TWI839279B - Fish tank - Google Patents

Fish tank Download PDF

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TWI839279B
TWI839279B TW112128341A TW112128341A TWI839279B TW I839279 B TWI839279 B TW I839279B TW 112128341 A TW112128341 A TW 112128341A TW 112128341 A TW112128341 A TW 112128341A TW I839279 B TWI839279 B TW I839279B
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solar panel
lampshade
layer
fish tank
electrode layer
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TW112128341A
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Chinese (zh)
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孫伯彰
陳伯綸
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大陸商業成光電(深圳)有限公司
大陸商業成科技(成都)有限公司
英特盛科技股份有限公司
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Abstract

A fish tank includes a water tank, a lighting device, a first solar panel, a second solar panel, a power distribution control unit, and a storage battery. A lighting device irradiates light into the water tank. The lighting device includes a lampshade and a lamp tube. The lamp tube is arranged inside the lampshade. A first solar panel is arranged on the outer surface of the lampshade. A second solar panel is arranged on the inner surface of the lampshade. A power distribution control unit is electrically connected to the first solar panel, the second solar panel, and the lighting device. A storage battery is electrically connected to the power distribution control unit.

Description

魚缸Fish Tank

本揭示內容是關於一種魚缸,特別是關於一種具有照明裝置的魚缸。The present disclosure relates to a fish tank, and more particularly to a fish tank with a lighting device.

隨著社會城市化、科技化、人性化的發展,人們生活水平的提高,越來越多的消費者更注重生活品質,更注重家居美觀,養魚逐漸成為潮流,魚缸的使用量也隨之增加。置放於室內環境的魚缸需要能代替太陽光的燈源,燈源可以使水體透明、清晰以供觀賞,同時可以使水草進行光合作用,促進水草生長發育。With the development of urbanization, technology and humanization, people's living standards have improved, and more and more consumers pay more attention to the quality of life and the beauty of their homes. Fish farming has gradually become a trend, and the use of fish tanks has also increased. Fish tanks placed in indoor environments need a light source that can replace sunlight. The light source can make the water transparent and clear for viewing, and at the same time enable aquatic plants to photosynthesize and promote their growth and development.

然而由於魚缸的燈源需要長時間開啟,耗電量相當大。而現今全球能源短缺,各界均推廣節約能源,因此,如何開發一種能省電節能之魚缸為此產業亟需解決之問題。However, since the light source of the fish tank needs to be turned on for a long time, it consumes a lot of electricity. In the current global energy shortage, all walks of life are promoting energy conservation. Therefore, how to develop a fish tank that can save electricity and energy is an urgent problem that the industry needs to solve.

本揭示內容提供一種魚缸,包括:水箱、照明裝置、第一太陽能板、第二太陽能板、配電控制單元及蓄電電池。照明裝置,照射光線至水箱。照明裝置包括燈罩及燈管,且燈管設置於燈罩的內部。第一太陽能板,設置於燈罩的外側表面。第二太陽能板,設置於燈罩的內側表面。配電控制單元,電性連接第一太陽能板、第二太陽能板及照明裝置。蓄電電池,電性連接配電控制單元。The present disclosure provides a fish tank, including: a water tank, a lighting device, a first solar panel, a second solar panel, a power distribution control unit and a storage battery. The lighting device irradiates light to the water tank. The lighting device includes a lampshade and a lamp tube, and the lamp tube is arranged inside the lampshade. The first solar panel is arranged on the outer surface of the lampshade. The second solar panel is arranged on the inner surface of the lampshade. The power distribution control unit is electrically connected to the first solar panel, the second solar panel and the lighting device. The storage battery is electrically connected to the power distribution control unit.

在一些實施方式中,魚缸更包括外部電源,電性連接配電控制單元。In some embodiments, the fish tank further includes an external power source electrically connected to the power distribution control unit.

在一些實施方式中,第一太陽能板環繞燈罩的外側表面。In some embodiments, the first solar panel surrounds the outer surface of the lampshade.

在一些實施方式中,第二太陽能板環繞燈罩的內側表面。In some embodiments, the second solar panel surrounds the inner surface of the lampshade.

在一些實施方式中,燈罩包括圓形筒型及矩形筒型。In some embodiments, the lampshade includes a circular tube type and a rectangular tube type.

在一些實施方式中,燈管包括複數個三原色發光二極管。In some embodiments, the light tube includes a plurality of three-primary-color light-emitting diodes.

在一些實施方式中,第一太陽能板及第二太陽能板各包括鈣鈦礦太陽能板。In some embodiments, the first solar panel and the second solar panel each include a calcium-titanium solar panel.

在一些實施方式中,鈣鈦礦太陽能板包括依序排列的金屬電極層、電洞傳輸層、鈣鈦礦層、電子傳輸層及透明電極層。金屬電極層最鄰近燈罩的外側表面或內側表面。In some embodiments, the calcium-titanium solar panel includes a metal electrode layer, a hole transport layer, a calcium-titanium layer, an electron transport layer, and a transparent electrode layer arranged in sequence. The metal electrode layer is closest to the outer surface or the inner surface of the lampshade.

在一些實施方式中,鈣鈦礦太陽能板包括依序排列的金屬電極層、電子傳輸層、鈣鈦礦層、電洞傳輸層及透明電極層。金屬電極層最鄰近燈罩的外側表面或內側表面。In some embodiments, the calcium-titanium solar panel includes a metal electrode layer, an electron transport layer, a calcium-titanium layer, a hole transport layer, and a transparent electrode layer arranged in sequence. The metal electrode layer is closest to the outer surface or the inner surface of the lampshade.

在一些實施方式中,鈣鈦礦太陽能板包括依序排列的金屬電極層、電洞傳輸層、鈣鈦礦層、緻密層及透明電極層。鈣鈦礦層包括複數個金屬氧化物,且金屬電極層最鄰近燈罩的外側表面或內側表面。In some embodiments, the calcium titanate solar panel includes a metal electrode layer, a hole transport layer, a calcium titanate layer, a dense layer, and a transparent electrode layer arranged in sequence. The calcium titanate layer includes a plurality of metal oxides, and the metal electrode layer is closest to the outer surface or the inner surface of the lampshade.

應該理解的是,前述的一般性描述和下列具體說明僅僅是示例性和解釋性的,並旨在提供所要求的本揭示內容的進一步說明。It is to be understood that both the foregoing general description and the following detailed description are exemplary and explanatory only and are intended to provide further explanation of the disclosure as claimed.

以下將以圖式揭示內容本揭示內容之複數個實施方式,為明確說明起見,許多實務上的細節將在以下敘述中一併說明。然而,應瞭解到,這些實務上的細節不應用以限制本揭示內容。也就是說,在本揭示內容部分實施方式中,這些實務上的細節是非必要的。此外,為簡化圖式起見,一些習知慣用的結構與元件在圖式中將以簡單示意的方式繪示之。另外,為了便於讀者觀看,圖式中各元件的尺寸並非依實際比例繪示。The following will disclose multiple implementations of the present disclosure with drawings. For the sake of clarity, many practical details will be described together in the following description. However, it should be understood that these practical details should not be used to limit the present disclosure. In other words, in some implementations of the present disclosure, these practical details are not necessary. In addition, in order to simplify the drawings, some commonly used structures and components will be depicted in the drawings in a simple schematic manner. In addition, in order to facilitate the reader's viewing, the size of each component in the drawings is not drawn according to the actual scale.

請參見第1圖,根據本揭示內容一些實施方式的魚缸的生態循環示意圖。魚缸養殖需要維持並仿造生態的循環,燈源L發出紅光R、藍光B及綠光G。綠色水草可吸收紅光R,紅色水草可吸收藍光B。水草行光合作用供給生物氧氣,生物產生的二氧化碳再提供給水草,生物的排泄再經由微生物分解形成肥料養分給水草,達到共生共榮的循環圈。水草行光合作用需要約8到12小時的時間,且需要每公升約60流明的光照。因此,魚缸的照明裝置長時間使用,耗電量相當大。鑑於上述,需要提供一種省電節能之魚缸。以太陽能供電的魚缸是一種節能環保的方案。利用太陽能板收集太陽能轉換為電能為魚缸提供照明,可以有效地提供足夠的光照,營造出良好的生長環境,減少傳統魚缸中的市電使用,是一種符合可持續發展的綠色選擇。Please refer to Figure 1, which is a schematic diagram of the ecological cycle of a fish tank according to some implementation methods of the present disclosure. Fish tank breeding needs to maintain and imitate the ecological cycle, and the light source L emits red light R, blue light B and green light G. Green aquatic plants can absorb red light R, and red aquatic plants can absorb blue light B. Aquatic plants perform photosynthesis to supply oxygen to organisms, and the carbon dioxide produced by organisms is then provided to aquatic plants. The excretion of organisms is then decomposed by microorganisms to form fertilizer nutrients for aquatic plants, achieving a cycle of symbiosis and prosperity. It takes about 8 to 12 hours for aquatic plants to photosynthesize, and about 60 lumens of light per liter are required. Therefore, the lighting device of the fish tank consumes a lot of electricity when used for a long time. In view of the above, it is necessary to provide a fish tank that saves electricity and energy. A fish tank powered by solar energy is an energy-saving and environmentally friendly solution. Using solar panels to collect solar energy and convert it into electricity to provide lighting for fish tanks can effectively provide sufficient light, create a good growth environment, and reduce the use of city electricity in traditional fish tanks. It is a green choice that is in line with sustainable development.

本揭示內容提供了一種節能省電的魚缸。魚缸的照明裝置包括燈管及燈罩,燈罩包括雙面的太陽能板,燈罩外側的太陽能板可接收來自環境的光線(例如太陽光、室內燈源等),燈罩內側的太陽能板可回收由燈管發出的光線,太陽能板將此兩種光線轉換成電能以供照明裝置使用,達到省電節能的效果。The present disclosure provides an energy-saving and power-saving fish tank. The lighting device of the fish tank includes a lamp tube and a lampshade. The lampshade includes a double-sided solar panel. The solar panel on the outer side of the lampshade can receive light from the environment (such as sunlight, indoor light source, etc.), and the solar panel on the inner side of the lampshade can recycle the light emitted by the lamp tube. The solar panel converts these two kinds of light into electrical energy for use by the lighting device, thereby achieving the effect of saving electricity and energy.

請同時參見第2圖及第3圖,第2圖及第3圖分別為根據本揭示內容一些實施方式的魚缸的電路方塊圖及外觀立體圖。本揭示內容提供了一種魚缸100,其包括水箱110、照明裝置120、第一太陽能板130A、第二太陽能板130B、配電控制單元140及蓄電電池150。照明裝置120照射光線至水箱110。照明裝置120是位於水箱110上方。在一些其他實施方式中,可調整照明裝置120的位置,使照明裝置120的一部份或全部位於水箱110的內部,或使照明裝置120位於水箱110的側面。照明裝置120包括燈罩1201及燈管1202,且燈管1202設置於燈罩1201的內部。太陽能板130設置於燈罩1201上。第一太陽能板130A設置於燈罩1201的外側表面。第二太陽能板130B設置於燈罩1201的內側表面。配電控制單元140電性連接第一太陽能板130A、第二太陽能板130B及照明裝置120。蓄電電池150電性連接配電控制單元140。配電控制單元140用以控制照明裝置120之開關。蓄電電池150用以儲存太陽能板130所轉換之電能。 Please refer to FIG. 2 and FIG. 3 at the same time, which are respectively a circuit block diagram and an external perspective diagram of a fish tank according to some embodiments of the present disclosure. The present disclosure provides a fish tank 100, which includes a water tank 110, a lighting device 120, a first solar panel 130A, a second solar panel 130B, a power distribution control unit 140 and a storage battery 150. The lighting device 120 irradiates light to the water tank 110. The lighting device 120 is located above the water tank 110. In some other embodiments, the position of the lighting device 120 can be adjusted so that a part or all of the lighting device 120 is located inside the water tank 110, or the lighting device 120 is located on the side of the water tank 110. The lighting device 120 includes a lampshade 1201 and a lamp tube 1202, and the lamp tube 1202 is disposed inside the lampshade 1201. The solar panel 130 is disposed on the lampshade 1201. The first solar panel 130A is disposed on the outer surface of the lampshade 1201. The second solar panel 130B is disposed on the inner surface of the lampshade 1201. The power distribution control unit 140 is electrically connected to the first solar panel 130A, the second solar panel 130B and the lighting device 120. The storage battery 150 is electrically connected to the power distribution control unit 140. The power distribution control unit 140 is used to control the switch of the lighting device 120. The storage battery 150 is used to store the electric energy converted by the solar panel 130.

在一些實施方式中,魚缸100更包括外部電源160電性連接配電控制單元140。配電控制單元140可調配外部電源160(市電)或是採用蓄電電池150之電能來進行照明裝置120的供電。在一些實施方式中,燈管1202包括複數個三原色發光二極管。複數個三原色發光二極管可提供色彩豐富的光線同時可具有省電效果。在一些實施方式中,可使用其他類型的燈管。在一些實施方式中,魚缸100更包括其他元件,例如溫度調節器、過濾泵等,由配電控制單元140進行供電。應理解,第3圖所繪示的各個元件的位置及形狀僅為示意性並非限制性的。 In some embodiments, the fish tank 100 further includes an external power source 160 electrically connected to the power distribution control unit 140. The power distribution control unit 140 can allocate the external power source 160 (mains power) or use the power of the storage battery 150 to power the lighting device 120. In some embodiments, the lamp tube 1202 includes a plurality of three-primary color light-emitting diodes. A plurality of three-primary color light-emitting diodes can provide colorful light and have a power saving effect. In some embodiments, other types of lamp tubes can be used. In some embodiments, the fish tank 100 further includes other components, such as a thermostat, a filter pump, etc., which are powered by the power distribution control unit 140. It should be understood that the position and shape of each component shown in Figure 3 are only schematic and non-restrictive.

值得注意的是,設置於燈罩1201的外側表面的第一太陽能板130A可以接收來自環境的光線,設置於燈罩1201的內側表面的第二太陽能板130B可以接收來自燈管1202的光線。換言之,第二太陽能板130B可以回收由照明裝置發出的光線,再次轉換成電能,達到循環利用的效果。 It is worth noting that the first solar panel 130A disposed on the outer surface of the lampshade 1201 can receive light from the environment, and the second solar panel 130B disposed on the inner surface of the lampshade 1201 can receive light from the lamp tube 1202. In other words, the second solar panel 130B can recycle the light emitted by the lighting device and convert it into electrical energy again, thereby achieving a recycling effect.

在一些實施方式中,燈罩1201包括圓形筒型及矩形筒型。應理解,第4圖及第5圖所示的燈罩1201形狀及尺寸僅為示意性並非限制性的,可使用任何其他形狀及尺寸的燈罩。In some embodiments, the lampshade 1201 includes a circular tube type and a rectangular tube type. It should be understood that the shape and size of the lampshade 1201 shown in Figures 4 and 5 are only illustrative and non-restrictive, and lampshades of any other shapes and sizes can be used.

請參見第4圖,根據本揭示內容一些實施方式的圓形筒型燈罩的外觀立體圖。在一些實施方式中,第一太陽能板130A環繞燈罩1201的外側表面。在一些實施方式中,第一太陽能板130A部分覆蓋燈罩1201的外側表面。在另一些實施方式中,第一太陽能板130A完整包覆燈罩1201的外側表面。換句話說,第一太陽能板130A覆蓋燈罩1201的外側的側面和頂面。Please refer to FIG. 4, which is a perspective view of a cylindrical lampshade according to some embodiments of the present disclosure. In some embodiments, the first solar panel 130A surrounds the outer surface of the lampshade 1201. In some embodiments, the first solar panel 130A partially covers the outer surface of the lampshade 1201. In other embodiments, the first solar panel 130A completely covers the outer surface of the lampshade 1201. In other words, the first solar panel 130A covers the outer side and top of the lampshade 1201.

請繼續參見第4圖,在一些實施方式中,第二太陽能板130B環繞燈罩1201的內側表面。在一些實施方式中,第二太陽能板130B部分覆蓋燈罩1201的內側表面。在另一些實施方式中,第二太陽能板130B完整包覆燈罩1201的內側表面。換句話說,第二太陽能板130B覆蓋燈罩1201的內側的側面和頂面。Please continue to refer to FIG. 4 . In some embodiments, the second solar panel 130B surrounds the inner surface of the lampshade 1201. In some embodiments, the second solar panel 130B partially covers the inner surface of the lampshade 1201. In other embodiments, the second solar panel 130B completely covers the inner surface of the lampshade 1201. In other words, the second solar panel 130B covers the inner side and top surface of the lampshade 1201.

請參見第5圖,根據本揭示內容一些實施方式的矩形筒型燈罩的外觀立體圖。在一些實施方式中,第一太陽能板130A環繞燈罩1201的外側表面。換句話說,第一太陽能板130A覆蓋燈罩1201的外側的四個側面。在另一些實施方式中,第一太陽能板130A部分覆蓋燈罩1201的外側表面。換句話說,第一太陽能板130A覆蓋燈罩1201的外側的一個或多個面。在另一些實施方式中,多個第一太陽能板130A分別部分覆蓋燈罩1201的外側的一個或多個面,且多個第一太陽能板130A彼此之間留有空隙並未直接接觸。在另一些實施方式中,第一太陽能板130A完整包覆燈罩1201的外側表面。在另一些實施方式中,多個第一太陽能板130A覆蓋燈罩1201的外側的四個側面及頂面且多個第一太陽能板130A彼此之間直接接觸並未留有空隙。Please refer to FIG. 5 , which is a perspective view of a rectangular cylindrical lampshade according to some embodiments of the present disclosure. In some embodiments, the first solar panel 130A surrounds the outer surface of the lampshade 1201. In other words, the first solar panel 130A covers four outer sides of the lampshade 1201. In other embodiments, the first solar panel 130A partially covers the outer surface of the lampshade 1201. In other words, the first solar panel 130A covers one or more outer surfaces of the lampshade 1201. In other embodiments, the plurality of first solar panels 130A partially cover one or more surfaces of the outer side of the lampshade 1201, and the plurality of first solar panels 130A are not in direct contact with each other with gaps left between them. In other embodiments, the first solar panels 130A completely cover the outer surface of the lampshade 1201. In other embodiments, the plurality of first solar panels 130A cover the four outer side surfaces and the top surface of the lampshade 1201, and the plurality of first solar panels 130A are in direct contact with each other without gaps left between them.

請繼續參見第5圖,在一些實施方式中,第二太陽能板130B環繞燈罩1201的內側表面。換句話說,第二太陽能板130B覆蓋燈罩1201的內側的四個側面。在另一些實施方式中,第二太陽能板130B部分覆蓋燈罩1201的內側表面。換句話說,第二太陽能板130B覆蓋燈罩1201的內側的一個或多個面。在另一些實施方式中,多個第二太陽能板130B分別部分覆蓋燈罩1201的內側的一個或多個面,且多個第二太陽能板130B彼此之間留有空隙並未直接接觸。在另一些實施方式中,第二太陽能板130B完整包覆燈罩1201的內側表面。換句話說,第二太陽能板130B覆蓋燈罩1201的內側的四個側面及頂面且多個第二太陽能板130B彼此之間直接接觸並未留有空隙。值得注意的是,矩形筒型燈罩可設置的太陽能板130的面積較廣,所以產電效率較高。Please continue to refer to FIG. 5. In some embodiments, the second solar panel 130B surrounds the inner surface of the lampshade 1201. In other words, the second solar panel 130B covers the four inner side surfaces of the lampshade 1201. In other embodiments, the second solar panel 130B partially covers the inner surface of the lampshade 1201. In other words, the second solar panel 130B covers one or more inner surfaces of the lampshade 1201. In other embodiments, multiple second solar panels 130B partially cover one or more inner surfaces of the lampshade 1201, and gaps are left between the multiple second solar panels 130B and they are not in direct contact with each other. In other embodiments, the second solar panel 130B completely covers the inner surface of the lampshade 1201. In other words, the second solar panel 130B covers the four inner side surfaces and the top surface of the lampshade 1201 and the plurality of second solar panels 130B are in direct contact with each other without leaving any gaps. It is worth noting that the rectangular cylindrical lampshade can accommodate a wider area of solar panels 130, so the power generation efficiency is higher.

請參見第6圖、第7圖及第8圖。在一些實施方式中,太陽能板130可包括非晶矽、微晶矽、硫化鎘、碲化鎘、銅銦硒化物、銅銦鎵硒化物、染料敏化電單元及有機導電高分子或其他合適的透明薄膜太陽能板。在一些實施方式中,第一太陽能板130A及第二太陽能板130B各包括鈣鈦礦太陽能板。鈣鈦礦太陽能電池(perovskite solar cell,PSC)具有高轉換效率、可撓曲、高穩定性及低製造成本的優點,並且針對室內光源或可見光光源的波長有較高的吸收轉換效率。鈣鈦礦太陽能板的結構可包括平板式(planar)結構、反式(inverted)結構或介孔式(mesoporous)結構,依序對應第6圖、第7圖及第8圖所繪示的鈣鈦礦太陽能板結構。Please refer to FIG. 6, FIG. 7 and FIG. 8. In some embodiments, the solar panel 130 may include amorphous silicon, microcrystalline silicon, cadmium sulfide, cadmium telluride, copper indium selenide, copper indium gallium selenide, dye-sensitized cells and organic conductive polymers or other suitable transparent thin film solar panels. In some embodiments, the first solar panel 130A and the second solar panel 130B each include a perovskite solar panel. The perovskite solar cell (PSC) has the advantages of high conversion efficiency, flexibility, high stability and low manufacturing cost, and has a higher absorption conversion efficiency for the wavelength of indoor light source or visible light source. The structure of the calcium-titanium solar panel may include a planar structure, an inverted structure or a mesoporous structure, which correspond to the calcium-titanium solar panel structures shown in FIG. 6 , FIG. 7 and FIG. 8 , respectively.

請參見第6圖,根據本揭示內容一些實施方式的鈣鈦礦太陽能板的平面式結構剖面圖。太陽能板130設置於燈罩1201上。第一太陽能板130A設置於燈罩1201的外側表面。第二太陽能板130B設置於燈罩1201的內側表面。第一太陽能板130A及第二太陽能板130B各包括平面式結構之鈣鈦礦太陽能板,鈣鈦礦太陽能板包括依序排列的金屬電極層ME、電洞傳輸層HTL、鈣鈦礦層PER、電子傳輸層ETL及透明電極層TE。金屬電極層ME最鄰近燈罩1201的外側表面或內側表面。值得注意的是,平面式結構之鈣鈦礦太陽能電池具有較高的光電轉換效率。Please refer to FIG. 6 for a planar structural cross-sectional view of a calcium titanate solar panel according to some embodiments of the present disclosure. A solar panel 130 is disposed on a lampshade 1201. A first solar panel 130A is disposed on the outer surface of the lampshade 1201. A second solar panel 130B is disposed on the inner surface of the lampshade 1201. The first solar panel 130A and the second solar panel 130B each include a calcium titanate solar panel of a planar structure, and the calcium titanate solar panel includes a metal electrode layer ME, a hole transport layer HTL, a calcium titanate layer PER, an electron transport layer ETL, and a transparent electrode layer TE arranged in sequence. The metal electrode layer ME is closest to the outer surface or the inner surface of the lampshade 1201. It is worth noting that the planar structured calcium-titanium solar cell has a higher photoelectric conversion efficiency.

透明電極層TE(transparent electrode)係作為入光面,可使用穿透度高的導電材料,LUMO(Lowest Unoccupied Molecular Orbital,最低未佔有分子軌道)能階需與電子傳輸層ETL匹配。透明電極層TE的材料可包括透明導電薄膜,例如氧化銦錫(ITO)、氧化銦鋅(IZO)、摻鋁之氧化鋅(AZO)及摻氟之二氧化錫(FTO)或其組合但不限於此。在一些實施方式中,透明電極層TE可藉由旋轉塗佈、縫模塗佈、濺鍍、蒸鍍或其他合適的製程形成。The transparent electrode layer TE (transparent electrode) serves as the light incident surface, and a conductive material with high transmittance can be used. The LUMO (Lowest Unoccupied Molecular Orbital) energy level needs to match the electron transport layer ETL. The material of the transparent electrode layer TE may include a transparent conductive film, such as indium tin oxide (ITO), indium zinc oxide (IZO), aluminum-doped zinc oxide (AZO) and fluorine-doped tin dioxide (FTO) or a combination thereof but is not limited thereto. In some embodiments, the transparent electrode layer TE can be formed by spin coating, slot die coating, sputtering, evaporation or other suitable processes.

電子傳輸層ETL(electron transmission layer)係用以促進電子傳輸並阻止電子電洞再複合。可使用高電子遷移率的材料,電子傳輸層ETL能階需與鈣鈦礦層PER匹配。電子傳輸層ETL的材料可包括例如富勒烯、過渡金屬氧化物或其組合但不限於此。過渡金屬氧化物可包括例如二氧化鈦、氧化鋅、氧化銦、二氧化錫或其組合但不限於此。電子傳輸層ETL可藉由旋轉塗佈、縫模塗佈、濺鍍、蒸鍍或其他合適的製程形成。The electron transmission layer (ETL) is used to promote electron transport and prevent electron-hole recombination. Materials with high electron mobility can be used, and the energy level of the electron transmission layer (ETL) needs to match the PER of the calcium titanate layer. The material of the electron transmission layer (ETL) may include, for example, fullerene, transition metal oxide, or a combination thereof, but is not limited thereto. The transition metal oxide may include, for example, titanium dioxide, zinc oxide, indium oxide, tin dioxide, or a combination thereof, but is not limited thereto. The electron transmission layer (ETL) may be formed by spin coating, slot die coating, sputtering, evaporation, or other suitable processes.

鈣鈦礦層PER(perovskite layer)係作為吸光層,用以吸收光源並且產生電子電洞對。鈣鈦礦層PER的材料可包括ABX 3結構,其中A是陽離子,包括例如甲基銨、甲脒、銫或銣,B是陽離子,包括例如鉛或錫, X是陰離子,包括鹵素,例如碘離子、溴離子、氯離子或其組合。在一些實施方式中,鈣鈦礦層PER的材料可包括例如CH 3NH 3PbI 3、CH 3NH 3PbBr 3、CH 3NH 3PbCl 3、CH 3NH 3PbI 2Br、CH 3NH 3PbI 2Cl、CH 3NH 3PbIBr 2、CH 3NH 3PbICl 2、CH 3NH 3SnI 3及HC(NH 2) 2PbI 3或其組合但不限於此。在一些實施方式中,鈣鈦礦層PER的材料為甲基銨碘化鉛(CH 3NH 3PbI 3,又稱為MAPbI 3)。在一些實施方式中,鈣鈦礦層PER可藉由旋轉塗佈(spin coating)、縫模塗佈(slot die coating)或其他合適的製程形成。在一些實施方式中,可使用旋轉塗佈快速旋轉基板將滴落中心的溶液均勻外擴至外圈,藉此形成整面式的鈣鈦礦層PER。在一些實施方式中,可使用縫模塗佈將溶液藉由線型噴嘴進行單一方向的塗佈,藉此形成整面式鈣鈦礦層PER。值得注意的是,縫模塗佈製程可形成較大尺寸的鈣鈦礦層PER。 The perovskite layer PER (perovskite layer) is used as a light absorbing layer to absorb light and generate electron-hole pairs. The material of the perovskite layer PER may include an ABX 3 structure, wherein A is a cation, including, for example, methylammonium, formamidine, cesium or ammonium, B is a cation, including, for example, lead or tin, and X is an anion, including a halogen, such as an iodine ion, a bromine ion, a chlorine ion or a combination thereof. In some embodiments, the material of the calcium titanate layer PER may include, for example, CH 3 NH 3 PbI 3 , CH 3 NH 3 PbBr 3 , CH 3 NH 3 PbCl 3 , CH 3 NH 3 PbI 2 Br, CH 3 NH 3 PbI 2 Cl, CH 3 NH 3 PbIBr 2 , CH 3 NH 3 PbICl 2 , CH 3 NH 3 SnI 3 , and HC(NH 2 ) 2 PbI 3 , or a combination thereof, but is not limited thereto. In some embodiments, the material of the calcium titanate layer PER is methylammonium lead iodide (CH 3 NH 3 PbI 3 , also referred to as MAPbI 3 ). In some embodiments, the calcite-titanium layer PER can be formed by spin coating, slot die coating or other suitable processes. In some embodiments, spin coating can be used to quickly rotate the substrate to evenly expand the solution in the center of the drop to the outer circle, thereby forming a full-surface calcite-titanium layer PER. In some embodiments, slot die coating can be used to coat the solution in a single direction through a linear nozzle, thereby forming a full-surface calcite-titanium layer PER. It is worth noting that the slot die coating process can form a larger-sized calcite-titanium layer PER.

電洞傳輸層HTL(hole transmission layer)係用以阻擋電子穿越,阻擋水氧侵入鈣鈦礦層。HOMO能階需與鈣鈦礦層PER的匹配。電洞傳輸層HTL的材料可包括例如PEDOT(poly(3,4-ethylene dioxythiophene))、PSS(poly styrene sulfonate)或其組合但不限於此。在一些實施方式中,電洞傳輸層HTL可藉由旋轉塗佈製程、縫模塗佈或其他合適的製程製程形成。The hole transport layer (HTL) is used to block the passage of electrons and prevent water and oxygen from invading the calcium titanate layer. The HOMO energy level needs to match the PER of the calcium titanate layer. The material of the hole transport layer (HTL) may include, for example, PEDOT (poly (3,4-ethylene dioxythiophene)), PSS (poly styrene sulfonate) or a combination thereof but is not limited thereto. In some embodiments, the hole transport layer (HTL) may be formed by a spin coating process, a slot die coating process or other suitable processes.

金屬電極層ME(metal electrode)係用以使電子注入。HOMO能階需與電洞傳輸層HTL匹配。金屬電極層ME的材料可包括導電材料但不限於此。在一些實施方式中,金屬電極層ME的材料為Ag。在一些實施方式中,金屬電極層ME可藉由濺鍍、蒸鍍或其他合適的製程形成。The metal electrode layer ME is used for electron injection. The HOMO energy level needs to match the hole transport layer HTL. The material of the metal electrode layer ME may include a conductive material but is not limited thereto. In some embodiments, the material of the metal electrode layer ME is Ag. In some embodiments, the metal electrode layer ME may be formed by sputtering, evaporation or other suitable processes.

在一些實施方式中,第一太陽能板130A及第二太陽能板130B可以直接形成在燈罩1201的外側表面及內側表面。換句話說,金屬電極層ME與燈罩1201直接接觸。在另一些實施方式中,第一太陽能板130A及第二太陽能板130B可以先形成於軟性基板(例如PET)上,再接合(例如黏合)至燈罩1201的外側表面及內側表面。換句話說,軟性基板位於金屬電極層ME與燈罩1201之間,金屬電極層ME與燈罩1201並未直接接觸。在一些實施方式中,鈣鈦礦太陽能板更包括透明保護層,用以保護透明電極層TE免於毀損。In some embodiments, the first solar panel 130A and the second solar panel 130B may be directly formed on the outer surface and the inner surface of the lampshade 1201. In other words, the metal electrode layer ME is in direct contact with the lampshade 1201. In other embodiments, the first solar panel 130A and the second solar panel 130B may be first formed on a flexible substrate (e.g., PET) and then bonded (e.g., adhered) to the outer surface and the inner surface of the lampshade 1201. In other words, the flexible substrate is located between the metal electrode layer ME and the lampshade 1201, and the metal electrode layer ME is not in direct contact with the lampshade 1201. In some embodiments, the calcium-titanium solar panel further includes a transparent protective layer to protect the transparent electrode layer TE from damage.

請參見第7圖,根據本揭示內容一些實施方式的鈣鈦礦太陽能板的反式結構剖面圖。太陽能板230設置於燈罩2201上。第一太陽能板230A設置於燈罩2201的外側表面。第二太陽能板230B設置於燈罩2201的內側表面。第一太陽能板230A及第二太陽能板230B各包括反式結構之鈣鈦礦太陽能板。鈣鈦礦太陽能板包括依序排列的金屬電極層ME、電子傳輸層ETL、鈣鈦礦層PER、電洞傳輸層HTL及透明電極層TE。金屬電極層ME最鄰近燈罩2201的外側表面或內側表面。金屬電極層ME、電洞傳輸層HTL、鈣鈦礦層PER及透明電極層TE的材料與形成方法可參照前文針對第6圖所述的各層的材料與形成方法。值得注意的是,反式結構之鈣鈦礦太陽能電池因製程溫度與電性考量皆較有好的優勢。Please refer to FIG. 7, which is a cross-sectional view of a trans-structured calcium titanite solar panel according to some embodiments of the present disclosure. A solar panel 230 is disposed on a lampshade 2201. A first solar panel 230A is disposed on the outer surface of the lampshade 2201. A second solar panel 230B is disposed on the inner surface of the lampshade 2201. The first solar panel 230A and the second solar panel 230B each include a calcium titanite solar panel of a trans-structure. The calcium titanite solar panel includes a metal electrode layer ME, an electron transport layer ETL, a calcium titanite layer PER, a hole transport layer HTL, and a transparent electrode layer TE arranged in sequence. The metal electrode layer ME is closest to the outer surface or inner surface of the lampshade 2201. The materials and formation methods of the metal electrode layer ME, the hole transport layer HTL, the calcium titanate layer PER and the transparent electrode layer TE can refer to the materials and formation methods of each layer described in the previous text with respect to FIG. 6. It is worth noting that the calcium titanate solar cell with a trans-structure has better advantages in terms of process temperature and electrical properties.

請參見第8圖,根據本揭示內容一些實施方式的鈣鈦礦太陽能板的結構剖面圖。太陽能板330設置於燈罩3201上。第一太陽能板330A設置於燈罩3201的外側表面。第二太陽能板330B設置於燈罩3201的內側表面。第一太陽能板330A及第二太陽能板330B各包括介孔式結構之鈣鈦礦太陽能板。鈣鈦礦太陽能板包括依序排列的金屬電極層ME、電洞傳輸層HTL、鈣鈦礦層PER、緻密層HBL及透明電極層TE。鈣鈦礦層PER包括複數個金屬氧化物MO。金屬電極層ME最鄰近燈罩3201的外側表面或內側表面。金屬電極層ME、電洞傳輸層HTL、鈣鈦礦層PER及透明電極層TE的材料與形成方法可參照前文針對第6圖所述的各層的材料與形成方法。第8圖中,緻密層HBL作為電洞阻擋層(hole blocking layer)係用以阻擋來自鈣鈦礦層PER中的電洞,避免電荷複合。在一些實施方式中,緻密層HBL的材料可包括金屬氧化物,例如二氧化鈦、二氧化錫、氧化鋅或其組合但不限於此。在一些實施方式中,緻密層HBL可藉由旋轉塗佈、濺鍍、原子層沉積、化學浴沉積或其他合適的製程形成。金屬氧化物MO填充於鈣鈦礦層PER中作為支架支撐鈣鈦礦層PER。金屬氧化物MO的材料可包括二氧化鈦、二氧化矽、氧化鋅、三氧化二鋁、氧化鋯或其組合但不限於此。值得注意的是,介孔結構之鈣鈦礦太陽能電池,電子傳輸層ETL與鈣鈦礦層PER充分接觸,可實現更快的電子傳輸。Please refer to FIG. 8 for a cross-sectional view of a calcium titanate solar panel according to some embodiments of the present disclosure. A solar panel 330 is disposed on a lampshade 3201. A first solar panel 330A is disposed on the outer surface of the lampshade 3201. A second solar panel 330B is disposed on the inner surface of the lampshade 3201. The first solar panel 330A and the second solar panel 330B each include a calcium titanate solar panel with a mesoporous structure. The calcium titanate solar panel includes a metal electrode layer ME, a hole transport layer HTL, a calcium titanate layer PER, a dense layer HBL, and a transparent electrode layer TE arranged in sequence. The calcite layer PER includes a plurality of metal oxides MO. The metal electrode layer ME is closest to the outer surface or the inner surface of the lampshade 3201. The materials and formation methods of the metal electrode layer ME, the hole transport layer HTL, the calcite layer PER and the transparent electrode layer TE can refer to the materials and formation methods of each layer described in the previous text with respect to FIG. 6. In FIG. 8, the dense layer HBL is used as a hole blocking layer to block holes from the calcite layer PER to avoid charge recombination. In some embodiments, the material of the dense layer HBL may include metal oxides, such as titanium dioxide, tin dioxide, zinc oxide or a combination thereof but is not limited thereto. In some embodiments, the dense layer HBL can be formed by spin coating, sputtering, atomic layer deposition, chemical bath deposition or other suitable processes. Metal oxide MO is filled in the calcium titanate layer PER as a bracket to support the calcium titanate layer PER. The material of the metal oxide MO may include titanium dioxide, silicon dioxide, zinc oxide, aluminum oxide, zirconium oxide or a combination thereof but is not limited thereto. It is worth noting that in the mesoporous calcium titanate solar cell, the electron transport layer ETL is in full contact with the calcium titanate layer PER, which can achieve faster electron transmission.

應理解,上述第6圖、第7圖及第8圖中的鈣鈦礦太陽能板的結構皆係是其中心的燈罩1201為軸,兩側具有對稱設置的多層結構。然而,本揭示內容所示的第6圖、第7圖及第8圖僅為示意性並非限制性的。設置於燈罩1201外側的第一太陽能板130A與設置於燈罩1201內側的第二太陽能板130B可各自包括相同或不同結構的鈣鈦礦太陽能板。例如,在一些實施方式中,燈罩1201外側與燈罩1201內側皆設置如第6圖所示的平面式結構的第一太陽能板130A及第二太陽能板130B。在另一些實施方式中,燈罩1201外側設置如第6圖所示的平面式結構的第一太陽能板130A,燈罩1201內側設置如第7圖所示的反式結構的第二太陽能板230B。在另一些實施方式中,燈罩1201外側設置如第6圖所示的平面式結構的第一太陽能板130A,燈罩1201內側設置如第8圖所示的介孔式結構的第二太陽能板330B。 It should be understood that the structures of the calcium-titanium solar panels in the above-mentioned Figures 6, 7 and 8 are all based on the lampshade 1201 at the center as the axis, and the two sides have a multi-layer structure symmetrically arranged. However, Figures 6, 7 and 8 shown in the present disclosure are only schematic and non-restrictive. The first solar panel 130A disposed on the outer side of the lampshade 1201 and the second solar panel 130B disposed on the inner side of the lampshade 1201 can each include calcium-titanium solar panels of the same or different structures. For example, in some embodiments, the first solar panel 130A and the second solar panel 130B of the planar structure shown in Figure 6 are both disposed on the outer side and the inner side of the lampshade 1201. In other embodiments, a first solar panel 130A with a planar structure as shown in FIG. 6 is disposed on the outer side of the lampshade 1201, and a second solar panel 230B with a transverse structure as shown in FIG. 7 is disposed on the inner side of the lampshade 1201. In other embodiments, a first solar panel 130A with a planar structure as shown in FIG. 6 is disposed on the outer side of the lampshade 1201, and a second solar panel 330B with a mesoporous structure as shown in FIG. 8 is disposed on the inner side of the lampshade 1201.

綜合上述,本揭示內容提供了一種節能省電的魚缸。魚缸設置有太陽能板,利用太陽能板收集太陽能轉換為電能為魚缸提供照明。照明裝置包括燈罩及燈管。燈罩包括雙面的太陽能板,燈罩外側的太陽能板可接收來自環境的光線,燈罩內側的太陽能板可回收由燈管發出的光線,太陽能板將此兩種光線轉換成電能以供照明裝置使用,達到省電節能的效果。 In summary, the present disclosure provides an energy-saving and power-saving fish tank. The fish tank is provided with a solar panel, which collects solar energy and converts it into electrical energy to provide lighting for the fish tank. The lighting device includes a lampshade and a lamp tube. The lampshade includes a double-sided solar panel. The solar panel on the outer side of the lampshade can receive light from the environment, and the solar panel on the inner side of the lampshade can recycle the light emitted by the lamp tube. The solar panel converts these two kinds of light into electrical energy for use in the lighting device, thereby achieving the effect of saving electricity and energy.

儘管已經參考各種實施方式相當詳細地描述了本揭示內容,但是亦可能有其他實施方式。因此,所附申請專利範圍的精神和範圍不應限於此處包含的實施方式的描述。Although the present disclosure has been described in considerable detail with reference to various embodiments, other embodiments are possible. Therefore, the spirit and scope of the appended claims should not be limited to the description of the embodiments contained herein.

對於所屬技術領域人員來說,顯而易見的是,在不脫離本揭示內容的範圍或精神的情況下,可以對本揭示內容的結構進行各種修改和變化。鑑於前述內容,本揭示內容意圖涵蓋落入所附權利要求範圍內的本揭示內容的修改和變化。It is obvious to those skilled in the art that various modifications and variations can be made to the structure of the disclosure without departing from the scope or spirit of the disclosure. In view of the foregoing, the disclosure is intended to cover modifications and variations of the disclosure that fall within the scope of the appended claims.

L:燈源 R:紅光 B:藍光 G:綠光 100:魚缸 110:水箱 120:照明裝置 1201:燈罩 1202:燈管 130:太陽能板 130A:第一太陽能板 130B:第二太陽能板 140:配電控制單元 150:蓄電電池 160:外部電源 2201:燈罩 230:太陽能板 230A:第一太陽能板 230B:第二太陽能板 3201:燈罩 330:太陽能板 330A:第一太陽能板 330B:第二太陽能板 HTL:電洞傳輸層 ETL:電子傳輸層 TE:透明電極層 ME:金屬電極層 PER:鈣鈦礦層 HBL:緻密層 MO:金屬氧化物 L: Light source R: Red light B: Blue light G: Green light 100: Fish tank 110: Water tank 120: Lighting device 1201: Lampshade 1202: Lamp tube 130: Solar panel 130A: First solar panel 130B: Second solar panel 140: Power distribution control unit 150: Storage battery 160: External power supply 2201: Lampshade 230: Solar panel 230A: First solar panel 230B: Second solar panel 3201: Lampshade 330: Solar panel 330A: First solar panel 330B: Second solar panel HTL: Hole transport layer ETL: Electron transport layer TE: Transparent electrode layer ME: Metal electrode layer PER: Calcium-titanium layer HBL: Dense layer MO: Metal oxide

藉由閱讀以下實施方式的詳細描述,並參照附圖,可以更全面地理解本揭示內容。 第1圖繪示本揭示內容一些實施方式的魚缸的生態循環示意圖。 第2圖繪示本揭示內容一些實施方式的魚缸的電路方塊圖。 第3圖繪示本揭示內容一些實施方式的魚缸的外觀立體圖。 第4圖繪示本揭示內容一些實施方式的圓形筒型燈罩的外觀立體圖。 第5圖繪示本揭示內容一些實施方式的矩形筒型燈罩的外觀立體圖。 第6圖繪示本揭示內容一些實施方式的平面式結構鈣鈦礦太陽能板的剖面圖。 第7圖繪示本揭示內容一些實施方式的反式結構鈣鈦礦太陽能板的剖面圖。 第8圖繪示本揭示內容一些實施方式的介孔式結構鈣鈦礦太陽能板的剖面圖。 By reading the detailed description of the following embodiments and referring to the attached figures, the present disclosure can be more fully understood. FIG. 1 shows a schematic diagram of the ecological cycle of a fish tank in some embodiments of the present disclosure. FIG. 2 shows a circuit block diagram of a fish tank in some embodiments of the present disclosure. FIG. 3 shows a three-dimensional view of the appearance of a fish tank in some embodiments of the present disclosure. FIG. 4 shows a three-dimensional view of the appearance of a circular tube-shaped lampshade in some embodiments of the present disclosure. FIG. 5 shows a three-dimensional view of the appearance of a rectangular tube-shaped lampshade in some embodiments of the present disclosure. FIG. 6 shows a cross-sectional view of a planar structured calcium-titanium solar panel in some embodiments of the present disclosure. FIG. 7 shows a cross-sectional view of a trans-structured calcium-titanium solar panel in some embodiments of the present disclosure. FIG. 8 shows a cross-sectional view of a mesoporous calcium-titanium solar panel according to some embodiments of the present disclosure.

國內寄存資訊(請依寄存機構、日期、號碼順序註記) 無 國外寄存資訊(請依寄存國家、機構、日期、號碼順序註記) 無 Domestic storage information (please note in the order of storage institution, date, and number) None Foreign storage information (please note in the order of storage country, institution, date, and number) None

100:魚缸 100: Fish tank

110:水箱 110: Water tank

120:照明裝置 120: Lighting device

1201:燈罩 1201: Lampshade

1202:燈管 1202: Tube

130:太陽能板 130: Solar panels

130A:第一太陽能板 130A: The first solar panel

130B:第二太陽能板 130B: Second solar panel

140:配電控制單元 140: Power distribution control unit

150:蓄電電池 150: Storage battery

160:外部電源 160: External power supply

Claims (10)

一種魚缸,包括: 一水箱; 一照明裝置,照射一光線至該水箱,其中該照明裝置包括一燈罩及一燈管,且該燈管設置於該燈罩的內部; 一第一太陽能板,設置於該燈罩的一外側表面; 一第二太陽能板,設置於該燈罩的一內側表面; 一配電控制單元,電性連接該第一太陽能板、該第二太陽能板及該照明裝置;以及 一蓄電電池,電性連接該配電控制單元。 A fish tank, comprising: a water tank; a lighting device, irradiating a light to the water tank, wherein the lighting device comprises a lampshade and a lamp tube, and the lamp tube is arranged inside the lampshade; a first solar panel, arranged on an outer surface of the lampshade; a second solar panel, arranged on an inner surface of the lampshade; a power distribution control unit, electrically connected to the first solar panel, the second solar panel and the lighting device; and a storage battery, electrically connected to the power distribution control unit. 如請求項1所述之魚缸,更包括一外部電源,電性連接該配電控制單元。The fish tank as described in claim 1 further includes an external power source electrically connected to the power distribution control unit. 如請求項1所述之魚缸,其中該第一太陽能板環繞該燈罩的該外側表面。A fish tank as described in claim 1, wherein the first solar panel surrounds the outer surface of the lampshade. 如請求項1所述之魚缸,其中該第二太陽能板環繞該燈罩的該內側表面。A fish tank as described in claim 1, wherein the second solar panel surrounds the inner surface of the lampshade. 如請求項1所述之魚缸,其中該燈罩包括圓形筒型及矩形筒型。A fish tank as described in claim 1, wherein the lampshade includes a circular cylindrical shape and a rectangular cylindrical shape. 如請求項1所述之魚缸,其中該燈管包括複數個三原色發光二極管。A fish tank as described in claim 1, wherein the light tube comprises a plurality of three-primary-color light-emitting diodes. 如請求項1所述之魚缸,其中該第一太陽能板及該第二太陽能板各包括一鈣鈦礦太陽能板。A fish tank as described in claim 1, wherein the first solar panel and the second solar panel each include a calcium-titanium solar panel. 如請求項7所述之魚缸,其中該鈣鈦礦太陽能板包括依序排列的一金屬電極層、一電洞傳輸層、一鈣鈦礦層、一電子傳輸層及一透明電極層,其中該金屬電極層最鄰近該燈罩的該外側表面或該內側表面。A fish tank as described in claim 7, wherein the calcium-titanium solar panel includes a metal electrode layer, a hole transport layer, a calcium-titanium layer, an electron transport layer and a transparent electrode layer arranged in sequence, wherein the metal electrode layer is closest to the outer surface or the inner surface of the lampshade. 如請求項7所述之魚缸,其中該鈣鈦礦太陽能板包括依序排列的一金屬電極層、一電子傳輸層、一鈣鈦礦層、一電洞傳輸層及一透明電極層,其中該金屬電極層最鄰近該燈罩的該外側表面或該內側表面。A fish tank as described in claim 7, wherein the calcium-titanium solar panel includes a metal electrode layer, an electron transport layer, a calcium-titanium layer, a hole transport layer and a transparent electrode layer arranged in sequence, wherein the metal electrode layer is closest to the outer surface or the inner surface of the lampshade. 如請求項7所述之魚缸,其中該鈣鈦礦太陽能板包括依序排列的一金屬電極層、一電洞傳輸層、一鈣鈦礦層、一緻密層及一透明電極層,其中該鈣鈦礦層包括複數個金屬氧化物,且該金屬電極層最鄰近該燈罩的該外側表面或該內側表面。A fish tank as described in claim 7, wherein the calcium-titanium solar panel includes a metal electrode layer, a hole transport layer, a calcium-titanium layer, a dense layer and a transparent electrode layer arranged in sequence, wherein the calcium-titanium layer includes a plurality of metal oxides, and the metal electrode layer is closest to the outer surface or the inner surface of the lampshade.
TW112128341A 2023-07-17 2023-07-28 Fish tank TWI839279B (en)

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CN209284040U (en) 2018-11-19 2019-08-23 南通理工学院 A kind of photovoltaic power supply Intelligent fish tank

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN209284040U (en) 2018-11-19 2019-08-23 南通理工学院 A kind of photovoltaic power supply Intelligent fish tank

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