9]?. J 0.修正i M350705 -八、新型說明： 【新型所屬之技術領域】 本創作係提供一「微波輔助自動化學成份分析系統」，利用微 波快速加熱之原理，縮短傳統化學成份分析系統萃取過程所需之 吸附時間，並結合自動化機械手臂可有效縮減檢驗流程所需時 間、減少人力成本，實現快速檢測之目的。 【先前技術】 固相微萃取（solid phase microextraction，SPME)為 Arthur 和Pawliszyn最早於1990年所提出的萃取技術，且於ι993年更 進一步發展出頂空固相微萃取技術（headspace-SPME)。固相微萃 取法能濃縮來自液態、氣態及固態基質之揮發性和非揮發性成 分，之後直接進行氣相層析儀（G〇或液相層析儀（HPLC)分 析’應用範圍包括化學、環境、製藥、氣味、食品及天然產物等 分析。此撤喊結合雜、萃取、_和雜品送人層析儀中 分析等成單-步驟且能自動化執行，並提供較其他技術更低的债 測極限及降低樣品製備咖。目相微萃取法考慮兩個分離步驟， 分別為吸附（abSGrPtiQn)及脫附（deSQrptiQn)。_微萃取最 佳化條件所考慮的變數包括纖維管的選擇、萃取步驟之萃取時間 及離子效應、賴溫度及咖，A部分文獻是·最早發展出的 SPME 纖維管 P〇1ydimethylsil〇xane (pMS)及⑽赠y㈣ (PA)塗佈。_微萃取與頂空萃取結合的技術由2_年 7 M350705 __ X修 等人針對雜及其代啦物、職及賴、麻賴、：稈 :金屬、農藥、内分泌物質及代謝產物在生物檢體分析上加以綜合 論述。在吸附過程上’過去主要利用線圈加熱樣品，以使物質吸 附於纖維管上，然此過程需要耗費較長之時間，因而降低單位時 間所能檢測之樣品數。 【新型内容】 由上述之原由，本創作之主要目的係在提供一快速且自動化 2化學成份分析錢，可細使时所賴之檢測_自動批次 完成樣品之檢驗’並顯示分析結果。為實現此目的，本創作乃由 i械手魏置一微波加紐置、—層析儀、—人機介面裝置、 控制裝置、乡錄^試瓶托盤、—m雜置、以及 清潔裝置所組成。 乳 其中，機械手臂裝置包含四軸手臂以移動試瓶於三維空間中 移動並能控制探針之運動，因而可實現多種程序分析，另外包人 夕個配件©找肋@紐品試瓶鋪、液歸雜置、氮 潔裝置及腳架一試瓶抓取H肋抓取試瓶、—探針活塞固定架月、 -探針主咖定架、以及—探針用以吸取試軸之待測溶液· 微波加熱裝置用以加熱樣品，以萃取樣品中之 发 附於探針上； 昇吸 層析儀可魏相層析儀m或_層析儀（HP[£)， 析樣品成份； ^ 8 M350705 人機介面裝置用以顯示系統狀態或分析結果，並^ U 者於此對檢測流程及其系統參數做設定；。、'能振供制 控制裝置用以接收各裳置之狀態資訊並將並 裝置上:_可依照使財設定之檢測流程參數吻=介面 樣奶式瓶托盤用Μ放置包含待測樣品之試瓶， 檢測排程； 崎仃樣品之 液態清潔裝置用以清除探針内之殘留物質，以確保下― 樣品分析結果不受上次樣品殘留影響；❿ '人之 氮氣清潔裝置用以清除探針表面之殘留物質，以確保下一次 之樣品分析結果不受上次樣品殘留影響。 - 、本創作可有效減少辦絲分析㈣歸之前題理時間， 並由於其透過機械手臂完成檢測程序所需之步驛流程，因而可減 少所需之人力資源。 ' 【實施方式】 為了使貝審查委員成更進一步瞭解本創作為達成預定目的 所採取之技術、手段及姐’請參咖下㈣本創狀詳細說明 與附圖。相信本創作之目的、特徵與特點，#可由此得一深入且 具體之瞭解，然而所_式僅供參考與綱使用，並制以對本 創作加以限制。 请參閱第—圖，本創作係一種微波輔助自動化學成份分析系 M350705 =、=置:介面裝置4°、_置5。、_ 夜一織置70、《及氮氣清潔裝置抑所組成。 =之機械手魏置1Q如第二圖所示，其主要由χ軸手臂 r針主广1〇2、Ζ轴手臂㈣軸手臂1〇4、探針控制器105、 探針主峨請，丨G7爾_丨㈣護請、 以及配件固定架1〇Α所組成。其中， X轴手臂101、γ轴手臂in? 4 路一 # 02以及Z軸手臂103用以使機械手 於一維』中移動，並可透過試瓶抓取器⑽抓取樣品試瓶托 盤60上之試瓶10B以進行多種分析程序，而_手臂舰可控制 探針控制器105做上下移動； 探針107依照應用上之差異，可為微注射針頭或萃取針，當 探針m為微注射針頭時，探針控制器1〇5能控制微注射針頭之 活塞，以吸取試瓶10B β之溶液樣本；當探針1〇7為萃取針時， 探針控制器105能控制萃取針内之針纖維進入試瓶之深度，以吸 附泮取試瓶10Β於加熱後所產生之氣化樣本； 探針主體固定架106用以固定探針，不同種類之探針有不同 之k針主體固定架106，如第五圖所示之組磁性編號1()61也會不 同，此編號會被機械手臂所感應並傳送至控制裝置5〇來進行此探 針所需之檢測流程； 保護蓋109平時為關閉狀態，當使用者需要更換探針〖ο?或 探針控制器105時’僅需開啟保護蓋109即可進行更換；及 M350705 抑>9·月 配件固定架10A則用以連接腳架、樣品試瓶托盤9]?. J 0. Amendment i M350705 - Eight, new description: [New technical field] This creation department provides a "microwave-assisted automatic chemical composition analysis system", using the principle of microwave rapid heating to shorten the traditional chemical composition analysis The adsorption time required for the system extraction process, combined with the automated robot arm, can effectively reduce the time required for the inspection process, reduce labor costs, and achieve rapid detection. [Prior Art] Solid phase microextraction (SPME) is the first extraction technique proposed by Arthur and Pawliszyn in 1990, and headspace-SPME was further developed in ι 993. Solid phase microextraction concentrates volatile and non-volatile components from liquid, gaseous and solid substrates, and then directly performs gas chromatography (G〇 or liquid chromatography (HPLC) analysis' applications including chemistry, Analysis of environment, pharmaceuticals, odors, foods and natural products. This withdrawal combines the analysis of impurities, extraction, _ and groceries into a single-step and can be automated and provides lower debt than other technologies. Measure the limit and reduce the sample preparation. The objective microextraction method considers two separation steps, namely adsorption (abSGrPtiQn) and desorption (deSQrptiQn). _ Micro-extraction optimization conditions include fiber tube selection and extraction. The extraction time of the step and the ion effect, temperature and coffee, Part A literature is the earliest developed SPME fiber tube P〇1ydimethylsil〇xane (pMS) and (10) gift y (four) (PA) coating._Microextraction and headspace extraction The combined technology consists of 2_year 7 M350705 __ X Xiu et al. for the hybrid and its generation, the job and Lai, Ma Lai,: stalk: metal, pesticides, endocrine substances and metabolites in the bio-sample analysis In the past, in the adsorption process, the coil is used to heat the sample to adsorb the substance on the fiber tube. However, this process takes a long time, thus reducing the number of samples that can be detected per unit time. [New content] The main purpose of this creation is to provide a fast and automated 2 chemical composition analysis, which can be used to test the results of the automated batch-completed samples and display the results of the analysis. To achieve this, the creation It consists of Wei Wei, a microwave plus button, a chromatograph, a human-machine interface device, a control device, a township recording bottle tray, a m miscellaneous device, and a cleaning device. The device consists of a four-axis arm to move the test bottle in three-dimensional space and to control the movement of the probe, thus enabling a variety of program analysis, and a package of accessories for the ribs @纽品试瓶铺,液归杂, Nitrogen cleaning device and tripod one test bottle grabs H rib grab test bottle, probe plunger fixer month, - probe main coffee set, and - probe to absorb the test solution of the test shaft · microwave plus The device is used to heat the sample to extract the hairpin attached to the sample; the ascending suction chromatograph can be a Wei-phase chromatograph m or a chromatograph (HP[£), sample component; ^ 8 M350705 human machine The interface device is used to display the system status or the analysis result, and the U is set to the detection process and its system parameters. The 'vibration supply control device is configured to receive the status information of each of the devices and install the device. : _ can be used according to the test procedure parameters of the financial setting = interface-like milk bottle tray for placing the test bottle containing the sample to be tested, detecting the schedule; the liquid cleaning device of the rugged sample is used to remove the residual substance in the probe To ensure that the results of the sample analysis are not affected by the last sample residue; ❿ 'Human nitrogen cleaning device is used to remove the residual material on the probe surface to ensure that the next sample analysis results are not affected by the last sample residue. - This creation can effectively reduce the time required for the analysis of the silk (4), and the necessary human resources can be reduced because of the steps required to complete the inspection process through the robotic arm. [Embodiment] In order to make the Becker Review Committee further understand the techniques, means, and sisters adopted by the author for the purpose of achieving the intended purpose, please refer to the following (4) for details and drawings. I believe that the purpose, characteristics and characteristics of this creation, # can get a deep and specific understanding, but the _ formula is for reference and use only, and to limit the creation of this creation. Please refer to the first figure. This is a microwave-assisted automatic chemical composition analysis system M350705 =, = set: interface device 4 °, _ set 5. , _ night woven 70, "and nitrogen cleaning device. = The robot Wei set 1Q as shown in the second figure, which is mainly composed of the χ axis arm r needle main 〇 2, Ζ axis arm (four) axis arm 1 〇 4, probe controller 105, probe main request,丨G7 _ 丨 (4) Guard, and accessories holder 1 〇Α. Wherein, the X-axis arm 101, the γ-axis arm in? 4 way one # 02 and the Z-axis arm 103 are used to move the robot in one dimension, and the sample bottle tray 60 can be grasped through the sample bottle grabber (10). The test bottle 10B is used to perform various analysis procedures, and the _arm ship can control the probe controller 105 to move up and down; the probe 107 can be a micro injection needle or an extraction needle according to the difference in application, when the probe m is micro When the needle is injected, the probe controller 1〇5 can control the piston of the microinjection needle to absorb the solution sample of the test bottle 10Bβ; when the probe 1〇7 is the extraction needle, the probe controller 105 can control the extraction needle The needle fiber enters the depth of the test bottle to adsorb the vaporized sample produced by heating the test bottle 10 ; after heating; the probe body fixing frame 106 is used for fixing the probe, and different types of probes have different k-pin bodies fixed The frame 106, as shown in the fifth figure, will also have a different magnetic number 1 () 61, which will be sensed by the robot arm and transmitted to the control device 5 to perform the detection process required for the probe; Usually closed, when the user needs to change the probe 〖?? or When the probe controller 105 is 'only need to open the protective cover 109, it can be replaced; and M350705 suppresses> 9 months. The accessory holder 10A is used to connect the tripod and the sample test bottle tray.
〇修正丨 '補允J 潔裝置70、以及氮氣清潔裝置8〇等配件，同時可視需求增加其他 配件。 為實現快速加熱樣品之目的，本线使用微波加熱裝置2〇取 代傳統所使狀加熱、_，以加快歸品之速度，加熱所產生之 氣化樣本會吸附於探針107之針纖維上，而後於層析儀3〇之注入 孔内脫附錢行1¾成份分析，成份之分析絲會齡於人機介 面裝置40上，若有需要，也可將個人電腦連接至層析儀3〇，以供 儲存分析之結果資訊。人機介面裝置4〇除可顯示樣品成份之分析 結果外，也可顯m狀態，並允許賴在此輸續t之檢測 流程及相關參數，可奴之參數包含機械手臂裝£ 1G之運動流 程、微波加熱裝置20之加熱溫度、加熱時間及溫度維持時間與氮 氣清潔裝置80之溫度，所設定之參數將會傳送並儲存至控制裝置 50内。 控制裝置50為系統之核心控制裝置，如第六圖所示，其與人 機介面裝置40及層析儀30間可做通訊連結，以接受使用者於人 機介面裝置40上所做的設定’並將層析儀3〇之化學成份分析結 果傳送至人機介面裝置40作顯示外。其另與機械手臂裝置1〇、微 波加熱裝置20、層析儀30、及氮氣清潔裝置8〇等週邊裝置彳故控 制連結，因而可依照使用者所設定之系統參數，對週邊裝置伯文控 制’並取得各週邊裝置之狀態，做出流程決策。 M350705 丨v 為避免探針107上所殘留之物質影響下-次之化^： ‘赘卷傲$--h A送η .、》) . Ι7ϋ 从田 斤仙― -”丨-入 塔風付承祈· 、、、〇果，母做元一次之樣品分析，探 休t 107皆必須經過清潔程序以 :獅質。本系統包含兩種清潔裝置， 7主0及氮氣_置8G，當探物為微轉針稱，需透過液態 清潔裝置70進行清潔程序；而當探 田休針107為卒取針時，需透過氮 氣清潔裝置80進行清潔程序。 液態清潔裝置70如第四圖f &〇Revision 丨 'Full J cleaning device 70, and nitrogen cleaning device 8 〇 and other accessories, while adding other accessories as needed. In order to achieve rapid heating of the sample, the line uses a microwave heating device 2 instead of the conventional heating, _, to speed up the return of the product, the gasification sample produced by heating will be adsorbed on the needle fiber of the probe 107, Then, the material is desorbed in the injection hole of the chromatograph 3, and the analysis component of the component is aged on the human-machine interface device 40. If necessary, the personal computer can be connected to the chromatograph. For storing information on the results of the analysis. The human-machine interface device 4 can display the analysis result of the sample component, and can also display the m state, and allows the detection process and related parameters of the continuous t-receiving. The slave parameter includes the motion process of the mechanical arm loaded with 1G. The heating temperature, the heating time and the temperature maintenance time of the microwave heating device 20 and the temperature of the nitrogen cleaning device 80, and the set parameters are transmitted and stored in the control device 50. The control device 50 is the core control device of the system. As shown in the sixth figure, it can be communicatively coupled with the human interface device 40 and the chromatograph 30 to accept the settings made by the user on the human interface device 40. 'Transfer the chemical composition analysis result of the chromatograph 3 to the human-machine interface device 40 for display. The utility model is further connected with the peripheral device such as the robot arm device 1 , the microwave heating device 20 , the chromatograph 30 , and the nitrogen cleaning device 8 , so that the peripheral device can be controlled according to the system parameters set by the user. 'And get the status of each peripheral device, make a process decision. M350705 丨v In order to avoid the influence of the substances remaining on the probe 107 - the next time ^: '赘卷傲 $--h A send η.,》) . Ι7ϋ From Tian Jinxian ― -丨丨入塔风付承Pray, ,, and fruit, the sample analysis of the mother once, the detection of t 107 must go through the cleaning process to: lion quality. The system contains two cleaning devices, 7 main 0 and nitrogen _ 8G, when the object For the micro-needle, the cleaning procedure is performed through the liquid cleaning device 70; and when the exploration needle 107 is the stroke needle, the cleaning procedure is performed through the nitrogen cleaning device 80. The liquid cleaning device 70 is as shown in the fourth figure f &
啊不其由清潔溶液試瓶70卜廢 棄溶液試瓶702以及703清潔;5窳本、々^ '月/累及廢棄溶液試瓶托盤所組成，透過 機械手臂H)的控制，萃取針可吸取清潔溶液試瓶7〇ι内之清潔溶 液，而後將_物質連服雜_出至廢棄I，_ 到清潔之目的。 氮氣清潔裝置80如第三圖所示，其由探針注入孔·、加教 線圈802、氮氣注入孔8〇3、氮氣排出孔8()4、清洗裝置控制端子 805、及氮娜· _所組成。清洗裝置_端子與控制裝 置50直接做連結’因而控難置5()可依照朗者之設定值對加 熱線圈哪t溫度健制。料取針之針雜獻探針注入孔8〇ι 時’氮氣清潔裝置80會透過加熱線圈8{)2所產生之高溫使針頭上 之殘留物質麵，同物辭臂裝置1G❻瓶抓取_ m會施壓 於氮氣閥開關8G6，使氮氣清潔裝置8Q之氮氣注入孔咖注入高 壓氮氣，並將殘留物經由氮氣排出孔804排出，以達到清潔之目 12 M350705 θ7ι • 本系統可依據探針主體固定架106背面之磁性編號1061.做.φ : 所需之檢測流程程序。各磁性編號1061所對應之檢測流程皆可由 使用者於人機介面裝置40上做設定。若探針1〇7為微注射針頭， 則其所採用之探針主體固定架1〇6上之磁性編號1〇61可能使系統 做出如第七圖所示之微量注射檢測流程，其程序包括： 一、機械手臂10移動至樣品試瓶托盤6〇上方，並使微注射針 頭刺入樣品試瓶托盤60上之試瓶10Β内； > 二、W轴手臂1〇4向上移動，使探針控制器1〇5拉起微注射針 頭刺之活塞，以抽取試瓶内之待測溶液； 三、 機械手臂10移動至層析儀30之注入孔上方； 四、 W軸手臂1〇4向下移動使探針控制器1〇5推回微注射針頭 刺之活塞，以將待測溶液注入至層析儀30内； 五、 控制裝置50傳送控制訊號至層析儀3〇，使其開始分析待 測溶液之成份； 、主六、機械手臂移動至如第四圖所示液態清潔裝置7〇所放置之 繁/合液瓶701上方，並使微注射針頭刺入清潔溶液試瓶 内； _七W轴手臂104向上移動，使探針控制器105拉起微注射針 頌刺之活塞’以抽取清潔溶液試瓶701内之清潔溶液； 飾顧手臂至如第四騎秘紐潔裝置了^所放置之 了奋液式瓶702上方，並使微注射針頭刺入廢棄溶液試觀观 13 M350705 • 九、W軸手臂104向下移動使探針控制器105推回參^針^ :刺之活塞，以將微注射針内之清潔驗制殘⑽排出至廢棄溶 液試瓶7G2内’㈣止微注射針内之殘_影響下次之分析結果； 以及 * 十、等待層析儀30完成溶液成份储後’將分析結果顯示於 人機介面裝置40上，並回至第！步驟重做，直到樣品試瓶托盤6〇 上之试瓶10B皆完成分析。 i 若探針107為萃取針’則其所採用之探針主體固定架觸上 之磁|·生編號1061可^^系統做&如第八圖所示之頂空固相微萃取 檢測流程，其程序包括： 機械手煮10移動至樣品試瓶托盤6〇上方，並利用試瓶 抓取器108抓取樣品試瓶托盤6〇上之試瓶1〇B ; 二、機械手臂10移動至微波加熱裝置2〇上方，並將試瓶⑽ 置入微波加熱裝置20内，而後啟動微波以加熱試瓶⑽； 二、加熱完成後，W軸手臂1〇4向下移動使萃取針内之針纖 維刺入並頂空於試瓶10B内’以使試瓶1〇B内之氣化樣本吸附於 針纖維上； 四、 W軸手臂1〇4向上移動，使針纖維收回萃取針内； 五、 機械手们0移動至層析儀30上方，並使w軸手臂1〇4 向下移動’使萃取針内之规_人層析儀3G之注入孔； 六、 控制裝置50傳送啟動訊號至層析儀3〇，使針纖維上之 牛月d ϋ m 7L· 上方，並使w袖手Ah, it is not cleaned by the cleaning solution test bottle 70, waste solution test bottles 702 and 703; 5 窳, 々 ^ 'month / involving the waste solution test bottle tray, through the control of the mechanical arm H), the extraction needle can be cleaned Solution test bottle 7 ι within the cleaning solution, and then _ substances even served _ out to waste I, _ to clean the purpose. As shown in the third figure, the nitrogen cleaning device 80 is provided by a probe injection hole, a teaching coil 802, a nitrogen gas injection hole 8〇3, a nitrogen gas discharge hole 8 () 4, a cleaning device control terminal 805, and a nitrogen na. Composed of. The cleaning device _ terminal and control device 50 are directly connected. Thus, the control is difficult to set 5 (), which can be used to control the temperature of the heating coil according to the set value of the singer. When the needle is taken from the needle and the probe is injected into the hole 8 〇, the 'nitrogen cleaning device 80 will pass through the high temperature generated by the heating coil 8{) 2 to make the surface of the residual material on the needle, and the same object is used to grab the 1G bottle. m will apply pressure to the nitrogen valve switch 8G6, the nitrogen gas injection device of the nitrogen cleaning device 8Q is injected into the high pressure nitrogen gas, and the residue is discharged through the nitrogen gas discharge hole 804 to achieve the cleaning purpose. 12 M350705 θ7ι • The system can be based on the probe Magnetic number 1061 on the back of the main body holder 106. Do .φ : required inspection flow program. The detection flow corresponding to each magnetic number 1061 can be set by the user on the human interface device 40. If the probe 1〇7 is a microinjection needle, the magnetic number 1〇61 on the probe main body holder 1〇6 used by the probe may cause the system to perform the microinjection detection process as shown in the seventh figure, the procedure The utility model comprises: 1. The mechanical arm 10 is moved to the top of the sample test bottle tray 6 and the micro injection needle is pierced into the test bottle 10 Β on the sample test bottle tray 60; > 2, the W-axis arm 1〇4 moves upwards, so that The probe controller 1〇5 pulls up the plunger of the microinjection needle to extract the solution to be tested in the test bottle; 3. The robot arm 10 moves to the injection hole of the chromatograph 30; 4. The W-axis arm 1〇4 Moving downward causes the probe controller 1〇5 to push back the piston of the microinjection needle to inject the solution to be tested into the chromatograph 30; 5. The control device 50 transmits a control signal to the chromatograph 3〇, Begin to analyze the composition of the solution to be tested;, the main six, the robot arm moves to the top of the complex/liquid bottle 701 placed in the liquid cleaning device 7 as shown in the fourth figure, and the microinjection needle is inserted into the cleaning solution test bottle ; _ seven W-axis arm 104 moves up, causing the probe controller 105 to pull up the micro-injection The spurting piston 'to extract the cleaning solution in the cleaning solution test bottle 701; aligning the arm to the top of the hydrating bottle 702 placed as the fourth cycling device, and causing the micro injection needle to puncture the waste Solution Trial View 13 M350705 • Nine, the W-axis arm 104 moves downward to push the probe controller 105 back into the needle ^: the spur piston to discharge the cleaning defect (10) in the micro-injection needle to the waste solution In the bottle 7G2, '(4) the residual in the microinjection needle_ influences the next analysis result; and *10, waits for the chromatograph 30 to complete the storage of the solution component', and displays the analysis result on the human-machine interface device 40, and returns to The first! The procedure is repeated until the test bottle 10B on the sample test bottle tray 6 is completed. i If the probe 107 is an extraction needle', the probe body used by the probe holder is magnetically exposed. · The number 1061 can be used to perform the system. The headspace solid phase microextraction detection process as shown in the eighth figure. The program includes: the robot is boiled and moved to the top of the sample test tray 6 ,, and the test bottle grabber 108 is used to grab the sample test bottle tray 6 试 on the test bottle 1 〇 B; Second, the mechanical arm 10 moves to Above the microwave heating device 2, the test bottle (10) is placed in the microwave heating device 20, and then the microwave is activated to heat the test bottle (10); 2. After the heating is completed, the W-axis arm 1〇4 moves downward to make the needle in the extraction needle The fiber is pierced and topped in the test bottle 10B' so that the vaporized sample in the test bottle 1〇B is adsorbed on the needle fiber; 4. The W-axis arm 1〇4 moves upwards, so that the needle fiber is retracted into the extraction needle; The robots move to the top of the chromatograph 30 and move the w-axis arm 1〇4 downwards to make the injection hole in the extraction needle _ human chromatograph 3G; 6. The control device 50 transmits the start signal to The chromatograph is 3 〇, so that the needle fiber on the cow month d ϋ m 7L· above, and w sleeve
M350705 樣品脫附，並進行成份分析； 七、移動機械手臂ίο至氮氣清潔装置8〇 # 104向下移動使萃取針内之針纖維刺入探針注入孔_，由於氮 氣清潔裝置80内之加熱線圈會產生高溫，_可脫附針纖維 上之前物質’並透過氮氣注入孔咖所注入之高壓氮氣將殘留 物質經氮氣排出孔803排出； 八、 W軸手们〇4向上移動，使針纖維收回萃取針内； 九、 機械手臂10移動至微波加熱裝置2〇上方並利用試瓶抓 取器108抓取微波加熱裝置20内之試瓶10B ; 移動機械手臂〗〇雜以桃托削G上方，並將試瓶⑽ 放回樣品試瓶托盤6〇上； 十 料層析儀30完成成份分析後，將分析結果顯示於 機;I面裝置40上，並回至第〗步職做，直到樣品試絲盤即 上之試瓶10B皆完成分析。 15 M350705M350705 sample is desorbed and analyzed for composition; 7. Mobile robot arm ίο to nitrogen cleaning device 8〇# 104 moves downward to puncture the needle fiber in the extraction needle into the probe injection hole_, due to the heating in the nitrogen cleaning device 80 The coil will generate high temperature, _ detachable needle material on the previous material' and high pressure nitrogen gas injected through the nitrogen injection hole coffee to discharge the residual material through the nitrogen discharge hole 803; VIII, W axis hand 〇4 move upward to make the needle fiber Retract the inside of the extraction needle; 9. Move the robot arm 10 to the top of the microwave heating device 2 and use the sample bottle grabber 108 to grab the test bottle 10B in the microwave heating device 20; move the robot arm to noisy to cut the top of the G And put the test bottle (10) back into the sample test bottle tray 6; after the component chromatography 30 completes the component analysis, the analysis result is displayed on the machine; the I face device 40, and returns to the step by step, until The sample test disc 10B on the sample test disc is completed. 15 M350705
【圖式簡單說明】 .9年月補㊆ 第一圖係顯示本創作之系統架構圖。 第二圖係顯示本創作之機械手臂裝置架構圖。 第三圖係顯示本創作之氮氣清潔裝置架構圖。 第四圖係顯示本創作之液態清潔裝置架構圖。 第五圖係顯示本創作之探針主體固定架外觀圖。 第六圖係顯示本創作之系統連接示意圖。 第七圖係顯示本創作之微量注射檢測流程圖。 第八圖係顯示本創作之頂空固相微萃取檢測流程圖。 【主要元件符號說明】 10機械手臂裝置 20微波加熱裝置 30層析儀 40人機介面裝置 50控制裝置 60樣品試瓶托盤 70液態清潔裝置 80氮氣清潔裝置 101 X轴手臂 102 Y轴手臂 103 Z軸手臂 16 M350705 ： 104 W軸手臂 105探針控制器 106探針主體固定架 107探針 108試瓶抓取器 109保護蓋 10A配件固定架 10B試瓶 | 701清潔溶液試瓶 702廢棄溶液試瓶 703清潔及廢棄溶液試瓶托盤 801探針注入孔 802加熱線圈 803氮氣注入孔 804氮氣排出孔 805清洗裝置控制端子 _ 806氮氣閥開關 1061磁性編號 1062探針固定器 17[Simple description of the diagram] .9 months and seven supplements The first diagram shows the system architecture diagram of this creation. The second figure shows the architecture of the robotic device of this creation. The third figure shows the architecture of the nitrogen cleaning device of this creation. The fourth figure shows the architecture of the liquid cleaning device of this creation. The fifth figure shows the appearance of the probe body holder of the present invention. The sixth figure shows the system connection diagram of this creation. The seventh figure shows the flow chart of the microinjection detection of this creation. The eighth figure shows the flow chart of the headspace solid phase microextraction detection of this creation. [Main component symbol description] 10 robot arm device 20 microwave heating device 30 chromatograph 40 human interface device 50 control device 60 sample test bottle tray 70 liquid cleaning device 80 nitrogen cleaning device 101 X-axis arm 102 Y-axis arm 103 Z-axis Arm 16 M350705 : 104 W axis arm 105 probe controller 106 probe body holder 107 probe 108 test bottle grabber 109 protection cover 10A accessory holder 10B test bottle | 701 cleaning solution test bottle 702 waste solution test bottle 703 Cleaning and waste solution bottle tray 801 probe injection hole 802 heating coil 803 nitrogen injection hole 804 nitrogen discharge hole 805 cleaning device control terminal _ 806 nitrogen valve switch 1061 magnetic number 1062 probe holder 17