysalises the product obtained by boiling the same with water. The new silk weighting baths are applied 1n the usual manner in liquid form to the silk, while the phosphate baths alternating with them may be employed in form of liquid or of froth. Obviously common salt and acid may be added where necessary to the silk weighting bath.
The use of the new silk weighting bath has the advantage that when a mixture of zinc chlorid and tin chlorid is employed for weighting silk, the same satisfactory results are obtained as by employing the more expensive tin chlorid alone. In all cases the silk weighted by use of the new metal chlorid bath shows a better afiinity for the dye.
What we claim is:
1. A metal chlorid bath. for weighting silk comprising a solution of at least one metal chlorid with silk and silkworm-chrysalises,
ber 1915, in the presence of two subscribing witnesses.
PETER SCHMID. KARL GROSS.
Witnesses:
ARNOLD ZUBER, AMAND BITTER.
Publications (1)
Publication Number | Publication Date |
---|---|
US1193429A true US1193429A (en) | 1916-08-01 |
Family
ID=3261380
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US1193429D Expired - Lifetime US1193429A (en) | Peter schmid and karl gross |
Country Status (1)
Country | Link |
---|---|
US (1) | US1193429A (en) |
-
0
- US US1193429D patent/US1193429A/en not_active Expired - Lifetime
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