TWM679238U - Solar cell stack module - Google Patents

Solar cell stack module

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Publication number
TWM679238U
TWM679238U TW114211142U TW114211142U TWM679238U TW M679238 U TWM679238 U TW M679238U TW 114211142 U TW114211142 U TW 114211142U TW 114211142 U TW114211142 U TW 114211142U TW M679238 U TWM679238 U TW M679238U
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Taiwan
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perovskite
solar cell
light
silicon
battery pack
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TW114211142U
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Chinese (zh)
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許政鴻
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聯合再生能源股份有限公司
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Priority to TW114211142U priority Critical patent/TWM679238U/en
Publication of TWM679238U publication Critical patent/TWM679238U/en

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Abstract

A solar cell stack module includes a first substrate, a first encapsulation layer, a silicon cell group, a second encapsulation layer, a perovskite cell group, and a second substrate. The first encapsulation layer is disposed on the first substrate. The silicon cell group is disposed on the first encapsulation layer. The silicon cell group includes a plurality of silicon cell units electrically connected to each other and arranged along a first direction and a second direction. The second encapsulation layer is disposed on the silicon cell group. The perovskite cell group is disposed on the second encapsulation layer and does not directly contact the silicon cell group. The perovskite cell group includes a plurality of perovskite cell units electrically connected to each other and arranged along the first direction and the second direction. The second substrate is disposed on the perovskite cell group.

Description

太陽能電池疊層模組Solar cell multilayer module

本創作涉及一種太陽能電池疊層模組。This creation relates to a solar cell stack module.

目前常見的太陽能電池,若依照製作材料區分,大致可區分為矽基半導體電池(下稱矽晶電池)、碲化鎘(CdTe)薄膜電池、銅銦鎵硒(CIGS)薄膜電池、染料敏化薄膜電池以及有機材料電池。然而,就矽晶電池而言,矽晶電池雖可吸收以利用介於約300 nm至約1,200 nm之範圍內的光,但在後段製成模組的過程中,至少因多片及大面積組裝等因素而將導致電量損失,從而影響太陽能電池的光電轉換效率。Currently, commonly used solar cells can be broadly classified according to their manufacturing materials into silicon-based semiconductor cells (hereinafter referred to as silicon cells), cadmium telluride (CdTe) thin-film cells, copper indium gallium selenide (CIGS) thin-film cells, dye-sensitized thin-film cells, and organic material cells. However, regarding silicon cells, although they can absorb and utilize light in the range of approximately 300 nm to approximately 1,200 nm, power loss will occur during the later-stage module fabrication process due to factors such as multi-chip and large-area assembly, thereby affecting the photoelectric conversion efficiency of the solar cell.

因此,在實際運作上,光電轉換單元僅由矽晶電池組成之太陽能電池模組的光電轉換效率將低於矽晶電池本身的光電轉換效率。基此,如何改善包含矽晶電池之太陽能電池模組的光電轉換效率,即為所屬技術領域中仍待解決的技術問題之一。Therefore, in practical operation, the photoelectric conversion efficiency of a solar cell module whose photoelectric conversion unit consists solely of silicon cells will be lower than that of the silicon cells themselves. Accordingly, how to improve the photoelectric conversion efficiency of solar cell modules containing silicon cells is one of the remaining technical problems to be solved in this field.

有鑑於此,一些實施例提出一種太陽能電池疊層模組,其包含第一基板、第一封裝膠層、矽晶電池組、第二封裝膠層、鈣鈦礦(perovskite)電池組以及第二基板。上述第一封裝膠層位於第一基板上。上述矽晶電池位於第一封裝膠層上,且上述矽晶電池組包含複數矽晶電池單元,上述矽晶電池單元彼此電性連接且分別沿第一方向及第二方向配置。上述第二封裝膠層位於矽晶電池組上。上述鈣鈦礦電池組位於第二封裝膠層上且未直接接觸矽晶電池組。上述鈣鈦礦電池組包含複數鈣鈦礦電池單元,上述複數鈣鈦礦電池單元彼此電性連接且分別沿第一方向及第二方向配置。上述第二基板位於鈣鈦礦電池組上。In view of this, some embodiments propose a solar cell stack module comprising a first substrate, a first encapsulating layer, a silicon crystal battery pack, a second encapsulating layer, a perovskite battery pack, and a second substrate. The first encapsulating layer is located on the first substrate. The silicon crystal batteries are located on the first encapsulating layer, and the silicon crystal battery pack comprises a plurality of silicon crystal battery cells electrically connected to each other and arranged along a first direction and a second direction, respectively. The second encapsulating layer is located on the silicon crystal battery pack. The perovskite battery pack is located on the second encapsulating layer and does not directly contact the silicon crystal battery pack. The aforementioned perovskite battery pack includes a plurality of perovskite battery cells, which are electrically connected to each other and arranged along a first direction and a second direction, respectively. The aforementioned second substrate is located on the perovskite battery pack.

在一些實施例中,上述鈣鈦礦電池組的總輸出電壓等於上述矽晶電池組的總輸出電壓。In some embodiments, the total output voltage of the aforementioned perovskite battery pack is equal to the total output voltage of the aforementioned silicon battery pack.

在一些實施例中,上述矽晶電池組電性並聯於上述鈣鈦礦電池組。In some embodiments, the silicon battery pack is electrically connected in parallel with the perovskite battery pack.

在一些實施例中,上述複數鈣鈦礦電池單元彼此電性連接而形成複數鈣鈦礦電池串,各鈣鈦礦電池串沿第一方向延伸,且鈣鈦礦電池串沿第二方向相間隔。In some embodiments, the aforementioned plurality of perovskite battery cells are electrically connected to each other to form a plurality of perovskite battery strings, each perovskite battery string extending along a first direction and the perovskite battery strings being spaced apart along a second direction.

在一些實施例中,各鈣鈦礦電池包含第一部分與第二部分,上述第一部分鈣鈦礦電池單元的數量等於上述第二部分的鈣鈦礦電池單元的數量。In some embodiments, each calcite battery comprises a first part and a second part, wherein the number of calcite battery cells in the first part is equal to the number of calcite battery cells in the second part.

在一些實施例中,上述第一部分電性並聯於第二部分。In some embodiments, the first part is electrically connected in parallel with the second part.

在一些實施例中,沿上述第二方向相鄰的鈣鈦礦電池串彼此電性並聯。In some embodiments, adjacent perovskite battery strings along the second direction are electrically connected in parallel.

在一些實施例中,上述第二基板為透明基板。In some embodiments, the second substrate is a transparent substrate.

在一些實施例中,上述第一封裝膠層及第二封裝膠層中之至少一者包含選自由乙酸-醋酸乙烯酯共聚物(ethylene vinyl acetate, EVA)及聚烯烴彈性體(polyolefin Elastomer, POE)所組成的群組中之至少一者。In some embodiments, at least one of the first and second encapsulation layers comprises at least one selected from the group consisting of ethylene vinyl acetate (EVA) and polyolefin elastomer (POE).

在一些實施例中,上述太陽能電池疊層模組更包含波長調整層,上述波長調整層位於第二基板與鈣鈦礦電池組之間。In some embodiments, the aforementioned solar cell stack module further includes a wavelength adjustment layer located between the second substrate and the perovskite battery pack.

在一些實施例中,上述波長調整層適於接收一光線,並調整光線中之波長係小於或等於420 nm的光線為波長係大於420 nm的光線,以輸出光線。In some embodiments, the wavelength adjustment layer is adapted to receive a light and adjust the light whose wavelength is less than or equal to 420 nm to a light whose wavelength is greater than 420 nm, so as to output the light.

在一些實施例中,上述波長調整層適於接收一光線,並調整光線中之波長係介於280 nm至420 nm之範圍間的光線為波長係大於420 nm的光線,以輸出光線。In some embodiments, the wavelength adjustment layer is adapted to receive a light and adjust the light whose wavelength is in the range of 280 nm to 420 nm to be a light with a wavelength greater than 420 nm, so as to output the light.

在一些實施例中,上述鈣鈦礦電池組適於吸收波長係小於或等於700 nm的光線,上述矽晶電池組適於吸收波長係大於或等於700 nm的光線。In some embodiments, the aforementioned perovskite battery pack is adapted to absorb light with a wavelength less than or equal to 700 nm, and the aforementioned silicon battery pack is adapted to absorb light with a wavelength greater than or equal to 700 nm.

在一些實施例中,上述鈣鈦礦電池組適於吸收波長係介於280 nm至700 nm之範圍間的光線,上述矽晶電池組適於吸收波長係介於700 nm至1,200 nm之範圍間的光線。In some embodiments, the aforementioned perovskite battery pack is adapted to absorb light with wavelengths in the range of 280 nm to 700 nm, and the aforementioned silicon battery pack is adapted to absorb light with wavelengths in the range of 700 nm to 1,200 nm.

以下在實施方式中詳細敘述本創作之詳細特徵及優點,其內容足以使任何熟習相關技藝者瞭解本創作之技術內容並據以實施,且根據本說明書所揭露之內容、申請專利範圍及圖式,任何熟習相關技藝者可輕易地理解本創作相關之目的及優點。The following detailed description of the features and advantages of this invention is sufficient to enable anyone skilled in the relevant art to understand the technical content of this invention and implement it accordingly. Furthermore, based on the content disclosed in this specification, the scope of the patent application, and the drawings, anyone skilled in the relevant art can easily understand the purpose and advantages of this invention.

用語「約」可在不同的技術中且在所屬技術領域中具有通常知識者所理解的偏差範圍中有所變化。用語「約」與特定距離或尺寸相結合可被解釋為不排除與指定距離或尺寸的微小偏差。The term "approximately" can vary across different technologies and within the range of deviations understood by a person of ordinary skill in the relevant technical field. When used in conjunction with a specific distance or size, "approximately" can be interpreted as not excluding minor deviations from the specified distance or size.

用語「…至…的範圍間」是指包含此範圍之上限數值、下限數值以及此二上、下限數值之間的任意數值。例如,用語「280 nm至700 nm之範圍間」是指可為≥280 nm且≤700 nm之任意數值。The term "between ... and ..." refers to the upper limit value, the lower limit value, and any value between these two upper and lower limits. For example, the term "between 280 nm and 700 nm" refers to any value that can be ≥280 nm and ≤700 nm.

請參考圖1A及圖1B,圖1A係根據第一實施例之太陽能電池疊層模組1之俯視結構示意圖;圖1B係如圖1A所示的太陽能電池疊層模組1沿剖面線A-A之剖面結構示意圖。在圖1A及圖1B,一種太陽能電池疊層模組1包含第一基板10、第一封裝膠層11、矽晶電池組12、第二封裝膠層13、鈣鈦礦電池組14及第二基板16。上述第一封裝膠層11位於第一基板10上。上述矽晶電池組12位於第一封裝膠層11上,矽晶電池組12包含複數矽晶電池單元120,矽晶電池單元120彼此電性連接且分別沿第一方向(例如圖1A及圖1B所示的X方向)及第二方向(例如圖1A及圖1B所示的Y方向)配置;上述第一方向與第二方向為彼此不同的方向,例如第一方向及第二方向為彼此正交。上述第二封裝膠層13位於矽晶電池組12上。上述鈣鈦礦電池組14位於第二封裝膠層13上且未直接接觸矽晶電池組12。上述鈣鈦礦電池組14包含複數鈣鈦礦電池單元140,鈣鈦礦電池單元140彼此電性連接且分別沿上述第一方向(例如圖1A及圖1B所示的X方向)及上述第二方向(例如圖1A及圖1B所示的Y方向)配置。上述第二基板16位於鈣鈦礦電池組14上。基此,在一些實施例中,太陽能電池疊層模組1至少包含鈣鈦礦電池組14及矽晶電池組12,且在光線L(例如太陽光)自太陽能電池疊層模組1之上方、經由第二基板16進入到太陽能電池疊層模組1內部後,將先經過鈣鈦礦電池組14,而後再經過矽晶電池組12。於此過程中,鈣鈦礦電池組14可先吸收一部分的光線L(例如波長相對較短的光線L)以進行光電轉換,矽晶電池組12再吸收另一部分的光線L(例如波長相對較長的光線L)以進行光電轉換;因此,太陽能電池疊層模組1整體可更充分地利用及吸收具有各種波長區間的光線L,進而提供更優異的總光電轉換效率。Please refer to Figures 1A and 1B. Figure 1A is a top view of the solar cell stacked module 1 according to the first embodiment; Figure 1B is a cross-sectional view of the solar cell stacked module 1 shown in Figure 1A along section line A-A. In Figures 1A and 1B, a solar cell stacked module 1 includes a first substrate 10, a first encapsulating layer 11, a silicon crystal battery pack 12, a second encapsulating layer 13, a perovskite battery pack 14, and a second substrate 16. The first encapsulating layer 11 is located on the first substrate 10. The aforementioned silicon crystal battery pack 12 is located on the first encapsulation layer 11. The silicon crystal battery pack 12 includes a plurality of silicon crystal battery cells 120, which are electrically connected to each other and arranged along a first direction (e.g., the X direction shown in Figures 1A and 1B) and a second direction (e.g., the Y direction shown in Figures 1A and 1B), respectively. The first direction and the second direction are different from each other, for example, the first direction and the second direction are orthogonal to each other. The aforementioned second encapsulation layer 13 is located on the silicon crystal battery pack 12. The aforementioned perovskite battery pack 14 is located on the second encapsulation layer 13 and does not directly contact the silicon crystal battery pack 12. The aforementioned perovskite battery pack 14 includes a plurality of perovskite battery cells 140, which are electrically connected to each other and arranged along the first direction (e.g., the X direction shown in FIG. 1A and FIG. 1B) and the second direction (e.g., the Y direction shown in FIG. 1A and FIG. 1B), respectively. The aforementioned second substrate 16 is located on the perovskite battery pack 14. Accordingly, in some embodiments, the solar cell stack module 1 includes at least a perovskite battery pack 14 and a silicon battery pack 12. After the light L (e.g., sunlight) enters the interior of the solar cell stack module 1 from above the solar cell stack module 1 via the second substrate 16, it will first pass through the perovskite battery pack 14 and then through the silicon battery pack 12. In this process, the permafrost battery pack 14 can first absorb a portion of the light L (e.g., light L with a relatively short wavelength) for photoelectric conversion, and the silicon battery pack 12 then absorbs another portion of the light L (e.g., light L with a relatively long wavelength) for photoelectric conversion. Therefore, the solar cell stack module 1 as a whole can make fuller use of and absorb light L with various wavelength ranges, thereby providing a better overall photoelectric conversion efficiency.

舉例而言,以長及寬分別為2 m及1 m的太陽能電池模組(其設置有120片的矽晶電池單元120)及太陽能電池疊層模組1(其至少設置有120片的鈣鈦礦電池單元140)為例,相較於光電轉換單元僅包含矽晶電池組12之太陽能電池模組的光電轉換效率(約23.1%;發電量為約500 W),光電轉換單元至少包含矽晶電池組12及鈣鈦礦電池組14之太陽能電池疊層模組1的光電轉換效率為約27.0%(發電量為約590 W),提升約3.9%(=27.0%-23.1%)。由此可見,光電轉換單元至少包含矽晶電池組12及鈣鈦礦電池組14之太陽能電池疊層模組1,確實能夠具有更優異的總光電轉換效率。For example, taking a solar cell module (containing 120 silicon crystal cell units 120) with a length and width of 2 m and 1 m respectively, and a solar cell stacked module 1 (containing at least 120 perovskite cell units 140) as examples, compared to the photoelectric conversion efficiency of a solar cell module whose photoelectric conversion unit only includes silicon crystal cell array 12 (approximately 23.1%; power generation of approximately 500 W), the photoelectric conversion efficiency of the solar cell stacked module 1, whose photoelectric conversion unit at least includes silicon crystal cell array 12 and perovskite cell array 14, is approximately 27.0% (power generation of approximately 590 W). W), an increase of approximately 3.9% (=27.0%-23.1%). It can be seen that the solar cell stacked module 1, which includes at least silicon cell array 12 and perovskite cell array 14, can indeed have a better overall photoelectric conversion efficiency.

此外,上述太陽能電池疊層模組1的發電量(即約590 W)係將由矽晶電池組12所貢獻的發電量(約240 W,佔約40.7%(=240 W/590 W))及由鈣鈦礦電池組14所貢獻的發電量(約350 W,佔約59.3%(=350 W/590 W))加總而得。換言之,對應於鈣鈦礦電池組14所能夠吸收的光線L(其發電量為約350 W),光電轉換單元僅包含矽晶電池組12之太陽能電池模組的發電量則僅為260 W(=500 W-240 W),明顯減少90 W(=350 W-260 W)。基此,在一些實施例中,太陽能電池疊層模組1整體確實可更充分地利用及吸收具有各種波長區間的光線L,進而能夠基於相同的入射光量而提供更加提升的發電量(例如由260 W提升為350 W,提升約90 W,提升率為約34.6%(=(350-260)/260))。Furthermore, the power output of the aforementioned solar cell stack module 1 (approximately 590 W) is obtained by summing the power output contributed by the silicon cell stack 12 (approximately 240 W, accounting for approximately 40.7% (=240 W/590 W)) and the power output contributed by the perovskite cell stack 14 (approximately 350 W, accounting for approximately 59.3% (=350 W/590 W)). In other words, corresponding to the light L that the permafrost battery pack 14 can absorb (its power generation is approximately 350 W), the power generation of the solar cell module whose photoelectric conversion unit only includes the silicon battery pack 12 is only 260 W (=500 W-240 W), a significant reduction of 90 W (=350 W-260 W). Based on this, in some embodiments, the solar cell stack module 1 as a whole can indeed more fully utilize and absorb light L with various wavelength ranges, thereby providing a greater power generation based on the same incident light amount (for example, from 260 W to 350 W, an increase of approximately 90 W, an improvement rate of approximately 34.6% (=(350-260)/260)).

上述第一基板10(如圖1B所示)可為任何具有固定及承載功能的元件,以作為太陽能電池疊層模組1之背板。上述第一基板10可為透明基板或非透明基板,例如可為但不限於玻璃、單面氟膜複合背板、雙面氟膜複合背板或無氟背板。The first substrate 10 (as shown in FIG. 1B) can be any component with fixing and load-bearing functions to serve as the backplane of the solar cell stack module 1. The first substrate 10 can be a transparent substrate or a non-transparent substrate, such as, but not limited to, glass, a single-sided fluorine film composite backplane, a double-sided fluorine film composite backplane, or a fluorine-free backplane.

上述第一封裝膠層11(如圖1B所示)可為任何具有黏合及封裝功能的元件,以至少保護矽晶電池組12之底部。上述第一封裝膠層11例如包含選自由乙酸-醋酸乙烯酯共聚物(ethylene vinyl acetate, EVA)及聚烯烴彈性體(polyolefin Elastomer, POE)所組成的群組中之至少一者。亦即,上述第一封裝膠層11例如包含乙酸-醋酸乙烯酯共聚物(EVA)、或包含聚烯烴彈性體(POE)、或包含乙酸-醋酸乙烯酯共聚物(EVA)及聚烯烴彈性體(POE)。The first encapsulating layer 11 (as shown in FIG. 1B) can be any component with adhesive and encapsulation functions to at least protect the bottom of the silicon crystal battery pack 12. The first encapsulating layer 11 may, for example, comprise at least one of the group consisting of ethylene vinyl acetate (EVA) and polyolefin elastomer (POE). That is, the first encapsulating layer 11 may, for example, comprise ethylene vinyl acetate (EVA), or comprise polyolefin elastomer (POE), or comprise both ethylene vinyl acetate (EVA) and polyolefin elastomer (POE).

上述矽晶電池組12(如圖1B所示)可包含複數矽晶電池單元120,各矽晶電池單元120可獨立地為單晶矽太陽能電池或多晶矽太陽能電池。矽晶電池單元120彼此電性連接而形成複數矽晶電池串A1’、A2’、A3’(如圖1B所示)。各矽晶電池串A1’、A2’、A3’可沿第一方向(例如圖1B所示的X方向)延伸,且矽晶電池串A1’、A2’、A3’可沿第二方向(例如圖1B所示的Y方向)相間隔。The aforementioned silicon cell array 12 (as shown in Figure 1B) may include a plurality of silicon cell units 120, each of which may be an independent monocrystalline silicon solar cell or a polycrystalline silicon solar cell. The silicon cell units 120 are electrically connected to each other to form a plurality of silicon cell strings A1’, A2’, A3’ (as shown in Figure 1B). Each silicon cell string A1’, A2’, A3’ may extend along a first direction (e.g., the X direction shown in Figure 1B), and the silicon cell strings A1’, A2’, A3’ may be spaced apart along a second direction (e.g., the Y direction shown in Figure 1B).

在一些實施例中,各矽晶電池串A1’、A2’、A3’(如圖1B所示)包含第一部分(未另標示)與第二部分(未另標示)。在一些實施例中,該第一部分的矽晶電池單元120彼此電性串聯,該第二部分的矽晶電池單元120彼此電性串聯,且該第一部分電性並聯於該第二部分。在一些實施例中,矽晶電池串A1’、A2’、A3’之第一部分的矽晶電池單元120的數量等於矽晶電池串A1’、A2’、A3’之第二部分的矽晶電池單元120的數量。基此,該第一部分與第二部分的矽晶電池單元120可分別用以光電轉換,從而分別提供對應的電能。因此,在一些實施例中,若任一部分的矽晶電池單元120無法運作時,電性並聯的另一部分的矽晶電池單元120仍可正常地進行光電轉換,而不致造成矽晶電池組12整體均無法進行光電轉換。In some embodiments, each silicon cell string A1’, A2’, A3’ (as shown in Figure 1B) comprises a first part (not otherwise labeled) and a second part (not otherwise labeled). In some embodiments, the silicon cell units 120 of the first part are electrically connected in series with each other, the silicon cell units 120 of the second part are electrically connected in series with each other, and the first part is electrically connected in parallel to the second part. In some embodiments, the number of silicon cell units 120 in the first part of silicon cell strings A1’, A2’, A3’ is equal to the number of silicon cell units 120 in the second part of silicon cell strings A1’, A2’, A3’. Accordingly, the silicon cell units 120 in the first part and the second part can be used for photoelectric conversion, thereby providing corresponding electrical energy. Therefore, in some embodiments, if any part of the silicon cell unit 120 fails to operate, the other part of the silicon cell unit 120 connected in parallel can still perform photoelectric conversion normally, so that the entire silicon cell group 12 will not be able to perform photoelectric conversion.

上述第二封裝膠層13(如圖1B所示)可為任何具有黏合及封裝功能的元件,以至少保護矽晶電池組12之頂部及鈣鈦礦電池組14之底部,從而避免矽晶電池組12與鈣鈦礦電池組14之間彼此直接接觸(例如避免二者之間彼此直接電性連接)。基此,若存在需使矽晶電池組12與鈣鈦礦電池組14之間彼此電性連接的需求,在一些實施例中,矽晶電池組12與鈣鈦礦電池組14之間係透過間接接觸的方式(例如透過各種導電元件)加以電性連接。上述第二封裝膠層13例如包含乙酸-醋酸乙烯酯共聚物(EVA)、或包含聚烯烴彈性體(POE)、或包含乙酸-醋酸乙烯酯共聚物(EVA)及聚烯烴彈性體(POE),且上述第二封裝膠層13與第一封裝膠層11可為彼此相同或不同的材料,並未限制。The second encapsulating layer 13 (as shown in Figure 1B) can be any component with adhesive and encapsulation functions to at least protect the top of the silicon crystal battery pack 12 and the bottom of the perovskite battery pack 14, thereby preventing direct contact between the silicon crystal battery pack 12 and the perovskite battery pack 14 (e.g., preventing direct electrical connection between them). Accordingly, if there is a need to electrically connect the silicon crystal battery pack 12 and the perovskite battery pack 14, in some embodiments, the silicon crystal battery pack 12 and the perovskite battery pack 14 are electrically connected through indirect contact (e.g., through various conductive elements). The second encapsulation layer 13 may contain, for example, vinyl acetate copolymer (EVA), or polyolefin elastomer (POE), or a mixture of vinyl acetate copolymer (EVA) and polyolefin elastomer (POE). The second encapsulation layer 13 and the first encapsulation layer 11 may be made of the same or different materials, and there is no limitation.

上述鈣鈦礦電池組14(如圖1B所示)可包含複數鈣鈦礦電池單元140。鈣鈦礦電池單元140彼此電性連接(例如電性並聯),且例如可沿第一方向(例如圖1B所示的X方向)延伸而形成複數鈣鈦礦電池串A1、A2、A3(如圖1B所示)。鈣鈦礦電池串A1、A2、A3可沿第二方向(例如圖1B所示的Y方向)相間隔。相鄰的二鈣鈦礦電池串A1、A2、A3彼此電性並聯。鈣鈦礦電池串A1、A2、A3可對應矽晶電池串A1’、A2’、A3’設置(例如以堆疊方式及電性匹配區分的四端點式(4T)太陽能電池疊層模組)。在一些實施例中,各鈣鈦礦電池串A1、A2、A3可同時對應矽晶電池串A1’、A2’、A3’以沿第一方向(例如圖1B所示的X方向)延伸,且鈣鈦礦電池串A1、A2、A3亦可同時對應矽晶電池串A1’、A2’、A3’以沿第二方向(例如圖1B所示的Y方向)相間隔。上述用語「對應」是指鈣鈦礦電池串A1、A2、A3之配置位置可分別依照矽晶電池串A1’、A2’、A3’之配置位置進行配置;例如,鈣鈦礦電池串A1於一投影面(例如圖1B所示的XY平面)上係重疊於矽晶電池串A1’,鈣鈦礦電池串A2於該投影面(例如圖1B所示的XY平面)上係重疊於矽晶電池串A2’,依此類推。在一些實施例中,鈣鈦礦電池串A1、A2、A3係未對應矽晶電池串A1’、A2’、A3’設置(例如以堆疊方式及電性匹配區分的二端點式(2T)太陽能電池疊層模組);亦即,鈣鈦礦電池串A1、A2、A3之配置位置於該投影面上,並未分別重疊於矽晶電池串A1’、A2’、A3’。The aforementioned perovskite battery pack 14 (as shown in FIG. 1B) may include a plurality of perovskite battery cells 140. The perovskite battery cells 140 are electrically connected to each other (e.g., electrically in parallel), and may extend, for example, along a first direction (e.g., the X direction shown in FIG. 1B) to form a plurality of perovskite battery strings A1, A2, A3 (as shown in FIG. 1B). The perovskite battery strings A1, A2, A3 may be spaced apart along a second direction (e.g., the Y direction shown in FIG. 1B). Adjacent perovskite battery strings A1, A2, A3 are electrically connected in parallel. The perovskite battery strings A1, A2, and A3 can correspond to the silicon battery strings A1’, A2’, and A3’ (e.g., a four-terminal (4T) solar cell stack module distinguished by stacking and electrical matching). In some embodiments, each perovskite battery string A1, A2, and A3 can simultaneously correspond to the silicon battery strings A1’, A2’, and A3’ extending along a first direction (e.g., the X direction shown in FIG. 1B), and the perovskite battery strings A1, A2, and A3 can also simultaneously correspond to the silicon battery strings A1’, A2’, and A3’ spaced apart along a second direction (e.g., the Y direction shown in FIG. 1B). The term "corresponding" as used above means that the configuration positions of the perovskite battery strings A1, A2, and A3 can be configured according to the configuration positions of the silicon battery strings A1', A2', and A3', respectively. For example, perovskite battery string A1 overlaps silicon battery string A1' on a projection plane (e.g., the XY plane shown in Figure 1B), perovskite battery string A2 overlaps silicon battery string A2' on the same projection plane (e.g., the XY plane shown in Figure 1B), and so on. In some embodiments, the perovskite battery strings A1, A2, and A3 are not configured to correspond to the silicon battery strings A1’, A2’, and A3’ (e.g., in a two-terminal (2T) solar cell stack module distinguished by stacking method and electrical matching); that is, the perovskite battery strings A1, A2, and A3 are positioned on the projection plane and do not overlap with the silicon battery strings A1’, A2’, and A3’ respectively.

在一些實施例中,上述鈣鈦礦電池單元140沿第一方向(例如圖1B所示的X方向)延伸,且鈣鈦礦電池單元140以一第一間距(未另標示)彼此相間隔,且該第一間距係透過雷射切割製得。在一些實施例中,上述鈣鈦礦電池串A1、A2、A3沿第二方向(例如圖1B所示的Y方向)以一第二間距(未另標示)彼此相間隔,且該第二間距係透過雷射切割製得。藉此,在一些實施例中,各鈣鈦礦電池單元140可依照不同規格及需求而快速製得,從而簡化製程時間及成本。In some embodiments, the aforementioned perovskite battery cells 140 extend along a first direction (e.g., the X direction shown in FIG. 1B) and are spaced apart by a first spacing (not otherwise indicated), which is formed by laser cutting. In some embodiments, the aforementioned perovskite battery strings A1, A2, A3 are spaced apart by a second spacing (not otherwise indicated) along a second direction (e.g., the Y direction shown in FIG. 1B), which is also formed by laser cutting. Therefore, in some embodiments, each perovskite battery cell 140 can be quickly manufactured according to different specifications and requirements, thereby simplifying manufacturing time and reducing costs.

請參考圖2,圖2係根據第二實施例之太陽能電池疊層模組1之俯視結構示意圖。在圖2,各鈣鈦礦電池串A1、A2、A3包含第一部分S1與第二部分S2,且第一部分S1的鈣鈦礦電池單元140的數量等於第二部分S2的鈣鈦礦電池單元140的數量。在一些實施例中,第一部分S1電性並聯於第二部分S2。基此,第一部分S1與第二部分S2的鈣鈦礦電池單元140均可分別用以光電轉換,從而分別提供對應的電能。因此,在一些實施例中,若任一部分的鈣鈦礦電池單元140無法運作時,電性並聯的另一部分的鈣鈦礦電池單元140仍可正常地進行光電轉換,而不致造成鈣鈦礦電池組14整體均無法進行光電轉換。Please refer to Figure 2, which is a top view of the solar cell stacked module 1 according to the second embodiment. In Figure 2, each perovskite battery string A1, A2, A3 includes a first part S1 and a second part S2, and the number of perovskite battery cells 140 in the first part S1 is equal to the number of perovskite battery cells 140 in the second part S2. In some embodiments, the first part S1 is electrically connected in parallel with the second part S2. Accordingly, the perovskite battery cells 140 in both the first part S1 and the second part S2 can be used for photoelectric conversion, thereby providing corresponding electrical energy. Therefore, in some embodiments, if any part of the calcite battery cell 140 fails to operate, the other part of the calcite battery cell 140 connected in parallel can still perform photoelectric conversion normally, so that the entire calcite battery pack 14 will not be able to perform photoelectric conversion.

在一些實施例中,上述鈣鈦礦電池組14(如圖1A及圖1B所示)的總輸出電壓係經配置以等於矽晶電池組12的總輸出電壓。舉例而言,因應各鈣鈦礦電池單元140本身的輸出電壓及各矽晶電池單元120本身的輸出電壓,鈣鈦礦電池單元140及矽晶電池單元120之配置數量可被分別調整,以使鈣鈦礦電池組14的總輸出電壓等於矽晶電池組12的總輸出電壓(例如若以堆疊方式及電性匹配區分的四端點式(4T)之太陽能電池疊層模組)。In some embodiments, the total output voltage of the aforementioned perovskite battery pack 14 (as shown in Figures 1A and 1B) is configured to be equal to the total output voltage of the silicon battery pack 12. For example, the number of perovskite battery cells 140 and silicon battery cells 120 can be adjusted according to the output voltage of each perovskite battery cell 140 and the output voltage of each silicon battery cell 120, so that the total output voltage of the perovskite battery pack 14 is equal to the total output voltage of the silicon battery pack 12 (e.g., in a four-terminal (4T) solar cell stack module distinguished by stacking and electrical matching).

在一些實施例中,由於鈣鈦礦電池組14(如圖1A及圖1B所示)的總輸出電壓係經配置以等於矽晶電池組12的總輸出電壓,而不致在二電池組(即矽晶電池組12及鈣鈦礦電池組14)之間形成電壓差;因此,上述矽晶電池組12可進一步電性並聯於鈣鈦礦電池組14,而不致造成二電池組(即矽晶電池組12及鈣鈦礦電池組14)之間彼此充電,從而影響光電轉換效率、甚至損壞太陽能電池疊層模組1。In some embodiments, since the total output voltage of the perovskite battery pack 14 (as shown in Figures 1A and 1B) is configured to be equal to the total output voltage of the silicon battery pack 12, a voltage difference is not formed between the two battery packs (i.e., silicon battery pack 12 and perovskite battery pack 14). Therefore, the silicon battery pack 12 can be further electrically connected in parallel with the perovskite battery pack 14, so as not to cause the two battery packs (i.e., silicon battery pack 12 and perovskite battery pack 14) to charge each other, thereby affecting the photoelectric conversion efficiency or even damaging the solar cell stack module 1.

在一些實施例中,上述鈣鈦礦電池組14適於吸收波長係小於或等於700 nm的光線(例如但不限於波長係介於280 nm至700 nm之範圍間的光線),上述矽晶電池組12適於吸收波長係大於或等於700 nm的光線(例如但不限於波長係介於700 nm至1,200 nm之範圍間的光線)。基此,在一些實施例中,在光線L(如圖1B所示)經由第二基板16進入到太陽能電池疊層模組1內部後,光線L中之波長係小於或等於700 nm的光線可先由鈣鈦礦電池組14吸收。而由於在上述波長區間(即小於或等於700 nm的波長),相較於由矽晶電池組12所進行的光電轉換之轉換效率(例如約12.0%(=23.1%*260 W/500 W);其發電量為約260 W),由鈣鈦礦電池組14所進行的光電轉換可具有相對較高之轉換效率(例如約13.7%(=23.1*350 W/590 W);其發電量約350 W,提升約34.6%(=(350 W-260 W)/260 W)),從而太陽能電池疊層模組1整體可更充分地利用及吸收具有各種波長區間的光線L,進而提供更優異的總光電轉換效率(例如由約23.1%提升為約27.0%,提升約3.9%(=27.0%-23.1%))。In some embodiments, the aforementioned perovskite battery pack 14 is adapted to absorb light with a wavelength less than or equal to 700 nm (e.g., but not limited to light with a wavelength between 280 nm and 700 nm), and the aforementioned silicon battery pack 12 is adapted to absorb light with a wavelength greater than or equal to 700 nm (e.g., but not limited to light with a wavelength between 700 nm and 1,200 nm). Accordingly, in some embodiments, after light L (as shown in FIG. 1B) enters the solar cell stack module 1 through the second substrate 16, light with a wavelength less than or equal to 700 nm in light L can first be absorbed by the perovskite battery pack 14. Because in the aforementioned wavelength range (i.e., wavelengths less than or equal to 700 nm), compared to the photoelectric conversion efficiency of the silicon cell array 12 (e.g., approximately 12.0% (=23.1%*260 W/500 W); its power generation is approximately 260 W), the photoelectric conversion efficiency of the perovskite cell array 14 can have a relatively higher conversion efficiency (e.g., approximately 13.7% (=23.1%*350 W/590 W); its power generation is approximately 350 W), representing an increase of approximately 34.6% (=(350 W-260 W)/260 W). W), thereby enabling the solar cell stacked module 1 to more fully utilize and absorb light L with various wavelength ranges, thereby providing a better total photoelectric conversion efficiency (e.g., from about 23.1% to about 27.0%, an increase of about 3.9% (=27.0%-23.1%)).

上述第二基板16(如圖1B所示)可為任何具有光線通過功能的元件,以作為太陽能電池疊層模組1之導光板。上述第二基板16可為透明基板,例如可為但不限於玻璃。The second substrate 16 (as shown in FIG. 1B) can be any element with light transmission function, serving as a light guide plate for the solar cell stack module 1. The second substrate 16 can be a transparent substrate, such as, but not limited to, glass.

請參考圖3A及圖3B,圖3A係根據第三實施例之太陽能電池疊層模組1之俯視結構示意圖;圖3B係如圖3A所示的太陽能電池疊層模組1沿剖面線B-B之剖面結構示意圖。在圖3A及圖3B,一些實施例之太陽能電池疊層模組1更包含波長調整層15,上述波長調整層15位於第二基板16與鈣鈦礦電池組14之間。上述波長調整層15可為各種具有調整入射光線之其中一部分的波長以輸出波長經過調整的光線之功能的元件;例如,波長調整層15為各種具有紅移(redshift,即導致波長增加及頻率降低,並使光譜的譜線朝向紅端移動)功能的元件,以將波長較短之光線轉換為波長較長之光線。上述波長調整層15例如但不限於包含以下之至少一者:乙烯-醋酸乙烯酯共聚物(EVA)、發泡聚乙稀(expanded polyethylene, EPE)、聚氧乙烯(poly(oxyethylene), POE)及熱塑性聚烯烴(thermoplastic polyolefin, TPO)。在一些實施例中,上述波長調整層15還包含苯並三唑(benzotriazole)之衍生物,例如但不限於4,7-二苯基-2H-苯並三唑(4,7-diphenyl-2H-benzotriazole)、4,7-二苯基-2-甲基-苯並三唑(4,7-diphenyl-2-methyl-benzotriazole)或其他具有相類似之化學結構及物化特性的苯並三唑之衍生物。基此,在一些實施例中,透過波長調整層15,可因應鈣鈦礦電池組14之特性(例如因具有較高的光衰而僅有較短的使用壽命)而調整進入到鈣鈦礦電池組14的光線L之波長(例如將紫外光波段之光源轉換為長波段之可見光光源),從而保護鈣鈦礦電池組14,以延長鈣鈦礦電池組14的使用壽命。在一些實施例中,經由本案創作人研究證實,透過波長調整層15,鈣鈦礦電池組14(乃至於太陽能電池疊層模組1整體)之使用壽命可由約10年,進一步延長為約30年。Please refer to Figures 3A and 3B. Figure 3A is a top view of the solar cell stacked module 1 according to the third embodiment; Figure 3B is a cross-sectional view of the solar cell stacked module 1 shown in Figure 3A along section line B-B. In Figures 3A and 3B, some embodiments of the solar cell stacked module 1 further include a wavelength adjustment layer 15, which is located between the second substrate 16 and the perovskite battery pack 14. The wavelength adjustment layer 15 described above can be any element that has the function of adjusting the wavelength of a portion of the incident light to output wavelength-adjusted light; for example, the wavelength adjustment layer 15 can be any element that has a redshift function (i.e., causing an increase in wavelength and a decrease in frequency, and shifting the spectral lines towards the red end of the spectrum) to convert shorter wavelength light into longer wavelength light. The wavelength adjustment layer 15 described above includes, for example but not limited to, at least one of the following: ethylene-vinyl acetate copolymer (EVA), expanded polyethylene (EPE), poly(oxyethylene) (POE), and thermoplastic polyolefin (TPO). In some embodiments, the wavelength adjustment layer 15 may also contain a benzotriazole derivative, such as, but not limited to, 4,7-diphenyl-2H-benzotriazole, 4,7-diphenyl-2-methyl-benzotriazole, or other benzotriazole derivatives having similar chemical structures and physicochemical properties. Therefore, in some embodiments, the wavelength adjustment layer 15 can be used to adjust the wavelength of the light L entering the perovskite battery pack 14 according to its characteristics (e.g., a shorter lifespan due to higher light decay). This can be achieved by converting an ultraviolet light source into a longer-wavelength visible light source, thereby protecting the perovskite battery pack 14 and extending its lifespan. In some embodiments, research by the inventors has confirmed that the wavelength adjustment layer 15 can further extend the lifespan of the perovskite battery pack 14 (and even the entire solar cell stack module 1) from approximately 10 years to approximately 30 years.

在一些實施例中,上述波長調整層15適於接收光線L(如圖3B所示),並調整光線L中之波長係小於或等於420 nm的光線(例如但不限於波長係介於280 nm至420 nm之範圍間的光線)為波長係大於420 nm的光線,以輸出波長經過調整的光線L。In some embodiments, the wavelength adjustment layer 15 is adapted to receive light L (as shown in FIG. 3B) and adjust light in light L whose wavelength is less than or equal to 420 nm (e.g., but not limited to light whose wavelength is in the range of 280 nm to 420 nm) to light whose wavelength is greater than 420 nm, so as to output light L with adjusted wavelength.

請參考圖4及表1,圖4係習知的透光層與根據一些實施例所使用的波長調整層15,於不同透射光之波長下的透射率比較圖;表1則係整理如圖4所示的習知的透光層與根據一些實施例所使用的波長轉換層15,分別於透射率為約30%及80%所對應的透射光波長。Please refer to Figure 4 and Table 1. Figure 4 is a comparison of the transmittance of the conventional light-transmitting layer and the wavelength adjustment layer 15 used in some embodiments at different transmittance wavelengths. Table 1 summarizes the transmittance wavelengths corresponding to approximately 30% and 80% for the conventional light-transmitting layer and the wavelength conversion layer 15 used in some embodiments, as shown in Figure 4.

表1:如圖4所示的習知的透光層與根據一些實施例所使用的波長調整層15,分別於透射率為約30%及80%所對應的透射光波長。 透射光波長 (nm) 透射率約30% 透射率約80% 比較例 習知的透光層 253 305 實施例 1 波長調整層 384 398 實施例 2 波長調整層 429 441 Table 1: The transmitted light wavelengths corresponding to a transmittance of approximately 30% and 80%, respectively, for the conventional light-transmitting layer shown in Figure 4 and the wavelength adjustment layer 15 used according to some embodiments. Transmitted light wavelength (nm) Transmittance is approximately 30%. Transmittance is approximately 80%. Comparative example The known light-transmitting layer 253 305 Implementation Example 1 Wavelength adjustment layer 384 398 Implementation Example 2 Wavelength adjustment layer 429 441

由圖4及上表1可知,作為比較例,將光線通入習知的「透光層」(如圖4所示)後,透射率約30%所對應的透射光波長為約253 nm,透射率約80%所對應的透射光波長為約305 nm。As shown in Figure 4 and Table 1 above, as a comparative example, when light is passed through a conventional "transmitting layer" (as shown in Figure 4), the transmitted light wavelength corresponding to a transmittance of about 30% is about 253 nm, and the transmitted light wavelength corresponding to a transmittance of about 80% is about 305 nm.

由圖4及上表1可知,作為本創作之一些實施例(即實施例1),將相同光線通入「波長調整層」(即如圖4所示之波長調整層15)後,透射率約30%所對應的透射光波長為約384 nm(相較於比較例,提升約131 nm),透射率約80%所對應的透射光波長為約398 nm(相較於比較例,提升約93 nm),二者均由紫外光波段紅移至紫光波段。As can be seen from Figure 4 and Table 1 above, as some embodiments of this invention (i.e., embodiment 1), after passing the same light into the "wavelength adjustment layer" (i.e., the wavelength adjustment layer 15 as shown in Figure 4), the transmitted light wavelength corresponding to approximately 30% transmittance is approximately 384 nm (an increase of approximately 131 nm compared to the comparative example), and the transmitted light wavelength corresponding to approximately 80% transmittance is approximately 398 nm (an increase of approximately 93 nm compared to the comparative example). Both of them are redshifted from the ultraviolet band to the violet band.

由圖4及上表1可知,作為本創作之一些實施例(即實施例2),將相同光線通入「波長調整層」(即如圖4所示之波長調整層15)後,透射率約30%所對應的透射光波長為約429 nm(相較於比較例,提升約176 nm),透射率約80%所對應的透射光波長為約441 nm(相較於比較例,提升約136 nm),二者均由紫外光波段紅移至藍紫光波段。As can be seen from Figure 4 and Table 1 above, as some embodiments of this invention (i.e., embodiment 2), after passing the same light into the "wavelength adjustment layer" (i.e., the wavelength adjustment layer 15 as shown in Figure 4), the transmitted light wavelength corresponding to approximately 30% transmittance is approximately 429 nm (an increase of approximately 176 nm compared to the comparative example), and the transmitted light wavelength corresponding to approximately 80% transmittance is approximately 441 nm (an increase of approximately 136 nm compared to the comparative example). Both of them are red-shifted from the ultraviolet light band to the blue-violet light band.

基此,在一些實施例中,透過波長調整層15,可將紫外光調整為紫光或藍紫光(甚至是藍光),從而保護鈣鈦礦電池組14,以延長鈣鈦礦電池組14的使用壽命。Therefore, in some embodiments, the ultraviolet light can be adjusted to violet or blue-violet light (or even blue light) through the wavelength adjustment layer 15, thereby protecting the calcite battery pack 14 and extending its service life.

綜合以上,在一些實施例中,透過作為光電轉換單元之鈣鈦礦電池組及矽晶電池組疊層,光線在進入到太陽能電池疊層模組內部之後,會先經過鈣鈦礦電池組、才經過矽晶電池組,從而使得太陽能電池疊層模組整體可更充分地利用及吸收具有各種波長區間的光線,進而提供更優異的總光電轉換效率及發電量。此外,在一些實施例中,透過設置在鈣鈦礦電池組上方的波長調整層,光線在經過鈣鈦礦電池組之前,至少有一部分的光線之波長將先經過調整(例如紅移),從而可避免含有波長未經調整的光線(例如含有紫外光)進入到鈣鈦礦電池組,從而對鈣鈦礦電池組造成損害(例如光衰)。因此,在一些實施例中,透過設置在鈣鈦礦電池組上方的波長調整層,太陽能電池疊層模組還可具有使用壽命再更延長的鈣鈦礦電池組,從而提升太陽能電池疊層模組整體的使用壽命。In summary, in some embodiments, through the stacking of perovskite and silicon cell arrays as photoelectric conversion units, light entering the solar cell stack module first passes through the perovskite cell array and then through the silicon cell array. This allows the solar cell stack module as a whole to more fully utilize and absorb light with various wavelength ranges, thereby providing superior overall photoelectric conversion efficiency and power generation. Furthermore, in some embodiments, by using a wavelength adjustment layer disposed above the perovskite battery pack, at least a portion of the light wavelength is adjusted (e.g., redshifted) before passing through the perovskite battery pack. This prevents unadjusted light (e.g., ultraviolet light) from entering the perovskite battery pack and causing damage (e.g., light decay). Therefore, in some embodiments, through the wavelength adjustment layer disposed above the perovskite battery pack, the solar cell stack module can also have perovskite battery packs with an even longer service life, thereby improving the overall service life of the solar cell stack module.

雖然本創作以前述之實施例揭露如上,然其並非用以限定本創作,任何熟習相像技藝者,在不脫離本創作之精神和範圍內,當可作些許之更動與潤飾,因此本創作之專利保護範圍須視本說明書所附之申請專利範圍所界定者為準。Although the present invention is disclosed above with reference to the aforementioned embodiments, it is not intended to limit the present invention. Anyone skilled in similar techniques may make some modifications and refinements without departing from the spirit and scope of the present invention. Therefore, the scope of patent protection of the present invention shall be determined by the scope of the patent application attached to this specification.

1:太陽能電池疊層模組 10:第一基板 11:第一封裝膠層 12:矽晶電池組 120:矽晶電池單元 13:第二封裝膠層 14:鈣鈦礦電池組 140:鈣鈦礦電池單元 15:波長調整層 16:第二基板 A1,A2,A3:鈣鈦礦電池串 A1’,A2’,A3’:矽晶電池串 L:光線 S1:第一部分 S2:第二部分 X,Y,Z:座標軸 A-A,B-B:剖面線1: Solar cell stack module; 10: First substrate; 11: First encapsulation layer; 12: Silicon crystal battery pack; 120: Silicon crystal battery unit; 13: Second encapsulation layer; 14: Perovskite battery pack; 140: Perovskite battery unit; 15: Wavelength adjustment layer; 16: Second substrate; A1, A2, A3: Perovskite battery string; A1’, A2’, A3’: Silicon crystal battery string; L: Light ray; S1: First part; S2: Second part; X, Y, Z: Coordinate axes; A-A, B-B: Section lines.

在結合附隨圖式閱讀以下詳細描述時可最佳地理解本揭露。應當強調的是,根據業界中的標準慣例,各種特徵未按比例繪製且僅用於說明目的。實際上,為了論述清楚,各種特徵的尺寸可任意地增大或減小。 圖1A係根據第一實施例之太陽能電池疊層模組之俯視結構示意圖; 圖1B係如圖1A所示的太陽能電池疊層模組沿剖面線A-A之剖面結構示意圖; 圖2係根據第二實施例之太陽能電池疊層模組之俯視結構示意圖; 圖3A係根據第三實施例之太陽能電池疊層模組之俯視結構示意圖; 圖3B係如圖3A所示的太陽能電池疊層模組沿剖面線B-B之剖面結構示意圖;及 圖4係習知的透光層與根據一些實施例所使用的波長調整層,於不同透射光之波長下的透射率比較圖。This disclosure is best understood when read in conjunction with the accompanying diagrams in the following detailed description. It should be emphasized that, in accordance with industry standard practice, the features are not drawn to scale and are for illustrative purposes only. In fact, the dimensions of the features may be arbitrarily increased or decreased for clarity of explanation. Figure 1A is a top view schematic diagram of a solar cell stacked module according to a first embodiment; Figure 1B is a cross-sectional schematic diagram of the solar cell stacked module shown in Figure 1A along section line A-A; Figure 2 is a top view schematic diagram of a solar cell stacked module according to a second embodiment; Figure 3A is a top view schematic diagram of a solar cell stacked module according to a third embodiment; Figure 3B is a cross-sectional schematic diagram of the solar cell stacked module shown in Figure 3A along section line B-B; and Figure 4 is a comparison graph of the transmittance of a conventional light-transmitting layer and a wavelength adjustment layer used according to some embodiments at different wavelengths of transmitted light.

10:第一基板 10: First substrate

11:第一封裝膠層 11: First sealing layer

12:矽晶電池組 12: Silicon Crystal Battery Pack

120:矽晶電池單元 120: Silicon Crystal Battery Unit

13:第二封裝膠層 13: Second sealing layer

14:鈣鈦礦電池組 14: Calcium-Titanium Ore Battery Pack

140:鈣鈦礦電池單元 140: Calcium TiO2 Battery Unit

16:第二基板 16: Second substrate

A1,A2,A3:鈣鈦礦電池串 A1, A2, A3: Calcium-titanium ore battery string

A1’,A2’,A3’:矽晶電池串 A1’, A2’, A3’: Silicon crystal battery string

L:光線 L:Light

X,Y,Z:座標軸 X, Y, Z: coordinate axes

A-A:剖面線 A-A: Section lines

Claims (14)

一種太陽能電池疊層模組,包含: 一第一基板; 一第一封裝膠層,位於該第一基板上; 一矽晶電池組,位於該第一封裝膠層上,該矽晶電池組包含複數矽晶電池單元,該複數矽晶電池單元彼此電性連接且分別沿一第一方向及一第二方向配置; 一第二封裝膠層,位於該矽晶電池組上; 一鈣鈦礦電池組,位於該第二封裝膠層上且未直接接觸該矽晶電池組,該鈣鈦礦電池組包含複數鈣鈦礦電池單元,該複數鈣鈦礦電池單元彼此電性連接且分別沿該第一方向及該第二方向配置;及 一第二基板,位於該鈣鈦礦電池組上。A solar cell stack module includes: a first substrate; a first encapsulation layer disposed on the first substrate; a silicon cell assembly disposed on the first encapsulation layer, the silicon cell assembly including a plurality of silicon cell units electrically connected to each other and respectively disposed along a first direction and a second direction; and a second encapsulation layer disposed on the silicon cell assembly. A perovskite battery pack, located on the second encapsulation layer and not in direct contact with the silicon battery pack, the perovskite battery pack comprising a plurality of perovskite battery cells electrically connected to each other and respectively arranged along the first direction and the second direction; and a second substrate located on the perovskite battery pack. 如請求項1所述的太陽能電池疊層模組,其中,該鈣鈦礦電池組的總輸出電壓等於該矽晶電池組的總輸出電壓。The solar cell stack module as described in claim 1, wherein the total output voltage of the perovskite battery pack is equal to the total output voltage of the silicon battery pack. 如請求項2所述的太陽能電池疊層模組,其中,該矽晶電池組電性並聯於該鈣鈦礦電池組。The solar cell stack module as described in claim 2, wherein the silicon cell array is electrically connected in parallel to the perovskite cell array. 如請求項1所述的太陽能電池疊層模組,其中,該複數鈣鈦礦電池單元彼此電性連接而形成複數鈣鈦礦電池串,各該鈣鈦礦電池串沿該第一方向延伸,且該複數鈣鈦礦電池串沿該第二方向相間隔。The solar cell stack module as described in claim 1, wherein the plurality of perovskite cell units are electrically connected to each other to form a plurality of perovskite cell strings, each of the perovskite cell strings extends along the first direction, and the plurality of perovskite cell strings are spaced apart along the second direction. 如請求項4所述的太陽能電池疊層模組,其中,各該鈣鈦礦電池串包含一第一部分與一第二部分,該第一部分的該些鈣鈦礦電池單元的數量等於該第二部分的該些鈣鈦礦電池單元的數量。The solar cell stack module as described in claim 4, wherein each of the perovskite battery strings comprises a first portion and a second portion, wherein the number of perovskite battery cells in the first portion is equal to the number of perovskite battery cells in the second portion. 如請求項5所述的太陽能電池疊層模組,其中,該第一部分電性並聯於該第二部分。The solar cell stacked module as described in claim 5, wherein the first part is electrically connected in parallel to the second part. 如請求項5或6所述的太陽能電池疊層模組,其中,沿該第二方向相鄰的二該鈣鈦礦電池串彼此電性並聯。The solar cell stack module as described in claim 5 or 6, wherein two adjacent perovskite cell strings along the second direction are electrically connected in parallel with each other. 如請求項1所述的太陽能電池疊層模組,其中,該第二基板為透明基板。The solar cell stack module as described in claim 1, wherein the second substrate is a transparent substrate. 如請求項1所述的太陽能電池疊層模組,其中,該第一封裝膠層及該第二封裝膠層中之至少一者包含選自由乙酸-醋酸乙烯酯共聚物(ethylene vinyl acetate, EVA)及聚烯烴彈性體(polyolefin elastomer, POE)所組成的群組中之至少一者。The solar cell stack module as claimed in claim 1, wherein at least one of the first encapsulation layer and the second encapsulation layer comprises at least one selected from the group consisting of ethylene vinyl acetate (EVA) and polyolefin elastomer (POE). 如請求項1所述的太陽能電池疊層模組,更包含一波長調整層,位於該第二基板與該鈣鈦礦電池組之間。The solar cell stack module as described in claim 1 further includes a wavelength adjustment layer located between the second substrate and the perovskite battery pack. 如請求項10所述的太陽能電池疊層模組,其中,該波長調整層適於接收一光線,並調整該光線中之波長係小於或等於420 nm的光線為波長係大於420 nm的光線,以輸出該光線。The solar cell stack module as described in claim 10, wherein the wavelength adjustment layer is adapted to receive a light and adjust light with a wavelength less than or equal to 420 nm to light with a wavelength greater than 420 nm, so as to output the light. 如請求項10所述的太陽能電池疊層模組,其中,該波長調整層適於接收一光線,並調整該光線中之波長係介於280 nm至420 nm之範圍間的光線為波長係大於420 nm的光線,以輸出該光線。The solar cell stack module as described in claim 10, wherein the wavelength adjustment layer is adapted to receive a light and adjust the light whose wavelength is in the range of 280 nm to 420 nm to a light with a wavelength greater than 420 nm, so as to output the light. 如請求項1所述的太陽能電池疊層模組,其中,該鈣鈦礦電池組適於吸收波長係小於或等於700 nm的光線,該矽晶電池組適於吸收波長係大於或等於700 nm的光線。The solar cell stack module as claimed in claim 1, wherein the perovskite cell array is adapted to absorb light with a wavelength less than or equal to 700 nm, and the silicon cell array is adapted to absorb light with a wavelength greater than or equal to 700 nm. 如請求項1所述的太陽能電池疊層模組,其中,該鈣鈦礦電池組適於吸收波長係介於280 nm至700 nm之範圍間的光線,該矽晶電池組適於吸收波長係介於700 nm至1,200 nm之範圍間的光線。The solar cell stack module as claimed in claim 1, wherein the perovskite cell array is adapted to absorb light with wavelengths in the range of 280 nm to 700 nm, and the silicon cell array is adapted to absorb light with wavelengths in the range of 700 nm to 1,200 nm.
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