US1057281A - Oxygen bath. - Google Patents
Oxygen bath. Download PDFInfo
- Publication number
- US1057281A US1057281A US55771710A US1910557717A US1057281A US 1057281 A US1057281 A US 1057281A US 55771710 A US55771710 A US 55771710A US 1910557717 A US1910557717 A US 1910557717A US 1057281 A US1057281 A US 1057281A
- Authority
- US
- United States
- Prior art keywords
- manganese
- water
- bath
- peroxid
- oxygen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title description 10
- 239000001301 oxygen Substances 0.000 title description 10
- 229910052760 oxygen Inorganic materials 0.000 title description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 9
- 230000003197 catalytic effect Effects 0.000 description 9
- 229910052748 manganese Inorganic materials 0.000 description 9
- 239000011572 manganese Substances 0.000 description 9
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 7
- GOPYZMJAIPBUGX-UHFFFAOYSA-N [O-2].[O-2].[Mn+4] Chemical compound [O-2].[O-2].[Mn+4] GOPYZMJAIPBUGX-UHFFFAOYSA-N 0.000 description 6
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 229910021538 borax Inorganic materials 0.000 description 3
- 244000144992 flock Species 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000004328 sodium tetraborate Substances 0.000 description 3
- 235000010339 sodium tetraborate Nutrition 0.000 description 3
- 229940095064 tartrate Drugs 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- -1 albumen Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000005018 casein Substances 0.000 description 2
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 2
- 235000021240 caseins Nutrition 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000012286 potassium permanganate Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 2
- 229930182490 saponin Natural products 0.000 description 2
- 150000007949 saponins Chemical class 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000002906 tartaric acid Nutrition 0.000 description 2
- 239000011975 tartaric acid Substances 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 240000004670 Glycyrrhiza echinata Species 0.000 description 1
- 235000001453 Glycyrrhiza echinata Nutrition 0.000 description 1
- 235000006200 Glycyrrhiza glabra Nutrition 0.000 description 1
- 235000017382 Glycyrrhiza lepidota Nutrition 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- 241000282342 Martes americana Species 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000008131 herbal destillate Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 1
- 229940010454 licorice Drugs 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 1
- 229910000342 sodium bisulfate Inorganic materials 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000003892 tartrate salts Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/02—Preparation of oxygen
- C01B13/0203—Preparation of oxygen from inorganic compounds
- C01B13/0218—Chlorate
Definitions
- Our invention relates to oxygen baths.
- the principal objects in the preparation of oxygen baths by a catalytic process are to decompose the peroxid, as evenly as possible during the continuance of the bath, to reduce the diameters of the free bubbles of oxygen as much as possible, and to obtain the highest possible degree of saturation of the water of the bath with oxygen.
- suflicient quantities of oxygen to precipitate on the skin of the bathing person in the form of adhesive bubbles, can only be brought into practical eli'ect by-the production of a high degree of super-saturation. For this reason, the selection of a suitable catalytic is very important.
- hydrosol of manganese dioxid does not form flocks, as hereinbefore described, even when perborate, percarbonate, and the like, are used as electrolytes, although the metal-. hydrosols, as is well known, do not act con sistently with even small quantities of electrolytes.
- the colloidal peroxid of manganese may be used in solution or in a dry state, and either alone or in combination with other substances.
- the finished hydrosol of manganese dioxid may be dissolved in the water of thebath or formed in the bath water from soluble salts of manganese, such as tartrate of manganese, chlorid of manga-. nese, and sulfate of manganese, and also from potassium permanganate by the influence of the oxygen in state; nascendz', but only very small quantities of said ingredients should be used.
- hydrosol which can be seen from the yellow color of the water, is promoted by the presence of certain acids and salts, especially tartaric acid, tartrates, bisulfate, carbonate, bicarbonate and borax.
- acids and salts especially tartaric acid, tartrates, bisulfate, carbonate, bicarbonate and borax.
- the stability of the hydrosol is increased by using, at the same time, a so-called protective colloid such as albumen, gelatin, casein, dextrin, sugar, glycerin, gum, saponin, licorice, starchy substances, or compositions of the same.
- One Way'of preparing a bath in accordance with our invention is to dissolve either 300 grams of perborate. of sodium, 150 grams peroxid of sodium or 2, liters of perand so-called protective colloids may be 10 to add sodium carbonate, borax, or the like, 0
- oxid ofhydro en in 250 liters of water, and afterward ad a colloidal solution of dioxid of manganese hich contains 0.42 gram of dioxid'of manganese.
- 0.5 oxygen baths comprising a substance capagram of permanganate of potassium or 4 'ble on contact with water, of setting free grams of sulfate of manganese may be used.
- hydrogen peroxid and a substance which,
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Description
marten sparse rarer @FFKQE.
LEOPOLD SARASON, OF BERLIN, .AND Ell/LIL FRANKE, OF GR'lZiNAU, NEAR BERLIN, GERMANY; SAID FRANKE ASSIGNOR TO SAID SAMSON.
QXYGEN BATH.
1l,57,281l. Ito Drawing.
Specification of Letters Patent.
Patented Mar. 19113.
Application filed Apri126; 1910. Serial No. 557,717.
To all whom, it may concern Be it known that we, LEOPOLD SARASON and Earn. FRANKE, subjects of the King of Prussia, German Emperor, and residing, respectively, at Berlin and Griinau, near Berlin, Germany, have invented certain new and useful Improvements in Oxygen Baths; and We do hereby declare the followin to be a full, clear, and exact description of t e invention, such as will enable others skilled in the art to which it appertains to make and use the same.
Our invention relates to oxygen baths.
The principal objects in the preparation of oxygen baths by a catalytic process are to decompose the peroxid, as evenly as possible during the continuance of the bath, to reduce the diameters of the free bubbles of oxygen as much as possible, and to obtain the highest possible degree of saturation of the water of the bath with oxygen. As the normal power of absorption of the water, at bath temperature, is very slight, suflicient quantities of oxygen, to precipitate on the skin of the bathing person in the form of adhesive bubbles, can only be brought into practical eli'ect by-the production of a high degree of super-saturation. For this reason, the selection of a suitable catalytic is very important.
Of all the catalytics which have been used for oxygen baths, peroxid of manganese, either in a finished state or statu nascendz', has proved to be the best. Even when this catalytic is used, it requires large quantities of it for eifectively accomplishin the desired result. Furthermore, peroxi of manganese, as heretofore used, produces flocks of floating undecomposed' material which are undesirable because they soil the skin and the bath receptacles. Under preexisting conditions a bath of 250 liters of water required from 8.75 grams to 12?; grams of peroxid of manganese and 300 grams of perborate of sodium, andthe degree of super-saturation obtained Was very slight, only from 2.2% to 3.5% of the volume after thirty minutes. 7
We have discovered that a better effect is obtained by the use of colloidal peroxid of manganese than by the use of any of the heretofore known catalytics. A very much smaller quantity of this new catalytic will suflice in the same proportions of water and oerborate of sodium. For instance, in 250 liters of water and 300 grams of perborate of sodium, only 0.42 gram of colloidal peroxid of manganese is required. In spite of the small quantity of this catalytic which is employed, the degree of supersaturation obtained is about 5.1% of the volume and the bubbles are much smaller in diameter than when insoluble manganese dioxid is used. The hydrosol of manganese dioxid is only active with alkaline reaction of the water of the bath. It is particularly surprising that the hydrosol of manganese dioxid does not form flocks, as hereinbefore described, even when perborate, percarbonate, and the like, are used as electrolytes, although the metal-. hydrosols, as is well known, do not act con sistently with even small quantities of electrolytes.
The colloidal peroxid of manganese may be used in solution or in a dry state, and either alone or in combination with other substances. The finished hydrosol of manganese dioxid may be dissolved in the water of thebath or formed in the bath water from soluble salts of manganese, such as tartrate of manganese, chlorid of manga-. nese, and sulfate of manganese, and also from potassium permanganate by the influence of the oxygen in state; nascendz', but only very small quantities of said ingredients should be used. For instance, from three to four rams of sulfate of manganese or tartrate of manganese, or 0.5 gram of potassium permanganate are usually sufiiment for the formation of the hydrosol of manganese dioxid. If larger quantitiesof these ingredients are used, the manganese dioxid is not converted into the active colloidal solution but appears in the more inactive flocks.
The formation of the hydrosol, which can be seen from the yellow color of the water, is promoted by the presence of certain acids and salts, especially tartaric acid, tartrates, bisulfate, carbonate, bicarbonate and borax. The stability of the hydrosol is increased by using, at the same time, a so-called protective colloid such as albumen, gelatin, casein, dextrin, sugar, glycerin, gum, saponin, licorice, starchy substances, or compositions of the same.
One Way'of preparing a bath in accordance with our invention is to dissolve either 300 grams of perborate. of sodium, 150 grams peroxid of sodium or 2, liters of perand so-called protective colloids may be 10 to add sodium carbonate, borax, or the like, 0
in order to obtain the alkaline reaction.
e We claim:
oxid ofhydro en, in 250 liters of water, and afterward ad a colloidal solution of dioxid of manganese hich contains 0.42 gram of dioxid'of manganese. 'If preferred, in. lieu A composition adapted of the solution of dioxid of manganese, 0.5 oxygen baths, comprising a substance capagram of permanganate of potassium or 4 'ble on contact with water, of setting free grams of sulfate of manganese may be used. hydrogen peroxid, and a substance which,
s already explained, other acids and salts on contact with the water containin hgdrogen peroxid, will be changed into y rosol of manganese 'dioxid for breaking up the hydrogen eroxid.
In testimony whereof, we aflix our signatures, in presence of two witnesses.
LEOPOLD SABASON.
for preparing used. For instance, from 8 to 10 gramsof tartaric acid, a tartrate or sodium bisulfate, or sodium carbonate, or borax, and 5 grams of casein, albumen, saponin, or the like, may be used with the quantities ofwater, catalytics, etc., given in theabove example."
It shoul be-understood that the order in Y which the rborate and the catalytic are Witnesses: p v added to the water may be reversed. When WOLDEMAR Ham,-
peroxid of hydrogen is used, it is necessary ARTHUR SCHROEDER.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US55771710A US1057281A (en) | 1910-04-26 | 1910-04-26 | Oxygen bath. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US55771710A US1057281A (en) | 1910-04-26 | 1910-04-26 | Oxygen bath. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1057281A true US1057281A (en) | 1913-03-25 |
Family
ID=3125534
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US55771710A Expired - Lifetime US1057281A (en) | 1910-04-26 | 1910-04-26 | Oxygen bath. |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1057281A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2498343A (en) * | 1944-08-10 | 1950-02-21 | Lever Brothers Ltd | Denture cleansers |
-
1910
- 1910-04-26 US US55771710A patent/US1057281A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2498343A (en) * | 1944-08-10 | 1950-02-21 | Lever Brothers Ltd | Denture cleansers |
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