US10385273B2 - Biochar kiln - Google Patents

Biochar kiln Download PDF

Info

Publication number
US10385273B2
US10385273B2 US15/453,502 US201715453502A US10385273B2 US 10385273 B2 US10385273 B2 US 10385273B2 US 201715453502 A US201715453502 A US 201715453502A US 10385273 B2 US10385273 B2 US 10385273B2
Authority
US
United States
Prior art keywords
kiln
biochar
biochar kiln
stack
subsystem
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active, expires
Application number
US15/453,502
Other versions
US20170283703A1 (en
Inventor
Mikel Olander
II Perry Pierce
William T. Beierwaltes
II James G. Gaspard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Biocharnow LLC
Original Assignee
BIOCHAR NOW LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BIOCHAR NOW LLC filed Critical BIOCHAR NOW LLC
Priority to US15/453,502 priority Critical patent/US10385273B2/en
Assigned to BIOCHARNOW, LLC reassignment BIOCHARNOW, LLC ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: OLANDER, MIKEL, BEIERWALTES, WILLIAM T, GASPARD, JAMES G, PIERCE, PERRY
Priority to CA2962293A priority patent/CA2962293C/en
Publication of US20170283703A1 publication Critical patent/US20170283703A1/en
Assigned to BIOCHAR NOW, LLC reassignment BIOCHAR NOW, LLC CORRECTIVE ASSIGNMENT TO CORRECT THE LAST RECEIVING PARTY NAME PREVIOUSLY RECORDED AT REEL: 41508 FRAME: 784. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Assignors: OLANDER, MIKEL, BEIERWALTES, WILLIAM T., GASPARD, JAMES G., II, PIERCE, PERRY
Priority to US16/503,875 priority patent/US10883052B2/en
Assigned to BIOCHAR NOW, LLC reassignment BIOCHAR NOW, LLC CORRECTIVE ASSIGNMENT TO CORRECT THE THE ASSIGNOR'S NAME FROM PERRY PIERCE TO PERRY PIERCE II PREVIOUSLY RECORDED ON REEL 049450 FRAME 0327. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Assignors: OLANDER, MIKEL, BEIERWALTES, WILLIAM T., GASPARD, JAMES G., II, PIERCE, PERRY, II
Application granted granted Critical
Publication of US10385273B2 publication Critical patent/US10385273B2/en
Active legal-status Critical Current
Adjusted expiration legal-status Critical

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B1/00Retorts
    • C10B1/02Stationary retorts
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • F23G5/027Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • F23G5/027Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
    • F23G5/0276Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage using direct heating
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/40Portable or mobile incinerators
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/10Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of field or garden waste or biomasses
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23LSUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
    • F23L1/00Passages or apertures for delivering primary air for combustion 
    • F23L1/02Passages or apertures for delivering primary air for combustion  by discharging the air below the fire
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2209/00Specific waste
    • F23G2209/26Biowaste
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel

Definitions

  • Biochar is made from biomass (trees, agricultural waste, etc.) in an oxygen deprived, high temperature environment. Quality biochar has high purity, absorptivity and cation exchange capacity. This can provide significant benefits to several large markets including, but not limited to, agriculture, pollution remediation, odor sequestration, separation of gases, and oil and gas clean up.
  • FIG. 1 is a perspective view of an example biochar kiln.
  • FIG. 2 is an interior view of a floor of the example biochar kiln, illustrating a ventilation subsystem.
  • FIG. 3 is a close-up view of the ventilation subsystem shown in FIG. 2 .
  • FIG. 4 is another close-up view of the ventilation subsystem shown in FIG. 2 .
  • FIGS. 5-8 are close-up views of the exterior of the example biochar kiln, illustrating the ventilation subsystem.
  • FIGS. 9-10 are perspective views of example components of an ember suppression subsystem of the biochar kiln.
  • FIG. 11 is a perspective view of an example stack subsystem of the biochar kiln.
  • FIG. 12 is a high-level block diagram of an example control subsystem of the biochar kiln.
  • FIG. 13-23 are illustrations of example insulation of the biochar kiln shown in FIG. 1 .
  • a biochar kiln is disclosed, including construction of the kiln and various subsystems such as, but not limited to, ventilation, stack, control, insulation, and ember suppression.
  • the kiln may be implemented to produce biochar.
  • the kiln is configured for internal combustion and heat generation as needed, to convert biomass into biochar.
  • the kiln may experience frequent and wide thermal cycling. For example, every 2 days, the kiln temperatures can vary between ⁇ 30 and +1300 degrees Fahrenheit (e.g., stack temperature ranges from ⁇ 30 F to 1850 F).
  • the biochar kiln is configured to support slow pyrolysis and can accommodate a number of variables. Variables include, but are not limited to, a “green” and/or dry feedstock, large and/or small pieces of the feedstock, various and multiple different species of the feedstock, and operation according to variable processing times.
  • the biochar kiln is robust in that it may be operated under a number of variable operating conditions, while still producing a consistent and high quality biochar product.
  • the biochar kiln may include a local and dedicated process control system.
  • the control system may be implemented with a ventilation subsystem, an ember suppression subsystem, and airflow management or “stack” subsystem, to help ensure high quality and high yield biochar is produced while simultaneously complying with emissions standards.
  • the biochar kiln has multi-zone combustion cells that are computer-controlled to maintain target temperatures while creating faster burns. Multi-zone servo dampers are computer-control to manage inlet air flows to the combustion cells to support optimum heating.
  • the biochar kiln may also have removable stacks and a stack hole sealing mechanism.
  • the kiln may also be configured for negative flue gas pressure to eliminate fugitive emissions.
  • the terms “includes” and “including” mean, but is not limited to, “includes” or “including” and “includes at least” or “including at least.”
  • the term “based on” means “based on” and “based at least in part on.”
  • FIG. 1 is a perspective view of an example biochar kiln 10 .
  • the biochar kiln 10 may include a main body portion 12 and a lid 14 .
  • the main body portion 12 is configured to receive a feedstock (not shown) by removing the lid 14 and loading the feedstock before replacing the lid 14 .
  • the biochar kiln further includes a base portion 16 .
  • the base portion 16 may be configured such that it is raised off of the ground. This enables airflow under the main body portion 12 .
  • a ring 18 may also be implemented to lift the biochar kiln 10 , e.g., using a loader tractor, forklift or other suitable machinery.
  • the kiln wall 20 may be made of a one-piece, rolled wall.
  • Body welds, where needed are made on curved surfaces to lower structural and thermal stress to those joints.
  • the floor 24 may also be a one-piece heavy gauge, high strength steel.
  • the floor 24 may be downward elliptical-shaped (the shape being visible in FIG. 1 and FIG. 5 ) to withstand heavy falling wood chunks during filling.
  • the surface of the floor 24 is curved and has only one weld joint along the perimeter where it joins with the wall 20 .
  • the floor 20 and walls 20 may anneal with use, which also serves to relieve stress.
  • FIG. 2 is an interior view of a floor 20 of the example biochar kiln 10 , illustrating a ventilation subsystem 24 .
  • the ventilation subsystem 24 may include a plurality of semi-independent combustion cells 25 a - g . In the example shown, there is a combustion cell 25 g in the center, and six combustion cells 25 a - f between the center cell 25 g and the kiln wall 20 . An outside vent pipe 28 a - f leads to the center of each cell to provide combustion air.
  • FIG. 3 is a close-up view of the ventilation subsystem 24 shown in FIG. 2 .
  • FIG. 4 is another close-up view of the ventilation subsystem 24 shown in FIG. 2 .
  • thermowell tubes 26 a - g may be built into the floor 20 for each combustion cell 25 a - f .
  • the thermowell tubes 26 a - f may be positioned adjacent vent pipes or air inlets 28 a - f .
  • Another thermowell tube 26 g may be positioned substantially in the center of the floor 20 , e.g., for combustion cell 25 g .
  • the thermowell tubes 26 a - g may be configured with monitors to enable interior biochar temperature sensing while the biochar is cooking.
  • FIGS. 5-8 are close-up views of the exterior of the example biochar kiln, illustrating a ventilation subsystem 30 .
  • the ventilation subsystem 30 includes ports 32 around the perimeter of the body 12 of the biochar kiln 10 . Each of the ports 32 is connected to the internal air inlets 28 a - f . These ports may be closed (e.g., as shown in FIG. 5 ) and opened manually, or via computer control.
  • an automatic control including dampers 34 with air inlet 36 which can be connected to a gas line 38 to a main line 40 to supply ignition gas into the chamber formed in the body 12 of the biochar kiln 10 .
  • the dampers 34 are each attached to the outside portion of the corresponding vent pipes 28 a - f to provide computer-controlled airflow.
  • Each damper has a servo-controlled butterfly valve 42 to regulate airflow. Damper airflow results from negative pressure in the kiln (the vacuum sucks air in), or can be blown in by an external blower or both.
  • the ventilation subsystem 30 may be implemented with the control system described herein to provide a controlled airflow, thus enabling a carefully controlled burn and emissions control.
  • each servo is computer-controlled and provides physical position feedback to the computer to confirm the valve's position. The feedback enables the computer control to determine whether a valve is working, blocked or failed.
  • servo accuracy is about +/ ⁇ 0.5 degrees to permit precise control.
  • the kiln is equipped with one or more pressure transducer(s) to insure negative kiln pressure.
  • Air vent pipes for each combustion cell may also pass through the floor flange. After a burn, the vent pipes can be sealed with cam-lock caps to help cut off oxygen, stop combustion and cool the biochar.
  • dampers 34 are removed from the vent pipe openings 32 and replaced with airtight, gasket cam-lock caps 33 (shown in FIG. 4 ) over the vent pipe openings 32 .
  • the dampers 34 are then temporally secured to the kiln wall during kiln transit or moved to another kiln for further use.
  • Damper wiring may be routed to a kiln-mounted control board to eliminate the need to unplug and plug damper wiring when the kiln travels to and from the workstations.
  • the damper assembly 34 provides a computer-controlled gas-start system to ignite the wood during a fresh burn. Gas flow is turned by the computer via a gas solenoid.
  • gas is piped into the assembly where it flows through a venturi pulling in air to the air/gas mix tube before being exposed to a preheated glow plug igniter.
  • the ignited gas then travels by a thermocouple probe to verify its ignition and down the vent pipe to start the wood fire at its combustion cell.
  • FIGS. 9-10 are perspective views of example components 46 and 48 of an ember suppression subsystem 44 of the biochar kiln 10 .
  • An ember suppression subsystem 44 is provided in the event ember suppression is needed after a burn.
  • a gas 46 e.g., nitrogen, carbon dioxide, and/or other inert gases
  • carbon dioxide is utilized because it is about two times heavier than air, which enables the biochar to flood a kiln from the bottom up so it can be processed the next morning. Without oxygen, there is no combustion and the embers are put out (stop burning) to allow the biochar to cool down.
  • suppression gases can be managed by a regulator 48 ( FIG. 10 ) at port 32 or other suitable location, to maintain a low, positive kiln pressure. This helps keep fresh air from entering the kiln.
  • the control system can turn off the gas supply.
  • a safe temperature is about 300 F to 400 F (e.g., it is noted that the auto ignition temperature of wood is about 570 F).
  • the ember suppression subsystem may also be implemented at least in part in the lid.
  • the lid has a gasket attached to it at the perimeter.
  • the gasket gets squeezed between lid flange located above the gasket and the flange on the kiln rim below.
  • the gasket reduces or prevents air leaks during ember suppression.
  • the gasket also helps retain fugitive smoke in the kiln (e.g., in case of a short term negative pressure drop).
  • FIG. 11 is a perspective view of an example stack subsystem 50 of the biochar kiln 10 .
  • a portion of the stack 51 (shown in FIG. 1 ) is illustrated in detail.
  • a stack 51 sits on top of the lid 14 of the biochar kiln 10 .
  • a reflector/flow director is attached to the underside of the lid. This reflects radiant heat back into the kiln and biochar while also directing the flue gas to the out perimeter of the kiln, which improves heat distribution in the kiln.
  • the stack may be anchored by gravity and/or other attachment(s).
  • the base of the stack is wide enough to provide stability (e.g., up to about 90 mph wind loads).
  • a smoke chamber 52 funnels kiln gases into the stack 50 .
  • a stack blower 54 moves the smoke first horizontally and then curves straight up and through the top of the stack 51 .
  • the stack blower 54 moves combustion air through the duct 52 where the smoke then enters a venturi mix tube. Air from the blower 54 entrains nearby flue gas to pull it up into the mix tube of the stack 51 . At the top end of the mix tube (see FIG. 1 ), the air and flue gas combine on their way to a secondary or exhaust burner (not shown).
  • the burner Natural gas or propane
  • volatile gases if any
  • burns particulates heats the vapors and spirals the smoke upward to heat refractory material above the burner.
  • the spiral effect is cause by vanes placed just after the burner. The spiraling hot vapors spend more time heating the refractory than a straight upward flow.
  • the target refractory temperature is about 1650 F, and is managed by adjusting the burner fuel flow rate and/or the blower flow rate.
  • CO combines with radical Oxygen to make CO2, which is an acceptable emission gas (whereas CO is highly regulated).
  • thermal NOX is also kept low.
  • An added stack extension may be provided to help increase flow rate due to stronger convection flow. Less entrainment air is required, for less cooling, less use of burner gas. This may reduce or eliminate the need for refractory material, thus reducing cost.
  • the blower 54 provides a negative kiln pressure (e.g., by reducing or altogether eliminating fugitive smoke, and providing suction to pull air in from the dampers).
  • the blower 54 also provides oxygen for emission conversion and burner combustion, and helps control stack temperatures by adding cooling air.
  • FIG. 12 is a high-level block diagram of an example control subsystem 56 of the biochar kiln 10 .
  • the control subsystem 56 may include one or more controller 58 .
  • the controller 58 may be implemented as a PLC (programmable logic array).
  • the controller 58 may be mounted in any suitable location (e.g., on a pole near the kiln).
  • the PLC has enough computing power to run multiple kilns.
  • the cable between the kiln and the PLC has 4 conductors (2 for DC power and 2 for data) which make plugging and unplugging easy.
  • a controller 58 may be provided for each kiln where and can travel with the kiln.
  • the controller 58 may receive input and/or feedback from the kiln (e.g., the ventilation subsystem 24 , the ember suppression subsystem 44 , and/or the stack subsystem 50 ). The controller 58 may also provide output or control of the various subsystems.
  • the kiln e.g., the ventilation subsystem 24 , the ember suppression subsystem 44 , and/or the stack subsystem 50 .
  • the controller 58 may also provide output or control of the various subsystems.
  • the kiln and stack may also be considered to include a plurality of control zones 60 .
  • the control zones 60 are independent, horizontal and/or vertical zones within the kiln body 12 and stack 51 .
  • the zones each have one or more process control variable (e.g., temperature, oxygen level).
  • the zones 60 may be physical component(s) and/or area(s) (both physical and virtual) of the kiln body 12 and/or stack 14 itself, and/or a process component, such as the feedstock, product (including intermediary product), air, gas(es), and smoke within the kiln body 12 and/or stack 14 .
  • zones 60 include, but are not limited to, floor combustion cells, the kiln feedstock itself, the produced biochar itself, the kiln lid 14 , the stack smoke chamber, stack mix venturi, the stack burner, Flue gas spiral vanes, Stack refractory, Stack extension.
  • the zones 60 may be equipped with one or more sensor and/or dampers. These zones 60 may be managed by the controller 58 .
  • each kiln 10 has its own computer control board (e.g., for easy transit and improved individual kiln reliability).
  • the control board may be wirelessly linked to a site controller to accept site-wide remote commands (e.g., fire start), to provide archive data and to send status alarms.
  • control subsystem 56 can apply one or more group state machines on top of individual zone state machines to insure even burns across individual zones.
  • group state machines may include a program to ask individual zones to stop at intermediate temperatures to permit slower zones to catch up. When all zones arrive at the temperature, the group is then released to continue the process.
  • the control board may be accessed via tablet, smart phone, and laptop devices, e.g., which provide the user interface and control.
  • the control board may also control work lights and strobe alarms at the site and/or individual kiln(s).
  • the controller 58 implements state machine software and device controllers to independently manage each of the various subsystems (e.g., 24 , 44 , and 50 ) and zones 60 (e.g., a floor combustion cell).
  • zones 60 e.g., a floor combustion cell.
  • the controller 58 can be implemented as one or more group state machines on top of individual state machines to ensure optimal group performance (e.g., to ensure consistent or even burns across all cells).
  • the controller 58 may enable non-programmers to develop advanced control logic and algorithms without making changes to its lower level program code.
  • Unique control instructions e.g., “recipes”
  • control subsystem 56 provides higher yields, higher biochar quality, greater consistency, optimized flow rates, vapor pressure control, end of cycle detection, lower emissions and shorter burn cycles.
  • each floor combustion cell may be provided with an optimal amount of combustion air for maximum temperature rise while working to reach a preset temperature goal.
  • the burn control can use Boolean logic and/or PID (proportional, integral and derivative) control or other techniques for fastest temperature attainment.
  • FIG. 13-23 are illustrations of example insulation of the biochar kiln 10 shown in FIG. 1 .
  • the steel shell e.g., lid 14 , walls 20 , and floor 22
  • heat loss can be under 30%.
  • the kiln is insulated with a ceramic blanket (or other types)
  • heat loss can be reduced by as much as 95%.
  • internal temperatures climb more quickly for shorter burn times, yield improvement (less wood burned), reduced emissions (less wood burned), improved consistency (soak heats are more evenly distributed), and improved quality. Exposing the ceramic blanket to rain and snow quickly transforms it into a poor insulator. To protect the blanket, it may be encapsulated in a high temperature weatherproof skin.
  • a cylindrical insulator 62 ( FIG. 13 ) is provided that follows the shape of the kiln wall 20 .
  • FIG. 14 is a close up of the upper side edge of the wall 20 showing the cylindrical insulator 62 in detail.
  • the insulating cylinder 62 ′ may stand away from the kiln wall 20 to allow forced airflow through a gap between the kiln wall 20 and the insulating cylinder 62 , and optionally through openings or vents 64 (e.g., after a burn).
  • a ring or band with similar sized and spaced openings can be fit snugly to the insulation.
  • the band can be rotated so that the vents 62 are at least partially or fully covered.
  • the band can be rotated so that openings in the ring line up with the vents 64 .
  • the air inside the space is heated by the Kiln wall. It then rises out the vent openings, drawing cool air into the air space from the bottom.
  • Ambient air (or chilled air) blowers may be provided to force air to pass between the kiln wall and insulation for cooling before it exits on the far side. Sensing the existing air temperature and internal thermowell temperatures can indicate when the kiln is safe to open.
  • the insulation is about 1.5 inches thick, although other sizes may be provided.
  • the insulator 62 and 62 ′ can detach from the kiln to permit replacement and maintenance as needed.
  • a clearance between a gripper ring 66 and the bottom of the insulation so that gripping the gripper ring 66 (e.g., with a forklift or other machinery to raise/lower the kiln 10 ) does not pinch or otherwise harm the insulation. This distance may depend on the dimensions of the gripper and the expected accuracy of the loader driver while picking up the Kiln.
  • the insulation 62 and 62 ′ holds significantly more heat inside the Kiln during processing, and is expected to reduce the amount of wood burned (increasing efficiency) with increased yield of char.
  • forced convection may be provided.
  • One way to accomplish forced convection is by mounting a pipe 68 vertically to the kiln 10 , as shown in FIG. 17 .
  • the pipe 68 can direct air into the space between the kiln wall 20 and the insulation. It may be possible to leave this pipe 68 uncapped during processing, since little air will escape. If desired, the pipe(s) 68 can be capped.
  • the pipe(s) 68 distribute forced air both ways (e.g., left and right) into the air space on one side of the kiln 10 . If it is desired to “collect” the air on the opposite side of the kiln 10 , another similar pipe can be installed. If faster cooling is desired, 4 pipes can be used, 2 for inlet and 2 for “exhaust”, though the complexity increases significantly. These are only exemplary configurations. Other configurations are also contemplated.
  • plenum walls 70 may be provided inside the air space to keep the cooling coverage more even than if the forced air could flow vertically inside the air space.
  • These plenum walls 70 may be welded to the Kiln wall in a circular direction and could be full or partial walls.
  • FIG. 20 shows a blower 72 attached to the inlet of the forced air system. Forced convection possibly will require an additional blower for each kiln 10 in the cool-down cycle.
  • FIG. 21 shows how to use the “waste” heat from the kilns 10 . If the heated air from cooling a processed kiln 10 is piped into the inlet air pipes of a waiting kiln 10 ′, some amount of drying of the wood might be accomplished while waiting to process the loaded kiln. This may reduce the time needed to evaporate all the moisture in the wood during processing.
  • the heated air may be forced into 2 or 3 inlets, as illustrated by FIG. 21 .
  • a manifold of sorts could be attached to the waiting kiln, where hot air could enter all air inlets and would exit through the lid (some venting mechanism might be provided on the lid if general air leaks are not enough).
  • FIGS. 22-23 show a kiln 10 ′′ having six 2 ⁇ 2 inch legs (legs 74 a - d are visible in FIG. 22 ) and a rolled angle bottom with top insulation 76 and bottom insulation 78 .
  • Bottom insulation 78 may not be provided if the bottom area is enclosed with insulation or insulation sections 78 .
  • a similar air space/insulation configuration may be used for the lid.
  • the stack blower may be used to provide the forced air for cooling. It may implement a switched damper to divert the air from the stack to the lid and/or kiln. It is noted that the kiln and lid may be hot if plumbing needs to be connected. In another example, a blower is attached to the lid that is used for cooling.
  • the kiln insulation is provided in sections to make it easier to install.
  • Overlapped sheet metal joints may hold sections together and help prevent air loss during cooling.
  • the kiln wall insulation is enclosed in a “box” (e.g., of 1/16′′ or 16-gauge (or thinner) sheet metal).
  • a “box” e.g., of 1/16′′ or 16-gauge (or thinner) sheet metal.
  • these may be rolled to fit, with bent or welded ends for fastening the “front” and “back” sides together.
  • An attachment mechanism/bracket may be welded to the kiln.
  • these insulation sections may be fastened to the brackets.
  • insulation section dimensions are about half or whole multiples of about 14.5 inches
  • fiberglass rolls may fill the inside of the insulation sections (e.g., 16 inch stud spacing less 1.5 inch stud is about 14.5 inches). It is noted that careful dimensioning may lead to more efficient use of the insulation.

Abstract

A biochar kiln is disclosed. An example of the biochar kiln includes a body having a one-piece rolled wall, a curved floor attached to the sidewall by a single weld line, and a removable lid. The example biochar kiln includes a plurality of semi-independent combustion cells. The example biochar kiln also includes a ventilation subsystem, an ember suppression subsystem, and a stack subsystem. A control subsystem may configured to monitor a plurality of zones of the biochar kiln for a plurality of process control variables, to produce a quality biochar product with well-managed emissions.

Description

CROSS REFERENCE TO RELATED APPLICATIONS
This application claims the priority benefit of U.S. Provisional Patent Application No. 62/317,573 filed Apr. 3, 2016 for “Biochar Kiln,” hereby incorporated by reference in its entirety as though fully set forth herein.
BACKGROUND
Biochar is made from biomass (trees, agricultural waste, etc.) in an oxygen deprived, high temperature environment. Quality biochar has high purity, absorptivity and cation exchange capacity. This can provide significant benefits to several large markets including, but not limited to, agriculture, pollution remediation, odor sequestration, separation of gases, and oil and gas clean up.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a perspective view of an example biochar kiln.
FIG. 2 is an interior view of a floor of the example biochar kiln, illustrating a ventilation subsystem.
FIG. 3 is a close-up view of the ventilation subsystem shown in FIG. 2.
FIG. 4 is another close-up view of the ventilation subsystem shown in FIG. 2.
FIGS. 5-8 are close-up views of the exterior of the example biochar kiln, illustrating the ventilation subsystem.
FIGS. 9-10 are perspective views of example components of an ember suppression subsystem of the biochar kiln.
FIG. 11 is a perspective view of an example stack subsystem of the biochar kiln.
FIG. 12 is a high-level block diagram of an example control subsystem of the biochar kiln.
FIG. 13-23 are illustrations of example insulation of the biochar kiln shown in FIG. 1.
DETAILED DESCRIPTION
A biochar kiln is disclosed, including construction of the kiln and various subsystems such as, but not limited to, ventilation, stack, control, insulation, and ember suppression. The kiln may be implemented to produce biochar.
In an example, the kiln is configured for internal combustion and heat generation as needed, to convert biomass into biochar. During operation, the kiln may experience frequent and wide thermal cycling. For example, every 2 days, the kiln temperatures can vary between −30 and +1300 degrees Fahrenheit (e.g., stack temperature ranges from −30 F to 1850 F).
The biochar kiln is configured to support slow pyrolysis and can accommodate a number of variables. Variables include, but are not limited to, a “green” and/or dry feedstock, large and/or small pieces of the feedstock, various and multiple different species of the feedstock, and operation according to variable processing times. The biochar kiln is robust in that it may be operated under a number of variable operating conditions, while still producing a consistent and high quality biochar product.
The biochar kiln may include a local and dedicated process control system. The control system may be implemented with a ventilation subsystem, an ember suppression subsystem, and airflow management or “stack” subsystem, to help ensure high quality and high yield biochar is produced while simultaneously complying with emissions standards.
In an example, the biochar kiln has multi-zone combustion cells that are computer-controlled to maintain target temperatures while creating faster burns. Multi-zone servo dampers are computer-control to manage inlet air flows to the combustion cells to support optimum heating. The biochar kiln may also have removable stacks and a stack hole sealing mechanism. The kiln may also be configured for negative flue gas pressure to eliminate fugitive emissions.
Before continuing, it is noted that as used herein, the terms “includes” and “including” mean, but is not limited to, “includes” or “including” and “includes at least” or “including at least.” The term “based on” means “based on” and “based at least in part on.”
FIG. 1 is a perspective view of an example biochar kiln 10. The biochar kiln 10 may include a main body portion 12 and a lid 14. The main body portion 12 is configured to receive a feedstock (not shown) by removing the lid 14 and loading the feedstock before replacing the lid 14. In an example, the biochar kiln further includes a base portion 16. The base portion 16 may be configured such that it is raised off of the ground. This enables airflow under the main body portion 12. A ring 18 may also be implemented to lift the biochar kiln 10, e.g., using a loader tractor, forklift or other suitable machinery.
In an example, the kiln wall 20 may be made of a one-piece, rolled wall. Body welds, where needed (e.g., between the floor 222 and wall 20, and various ports), are made on curved surfaces to lower structural and thermal stress to those joints.
The floor 24 may also be a one-piece heavy gauge, high strength steel. The floor 24 may be downward elliptical-shaped (the shape being visible in FIG. 1 and FIG. 5) to withstand heavy falling wood chunks during filling. The surface of the floor 24 is curved and has only one weld joint along the perimeter where it joins with the wall 20. The floor 20 and walls 20 may anneal with use, which also serves to relieve stress.
Before continuing, it should be noted that the examples described above are provided for purposes of illustration, and are not intended to be limiting. Other devices and/or device configurations may be utilized to carry out the operations described herein.
FIG. 2 is an interior view of a floor 20 of the example biochar kiln 10, illustrating a ventilation subsystem 24. The ventilation subsystem 24 may include a plurality of semi-independent combustion cells 25 a-g. In the example shown, there is a combustion cell 25 g in the center, and six combustion cells 25 a-f between the center cell 25 g and the kiln wall 20. An outside vent pipe 28 a-f leads to the center of each cell to provide combustion air. FIG. 3 is a close-up view of the ventilation subsystem 24 shown in FIG. 2. FIG. 4 is another close-up view of the ventilation subsystem 24 shown in FIG. 2.
In an example, upward facing thermowell tubes 26 a-g may be built into the floor 20 for each combustion cell 25 a-f. The thermowell tubes 26 a-f may be positioned adjacent vent pipes or air inlets 28 a-f. Another thermowell tube 26 g may be positioned substantially in the center of the floor 20, e.g., for combustion cell 25 g. The thermowell tubes 26 a-g may be configured with monitors to enable interior biochar temperature sensing while the biochar is cooking.
FIGS. 5-8 are close-up views of the exterior of the example biochar kiln, illustrating a ventilation subsystem 30. The ventilation subsystem 30 includes ports 32 around the perimeter of the body 12 of the biochar kiln 10. Each of the ports 32 is connected to the internal air inlets 28 a-f. These ports may be closed (e.g., as shown in FIG. 5) and opened manually, or via computer control.
In FIGS. 6-8, an automatic control is shown including dampers 34 with air inlet 36 which can be connected to a gas line 38 to a main line 40 to supply ignition gas into the chamber formed in the body 12 of the biochar kiln 10.
The dampers 34 are each attached to the outside portion of the corresponding vent pipes 28 a-f to provide computer-controlled airflow. Each damper has a servo-controlled butterfly valve 42 to regulate airflow. Damper airflow results from negative pressure in the kiln (the vacuum sucks air in), or can be blown in by an external blower or both.
In an example, the ventilation subsystem 30 may be implemented with the control system described herein to provide a controlled airflow, thus enabling a carefully controlled burn and emissions control. In an example, each servo is computer-controlled and provides physical position feedback to the computer to confirm the valve's position. The feedback enables the computer control to determine whether a valve is working, blocked or failed. In an example, servo accuracy is about +/−0.5 degrees to permit precise control.
In an example, the kiln is equipped with one or more pressure transducer(s) to insure negative kiln pressure. Air vent pipes for each combustion cell may also pass through the floor flange. After a burn, the vent pipes can be sealed with cam-lock caps to help cut off oxygen, stop combustion and cool the biochar.
At the end of a burn, dampers 34 are removed from the vent pipe openings 32 and replaced with airtight, gasket cam-lock caps 33 (shown in FIG. 4) over the vent pipe openings 32. The dampers 34 are then temporally secured to the kiln wall during kiln transit or moved to another kiln for further use.
Damper wiring may be routed to a kiln-mounted control board to eliminate the need to unplug and plug damper wiring when the kiln travels to and from the workstations.
In addition to airflow control, the damper assembly 34 provides a computer-controlled gas-start system to ignite the wood during a fresh burn. Gas flow is turned by the computer via a gas solenoid.
During operation gas is piped into the assembly where it flows through a venturi pulling in air to the air/gas mix tube before being exposed to a preheated glow plug igniter. The ignited gas then travels by a thermocouple probe to verify its ignition and down the vent pipe to start the wood fire at its combustion cell.
FIGS. 9-10 are perspective views of example components 46 and 48 of an ember suppression subsystem 44 of the biochar kiln 10. An ember suppression subsystem 44 is provided in the event ember suppression is needed after a burn. In an example, a gas 46 (e.g., nitrogen, carbon dioxide, and/or other inert gases) can be injected into the kiln 10 (e.g., at one or more ports 32, the exhaust stack 51, or other suitable location) to purge and/or dilute residual oxygen in the chamber of kiln 10. In an example, carbon dioxide is utilized because it is about two times heavier than air, which enables the biochar to flood a kiln from the bottom up so it can be processed the next morning. Without oxygen, there is no combustion and the embers are put out (stop burning) to allow the biochar to cool down.
The introduction of suppression gases can be managed by a regulator 48 (FIG. 10) at port 32 or other suitable location, to maintain a low, positive kiln pressure. This helps keep fresh air from entering the kiln. After the heat is reduced to a safe level, the control system can turn off the gas supply. In an example, a safe temperature is about 300 F to 400 F (e.g., it is noted that the auto ignition temperature of wood is about 570 F). By using suppression gases, instead of a water quench, the biochar can be processed in its dry state.
The ember suppression subsystem may also be implemented at least in part in the lid. In an example, the lid has a gasket attached to it at the perimeter. The gasket gets squeezed between lid flange located above the gasket and the flange on the kiln rim below. The gasket reduces or prevents air leaks during ember suppression. During the burn, the gasket also helps retain fugitive smoke in the kiln (e.g., in case of a short term negative pressure drop).
FIG. 11 is a perspective view of an example stack subsystem 50 of the biochar kiln 10. In FIG. 11, a portion of the stack 51 (shown in FIG. 1) is illustrated in detail. In an example, a stack 51 sits on top of the lid 14 of the biochar kiln 10.
In an example, a reflector/flow director is attached to the underside of the lid. This reflects radiant heat back into the kiln and biochar while also directing the flue gas to the out perimeter of the kiln, which improves heat distribution in the kiln.
The stack may be anchored by gravity and/or other attachment(s). In an example, the base of the stack is wide enough to provide stability (e.g., up to about 90 mph wind loads). At the bottom of the stack 51, a smoke chamber 52 funnels kiln gases into the stack 50. A stack blower 54 moves the smoke first horizontally and then curves straight up and through the top of the stack 51.
During example operation, the stack blower 54 moves combustion air through the duct 52 where the smoke then enters a venturi mix tube. Air from the blower 54 entrains nearby flue gas to pull it up into the mix tube of the stack 51. At the top end of the mix tube (see FIG. 1), the air and flue gas combine on their way to a secondary or exhaust burner (not shown).
As the air and flue gas pass through the burner (natural gas or propane), it ignites volatile gases (if any), which lowers emission pollution, burns particulates, heats the vapors and spirals the smoke upward to heat refractory material above the burner. The spiral effect is cause by vanes placed just after the burner. The spiraling hot vapors spend more time heating the refractory than a straight upward flow.
In an example, the target refractory temperature is about 1650 F, and is managed by adjusting the burner fuel flow rate and/or the blower flow rate. At 1650 F, CO combines with radical Oxygen to make CO2, which is an acceptable emission gas (whereas CO is highly regulated). In addition, at 1650 F, thermal NOX is also kept low.
An added stack extension (not shown) may be provided to help increase flow rate due to stronger convection flow. Less entrainment air is required, for less cooling, less use of burner gas. This may reduce or eliminate the need for refractory material, thus reducing cost.
The blower 54 provides a negative kiln pressure (e.g., by reducing or altogether eliminating fugitive smoke, and providing suction to pull air in from the dampers). The blower 54 also provides oxygen for emission conversion and burner combustion, and helps control stack temperatures by adding cooling air.
FIG. 12 is a high-level block diagram of an example control subsystem 56 of the biochar kiln 10. The control subsystem 56 may include one or more controller 58. In an example, the controller 58 may be implemented as a PLC (programmable logic array). The controller 58 may be mounted in any suitable location (e.g., on a pole near the kiln). The PLC has enough computing power to run multiple kilns. In an example, the cable between the kiln and the PLC has 4 conductors (2 for DC power and 2 for data) which make plugging and unplugging easy. In another example, a controller 58 may be provided for each kiln where and can travel with the kiln.
The controller 58 may receive input and/or feedback from the kiln (e.g., the ventilation subsystem 24, the ember suppression subsystem 44, and/or the stack subsystem 50). The controller 58 may also provide output or control of the various subsystems.
In addition, the kiln and stack may also be considered to include a plurality of control zones 60. The control zones 60 are independent, horizontal and/or vertical zones within the kiln body 12 and stack 51. The zones each have one or more process control variable (e.g., temperature, oxygen level). The zones 60 may be physical component(s) and/or area(s) (both physical and virtual) of the kiln body 12 and/or stack 14 itself, and/or a process component, such as the feedstock, product (including intermediary product), air, gas(es), and smoke within the kiln body 12 and/or stack 14.
Examples zones 60 include, but are not limited to, floor combustion cells, the kiln feedstock itself, the produced biochar itself, the kiln lid 14, the stack smoke chamber, stack mix venturi, the stack burner, Flue gas spiral vanes, Stack refractory, Stack extension. The zones 60 may be equipped with one or more sensor and/or dampers. These zones 60 may be managed by the controller 58.
In an example, each kiln 10 has its own computer control board (e.g., for easy transit and improved individual kiln reliability). The control board may be wirelessly linked to a site controller to accept site-wide remote commands (e.g., fire start), to provide archive data and to send status alarms.
To integrate multiple zones across multiple kilns 10, and/or multiple zones within a single kiln 10, the control subsystem 56 can apply one or more group state machines on top of individual zone state machines to insure even burns across individual zones. For example, group state machines may include a program to ask individual zones to stop at intermediate temperatures to permit slower zones to catch up. When all zones arrive at the temperature, the group is then released to continue the process.
The control board may be accessed via tablet, smart phone, and laptop devices, e.g., which provide the user interface and control. The control board may also control work lights and strobe alarms at the site and/or individual kiln(s).
In an example, the controller 58 implements state machine software and device controllers to independently manage each of the various subsystems (e.g., 24, 44, and 50) and zones 60 (e.g., a floor combustion cell). To integrate zones 60, the controller 58 can be implemented as one or more group state machines on top of individual state machines to ensure optimal group performance (e.g., to ensure consistent or even burns across all cells).
The controller 58 may enable non-programmers to develop advanced control logic and algorithms without making changes to its lower level program code. Unique control instructions (e.g., “recipes”) can be generated for unique customer needs, feedstock type, emissions requirements, biochar attributes, etc.
In an example, the control subsystem 56 provides higher yields, higher biochar quality, greater consistency, optimized flow rates, vapor pressure control, end of cycle detection, lower emissions and shorter burn cycles. By way of illustration, each floor combustion cell may be provided with an optimal amount of combustion air for maximum temperature rise while working to reach a preset temperature goal. The burn control can use Boolean logic and/or PID (proportional, integral and derivative) control or other techniques for fastest temperature attainment.
FIG. 13-23 are illustrations of example insulation of the biochar kiln 10 shown in FIG. 1. On cold, windy days, over 80% of the kiln's heat can be lost through the steel shell (e.g., lid 14, walls 20, and floor 22) of the biochar kiln 10. On a windless, warm day, heat loss can be under 30%. If the kiln is insulated with a ceramic blanket (or other types), heat loss can be reduced by as much as 95%. When insulation is used, internal temperatures climb more quickly for shorter burn times, yield improvement (less wood burned), reduced emissions (less wood burned), improved consistency (soak heats are more evenly distributed), and improved quality. Exposing the ceramic blanket to rain and snow quickly transforms it into a poor insulator. To protect the blanket, it may be encapsulated in a high temperature weatherproof skin.
In an example, a cylindrical insulator 62 (FIG. 13) is provided that follows the shape of the kiln wall 20. FIG. 14 is a close up of the upper side edge of the wall 20 showing the cylindrical insulator 62 in detail.
In another example, the insulating cylinder 62′ may stand away from the kiln wall 20 to allow forced airflow through a gap between the kiln wall 20 and the insulating cylinder 62, and optionally through openings or vents 64 (e.g., after a burn). In an example, (not shown), a ring or band with similar sized and spaced openings can be fit snugly to the insulation. During processing, the band can be rotated so that the vents 62 are at least partially or fully covered. To aid in cooling, the band can be rotated so that openings in the ring line up with the vents 64. By natural convection, the air inside the space is heated by the Kiln wall. It then rises out the vent openings, drawing cool air into the air space from the bottom.
Ambient air (or chilled air) blowers may be provided to force air to pass between the kiln wall and insulation for cooling before it exits on the far side. Sensing the existing air temperature and internal thermowell temperatures can indicate when the kiln is safe to open.
In an example, the insulation is about 1.5 inches thick, although other sizes may be provided. The insulator 62 and 62′ can detach from the kiln to permit replacement and maintenance as needed.
There may be provided a clearance between a gripper ring 66 and the bottom of the insulation so that gripping the gripper ring 66 (e.g., with a forklift or other machinery to raise/lower the kiln 10) does not pinch or otherwise harm the insulation. This distance may depend on the dimensions of the gripper and the expected accuracy of the loader driver while picking up the Kiln.
The insulation 62 and 62′ holds significantly more heat inside the Kiln during processing, and is expected to reduce the amount of wood burned (increasing efficiency) with increased yield of char.
If using natural convection doesn't allow cooling of the Kiln in a short enough time, forced convection may be provided. One way to accomplish forced convection is by mounting a pipe 68 vertically to the kiln 10, as shown in FIG. 17. The pipe 68 can direct air into the space between the kiln wall 20 and the insulation. It may be possible to leave this pipe 68 uncapped during processing, since little air will escape. If desired, the pipe(s) 68 can be capped.
The pipe(s) 68 distribute forced air both ways (e.g., left and right) into the air space on one side of the kiln 10. If it is desired to “collect” the air on the opposite side of the kiln 10, another similar pipe can be installed. If faster cooling is desired, 4 pipes can be used, 2 for inlet and 2 for “exhaust”, though the complexity increases significantly. These are only exemplary configurations. Other configurations are also contemplated.
As shown in FIGS. 18-19, plenum walls 70 may be provided inside the air space to keep the cooling coverage more even than if the forced air could flow vertically inside the air space. These plenum walls 70 may be welded to the Kiln wall in a circular direction and could be full or partial walls.
FIG. 20 shows a blower 72 attached to the inlet of the forced air system. Forced convection possibly will require an additional blower for each kiln 10 in the cool-down cycle.
FIG. 21 shows how to use the “waste” heat from the kilns 10. If the heated air from cooling a processed kiln 10 is piped into the inlet air pipes of a waiting kiln 10′, some amount of drying of the wood might be accomplished while waiting to process the loaded kiln. This may reduce the time needed to evaporate all the moisture in the wood during processing.
The heated air may be forced into 2 or 3 inlets, as illustrated by FIG. 21. Or a manifold of sorts could be attached to the waiting kiln, where hot air could enter all air inlets and would exit through the lid (some venting mechanism might be provided on the lid if general air leaks are not enough).
FIGS. 22-23 show a kiln 10″ having six 2×2 inch legs (legs 74 a-d are visible in FIG. 22) and a rolled angle bottom with top insulation 76 and bottom insulation 78. Bottom insulation 78 may not be provided if the bottom area is enclosed with insulation or insulation sections 78.
In this example, there may be no air blown into/out of the bottom for cooling to reduce the need for plumbing through the insulation 80. As the heat rises, and when the walls and inside air were cooled, the bottom may lose heat to the Kiln air. If forced air cooling is desired for the bottom, a small diameter pipe may be attached to the blower, and cool air can be blown into the bottom chamber which exits from vents in the bottom insulation sections.
A similar air space/insulation configuration may be used for the lid. The stack blower may be used to provide the forced air for cooling. It may implement a switched damper to divert the air from the stack to the lid and/or kiln. It is noted that the kiln and lid may be hot if plumbing needs to be connected. In another example, a blower is attached to the lid that is used for cooling.
In an example, the kiln insulation is provided in sections to make it easier to install. Overlapped sheet metal joints may hold sections together and help prevent air loss during cooling.
In an example, the kiln wall insulation is enclosed in a “box” (e.g., of 1/16″ or 16-gauge (or thinner) sheet metal). For the kiln walls and bottom sections, these may be rolled to fit, with bent or welded ends for fastening the “front” and “back” sides together. An attachment mechanism/bracket may be welded to the kiln. In other examples, these insulation sections may be fastened to the brackets.
If the insulation section dimensions are about half or whole multiples of about 14.5 inches, fiberglass rolls may fill the inside of the insulation sections (e.g., 16 inch stud spacing less 1.5 inch stud is about 14.5 inches). It is noted that careful dimensioning may lead to more efficient use of the insulation.
It is noted that the examples shown and described are provided for purposes of illustration and are not intended to be limiting. Still other examples are also contemplated.

Claims (13)

The invention claimed is:
1. A biochar kiln, comprising:
a body having a one-piece rolled wall, a curved floor attached to the sidewall by a single weld line, and a removable lid;
a plurality of semi-independent combustion cells, wherein a center combustion cell is provided in the center of the body and six perimeter combustion cells are provided between the center combustion cell and the wall;
an outside vent pipe loading to a center of each of the perimeter combustion cells to provide combustion air;
a plurality of thermowell tubes built into the curved floor for each of the combustion cells, wherein the thermowell tubes are positioned adjacent the vent pipes;
a ventilation subsystem;
an ember suppression subsystem;
a stack subsystem; and
a control subsystem.
2. The biochar kiln of claim 1, wherein the ventilation subsystem includes ports around the perimeter of the body of the biochar kiln, each of the ports connected to internal air inlets.
3. The biochar kiln of claim 1, further comprising an automatic control including computer-controlled dampers to regulate airflow into the body of the biochar kiln.
4. The biochar kiln of claim 3, wherein damper airflow is by negative pressure in the kiln or blown in by an external blower or both.
5. The biochar kiln of claim 1, wherein the stack subsystem includes a stack blower to move combustion air through a duct where smoke then enters a venturi mix tube.
6. The biochar kiln of claim 5, wherein air from the blower entrains nearby flue gas to pull up into the venturi mix tube, and the air and flue gas combine en route a secondary burner.
7. The biochar kiln of claim 1, wherein the ember suppression subsystem includes a gas injected into the body of the biochar kiln to purge and/or dilute residual oxygen in the body.
8. The biochar kiln of claim 7, wherein carbon dioxide gas is utilized to enable produced biochar to flood the body of the biochar kiln from bottom-up.
9. The biochar kiln of claim 1, wherein the control subsystem manages a plurality of zones within the body.
10. The biochar kiln of claim 9, wherein the zones include independent horizontal and vertical zones.
11. The biochar kiln of claim 9, wherein the zones include at least one of a plurality of floor combustion cells.
12. The biochar kiln of claim 9, wherein the zones are managed for variable kiln wood, kiln biochar, stack smoke, stack mix, stack burner temperature, and flue gas.
13. The biochar kiln of claim 9, wherein the zones are monitored by one or more sensor and/or dampers.
US15/453,502 2016-04-03 2017-03-08 Biochar kiln Active 2037-10-31 US10385273B2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US15/453,502 US10385273B2 (en) 2016-04-03 2017-03-08 Biochar kiln
CA2962293A CA2962293C (en) 2016-04-03 2017-03-29 Biochar kiln
US16/503,875 US10883052B2 (en) 2016-04-03 2019-07-05 Biochar kiln

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201662317573P 2016-04-03 2016-04-03
US15/453,502 US10385273B2 (en) 2016-04-03 2017-03-08 Biochar kiln

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US16/503,875 Continuation US10883052B2 (en) 2016-04-03 2019-07-05 Biochar kiln

Publications (2)

Publication Number Publication Date
US20170283703A1 US20170283703A1 (en) 2017-10-05
US10385273B2 true US10385273B2 (en) 2019-08-20

Family

ID=59960269

Family Applications (3)

Application Number Title Priority Date Filing Date
US15/453,502 Active 2037-10-31 US10385273B2 (en) 2016-04-03 2017-03-08 Biochar kiln
US15/453,601 Active 2037-12-19 US10385274B2 (en) 2012-02-16 2017-03-08 Portable biochar kiln
US16/503,875 Active 2037-04-04 US10883052B2 (en) 2016-04-03 2019-07-05 Biochar kiln

Family Applications After (2)

Application Number Title Priority Date Filing Date
US15/453,601 Active 2037-12-19 US10385274B2 (en) 2012-02-16 2017-03-08 Portable biochar kiln
US16/503,875 Active 2037-04-04 US10883052B2 (en) 2016-04-03 2019-07-05 Biochar kiln

Country Status (2)

Country Link
US (3) US10385273B2 (en)
CA (2) CA2962293C (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10883052B2 (en) * 2016-04-03 2021-01-05 Biochar Now, Llc Biochar kiln
US11135728B2 (en) 2012-02-16 2021-10-05 Biochar Now, Llc Lid assembly for portable biochar kiln
US20220074666A1 (en) * 2020-09-04 2022-03-10 Mobile Biochar Solutions LLC Mobile Kiln System

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10160911B2 (en) 2012-02-16 2018-12-25 Biochar Now, Llc Exhaust system for a biochar kiln
US10751885B2 (en) 2012-02-16 2020-08-25 Biochar Now, Llc Gripper assembly for portable biochar kiln
WO2013123096A1 (en) * 2012-02-16 2013-08-22 Biochar Now, Llc Controlled kiln and manufacturing system for biochar production
CA2863105A1 (en) 2012-03-11 2013-08-22 Biochar Now, Llc Airflow control and heat recovery in a managed kiln
US11619383B2 (en) * 2020-06-12 2023-04-04 Global Polymer Industries, Inc. Burn bucket
CA3183182A1 (en) 2020-06-19 2021-12-23 Climate Robotics Inc. Autonomous device for in-field conversion of biomass into biochar

Citations (79)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US414938A (en) 1889-11-12 Apparatus for distilling wood
US2847369A (en) 1954-09-13 1958-08-12 Hughes By Product Coke Oven Co Vertical retorts with a side discharge device
US3595181A (en) 1970-04-15 1971-07-27 Air Preheater Air modulation for waste incinerator
US3695192A (en) 1970-10-12 1972-10-03 Joe W Von Brimer Combustion product processing device and method
US3777676A (en) 1972-07-31 1973-12-11 W Lagen Apparatus and technique for incinerating solid fuels containing carbonizable material
US4117826A (en) 1977-03-07 1978-10-03 Bette Joseph A Wood burning stove
US4167909A (en) 1976-12-09 1979-09-18 Dauvergne Hector A Solid fuel burner
US4261269A (en) 1977-08-04 1981-04-14 Kernforschungsanlage Julich Gesellschaft Mit Beschrankter Haftung Furnace for incinerating waste
US4419942A (en) 1982-07-26 1983-12-13 Johnson Charles A Stove
US4810385A (en) 1987-05-12 1989-03-07 Sybron Chemicals, Inc. Device for seeding bacterial cultures to systems to assist in biodegrading waste
US5014680A (en) 1989-03-15 1991-05-14 The United States Of America As Represented By The United States Department Of Energy Self-powered automatic secondary air controllers for woodstoves and small furnaces
US5018458A (en) 1990-09-12 1991-05-28 Zimpro Passavant Environmental Systems, Inc. Furnace combustion zone temperature control method
US5160259A (en) 1991-05-01 1992-11-03 Hauck Manufacturing Company Draft control method and apparatus for material processing plants
US5190901A (en) 1990-08-15 1993-03-02 Heiyo Shoji Kabushiki Kaisha Method for producing active carbon using carbon-containing material
US5499622A (en) 1995-01-20 1996-03-19 Woods; Maurice G. Afterburner system and process
US5770079A (en) 1997-06-25 1998-06-23 Haase; Richard Alan Biological injector and method of application thereof
US5799590A (en) 1994-04-13 1998-09-01 Sunny Industry Company, Limited Air supply system for incinerator apparatus
US5968320A (en) 1997-02-07 1999-10-19 Stelco, Inc. Non-recovery coke oven gas combustion system
KR20020001090A (en) 2000-06-24 2002-01-09 정문술 Home Managing System and Control Method Thereof
KR20020010902A (en) 2000-02-29 2002-02-06 마스다 노부유키 Biomass gasifying furnace and system for methanol synthesis using gas produced by gasifying biomass
US6484714B1 (en) 2001-12-31 2002-11-26 Richard D. Smith High temperature fireplace grate including room heating transfer tubes
US20030024165A1 (en) 2001-06-28 2003-02-06 Antal Michael J. Process for flash carbonization of biomass
US20030034286A1 (en) 2001-08-14 2003-02-20 Butler George R. Flow through drain filter for a stormwater or wastewater catch basin
US20030136734A1 (en) 2002-01-18 2003-07-24 Behzad Mirzayi Treatment of contaminated activated charcoal
US20050051918A1 (en) 2002-01-10 2005-03-10 Shigeo Muramatsu Smokeless porous carbon production method and its production system
WO2006117006A1 (en) 2005-05-03 2006-11-09 Danmarks Tekniske Universitet A method and a mobile unit for collecting and pyrolysing biomass
US7371308B1 (en) 1998-07-31 2008-05-13 Eva Maria Hackl, legal representative Method and plant for pyrolizing of hydrocarbon-containing waste products
US7381333B1 (en) 2006-10-19 2008-06-03 Rainer Norman B Treatment of water flowing in a horizontal conduit
US7399458B1 (en) 2005-11-18 2008-07-15 Callidus Technologies Inc. Fired equipment with catalytic converter and method of operating same
US20080223269A1 (en) 2007-03-18 2008-09-18 Paoluccio John A Method and apparatus for biomass torrefaction using conduction heating
US7458809B2 (en) 2002-12-11 2008-12-02 Jsh Management, Inc. Portable kiln
JP4267968B2 (en) 2003-05-15 2009-05-27 三菱重工環境エンジニアリング株式会社 Biomass processing method
US20090211892A1 (en) 2004-10-05 2009-08-27 Afab Financial Ltd. Pyrolysis system for waste rubber
US20090215375A1 (en) 2003-03-06 2009-08-27 Greenvex Fan Assemblies, Mechanical Draft Systems and Methods
US20100031571A1 (en) 2006-12-05 2010-02-11 Bengt-Sture Ershag Reactor for pyrolysis and method for charging and emptying such a reactor
US7678176B2 (en) 2006-06-30 2010-03-16 Midrex Technologies, Inc. Method and apparatus for charging hot direct reduced iron from hot transport vessels into a melter or finisher
US20100120128A1 (en) 2008-06-18 2010-05-13 Zhi-Wei Liang Eco-engineering for systematic carbon mitigation
WO2010122525A1 (en) 2009-04-24 2010-10-28 Savino Sartori Process for converting biomass to solid fuel
WO2010129996A1 (en) 2009-05-14 2010-11-18 Chaotech Pty Ltd A pyrolytic process and apparatus for producing biomass char and energy
US20110100272A1 (en) 2009-08-20 2011-05-05 Robert Joel Hasselbring Vortex incinerator
US20110114144A1 (en) 2009-11-17 2011-05-19 Green Liquid and Gas Technologies Improved process and device for the pyrolysis of feedstock
US20110172092A1 (en) 2010-01-13 2011-07-14 Ut-Battelle, Llc Biochar Production Method and Composition Therefrom
WO2011097183A2 (en) 2010-02-03 2011-08-11 University Of Florida Research Foundation, Inc. Biologically activated biochar, methods of making biologically activated biochar, and methods of removing contaminants from water
US20110252699A1 (en) 2010-02-12 2011-10-20 Britton Shepard Biochar retort kiln
WO2011143718A1 (en) 2010-05-21 2011-11-24 Errol John Smith Biochar-coke produced in an energy efficient manner
US8100990B2 (en) 2011-05-15 2012-01-24 Avello Bioenery, Inc. Methods for integrated fast pyrolysis processing of biomass
US20120079762A1 (en) 2009-04-17 2012-04-05 European Charcoal Ag Continuously Converting Biomass
WO2012061795A2 (en) 2010-11-05 2012-05-10 Clearstak Llc Intelligently-controlled catalytic converter for biofuel-fired boiler
US20120193212A1 (en) 2009-10-07 2012-08-02 Katsumori Taniguro Method for treating biomass material and method for using heat energy
US20120237994A1 (en) 2009-08-12 2012-09-20 University Of Georia Research Foundation, Inc. Biochars, methods of using biochars, methods of making biochars and reactors
US8287728B2 (en) 2009-02-10 2012-10-16 Fountainhead L.L.C. Elevated swale for treatment of contaminated stormwater
US20120305380A1 (en) 2010-02-23 2012-12-06 Shanxi Supply And Marketing Cooperative Method and device for carbonification of crop straws
US20120304718A1 (en) 2011-06-06 2012-12-06 Michael Cheiky Method for enhancing soil growth using bio-char
US8361186B1 (en) 2009-06-08 2013-01-29 Full Circle Biochar, Inc. Biochar
US20130068690A1 (en) 2010-04-20 2013-03-21 North Carolina State University Adsorption devices, systems and methods
US8512644B1 (en) 2012-08-01 2013-08-20 Thomas C. Maganas System for transforming organic waste materials into thermal energy and electric power
WO2013126477A1 (en) 2012-02-22 2013-08-29 University Of Florida Research Foundation, Inc. Biochar/metal composites, methods of making biochar/metal composites, and methods of removing contaminants from water
WO2013152337A1 (en) 2012-04-05 2013-10-10 Full Circle Biochar, Inc. Biochar compositions and methods of use thereof
US20130341175A1 (en) 2012-06-22 2013-12-26 The Regents Of The University Of Colorado, A Body Corporate Thermal treatment system and method
US8673150B2 (en) 2011-05-31 2014-03-18 George John Joseph Pearson Method for reducing organic waste in waste water
WO2014059141A1 (en) 2012-10-11 2014-04-17 Biochar Now, Llc Modified biochar treatment media, system and method
US20140151296A1 (en) 2012-11-30 2014-06-05 General Electric Company Produced water treatment to remove organic compounds
WO2014170670A2 (en) 2013-04-18 2014-10-23 Mbda Uk Limited Imaging apparatus and method
US20140323297A1 (en) 2011-11-23 2014-10-30 Cornell University Highly efficient organic fertilizer and components thereof
WO2014179670A1 (en) 2013-05-02 2014-11-06 William Marsh Rice University Manufacture of oxidatively modified carbon (omc)
US20150040804A1 (en) 2012-03-11 2015-02-12 Biochar Now, Llc Airflow control and heat recovery in a managed kiln
US20150136581A1 (en) 2012-02-16 2015-05-21 Biochar Now, Llc Controlled kiln and manufacturing system for biochar production
US20150144564A1 (en) 2013-11-25 2015-05-28 University Of Idaho Biochar water treatment
US20150219341A1 (en) * 2012-09-12 2015-08-06 Flint Co., Ltd. Combustion apparatus
US20150237813A1 (en) 2007-10-09 2015-08-27 Leslie A. Field Systems for decreasing local temperature using high albedo materials
US20160211041A1 (en) 2015-01-15 2016-07-21 Thomas C. Maganas Production of thermal energy and radioactive species
US20160229709A1 (en) 2015-02-06 2016-08-11 Biochar Now, Llc Contaminant removal from water bodies with biochar
US20170055502A1 (en) 2014-05-15 2017-03-02 Coastal Environments, Incorporated Apparatus facilitating formation of a vertical oyster reef and shoreline rehabilitation with induced oyster reef barrier and lagoon implementing the same
US20170283704A1 (en) 2016-04-03 2017-10-05 Biochar Now, Llc Portable biochar kiln
US9878301B1 (en) 2014-06-09 2018-01-30 Orin Technologies, Llc Method and composition for the remediation of contaminants
US20180105437A1 (en) 2015-02-06 2018-04-19 Biochar Now, Llc Contaminant removal from water with containerized biochar
US9975792B2 (en) 2011-04-08 2018-05-22 United Laboratories, Inc. Water-dissolvable device for treatment of waste material
US20180282628A1 (en) 2012-02-16 2018-10-04 Biochar Now , Llc Exhaust System For A Biochar Kiln
US20190030725A1 (en) 2012-02-16 2019-01-31 Biochar Now, Llc Gripper assembly for portable biochar kiln

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE23694E (en) 1953-08-04 Material handling device fob
US2571550A (en) 1948-06-11 1951-10-16 Hyster Co Material handling device for industrial trucks
US2739009A (en) 1952-12-29 1956-03-20 Shell Dev Clamps with pre-stressed and pre-set flexible grab arms
US2819113A (en) 1953-10-08 1958-01-07 Shell Dev Clamps with composite flexible grab arms
US3438523A (en) 1967-04-19 1969-04-15 Inventors Engineering Load clamping and articulate apparatus
US3500812A (en) 1968-04-19 1970-03-17 Otto Korngold Barbeque stove
US3512670A (en) 1968-12-27 1970-05-19 Materials Handling Systems Inc Ninety degree turning attachment for forklift truck
US4249883A (en) 1977-06-20 1981-02-10 Save Fuel Corporation Automatic damper device
US4263890A (en) 1978-09-01 1981-04-28 Michigan Consolidated Gas Company Flue restrictor
US4256081A (en) 1979-05-16 1981-03-17 Stover Michael L Air circulation and humidification system for stoves
US4276871A (en) 1979-11-13 1981-07-07 Sid Harvey, Inc. Flue damper and draft regulator
US4454826A (en) * 1982-06-23 1984-06-19 Regenerative Environmental Equipment Co., Inc. Vertical flow incinerator having regenerative heat exchange
US4765256A (en) 1987-11-18 1988-08-23 New Hampshire Flakeboard, Inc. Reinjection gasifier
JPH0678814B2 (en) 1988-08-17 1994-10-05 三菱電機株式会社 Combustion device
US5281076A (en) 1991-05-08 1994-01-25 Liberty Diversified Industries Forklift attachment
US5236298A (en) 1991-08-22 1993-08-17 Valley Craft Fork lift attachment
US5305954A (en) 1993-02-11 1994-04-26 Abel Guenther Heating systems
DE60044059D1 (en) * 1999-05-21 2010-05-06 Barlow Projects Inc IMPROVED FUEL BURNING SYSTEM
US7241322B2 (en) * 2003-11-21 2007-07-10 Graham Robert G Pyrolyzing gasification system and method of use
US20080141997A1 (en) 2006-12-18 2008-06-19 Chaim Druin Outdoor gas barbecue grill with an electric self-cleaning unit
US20090199747A1 (en) 2008-02-08 2009-08-13 Wood-Mizer Products, Inc. Biomass burner system
US20090269181A1 (en) 2008-04-25 2009-10-29 Moffitt James A Adjustable gripping arms for lifting machine
US20110108018A1 (en) 2009-11-09 2011-05-12 Heinsohn Richard G Solar based energy conversion apparatus
BRPI1104219B1 (en) 2011-08-25 2013-04-02 thermal gradient based solid waste treatment process composed of two distinct thermal sources.

Patent Citations (99)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US414938A (en) 1889-11-12 Apparatus for distilling wood
US2847369A (en) 1954-09-13 1958-08-12 Hughes By Product Coke Oven Co Vertical retorts with a side discharge device
US3595181A (en) 1970-04-15 1971-07-27 Air Preheater Air modulation for waste incinerator
US3695192A (en) 1970-10-12 1972-10-03 Joe W Von Brimer Combustion product processing device and method
US3777676A (en) 1972-07-31 1973-12-11 W Lagen Apparatus and technique for incinerating solid fuels containing carbonizable material
US4167909A (en) 1976-12-09 1979-09-18 Dauvergne Hector A Solid fuel burner
US4117826A (en) 1977-03-07 1978-10-03 Bette Joseph A Wood burning stove
US4261269A (en) 1977-08-04 1981-04-14 Kernforschungsanlage Julich Gesellschaft Mit Beschrankter Haftung Furnace for incinerating waste
US4419942A (en) 1982-07-26 1983-12-13 Johnson Charles A Stove
US4810385A (en) 1987-05-12 1989-03-07 Sybron Chemicals, Inc. Device for seeding bacterial cultures to systems to assist in biodegrading waste
US5014680A (en) 1989-03-15 1991-05-14 The United States Of America As Represented By The United States Department Of Energy Self-powered automatic secondary air controllers for woodstoves and small furnaces
US5190901A (en) 1990-08-15 1993-03-02 Heiyo Shoji Kabushiki Kaisha Method for producing active carbon using carbon-containing material
US5018458A (en) 1990-09-12 1991-05-28 Zimpro Passavant Environmental Systems, Inc. Furnace combustion zone temperature control method
US5160259A (en) 1991-05-01 1992-11-03 Hauck Manufacturing Company Draft control method and apparatus for material processing plants
US5799590A (en) 1994-04-13 1998-09-01 Sunny Industry Company, Limited Air supply system for incinerator apparatus
US5499622A (en) 1995-01-20 1996-03-19 Woods; Maurice G. Afterburner system and process
US5968320A (en) 1997-02-07 1999-10-19 Stelco, Inc. Non-recovery coke oven gas combustion system
US5770079A (en) 1997-06-25 1998-06-23 Haase; Richard Alan Biological injector and method of application thereof
US7371308B1 (en) 1998-07-31 2008-05-13 Eva Maria Hackl, legal representative Method and plant for pyrolizing of hydrocarbon-containing waste products
KR20020010902A (en) 2000-02-29 2002-02-06 마스다 노부유키 Biomass gasifying furnace and system for methanol synthesis using gas produced by gasifying biomass
KR20020001090A (en) 2000-06-24 2002-01-09 정문술 Home Managing System and Control Method Thereof
US20030024165A1 (en) 2001-06-28 2003-02-06 Antal Michael J. Process for flash carbonization of biomass
US6790317B2 (en) 2001-06-28 2004-09-14 University Of Hawaii Process for flash carbonization of biomass
US20040178052A1 (en) 2001-06-28 2004-09-16 University Of Hawaii Process for flash carbonization of biomass
US20030034286A1 (en) 2001-08-14 2003-02-20 Butler George R. Flow through drain filter for a stormwater or wastewater catch basin
US6484714B1 (en) 2001-12-31 2002-11-26 Richard D. Smith High temperature fireplace grate including room heating transfer tubes
US7354557B2 (en) 2002-01-10 2008-04-08 Shigeo Muramatsu Smokeless porous carbon production method and its production system
US20050051918A1 (en) 2002-01-10 2005-03-10 Shigeo Muramatsu Smokeless porous carbon production method and its production system
US20030136734A1 (en) 2002-01-18 2003-07-24 Behzad Mirzayi Treatment of contaminated activated charcoal
US7458809B2 (en) 2002-12-11 2008-12-02 Jsh Management, Inc. Portable kiln
US20090215375A1 (en) 2003-03-06 2009-08-27 Greenvex Fan Assemblies, Mechanical Draft Systems and Methods
JP4267968B2 (en) 2003-05-15 2009-05-27 三菱重工環境エンジニアリング株式会社 Biomass processing method
US20090211892A1 (en) 2004-10-05 2009-08-27 Afab Financial Ltd. Pyrolysis system for waste rubber
WO2006117006A1 (en) 2005-05-03 2006-11-09 Danmarks Tekniske Universitet A method and a mobile unit for collecting and pyrolysing biomass
US7399458B1 (en) 2005-11-18 2008-07-15 Callidus Technologies Inc. Fired equipment with catalytic converter and method of operating same
US7678176B2 (en) 2006-06-30 2010-03-16 Midrex Technologies, Inc. Method and apparatus for charging hot direct reduced iron from hot transport vessels into a melter or finisher
US7381333B1 (en) 2006-10-19 2008-06-03 Rainer Norman B Treatment of water flowing in a horizontal conduit
US8419812B2 (en) 2006-12-05 2013-04-16 Ses Ip Ab Reactor for pyrolysis and method for charging and emptying such a reactor
US20100031571A1 (en) 2006-12-05 2010-02-11 Bengt-Sture Ershag Reactor for pyrolysis and method for charging and emptying such a reactor
US20080223269A1 (en) 2007-03-18 2008-09-18 Paoluccio John A Method and apparatus for biomass torrefaction using conduction heating
US20150237813A1 (en) 2007-10-09 2015-08-27 Leslie A. Field Systems for decreasing local temperature using high albedo materials
US20100120128A1 (en) 2008-06-18 2010-05-13 Zhi-Wei Liang Eco-engineering for systematic carbon mitigation
US8287728B2 (en) 2009-02-10 2012-10-16 Fountainhead L.L.C. Elevated swale for treatment of contaminated stormwater
US20120079762A1 (en) 2009-04-17 2012-04-05 European Charcoal Ag Continuously Converting Biomass
WO2010122525A1 (en) 2009-04-24 2010-10-28 Savino Sartori Process for converting biomass to solid fuel
US8986507B2 (en) 2009-04-27 2015-03-24 European Charcoal Ag Continuously converting biomass
WO2010129996A1 (en) 2009-05-14 2010-11-18 Chaotech Pty Ltd A pyrolytic process and apparatus for producing biomass char and energy
US8747797B2 (en) 2009-06-08 2014-06-10 Full Circle Biochar, Inc. Biochar
US8361186B1 (en) 2009-06-08 2013-01-29 Full Circle Biochar, Inc. Biochar
US20120237994A1 (en) 2009-08-12 2012-09-20 University Of Georia Research Foundation, Inc. Biochars, methods of using biochars, methods of making biochars and reactors
US20110100272A1 (en) 2009-08-20 2011-05-05 Robert Joel Hasselbring Vortex incinerator
US20120193212A1 (en) 2009-10-07 2012-08-02 Katsumori Taniguro Method for treating biomass material and method for using heat energy
US9139790B2 (en) 2009-10-07 2015-09-22 Katsumori Taniguro Method for treating biomass material and method for using heat energy
US20110114144A1 (en) 2009-11-17 2011-05-19 Green Liquid and Gas Technologies Improved process and device for the pyrolysis of feedstock
US20110172092A1 (en) 2010-01-13 2011-07-14 Ut-Battelle, Llc Biochar Production Method and Composition Therefrom
WO2011097183A2 (en) 2010-02-03 2011-08-11 University Of Florida Research Foundation, Inc. Biologically activated biochar, methods of making biologically activated biochar, and methods of removing contaminants from water
US20110252699A1 (en) 2010-02-12 2011-10-20 Britton Shepard Biochar retort kiln
US20120305380A1 (en) 2010-02-23 2012-12-06 Shanxi Supply And Marketing Cooperative Method and device for carbonification of crop straws
US9321966B2 (en) 2010-02-23 2016-04-26 Shanxi Supply And Marketing Cooperative Method for carbonization of crop straws
US20130068690A1 (en) 2010-04-20 2013-03-21 North Carolina State University Adsorption devices, systems and methods
WO2011143718A1 (en) 2010-05-21 2011-11-24 Errol John Smith Biochar-coke produced in an energy efficient manner
US8812162B2 (en) 2010-11-05 2014-08-19 Clearstak Llc Intelligently-controlled catalytic converter for biofuel-fired boiler
WO2012061795A2 (en) 2010-11-05 2012-05-10 Clearstak Llc Intelligently-controlled catalytic converter for biofuel-fired boiler
US20120116589A1 (en) 2010-11-05 2012-05-10 Clearstak Llc Intelligently-controlled catalytic converter for biofuel-fired boiler
US9975792B2 (en) 2011-04-08 2018-05-22 United Laboratories, Inc. Water-dissolvable device for treatment of waste material
US8100990B2 (en) 2011-05-15 2012-01-24 Avello Bioenery, Inc. Methods for integrated fast pyrolysis processing of biomass
US8673150B2 (en) 2011-05-31 2014-03-18 George John Joseph Pearson Method for reducing organic waste in waste water
US20180327329A1 (en) 2011-06-06 2018-11-15 Cool Planet Energy Systems, Inc. Biochars and biochar treatment processes
US20120304718A1 (en) 2011-06-06 2012-12-06 Michael Cheiky Method for enhancing soil growth using bio-char
US20140323297A1 (en) 2011-11-23 2014-10-30 Cornell University Highly efficient organic fertilizer and components thereof
US20150136581A1 (en) 2012-02-16 2015-05-21 Biochar Now, Llc Controlled kiln and manufacturing system for biochar production
US20180282628A1 (en) 2012-02-16 2018-10-04 Biochar Now , Llc Exhaust System For A Biochar Kiln
US20190030725A1 (en) 2012-02-16 2019-01-31 Biochar Now, Llc Gripper assembly for portable biochar kiln
WO2013126477A1 (en) 2012-02-22 2013-08-29 University Of Florida Research Foundation, Inc. Biochar/metal composites, methods of making biochar/metal composites, and methods of removing contaminants from water
US20180282630A1 (en) 2012-03-11 2018-10-04 Biochar Now, Llc Managed Biochar Kiln
US20180282629A1 (en) 2012-03-11 2018-10-04 Biochar Now, Llc Flow Regulation For A Biochar Kiln
US20180072954A1 (en) 2012-03-11 2018-03-15 Biochar Now, Llc Airflow control and heat recovery in a managed kiln
US20170369785A1 (en) 2012-03-11 2017-12-28 Biochar Now, Llc Airflow control and heat recovery in a managed kiln
US9752078B2 (en) 2012-03-11 2017-09-05 Biochar Now, Llc Airflow control and heat recovery in a managed kiln
US20150040804A1 (en) 2012-03-11 2015-02-12 Biochar Now, Llc Airflow control and heat recovery in a managed kiln
US20180072953A1 (en) 2012-03-11 2018-03-15 Biochar Now, Llc Airflow control and heat recovery in a managed kiln
US9725371B2 (en) 2012-04-05 2017-08-08 Full Circle Biochar Inc. Biochar compositions and methods of use thereof
WO2013152337A1 (en) 2012-04-05 2013-10-10 Full Circle Biochar, Inc. Biochar compositions and methods of use thereof
US20130341175A1 (en) 2012-06-22 2013-12-26 The Regents Of The University Of Colorado, A Body Corporate Thermal treatment system and method
US8512644B1 (en) 2012-08-01 2013-08-20 Thomas C. Maganas System for transforming organic waste materials into thermal energy and electric power
US20150219341A1 (en) * 2012-09-12 2015-08-06 Flint Co., Ltd. Combustion apparatus
WO2014059141A1 (en) 2012-10-11 2014-04-17 Biochar Now, Llc Modified biochar treatment media, system and method
US20140151296A1 (en) 2012-11-30 2014-06-05 General Electric Company Produced water treatment to remove organic compounds
WO2014170670A2 (en) 2013-04-18 2014-10-23 Mbda Uk Limited Imaging apparatus and method
US20160075567A1 (en) 2013-05-02 2016-03-17 William Marsh Rice University Manufacture of oxidatively modified carbon (omc) and its use for capture of radionuclides and metals from water
WO2014179670A1 (en) 2013-05-02 2014-11-06 William Marsh Rice University Manufacture of oxidatively modified carbon (omc)
US20150144564A1 (en) 2013-11-25 2015-05-28 University Of Idaho Biochar water treatment
US20170055502A1 (en) 2014-05-15 2017-03-02 Coastal Environments, Incorporated Apparatus facilitating formation of a vertical oyster reef and shoreline rehabilitation with induced oyster reef barrier and lagoon implementing the same
US9878301B1 (en) 2014-06-09 2018-01-30 Orin Technologies, Llc Method and composition for the remediation of contaminants
US20160211041A1 (en) 2015-01-15 2016-07-21 Thomas C. Maganas Production of thermal energy and radioactive species
US9878924B2 (en) 2015-02-06 2018-01-30 Biochar Now, Llc Contaminant removal from water bodies with biochar
US20180105437A1 (en) 2015-02-06 2018-04-19 Biochar Now, Llc Contaminant removal from water with containerized biochar
US20160229709A1 (en) 2015-02-06 2016-08-11 Biochar Now, Llc Contaminant removal from water bodies with biochar
US20170283704A1 (en) 2016-04-03 2017-10-05 Biochar Now, Llc Portable biochar kiln

Non-Patent Citations (20)

* Cited by examiner, † Cited by third party
Title
Co-owned U.S. Appl. No. 15/997,367, filed Jun. 4, 2018.
Co-owned U.S. Appl. No. 15/997,418, filed Jun. 4, 2018.
Co-owned U.S. Appl. No. 15/997,440, filed Jun. 4, 2018.
English abstract for JP No. 4267968 dated May 27, 2009, 2 pgs.
Greenyarn-Technology in Nature, www.greenyarn.com, Copyright 2005 (downloaded Dec. 31, 2018), 5 pages, Greenyarn LLC, Boston, Massachusetts.
Greenyarn—Technology in Nature, www.greenyarn.com, Copyright 2005 (downloaded Dec. 31, 2018), 5 pages, Greenyarn LLC, Boston, Massachusetts.
International Preliminary Report on Patentability for International Application No. PCT/US2013/025999, dated Aug. 19, 2014, 5 pp.
International Preliminary Report on Patentability for International Application No. PCT/US2013/030079, dated Aug. 19, 2014, 5 pp.
International Preliminary Report on Patentability for International Application No. PCT/US2016/015943, dated Aug. 8, 2017, 7 pp.
International Search Report and the Written Opinion for app. No. PCT/US2013/025999 dated Jun. 12, 2013, 8 pgs.
International Search Report and the Written Opinion for app. No. PCT/US2013/030079 dated Jun. 18, 2013, 9 pgs.
International Search Report and the Written Opinion for app. No. PCT/US2016/015943 dated Jun. 9, 2016, 11 pgs.
Machine Translation of KR-10-2002-0010902, obtained from KIPRIS, Feb. 6, 2002, 83 pp.
Schmidt, Hans-Peter, "Novel Uses of Biochar-a key technology for the future of the planet," downloaded from https://scholarworks.umass.edu/biochar/2013/Benefits/7/ (downloaded Dec. 31, 2018), 106 pages.
Schmidt, Hans-Peter, "Novel Uses of Biochar—a key technology for the future of the planet," downloaded from https://scholarworks.umass.edu/biochar/2013/Benefits/7/ (downloaded Dec. 31, 2018), 106 pages.
Sugarman, Joe, "Is it Safe to Swim in the Chesapeake Bay?", Washingtonian Magazine, Jun. 28, 2016 (downloaded Dec. 31, 2018), 21 pages, Washington, D.C.
USEPA technical report "Toxic Contaminants in the Chesapeake by and Its Watershed; Extent and Severity of Occurrence and Potential Biological Effects," Technical Report Dec. 2012, pp. 44-59, Annapolis, Maryland.
Wang, Zhanghong, et al. Biochar produced from oak sawdust by Lanthanum (La)-involved pyrolysis for adsorption of ammonium (NH4+), nitrate (NO3−), and phosphate (PO3/4−), Chemosphere, 2015, pp. 646-653, vol. 119, Elsevier, China.
www.reddit.com, "Are you supposed to wear underwear under swim trunks?", blog conversation dated 2015 (downloaded Dec. 31, 2018), 8 pages.
Yao, Ying, et al., "Effect of biochar amendment on sorption and leaching of nitrate, ammonium, and phosphate in a sandy soil," Chemosphere, 2012, pp. 1467-1471, vol. 89, Elsevier, Gainesville, Florida.

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11135728B2 (en) 2012-02-16 2021-10-05 Biochar Now, Llc Lid assembly for portable biochar kiln
US10883052B2 (en) * 2016-04-03 2021-01-05 Biochar Now, Llc Biochar kiln
US20220074666A1 (en) * 2020-09-04 2022-03-10 Mobile Biochar Solutions LLC Mobile Kiln System
US11852411B2 (en) * 2020-09-04 2023-12-26 Mobile Biochar Solutions LLC Mobile kiln system

Also Published As

Publication number Publication date
US20190330533A1 (en) 2019-10-31
CA2962293C (en) 2021-05-18
CA2962387A1 (en) 2017-10-03
US10883052B2 (en) 2021-01-05
US20170283703A1 (en) 2017-10-05
CA2962293A1 (en) 2017-10-03
CA2962387C (en) 2021-05-18
US20170283704A1 (en) 2017-10-05
US10385274B2 (en) 2019-08-20

Similar Documents

Publication Publication Date Title
US10883052B2 (en) Biochar kiln
US20160377297A1 (en) Biomass fuel stove
KR101524436B1 (en) Firewood and pellet combination stove
US4129251A (en) Heat extractor for stoves
EP2978821B1 (en) A method for producing biochar
CN102266114B (en) Airflow descending dense curing barn having brick-concrete structure
CN104613641B (en) Flue-cured tobacco biological particles combustion furnace
JP3155768U (en) Hot air heater
JP7231528B2 (en) Batch type carbonization equipment
JP2011002183A (en) Pellet burner for pellet stove, pellet stove, and house for cultivating crop
US4506653A (en) Combustion method and apparatus
CN104359112B (en) A kind of high-temperature incinerator burning cover air curtain protection system
CN208269409U (en) A kind of biologic matter particle fuel hot-air furnace
KR101452467B1 (en) Apparatus for supplying hot air
CN104560073B (en) Biomass pyrolysis gasifier
RU116855U1 (en) CHARCOAL INSTALLATION
JP5887627B2 (en) Carbonization apparatus and carbonization method
CN106821036B (en) Automatic temperature control structure suitable for barbecue oven
CN205373002U (en) Novel control by temperature change boiler is bred to intelligence
CN201819253U (en) Electrical control constant temperature furnace
RU2621418C2 (en) Pyrolysis boiler with the upper, layered combustion of fuel
KR20160067328A (en) Wood pellet stove
CN104697164B (en) A kind of burner
US9808859B2 (en) Furnace assembly
JP7399376B2 (en) Heat treatment equipment and heat treatment method

Legal Events

Date Code Title Description
AS Assignment

Owner name: BIOCHARNOW, LLC, COLORADO

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:OLANDER, MIKEL;PIERCE, PERRY;BEIERWALTES, WILLIAM T;AND OTHERS;SIGNING DATES FROM 20170306 TO 20170307;REEL/FRAME:041508/0784

STPP Information on status: patent application and granting procedure in general

Free format text: DOCKETED NEW CASE - READY FOR EXAMINATION

STPP Information on status: patent application and granting procedure in general

Free format text: NOTICE OF ALLOWANCE MAILED -- APPLICATION RECEIVED IN OFFICE OF PUBLICATIONS

AS Assignment

Owner name: BIOCHAR NOW, LLC, COLORADO

Free format text: CORRECTIVE ASSIGNMENT TO CORRECT THE LAST RECEIVING PARTY NAME PREVIOUSLY RECORDED AT REEL: 41508 FRAME: 784. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT;ASSIGNORS:OLANDER, MIKEL;PIERCE, PERRY;BEIERWALTES, WILLIAM T.;AND OTHERS;SIGNING DATES FROM 20190603 TO 20190606;REEL/FRAME:049450/0327

AS Assignment

Owner name: BIOCHAR NOW, LLC, COLORADO

Free format text: CORRECTIVE ASSIGNMENT TO CORRECT THE THE ASSIGNOR'S NAME FROM PERRY PIERCE TO PERRY PIERCE II PREVIOUSLY RECORDED ON REEL 049450 FRAME 0327. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT;ASSIGNORS:PIERCE, PERRY, II;OLANDER, MIKEL;BEIERWALTES, WILLIAM T.;AND OTHERS;SIGNING DATES FROM 20190603 TO 20190606;REEL/FRAME:050032/0643

STPP Information on status: patent application and granting procedure in general

Free format text: PUBLICATIONS -- ISSUE FEE PAYMENT VERIFIED

STCF Information on status: patent grant

Free format text: PATENTED CASE

MAFP Maintenance fee payment

Free format text: PAYMENT OF MAINTENANCE FEE, 4TH YR, SMALL ENTITY (ORIGINAL EVENT CODE: M2551); ENTITY STATUS OF PATENT OWNER: SMALL ENTITY

Year of fee payment: 4