UA102767C2 - Способ рафинирования вторичного чернового свинцу от меди - Google Patents
Способ рафинирования вторичного чернового свинцу от меди Download PDFInfo
- Publication number
- UA102767C2 UA102767C2 UAA201202770A UAA201202770A UA102767C2 UA 102767 C2 UA102767 C2 UA 102767C2 UA A201202770 A UAA201202770 A UA A201202770A UA A201202770 A UAA201202770 A UA A201202770A UA 102767 C2 UA102767 C2 UA 102767C2
- Authority
- UA
- Ukraine
- Prior art keywords
- lead
- iron
- copper
- powder
- sulfur
- Prior art date
Links
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 54
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 53
- 239000010949 copper Substances 0.000 title claims abstract description 53
- 238000000034 method Methods 0.000 title claims abstract description 45
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 78
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 47
- 239000011593 sulfur Substances 0.000 claims abstract description 46
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 45
- 229910052742 iron Inorganic materials 0.000 claims abstract description 36
- 239000000843 powder Substances 0.000 claims abstract description 36
- 239000000203 mixture Substances 0.000 claims abstract description 35
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000010941 cobalt Substances 0.000 claims abstract description 24
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 24
- 229910000640 Fe alloy Inorganic materials 0.000 claims abstract description 18
- 238000001816 cooling Methods 0.000 claims abstract description 7
- 238000007670 refining Methods 0.000 claims description 44
- 238000006477 desulfuration reaction Methods 0.000 claims description 21
- 230000023556 desulfurization Effects 0.000 claims description 21
- 239000012256 powdered iron Substances 0.000 claims description 3
- 238000005265 energy consumption Methods 0.000 abstract description 2
- 238000009856 non-ferrous metallurgy Methods 0.000 abstract description 2
- 230000003247 decreasing effect Effects 0.000 abstract 1
- 239000000155 melt Substances 0.000 description 16
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 14
- 241000500881 Lepisma Species 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
- 238000005272 metallurgy Methods 0.000 description 8
- 230000008569 process Effects 0.000 description 8
- 230000009467 reduction Effects 0.000 description 8
- 239000002893 slag Substances 0.000 description 8
- 229910052785 arsenic Inorganic materials 0.000 description 7
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 7
- 230000003197 catalytic effect Effects 0.000 description 7
- 230000006872 improvement Effects 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 239000007789 gas Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- BWFPGXWASODCHM-UHFFFAOYSA-N copper monosulfide Chemical compound [Cu]=S BWFPGXWASODCHM-UHFFFAOYSA-N 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000007717 exclusion Effects 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 238000005984 hydrogenation reaction Methods 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000002480 mineral oil Substances 0.000 description 3
- 235000010446 mineral oil Nutrition 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 229910000978 Pb alloy Inorganic materials 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052797 bismuth Inorganic materials 0.000 description 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 229910052976 metal sulfide Inorganic materials 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 239000011265 semifinished product Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000009423 ventilation Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229910000531 Co alloy Inorganic materials 0.000 description 1
- 239000005749 Copper compound Substances 0.000 description 1
- 229910000796 S alloy Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- GSOLWAFGMNOBSY-UHFFFAOYSA-N cobalt Chemical compound [Co][Co][Co][Co][Co][Co][Co][Co] GSOLWAFGMNOBSY-UHFFFAOYSA-N 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 150000001880 copper compounds Chemical class 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007210 heterogeneous catalysis Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000010907 mechanical stirring Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Manufacture And Refinement Of Metals (AREA)
Abstract
Изобретение относится к области цветной металлургии, а именно – к способу рафинирования чернового свинца от меди. Способ включает удаление меди в два этапа, на первом этапе выполняют обезмедивание чернового свинца ликвацией – его охлаждением от 800- до 600- и снятием сухих шликеров, повторным охлаждением до 350- и снятием жирных шликеров, на втором этапе выполняют тонкое обезмедивание чернового свинца смесью, содержащей 12-18 масс. % порошка сплава железа или столько же порошка, содержащего железо, остальное – порошкообразная сера, которая замешивается в расплавленный свинец мешалкой, в количестве 0,8- на 1 тонну чернового свинца, при этом сплав
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| UAA201202770A UA102767C2 (ru) | 2012-03-07 | 2012-03-07 | Способ рафинирования вторичного чернового свинцу от меди |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| UAA201202770A UA102767C2 (ru) | 2012-03-07 | 2012-03-07 | Способ рафинирования вторичного чернового свинцу от меди |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| UA102767C2 true UA102767C2 (ru) | 2013-08-12 |
Family
ID=52274515
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| UAA201202770A UA102767C2 (ru) | 2012-03-07 | 2012-03-07 | Способ рафинирования вторичного чернового свинцу от меди |
Country Status (1)
| Country | Link |
|---|---|
| UA (1) | UA102767C2 (ru) |
-
2012
- 2012-03-07 UA UAA201202770A patent/UA102767C2/ru unknown
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2933448C (en) | A process for extracting noble metals from anode slime | |
| CN109923225A (zh) | 改进型焊料及用于生产高纯铅的方法 | |
| CN1800423A (zh) | 利用处理铅阳极泥的渣料生产锑白的工艺 | |
| AU2010246666B2 (en) | Recovery of precious metals from spent homogeneous catalysts | |
| CN113355525A (zh) | 一种铜冶炼渣协同搭配处理含金废渣的方法 | |
| CN1257295C (zh) | 一种火法提取镍的生产方法 | |
| US8500845B2 (en) | Process for refining lead bullion | |
| EP4061972B1 (en) | Improved copper smelting process | |
| CN115433835B (zh) | 一种同时回收汽车废催化剂中贵金属和制备高纯锑的方法 | |
| FI97396B (fi) | Menetelmä nikkelihienokiven valmistamiseksi ainakin osittain pyrometallurgisesti jalostetuista nikkelipitoisista raaka-aineista | |
| CN108531737B (zh) | 一种含铜污泥和线路板的综合处理系统 | |
| UA102767C2 (ru) | Способ рафинирования вторичного чернового свинцу от меди | |
| JP2012021176A (ja) | 金属鉛の製造方法 | |
| UA102768C2 (ru) | Способ рафинирования вторичного чернового свинцу от меди | |
| CN1188533C (zh) | 铜锌钴分离的熔炼法 | |
| RU2599464C2 (ru) | Шихта и способ алюминотермического получения сплава на основе хрома с ее использованием | |
| KR102598776B1 (ko) | 탄화규소를 포함하는 촉매로부터 백금족 금속을 회수하는 방법 | |
| EP4417719A1 (en) | Method of refining a lead-tin alloy | |
| RU2156820C1 (ru) | Способ переработки концентратов гравитационного обогащения, содержащих благородные металлы | |
| CN118406874B (zh) | 一种钢铁尘泥协同处置含铅废渣的资源化利用方法 | |
| CN108103328A (zh) | 一种铝铋中间合金的制备工艺 | |
| EP4314364B1 (en) | Improved method for recycling zinc (zn) | |
| RU1808812C (ru) | Способ получени кремни | |
| KR101118575B1 (ko) | 석유탈황 폐촉매의 용융환원을 위한 슬래그 조성물 | |
| KR20030065204A (ko) | 바나듐 함유 폐기물로부터 바나듐을 회수하는 재활용 방법 |