US103465A - Improvement in machines for generating and carbureting hydrogen gas - Google Patents
Improvement in machines for generating and carbureting hydrogen gas Download PDFInfo
- Publication number
- US103465A US103465A US103465DA US103465A US 103465 A US103465 A US 103465A US 103465D A US103465D A US 103465DA US 103465 A US103465 A US 103465A
- Authority
- US
- United States
- Prior art keywords
- carbureting
- gas
- pipe
- holder
- generating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title description 8
- 239000007789 gas Substances 0.000 description 30
- 230000001808 coupling Effects 0.000 description 16
- 238000010168 coupling process Methods 0.000 description 16
- 238000005859 coupling reaction Methods 0.000 description 16
- 239000007788 liquid Substances 0.000 description 14
- 239000004215 Carbon black (E152) Substances 0.000 description 12
- 150000002430 hydrocarbons Chemical class 0.000 description 12
- 239000002253 acid Substances 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000010276 construction Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- 238000009877 rendering Methods 0.000 description 2
- 230000036633 rest Effects 0.000 description 2
- 230000000630 rising Effects 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/10—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
- B01J8/0085—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction promoting uninterrupted fluid flow, e.g. by filtering out particles in front of the catalyst layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Definitions
- My invention relates to improvements upon machines for generating pure hydrogen gas by the action of dilute acid upon iron or zinc filings or chippings, and to devices in combination therewith for carburetin g said gasbefore it leaves the apparatus in which it is generated by passing it through gasoline or other hydrocarbon liquid; and my improvements consist, first, in so constructing and arranging the wire basket for holding the metal chippings that it m.
- Figure 1 represents a vertical section of an apparatus containing my improvements
- Fig. 2 a sectional view of my improved pipe-couplin g.
- A is a cylindrical vessel, of any desired size, made of sheet metal, having an inverted conical bottom, B, from the apex of which apipe, a, extends through the side of the cylinder and up to the top of the same on the outside, where it terminates in a funnel, b, for introducing the dilute acid.
- this pipe branches, and the branch a, provided with a miter-valve, 1), serves for drawingoff the sediment depositedin the acidulated water.
- this pipe Within said cylinder A, and concentric therewith, is another cylinder, C, attached to the bottom 13, and extending up flush with top of the cylinder A, forming a water-tight annular chamber, 0, between said cylinders.
- the gasholderD dips in the ordinary way.
- Said gasholder is annular in form, having acylindrical cavity or opening down through its center, for insertin g the carburetin g vessel and metal-holding basket.
- the carbureting-vessel E is the carbureting-vessel, which contains the hydrocarbon liquid, through which the gas passes from the generating-chamber before passing into the holder.
- This carbureting-vessel F is surrounded by a cylinder, F attached to the same cover which dips into the annular chamber d, thus forming a liquid joint or seal, to prevent the escape of gas from the generating-chamber around the outside of the carbureting-vessel.
- the said carbureting-vessel E is divided into two compartments by an annular partition, which compartments communicate with each other through openings f f, the gas being introduced into the inner compartment only.
- Gr is the gas-generating chamber, immedi ately under the carbureting-chamber.
- H is a woven-wire basket for holding the metal turnings or chippings; and H, a cone 'of woven wire, rising from thebottom of said basket, to
- the wire basket H is suspended 117i): the earbureting-vessel by means of hookjsfjy-j 'j, or, when said hooks are detached, rests upon cross-slats k, which, as well as the wings or fans 70, attached to the inner cylinder of the holder, serve as agitators, to mix the acid and water by rotating the holder.
- a cylinder or tube, L Extending down through theceuter of the carbureting-vessel to the bottom thereof is a cylinder or tube, L, which is closed at the top' by a screw or clamp cap,M, and is used for introducing the liquid hydrocarbon into the carbureting-chamber.
- a smaller pipe, L is located within the pipe L, its lower end opening to the gas-generating chamber, and its upper end being covered by a hood, I, to prevent the hydrocarbon liquid from entering the pipe L when poured down the pipe L.
- the hydrocarbon liquid enters the carburetin g-chamber through openings or perforations t t, and the gas, risin g from the generating-chal'nber through the pipe L, descends around the outside of said pipe to the said perforations 11 4, through which it enters the carbureting-chamber at the bottom, thence passing up through the hydrocarbon liquid and over into the holder through the connecting-pipe T.
- this connecting-pipe is made detachable; and in order to prevent the escape of gas from the holder when the pipe is detached, I employ a coupling device and a stop-cock in combination, so constructed and arranged that the pipe cannot be uncoupled without turning the stop-cock, so as to close that part of the pipe which connects with the gas-holder, and so preventing the escape of gas therefrom.
- This combined coupling device and stop-cock are most clearly shown in Fig. 2.
- the coupling device consists of a clamp or shackle, 0, provided with two handles, 1) p, and the stop-cock S is provided with a handle, t and these devices are so arranged that the planes of rotation of the handles cross each other at right angles, and so that the handles of the coupling device cannot be turned to uncouple the connecting-pipe till the handle of the stop-cock has been so turned as to close the pipe leading to the gas-holder.
- the hooks on the lower end of the carbureting-vessel engage with hooks on cross-rods on the top of the metal-holding basket, and as said hooks all turn in the same direction they may be made to seize or release the basket by partially rotating the said carbureting-vessel.
- the carburetingvessel may be removed from the apparatus, either with or without the basket, as may be desired; and in either case, the connecting pipe N being uncoupled and that part entering the gas-holder being closed by the stopcock O, the flow of gas to the burners will be continued Without interruption till the holder is exhausted, though the carbureting-vessel and metal-holding basket may both or either of them be removed from the apparatus.
- Q is a condenser, through which the gas must pass from the holder before reaching the service-pipe g.
- the apparatus so constructed and arranged that the carbureting vessel may be re moved from the apparatus, either with or without the metal-holding basket, without arresting the flow of gas to the burners, substantially as and for the purpose set forth.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Feeding And Controlling Fuel (AREA)
Description
IPATENTED MAY 24, 1870.
- H. LHOYT. I MACHINE FOR GENERATING ANDCARBURETING HYDROGEN GAS.
INVENTDP,
VS/'1' INES SE S .JJ N
UNITED STATES PATENT OEEIoE.
HENRY I. HOYT, OF-NORWALK, CONNECTICUT.
Specification forming part of Letters Patent N 0. 103,465, dated May 24, 1870.
To all whom it may concern:
Be it known that I, HENRY I. HOYT, 01 N orwalk, in the county of Fairfield and State of Connecticut, have invented certain new and useful Improvements in Machines for Generating and Carbureting Hydrogen Gas; and I hereby declare that the following is a full, clear, and exact description thereof, reference being had to the accompanying drawings, making a part of this specification, and the letters of reference marked thereon, in which the same letter represents the same thing in each figure.
My invention relates to improvements upon machines for generating pure hydrogen gas by the action of dilute acid upon iron or zinc filings or chippings, and to devices in combination therewith for carburetin g said gasbefore it leaves the apparatus in which it is generated by passing it through gasoline or other hydrocarbon liquid; and my improvements consist, first, in so constructing and arranging the wire basket for holding the metal chippings that it m. y be removed, recharged, and replaced without stopping the supply of ga to the burners secondly, in so constructing and arranging the vessel which contains the carbureting-chamber that it can be removed from the apparatus without stopping the flow of gas to the burners; thirdly, in the construction and employment of a combined pipe and coupling and stop-cock for the pipe which connects the carbureting-chamber with the gas-holder, said coupling being so constructed and arranged that it cannot be disconnected for the purpose of removing the carburetingchamber without closing the pipe from the gas-holder so as to confine the gas therein.
In the accompanying drawings, Figure 1 represents a vertical section of an apparatus containing my improvements, and Fig. 2 a sectional view of my improved pipe-couplin g.
A is a cylindrical vessel, of any desired size, made of sheet metal, having an inverted conical bottom, B, from the apex of which apipe, a, extends through the side of the cylinder and up to the top of the same on the outside, where it terminates in a funnel, b, for introducing the dilute acid.
At the bottom of the cylinder A, and at the outside thereof, this pipe a branches, and the branch a, provided with a miter-valve, 1), serves for drawingoff the sediment depositedin the acidulated water. Within said cylinder A, and concentric therewith, is another cylinder, C, attached to the bottom 13, and extending up flush with top of the cylinder A, forming a water-tight annular chamber, 0, between said cylinders. Into this annular water-space the gasholderD dips in the ordinary way. Said gasholder is annular in form, having acylindrical cavity or opening down through its center, for insertin g the carburetin g vessel and metal-holding basket. Within said cylindrical opening, and concentric therewith, is another cylinder, E, which is attached to the cylinder which forms the inner wall of the holder by a watertight joint at e, forming an annular waterchamber between the said'cylinder E'and the inner wall of the annular gas-holder.
F is the carbureting-vessel, which contains the hydrocarbon liquid, through which the gas passes from the generating-chamber before passing into the holder. This carbureting-vessel F is surrounded by a cylinder, F attached to the same cover which dips into the annular chamber d, thus forming a liquid joint or seal, to prevent the escape of gas from the generating-chamber around the outside of the carbureting-vessel. The said carbureting-vessel E is divided into two compartments by an annular partition, which compartments communicate with each other through openings f f, the gas being introduced into the inner compartment only.
Gr is the gas-generating chamber, immedi ately under the carbureting-chamber. H is a woven-wire basket for holding the metal turnings or chippings; and H, a cone 'of woven wire, rising from thebottom of said basket, to
facilitate the upward flow of the gas and 'pre-' vent it from passing out into the holder before passing through the carbureting chamber.
The wire basket H is suspended 117i): the earbureting-vessel by means of hookjsfjy-j 'j, or, when said hooks are detached, rests upon cross-slats k, which, as well as the wings or fans 70, attached to the inner cylinder of the holder, serve as agitators, to mix the acid and water by rotating the holder.
Extending down through theceuter of the carbureting-vessel to the bottom thereof is a cylinder or tube, L, which is closed at the top' by a screw or clamp cap,M, and is used for introducing the liquid hydrocarbon into the carbureting-chamber.
A smaller pipe, L, is located within the pipe L, its lower end opening to the gas-generating chamber, and its upper end being covered by a hood, I, to prevent the hydrocarbon liquid from entering the pipe L when poured down the pipe L. The hydrocarbon liquid enters the carburetin g-chamber through openings or perforations t t, and the gas, risin g from the generating-chal'nber through the pipe L, descends around the outside of said pipe to the said perforations 11 4, through which it enters the carbureting-chamber at the bottom, thence passing up through the hydrocarbon liquid and over into the holder through the connecting-pipe T.
In order to admit of the removal of the carbureting-vessel from the apparatus, this connecting-pipe is made detachable; and in order to prevent the escape of gas from the holder when the pipe is detached, I employ a coupling device and a stop-cock in combination, so constructed and arranged that the pipe cannot be uncoupled without turning the stop-cock, so as to close that part of the pipe which connects with the gas-holder, and so preventing the escape of gas therefrom. This combined coupling device and stop-cock are most clearly shown in Fig. 2.
The coupling device consists of a clamp or shackle, 0, provided with two handles, 1) p, and the stop-cock S is provided with a handle, t and these devices are so arranged that the planes of rotation of the handles cross each other at right angles, and so that the handles of the coupling device cannot be turned to uncouple the connecting-pipe till the handle of the stop-cock has been so turned as to close the pipe leading to the gas-holder.
The hooks on the lower end of the carbureting-vessel engage with hooks on cross-rods on the top of the metal-holding basket, and as said hooks all turn in the same direction they may be made to seize or release the basket by partially rotating the said carbureting-vessel. By this means the carburetingvessel may be removed from the apparatus, either with or without the basket, as may be desired; and in either case, the connecting pipe N being uncoupled and that part entering the gas-holder being closed by the stopcock O, the flow of gas to the burners will be continued Without interruption till the holder is exhausted, though the carbureting-vessel and metal-holding basket may both or either of them be removed from the apparatus.
Q is a condenser, through which the gas must pass from the holder before reaching the service-pipe g.
It will be seen that as the gas-holder rises it carries the carbureting-vessel and metal basket with it, so that when an excess of gas is generated the holder will lift the metalholding basket out of the dilute acid, and no more gas will be generated till the holder again descends from exhaustion, thus rendering the apparatus automatically self-regulating. This feature, however, is not new, and I lay no claim to it. t
In this application I have described several devices which are claimed jointly by John T. Earle and myself in an application for Letters Patent by us now pending in the Patent Office, all of which I disclaim as my sole invention. There are other devices described which are not new, and have been patented to others; I therefore disclaim everything described herein except what is hereinafter specifically claimed; but
I do claim as improvements invented by me, and desire to secure by Letters Patent 1. The apparatus so constructed and the metal-holding basket so arranged that the latter can be removed from the apparatus without arresting the flow of the gas to the burners, substantially as and for the purpose described.
2. The apparatus so constructed and arranged that the carbureting vessel may be re moved from the apparatus, either with or without the metal-holding basket, without arresting the flow of gas to the burners, substantially as and for the purpose set forth.
3. The combined coupling device and stop cock, constructed, arranged, and operating substantially as described.
4. The combined coupling device and stopcock, in combination with the removable carbureting-chamber and the gas-holder, substantially as described.
HENRY I. HOYT.
\Vitnesses S. J. GORDON, THOMAS J. BALDWIN.
Publications (1)
Publication Number | Publication Date |
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US103465A true US103465A (en) | 1870-05-24 |
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US103465D Expired - Lifetime US103465A (en) | Improvement in machines for generating and carbureting hydrogen gas |
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