UA104721C2 - Каталізатори - Google Patents

Каталізатори

Info

Publication number
UA104721C2
UA104721C2 UAA201013423A UAA201013423A UA104721C2 UA 104721 C2 UA104721 C2 UA 104721C2 UA A201013423 A UAA201013423 A UA A201013423A UA A201013423 A UAA201013423 A UA A201013423A UA 104721 C2 UA104721 C2 UA 104721C2
Authority
UA
Ukraine
Prior art keywords
carboxylic acid
support
onto
surface area
precursor
Prior art date
Application number
UAA201013423A
Other languages
English (en)
Russian (ru)
Inventor
де Лоосдрехт Ян ван
Майкл Стівен Датт
Ян Маттеус Ботха
Original Assignee
Сасол Текнолоджі (Пропріетарі) Лімітед
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Сасол Текнолоджі (Пропріетарі) Лімітед filed Critical Сасол Текнолоджі (Пропріетарі) Лімітед
Publication of UA104721C2 publication Critical patent/UA104721C2/uk

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Процес для приготування попередника каталізатора синтезу Фішера-Тропша на основі кобальту, який включає введення багатофункціональної карбонової кислоти загальної формули (1) EMBED ISISServer (1) чи її попередника, де С* в кожному з С*R1 і C*R2 є вуглецем sp2, і R1 і R2 є однаковими чи різними і кожний вибирається з групи, що містить водень і органічну групу, в та/або на дисперсну підкладку каталізатору. Відношення кількості використаної багатофункціональної карбонової кислоти до площі поверхні підкладки становить щонайменше 0,3 мкмоль карбонової кислоти/м2 площі поверхні підкладки. Одночасно з введенням карбонової кислоти в та/або на підкладку каталізатору або після нього в та/або на підкладку каталізатора вводять сполуку кобальту. Таку імпрегновану підкладку кальцинують, щоб отримати попередник каталізатору синтезу вуглеводнів типу Фішера-Тропша на основі кобальту.
UAA201013423A 2008-04-15 2009-04-03 Каталізатори UA104721C2 (uk)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US4493408P 2008-04-15 2008-04-15
ZA200803339 2008-04-15
PCT/IB2009/051407 WO2009127990A1 (en) 2008-04-15 2009-04-03 Catalysts

Publications (1)

Publication Number Publication Date
UA104721C2 true UA104721C2 (uk) 2014-03-11

Family

ID=41055331

Family Applications (1)

Application Number Title Priority Date Filing Date
UAA201013423A UA104721C2 (uk) 2008-04-15 2009-04-03 Каталізатори

Country Status (12)

Country Link
US (1) US8394864B2 (uk)
EP (1) EP2276563B1 (uk)
JP (1) JP5395164B2 (uk)
CN (1) CN102006932A (uk)
AP (1) AP2010005415A0 (uk)
AU (1) AU2009237307B2 (uk)
BR (1) BRPI0911218B8 (uk)
CA (1) CA2721637C (uk)
NZ (1) NZ588412A (uk)
RU (1) RU2481156C2 (uk)
UA (1) UA104721C2 (uk)
WO (1) WO2009127990A1 (uk)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2481156C2 (ru) 2008-04-15 2013-05-10 Сэсол Текнолоджи (Проприетери) Лимитед Способ получения катализатора синтеза фишера-тропша
UA106739C2 (uk) * 2009-02-26 2014-10-10 Сесол Текнолоджі (Пропрайєтері) Лімітед Спосіб одержання каталізаторів фішера-тропша та їх застосування
EP2488476B1 (en) 2009-10-13 2013-12-04 Sasol Technology (Proprietary) Limited Production of hydrocarbons
CN103442806B (zh) 2011-02-07 2017-07-11 维洛塞斯科技有限公司 费‑托催化剂及其制备方法
GB201201619D0 (en) * 2012-01-30 2012-03-14 Oxford Catalysts Ltd Treating of catalyst support
CA2833964C (en) 2011-05-06 2019-07-02 Sasol Technology (Proprietary) Limited Process for preparing a cobalt-containing hydrocarbon synthesis catalyst precursor
CN102989511B (zh) * 2011-09-08 2015-04-29 中国石油化工股份有限公司 一种费托合成催化剂及其制备和应用
CN102989458B (zh) * 2011-09-08 2015-03-18 中国石油化工股份有限公司 一种费托合成催化剂的制备方法以及由该方法制备的催化剂
FR2991198B1 (fr) * 2012-05-30 2015-05-15 IFP Energies Nouvelles Procede de preparation d'un catalyseur mettant en oeuvre au moins une etape de sechage rapide et au moins une etape de sechage en lit fluidise et son utilisation pour la synthese fischer-tropsch
GB201214122D0 (en) * 2012-08-07 2012-09-19 Oxford Catalysts Ltd Treating of catalyst support
US9192921B1 (en) 2014-09-10 2015-11-24 Chevron U.S.A. Inc. Support for Fischer-Tropsch catalyst having improved activity
US9687826B2 (en) 2014-09-10 2017-06-27 Chevron U.S.A. Inc. Support for fischer-tropsch catalyst having improved activity
WO2016201218A2 (en) 2015-06-12 2016-12-15 Velocys, Inc. Synthesis gas conversion process
EP3393659B1 (en) 2015-12-21 2022-02-09 Shell Internationale Research Maatschappij B.V. Method for preparing a hydrogenation catalyst
FR3050663A1 (fr) 2016-04-29 2017-11-03 Ifp Energies Now Catalyseur de cobalt a base d'un support contenant une phase d'oxyde mixte contenant du cobalt et/ou du nickel prepare par l'utilisation d'acide oxalique ou d'oxalate
FR3050659B1 (fr) 2016-04-29 2021-09-03 Ifp Energies Now Catalyseur de cobalt a base d'un support contenant une phase d'oxyde mixte contenant du cobalt et/ou du nickel prepare par l'utilisation d'un compose ester
FR3050660B1 (fr) 2016-04-29 2021-09-03 Ifp Energies Now Catalyseur de cobalt a base d'un support contenant une phase d'oxyde mixte contenant du cobalt et/ou du nickel prepare par l'utilisation d'un compose comportant deux fontions acides carboxyliques et au moins trois atomes de carbone
FR3057472B1 (fr) 2016-10-17 2018-11-16 IFP Energies Nouvelles Catalyseur de cobalt a base d'un support contenant une phase d'oxyde mixte contenant du cobalt et/ou du nickel prepare par l'utilisation d'un compose hydrogenocarbone.
FR3064498B1 (fr) * 2017-03-30 2021-10-29 Ifp Energies Now Procede de preparation de catalyseurs a base de cobalt
CN108435177A (zh) * 2018-03-26 2018-08-24 青岛科技大学 一种多孔碳包覆纳米金属钴复合催化剂及其制备和应用
FR3087673B1 (fr) 2018-10-25 2022-12-02 Ifp Energies Now Catalyseur de cobalt a base d’un support comprenant une phase d’oxyde mixte contenant du cobalt et/ou du nickel prepare a partir d’un compose dilactone
FR3087786B1 (fr) * 2018-10-25 2020-12-18 Ifp Energies Now Procede de synthese fischer-tropsch comprenant un catalyseur prepare par addition d’un compose organique en phase gazeuse
FR3087672B1 (fr) 2018-10-25 2023-09-29 Ifp Energies Now Catalyseur de cobalt a base d’un support comprenant une phase d’oxyde mixte contenant du cobalt et/ou du nickel prepare a partir d’un compose organique de la famille des carboxyanhydrides
FR3087671B1 (fr) 2018-10-25 2023-09-29 Ifp Energies Now Catalyseur de cobalt a base d’un support comprenant une phase d’oxyde mixte contenant du cobalt et/ou du nickel prepare a partir d’un compose ether
CA3122220A1 (en) * 2018-12-10 2020-06-18 Sasol South Africa Limited Process for preparing a cobalt-containing catalyst precursor and process for hydrocarbon synthesis
JP7239346B2 (ja) * 2019-02-21 2023-03-14 日揮触媒化成株式会社 フィッシャー・トロプシュ合成用触媒酸化物の製造方法
FR3119556A1 (fr) 2021-02-11 2022-08-12 IFP Energies Nouvelles Procédé de préparation d’un catalyseur de Fischer-Tropsch en présence d’un additif et d’une étape de calcination spécifique

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1130265A (en) 1978-10-06 1982-08-24 William J. Ball Process for the production of amorphous aluminosilicates and their use as catalysts
US4518707A (en) * 1983-12-14 1985-05-21 Exxon Research & Engineering Co. Process for preparing high surface area iron/cobalt Fischer-Tropsch slurry catalysts
CA2038773C (en) 1990-04-04 1999-06-08 Kym B. Arcuri Slurry fischer-tropsch process with co/ti02 catalyst
US5248701A (en) * 1991-08-05 1993-09-28 Exxon Research And Engineering Company Substituted cobalt catalysts for Fischer-Tropsch synthesis
DZ2013A1 (fr) 1995-04-07 2002-10-23 Sastech Ltd Catalyseurs.
US5863856A (en) * 1997-04-22 1999-01-26 Exxon Research And Engineering Company Preparation of high activity catalysts the catalysts and their use
US5856261A (en) 1997-04-22 1999-01-05 Exxon Research And Engineering Company Preparation of high activity catalysts; the catalysts and their use
US5856260A (en) 1997-04-22 1999-01-05 Exxon Research And Engineering Company Preparation of high activity catalysts; the catalysts and their use
DZ2724A1 (fr) 1998-02-20 2003-09-01 Sasol Tech Pty Ltd Procédé pour la production d'hydrocarbures à partir d'un gaz de synthèse et leurs catalyseurs.
ZA200102782B (en) 1998-10-05 2002-08-26 Sasol Tech Pty Ltd Impregnation process for catalysts.
EP1119411B1 (en) 1998-10-05 2003-06-25 Sasol Technology (Proprietary) Limited Impregnation process for catalysts
KR100704998B1 (ko) 1999-02-26 2007-04-09 소니 가부시끼 가이샤 기록방법, 관리방법 및 기록장치
AU779645C (en) 1999-12-01 2005-12-01 Sasol Technology (Proprietary) Limited Cobalt catalysts
WO2001076734A1 (en) 2000-04-07 2001-10-18 Phillips Petroleum Company Process for preparing fischer-tropsch catalyst
AU6257801A (en) 2000-06-12 2001-12-24 Sasol Tech Pty Ltd Cobalt catalysts
DE60123791T2 (de) * 2000-07-14 2007-08-23 Shell Internationale Research Maatschappij B.V. Verfahren für die herstellung eines kobalt-trägerkatalysators und dessen vorläufer und die verwendung des trägerkatalysators
US20030008929A1 (en) 2001-07-03 2003-01-09 Conoco Inc. Surface active agent use in catalyst preparation
EP1432778B2 (en) 2001-07-27 2010-08-11 Sasol Technology (Proprietary) Limited Production of fischer-tropsch synthesis produced wax
US6753351B2 (en) * 2002-01-29 2004-06-22 Exxonmobil Research And Engineering Company Supported catalyst activation
RU2299764C2 (ru) * 2002-05-15 2007-05-27 Зюд-Хеми Аг Катализатор фишера-тропша, полученный при использовании высокочистого железосодержащего предшественника (варианты)
EP1827690A1 (en) * 2004-12-23 2007-09-05 Shell Internationale Research Maatschappij B.V. Process for preparing a catalyst
CN100425676C (zh) * 2005-04-29 2008-10-15 中国石油化工股份有限公司 一种加氢裂化催化剂组合物
WO2008135940A2 (en) * 2007-05-04 2008-11-13 Sasol Technology (Proprietary) Limited Catalysts
RU2481156C2 (ru) 2008-04-15 2013-05-10 Сэсол Текнолоджи (Проприетери) Лимитед Способ получения катализатора синтеза фишера-тропша

Also Published As

Publication number Publication date
BRPI0911218A2 (pt) 2015-09-29
CA2721637A1 (en) 2009-10-22
NZ588412A (en) 2012-06-29
AP2010005415A0 (en) 2010-10-31
US8394864B2 (en) 2013-03-12
RU2010146146A (ru) 2012-05-20
CA2721637C (en) 2016-02-09
AU2009237307B2 (en) 2013-04-18
EP2276563B1 (en) 2018-05-23
US20110028575A1 (en) 2011-02-03
CN102006932A (zh) 2011-04-06
JP2011519308A (ja) 2011-07-07
BRPI0911218B8 (pt) 2018-02-14
RU2481156C2 (ru) 2013-05-10
JP5395164B2 (ja) 2014-01-22
AU2009237307A1 (en) 2009-10-22
BRPI0911218B1 (pt) 2018-01-16
EP2276563A1 (en) 2011-01-26
WO2009127990A1 (en) 2009-10-22

Similar Documents

Publication Publication Date Title
UA104721C2 (uk) Каталізатори
Song et al. Improved effect of Fe on the stable NiFe/Al2O3 catalyst in low-temperature dry reforming of methane
Chen et al. Hydrogen production via steam reforming of acetic acid over biochar-supported nickel catalysts
Li et al. Development of nano-NiO/Al2O3 catalyst to be used for tar removal in biomass gasification
RU2011135465A (ru) Катализаторы
MY145792A (en) Hydro-oxidation process using a catalyst prepared from a gold cluster complex
MY160594A (en) Process for the preparation of a titanium zeolite catalyst
MY148512A (en) Production of aromatics from aliphatics
Aw et al. Insights into durable NiCo catalysts on β-SiC/CeZrO2 and γ-Al2O3/CeZrO2 advanced supports prepared from facile methods for CH4–CO2 dry reforming
WO2008135939A3 (en) Catalysts
KR101272082B1 (ko) 철-코발트 복합 촉매 및 그 제조 방법과 이를 촉매로 이용한 피셔-트롭쉬 합성 반응에서의 수성가스전환반응 활성구현과 고선택적 액체 연료 제조방법
WO2009124019A3 (en) Sour shift process for the removal of carbon monoxide from a gas stream
WO2009119977A3 (en) Cobalt/zirconium-phosphorus/silica catalyst for fischer-tropsch synthesis and method of preparing the same
WO2008016390A3 (en) Catalyst for the growth of carbon single-walled nanotubes
WO2008016456A3 (en) Molecular sieve composition (emm-10), its method of making, and use for hydrocarbon conversions
IN2012DN02790A (uk)
WO2010143783A3 (en) Iron-based catalyst for fischer-tropsch synthesis and preparation method thereof
DE602005026167D1 (de) Verfahren zur herstellung von trägerkatalysatoren aus metallbeladenen kohlenstoffnanoröhrchen
Ramesh et al. Template free synthesis of Ni-perovskite: an efficient catalyst for hydrogen production by steam reforming of bioglycerol
EP2165972A3 (en) Process for the production of hydrogen gas employing a thermally stable catalyst
CN103406137A (zh) 用于费托合成的氮掺杂碳纳米管负载型催化剂
WO2010059027A3 (en) A PROCESS FOR PRODUCING CARBON NANOTUBES (CNTs)
Wang et al. Two-stage gasification of sewage sludge for enhanced hydrogen production: alkaline pyrolysis coupled with catalytic reforming using waste-supported Ni catalysts
Ma et al. Application of engineered natural ores to intermediate‐and high‐temperature CO2 capture and conversion
Shang et al. Nano‐engineered nickel catalysts supported on 4‐channel α‐Al2O3 hollow fibers for dry reforming of methane