TWI829942B - 殺蟲效力增強劑、害蟲防除方法及加熱蒸散用水性殺蟲劑組成物 - Google Patents
殺蟲效力增強劑、害蟲防除方法及加熱蒸散用水性殺蟲劑組成物 Download PDFInfo
- Publication number
- TWI829942B TWI829942B TW109123155A TW109123155A TWI829942B TW I829942 B TWI829942 B TW I829942B TW 109123155 A TW109123155 A TW 109123155A TW 109123155 A TW109123155 A TW 109123155A TW I829942 B TWI829942 B TW I829942B
- Authority
- TW
- Taiwan
- Prior art keywords
- insecticidal
- glycol
- water
- ether
- compound
- Prior art date
Links
- 230000000749 insecticidal effect Effects 0.000 title claims abstract description 118
- 239000000203 mixture Substances 0.000 title claims abstract description 94
- 239000003623 enhancer Substances 0.000 title claims abstract description 36
- 241000607479 Yersinia pestis Species 0.000 title claims description 49
- 238000000034 method Methods 0.000 title claims description 13
- 241000238631 Hexapoda Species 0.000 title description 13
- 238000009792 diffusion process Methods 0.000 title 1
- 230000008016 vaporization Effects 0.000 title 1
- 238000009834 vaporization Methods 0.000 title 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 83
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 50
- 239000002917 insecticide Substances 0.000 claims abstract description 49
- 239000004615 ingredient Substances 0.000 claims abstract description 45
- -1 glycol compound Chemical class 0.000 claims abstract description 35
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000002728 pyrethroid Substances 0.000 claims abstract description 22
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 18
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 11
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 10
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 8
- 239000004480 active ingredient Substances 0.000 claims abstract description 7
- 150000001335 aliphatic alkanes Chemical class 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 claims description 49
- 239000002250 absorbent Substances 0.000 claims description 47
- 238000010438 heat treatment Methods 0.000 claims description 42
- 239000000575 pesticide Substances 0.000 claims description 37
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 claims description 33
- VQXSOUPNOZTNAI-UHFFFAOYSA-N Pyrethrin I Natural products CC(=CC1CC1C(=O)OC2CC(=O)C(=C2C)CC=C/C=C)C VQXSOUPNOZTNAI-UHFFFAOYSA-N 0.000 claims description 32
- VJFUPGQZSXIULQ-XIGJTORUSA-N pyrethrin II Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VJFUPGQZSXIULQ-XIGJTORUSA-N 0.000 claims description 32
- 150000001875 compounds Chemical class 0.000 claims description 22
- 150000002894 organic compounds Chemical class 0.000 claims description 22
- 238000002207 thermal evaporation Methods 0.000 claims description 10
- 229940015975 1,2-hexanediol Drugs 0.000 claims description 7
- FHKSXSQHXQEMOK-UHFFFAOYSA-N hexane-1,2-diol Chemical compound CCCCC(O)CO FHKSXSQHXQEMOK-UHFFFAOYSA-N 0.000 claims description 7
- HRWADRITRNUCIY-UHFFFAOYSA-N 2-(2-propan-2-yloxyethoxy)ethanol Chemical compound CC(C)OCCOCCO HRWADRITRNUCIY-UHFFFAOYSA-N 0.000 claims description 5
- YJTIFIMHZHDNQZ-UHFFFAOYSA-N 2-[2-(2-methylpropoxy)ethoxy]ethanol Chemical compound CC(C)COCCOCCO YJTIFIMHZHDNQZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000012298 atmosphere Substances 0.000 claims description 5
- XYVAYAJYLWYJJN-UHFFFAOYSA-N 2-(2-propoxypropoxy)propan-1-ol Chemical compound CCCOC(C)COC(C)CO XYVAYAJYLWYJJN-UHFFFAOYSA-N 0.000 claims description 4
- QCAHUFWKIQLBNB-UHFFFAOYSA-N 3-(3-methoxypropoxy)propan-1-ol Chemical compound COCCCOCCCO QCAHUFWKIQLBNB-UHFFFAOYSA-N 0.000 claims description 4
- MFKRHJVUCZRDTF-UHFFFAOYSA-N 3-methoxy-3-methylbutan-1-ol Chemical compound COC(C)(C)CCO MFKRHJVUCZRDTF-UHFFFAOYSA-N 0.000 claims description 4
- BMRWNKZVCUKKSR-UHFFFAOYSA-N butane-1,2-diol Chemical compound CCC(O)CO BMRWNKZVCUKKSR-UHFFFAOYSA-N 0.000 claims description 4
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 claims description 4
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 claims description 4
- WCVRQHFDJLLWFE-UHFFFAOYSA-N pentane-1,2-diol Chemical compound CCCC(O)CO WCVRQHFDJLLWFE-UHFFFAOYSA-N 0.000 claims description 4
- GZMAAYIALGURDQ-UHFFFAOYSA-N 2-(2-hexoxyethoxy)ethanol Chemical compound CCCCCCOCCOCCO GZMAAYIALGURDQ-UHFFFAOYSA-N 0.000 claims description 3
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 claims description 3
- 150000002334 glycols Chemical class 0.000 claims description 3
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 claims description 3
- MWFQAAWRPDRKDG-KOLCDFICSA-N [2,3,5,6-tetrafluoro-4-(methoxymethyl)phenyl]methyl (1r,3s)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylate Chemical compound FC1=C(F)C(COC)=C(F)C(F)=C1COC(=O)[C@H]1C(C)(C)[C@@H]1C=C(Cl)Cl MWFQAAWRPDRKDG-KOLCDFICSA-N 0.000 claims description 2
- BKACAEJQMLLGAV-PLNGDYQASA-N heptafluthrin Chemical compound FC1=C(F)C(COC)=C(F)C(F)=C1COC(=O)C1C(C)(C)C1\C=C/C(F)(F)F BKACAEJQMLLGAV-PLNGDYQASA-N 0.000 claims description 2
- 229960002078 sevoflurane Drugs 0.000 claims description 2
- DFEYYRMXOJXZRJ-UHFFFAOYSA-N sevoflurane Chemical compound FCOC(C(F)(F)F)C(F)(F)F DFEYYRMXOJXZRJ-UHFFFAOYSA-N 0.000 claims 1
- 230000002147 killing effect Effects 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 description 52
- 230000008020 evaporation Effects 0.000 description 47
- 230000002745 absorbent Effects 0.000 description 35
- 239000000047 product Substances 0.000 description 29
- 230000000694 effects Effects 0.000 description 28
- 239000011162 core material Substances 0.000 description 23
- 238000009835 boiling Methods 0.000 description 22
- 230000000052 comparative effect Effects 0.000 description 16
- 238000012360 testing method Methods 0.000 description 16
- 239000000843 powder Substances 0.000 description 15
- 239000000126 substance Substances 0.000 description 15
- 241000255925 Diptera Species 0.000 description 14
- 239000011230 binding agent Substances 0.000 description 11
- 239000000463 material Substances 0.000 description 10
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 9
- 238000002156 mixing Methods 0.000 description 9
- 239000003921 oil Substances 0.000 description 9
- 235000019198 oils Nutrition 0.000 description 9
- 239000000835 fiber Substances 0.000 description 8
- 230000017525 heat dissipation Effects 0.000 description 8
- 230000002265 prevention Effects 0.000 description 8
- 239000004094 surface-active agent Substances 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 239000000919 ceramic Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 230000009545 invasion Effects 0.000 description 5
- 241000256059 Culex pipiens Species 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 4
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 4
- 239000004927 clay Substances 0.000 description 4
- 229910002804 graphite Inorganic materials 0.000 description 4
- 239000010439 graphite Substances 0.000 description 4
- 239000003350 kerosene Substances 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 229920001155 polypropylene Polymers 0.000 description 4
- AGMMRUPNXPWLGF-AATRIKPKSA-N (2,3,5,6-tetrafluoro-4-methylphenyl)methyl 2,2-dimethyl-3-[(e)-prop-1-enyl]cyclopropane-1-carboxylate Chemical compound CC1(C)C(/C=C/C)C1C(=O)OCC1=C(F)C(F)=C(C)C(F)=C1F AGMMRUPNXPWLGF-AATRIKPKSA-N 0.000 description 3
- 240000004460 Tanacetum coccineum Species 0.000 description 3
- ROVGZAWFACYCSP-MQBLHHJJSA-N [2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(C\C=C/C=C)C(=O)C1 ROVGZAWFACYCSP-MQBLHHJJSA-N 0.000 description 3
- 239000013011 aqueous formulation Substances 0.000 description 3
- 238000010304 firing Methods 0.000 description 3
- 230000001771 impaired effect Effects 0.000 description 3
- 239000010445 mica Substances 0.000 description 3
- 229910052618 mica group Inorganic materials 0.000 description 3
- 230000000361 pesticidal effect Effects 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 229940015367 pyrethrum Drugs 0.000 description 3
- 239000012779 reinforcing material Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 2
- SPSPIUSUWPLVKD-UHFFFAOYSA-N 2,3-dibutyl-6-methylphenol Chemical compound CCCCC1=CC=C(C)C(O)=C1CCCC SPSPIUSUWPLVKD-UHFFFAOYSA-N 0.000 description 2
- HJJZIMFAIMUSBW-UHFFFAOYSA-N 3-methylbutane-1,2-diol Chemical compound CC(C)C(O)CO HJJZIMFAIMUSBW-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- 244000269722 Thea sinensis Species 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- YXWCBRDRVXHABN-JCMHNJIXSA-N [cyano-(4-fluoro-3-phenoxyphenyl)methyl] 3-[(z)-2-chloro-2-(4-chlorophenyl)ethenyl]-2,2-dimethylcyclopropane-1-carboxylate Chemical compound C=1C=C(F)C(OC=2C=CC=CC=2)=CC=1C(C#N)OC(=O)C1C(C)(C)C1\C=C(/Cl)C1=CC=C(Cl)C=C1 YXWCBRDRVXHABN-JCMHNJIXSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 239000004760 aramid Substances 0.000 description 2
- 229920003235 aromatic polyamide Polymers 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 239000012784 inorganic fiber Substances 0.000 description 2
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 2
- 239000001525 mentha piperita l. herb oil Substances 0.000 description 2
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 235000019477 peppermint oil Nutrition 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 235000013772 propylene glycol Nutrition 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 230000002940 repellent Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 1
- NFLGAXVYCFJBMK-RKDXNWHRSA-N (+)-isomenthone Natural products CC(C)[C@H]1CC[C@@H](C)CC1=O NFLGAXVYCFJBMK-RKDXNWHRSA-N 0.000 description 1
- CXBMCYHAMVGWJQ-CABCVRRESA-N (1,3-dioxo-4,5,6,7-tetrahydroisoindol-2-yl)methyl (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-CABCVRRESA-N 0.000 description 1
- MIZYPRIEDMSCAC-UHFFFAOYSA-N (2-methyl-4-oxo-3-prop-2-enylcyclopent-2-en-1-yl) 2,2,3,3-tetramethylcyclopropane-1-carboxylate Chemical compound CC1=C(CC=C)C(=O)CC1OC(=O)C1C(C)(C)C1(C)C MIZYPRIEDMSCAC-UHFFFAOYSA-N 0.000 description 1
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 1
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 description 1
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 1
- ZFHGXWPMULPQSE-SZGBIDFHSA-N (Z)-(1S)-cis-tefluthrin Chemical compound FC1=C(F)C(C)=C(F)C(F)=C1COC(=O)[C@@H]1C(C)(C)[C@@H]1\C=C(/Cl)C(F)(F)F ZFHGXWPMULPQSE-SZGBIDFHSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- GZOKBPPGHUGEHR-UHFFFAOYSA-N 1-methoxy-3-methylbutan-1-ol Chemical compound COC(O)CC(C)C GZOKBPPGHUGEHR-UHFFFAOYSA-N 0.000 description 1
- GQCZPFJGIXHZMB-UHFFFAOYSA-N 1-tert-Butoxy-2-propanol Chemical compound CC(O)COC(C)(C)C GQCZPFJGIXHZMB-UHFFFAOYSA-N 0.000 description 1
- GGYRTIXZGALMIO-UHFFFAOYSA-N 2-(2-hydroxyethyl)piperidine-1-carboxylic acid Chemical compound OCCC1CCCCN1C(O)=O GGYRTIXZGALMIO-UHFFFAOYSA-N 0.000 description 1
- ZUAURMBNZUCEAF-UHFFFAOYSA-N 2-(2-phenoxyethoxy)ethanol Chemical compound OCCOCCOC1=CC=CC=C1 ZUAURMBNZUCEAF-UHFFFAOYSA-N 0.000 description 1
- OADIZUFHUPTFAG-UHFFFAOYSA-N 2-[2-(2-ethylhexoxy)ethoxy]ethanol Chemical compound CCCCC(CC)COCCOCCO OADIZUFHUPTFAG-UHFFFAOYSA-N 0.000 description 1
- UPGSWASWQBLSKZ-UHFFFAOYSA-N 2-hexoxyethanol Chemical compound CCCCCCOCCO UPGSWASWQBLSKZ-UHFFFAOYSA-N 0.000 description 1
- RKLRVTKRKFEVQG-UHFFFAOYSA-N 2-tert-butyl-4-[(3-tert-butyl-4-hydroxy-5-methylphenyl)methyl]-6-methylphenol Chemical compound CC(C)(C)C1=C(O)C(C)=CC(CC=2C=C(C(O)=C(C)C=2)C(C)(C)C)=C1 RKLRVTKRKFEVQG-UHFFFAOYSA-N 0.000 description 1
- BZZFHUVTWGGVBA-UHFFFAOYSA-N 3-(2-chloro-3,3,3-trifluoroprop-1-enyl)-2,2-dimethyl-1-[[2,3,5,6-tetrafluoro-4-(methoxymethyl)phenyl]methyl]cyclopropane-1-carboxylic acid Chemical compound CC1(C(C1(CC2=C(C(=C(C(=C2F)F)COC)F)F)C(=O)O)C=C(C(F)(F)F)Cl)C BZZFHUVTWGGVBA-UHFFFAOYSA-N 0.000 description 1
- PSJBSUHYCGQTHZ-UHFFFAOYSA-N 3-Methoxy-1,2-propanediol Chemical compound COCC(O)CO PSJBSUHYCGQTHZ-UHFFFAOYSA-N 0.000 description 1
- IJALWSVNUBBQRA-UHFFFAOYSA-N 4-Isopropyl-3-methylphenol Chemical compound CC(C)C1=CC=C(O)C=C1C IJALWSVNUBBQRA-UHFFFAOYSA-N 0.000 description 1
- RNKURRDNOYXATR-UHFFFAOYSA-N 4-methylpentane-2,3-diol Chemical compound CC(C)C(O)C(C)O RNKURRDNOYXATR-UHFFFAOYSA-N 0.000 description 1
- YVNRSOMGUGTRMU-UHFFFAOYSA-N 6-ethyl-5-methylphenanthridin-5-ium-3,8-diamine;bromide Chemical compound [Br-].C1=C(N)C=C2C(CC)=[N+](C)C3=CC(N)=CC=C3C2=C1 YVNRSOMGUGTRMU-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 241000256111 Aedes <genus> Species 0.000 description 1
- 241000256118 Aedes aegypti Species 0.000 description 1
- 241000256173 Aedes albopictus Species 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 244000146553 Ceiba pentandra Species 0.000 description 1
- 235000003301 Ceiba pentandra Nutrition 0.000 description 1
- 241000255930 Chironomidae Species 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 241000256057 Culex quinquefasciatus Species 0.000 description 1
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 1
- YUGWDVYLFSETPE-JLHYYAGUSA-N Empenthrin Chemical compound CC\C=C(/C)C(C#C)OC(=O)C1C(C=C(C)C)C1(C)C YUGWDVYLFSETPE-JLHYYAGUSA-N 0.000 description 1
- QTANTQQOYSUMLC-UHFFFAOYSA-O Ethidium cation Chemical compound C12=CC(N)=CC=C2C2=CC=C(N)C=C2[N+](CC)=C1C1=CC=CC=C1 QTANTQQOYSUMLC-UHFFFAOYSA-O 0.000 description 1
- VZRKEAFHFMSHCD-UHFFFAOYSA-N Ethyl 3-(N-butylacetamido)propionate Chemical compound CCCCN(C(C)=O)CCC(=O)OCC VZRKEAFHFMSHCD-UHFFFAOYSA-N 0.000 description 1
- 239000005792 Geraniol Substances 0.000 description 1
- GLZPCOQZEFWAFX-YFHOEESVSA-N Geraniol Natural products CC(C)=CCC\C(C)=C/CO GLZPCOQZEFWAFX-YFHOEESVSA-N 0.000 description 1
- LMXFTMYMHGYJEI-UHFFFAOYSA-N Menthoglycol Natural products CC1CCC(C(C)(C)O)C(O)C1 LMXFTMYMHGYJEI-UHFFFAOYSA-N 0.000 description 1
- NFLGAXVYCFJBMK-UHFFFAOYSA-N Menthone Chemical compound CC(C)C1CCC(C)CC1=O NFLGAXVYCFJBMK-UHFFFAOYSA-N 0.000 description 1
- 241000257226 Muscidae Species 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 241000258242 Siphonaptera Species 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 239000005939 Tefluthrin Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- VXSIXFKKSNGRRO-MXOVTSAMSA-N [(1s)-2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate;[(1s)-2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-3-[(e)-3-methoxy-2-methyl-3-oxoprop-1-enyl Chemical class CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1.CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VXSIXFKKSNGRRO-MXOVTSAMSA-N 0.000 description 1
- KVIZNNVXXNFLMU-AIIUZBJTSA-N [2,3,5,6-tetrafluoro-4-(methoxymethyl)phenyl]methyl (1r,3r)-2,2-dimethyl-3-[(e)-prop-1-enyl]cyclopropane-1-carboxylate Chemical compound FC1=C(F)C(COC)=C(F)C(F)=C1COC(=O)[C@H]1C(C)(C)[C@@H]1\C=C\C KVIZNNVXXNFLMU-AIIUZBJTSA-N 0.000 description 1
- OOWCJRMYMAMSOH-UHFFFAOYSA-N [2,3,5,6-tetrafluoro-4-(methoxymethyl)phenyl]methyl 2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound FC1=C(F)C(COC)=C(F)C(F)=C1COC(=O)C1C(C)(C)C1C=C(C)C OOWCJRMYMAMSOH-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- LJQRTRWRVDBRBB-UHFFFAOYSA-N benzyl 3-(2-chloro-3,3,3-trifluoroprop-1-enyl)-2,2-dimethylcyclopropane-1-carboxylate Chemical compound CC1(C)C(C=C(Cl)C(F)(F)F)C1C(=O)OCC1=CC=CC=C1 LJQRTRWRVDBRBB-UHFFFAOYSA-N 0.000 description 1
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 description 1
- HECGKCOICWUUJU-UHFFFAOYSA-N bis(diphenylphosphanylmethyl)-phenylphosphane Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)CP(C=1C=CC=CC=1)CP(C=1C=CC=CC=1)C1=CC=CC=C1 HECGKCOICWUUJU-UHFFFAOYSA-N 0.000 description 1
- QLHULAHOXSSASE-UHFFFAOYSA-N butan-2-yl 2-(2-hydroxyethyl)piperidine-1-carboxylate Chemical compound CCC(C)OC(=O)N1CCCCC1CCO QLHULAHOXSSASE-UHFFFAOYSA-N 0.000 description 1
- OWBTYPJTUOEWEK-UHFFFAOYSA-N butane-2,3-diol Chemical compound CC(O)C(C)O OWBTYPJTUOEWEK-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000010632 citronella oil Substances 0.000 description 1
- 235000000484 citronellol Nutrition 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 229910052878 cordierite Inorganic materials 0.000 description 1
- YMGUBTXCNDTFJI-UHFFFAOYSA-M cyclopropanecarboxylate Chemical compound [O-]C(=O)C1CC1 YMGUBTXCNDTFJI-UHFFFAOYSA-M 0.000 description 1
- YSRSBDQINUMTIF-UHFFFAOYSA-N decane-1,2-diol Chemical compound CCCCCCCCC(O)CO YSRSBDQINUMTIF-UHFFFAOYSA-N 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000003759 ester based solvent Substances 0.000 description 1
- 239000004210 ether based solvent Substances 0.000 description 1
- 239000010642 eucalyptus oil Substances 0.000 description 1
- 229940044949 eucalyptus oil Drugs 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 229940113087 geraniol Drugs 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052621 halloysite Inorganic materials 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- HJJLDNAELNDBBL-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO.OCCCCCCO HJJLDNAELNDBBL-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229950011440 icaridin Drugs 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- NFIDBGJMFKNGGQ-UHFFFAOYSA-N isopropylmethylphenol Natural products CC(C)CC1=CC=CC=C1O NFIDBGJMFKNGGQ-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000000171 lavandula angustifolia l. flower oil Substances 0.000 description 1
- 230000001665 lethal effect Effects 0.000 description 1
- 231100000225 lethality Toxicity 0.000 description 1
- 229930007744 linalool Natural products 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000008155 medical solution Substances 0.000 description 1
- 229940041616 menthol Drugs 0.000 description 1
- 229930007503 menthone Natural products 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- 229960002216 methylparaben Drugs 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 229940070846 pyrethrins Drugs 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 229960005199 tetramethrin Drugs 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000012719 thermal polymerization Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- DDVNRFNDOPPVQJ-HQJQHLMTSA-N transfluthrin Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=C(F)C(F)=CC(F)=C1F DDVNRFNDOPPVQJ-HQJQHLMTSA-N 0.000 description 1
- JLGLQAWTXXGVEM-UHFFFAOYSA-N triethylene glycol monomethyl ether Chemical compound COCCOCCOCCO JLGLQAWTXXGVEM-UHFFFAOYSA-N 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/18—Vapour or smoke emitting compositions with delayed or sustained release
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M1/00—Stationary means for catching or killing insects
- A01M1/20—Poisoning, narcotising, or burning insects
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
- A01N25/10—Macromolecular compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/02—Acyclic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P7/00—Arthropodicides
- A01P7/04—Insecticides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
- A01M1/00—Stationary means for catching or killing insects
- A01M1/20—Poisoning, narcotising, or burning insects
- A01M1/2022—Poisoning or narcotising insects by vaporising an insecticide
- A01M1/2061—Poisoning or narcotising insects by vaporising an insecticide using a heat source
- A01M1/2066—Poisoning or narcotising insects by vaporising an insecticide using a heat source burning insecticide, e.g. impregnated candles, burning coils
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Dentistry (AREA)
- Toxicology (AREA)
- Insects & Arthropods (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Catching Or Destruction (AREA)
Abstract
本發明係提供一種在含有相對蒸氣壓高之除蟲菊酯(Pyrethroid)系殺蟲成分之加熱蒸散用水性殺蟲劑組成物,可有效果地增強該除蟲菊酯系殺蟲成分的殺蟲效力之殺蟲效力增強劑。
本發明係將甘醇系化合物作為有效成分之殺蟲效力增強劑,該甘醇系化合物係於碳數為4~7之烷烴的2個相鄰之碳原子各鍵結一個羥基,其特徵為摻合在加熱蒸散用水性殺蟲劑組成物,該殺蟲劑組成物係含有在30℃之蒸氣壓為2×10-4
~1×10-2
mmHg之除蟲菊酯系殺蟲成分。
Description
本發明係關於摻合在含有相對蒸氣壓高之除蟲菊酯系殺蟲成分的加熱蒸散用水性殺蟲劑組成物之殺蟲效力增強劑、使用摻合該殺蟲效力增強劑之加熱蒸散用水性殺蟲劑組成物的害蟲防除方法及含有該殺蟲效力增強劑之加熱蒸散用水性殺蟲劑組成物。
作為用以防除蚊等之飛行害蟲的飛行害蟲防除製品,市售有採用藉由於含有殺蟲成分之藥液浸漬吸液芯,並將被吸液之藥液導向吸液芯的上部,並加熱吸液芯,使殺蟲成分蒸散至大氣中之方式的所謂「液體式捕蚊」。液體式捕蚊的殺蟲成分,一般而言,使用有除蟲菊酯系殺蟲成分。除蟲菊酯系殺蟲成分以往亞烈寧、普亞列寧、炔呋菊酯等雖為主流,但近年來,有使用殺蟲活性優異之拜富靈(Transfluthrin)、美特寧(Metofluthrin)、丙氟菊酯(Profluthrin)等之嶄新成分的傾向。
又,液體式捕蚊所使用之藥液中,存在將煤油作為基底之油性配方、與將水作為基底之水性配方。目前為止的液體式捕蚊,世界上油性配方雖為主流,但水性配方與油性配方相比較,可減輕對於著火之危險性,進而,由於對於害蟲之殺蟲效果與油性配方相比較,可說是同等以上,故今後預測水性配方的需求會增加。
作為以往之水性配方的飛行害蟲防除製品,係使用包含除蟲菊酯系殺蟲成分、與界面活性劑、與水之藥液的加熱蒸散用水性殺蟲劑(例如參照專利文獻1)。專利文獻1之加熱蒸散用水性殺蟲劑,係使用在使用加熱蒸散用之吸液芯,加熱蒸散藥液之方式者,藉由對藥液摻合界面活性劑,維持藥液之成分組成的平衡,並成為通過長期安定地蒸散除蟲菊酯系殺蟲成分者。
又,作為其他以往之水性配方的飛行害蟲防除製品,係包含加熱蒸散性藥劑、與有機溶劑、與水之加熱蒸散用水性藥劑(例如參照專利文獻2)。在專利文獻2之加熱蒸散用水性藥劑,作為相當於界面活性劑之成分,已網羅多數之水性有機溶劑或水性有機化合物,嘗試調整加熱蒸散用水性藥劑的揮散性。
[先前技術文獻]
[專利文獻]
[專利文獻1]日本特開平3-7207號公報
[專利文獻2]日本特開平7-316002號公報
[發明欲解決之課題]
將飛行害蟲防除製品於屋內使用時,為了有效果地提高對於飛行害蟲之防除作用,有必要將蒸散自飛行害蟲防除製品之蒸散粒子所包含之除蟲菊酯系殺蟲成分有效果地與飛行害蟲接觸,而到達飛行害蟲的體內。而且,對於水性配方之飛行害蟲防除製品,蒸散粒子所包含之除蟲菊酯系殺蟲成分,前提是保持與界面活性劑(水性有機溶劑或是水性有機化合物)或水平衡進行揮散。
關於此點,專利文獻1之加熱蒸散用水性殺蟲劑,或專利文獻2之加熱蒸散用水性藥劑,為了將除蟲菊酯系殺蟲成分的濃度保持一定,故有提高蒸散安定性或是嘗試揮散性的調整作為課題。亦即,在包含專利文獻1或專利文獻2之以往技術,限於蒸散性能的研究,著重在蒸散粒子所包含之除蟲菊酯系殺蟲成分本身的課題,或將該除蟲菊酯系殺蟲成分有效果地與飛行害蟲接觸,增強殺蟲效力的技術思想,於以往技術的當時尚未有充分的認識。
本發明係鑑於上述問題點而完成者,以提供一種在含有相對蒸氣壓高之除蟲菊酯系殺蟲成分的加熱蒸散用水性殺蟲劑組成物,可有效果地增強該除蟲菊酯系殺蟲成分的殺蟲效力之殺蟲效力增強劑作為目的。進而,本發明係以提供一種有效果地增強除蟲菊酯系殺蟲成分的殺蟲效力之害蟲防除方法及加熱蒸散用水性殺蟲劑組成物作為目的。
[用以解決課題之手段]
本發明係發現以下之構成為了達成上述目的而發揮優異之效果。
(1)一種殺蟲效力增強劑,其係將甘醇系化合物作為有效成分之殺蟲效力增強劑,該甘醇系化合物係於碳數為4~7之烷烴的2個相鄰之碳原子各鍵結一個羥基,其特徵為摻合在加熱蒸散用水性殺蟲劑組成物,該殺蟲劑組成物係含有在30℃之蒸氣壓為2×10-4
~1×10-2
mmHg之除蟲菊酯系殺蟲成分。
(2)如(1)所記載之殺蟲效力增強劑,其中,前述碳數為4~7之烷烴的2個相鄰之碳原子係碳位置編號為1位及2位。
(3)如(2)所記載之殺蟲效力增強劑,其中,前述甘醇系化合物係選自由1,2-丁烷二醇、1,2-戊烷二醇及1,2-己烷二醇所成之群組中之至少一種。
(4)如(1)~(3)中任一項所記載之殺蟲效力增強劑,其中,前述加熱蒸散用水性殺蟲劑組成物係含有前述除蟲菊酯系殺蟲成分、與水性有機化合物、與水,前述水性有機化合物係其20質量%以上為以前述甘醇系化合物構成。
(5)如(1)~(4)中任一項所記載之殺蟲效力增強劑,其中,前述除蟲菊酯系殺蟲成分係選自由拜富靈、美特寧、丙氟菊酯、氯氟醚菊酯(meperfluthrin)、右旋七氟甲醚菊酯(heptafluthrin)、四氟甲醚菊酯(dimefluthrin)及4-甲氧基甲基-2,3,5,6-四氟苄基-2,2-二甲基-3-(2-氯-2-三氟甲基乙烯基)環丙烷羧酸鹽所成之群組中之至少一種。
(6)如(5)所記載之殺蟲效力增強劑,其中,前述除蟲菊酯系殺蟲成分為拜富靈。
(7)如(4)~(6)中任一項所記載之殺蟲效力增強劑,其中,前述水性有機化合物係進一步含有甘醇醚系化合物。
(8)如(7)所記載之殺蟲效力增強劑,其中,前述甘醇醚系化合物係選自由二乙二醇單乙基醚、二乙二醇單異丙基醚、二乙二醇單丁基醚、二乙二醇單異丁基醚、二乙二醇單己基醚、二丙二醇單甲基醚、二丙二醇單丙基醚及3-甲氧基-3-甲基丁醇所成之群組中之至少一種。
(9)一種害蟲防除方法,其係使用加熱蒸散用吸液芯之害蟲防除方法,其特徵為包含:於摻合如(1)~(8)中任一項所記載之殺蟲效力增強劑的加熱蒸散用水性殺蟲劑組成物,浸漬前述加熱蒸散用吸液芯的下部之步驟、與藉由將由前述加熱蒸散用吸液芯的下部吸液之前述加熱蒸散用水性殺蟲劑組成物導向前述加熱蒸散用吸液芯的上部,並於80~150℃加熱,使前述除蟲菊酯系殺蟲成分蒸散至大氣中之步驟。
(10)一種加熱蒸散用水性殺蟲劑組成物,其係含有在30℃之蒸氣壓為2×10-4
~1×10-2
mmHg之除蟲菊酯系殺蟲成分、與將甘醇系化合物作為有效成分之殺蟲效力增強劑,該甘醇系化合物係於碳數為4~7之烷烴的2個相鄰之碳原子各鍵結一個羥基。
[發明效果]
本發明之殺蟲效力增強劑及害蟲防除方法,在含有相對蒸氣壓高之除蟲菊酯系殺蟲成分的加熱蒸散用水性殺蟲劑組成物,不僅有助於該加熱蒸散用水性殺蟲劑組成物的蒸散安定性或揮散調整,並由於可有效果地增強該加熱蒸散用水性殺蟲劑組成物所包含之除蟲菊酯系殺蟲成分的殺蟲效力,故極為有用。又,本發明之加熱蒸散用水性殺蟲劑組成物由於包含將增強除蟲菊酯系殺蟲成分的殺蟲效果之甘醇系化合物作為有效成分之殺蟲效力增強劑,故成為作為害蟲防除製品非常優異者,實用上亦極為有用。
以下,針對本發明之殺蟲效力增強劑、害蟲防除方法及加熱蒸散用水性殺蟲劑組成物進行說明。惟,本發明並非故意被限定於以下所說明之實施形態或實施例。
<加熱蒸散用水性殺蟲劑組成物>
摻合本發明之殺蟲效力增強劑的本發明之加熱蒸散用水性殺蟲劑組成物(以下,稱為「水性殺蟲劑組成物」),係含有在30℃之蒸氣壓為2×10-4
~1×10-2
mmHg之除蟲菊酯系殺蟲成分。根據本發明,藉由於含有在30℃之蒸氣壓為2×10-4
~1×10-2
mmHg之除蟲菊酯系殺蟲成分的加熱蒸散用水性殺蟲劑組成物,摻合將甘醇系化合物作為有效成分之殺蟲效力增強劑,該甘醇系化合物係於碳數為4~7之烷烴的2個相鄰之碳原子各鍵結一個羥基,可增強加熱蒸散用水性殺蟲劑組成物的殺蟲效力。
<除蟲菊酯系殺蟲成分>
除蟲菊酯系殺蟲成分,例如可列舉拜富靈、美特寧、丙氟菊酯、益避寧(Empenthrin)、環戊烯丙菊酯(terallethrin)、氯氟醚菊酯、右旋七氟甲醚菊酯、四氟甲醚菊酯及4-甲氧基甲基-2,3,5,6-四氟苄基-2,2-二甲基-3-(2-氯-2-三氟甲基乙烯基)環丙烷羧酸鹽等。此等當中,考量加熱蒸散性、殺蟲效力、安定性等時,較佳為拜富靈、美特寧、丙氟菊酯、氯氟醚菊酯、右旋七氟甲醚菊酯、四氟甲醚菊酯及4-甲氧基甲基-2,3,5,6-四氟苄基-2,2-二甲基-3-(2-氯-2-三氟甲基乙烯基)環丙烷羧酸鹽,更佳為拜富靈。上揭之除蟲菊酯系殺蟲成分可單獨使用,亦可以混合複數種的狀態使用。又,在除蟲菊酯系殺蟲成分,於酸部分或醇部分,依據不齊碳,存在光學異構物或幾何異構物時,該等皆包含在可於本發明使用之除蟲菊酯系殺蟲成分。
加熱蒸散用水性殺蟲劑組成物中之除蟲菊酯系殺蟲成分的含量較佳為0.1~3.0質量%,更佳為0.7~2.0質量%。含量未滿0.1質量%時,有降低殺蟲效力之虞。另一方面,含量超過3.0質量%時,有對水性殺蟲劑組成物的性狀帶來阻礙的可能性。
<殺蟲效力增強劑>
本發明者們在含有上述除蟲菊酯系殺蟲成分之加熱蒸散用水性殺蟲劑組成物,重複苦心研究的結果,令人驚訝的是發現特定之甘醇系化合物,不僅可作為加熱蒸散用水性殺蟲劑組成物的一成分(水性有機化合物)使用,亦可用作增強除蟲菊酯系殺蟲成分的殺蟲效果的成分。亦即,本發明係關於將甘醇系化合物作為有效成分之殺蟲效力增強劑,該甘醇系化合物係碳數為4~7之烷烴的2個相鄰之碳原子各鍵結一個羥基。
<甘醇系化合物>
作為甘醇系化合物,例如可列舉1,2-丁烷二醇(沸點:194℃)、1,2-戊烷二醇(沸點:210℃)、1,2-己烷二醇(沸點:223℃)、3-甲基-1,2-丁烷二醇(沸點:206℃)、2,3-丁烷二醇(沸點:177℃)、4-甲基-2,3-戊烷二醇(沸點:190℃)等。此等之甘醇系化合物當中,適合相鄰之2個碳原子的碳位置編號為1位及2位,即1,2-丁烷二醇、1,2-戊烷二醇、1,2-己烷二醇、3-甲基-1,2-丁烷二醇,更適合1,2-己烷二醇。
將於本發明使用之甘醇系化合物摻合在加熱蒸散用水性殺蟲劑組成物時,對於發揮優異之殺蟲效力增強效果的理由雖並未明確,但認為是藉由存在於甘醇系化合物的分子構造中之二個羥基相鄰,於兩者間形成氫鍵,此氫鍵對除蟲菊酯系殺蟲成分的殺蟲效力增強效果給予一定的好影響。
在摻合甘醇系化合物之加熱蒸散用水性殺蟲劑組成物,作為殺蟲效力增強劑之甘醇系化合物的加熱蒸散用水性殺蟲劑組成物中的含量,較佳為2~70質量%,更佳為6~60質量%。含量未滿2質量%時,有得不到充分之殺蟲效力增強效果之虞。另一方面,即使含量超過70質量%,不僅對於飛行害蟲之殺蟲效果或防止侵入屋內效果達到最高限度,而且增大對於著火之危險性,亦有損害作為水性配方的優點之虞。
<水性有機化合物>
於本發明使用之加熱蒸散用水性殺蟲劑組成物,為了作為水性配方,使用水作為溶媒,進而為了可溶化除蟲菊酯系殺蟲成分,而摻合水性有機化合物。如此藉由成為水性配方,與油性配方比較,可減輕對於著火之危險性,對於害蟲之殺蟲效果可說為同等以上。為了作為水性配方而摻合之水性有機化合物,係將以下三點作為前提者:(1)可溶化除蟲菊酯系殺蟲成分、(2)具有加熱蒸散性、(3)介在除蟲菊酯系殺蟲成分與水之間,3成分保持一定的比率並進行加熱蒸散。於本發明,用作殺蟲效力增強劑之甘醇系化合物,可因應對於除蟲菊酯系殺蟲成分之可溶化能等,以成為水性有機化合物的一部分或全部的方式進行摻合。又,藉由與該甘醇系化合物一起併用其他化合物,例如甘醇醚系化合物,可構成水性有機化合物。甘醇醚系化合物係除蟲菊酯系殺蟲成分之可溶化能或加熱蒸散性優異,在專利文獻1或專利文獻2,作為主要之水性有機化合物(皆稱為界面活性劑或水性有機溶劑)表示。在本發明,甘醇醚系化合物係作為甘醇系化合物的補充成分有用者。
<甘醇醚系化合物>
作為甘醇醚系化合物,較佳為沸點為150~300℃者,更佳為170~260℃者。作為該甘醇醚系化合物,例如可列舉二乙二醇單乙基醚(沸點:202℃、以下稱為DEME)、二乙二醇單異丙基醚(沸點:207℃、以下稱為DEMIP)、二乙二醇單丁基醚(沸點:231℃、以下稱為DEMB)、二乙二醇單異丁基醚(沸點:220℃、以下稱為DEMIB)、二乙二醇單己基醚(沸點:259℃、以下稱為DEMH)、二乙二醇單2-乙基己基醚(沸點:272℃)、二乙二醇單苯基醚(沸點:283℃)、三乙二醇單甲基醚(沸點:249℃)、丙二醇單第三丁基醚(沸點:151℃)、二丙二醇單甲基醚(沸點:188℃)、二丙二醇單丙基醚(沸點:210℃、以下稱為DPMP)、3-甲氧基-1,2-丙烷二醇(沸點:220℃)及3-甲氧基-3-甲基丁醇(沸點:174℃、以下稱為Solfit)等。此等之甘醇醚系化合物當中,適合二乙二醇單乙基醚、二乙二醇單異丙基醚、二乙二醇單丁基醚、二乙二醇單異丁基醚、二乙二醇單己基醚、二丙二醇單甲基醚、二丙二醇單丙基醚及3-甲氧基-3-甲基丁醇。上揭之甘醇醚系化合物可單獨使用,亦可以混合複數種的狀態使用。
加熱蒸散用水性殺蟲劑組成物中之水性有機化合物的含量,較佳為10~70質量%,更佳為30~60質量%。含量未滿10質量%時,有對水性製劑化帶來阻礙之虞。又,飛行害蟲防除效果的持續性亦變貧乏。另一方面,含量即使超過70質量%,不僅對於飛行害蟲之殺蟲效果或防止侵入屋內效果達到最高限度,而且增大對於著火之危險性,亦有損害作為水性配方的優點之虞。尚,水性有機化合物當中,作為殺蟲效力增強劑使用之甘醇系化合物,較佳為以以下所描述之摻合量含有。亦即,較佳為將水性有機化合物中之甘醇系化合物的摻合量定為20~100質量%。又,較佳為將加熱蒸散用水性殺蟲劑組成物中之甘醇系化合物的摻合量定為2~70質量%,更佳為定為6~60質量%。藉由成為這般的摻合,使得水性製劑化變可能,而且維持優異之加熱蒸散性,進而可增強殺蟲效力。
於加熱蒸散用水性殺蟲劑組成物,作為殺蟲效力增強劑摻合之甘醇系化合物,在不脫離增強除蟲菊酯系殺蟲成分的殺蟲效力所謂本發明的趣旨的限度,可摻合其他成分。例如可適當摻合待乙妥、1-メチルプロピル2-(2-ヒドロキシエチル)-1-ピペリジンカルボキシラート1-メチルプロピル2-(2-ヒドロキシエチル)-1-ピペリジンカルボキシラート1-甲基丙基2-(2-羥基乙基)-1-哌啶羧酸鹽(埃卡瑞丁(Icaridin))、3-(N-n-丁基-N-乙醯基)胺基丙酸乙基酯(3-(N-n-ブチル-N-アセチル)アミノプロピオン酸エチルエステル3-(N-n-ブチル-N-アセチル)アミノプロピオン酸エチルエステルIR3535)等之非除蟲菊酯系害蟲忌避成分、香茅醇、香葉醇、芳樟醇、p-薄荷烷-3,8-二醇、薄荷醇及薄荷酮等之萜烯系化合物、香茅油、薰衣草油、薄荷油、檸檬桉樹油及薄荷油(Peppermint oil)等之有忌避效果之天然精油、異丙基甲基酚等之抗菌劑、防黴劑、如二丁基羥基甲苯(BHT)、對羥基苯甲酸甲酯之安定化劑、pH調整劑、著色劑、茶萃取物或茶乾餾液等之除臭劑等。又,在調製加熱蒸散用水性殺蟲劑組成物,若不損害水性配方的優點的範圍,水之外即使適當使用如乙醇、異丙醇之低級醇、如煤油(kerosene)之烴系溶劑、酯系或醚系溶劑、可溶化劑、分散劑亦無妨。
<害蟲防除方法>
如上述調製之加熱蒸散用水性殺蟲劑組成物,係填充在具備加熱蒸散用吸液芯之容器本體(未圖示),而構成害蟲防除製品(液體式捕蚊)。亦即,適用在藉由於加熱蒸散用水性殺蟲劑組成物浸漬加熱蒸散用吸液芯,將經吸液之加熱蒸散用水性殺蟲劑組成物導向加熱蒸散用吸液芯的上部,並於80~150℃進行加熱,使除蟲菊酯系殺蟲成分蒸散至大氣中之害蟲防除方法。
收容加熱蒸散用水性殺蟲劑組成物之藥液容器,一般為聚丙烯等之聚烯烴、聚酯、聚氯乙烯等之塑膠製容器。於藥液容器的上部透過中栓附上吸液芯。為水性配方時,藥液容器的材質,考量甘醇系化合物或甘醇醚系化合物等之物性,較佳為聚丙烯等之聚烯烴系塑膠。
<加熱蒸散用吸液芯>
然而,液體式捕蚊之加熱蒸散用吸液芯,根據一般的區分,雖大致上分成燒成芯、多孔質陶瓷芯、毛氈芯、編結芯、黏結芯,但於本發明,適合使用燒成芯、多孔質陶瓷芯、毛氈芯、編結芯,更適合為使用燒成芯或多孔質陶瓷芯。以下,針對使用燒成芯或編結芯作為加熱蒸散用吸液芯的情況進行說明。尚,加熱蒸散用吸液芯的素材,若為對於包含除蟲菊酯系殺蟲成分之加熱蒸散用水性殺蟲劑組成物安定,且為可以毛細現象吸液水溶液者,則並未特別限定。
燒成芯係藉由將包含(a)無機物質(無機質粉體、無機質黏結劑等),或較佳為於此包含(b)有機物質(碳質粉體、有機質黏結劑等)之混合物,以600~2000℃進行燒成而獲得。於此,雖亦存在(b)的摻合量少,且幾乎僅由(a)所構成之燒成芯,但這般的燒成芯有時稱為多孔質陶瓷芯。
無機物質雖將無機質粉體作為必須成分包含,但如有必要可為將無機質黏結劑作為補助成分包含者。無機質粉體,例如可列舉雲母、氧化鋁、二氧化矽、滑石、莫來石、堇青石及氧化鋯等。此等當中,雲母由於尤其是於液體式捕蚊用之吸液芯可生成比較均一之微細孔,故為較佳之材料。上揭之無機質粉體可單獨使用,亦可以混合複數種的狀態使用。在加熱蒸散用吸液芯之無機質粉體的含量較佳為10~90質量%,更佳為30~70質量%。無機質粉體的形狀從外觀、吸液性、強度等之物性的點來看,較佳為50網目以下之微粉狀。惟,在加熱蒸散用吸液芯之製造步驟,伴隨粉碎等之處理時,不限於此。
無機質黏結劑,例如可列舉黏土(高嶺黏土)、膨潤土、埃洛石等之各種黏土、焦油瀝青、水玻璃等。此等當中,黏土由於黏結作用性優異,故為較佳之材料。上揭之無機質黏結劑可單獨使用,亦可以混合複數種的狀態使用。在加熱蒸散用吸液芯之無機質黏結劑的含量較佳為5~50質量%,更佳為10~40質量%。無機質黏結劑於常溫雖黏結作用貧乏,但藉由以600~2000℃燒成,變成顯示充分之黏結作用,變成可適合作為加熱蒸散用吸液芯使用。
有機物質,可列舉石墨、碳黑、活性炭、木炭及焦炭等之碳質粉體,或羧基甲基纖維素(CMC)、丙烯酸樹脂、聚烯烴樹脂等之有機質黏結劑。此等當中,石墨由於形狀比較為均一且雜質少,故為較佳之材料。摻合石墨等之碳質粉體時,可改善加熱蒸散用吸液芯之外觀、色調、吸液性、強度等。上揭之碳質粉體或有機質黏結劑可單獨使用,亦可以混合複數種的狀態使用。在加熱蒸散用吸液芯之有機物質的含量較佳為5~40質量%。若為此範圍,於燒成加熱蒸散用吸液芯之過程,藉由產生一氧化碳或二氧化碳等之氣體,於加熱蒸散用吸液芯中生成連續氣孔,為了藉由毛細現象顯示吸液性能,可形成充分之多孔質構造。
尚,於加熱蒸散用吸液芯,上述之物質之外,可適當添加防腐劑、4,4’-亞甲基雙(2-甲基-6-t-丁基酚)、硬脂基-β-(3,5-二-t-丁基-4-羥基苯基)丙酸酯等之抗氧化劑。
編結芯係於芯材之外周面吸液加熱蒸散用水性殺蟲劑組成物,並被覆用以揮散之護套材料(sheath material)而成,該護套材料一般係作為選自天然纖維、合成纖維及無機纖維中之一種以上的纖維集合體形成。在編結芯,芯材係具有加熱蒸散用吸液芯之形狀保持機能者。作為其材質,不需要一定具備吸液加熱蒸散用水性殺蟲劑組成物之機能,例如可用具有130℃以上之耐熱性的熱塑性及/或熱硬化性之合成樹脂形成。尚,為了強化形狀保持機能,作為芯材之補強材,亦可藉由玻璃纖維、陶瓷纖維、碳纖維等之纖維狀補強材,或玻璃粉體、被稱為無機填料之二氧化矽、氧化鋁、氧化鈦等之粉體狀補強材等,補強熱塑性及/或熱硬化性之合成樹脂。
護套材料通常作為纖維集合體形成,作為構成此之纖維,例如雖可列舉木綿等之天然纖維、聚丙烯、聚酯、尼龍、芳綸等之合成纖維、玻璃纖維或碳纖維等之無機纖維等之一種以上,但較佳為其耐熱溫度為130℃以上之聚丙烯、聚酯、尼龍、芳綸等之合成纖維。而且,這般的纖維集合體一般係以編織(Braid)、織布、針織布、毛氈或不織布等之纖維素材構成。此時,可對纖維素材實施界面活性劑處理,調節吸液速度,或是,又將護套材料的表面進而使用清漆等被覆,或實施親水加工等之機能加工。
如此進行所得之加熱蒸散用吸液芯,適用在透過該加熱蒸散用吸液芯,使加熱蒸散用水性殺蟲劑組成物加熱蒸散之方式的液體製品。亦即,將加熱蒸散用水性殺蟲劑組成物收容在藥液容器,透過中栓,使加熱蒸散用吸液芯的下部浸漬在加熱蒸散用水性殺蟲劑組成物中。如此一來,藥液容器內之加熱蒸散用水性殺蟲劑組成物導向加熱蒸散用吸液芯的上部,藉由設置在加熱蒸散裝置的上部之發熱體,加熱至60~130℃,蒸散至大氣中。加熱蒸散用吸液芯由於設置構成發熱體之中空筒狀的散熱筒體與間隙並成為對向,故加熱蒸散用吸液芯的上部之目的的表面溫度(例如為60~130℃),藉由將發熱體的溫度設置在較該溫度更高(例如為80~150℃)來達成。加熱蒸散用水性殺蟲劑組成物的加熱溫度過高時,加熱蒸散用水性殺蟲劑組成物早期蒸散,或有產生加熱蒸散用水性殺蟲劑組成物的熱分解或聚合的可能性,其結果,於加熱蒸散用吸液芯的表面生成高沸點物質,蓄積此有引起堵塞之虞。另一方面,加熱溫度過低時,加熱蒸散用水性殺蟲劑組成物蒸散變困難,變成無法達成充分之殺蟲性能。
根據本發明者們的研究,認為加熱蒸散用吸液芯的上部(外徑:6.7~7.3mm)、與和此對向之散熱筒體的內壁(內徑:10mm、高度:8~12mm)的位置關係,雖為間接性但有助於害蟲防除製品的侵入阻止效果。亦即,將與散熱筒體的內壁對向之加熱蒸散用吸液芯的上部的長度定為a,將散熱筒體的內壁的高度定為b時,比率(a/b)可藉由上下移動加熱蒸散用吸液芯的上部變更。在有關本發明之害蟲防除製品,上述之比率(a/b)可設定在0.1~1.3的範圍。於此,比率(a/b)超過1.0時,為加熱蒸散用吸液芯的上部突出自散熱筒體的上端的狀態。尚,認為比率(a/b)超過1.0時,除蟲菊酯系殺蟲成分每一單位時間的蒸散量雖增加,但尤其是不需要加熱蒸散用水性殺蟲劑組成物之蒸散量的增加時,較佳為將前述比率(a/b)設定在0.2~0.8。
作為害蟲防除製品使用之加熱蒸散裝置,除了前述之發熱體,可依照以往之裝置,成為可附設各種機能或構件者。雖於發熱體的上部載置安全上保護蓋,並於其中央部形成開口部,但只要加熱蒸散用水性殺蟲劑組成物不會過度凝縮、附著在保護蓋或器體,其大小及形狀可為任意。例如,將內徑10~30mm之圓筒狀蒸散筒從開口部附近垂下為有效,此情況下,從蒸散筒部分的耐熱性或蒸散性能的面來看,蒸散筒下端與發熱體上面的距離較佳為通常為1~5mm的範圍內。又,亦可適當附設與發熱體連接之電源線、開閉操作開關、指示燈等。
根據適用本發明之害蟲防除方法,於客廳或居室、寢室等之屋內,除蟲菊酯感受性系統當然不僅降低感受性之尖音家蚊、三斑家蚊、熱帶家蚊、地下家蚊等之家蚊類、埃及斑蚊、白線斑蚊等之伊蚊類、搖蚊類等,即使對於家蠅類、白斑蛾蚋類、蚤蠅類、虻類、蚋類、蠓類等之其他有害飛行性昆蟲,不僅實用的殺蟲效力,亦發揮有效率地阻止害蟲從屋外對屋內的侵入的效果。由於特別是對於蚊類之侵入阻止效果顯著優異,故為有用性極為高者。
[實施例]
以下,根據實施例,針對本發明之殺蟲效力增強劑、害蟲防除方法及加熱蒸散用水性殺蟲劑組成物的有效性進行說明。
[實施例1]
<加熱蒸散用水性殺蟲劑組成物>
摻合作為除蟲菊酯系殺蟲成分之拜富靈0.9質量%、作為殺蟲效力增強劑之甘醇系化合物即1,2-己烷二醇40質量%、作為水性有機化合物之3-甲氧基-3-甲基丁醇(Solfit)10質量%、作為安定劑之二丁基羥基甲苯(BHT)0.1質量%及純化水49質量%,調製加熱蒸散用水性殺蟲劑組成物。
<加熱蒸散用吸液芯>
於包含作為無機質粉體之雲母粉52質量%、作為無機質黏結劑之黏土粉33質量%、作為有機物質之石墨10質量%、作為有機質黏結劑之羧基甲基纖維素3質量%、澱粉2質量%之混合物,加入水進行混煉,一邊加壓混煉物一邊擠出,風乾後再以1100℃燒成,而得到加熱蒸散用吸液芯(直徑7mm、長度66mm之圓棒)。
<害蟲防除製品>
將加熱蒸散用水性殺蟲劑組成物45mL收容在塑膠製容器,透過中栓,裝填加熱蒸散用吸液芯後,安裝在加熱蒸散裝置[例如,日本專利第2926172號所記載之加熱蒸散裝置、於吸液芯的上部之周圍設置中空筒狀之散熱筒體(內徑:10mm、高度:10mm、表面溫度:137℃)],作為實施例1之害蟲防除製品。尚,與散熱筒體的內壁對向之加熱蒸散用吸液芯的上部的長度係散熱筒體的內壁的高度之0.7倍。
<害蟲防除效果確認試驗>
將實施例1之害蟲防除製品放置在6榻榻米之房間(25m3
)的中央,四個側面之一以打開面向屋外的窗的狀態,每1天通電12小時使用時,通過60天(約700小時),並未有蚊從窗侵入屋內刺咬人的情況。
[實施例2~16、比較例1~6]
依照實施例1,調製加熱蒸散用水性殺蟲劑組成物及加熱蒸散用吸液芯,並將此等裝填在加熱蒸散裝置,製作實施例2~16之害蟲防除製品。其中,針對實施例2~15之各害蟲防除製品,實施後述之(1)~(3)的測定及試驗。又,對於為了比較而製作之比較例1~6之害蟲防除製品,亦與實施例實施同樣之測定及試驗。將在各實施例及比較例之加熱蒸散用水性殺蟲劑組成物的配方及加熱蒸散用吸液芯的摻合分別示於表1~2。尚,表1亦記載實施例1之加熱蒸散用水性殺蟲劑組成物的配方及加熱蒸散用吸液芯的摻合。
[比較例7]
為了與水性配方之殺蟲劑組成物的比較,而調製油性配方之殺蟲劑組成物。具體而言,在比較例1之加熱蒸散用水性殺蟲劑組成物,調製未包含水性有機化合物(甘醇系化合物及甘醇醚系化合物)者,進而取代水改使用煤油(kerosene),而得到油性配方之殺蟲劑組成物(加熱蒸散用油性殺蟲劑組成物)。加熱蒸散用油性殺蟲劑組成物的蒸散所使用之加熱蒸散用吸液芯,使用與比較例1相同組成之燒成芯,並將此裝填在加熱蒸散裝置,作為比較例7之害蟲防除製品。針對比較例7之害蟲防除製品,亦與實施例實施同樣的測定及試驗。
(1)蒸散性能
於6榻榻米之房間(25m3
)的中央放置供試害蟲防除製品,並通電加熱。於使用初期(使用天數第2天),從加熱蒸散裝置離開上方1m之位置,使用二氧化矽凝膠填充管柱,捕集蒸散粒子,並以丙酮萃取殺蟲成分後,藉由氣相層析分析求出每一單位時間之殺蟲成分的蒸散量。
(2)殺蟲效力試驗
堆疊2層內徑20cm、高度43cm之塑膠製圓筒,並於其上透過16網目之絲網,載放內徑20cm、高度20cm之圓筒(放入供試昆蟲之場所),將其上同樣以16網目之絲網劃分,進而於其上以同徑載放高度20cm之圓筒。於將此堆疊4層之圓筒載放在台之圓板上,挾持橡膠包裝放置。於圓板中央有5cm之圓孔,於此圓孔之上放置供試害蟲防除製品並通電加熱。通電3小時後,於上部第3層之圓筒放入供試昆蟲之尖音家蚊雌成蟲約20隻。伴隨時間經過,數算落下仰臥之供試昆蟲,求出KT50
值。又,於曝露20分鐘後回收全供試昆蟲,於24小時後調查該等之致死率。殺蟲效力試驗係針對使用初期(使用天數第2天)及使用後期(有效期限之數天前)實施。
(3)侵入阻止率
於相鄰之10榻榻米的2居室的邊界設置窗,窗以外密閉。於另一居室放置供試害蟲防除製品,觀察者停留在室內,並且進行通電加熱而作為藥劑處理區。於相鄰之無藥放蟲區放入供試昆蟲之尖音家蚊雌成蟲100隻,通過窗,觀察從無藥放蟲區侵入藥劑處理區之供試蟲數60分鐘。又,由於設定效果判定的基準,故作為無處理對照區,同樣實施未使用害蟲防除製品之試驗。侵入阻止試驗係針對供試害蟲防除製品之使用初期(使用天數第2天)及使用後期(有效期限之數天前)重複2次實施。針對無處理對照區,亦同樣進行2次重複試驗,求出平均侵入蟲數,並藉由以下之式算出侵入阻止率。
侵入阻止率(%) = (C-T)/C × 100
C:無處理對照區之60分鐘的平均侵入蟲數(隻)
T:藥劑處理區之60分鐘的平均侵入蟲數(隻)
將在各實施例及比較例之測定及試驗結果示於表3。
由表1~3之結果,確認使用摻合本發明之殺蟲效力增強劑的加熱蒸散用水性殺蟲劑組成物之害蟲防除製品(實施例1~15),作為水性有機化合物,與僅摻合甘醇醚系化合物的以往品(比較例1)相比較,同樣顯示安定之蒸散性能之外,於殺蟲效力的點,亦發揮優異之增強效果。尤其是在擊倒效果與侵入阻止效果,認為有顯著的增強效果。又,比較拜富靈配方(實施例1)、美特寧配方(實施例3)、丙氟菊酯配方(實施例4)、右旋七氟甲醚菊酯配方(實施例5)及氯氟醚菊酯配方(實施例10)時,即使為於致死活性的點幾乎顯示同等之效力的配方,拜富靈配方係擊倒效果高,且於侵入阻止效果的點特異性優異。進而,從實施例12、實施例13及比較例1之對比,作為加熱蒸散用水性殺蟲劑組成物所使用之水性有機化合物,將其20質量%以上以甘醇系化合物構成時,觀察到提高擊倒效果及侵入阻止效果的傾向,為較佳者。
另一方面,作為加熱蒸散用水性殺蟲劑組成物所包含之水性有機化合物,包含即使為甘醇系化合物,亦具有羥基之2個碳原子不相鄰之1,6-己烷二醇(比較例2)、碳數為3之1,2-丙烷二醇(比較例3)及碳數為10之1,2-癸烷二醇(比較例4)者,並未觀察到殺蟲效果的增強。如此,於本發明特有之殺蟲效力增強作用是,對照在專利文獻2,1,2-己烷二醇與1,6-己烷二醇及1,2-丙烷二醇同列顯示揮散調整作用,是出乎意料的結果。又,為除蟲菊酯系殺蟲成分之蒸氣壓脫離本發明之範圍的d,d-T80-普亞列寧(比較例5及6)時,並未觀察到1,2-己烷二醇所看到之殺蟲效力增強作用,確認到本發明特有之效力增強作用是,只有在與有特定之蒸氣壓範圍之除蟲菊酯系殺蟲成分組合的情況,才會表現極為異質的效果。進而,並非水性配方,即使作為油性配方時(比較例7),亦無法得到充分之殺蟲效果。
[產業上之可利用性]
本發明雖為可作為人體或寵物用之害蟲防除製品利用者,但亦可作為其他用途,例如亦可於殺蟎、殺菌、抗菌、除臭及防臭的用途利用。
Claims (6)
- 一種殺蟲效力增強劑的使用,其係將甘醇系化合物作為有效成分之殺蟲效力增強劑,該甘醇系化合物係於碳數為4~7之烷烴的2個相鄰之碳原子各鍵結一個羥基,其特徵為摻合在加熱蒸散用水性殺蟲劑組成物,該殺蟲劑組成物係含有在30℃之蒸氣壓為2×10-4~1×10-2mmHg之除蟲菊酯系殺蟲成分,前述除蟲菊酯系殺蟲成分係選自由拜富靈、美特寧、丙氟菊酯、氯氟醚菊酯(meperfluthrin)及右旋七氟甲醚菊酯(heptafluthrin)所成之群組中之至少一種,前述甘醇系化合物係選自由1,2-丁烷二醇、1,2-戊烷二醇及1,2-己烷二醇所成之群組中之至少一種,前述加熱蒸散用水性殺蟲劑組成物中之除蟲菊酯系殺蟲成分的含量為0.1~3.0質量%,前述加熱蒸散用水性殺蟲劑組成物中之甘醇系化合物的的含量為2~70質量%。
- 如請求項1之殺蟲效力增強劑的使用,其中,前述加熱蒸散用水性殺蟲劑組成物係含有前述除蟲菊酯系殺蟲成分、與水性有機化合物、與水,前述水性有機化合物係其20質量%以上為以前述甘醇系化合物構成。
- 如請求項1或2之殺蟲效力增強劑的使用,其中,前述除蟲菊酯系殺蟲成分為拜富靈。
- 如請求項2之殺蟲效力增強劑的使用,其中,前述水性有機化合物係進一步含有甘醇醚系化合物。
- 如請求項4之殺蟲效力增強劑的使用,其中,前述甘醇醚系化合物係選自由二乙二醇單乙基醚、二乙二醇單異丙基醚、二乙二醇單丁基醚、二乙二醇單異丁基醚、二乙二醇單己基醚、二丙二醇單甲基醚、二丙二醇單丙基醚及3-甲氧基-3-甲基丁醇所成之群組中之至少一種。
- 一種害蟲防除方法,其係使用加熱蒸散用吸液芯之害蟲防除方法,其特徵為包含:於摻合如請求項1~5中任一項所記載之殺蟲效力增強劑的加熱蒸散用水性殺蟲劑組成物,浸漬前述加熱蒸散用吸液芯的下部之步驟、與藉由將由前述加熱蒸散用吸液芯的下部吸液之前述加熱蒸散用水性殺蟲劑組成物導向前述加熱蒸散用吸液芯的上部,並於80~150℃加熱,使前述除蟲菊酯系殺蟲成分蒸散至大氣中之步驟。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2019-129826 | 2019-07-12 | ||
JP2019129826 | 2019-07-12 |
Publications (2)
Publication Number | Publication Date |
---|---|
TW202116167A TW202116167A (zh) | 2021-05-01 |
TWI829942B true TWI829942B (zh) | 2024-01-21 |
Family
ID=74209849
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW109123155A TWI829942B (zh) | 2019-07-12 | 2020-07-09 | 殺蟲效力增強劑、害蟲防除方法及加熱蒸散用水性殺蟲劑組成物 |
TW112133975A TWI830684B (zh) | 2019-07-12 | 2020-07-09 | 殺蟲效力增強劑、害蟲防除方法及加熱蒸散用水性殺蟲劑組成物 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW112133975A TWI830684B (zh) | 2019-07-12 | 2020-07-09 | 殺蟲效力增強劑、害蟲防除方法及加熱蒸散用水性殺蟲劑組成物 |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP3964068A4 (zh) |
JP (2) | JP7346570B2 (zh) |
KR (1) | KR20220002598A (zh) |
CN (1) | CN114007425B (zh) |
AU (1) | AU2020313634B2 (zh) |
TW (2) | TWI829942B (zh) |
WO (1) | WO2021010195A1 (zh) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102581275B1 (ko) | 2022-01-07 | 2023-09-21 | 주식회사 성우하이텍 | 배터리 케이스용 크로스 멤버의 조립 장치 |
WO2024089230A1 (en) | 2022-10-28 | 2024-05-02 | Vebi Istituto Biochimico S.r.l. | Hydrocarbon alcohols and their derivatives as synergists in pesticide activity |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07316002A (ja) * | 1993-04-15 | 1995-12-05 | Earth Chem Corp Ltd | 加熱蒸散用水性薬剤及び加熱蒸散方法並びに加熱蒸散用水性薬剤の揮散性調整剤 |
CN102626082A (zh) * | 2011-02-04 | 2012-08-08 | 住友化学株式会社 | 热蒸散用杀虫材料和用于通过热蒸散控制害虫的方法 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0774130B2 (ja) | 1989-03-02 | 1995-08-09 | 大日本除蟲菊株式会社 | 液体式加熱蒸散用水性殺虫剤 |
JPH07100641B2 (ja) * | 1990-11-06 | 1995-11-01 | 大日本除蟲菊株式会社 | 加熱蒸散用水性殺虫剤の効力増強剤 |
JP2926172B2 (ja) | 1995-02-17 | 1999-07-28 | 大日本除蟲菊株式会社 | 加熱蒸散装置および加熱蒸散殺虫方法 |
WO2016140172A1 (ja) * | 2015-03-05 | 2016-09-09 | 大日本除蟲菊株式会社 | 加熱蒸散用水性殺虫剤組成物、及び加熱蒸散用水性殺虫剤組成物の加熱蒸散方法 |
JPWO2017130921A1 (ja) * | 2016-01-25 | 2018-09-27 | 大日本除蟲菊株式会社 | 害虫防除製品、及び害虫防除方法 |
CN108601339B (zh) * | 2016-01-25 | 2024-03-08 | 大日本除虫菊株式会社 | 加热蒸散用吸液芯及其制造方法以及使用该加热蒸散用吸液芯的加热蒸散方法 |
-
2020
- 2020-07-03 CN CN202080043613.7A patent/CN114007425B/zh active Active
- 2020-07-03 EP EP20840626.4A patent/EP3964068A4/en active Pending
- 2020-07-03 KR KR1020217039068A patent/KR20220002598A/ko not_active Application Discontinuation
- 2020-07-03 AU AU2020313634A patent/AU2020313634B2/en active Active
- 2020-07-03 JP JP2021532787A patent/JP7346570B2/ja active Active
- 2020-07-03 WO PCT/JP2020/026213 patent/WO2021010195A1/ja unknown
- 2020-07-09 TW TW109123155A patent/TWI829942B/zh active
- 2020-07-09 TW TW112133975A patent/TWI830684B/zh active
-
2023
- 2023-06-07 JP JP2023093914A patent/JP2023113861A/ja active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07316002A (ja) * | 1993-04-15 | 1995-12-05 | Earth Chem Corp Ltd | 加熱蒸散用水性薬剤及び加熱蒸散方法並びに加熱蒸散用水性薬剤の揮散性調整剤 |
CN102626082A (zh) * | 2011-02-04 | 2012-08-08 | 住友化学株式会社 | 热蒸散用杀虫材料和用于通过热蒸散控制害虫的方法 |
Also Published As
Publication number | Publication date |
---|---|
CN114007425A (zh) | 2022-02-01 |
JPWO2021010195A1 (ja) | 2021-12-09 |
TWI830684B (zh) | 2024-01-21 |
JP2023113861A (ja) | 2023-08-16 |
EP3964068A1 (en) | 2022-03-09 |
TW202400020A (zh) | 2024-01-01 |
CN114007425B (zh) | 2024-04-26 |
AU2020313634B2 (en) | 2023-11-09 |
WO2021010195A1 (ja) | 2021-01-21 |
KR20220002598A (ko) | 2022-01-06 |
EP3964068A4 (en) | 2023-01-11 |
JP7346570B2 (ja) | 2023-09-19 |
AU2020313634A1 (en) | 2021-12-16 |
TW202116167A (zh) | 2021-05-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
TWI711374B (zh) | 害蟲防除製品的使用方法及害蟲防除方法 | |
JP2002173407A (ja) | 飛翔昆虫忌避剤 | |
JP7364312B2 (ja) | 害虫忌避成分の選択的蒸散方法 | |
TWI829942B (zh) | 殺蟲效力增強劑、害蟲防除方法及加熱蒸散用水性殺蟲劑組成物 | |
JP2020120672A (ja) | 水性処方薬液加熱蒸散用吸液芯、及びその製造方法、並びに当該水性処方薬液加熱蒸散用吸液芯を用いた水性処方薬液加熱蒸散方法 | |
JP2020002173A (ja) | 害虫防除製品、及び害虫防除方法 | |
JP2023014145A (ja) | 害虫侵入阻止製品、及び害虫侵入阻止方法 | |
JP6321882B2 (ja) | 加熱蒸散用水性殺虫剤組成物、及び加熱蒸散用水性殺虫剤組成物の加熱蒸散方法 |