TWM464797U - Base metal composite electrode of electronic ceramic element - Google Patents
Base metal composite electrode of electronic ceramic element Download PDFInfo
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- TWM464797U TWM464797U TW102212038U TW102212038U TWM464797U TW M464797 U TWM464797 U TW M464797U TW 102212038 U TW102212038 U TW 102212038U TW 102212038 U TW102212038 U TW 102212038U TW M464797 U TWM464797 U TW M464797U
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本創作係有關於一種電子陶瓷元件的卑金屬複合電極的技術領域,具體涉及一種電子陶瓷元件的卑金屬複合電極。 The present invention relates to the technical field of a base metal composite electrode of an electronic ceramic component, and in particular to a base metal composite electrode of an electronic ceramic component.
本發明主張國內優先權之基礎案係為民國102年4月18日所提出之發明申請案,其申請案號第102207108號,據此作為本發明優先權之基礎,在此先予聲明。 The present invention claims that the basis of the domestic priority is the invention application filed on April 18, 1988, the application of which is incorporated herein by reference.
現有氧化鋅壓敏電阻器(Metal Oxide Varistors)具有特殊的非線性電流-電壓特性。使用中一旦發生異常狀況,比如遭遇雷擊、電磁場干擾,電源開關頻繁動作、電源系統故障,使得線路上電壓突增,超過氧化鋅壓敏電阻器的導通電壓,就會進入導通區。此時電流(I)和電壓(V)呈非線性關係,一般稱之為非線性係數(Nonlinearity Parameter),其值可達數十或上百。此時,氧化鋅壓敏電阻器阻抗會變低,僅有幾個歐姆,讓過電壓形成突波電流流出,藉以保護所連接的電子產品或昂貴組件。氧化鋅壓敏電阻器是屬於電子陶瓷元件的一種。 Existing metal oxide varistor (Metal Oxide Varistors) have special nonlinear current-voltage characteristics. In the event of abnormal conditions in use, such as lightning strikes, electromagnetic field interference, frequent power switch operation, power system failure, the voltage on the line suddenly increases, exceeding the conduction voltage of the zinc oxide varistor, it will enter the conduction area. At this time, the current (I) and the voltage (V) have a nonlinear relationship, which is generally called a nonlinearity parameter, and the value can be several tens or hundreds. At this point, the resistance of the zinc oxide varistor will be low, only a few ohms, allowing the overvoltage to form a surge current to protect the connected electronic products or expensive components. A zinc oxide varistor is a type of electronic ceramic component.
現有的電子陶瓷元件的電極普遍採用銀電極材料或銅電極材料,由圖1可知,常規的電子陶瓷元件的呈圓形或矩形的平面狀,電 子陶瓷芯片111上覆蓋銀電極層或銅電極層112,而銀電極材料的價格昂貴,銅電極材料的成本也較高,因此,現有的單層銀電極或單層銅電極不符合現代電子技術對產品高性價比的要求。 The electrode of the existing electronic ceramic component generally adopts a silver electrode material or a copper electrode material. As can be seen from FIG. 1, the conventional electronic ceramic component has a circular or rectangular planar shape, and is electrically The sub-ceramic chip 111 is covered with a silver electrode layer or a copper electrode layer 112, and the silver electrode material is expensive, and the cost of the copper electrode material is also high. Therefore, the existing single-layer silver electrode or single-layer copper electrode does not conform to modern electronic technology. The product is cost-effective.
有鑑於此,本創作人遂針對上述現有技術,特潛心研究並配合學理的運用,盡力解決上述之問題點,即成為本創作人改良之目標。 In view of this, the creator has made great efforts to solve the above problems by focusing on the above-mentioned prior art, and has devoted himself to the application of the theory, that is, the goal of the creator's improvement.
本創作之一目的,在於提供一種電子陶瓷元件的卑金屬複合電極,其係解決了在保持電極功能的基礎上提高電子陶瓷元件的性價比的技術問題。 One of the aims of the present invention is to provide a base metal composite electrode of an electronic ceramic component, which solves the technical problem of improving the cost performance of the electronic ceramic component while maintaining the function of the electrode.
為了達成上述之目的,本創作係提供一種電子陶瓷元件的卑金屬複合電極,所述電子陶瓷元件包括一電子陶瓷芯片,該卑金屬複合電極包括:二第一卑金屬電極層,該二第一卑金屬電極層覆蓋在所述電子陶瓷芯片的兩面;以及二第二卑金屬電極層,覆蓋在各該第一卑金屬電極層上。 In order to achieve the above object, the present invention provides a base metal composite electrode of an electronic ceramic component, the electronic ceramic component comprising an electronic ceramic chip, the base metal composite electrode comprising: a first first metal electrode layer, the first A base metal electrode layer covers both sides of the electronic ceramic chip; and two second base metal electrode layers cover each of the first base metal electrode layers.
本創作還具有以下功效:鋁材有良好的導電性,而且與電子陶瓷本體有著很好的附著性,而為了保證電極良好的可焊性,銅、鋅、鎳或錫被作為焊接層的電極材料,依次噴塗在鋁電極層之上,保證了焊接的可靠性,兩種卑金屬材料共同組成廉價電極,替代原有昂貴的銀電極或較昂 貴的銅電極,在保持電極功能的基礎上降低了電極材料的成本,提高生產的電子陶瓷元件的性價比。 The creation also has the following effects: aluminum has good electrical conductivity and has good adhesion to the electronic ceramic body, and in order to ensure good solderability of the electrode, copper, zinc, nickel or tin is used as the electrode of the solder layer. The material is sprayed on top of the aluminum electrode layer in turn to ensure the reliability of the soldering. The two kinds of base metal materials together form an inexpensive electrode, which replaces the expensive silver electrode or is more expensive. The expensive copper electrode reduces the cost of the electrode material on the basis of maintaining the function of the electrode, and improves the cost performance of the produced electronic ceramic component.
<習知> <知知>
111‧‧‧電子陶瓷芯片 111‧‧‧Electronic Ceramic Chip
112‧‧‧銀電極層、銅電極層 112‧‧‧Silver electrode layer, copper electrode layer
<本創作> <this creation>
111‧‧‧電子陶瓷芯片 111‧‧‧Electronic Ceramic Chip
113‧‧‧第一金屬電極層、鋁電極層 113‧‧‧First metal electrode layer, aluminum electrode layer
1131、1132‧‧‧鋁電極層 1131, 1132‧‧‧ aluminum electrode layer
114‧‧‧第二金屬電極層、銅電極層、鋅電極層、錫電極層、鎳電極層 114‧‧‧Second metal electrode layer, copper electrode layer, zinc electrode layer, tin electrode layer, nickel electrode layer
1141、1142‧‧‧鋅覆蓋部分 1141, 1142‧‧ ‧ zinc covered part
115‧‧‧電極引出線 115‧‧‧Electrode lead wire
圖1係習知的電極結構圖。 Figure 1 is a conventional electrode structure diagram.
圖2係本創作實施例一提供的卑金屬複合電極的結構示意圖。 FIG. 2 is a schematic structural view of a base metal composite electrode provided in the first embodiment of the present invention.
圖3係本創作實施例二提供的卑金屬複合電極的結構示意圖。 FIG. 3 is a schematic structural view of a base metal composite electrode provided in the second embodiment of the present invention.
圖4係本創作實施例三提供的卑金屬複合電極的結構示意圖。 4 is a schematic structural view of a base metal composite electrode provided in the third embodiment of the present invention.
圖5-1係本創作實施例四提供的卑金屬複合電極的結構示意圖。 5-1 is a schematic structural view of a base metal composite electrode provided in the fourth embodiment of the present invention.
圖5-2係本創作實施例四提供的卑金屬複合電極的另一結構示意圖。 FIG. 5-2 is another schematic structural view of a base metal composite electrode provided in the fourth embodiment of the present invention.
圖6係本創作實施例五提供的卑金屬複合電極的結構示意圖。 FIG. 6 is a schematic structural view of a base metal composite electrode provided in the fifth embodiment of the present invention.
圖7係本創作實施例六提供的卑金屬複合電極的結構示意圖。 FIG. 7 is a schematic structural view of a base metal composite electrode provided in the sixth embodiment of the present invention.
有關本創作之詳細說明及技術內容,將配合圖式說明如下,然而所附圖式僅作為說明用途,並非用於侷限本創作。 The detailed description and technical content of the present invention will be described below in conjunction with the drawings, but the drawings are for illustrative purposes only and are not intended to limit the present invention.
請參考圖2至圖7所示,本創作係提供一種電子陶瓷元件的卑金屬複合電極,電子陶瓷元件包括一電子陶瓷芯片111,此金屬複合電極主要包括二第一卑金屬電極層113及二第二卑金屬電極層114。 Referring to FIG. 2 to FIG. 7 , the present invention provides a base metal composite electrode of an electronic ceramic component. The electronic ceramic component includes an electronic ceramic chip 111 , and the metal composite electrode mainly includes two first and second metal electrode layers 113 and two. The second base metal electrode layer 114.
卑金屬(或稱賤金屬,基本金屬,英文:Base metal)是除了金 、銀、白金等貴金屬(Precious metal)之外,其他所有的金屬。例如:鐵、銅、鋁等。 Base metal (or base metal, English: Base metal) is in addition to gold Other than precious metals such as silver and platinum, all other metals. For example: iron, copper, aluminum, etc.
圖2係本創作實施例一提供的卑金屬複合電極的結構示意圖。如圖2所示,電子陶瓷元件包括電子陶瓷芯片111和卑金屬複合電極,電子陶瓷芯片111指未塗覆電極層的陶瓷本體;卑金屬複合電極包括第一卑金屬電極層113和第二卑金屬電極層114,第一卑金屬電極層113覆蓋在電子陶瓷芯片的兩面,第二卑金屬電極層114覆蓋在第一卑金屬電極層113上。其中,第二卑金屬電極層114為焊接層。 FIG. 2 is a schematic structural view of a base metal composite electrode provided in the first embodiment of the present invention. As shown in FIG. 2, the electronic ceramic component includes an electronic ceramic chip 111 and a base metal composite electrode, and the electronic ceramic chip 111 refers to a ceramic body not coated with an electrode layer; the base metal composite electrode includes a first base metal electrode layer 113 and a second The metal electrode layer 114 covers the both sides of the electronic ceramic chip, and the second base metal layer 114 covers the first base metal layer 113. The second base metal electrode layer 114 is a solder layer.
在本實施例中,採用熱噴塗技術將卑金屬噴塗到電子陶瓷芯片的表面。 In this embodiment, a blast metal is sprayed onto the surface of the electronic ceramic chip using a thermal spray technique.
在本實施例中,第一卑金屬電極層113採用鋁電極材料,第二卑金屬電極層114採用銅電極材料,即第一卑金屬電極層113為鋁電極層113,第二卑金屬電極層114為銅電極層114。 In this embodiment, the first base metal electrode layer 113 is made of an aluminum electrode material, and the second base metal electrode layer 114 is made of a copper electrode material, that is, the first base metal electrode layer 113 is an aluminum electrode layer 113, and the second base metal electrode layer is used. 114 is a copper electrode layer 114.
另外,鋁電極層113的形狀和電子陶瓷元件的形狀相互配合,並不局限於任何形狀。舉例說明,本實施例中,電子陶瓷元件為圓形,鋁電極層113也為圓形。 Further, the shape of the aluminum electrode layer 113 and the shape of the electronic ceramic element are mutually compatible, and are not limited to any shape. For example, in the embodiment, the electronic ceramic component is circular, and the aluminum electrode layer 113 is also circular.
再者,銅電極層114不局限於任何形狀,銅電極層114的覆蓋面積可小於、等於或大於鋁電極層113的覆蓋面積。 Furthermore, the copper electrode layer 114 is not limited to any shape, and the coverage area of the copper electrode layer 114 may be smaller than, equal to or larger than the coverage area of the aluminum electrode layer 113.
在本實施例中,銅電極層114包括一個銅覆蓋部分,並且銅電極層114也為圓形。銅電極層114的覆蓋面積小於鋁電極層113的覆蓋面積,即銅電極層114的直徑小於鋁電極層113的直徑。 In the present embodiment, the copper electrode layer 114 includes a copper covered portion, and the copper electrode layer 114 is also circular. The coverage area of the copper electrode layer 114 is smaller than the coverage area of the aluminum electrode layer 113, that is, the diameter of the copper electrode layer 114 is smaller than the diameter of the aluminum electrode layer 113.
在本實施例中,覆蓋在電子陶瓷芯片111的兩面的銅電極層114的形狀和面積是相同的,為直徑相同的圓形。 In the present embodiment, the shape and area of the copper electrode layer 114 covering both sides of the electronic ceramic chip 111 are the same, and are circular shapes having the same diameter.
在本實施例中,鋁電極層113為主電極層,銅電極層114為次電極層兼焊接層,基於強度、硬度需求,鋁銅複合電極還可包括在鋁電極層113和銅電極層114中間增加的至少一層卑金屬加強層。 In the present embodiment, the aluminum electrode layer 113 is a main electrode layer, and the copper electrode layer 114 is a sub-electrode layer and a solder layer. The aluminum-copper composite electrode may further be included between the aluminum electrode layer 113 and the copper electrode layer 114 based on strength and hardness requirements. Add at least one layer of base metal reinforcement.
在本實施例中,電子陶瓷芯片的形狀可以為圓形、矩形、管狀形、環形、圓柱形或錐形,但其不被上述形狀所限制,可視實際情況自行調整。 In this embodiment, the shape of the electronic ceramic chip may be circular, rectangular, tubular, annular, cylindrical or tapered, but it is not limited by the above shape, and may be adjusted according to actual conditions.
此外,電子陶瓷元件可廣泛應用於如陶瓷電容器、氣敏電阻、壓電元件、濕敏電阻、熱敏電阻、壓敏電阻中的任意一種。 Further, the electronic ceramic component can be widely applied to any one of a ceramic capacitor, a gas resistance, a piezoelectric element, a humidity sensitive resistor, a thermistor, and a varistor.
圖3係本創作實施例二提供的卑金屬複合電極的結構示意圖。本實施例與實施例一的不同之處僅在於:在本實施例中,第一卑金屬電極層113採用鋁電極材料,第二卑金屬電極層114採用鋅電極材料,即第一卑金屬電極層113為鋁電極層113,所述第二卑金屬電極層114為鋅電極層114。 FIG. 3 is a schematic structural view of a base metal composite electrode provided in the second embodiment of the present invention. The first embodiment is different from the first embodiment in that: in the embodiment, the first base metal electrode layer 113 is made of an aluminum electrode material, and the second base metal electrode layer 114 is made of a zinc electrode material, that is, the first base metal electrode. The layer 113 is an aluminum electrode layer 113, and the second base metal electrode layer 114 is a zinc electrode layer 114.
並且,如圖3所示,鋅電極層114為環形。在本實施例中,環形寬度最小2mm,最大為30mm。 Also, as shown in FIG. 3, the zinc electrode layer 114 is annular. In the present embodiment, the annular width is at least 2 mm and the maximum is 30 mm.
圖4係本創作實施例三提供的卑金屬複合電極結構示意圖。本實施例與實施例一的不同之處僅在於:在本實施例中,第一卑金屬電極層113採用鋁電極材料,第二卑金屬電極層114採用錫電極材料,即第一卑金屬電極層113為鋁電 極層113,所述第二卑金屬電極層114為錫電極層114。 4 is a schematic structural view of a base metal composite electrode provided in the third embodiment of the present invention. The first embodiment is different from the first embodiment in that: in the embodiment, the first base metal electrode layer 113 is made of an aluminum electrode material, and the second base metal electrode layer 114 is made of a tin electrode material, that is, the first base metal electrode. Layer 113 is aluminum The second layer 113, the second base metal layer 114 is a tin electrode layer 114.
並且,如圖4所示,覆蓋在電子陶瓷芯片111的一面上的錫電極層114包括多個相互分離的覆蓋部分。在本實施例中,錫電極層114包括兩個形狀為半圓形的覆蓋部分,兩個覆蓋部分之間具有1mm以上的間距。 Also, as shown in FIG. 4, the tin electrode layer 114 overlying one side of the electronic ceramic chip 111 includes a plurality of cover portions separated from each other. In the present embodiment, the tin electrode layer 114 includes two cover portions having a semicircular shape with a pitch of 1 mm or more between the two cover portions.
圖5-1、5-2係本創作實施例四提供的卑金屬複合電極的結構示意圖。本實施例與實施例一的不同之處僅在於:在電子陶瓷芯片一面的鋁電極層1131包括一個以上的鋁覆蓋部分,在鋁覆蓋部分上覆蓋有鋅覆蓋部分1141;在圖5-1中,在電子陶瓷芯片一面的鋁電極層1131包括一個鋁覆蓋部分;在圖5-2中,鋁電極層1131包括兩個鋁覆蓋部分。 5-1 and 5-2 are schematic structural views of a base metal composite electrode provided in the fourth embodiment of the present invention. The difference between this embodiment and the first embodiment is that the aluminum electrode layer 1131 on one side of the electronic ceramic chip includes more than one aluminum covering portion, and the aluminum covering portion is covered with the zinc covering portion 1141; in FIG. 5-1 The aluminum electrode layer 1131 on one side of the electronic ceramic chip includes an aluminum covered portion; in Fig. 5-2, the aluminum electrode layer 1131 includes two aluminum covered portions.
另外,在電子陶瓷芯片另一面的鋁電極層1132包括兩個以上的鋁覆蓋部分,在每個鋁覆蓋部分上覆蓋有鋅覆蓋部分1142;在圖5-1、5-2中,在電子陶瓷芯片另一面的鋁電極層1132均包括三個鋁覆蓋部分。 In addition, the aluminum electrode layer 1132 on the other side of the electronic ceramic chip includes two or more aluminum covering portions, each of which is covered with a zinc covering portion 1142; in FIGS. 5-1 and 5-2, in the electronic ceramic The aluminum electrode layers 1132 on the other side of the chip each include three aluminum covered portions.
本實施例提供的卑金屬複合電極結構可實現在一個電子陶瓷芯片上形成多個電子陶瓷元件,如,陶瓷電容器、氣敏電阻、壓電元件、濕敏電阻、熱敏電阻、壓敏電阻等,形成的多個電阻或電容陶瓷元件的電極可能相互連接。 The base metal composite electrode structure provided in this embodiment can realize forming a plurality of electronic ceramic components on an electronic ceramic chip, such as a ceramic capacitor, a gas sensor, a piezoelectric element, a humidity sensitive resistor, a thermistor, a varistor, etc. The electrodes of the plurality of resistor or capacitor ceramic elements formed may be connected to each other.
圖6係本創作實施例五提供的卑金屬複合電極的結構示意圖。本實施例與實施例一的不同之處僅在於: 鎳電極層114的覆蓋面積大於鋁電極層113的覆蓋面積,即鎳電極層114的直徑大於鋁電極層113的直徑。 FIG. 6 is a schematic structural view of a base metal composite electrode provided in the fifth embodiment of the present invention. The difference between this embodiment and the first embodiment is only: The coverage area of the nickel electrode layer 114 is larger than the coverage area of the aluminum electrode layer 113, that is, the diameter of the nickel electrode layer 114 is larger than the diameter of the aluminum electrode layer 113.
如圖6所示,鎳電極層114的周邊部分直接覆蓋在電子陶瓷芯片111上。在本實施例中,第一電極層直徑最小可為2mm,第二電極層114的直徑最小為2.5mm。 As shown in FIG. 6, the peripheral portion of the nickel electrode layer 114 is directly covered on the electronic ceramic chip 111. In this embodiment, the diameter of the first electrode layer may be at least 2 mm, and the diameter of the second electrode layer 114 may be at least 2.5 mm.
圖7係本創作實施例六提供的卑金屬複合電極的結構示意圖。本實施例與實施例一的不同之處僅在於:如圖7所示,銅電極層114僅覆蓋需焊接電極引出線115的區域,且在本實施例中,覆蓋在電子陶瓷芯片111的兩面的銅電極層114的形狀和面積是不相同的,即兩面的銅電極層114是非對稱的,以適應不同的焊接電極引出線115的需要。 FIG. 7 is a schematic structural view of a base metal composite electrode provided in the sixth embodiment of the present invention. This embodiment differs from the first embodiment only in that, as shown in FIG. 7, the copper electrode layer 114 covers only the region where the electrode lead wires 115 are to be soldered, and in the present embodiment, covers both sides of the electronic ceramic chip 111. The shape and area of the copper electrode layer 114 are different, that is, the two-sided copper electrode layer 114 is asymmetrical to accommodate the needs of different solder electrode lead wires 115.
此外,上述之鋁電極材料可以是純鋁,也可以是鋁含量佔40%以上的鋁合金;銅電極材料可以是純銅,也可以是銅含量佔40%以上的銅合金;鋅電極材料可以是純鋅,也可以是鋅含量佔40%以上的鋅合金;鎳電極材料可以是純鎳,也可以是鎳含量佔40%以上的鎳合金;錫電極材料可以是純錫,也可以是錫含量佔40%以上的錫合金。 In addition, the aluminum electrode material may be pure aluminum or an aluminum alloy having an aluminum content of 40% or more; the copper electrode material may be pure copper or a copper alloy having a copper content of 40% or more; the zinc electrode material may be Pure zinc can also be a zinc alloy with a zinc content of more than 40%; the nickel electrode material can be pure nickel or a nickel alloy with a nickel content of 40% or more; the tin electrode material can be pure tin or tin content. More than 40% of the tin alloy.
鋁材有良好的導電性,而且與電子陶瓷本體有著很好的附著性,而為了保證電極良好的可焊性,銅、鋅、鎳或錫被作為焊接層的電極材料,依次噴塗在鋁電極層之上,保證了焊接的可靠性,兩種卑金屬材料共同組成廉價電極,替代原有昂貴的銀電極或較昂貴的銅電極,在保持電極功能的基礎上降低了電極材料的成本, 提高生產的電子陶瓷元件的性價比。 Aluminum has good electrical conductivity and has good adhesion to the electronic ceramic body. In order to ensure good solderability of the electrode, copper, zinc, nickel or tin is used as the electrode material of the soldering layer, and is sequentially sprayed on the aluminum electrode. Above the layer, the reliability of the solder is ensured. The two kinds of base metal materials together form an inexpensive electrode, replacing the expensive silver electrode or the more expensive copper electrode, and the cost of the electrode material is reduced on the basis of maintaining the function of the electrode. Improve the cost performance of electronic ceramic components produced.
綜上所述,本創作之電子陶瓷元件的卑金屬複合電極,確可達到預期之使用目的,而解決習知之缺失,並具有產業利用性、新穎性與進步性,完全符合新型專利申請要件,爰依專利法提出申請,敬請詳查並賜准本案專利,以保障創作人之權利。 In summary, the base metal composite electrode of the electronic ceramic component of the present invention can achieve the intended use purpose, and solve the lack of conventional knowledge, and has industrial utilization, novelty and progress, and fully conforms to the requirements of the new patent application. To file an application in accordance with the Patent Law, please check and grant the patent in this case to protect the rights of the creator.
111‧‧‧電子陶瓷芯片 111‧‧‧Electronic Ceramic Chip
113‧‧‧第一金屬電極層、鋁電極層 113‧‧‧First metal electrode layer, aluminum electrode layer
114‧‧‧第二金屬電極層、銅電極層 114‧‧‧Second metal electrode layer, copper electrode layer
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