UA43405C2 - РИФОРМІНГ-АПАРАТ ДЛЯ КОНВЕРСІЇ МЕТАНУ ТА ПАРИ В СО,С0<sub>2</sub> І Н<sub>2</sub> ТА УЩІЛЬНЮЮЧИЙ ЗАСІБ ДЛЯ ПРОВЕДЕННЯ ЕНДОТЕРМІЧНИХ АБО ЕКЗОТЕРМІЧНИХ ХІМІЧНИХ РЕАКЦІЙ У РЕАКТОРАХ - Google Patents

РИФОРМІНГ-АПАРАТ ДЛЯ КОНВЕРСІЇ МЕТАНУ ТА ПАРИ В СО,С0<sub>2</sub> І Н<sub>2</sub> ТА УЩІЛЬНЮЮЧИЙ ЗАСІБ ДЛЯ ПРОВЕДЕННЯ ЕНДОТЕРМІЧНИХ АБО ЕКЗОТЕРМІЧНИХ ХІМІЧНИХ РЕАКЦІЙ У РЕАКТОРАХ

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Publication number
UA43405C2
UA43405C2 UA97115447A UA97115447A UA43405C2 UA 43405 C2 UA43405 C2 UA 43405C2 UA 97115447 A UA97115447 A UA 97115447A UA 97115447 A UA97115447 A UA 97115447A UA 43405 C2 UA43405 C2 UA 43405C2
Authority
UA
Ukraine
Prior art keywords
conversion
area
vapor
methane
heat exchange
Prior art date
Application number
UA97115447A
Other languages
English (en)
Russian (ru)
Inventor
Ерманно Філіппі
Эрманно Филиппи
Енріко Ріцці
Энрико РИЦЦИ
Original Assignee
Аммоніа Казале С.А.
Аммониа Казале С.А.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Аммоніа Казале С.А., Аммониа Казале С.А. filed Critical Аммоніа Казале С.А.
Publication of UA43405C2 publication Critical patent/UA43405C2/uk

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/067—Heating or cooling the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C1/00—Ammonia; Compounds thereof
    • C01C1/02—Preparation, purification or separation of ammonia
    • C01C1/04—Preparation of ammonia by synthesis in the gas phase
    • C01C1/0405—Preparation of ammonia by synthesis in the gas phase from N2 and H2 in presence of a catalyst
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/152—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the reactor used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212—Plates; Jackets; Cylinders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212—Plates; Jackets; Cylinders
    • B01J2208/00221—Plates; Jackets; Cylinders comprising baffles for guiding the flow of the heat exchange medium
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0833—Heating by indirect heat exchange with hot fluids, other than combustion gases, product gases or non-combustive exothermic reaction product gases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844—Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/16—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged in parallel spaced relation
    • F28D7/163—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged in parallel spaced relation with conduit assemblies having a particular shape, e.g. square or annular; with assemblies of conduits having different geometrical features; with multiple groups of conduits connected in series or parallel and arranged inside common casing
    • F28D7/1669—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged in parallel spaced relation with conduit assemblies having a particular shape, e.g. square or annular; with assemblies of conduits having different geometrical features; with multiple groups of conduits connected in series or parallel and arranged inside common casing the conduit assemblies having an annular shape; the conduits being assembled around a central distribution tube
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F2265/00—Safety or protection arrangements; Arrangements for preventing malfunction
    • F28F2265/26—Safety or protection arrangements; Arrangements for preventing malfunction for allowing differential expansion between elements
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Analytical Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Abstract

Запропонований риформінг-апарат для конверсії метану та пари в CO, CO2 і Н2, містить переважно циліндричний зовнішній кожух з трубами, розміщеними в ньому, та з визначеною зоною непрямого теплообміну і зоною для подавання газоподібного потоку, що включає метан та пару, до зони непрямого теплообміну. Отвір, виконаний у згаданому кожусі, для подавання у згадану зону непрямого теплообміну розігрітого газового потоку як джерела для згаданої конверсії. Труби виконані з плаваючими головками, що містять каталізатор риформінгу, які розміщені вздовж головної осі у згадану зону непрямого теплообміну, та сполучення потоку зі згаданою зоною подавання. Камера для збирання газового потоку, що включає CO, CO2 та H2, отримані в результаті згаданої конверсії, розташована внизу за потоком від згаданих труб. Для вилучення з кожуха згаданого газового потоку, що включає CO, СО2 та Н2, трубопровід виконаний відкритим.
UA97115447A 1996-11-12 1997-11-12 РИФОРМІНГ-АПАРАТ ДЛЯ КОНВЕРСІЇ МЕТАНУ ТА ПАРИ В СО,С0<sub>2</sub> І Н<sub>2</sub> ТА УЩІЛЬНЮЮЧИЙ ЗАСІБ ДЛЯ ПРОВЕДЕННЯ ЕНДОТЕРМІЧНИХ АБО ЕКЗОТЕРМІЧНИХ ХІМІЧНИХ РЕАКЦІЙ У РЕАКТОРАХ UA43405C2 (uk)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP96118105A EP0841301B1 (en) 1996-11-12 1996-11-12 Reforming apparatus

Publications (1)

Publication Number Publication Date
UA43405C2 true UA43405C2 (uk) 2001-12-17

Family

ID=8223390

Family Applications (1)

Application Number Title Priority Date Filing Date
UA97115447A UA43405C2 (uk) 1996-11-12 1997-11-12 РИФОРМІНГ-АПАРАТ ДЛЯ КОНВЕРСІЇ МЕТАНУ ТА ПАРИ В СО,С0<sub>2</sub> І Н<sub>2</sub> ТА УЩІЛЬНЮЮЧИЙ ЗАСІБ ДЛЯ ПРОВЕДЕННЯ ЕНДОТЕРМІЧНИХ АБО ЕКЗОТЕРМІЧНИХ ХІМІЧНИХ РЕАКЦІЙ У РЕАКТОРАХ

Country Status (11)

Country Link
US (2) US6426054B1 (uk)
EP (2) EP1138630A3 (uk)
JP (1) JPH10182101A (uk)
CN (2) CN1172841C (uk)
AU (1) AU735457B2 (uk)
BR (1) BR9705467A (uk)
CA (1) CA2219970C (uk)
DE (1) DE69631886T2 (uk)
RO (1) RO118128B1 (uk)
RU (1) RU2185879C2 (uk)
UA (1) UA43405C2 (uk)

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CN104645897B (zh) * 2015-02-11 2016-05-04 南京敦先化工科技有限公司 一种双封头可控水移热反应器
CN105861055B (zh) * 2016-06-07 2019-01-22 太原理工大学 用于甲烷二氧化碳催化重整制备合成气的反应装置
CN108278913B (zh) * 2017-12-29 2019-11-12 昌邑恒昌新材料科技有限公司 一种非焊接双密封快速拆装式蒸汽换热器及其实现方法
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Also Published As

Publication number Publication date
CN1172841C (zh) 2004-10-27
CA2219970A1 (en) 1998-05-12
EP1138630A2 (en) 2001-10-04
DE69631886T2 (de) 2004-12-30
EP1138630A3 (en) 2003-04-02
EP0841301A1 (en) 1998-05-13
AU735457B2 (en) 2001-07-12
US6426054B1 (en) 2002-07-30
AU4359597A (en) 1998-05-14
CA2219970C (en) 2007-01-09
CN1536252A (zh) 2004-10-13
EP0841301B1 (en) 2004-03-17
JPH10182101A (ja) 1998-07-07
MX9708707A (es) 1998-06-30
CN1182050A (zh) 1998-05-20
RO118128B1 (ro) 2003-02-28
RU2185879C2 (ru) 2002-07-27
US20020182129A1 (en) 2002-12-05
BR9705467A (pt) 1999-05-25
DE69631886D1 (de) 2004-04-22

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