TWM495297U - Functional multilayer thin film - Google Patents

Functional multilayer thin film Download PDF

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Publication number
TWM495297U
TWM495297U TW103212348U TW103212348U TWM495297U TW M495297 U TWM495297 U TW M495297U TW 103212348 U TW103212348 U TW 103212348U TW 103212348 U TW103212348 U TW 103212348U TW M495297 U TWM495297 U TW M495297U
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layer
film
functional
nano ceramic
multilayer film
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TW103212348U
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Chinese (zh)
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yi-yang Liu
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yi-yang Liu
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Description

機能型多層薄膜Functional multilayer film

本創作係有關一種可透光的薄膜製品,特別是一種具有防霧、隔熱及抗紫外線功能的機能型多層薄膜。The present invention relates to a light transmissive film product, in particular to a functional multilayer film having anti-fog, heat insulation and UV resistance functions.

已知存在有許多產品或用品在可見光範圍內必需具備可透光性,例如:車窗玻璃、汽車後視鏡、建築玻璃窗/門使用的玻璃、安全帽的護目鏡片、玻璃展示櫃或是冷藏櫃的玻璃門。上述的產品或用品依據其用途及使用的環境,除了需要具備透光性之外,通常還需要具備其他的功能或機能,例如防霧和隔熱的機能。It is known that there are many products or articles that must be permeable in the visible range, such as: window glass, automotive rearview mirrors, glass for architectural glazing/doors, safety glasses for safety helmets, glass display cabinets or It is the glass door of the refrigerator. In addition to the need for light transmission, the above-mentioned products or products generally require other functions or functions, such as anti-fog and heat insulation functions, depending on the use and environment in which they are used.

在具有温差的大氣環境中,含有水份的空氣很容易因為溫差的現象而在上述的產品或用品的表面凝結成水滴進而造成起霧現象,在上述產品或用品的表面產生的起霧現象將會降低可透光性,對於某些特定的產品或用品而言甚至會影響使用者的安全,例如車窗玻璃、汽車後視鏡和安全帽的護目鏡片;已知用於防止上述產品或用品產生起霧現象的方法,包括在上述產品或物品的表面噴塗防(抗)霧劑,防(抗)霧劑通常是一種含有親水性界面活性劑(Hydrophilic surfactant)或疏水性撥水劑(Hydrophobic agent)的溶液,透過形成一層具有親水性或疏水性的薄膜進而具備防霧的效果,但是這種溶液容易因為外力或其他氣候的因素而減損無法提供長期的 防霧功能。In an atmosphere with a temperature difference, the moisture-containing air is easily condensed into water droplets on the surface of the above-mentioned products or articles due to the temperature difference, causing fogging, and fogging on the surface of the above products or articles will occur. Will reduce opacity, and even affect the safety of users for certain products or supplies, such as window glass, car mirrors and safety glasses for eyewear; known to prevent these products or A method for producing fogging, comprising spraying an anti-anti-fogging agent on the surface of the above-mentioned product or article, and the anti-fogging agent is usually a hydrophilic surfactant or a hydrophobic water repellent ( Hydrophobic agent) has an anti-fog effect by forming a hydrophilic or hydrophobic film, but this solution is easily degraded by external force or other climatic factors and cannot provide long-term Anti-fog function.

為了解決上述防(抗)霧劑在使用上容易減損的問題,一種可以貼覆於上述產品或物品表面的防霧膜被提出,例如:在已核准的中華民國新型專利M452059「一種防霧膜」提出了一種可防止霧氣產生的透光防霧膜,其中利用一保護膜披覆在防霧層之一平面上,用以保護該防霧層;另外在已公開的中華民國發明專利200732396「防霧薄膜組合,其製造方法及由其製得之物件」提出了一種具有防霧層的薄膜,其包含一薄膜及一由形成聚胺基甲酸酯薄膜之組合物所形成的防霧層,該組合物包含具有異氰酸酯反應性分子團及疏水區及親水區之界面活性劑,透過特定成分的上述組合物以及聚胺基甲酸酯的耐擦傷性,提供一種具有防霧功能的薄膜;在已核准的中華民國新型專利M359423「具防霧功能之隔熱節能膜」則是提出了一種具有防霧以及隔熱效果的薄膜構造。In order to solve the problem that the above anti-fogging agent is easily degraded in use, an anti-fog film which can be applied to the surface of the above-mentioned product or article is proposed, for example, in the approved new patent of the Republic of China M452059 "an anti-fog film" A light-transmitting anti-fog film capable of preventing the generation of mist is proposed, wherein a protective film is coated on one of the planes of the anti-fog layer to protect the anti-fog layer; and in addition, the disclosed invention patent of the Republic of China 200732396 " An antifogging film combination, a method for producing the same, and an article obtained therefrom, proposes a film having an antifogging layer comprising a film and an antifogging layer formed of a composition forming a polyurethane film The composition comprises a surfactant having an isocyanate-reactive molecular group and a hydrophobic region and a hydrophilic region, and the above composition of the specific component and the scratch resistance of the polyurethane provide a film having an anti-fog function; In the approved Republic of China new patent M359423 "insulation-proof and energy-saving membrane with anti-fog function", a film structure with anti-fog and heat insulation effect is proposed.

本創作的目的之一在提出一種具有防霧、隔熱及抗紫外線功能的機能型多層薄膜。One of the purposes of this creation is to propose a functional multilayer film having anti-fog, heat insulation and UV resistance.

為實現上述目的,本創作提出的一種機能型多層薄膜的實施例構造,包括:互相重疊並黏結在一起的一第一機能薄膜和一第二機能薄膜:第一機能薄膜包含:一第一基材層,具有一第一表面及與第一表面相對之一第二表面,第一表面塗佈有一防霧層,第二表面塗佈有一第一感壓膠層(Pressure sensitive adhesion,PSA);第二機能薄膜包含:一第二基材層具有正面及與正面相對之背面,正面塗佈有一隔熱層,隔熱層相對於第二基材層的另一側與第一感壓膠層黏結在一起,背面塗佈有一抗紫外線層(抗 UV層),在抗紫外線層相對於第二基材層的另一側塗佈有一第二感壓膠層,在第二感壓膠層相對於抗紫外線層的另一側貼覆有一離形膜,藉此構成一種具有防霧、隔熱及抗紫外線功能的機能型多層薄膜。In order to achieve the above object, an embodiment of a functional multilayer film proposed by the present invention comprises: a first functional film and a second functional film which are overlapped and bonded together: the first functional film comprises: a first base The material layer has a first surface and a second surface opposite to the first surface, the first surface is coated with an anti-fog layer, and the second surface is coated with a first first pressure sensitive layer (PSA); The second functional film comprises: a second substrate layer having a front surface and a back surface opposite to the front surface, the front surface being coated with a heat insulating layer, and the other side of the heat insulating layer opposite to the second substrate layer and the first pressure sensitive adhesive layer Bonded together, coated with an anti-UV layer on the back a UV layer), a second pressure sensitive adhesive layer is coated on the other side of the UV resistant layer relative to the second substrate layer, and a second release layer is attached to the other side of the UV resistant layer. The film thereby forms a functional multilayer film having anti-fog, heat insulation and UV resistance.

在本創作的一實施例,其中的防霧層係為一種溶劑型丙烯酸酯塗層。In an embodiment of the present invention, the antifogging layer is a solvent based acrylate coating.

在本創作的一實施例,其中的第一基材層和第二基材層係為一種可透光的聚對苯二甲酸乙二醇酯薄膜(PET薄膜)。In an embodiment of the present invention, the first substrate layer and the second substrate layer are a light transmissive polyethylene terephthalate film (PET film).

在本創作的一實施例,其中的隔熱層係為一種奈米陶瓷層,具有隔熱及可供電磁波穿透的功能。In an embodiment of the present invention, the heat insulating layer is a nano ceramic layer having a function of insulating and providing electromagnetic wave penetration.

本創作的一實施例,其中的隔熱層係為一種奈米陶瓷層,該奈米陶瓷層係具有奈米陶瓷材料,其包含奈米陶瓷材料微粒或/及奈米感光變色微粒。In an embodiment of the present invention, the insulating layer is a nano ceramic layer having a nano ceramic material comprising nano ceramic material particles and/or nano photosensitive color changing particles.

在本創作的一實施例,其中的隔熱層係為一種奈米陶瓷層,且該奈米陶瓷層可為不同顏色。In an embodiment of the present invention, the insulating layer is a nano ceramic layer, and the nano ceramic layer can be different colors.

有關本創作的其他功效及實施例的詳細內容,將配合圖式說明如下。Other functions and embodiments of the present invention will be described below in conjunction with the drawings.

10‧‧‧第一基材層10‧‧‧First substrate layer

11‧‧‧第一表面11‧‧‧ first surface

12‧‧‧第二表面12‧‧‧ second surface

20‧‧‧防霧層20‧‧‧Anti-fog layer

30‧‧‧第一感壓膠層30‧‧‧First pressure sensitive adhesive layer

40‧‧‧第二基材層40‧‧‧Second substrate layer

41‧‧‧正面41‧‧‧ positive

42‧‧‧背面42‧‧‧Back

50‧‧‧隔熱層50‧‧‧Insulation

60‧‧‧抗紫外線層60‧‧‧Anti-UV layer

70‧‧‧第二感壓膠層70‧‧‧Second pressure layer

80‧‧‧離形膜80‧‧‧Dissecting film

第1圖,為本創作的一實施例的斷面構造圖,繪示各層構造分離後的關係。Fig. 1 is a cross-sectional structural view showing an embodiment of the present invention, showing the relationship of the structure separation of each layer.

第2圖,為本創作的一實施例的斷面構造圖,繪示各層構造互相重疊結合在一起的構造關係。Fig. 2 is a cross-sectional structural view showing an embodiment of the present invention, showing a structural relationship in which the layers are overlapped and joined to each other.

請參閱第1圖及第2圖,其中第1圖係為本創作的一實施例的斷面構造圖,繪示各層構造分離後的關係,第2圖繪示了第1圖中各層構造互相重疊結合在一起後構成的一種機能型多層薄膜的斷面構造。Please refer to FIG. 1 and FIG. 2 , wherein FIG. 1 is a cross-sectional structural view of an embodiment of the present invention, showing the relationship of the layers after the structure is separated, and FIG. 2 is a view showing the structure of each layer in FIG. 1 . A cross-sectional structure of a functional multilayer film formed by overlapping and bonding.

本創作提出的機能型多層薄膜,包括:互相重疊並黏結在一起的一第一機能薄膜和一第二機能薄膜。其中第一機能薄膜包含:一第一基材層10,具有一第一表面11及與第一表面11相對之一第二表面12,第一表面11塗佈有一防霧層20,第二表面12塗佈有一第一感壓膠層30(Pressure sensitive adhesion,PSA),較佳的實施方式是採用光學等級的感壓膠以便具有較佳的透光性。The functional multilayer film proposed by the present invention comprises: a first functional film and a second functional film which are overlapped and bonded together. The first functional film comprises: a first substrate layer 10 having a first surface 11 and a second surface 12 opposite to the first surface 11. The first surface 11 is coated with an anti-fog layer 20 and a second surface. 12 is coated with a first pressure sensitive adhesive layer 30 (PSA). A preferred embodiment is to use an optical grade pressure sensitive adhesive to have better light transmittance.

防霧層20的一種實施方式係為一種溶劑型丙烯酸酯塗層,具有防霧及耐磨的能力,因此不需要再利用其他的保護層予以保護即能長期使用而不虞減損。One embodiment of the anti-fog layer 20 is a solvent-based acrylate coating having the ability to resist fogging and abrasion, so that it can be used for a long period of time without loss of damage without the need for protection with other protective layers.

第二機能薄膜包含:一第二基材層40具有正面41及與正面41相對之背面42,正面41塗佈有一隔熱層50,隔熱層50相對於第二基材層40的另一側與第一感壓膠層30黏結在一起,背面42塗佈有一抗紫外線層60(Anti-Ultra Violet層),在抗紫外線層60相對於第二基材層40的另一側塗佈有一第二感壓膠層70,在第二感壓膠層70相對於抗紫外線層60的另一側貼覆有一離形膜80,離形膜80係可方便地與第二感壓膠層70剝離,藉此構成一種具有隔熱及抗紫外線功能的第二機能薄膜。The second functional film comprises: a second substrate layer 40 having a front surface 41 and a back surface 42 opposite to the front surface 41. The front surface 41 is coated with a heat insulating layer 50, and the heat insulating layer 50 is opposite to the second substrate layer 40. The side is bonded to the first pressure sensitive adhesive layer 30, and the back surface 42 is coated with an anti-ultraviolet layer 60 (Anti-Ultra Violet layer), and the anti-ultraviolet layer 60 is coated on the other side of the second substrate layer 40. The second pressure sensitive adhesive layer 70 is attached with a release film 80 on the other side of the second pressure sensitive adhesive layer 70 opposite to the ultraviolet resistant layer 60. The release film 80 is conveniently combined with the second pressure sensitive adhesive layer 70. Peeling, thereby forming a second functional film having heat insulating and ultraviolet blocking functions.

第一基材層10和第二基材層40係為一種可透光的聚對苯二甲酸乙二醇酯薄膜(PET薄膜),第一基材層10和第二基材層40係分別作為第一機能薄膜和第二機能薄膜的基層材料;換言之、前述的防霧層20和第一 感壓膠層30係以第一基材層10為基層材料分別塗佈於第一基材層10的第一表面11和第二表面12,進而構成具有防霧功能的第一機能薄膜;前述的隔熱層50、抗紫外線層60係以第二基材層40為基層材料分別塗佈於第二基材層40的正面41和背面42,進而構成具有隔熱和抗紫外線功能的第二機能薄膜。透過互相重疊並黏結在一起的第一機能薄膜和第二機能薄膜,即可成為一種具有防霧、隔熱及抗紫外線功能的機能型多層薄膜。The first substrate layer 10 and the second substrate layer 40 are a light transmissive polyethylene terephthalate film (PET film), and the first substrate layer 10 and the second substrate layer 40 are respectively As a base material of the first functional film and the second functional film; in other words, the aforementioned anti-fog layer 20 and the first The pressure sensitive adhesive layer 30 is applied to the first surface 11 and the second surface 12 of the first substrate layer 10 with the first substrate layer 10 as a base material, thereby forming a first functional film having an anti-fog function; The heat-insulating layer 50 and the ultraviolet-resistant layer 60 are respectively applied to the front surface 41 and the back surface 42 of the second base material layer 40 with the second base material layer 40 as a base material, thereby forming a second heat-insulating and ultraviolet-resistant function. Functional film. Through the first functional film and the second functional film which are overlapped and bonded together, it can be a functional multilayer film with anti-fog, heat insulation and UV resistance.

隔熱層50的一種實施方式係採用奈米等級不含金屬的無機奈米陶瓷材料所製成的奈米陶瓷層,將奈米陶瓷材料透過例如濺鍍的方式塗佈於第二基材層40的正面41,透過控制隔熱層50之濺鍍層之厚度的方式,令隔熱層50在可見光的範圍內保持透光性,同時控制紫外線及紅外線光波的穿透,進而達到隔熱的功效,本創作之隔熱層50係採用奈米等級不含金屬的無機奈米陶瓷材料,具較佳硬度和高緻密度之特性,除了具有隔熱的功能又可供電磁波穿透,因此本創作機能型多層薄膜應用於例如車窗玻璃作為隔熱防霧膜,亦不會影響感應式電子標籤的使用,例如目前安裝於汽車之車窗上採用射頻識別(Radio Frequency Identification,RFID)技術的電子標籤(e-tag標籤)的正常使用。在本創作的一實施例,該奈米陶瓷層的顏色還具有可以設定顏色的功能,進而令該奈米陶瓷層可為不同顏色,在較佳實施例中,該奈米陶瓷層50之奈米陶瓷材料係包含奈米陶瓷材料微粒或/及奈米感光變色微粒,該等奈米陶瓷材料微粒,在光線照射時能夠降低該紅外線阻隔層之透光性,以減少所述紅外線穿透,或進一步該奈米陶瓷材料包含奈米感光變色微粒,該奈米感光變色微粒可以和紫外線反應而改變深淺顏色。One embodiment of the heat insulating layer 50 is a nano ceramic layer made of a nano-grade metal-free inorganic nano ceramic material, and the nano ceramic material is applied to the second substrate layer by, for example, sputtering. The front surface 41 of the 40, by controlling the thickness of the sputter layer of the heat insulating layer 50, keeps the heat insulating layer 50 transparent in the visible light range, and controls the penetration of ultraviolet light and infrared light waves to achieve the heat insulating effect. The insulation layer 50 of this creation adopts nano-grade inorganic nano-ceramic material without metal, which has better hardness and high density. Besides the function of heat insulation, it can penetrate electromagnetic waves, so this creation Functional multi-layer films are used, for example, as window glass as an anti-fog film, and do not affect the use of inductive electronic tags, such as those currently installed on the window of a car using radio frequency identification (RFID) technology. Normal use of tags (e-tag tags). In an embodiment of the present invention, the color of the nano ceramic layer further has a function of setting a color, and thus the nano ceramic layer can be of different colors. In a preferred embodiment, the nano ceramic layer 50 is The rice ceramic material comprises nano ceramic material particles and/or nano photosensitive color-changing particles, and the nano ceramic material particles can reduce the light transmittance of the infrared blocking layer when the light is irradiated to reduce the infrared light penetration. Or the nano ceramic material further comprises nano photosensitive color-changing particles, and the nano photosensitive photosensitive particles can react with ultraviolet rays to change the dark color.

因此,由以上的實施例說明可以瞭解,依據本創作機能型多層薄膜的用途,藉由防霧層20、隔熱層50和抗紫外線層60的配合,可以應用於例如車窗玻璃、汽車後視鏡、建築玻璃窗/門使用的玻璃、安全帽的護目鏡片、玻璃展示櫃或是冷藏櫃的玻璃門,實際施作時,只要將本創作機能型多層薄膜的離形膜80剝離之後,再將具有第二感壓膠層70的一面施壓貼附於上述的物品的表面,就能使該些物品具備防霧、遮陽及抗紫外線功能。Therefore, it can be understood from the above embodiments that, according to the use of the inventive functional multilayer film, the cooperation of the anti-fog layer 20, the heat insulating layer 50 and the ultraviolet resistant layer 60 can be applied to, for example, a window glass or a car. Sight glass, glass for building glazing/doors, goggles for safety helmets, glass display cabinets or glass doors for refrigerated cabinets, as long as the release film 80 of the functional multilayer film is peeled off after actual application Then, the side having the second pressure sensitive adhesive layer 70 is pressed and attached to the surface of the article, so that the articles can be provided with anti-fog, sunshade and ultraviolet-resistant functions.

雖然本創作已透過上述之實施例揭露如上,然其並非用以限定本創作,任何熟悉此一技術領域具有通常知識者,在瞭解本創作前述的技術特徵及實施例,並在不脫離本創作之精神和範圍內,當可作些許之更動與潤飾,因此本創作之專利保護範圍須視本說明書所附之請求項所界定者為準。Although the present invention has been disclosed above through the above embodiments, it is not intended to limit the present creation, and anyone skilled in the art can understand the foregoing technical features and embodiments of the present invention without departing from the present invention. In the spirit and scope of the invention, the scope of patent protection of this creation shall be subject to the definition of the requirements attached to this specification.

10‧‧‧第一基材層10‧‧‧First substrate layer

11‧‧‧第一表面11‧‧‧ first surface

12‧‧‧第二表面12‧‧‧ second surface

20‧‧‧防霧層20‧‧‧Anti-fog layer

30‧‧‧第一感壓膠層30‧‧‧First pressure sensitive adhesive layer

40‧‧‧第二基材層40‧‧‧Second substrate layer

41‧‧‧正面41‧‧‧ positive

42‧‧‧背面42‧‧‧Back

50‧‧‧隔熱層50‧‧‧Insulation

60‧‧‧抗紫外線層60‧‧‧Anti-UV layer

70‧‧‧第二感壓膠層70‧‧‧Second pressure layer

80‧‧‧離形膜80‧‧‧Dissecting film

Claims (6)

一種機能型多層薄膜,包括:互相重疊並黏結在一起的一第一機能薄膜和一第二機能薄膜:該第一機能薄膜包含:一第一基材層,具有一第一表面及與該第一表面相對之一第二表面,該第一表面塗佈有一防霧層,該第二表面塗佈有一第一感壓膠層;該第二機能薄膜包含:一第二基材層具有一正面及與該正面相對之一背面,該正面塗佈有一隔熱層,該隔熱層相對於該第二基材層的另一側與該第一感壓膠層黏結在一起,該背面塗佈有一抗紫外線層,在該抗紫外線層相對於該第二基材層的另一側塗佈有一第二感壓膠層,在該第二感壓膠層相對於該抗紫外線層的另一側貼覆有一離形膜。A functional multilayer film comprising: a first functional film and a second functional film which are overlapped and bonded together: the first functional film comprises: a first substrate layer having a first surface and the same a surface opposite to the second surface, the first surface is coated with an anti-fog layer, the second surface is coated with a first pressure sensitive adhesive layer; the second functional film comprises: a second substrate layer having a front surface And a back surface opposite to the front surface, the front surface is coated with a heat insulation layer, and the heat insulation layer is bonded to the first pressure sensitive adhesive layer on the other side of the second base material layer, the back surface coating An ultraviolet resistant layer having a second pressure sensitive adhesive layer coated on the other side of the ultraviolet resistant layer opposite to the second substrate layer, the second pressure sensitive adhesive layer being opposite to the other side of the ultraviolet resistant layer There is a release film attached. 如請求項1所述的機能型多層薄膜,其中該防霧層係為一種溶劑型丙烯酸酯塗層。The functional multilayer film of claim 1, wherein the antifogging layer is a solvent acrylate coating. 如請求項1所述的機能型多層薄膜,其中該第一基材層和該第二基材層係為一種可透光的聚對苯二甲酸乙二醇酯薄膜。The functional multilayer film of claim 1, wherein the first substrate layer and the second substrate layer are a light transmissive polyethylene terephthalate film. 如請求項1所述的機能型多層薄膜,其中該隔熱層係採用奈米等級不含金屬的無機奈米陶瓷材料所製成的一奈米陶瓷層。The functional multilayer film according to claim 1, wherein the heat insulating layer is a nano ceramic layer made of a nano-grade metal-free inorganic nano ceramic material. 如請求項4所述之機能型多層薄膜,其中該奈米陶瓷層係具有奈米陶瓷材料,其包含奈米陶瓷材料微粒或/及奈米感光變色微粒。The functional multilayer film according to claim 4, wherein the nano ceramic layer has a nano ceramic material comprising nano ceramic material particles or/and nano photosensitive color-sensitive particles. 如請求項5所述的機能型多層薄膜,其中該奈米陶瓷層的顏色可為深淺或不同顏色。The functional multilayer film of claim 5, wherein the nano ceramic layer has a color that is dark or different in color.
TW103212348U 2014-07-11 2014-07-11 Functional multilayer thin film TWM495297U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI822211B (en) * 2021-08-02 2023-11-11 日商長瀨產業股份有限公司 Anti-fog layer and its use

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI822211B (en) * 2021-08-02 2023-11-11 日商長瀨產業股份有限公司 Anti-fog layer and its use

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